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1.
—We have examined the effect of surface contamination on the attenuation and stiffness of compressional seismic waves in artificial cylindrical glass cracks that are partially saturated with water. The compression of the gap perpendicularly to its plane reduces the gap volume and forces the water to redistribute within the gap (conservation of volume of an incompressible liquid). On clean surfaces, the water can flow without significant resistance across the glass. This leads to a very low and almost constant attenuation over a wide frequency range (approx. 3 mHz to 10 Hz), while the sample stiffness is constant. In the case of propanol contaminated surfaces, both the attenuation and the stiffness are considerably higher than in the clean case, and display a considerable frequency dependence. Both effects can be explained with the Restricted Meniscus Motion Model. In this model, the redistribution of the liquid in the gap first leads to a change (increase) of the contact angle. The change of the meniscus curvature results in an increase of the pressure in the liquid and thus to a stiffening of the sample. When the resistive force, that prevents the contact line from sliding along the surface, is finally overcome, the contact line starts moving across the contaminated surface. The motion against the resistive force dissipates energy and increases the attenuation. The calculated data are in good agreement for both the clean and the contaminated case; the model parameters fall in the range that was established by independent experiments (e.g. ). 相似文献
2.
We present results of laboratory experiments to study the behavior of liquids moving in unsaturated wide-aperture fractures. A 5-mm-thick glass plate cut with a 1.7-mm aperture was used as a fractured rock analog to study behavior of film and capillary droplet flow modes. Flow rates ranged between 0.6 and 6.0 ml/min. Variability in the ambient barometric pressure, resulting from weather conditions, seemed to play a role in the natural selection of flow mode. For droplet mode, constant input conditions resulted in highly variable transport properties within the fracture. The advancing meniscus exhibited a dynamic contact angle that was a function of the droplet speed and much larger than the static contact angle. Flow rate was reduced due to the larger contact angle. Analytical expressions for droplet velocity and flow capacity are presented as a function of the dynamic rather than the static contact angle. 相似文献
3.
《Advances in water resources》2002,25(1):33-49
Experiments designed to elucidate the pore-scale mechanisms of the dissolution of a residual non-aqueous phase liquid (NAPL), trapped in the form of ganglia within a porous medium, are discussed. These experiments were conducted using transparent glass micromodels with controlled pore geometry, so that the evolution of the size and shape of individual NAPL ganglia and, hence, the pore-scale mass transfer rates and mass transfer coefficients could be determined by image analysis. The micromodel design permitted reasonably accurate control of the pore water velocity, so that the mass transfer coefficients could be correlated in terms of a local (pore-scale) Peclet number. A simple mathematical model, incorporating convection and diffusion in a slit geometry was developed and used successfully to predict the observed mass transfer rates. For the case of non-wetting NAPL ganglia, water flow through the corners in the pore walls was seen to control the rate of NAPL dissolution, as recently postulated by Dillard and Blunt [Water Resour. Res. 36 (2000) 439–454]. Break-up of doublet non-wetting phase ganglia into singlet ganglia by snap-off in pore throats was also observed, confirming the interplay between capillarity and mass transfer. Additionally, the effect of wettability on dissolution mass transfer was demonstrated. Under conditions of preferential NAPL wettability, mass transfer from NAPL films covering the solid surfaces was seen to control the dissolution process. Supply of NAPL from the trapped ganglia to these films by capillary flow along pore corners was observed to result in a sequence of pore drainage events that increase the interfacial area for mass transfer. These observations provide new experimental evidence for the role of capillarity, wettability and corner flow on NAPL ganglia dissolution. 相似文献
4.
Igor E. Agranovski 《洁净——土壤、空气、水》2007,35(1):111-117
A new personal bioaerosol sampler has been developed and verified as an efficient tool for monitoring of viable/non‐viable airborne microorganisms, including bacteria, fungi, and viruses. The operational principle of the device is based on continuous passage of an air sample through porous media submerged into a liquid layer. During motion along narrow and tortuous ways inside the porous media, the air stream is split into a large number of ultra small bubbles with the particulates are being scavenged by these bubbles and, thus, effectively trapped. The device was initially verified for monitoring of viable airborne bacteria and fungi, firstly, under controlled laboratory conditions and later in a field. It was demonstrated that bacterial recovery rates for these two groups of microorganisms were very high and the device was found to be fully feasible for such monitoring. The next step of the device investigation was performed in the laboratory on monitoring viable airborne viruses with a range of sensitivities to physical and biological stresses. As the result, the new personal sampler demonstrated a very high recovery rate even for viruses which are rather sensitive to environmental stress (Avian Influenza, SARS, Mumps, etc.). Some following field studies, undertook in a hospital and animal houses, also demonstrated an excellent performance of the new device for selective and reliable monitoring of viable airborne viruses even in environments highly contaminated by other microorganisms. This paper reviews the main development staged of the new personal bioaerosol sampler. 相似文献
5.
Horizontal and Vertical Well Comparison for In Situ Air Sparging 总被引：1，自引：0，他引：1
Charles R. Plummer James D. Nelson Gary S. Zumwalt 《Ground Water Monitoring & Remediation》1997,17(1):91-96
A laboratory study was conducted to determine the effectiveness ol vertical and horizontal well configurations for ground water remediation using in situ air sparging. A lexan lank was designed and constructed to allow both the visualization of air flow and quantitative measurement of the distribution of air flow. Two media, sand and glass beads. were tested with both Vertical and horizontal air sources. In each case, most of the air traveled through preferential channels as continuous flow rather than as discrete bubbles as reported in other studies. Liven though glass beads were selected to have the same grain-size distribution as the sand, air flow was quite different through the two media. Results show that glass beads are not a suitable material for modeling air flow through natural sediments. In this study, the horizontal well proved to be more effective than the vertical well by impacting more of the media with a uniform distribution of air throughout the media. The vertical well resulted in a nonuniform distribution of air flow with most of the air concentrated directly above the well. 相似文献
6.
Surface‐wetting properties are an important cause of changing the groundwater and two‐phase fluid flows. Various factors affecting the surface wettability were investigated in a parallel‐walled glass fracture with non‐aqueous phase liquid (NAPL) (gasoline, diesel, trichloroethylene, and creosote) wetted surfaces. First, the effect of the duration of NAPL exposure on wettability change was considered at pre‐wet fracture surfaces using the various NAPL species, and the result showed that the surface became hydrophobic after the exposure time of NAPL exceeded 2000 min. Second, the initial wetting state of the surface affected the timing when the wettability change begins as well as the extent of the wettability change in an NAPL‐wetted rock fractures. Under the dry condition, the wettability change was completed within a very short time of exposure to NAPL (~5 min), and then it finally reached the intermediate and weakly NAPL wetting (contact angle of 118°). Under the pre‐wet condition, a relatively long time of exposure (~5000 min) was needed to observe the obvious change of the surface wettability, which was changed up to strongly NAPL wetting (contact angle of 142°). Third, the wettability changed by NAPL exposure was stable and maintained for a long time, regardless of water flushing rate and temperature. Finally, the wettability change by the exposure of NAPL on parallel fracture surfaces was evaluated at various groundwater flow velocities. Result showed that groundwater flow velocity has an important impact upon measured contact angle. Although fracture surfaces were exposed to NAPL at the low groundwater flow velocity, the wettability was not changed from hydrophilic to hydrophobic when the contact time between NAPL and mineral surfaces was not sufficient owing to the pulse‐type movement of NAPL. This implies that the variation of exposure pattern due to groundwater flow on the wettability change can be an important factor affecting the wettability change of fracture surface and migration behaviour at natural fractured rock aquifers in case of NAPL spill. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
7.
— We studied experimentally the stability of the front between two immiscible fluids in a Hele-Shaw cell, which consists of two parallel glass plates separated by a narrow spacing. The fluid flow in a Hele-Shaw cell is governed by the Laplace's equation (pressure field) and Darcy's law (fluid transport), which makes of this experimental setup a two-dimensional analog of a porous medium (FABER, 1997). SAFFMAN and TAYLOR (1958) demonstrated that when the injected fluid is less viscous than the displaced one, the front between the fluids can be unstable and fingers may develop along the interface. We investigated the possibility of influencing the development of the Saffman-Taylor instability by modulating the injection pressure with weak periodic oscillations of low frequency (5 to 15 Hz). A series of experiments were performed, in which the evolution of the interface between the injected air and the displaced silicon oil was recorded with the help of a numerical photo camera. We observed that the oscillations of the injection pressure inhibit the development of fingers. We quantified the observed stabilization effect by performing a harmonic analysis of the shape of the front, and suggested an interpretation in terms of “stiffening” of the interface. 相似文献
8.
Michael C. Brooks William R. Wise Michael D. Annable 《Ground Water Monitoring & Remediation》1999,19(2):105-113
Two types of gas-phase flow patterns have been discussed and observed in the in situ air sparging (ISAS) literature: bubble flow and air channels. A critical factor affecting the flow pattern at a given location is the grain size of the porous medium. Visualization experiments reported in the literature indicate that a change in the flow pattern occurs around 1 to 2 mm grain diameters, with air channels occurring below the transition size and bubbles above. Analysis of capillary and buoyancy forces suggests that for a given gas-liquid-solid system, there is a critical size that dictates the dominant force, and the dominant force will in turn dictate the flow pattern. The dominant forces, and consequently the two-phase flow patterns, were characterized using a Bond number modified with the porous media aspect ratio (pore throat to pore body ratio). Laboratory experiments were conducted to observe flow patterns as a function of porous media size and air flow rate. The experimental results and the modified Bond number analysis support the relationship of flow patterns to grain size reported in the literature. 相似文献
9.
Fluid conductivity and elastic properties in fractures depend on the aperture geometry – in particular, the roughness of fracture surfaces. In this study, we have characterized the surface roughness with a log-normal distribution and investigated the transport and flow behaviour of the fractures with varying roughness characteristics. Numerical flow and transport simulations have been performed on a single two-dimensional fracture surface, whose aperture geometry changes with different variances and correlation lengths in each realization. We have found that conventional measurement of hydraulic conductivity alone is insufficient to determine these two parameters. Transient transport measurements, such as the particle breakthrough time, provide additional constraints to the aperture distribution. Nonetheless, a unique solution to the fracture aperture distribution is still under-determined with both hydraulic conductivity and transport measurements. From numerical simulations at different compression states, we have found that the flow and transport measurements exhibit different rates of changes with respect to changes in compression. Therefore, the fracture aperture distribution could be further constrained by considering the flow and transport properties under various compression states. 相似文献
10.
11.
A systematic numerical method has been presented to investigate the constitutive relationships between two-phase flow properties of horizontal fractures and aperture distributions. Based on fractal geometry, single rough-walled fractures are generated numerically by modified successive random addition (SRA) method and then aperture distributions with truncated Gaussian distribution are formed by shear displacement between lower and upper surfaces. (The truncated Gaussian distribution is used to describe aperture evolution under different normal stresses.) According to the assumption of two-dimensional porous media and local parallel plate model, invasion percolation approach is employed to model the two-phase flow displacement (imbibition) in generated horizontal fractures, in which capillary forces are dominant over viscous and gravity forces. For truncated Gaussian distributions, constitutive relationships from numerical simulation are compared to closed-form relationships and a good agreement is obtained. The simulation results indicate strong phase interference with the sum of two phase relative permeability values being less than one in the intermediate saturations. It is found that fracture properties related to residual saturations depend on spatial correlation of aperture distributions. Based on the simulation results, we proposed an empirical relationship between the fracture residual-saturation-rated parameters and the corresponding aperture distributions. 相似文献
12.
The effect of surface phenomena occurring at the interfaces between immiscible fluids and a solid on the seismic attributes of partially saturated rocks has not yet been fully studied. Meanwhile, over the past two decades considerable progress has been made in the physics of wetting to understand effects such as contact line friction, contact line pinning, contact angle hysteresis, and equilibrium contact angle. In this paper, we developed a new rock physics model considering the aforementioned effects on seismic properties of the rock with a partially saturated plane-strain crack. We demonstrated that for small wave-induced stress perturbations, the contact line of the interface meniscus will remain pinned, while the meniscus will bulge and change its shape through the change of the contact angles. When the stress perturbation is larger than a critical value, the contact line will move with advancing or receding contact angle depending on the direction of contact line motion. A critical stress perturbation predicted by our model can be in the range of ∼102−104 Pa, that is typical for linear seismic waves. Our model predicts strong seismic attenuation in the case when the contact line is moving. When the contact line is pinned, the attenuation is negligibly small. Seismic attenuation is associated with the hysteresis of loading and unloading bulk moduli, predicted by our model. The hysteresis is large when the contact line is moving and negligibly small when the contact line is pinned. Furthermore, we demonstrate that the bulk modulus of the rock with a partially saturated crack depends also on the surface tension and on the contact angle hysteresis. These parameters are typically neglected during calculation of the effecting fluid moduli by applying different averaging techniques. We demonstrate that contact line friction may be a dominant seismic attenuation mechanism in the low frequency limit (<∼10 Hz) when capillary forces dominate over viscous forces during wave-induced two-phase fluid flow. 相似文献
13.
Flow on fracture surfaces has been identified by many authors as an important flow process in unsaturated fractured rock formations. Given the complexity of flow dynamics on such small scales, robust numerical methods have to be employed in order to capture the highly dynamic interfaces and flow intermittency. In this work we use a three-dimensional multiphase Smoothed Particle Hydrodynamics (SPH) model to simulate surface tension dominated flow on smooth fracture surfaces. We model droplet and film flow over a wide range of contact angles and Reynolds numbers encountered in such flows on rock surfaces. We validate our model via comparison with existing empirical and semi-analytical solutions for droplet flow. We use the SPH model to investigate the occurrence of adsorbed trailing films left behind droplets under various flow conditions and its importance for the flow dynamics when films and droplets coexist. It is shown that flow velocities are higher on prewetted surfaces covered by a thin film which is qualitatively attributed to the enhanced dynamic wetting and dewetting at the trailing and advancing contact lines. Finally, we demonstrate that the SPH model can be used to study flow on rough surfaces. 相似文献
14.
David W. Ostendorf Ellen E. Moyer Yuefeng Xie R. V. Rajan 《Ground Water Monitoring & Remediation》1993,13(1):139-150
The diffusion of 2,2,4-trimethylpentane (TMP) and 2,2,5-trimethylhexane (TMH) vapors put of residually contaminated sandy soil from the U.S. Environmental Protection Agency (EPA) field research site at Traverse City, Michigan, was measured and modeled. The headspace of an intact core sleeve sample was swept with nitrogen gas to simulate the diffusive release of hydrocarbon vapors from residual aviation gasoline in and immediately above the capillary fringe to a soil-venting air flow in the unsaturated zone. The resulting steady-state profile was modeled using existing diffusivity and air porosity estimates in a balance of diffusive flux and a first order source term. The source strength, which was calibrated with the observed flux of 2,2,4-TMP leaving the sleeve, varied with the residual gasoline remaining in the core, but was independent of the headspace sweep flow rate. This finding suggested that lower soil-venting air flow rates were in principle as effective as higher air flow rates in venting LNAPL vapors from contaminated soils. The saturated vapor concentration ratio of 2,2,4-TMP to 2,2,5-TMH decreased from 6.6 to 3.5 over the duration of the experiments in an expression of distillation effects. The vertical profile model was tested against sample port data in four separate experiments for both species, yielding mean errors ranging from 0 to—24 percent in magnitude. 相似文献
15.
本文首次运用显微CT技术对中国早期料珠进行研究。X-射线衍射（XRD）及CT切片分析结果表明,河南淅川县马川墓地出土的料珠为玻璃珠,与西周时期的釉砂珠在结构上存在显著区别。显微CT技术为料珠材质的鉴定提供了一种新方法。结合玻璃珠的三维模型表明,战国时期玻璃珠内的气泡以球形为主,内部存在许多细小不规则的空隙,应是采用模压法工艺制造;这是在研究中首次发现战国时期采用模压法工艺制造玻璃珠。西汉时期玻璃珠内的气泡是纺锤状,应是采用拉制法工艺制造。显微CT技术能清晰无损地揭示古代玻璃珠内部结构特点,显示了该技术在古代玻璃珠制造工艺研究中有着广阔的运用前景。 相似文献
16.
Laboratory Study of Air Sparging: Air Flow Visualization 总被引：15，自引：0，他引：15
Wei Ji Amine Dahmani David P. Ahlfeld Jia Ding Lin Edward Hill III 《Ground Water Monitoring & Remediation》1993,13(4):115-126
Laboratory flow visualization experiments, using glass beads as the porous medium, were conducted to study air sparging, an innovative technology for subsurface contaminant remediation. The purpose of these experiments was to observe how air flows through saturated porous media and to obtain a basic understanding of air plume formation and medium heterogeneity effects. The experiments indicate that air flow occurring in discrete, stable channels is the most probable flow behavior in medium to fine grained water saturated porous media and that medium heterogeneity plays an important role in the development of air channels. Several simulated scales of heterogeneities, from pore to field, have been studied. The results suggest that air channel formation is sensitive to the various scales of heterogeneities. Site-specific hydrogeologic settings have to be carefully reviewed before air sparging is applied to remediate sites contaminated by volatile organic compounds. 相似文献
17.
Qingshu Yang Yan Li Jinfeng Zhou Xiaoxi Xie Yu Su Qingbao Gu Masashi Kamon 《水文研究》2013,27(22):3217-3226
The non‐aqueous phase liquid simulator was used to model and interpret the occurrence of a thin benzene‐contaminated soil layer 9.0 m below the groundwater table in an abandoned gas plant site. The simulator was first evaluated in column tests under similar conditions to the contaminated site. Saturation–capillary pressure (S–P) relationships were extended from the laboratory scale of the column tests to the field scale of the subsurface at the abandoned site. Dynamic boundary conditions were established in order to prevent the model from generating excessive vertical velocities. The modelled benzene layer formation process agreed well with the in situ observations. With falling and then rising of the water table, benzene release from the surface migrated downward and then upward and distributed itself below and above the water table. Biochemical degradation of benzene made the distribution discontinuous in the subsurface. These two factors resulted in the thin benzene‐contaminated layer below the groundwater table. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
18.
《Advances in water resources》1999,22(6):623-632
In a phreatic aquifer, fresh water is withdrawn by pumping from a recovery well. As is the case here, the interfacial surface (air/water) is typically assumed to be a sharp boundary between the regions occupied by each fluid. The pumping efficiency depends on the method by which the fluid is withdrawn. We consider the efficiency of both continuous and pulsed pumping. The maximum steady pumping rate, above which the undesired fluid will break through into the well, is defined as critical pumping rate. This critical rate can be determined analytically using an existing solution based on the hodograph method, while a Boundary Element Method is applied to examine a high flow rate, pulsed pumping strategy in an attempt to achieve more rapid withdrawal. A modified kinematic interface condition, which incorporates the effect of capillarity, is used to simulate the fluid response of pumping. It is found that capillarity influences significantly the relationship between the pumping frequency and the fluid response. A Hele-Shaw model is set up for experimental verification of the analytical and numerical solutions in steady and unsteady cases for pumping of a phreatic aquifer. When capillarity is included in the numerical model, close agreement is found in the computed and observed phreatic surfaces. The same model without capillarity predicts the magnitude of the free surface fluctuation induced by the pulsed pumping, although the phase of the fluctuation is incorrect. 相似文献
19.
Peter A. Waldner Martin Schneebeli Ute Schultze‐Zimmermann Hannes Flühler 《水文研究》2004,18(7):1271-1290
Water flow through a melting snow pack modifies its structure and stability and affects the release of water and nutrients into soils and surface waters. Field and laboratory observations indicate a large spatial variability on various scales of the liquid water content and flow, a dominant system feature currently not included in numerical models. We investigated experimentally water and dye tracer movement through microstructurally different snow pack horizons and the persistence of preferential flow paths. Naturally rounded snow of varying grain size was artificially packed to obtain well known conditions by sieving it into rectangular bins. Surface melt was induced with infrared lamps. The flow paths were visualized with tracers and liquid water content was monitored with time domain reflectometry probes. Vertical cuts through the snow pack were imaged. The dye tracer patterns allowed the two flow regimes ‘matrix flow’ and ‘preferential flow’ to be distinguished. Matrix flow is apparently dominated by film and capillary flow in the unsaturated snow matrix. The capillary barrier effect at a boundary between a fine over a coarse textured layer on matrix flow in snow was confirmed. In contrast, preferential flow appears as well‐defined flow fingers that advance from 0·1 to 1 cm s?1. During a melt phase, the advancing flow fingers enlarge and are only partially time invariant. It remains to be shown whether the continuum concept, including the Darcy–Buckingham law is apt to describe the extremely non‐linear nature of water flow and the travel time of solutes in snow under conditions of melt water percolation. Probably, snow packs that include faceted crystals and large variations in bulk density, feature more pronounced capillary barriers and preferential flow triggering, but also stronger impeding of fingers by lateral dispersion. Further, triggering and persistence of preferential flow is complicated by the usually transient infiltration rate. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
20.
Seven techniques designed to measure the dry aeolian deposition of dust on a desert surface were tested during field experiments in Niger, central‐west Africa. Deposition fluxes were measured during eight periods of 3–4 days each. Experimental techniques tested were the MDCO (marble dust collector) method, the Frisbee method, the glass plate method (optical analysis of dust deposited on glass surfaces using particle imaging software), the soil surface method (deposition on a simulated desert floor) and the CAPYR (capteur pyramidal) method. Theoretical techniques tested were the inferential method and the combination method (gradient method extended with a deposition term for coarse dust particles). The results obtained by the MDCO, Frisbee, inferential and combination methods could be directly compared by converting the data to identical standard conditions (deposition on a water surface producing no resuspension). The results obtained by the other methods (glass plate, soil surface, CAPYR) were compared relatively. The study shows that the crude (unconverted) deposition fluxes of the five experimental techniques were similar, while the crude deposition fluxes calculated by the two theoretical techniques were substantially higher, of the order of four to five times as high as for the experimental techniques. Recalculation of the data to identical environmental conditions (the standard water surface) resulted in nearly identical deposition fluxes for the MDCO, Frisbee, inferential and combination techniques, although the latter two still had slightly higher values (but the differences remained small). The measurements illustrate the need to include a grain shape factor in theoretical dust deposition models. Without such a factor, theoretical models overestimate the deposition. The paper also discusses the advantages and disadvantages of the techniques tested. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献