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1.
We characterize the precipitation and groundwater in a mountainous (peaks slightly above 3000 m a.s.l.), semi‐arid river basin in SE Spain in terms of the isotopes 18O and 2H. This basin, with an extension of about 7000 km2, is an ideal site for such a study because fronts from the Atlantic and the Mediterranean converge here. Much of the land is farmed and irrigated both by groundwater and runoff water collected in reservoirs. A total of approximately 100 water samples from precipitation and 300 from groundwater have been analysed. To sample precipitation we set up a network of 39 stations at different altitudes (800–1700 m a.s.l.), with which we were able to collect the rain and snowfall from 29 separate events between July 2005 and April 2007 and take monthly samples during the periods of maximum recharge of the aquifers. To characterize the groundwater we set up a control network of 43 points (23 springs and 20 wells) to sample every 3 months the main aquifers and both the thermal and non‐thermal groundwater. We also sampled two shallow‐water sites (a reservoir and a river). The isotope composition of the precipitation forms a local meteoric water line (LMWL) characterized by the equation δD = 7·72δ18O + 9·90, with mean values for δ18O and δD of − 10·28‰ and − 69·33‰, respectively, and 12·9‰ for the d‐excess value. To correlate the isotope composition of the rainfall water with groundwater we calculated the weighted local meteoric water line (WLMWL), characterized by the equation δD = 7·40δ18O + 7·24, which takes into account the quantity of water precipitated during each event. These values of (dδD/dδ18O)< 8 and d‐excess (δD–8δ18O)< 10 in each curve bear witness to the ‘amount effect’, an effect which is more manifest between May and September, when the ground temperature is higher. Other effects noted in the basin were those of altitude and the continental influence. The isotopic compositions of the groundwater are represented by the equation δD = 4·79δ18O − 18·64. The groundwater is richer in heavy isotopes than the rainfall, with mean values of − 8·48‰ for δ18O and − 59·27‰ for δD. The isotope enrichment processes detected include a higher rate of evaporation from detrital aquifers than from carbonate ones, the effects of recharging aquifers from irrigation return flow and/or from reservoirs' leakage and enrichment in δ18O from thermal water. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

2.
Stable isotope data on humid tropical hydrology are scarce and, at present, no such data exist for Borneo. Delta18O, δ2H and δ13C were analysed on 22 water samples from different parts of the Sungai (river) Niah basin (rain, cave drip, rainforest pool, tributary stream, river, estuary, sea) in north‐central Sarawak, Malaysian Borneo. This was done to improve understanding of the modern stable isotope systematics of the Sungai Niah basin, essential for the palaeoenvironmental interpretation of the Late Quaternary stable isotope proxies preserved in the Great Cave of Niah. The Niah hydrology data are put into a regional context using the meteoric water line for Southeast Asia, as derived from International Atomic Energy Agency/World Meteorological Organization isotopes in precipitation network data. Although the Niah hydrological data‐set is relatively small, spatial isotopic variability was found for the different subenvironments of the Sungai Niah basin. A progressive enrichment occurs towards the South China Sea (δ18O ?4·6‰; δ2H ?29·3‰; δ13C ?4·8‰) from the tributary stream (δ18O ?8·4‰; δ2H ?54·7‰; δ13C ?14·5‰) to up‐river (δ18O c. ?8‰; δ2H c. ?51‰; δ13C c. ?12‰) and down‐river values (δ18O c. ?7·5‰; δ2H c. ?45‰; δ13C c. ?11‰). This is thought to reflect differential evaporation and mixing of different components of the water cycle and a combination of depleted biogenic δ13C (plant respiration and decay) with enriched δ13C values (due to photosynthesis, atmospheric exchange, mixing with limestone and marine waters) downstream. Cave drip waters are relatively enriched in δ13C as compared to the surface waters. This may indicate rapid degassing of the cave drips as they enter the cave atmosphere. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

3.
Water samples were collected from cold and warm karst springs for stable isotopes (δ18O and δD) and 3H from SE of Kashmir valley (western Himalayas) to distinguish the sources of recharge and infer their recharge areas. The spring water samples were most depleted in heavier isotopes in May (average δ18O: ?8.87‰ and δD: ?50.3‰) and enriched in September (average δ18O: ?7.58‰ and δD: ?48.1‰). The depleted 18O and 2H of spring waters bear the signatures of winter precipitation while as the enriched 18O and 2H of spring waters bear the signature of summer rainfall. D‐excess and 3H corroborate with the stable isotope results that the spring flow in spring season (May) and autumn (September) is dominantly controlled by the melting of winter snowmelt and summer rainfall, respectively. The results showed that unlike δD, the δ18O value in the karst spring waters decreases in January suggesting δ18O shift. The spring water samples also fall above the Local Meteoric Water Line and Global Meteoric Water Line indicating the δ18O shift due to interaction of groundwater with the host carbonate rocks during its traverse. The mean elevation of the recharge areas of the springs using δ18O and δD tracers was also estimated. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

4.
A typical agricultural water reservoir (AWR) of 2400 m2 area and 5 m depth, located in a semi‐arid area (southern Spain), was surveyed on a daily basis for 1 year. The annual evaporation flux was 102·7 W m?2, equivalent to an evaporated water depth of 1310 mm year?1. The heat storage rate G exhibited a clear annual cycle with a peak gain in April (G ～ 45 W m?2) and a peak loss in November (G ～ 40 W m?2), leading to a marked annual hysteretic trend when evaporation (λE) was related to net radiation (Rn). λE was strongly correlated with the available energy A, representing 91% of the annual AWR energy loss. The sensible heat flux H accounted for the remaining 9%, leading to an annual Bowen ratio in the order of 0·10. The equilibrium and advective evaporation terms of the Penman formula represented 76 and 24%, respectively, of the total evaporation, corresponding to a annual value of the Priestley–Taylor (P–T) coefficient (α) of 1·32. The P–T coefficient presented a clear seasonal pattern, with a minimum of 1·23 (July) and a maximum of 1·65 (December), indicating that, during periods of limited available energy, AWR evaporation increased above the potential evaporation as a result of the advection process. Overall, the results stressed that accurate prediction of monthly evaporation by means of the P–T formula requires accounting for both the annual cycle of storage and the advective component. Some alternative approaches to estimating Rn, G and α are proposed and discussed. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

5.
Characterization of spatial and temporal variability of stable isotopes (δ18O and δ2H) of surface waters is essential to interpret hydrological processes and establish modern isotope–elevation gradients across mountainous terrains. Here, we present stable isotope data for river waters across Kyrgyzstan. River water isotopes exhibit substantial spatial heterogeneity among different watersheds in Kyrgyzstan. Higher river water isotope values were found mainly in the Issyk‐Kul Lake watershed, whereas waters in the Son‐Kul Lake watershed display lower values. Results show a close δ18O–δ2H relation between river water and the local meteoric water line, implying that river water experiences little evaporative enrichment. River water from the high‐elevation regions (e.g., Naryn and Son‐Kul Lake watershed) had the most negative isotope values, implying that river water is dominated by snowmelt. Higher deuterium excess (average d = 13.9‰) in river water probably represents the isotopic signature of combined contributions from direct precipitation and glacier melt in stream discharge across Kyrgyzstan. A significant relationship between river water δ18O and elevation was observed with a vertical lapse rate of 0.13‰/100 m. These findings provide crucial information about hydrological processes across Kyrgyzstan and contribute to a better understanding of the paleoclimate/elevation reconstruction of this region.  相似文献   

6.
Thermokarst lakes cover > 20% of the landscape throughout much of the Alaskan Arctic Coastal Plain (ACP) with shallow lakes freezing solid (grounded ice) and deeper lakes maintaining perennial liquid water (floating ice). Thus, lake depth relative to maximum ice thickness (1·5–2·0 m) represents an important threshold that impacts permafrost, aquatic habitat, and potentially geomorphic and hydrologic behaviour. We studied coupled hydrogeomorphic processes of 13 lakes representing a depth gradient across this threshold of maximum ice thickness by analysing remotely sensed, water quality, and climatic data over a 35‐year period. Shoreline erosion rates due to permafrost degradation ranged from < 0·2 m/year in very shallow lakes (0·4 m) up to 1·8 m/year in the deepest lakes (2·6 m). This pattern of thermokarst expansion masked detection of lake hydrologic change using remotely sensed imagery except for the shallowest lakes with stable shorelines. Changes in the surface area of these shallow lakes tracked interannual variation in precipitation minus evaporation (P ? EL) with periods of full and nearly dry basins. Shorter‐term (2004–2008) specific conductance data indicated a drying pattern across lakes of all depths consistent with the long‐term record for only shallow lakes. Our analysis suggests that grounded‐ice lakes are ice‐free on average 37 days longer than floating‐ice lakes resulting in a longer period of evaporative loss and more frequent negative P ? EL. These results suggest divergent hydrogeomorphic responses to a changing Arctic climate depending on the threshold created by water depth relative to maximum ice thickness in ACP lakes. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

7.
A disproportionate increase or decrease in water table in response to minor water input or drainage is observed in shallow water table conditions inside drainage lysimeters. This increase happens because the capillary fringe of the shallow water table reaches up to or near the surface (Wieringermeer effect). The correlations between water table level changes and rainfall, seepage irrigation, drip irrigation, and drainage were analysed. Correlations with rainfall, seepage irrigation, and drainage were high (R2 ranged from 0·46 to 0·97). Drip irrigation had low correlations due to the low rates of application (R2 ranged from 0·26 to 0·44). Conventional methods of calculating recharge, such as multiplying the specific yield with the water table fluctuations, cannot be used for Wieringermeer effect situations. A method using water balance data and soil moisture at different depths in the lysimeters was developed to estimate recharge and upflux. The recharge results were used to develop the apparent specific yield Sya, which could be used to calculate consequent recharge events from water table fluctuation data. Combining the water table fluctuation relationships developed with the Sya value will allow the prediction of recharge from rainfall and irrigation events without the need for soil moisture equipment. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

8.
Understanding flow pathways and mechanisms that generate streamflow is important to understanding agrochemical contamination in surface waters in agricultural watersheds. Two environmental tracers, δ18O and electrical conductivity (EC), were monitored in tile drainage (draining 12 ha) and stream water (draining nested catchments of 6‐5700 ha) from 2000 to 2008 in the semi‐arid agricultural Missouri Flat Creek (MFC) watershed, near Pullman Washington, USA. Tile drainage and streamflow generated in the watershed were found to have baseline δ18O value of ?14·7‰ (VSMOW) year round. Winter precipitation accounted for 67% of total annual precipitation and was found to dominate streamflow, tile drainage, and groundwater recharge. ‘Old’ and ‘new’ water partitioning in streamflow were not identifiable using δ18O, but seasonal shifts of nitrate‐corrected EC suggest that deep soil pathways primarily generated summer streamflow (mean EC 250 µS/cm) while shallow soil pathways dominated streamflow generation during winter (EC declining as low as 100 µS/cm). Using summer isotopic and EC excursions from tile drainage in larger catchment (4700‐5700 ha) stream waters, summer in‐stream evaporation fractions were estimated to be from 20% to 40%, with the greatest evaporation occurring from August to October. Seasonal watershed and environmental tracer dynamics in the MFC watershed appeared to be similar to those at larger watershed scales in the Palouse River basin. A 0·9‰ enrichment, in shallow groundwater drained to streams (tile drainage and soil seepage), of δ18O values from 2000 to 2008 may be evidence of altered precipitation conditions due to the Pacific Decadal Oscillation (PDO) in the Inland Northwest. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

9.
In the present study, the stable isotopes δ18O and δ2H were used for assessment of the water balance in a heterogeneously structured catchment area in the Lusatian Lignite Mining District, in particular, for estimation of the annual groundwater inflow and outflow (IGW and OGW) of Mining Lake Plessa 117. The application of stable isotopes was possible since the water exchange in the catchment area had reached steady‐state conditions after the abandonment of mining activities in 1968 and the filling of the voids and aquifers by re‐rising groundwater in the years thereafter. Diverging slopes of the Evaporation Line and the Global Meteoric Water Line manifested as evaporation from the lake catchment area. The calculated isotope water balance was compared with the commonly used surface water balance, which is unable to differentiate between IGW and OGW, and with a local groundwater model. The groundwater model calculated an IGW of about 811 000 m3 yr?1 and an OGW close to zero, whereas the isotope water balance showed fluxes of about 914 000 and 140 000 m3 yr?1, respectively. Considering the contribution of the groundwater inflow to the total annual input into the lake (ΔIT) and the mean residence time (τ), where the groundwater model and the isotope water balance calculated 42 and 47% for ΔIT and 4·3 and 3·9 years for τ, respectively, it was shown that both water balance calculation methods led to comparable results despite the differences in IGW and OGW. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   

10.
The coprecipitation method is widely used for the preconcentration of trace metal ions prior to their determination by flame atomic absorption spectrometry (FAAS). A simple and sensitive method based on coprecipitation of Fe(III) and Ni(II) ions with Cu(II)‐4‐(2‐pyridylazo)‐resorcinol was developed. The analytical parameters including pH, amount of copper (II), amount of reagent, sample volume, etc., were examined. It was found that the metal ions studied were quantitatively coprecipitated in the pH range of 5.0–6.5. The detection limits (DL) (n = 10, 3s/b) were found to be 0.68 µg L?1 for Fe(III) and 0.43 µg L?1 for Ni(II) and the relative standard deviations (RSD) were ≤4.0%. The proposed method was validated by the analysis of three certified reference materials (TMDA 54.4 fortified lake water, SRM 1568a rice flour, and GBW07605 tea) and recovery tests. The method was successfully applied to sea water, lake water, and various food samples.  相似文献   

11.
Recharge patterns, possible flow paths and the relative age of groundwater in the Akaki catchment in central Ethiopia have been investigated using stable environmental isotopes δ18O and δ2H and radioactive tritium (3H) coupled with conservative chloride measurements. Stable isotopic signatures are encoded in the groundwater solely from summer rainfall. Thus, groundwater recharge occurs predominantly in the summer months from late June to early September during the major Ethiopian rainy season. Winter recharge is lost through high evaporation–evapotranspiration within the unsaturated zone after relatively long dry periods of high accumulated soil moisture deficits. Chloride mass balance coupled with the isotope results demonstrates the presence of both preferential and piston flow groundwater recharge mechanisms. The stable and radioactive isotope measurements further revealed that groundwater in the Akaki catchment is found to be compartmentalized into zones. Groundwater mixing following the flow paths and topography is complicated by the lithologic complexity. An uncommon, highly depleted stable isotope and zero‐3H groundwater, observed in a nearly east–west stretch through the central sector of the catchment, is coincident with the Filwoha Fault zone. Here, deep circulating meteoric water has lost its isotopic content through exchange reactions with CO2 originating at deeper sources or it has been recharged with precipitation from a different rainfall regime with a depleted isotopic content. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

12.
Grazing is common in the foothills fescue grasslands and may influence the seasonal soil‐water patterns, which in turn determine range productivity. Hydrological modelling using the soil and water assessment tool (SWAT) is becoming widely adopted throughout North America especially for simulation of stream flow and runoff in small and large basins. Although applications of the SWAT model have been wide, little attention has been paid to the model's ability to simulate soil‐water patterns in small watersheds. Thus a daily profile of soil water was simulated with SWAT using data collected from the Stavely Range Sub‐station in the foothills of south‐western Alberta, Canada. Three small watersheds were established using a combination of natural and artificial barriers in 1996–97. The watersheds were subjected to no grazing (control), heavy grazing (2·4 animal unit months (AUM) per hectare) or very heavy grazing (4·8 AUM ha?1). Soil‐water measurements were conducted at four slope positions within each watershed (upper, middle, lower and 5 m close to the collector drain), every 2 weeks annually from 1998 to 2000 using a downhole CPN 503 neutron moisture meter. Calibration of the model was conducted using 1998 soil‐water data and resulted in Nash–Sutcliffe coefficient (EF or R2) and regression coefficient of determination (r2) values of 0·77 and 0·85, respectively. Model graphical and statistical evaluation was conducted using the soil‐water data collected in 1999 and 2000. During the evaluation period, soil water was simulated reasonably with an overall EF of 0·70, r2 of 0·72 and a root mean square error (RMSE) of 18·01. The model had a general tendency to overpredict soil water under relatively dry soil conditions, but to underpredict soil water under wet conditions. Sensitivity analysis indicated that absolute relative sensitivity indices of input parameters in soil‐water simulation were in the following order; available water capacity > bulk density > runoff curve number > fraction of field capacity (FFCB) > saturated hydraulic conductivity. Thus these data were critical inputs to ensure reasonable simulation of soil‐water patterns. Overall, the model performed satisfactorily in simulating soil‐water patterns in all three watersheds with a daily time‐step and indicates a great potential for monitoring soil‐water resources in small watersheds. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

13.
Pan evaporation (Ep) is an important indicator of water and energy and the decline of Ep has been reported in many regions over the last decades. The climate and Ep are dependent on each other. In this study, the temporal trends of Ep and main Ep drivers, namely mean air temperature (Ta), wind speed (u), global solar radiation (Rs), net long‐wave radiation(Rnl) and vapour pressure deficit (D) from 1970 to 2012, were calculated on the basis of 26 meteorological stations on the Tibetan Plateau. The arithmetic average of Ep from 26 stations decreased with the rate of ?11.91 mm a?2; the trends of Rs, Rnl, Ta, u and D were ?1.434 w m?2 decade?1, 0.2511 w m?2 decade?1, 0.3590°C decade?1, ?0.2376 m s?1 decade?1 and 9.523 Pa decade?1, respectively. The diffuse irradiance is an essential parameter to model Ep and quantify the contribution of climatic factors to changing Ep. 60 724 observations of Rs and diffuse solar irradiance (Rd) from seven of the 26 stations were used to develop the correlation between the diffuse fraction (Rd/Rs), and the clearness index (Rs/Ro). On the basis of the estimation of the diffuse component of Rs and climatic data, we modified the PenPan model to estimate Chinese micro‐pan evaporation (Ep) and assess the attribution of Ep dynamics using partial derivatives. The results showed that there was a good agreement between the observed and calculated daily Ep values. The observed decrease in Ep was mostly due to declining wind speed (?13.7 mm a?2) with some contributions from decreasing solar irradiance (?3.1 mm a?2); and the increase of temperature had a large positive effect (4.55 mm a?2) in total whilst the increase of Rnl had insignificant effect (0.35 mm a?2) on Ep rates. The change of Ep is the net result of all the climatic variables. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

14.
Estimates of sediment yield are essential in water resources analysis, modelling and engineering, in investigations of continental denudation rates, and in studies of drainage basin response to changes in climate and land use. The availability of high resolution, global environmental datasets offers an opportunity to examine the relationships between specific sediment yield (SYsp) and drainage basin attributes in a geographical information system (GIS) environment. This study examines SYsp at 14 long‐term gauging stations within the upper Indus River basin. Twenty‐nine environmental variables were derived from global datasets, the majority with a 1 × 1 km resolution. The SYsp ranges from 194 to 1302 t km?2 yr?1 for sub‐basins ranging from 567 to 212 447 km2. The high degree of scatter in SYsp is greatly reduced when the stations are divided into three groups: upper, glacierized sub‐basins; lower, monsoon sub‐basins; and the main Indus River. Percentage snow/ice cover (LCs) emerges as the single major land cover control for SYsp in the high mountainous upper Indus River basin. A regression model with percentage snow/ice cover (LCs) as the single independent variable explains 73·4% of the variance in SYsp for the whole Indus basin. A combination of percentage snow/ice cover (LCs), relief and climate variables explains 98·5% of the variance for the upper, glacierized sub‐basins. For the lower monsoon region, a regression model with only mean annual precipitation (P) explains 99·4% of the variance. Along the main Indus River, a regression model including just basin relief (R) explains 92·4% of the variance in SYsp. Based on the R2adj and P‐value statistics, the variables used are capable of explaining the majority of variance in the upper Indus River basin. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

15.
Small‐scale aerial photographs and high‐resolution satellite images, available for Ethiopia since the second half of the twentieth century as for most countries, allow only the length of gullies to be determined. Understanding the development of gully volumes therefore requires that empirical relations between gully volume (V) and length (L) are established in the field. So far, such V–L relations have been proposed for a limited number of gullies/environments and were especially developed for ephemeral gullies. In this study, V–L relations were established for permanent gullies in northern Ethiopia, having a total length of 152 km. In order to take the regional variability in environmental characteristics into account, factors that control gully cross‐sectional morphology were studied from 811 cross‐sections. This indicated that the lithology and the presence of check dams or low‐active channels were the most important controls of gully cross‐sectional shape and size. Cross‐sectional size could be fairly well predicted by their drainage area. The V–L relation for the complete dataset was V = 0 · 562 L 1·381 (n = 33, r2 = 0 · 94, with 34 · 9% of the network having check dams and/or being low‐active). Producing such relations for the different lithologies and percentages of the gully network having check dams and/or being low‐active allows historical gully development from historical remote sensing data to be assessed. In addition, gully volume was also related to its catchments area (A) and catchment slope gradient (Sc). This study demonstrates that V–L and V–A × Sc relations can be very suitable for planners to assess gully volume, but that the establishment of such relations is necessarily region‐specific. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

16.
Results from kinetic laboratory studies of reactions of the carbonate radical anion (CO3–·) with aromatic compounds in aqueous solution at T = 298 K are presented. Data were obtained in using a laser photolysis laser long-path absorption (LP-LPLA) apparatus which was designed for direct time-resolved studies of radical reactions. For the reactions of CO3–· with hydroquinone dimethyl ether (2), methyl anisole (3), benzene (4), p-xylene (5), toluene (6), chlorobenzene (7), nitrobenzene (8), and benzonitrile (9), rate coefficients of k2 = (3.0 ± 0.6)·107 M–1 s–1, k3 = (9.7 ± 1.7)·105 M–1 s–1, k4 = (3.2 ± 0.7)·105 M–1 s–1, k5 = (3.8 ± 0.9)·104 M–1 s–1, k6 = (6.8 ± 2.3)·104 M–1 s–1, k7 = (2.7 ± 0.6)·105 M–1 s–1, k8 = (1.4 ± 0.5)·104 M–1 s–1, and k9 < 1.3·102 M–1 s–1 were obtained. In further studies the effect of temperature on the reactions (2), (4), and (5) has been studied. The kinetic data obtained for the reaction of the carbonate radical anion with aromatic compounds were compared to the corresponding reactions of the hydroxyl radical. Finally, these kinetic data were used within a simple model system to investigate the implications of carbonate radical anion kinetics within water treatment processes. It is shown that the degradation of organic pollutants in ·OH-radical based water treatment may proceed via the CO3–·/HCO3· radical under certain conditions.  相似文献   

17.
The Manning equation is one of the most widely used formulae for calculating the velocity of shallow overland flow in hydrological and erosion models. Precise estimation of the Manning's friction coefficient (n) is critical to determining overland flow and soil erosion processes. Few studies have been conducted to quantify the effects of sediment load on Manning's n on steep slopes. This study was conducted to investigate the potential effects of sediment load on Manning's n in a flume with a fixed bed, under wide ranges of hydraulics and sediment loads. Slope gradient varied from 8·7 to 34·2%, unit flow rate from 0·66 to 5·26 × 10?3 m2 s?1, and sediment load from 0 to 6·95 kg m?1 s?1. The Reynolds number ranged from 350 to 5899. Results showed that Manning's n varied in both sediment‐free and sediment‐laden flows ranging from 0·012 to 0·055. The apparent Manning's coefficients of sediment‐laden flow were much greater than those of sediment‐free flow. The mean Manning coefficient of sediment‐laden flow was 51·27% greater than the mean value of sediment‐free flow. For sediment‐laden flow, Manning's n could be estimated with a power function of unit flow discharge and sediment content. Further studies are needed to quantify the potential effects of sediment load on the Manning's n on erodible beds and in fields. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

18.
18O is an ideal tracer for characterizing hydrological processes because it can be reliably measured in several watershed hydrological compartments. Here, we present multiyear isotopic data, i.e. 18O variations (δ18O), for precipitation inputs, surface water and groundwater in the Shingobee River Headwaters Area (SRHA), a well‐instrumented research catchment in north‐central Minnesota. SRHA surface waters exhibit δ18O seasonal variations similar to those of groundwaters, and seasonal δ18O variations plotted versus time fit seasonal sine functions. These seasonal δ18O variations were interpreted to estimate surface water and groundwater mean residence times (MRTs) at sampling locations near topographically closed‐basin lakes. MRT variations of about 1 to 16 years have been estimated over an area covering about 9 km2 from the basin boundary to the most downgradient well. Estimated MRT error (±0·3 to ±0·7 years) is small for short MRTs and is much larger (±10 years) for a well with an MRT (16 years) near the limit of the method. Groundwater transit time estimates based on Darcy's law, tritium content, and the seasonal δ18O amplitude approach appear to be consistent within the limits of each method. The results from this study suggest that use of the δ18O seasonal variation method to determine MRTs can help assess groundwater recharge areas in small headwaters catchments. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

19.
High‐resolution, spatially extensive climate grids can be useful in regional hydrologic applications. However, in regions where precipitation is dominated by snow, snowmelt models are often used to account for timing and magnitude of water delivery. We developed an empirical, nonlinear model to estimate 30‐year means of monthly snowpack and snowmelt throughout Oregon. Precipitation and temperature for the period 1971–2000, derived from 400‐m resolution PRISM data, and potential evapotranspiration (estimated from temperature and day length) drive the model. The model was calibrated using mean monthly data from 45 SNOTEL sites and accurately estimated snowpack at 25 validation sites: R2 = 0·76, Nash‐Sutcliffe Efficiency (NSE) = 0·80. Calibrating it with data from all 70 SNOTEL sites gave somewhat better results (R2 = 0·84, NSE = 0·85). We separately applied the model to SNOTEL stations located < 200 and ≥ 200 km from the Oregon coast, since they have different climatic conditions. The model performed equally well for both areas. We used the model to modify moisture surplus (precipitation minus potential evapotranspiration) to account for snowpack accumulation and snowmelt. The resulting values accurately reflect the shape and magnitude of runoff at a snow‐dominated basin, with low winter values and a June peak. Our findings suggest that the model is robust with respect to different climatic conditions, and that it can be used to estimate potential runoff in snow‐dominated basins. The model may allow high‐resolution, regional hydrologic comparisons to be made across basins that are differentially affected by snowpack, and may prove useful for investigating regional hydrologic response to climate change. Published in 2011 by John Wiley & Sons, Ltd.  相似文献   

20.
Polar Bear Pass is a large High Arctic low‐gradient wetland (100 km2) bordered by low‐lying hills which are notched by a series of v‐shaped valleys. The spring and summer hydrology of two High Arctic hillslope‐wetland catchments, a first‐order stream, 0·2 km2 Landing Strip Creek (LSC) and a larger second‐order basin, 4·2 km2 Windy Creek (WC), is described here. A water balance framework was employed in 2008 to examine the movement of water from upland reaches into the low‐lying wetland. Snowcover was low in both basins (<50 mm in water equivalent units), but they both exhibited nival‐type regimes. After the main snowmelt season ended, runoff ceased in the smaller catchment (LSC), but not at the larger basin (WC) which continued to flow throughout the summer. Both basins responded to summer rains in different ways. At LSC, late‐summer continuous streamflow occurred only when rainfall satisfied the large soil moisture deficit in the upper bowl‐shaped zone of the basin. At WC, the presence of thinly thawed, ice‐rich polygonal terrain within the stream channel and in the upper reaches of the catchment likely limited infiltration in these near‐stream zones and enhanced runoff in response to both moderate and high rainfall. Subsequently, seasonal runoff ratios differed between the two sites (0·19 vs 0·68) as did the seasonal storage + residual (+16 vs ?50 mm). This suggests that the post‐snowmelt season runoff response to summer precipitation is very much modified by the unique basin characteristics (soil‐type, vegetation, ground ice) and their location within each stream order type. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

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