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《International Geology Review》2012,54(2):325-342
A review of 174 Soviet publications on physicochemical studies in magmatism, post-magmatic phenomena, origins of rocks, minerals ores, and related subjects, with particular attention to the impact of the derivations of Korzhinskiy of the Phase Rule upon modern physical chemistry in petrology. — V.P. Sokoloff 相似文献
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ZHANG Shao-nan 《沉积学报》1999,17(2):263-268
Quartz cementation is a very important diagenetic event and main porosity-occluding factor in the reservoir sandstones in middle Jurassic i n North Sea. Petrological studies indicate the quartz cementation is limited in shallower burial depth and increases significantly at depth around 3.5 - 4 km. T he amount of quartz cement increases with burial depth from an average of approx imately 4%-5 vol% at 2.5 km to 17%-20 vol% at 4 km. Highest abundances of quartz cement exceeds 28% which has been found in the Ness Formation. Variations in qu artz cementation between different sandstone facies is minimal for any one forma tion, with exception of the generally lower quantities present in the heterolith ic sandstone. Homogenisation temperatures of fluid inclusion in quartz overgrowt h from the North Sea reservoirs indicate that few quartz cement occur below the temperature 70 ℃～80 ℃, the onset of large volume quartz cement starts at the temperatures higher than 90 ℃ which suggests the quartz cementation is temperat ure - dependent during progressing diagenesis of sandstones. 相似文献
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《International Geology Review》2012,54(1):123-125
The authors by their own statement do not intend to make a general criticism of the work but which only to point out these specific errors: 1) There is no justification in assigning all the massifs to the junction zone of East and West Sayans. It is incomprehensible to include such dissimilar massifs as the gabbros of Kazyr and the granitic Kryzhin range, both because of age and form; 2) There are no chromite deposits in the West Sayans; 3) The use of an effusive-schist formation in the Upper Proterozoic is incorrect; it should read series; 4) What do Ordovician faults have to do with the Lysansk massifs? 5) There are serious errors and omissions in the petrography of the Lysansk complex, on which the authors elaborate; 6) The TiO2 deposits in gabbros were discovered not in 1956, as claimed, but in 1954 by two other geologists; 7) The sequence of the emergence of secondary minerals from a magmatic melt “can only be visualized;” 8) They object to “superimposing” an autometamorphic phase on the mineralization; 9) They object to the concepts of the origin of Lysansk intrusions, as being “in the dogmatic form of an article of faith.” — M.A. Klugman 相似文献
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V. L. Tauson S. V. Lipko K. Yu. Arsent’ev Yu. L. Mikhlin D. N. Babkin N. V. Smagunov T. M. Pastushkova I. Yu. Voronova O. Yu. Belozerova 《Geochemistry International》2017,55(9):753-774
The FeS2–Ag–Pt–As system was studied using hydrothermal thermogradient synthesis (with internal sampling) of pyrite crystals at a temperature of 500°C and pressure of 1 kbar in ammonium chloridebased solutions. The modes of occurrence of precious metals (PM) were determined using atomic absorption spectrometry (AAS) in its version of statistical selections of analytical data on single crystals (SSADSC), electron microprobe analysis (EMPA), scanning electron microscopy with energy-dispersive spectrometry (SEM-EDS), atomic force microscopy (AFM), and X-ray photoelectron spectroscopy (XPS). The concentration of Pt in its structural mode in pyrite is as high as 10–11 ppm and is practically not correlated with the As concentration. The dualistic distribution coefficient of Pt between pyrite and hydrothermal solution is 21 ± 7 for the structural mode and 210 ± 80 for the surface-related mode of this element. No inclusions of either any Pt-bearing minerals or Pt itself was detected. Platinum is an element highly compatible with hydrothermal pyrite and is different in this sense from gold, and pyrite is underestimated as a potential concentrator of platinumgroup elements (PGE). The distribution of Ag in pyrite is highly heterogeneous. The likely reason for this is that the Ag solid solution cannot be quenched, and hence, the Ag concentrations broadly vary and are very unsystematically distributed in natural pyrite crystals. Assuming this hypothesis, the limit for Ag accommodation in FeS2 can be estimated using SSADSC at 0.09 ± 0.06 wt % under the experimental parameters, and the distribution coefficient of the structural Ag mode is thereby evaluated at 1400 ± 700. When crystallizing together with FeS2 proustite (Ag3AsS3) near its melting point, forms mixtures with dervillite (Ag2AsS2), in which Ag deficit is counterbalanced by excess divalent As. The limit of As incorporation into pyrite under these conditions is ≤0.1 wt %. SEM-EDS and XPS data indicate that the surface phases are of three types. In the course of crystal growth, practically two-dimensional nonautonomous phases (NP) are aggregated into submicroscopic and micrometer-sized crystalline bodies (mesocrystals) that largely inherit their unusual minor-element composition from NP and are enriched in Ag, Pt, As, and other minor elements. NP and mesocrystals are enriched in Al, which was transferred into them from the Al-bearing Ti alloy of the reaction containers. Silver occur in the volume of the crystals and on their surface as monovalent silver sulfide. Arsenic was detected mostly in the form of di- and trivalent arsenic sulfides. Pentavalent arsenic oxide was identified only on the surface of the crystals and can be easily eliminated by ion milling. 相似文献
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《Chemie der Erde / Geochemistry》2017,77(1):121-130
Prosecco, one of the most popular sparkling wines in the world, is produced in Italy. For this reason, it is important to develop a scientific method for determining geographic origin in order to prevent fraudulent labelling. To establish the relationship between geochemistry of vineyard soil and chemical composition of grape, a geochemical characterization of “Glera”, a Vitis vinifera cultivar from Italian Region, Veneto was undertaken. We evaluated the relationship between major and trace elements in soil and their concentrations in “Glera” grape berries in vineyards belonging to five localities in the Veneto alluvial plain, all included in the Controlled Designation of Origin (DOC) area of Prosecco. A statistically significant correspondence between the soil and grape was observed for Sr. Multivariate analysis (LDA) allowed discrimination of samples of soil and grape berries from each single winery according to the geographic origin. The elements that could establish a reliable correspondence between the geolithological features of the vineyard soil and the chemical composition of grape berries are: Sr, Ba, Ca, Mg, Al, K, Zn, B, Ni, Co. 相似文献
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《Applied Geochemistry》1993,8(6):569-586
Crude oil floating on the water table in a sand and gravel aquifer provides a constant source of hydrocarbons to the groundwater at a site near Bemidji, Minnesota. The degradation of hydrocarbons affects the concentrations of oxidized and reduced aqueous species in the anoxic part of the contaminant plume that developed downgradient from the oil body. The concentrations of Fe2+, Mn2+ and CH4, Eh measurements, and the δ13C ratios of the total inorganic C indicate that the plume became more reducing ver a 5-a period. However, the size of the contaminant plume remained stable during this time. Field data coupled with laboratory microcosm experiments indicate that benzene and the alkylbenzenes are degraded in an anoxic environment. In anaerobic microcosm experiments conducted under field conditions, almost complete degradation (98%) was observed for benzene in 125 d and for toluene in 45 d. Concentrations of aqueous Fe2+ and Mn2+ increased in these experiments, indicating that the primary reactions were hydrocarbon degradation coupled with Fe and Mn reduction.Mass transfer calculations on a 40-m flowpath in the anoxic zone, downgradient from the oil body, indicated that the primary reactions in the anoxic zone are oxidation of organic compounds, precipitation of siderite and a ferroan calcite, dissolution of iron oxide and outgassing of CH4 and CO2. The major difference in the two models presented is the ratio of CO2 and CH4 that outgasses. Both models indicate quantitatively that large amounts of Fe are dissolved and reprecipitated as ferrous iron in the anoxic zone of the contaminant plume. 相似文献
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《Applied Geochemistry》1993,8(6):529-549
Changes in the distribution of inorganic solutes in a shallow ground water contaminated by crude oil document a series of geochemical reactions initiated by biodegradation of the oil. Upgradient of an oil body floating on the water table, oxidation of oil to carbonic acid dissolves carbonate minerals in the aquifer matrix. In this oxidized zone pH is depressed ∼1 pH unit, and the concentrations of Ca, Mg and HCO3− increase to more than twice that of the native ground water. In the anoxic zone beneath the oil body concentrations of dissolved SiO2, Sr, K, Fe and Mn increase significantly. Here, Fe is mobilized by microbial reduction, pH is buffered by the carbonate system, and silicates weather via hydrolysis and organic-acid-enhanced dissolution. Farther down-gradient the ground water is reoxygenated and Fe precipitates from solution, possibly as iron hydroxide or iron carbonates, while SiO2 precipitates as amorphous silica. Other solutes, such as Mg, are transported more conservatively down-gradient where contaminated and native ground water mix.The observed changes in inorganic aqueous chemistry document changes in water-mineral interactions caused by the presence of an organic contaminant. These organic-initiated interactions are likely present in many contaminated aquifers and may be analogous to interactions occurring in other organic-rich natural waters. 相似文献
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A. A. Konovalenko 《Astronomy Reports》2017,61(4):317-323
Radio astronomy at decameter wavelengths is currently undergoing very active development. Large-scale, new generation low-frequency radio telescopes are being constructed and already used in many countries around the world. As before, the largest, most sensitive, and most versatile telescope at decameter wavelengths is the Ukrainian UTR-2 radio telescope operating at 8–32 MHz, which has an effective area of more than 105 m2 and an angular resolution of about 0.5?, as well as the URAN interferometric system based on the UTF-2. Many studies that have been carried out on these facilities have been based on important results and far-sighted predictions of Shklovskii. These include, in particular, studies of dynamical spectra and the brightness distributions of the sporadic and quiescent decameter radio emission of the hot solar corona, complex, broadband radio spectroscopy of the interstellar medium, and multi-frequency monitoring of secular decreases in the flux densities of supernova remnants. The coordinated use of highly effective existing and newly constructed radio telescopes joined into ground networks, as well as specialized space missions, are opening new prospects for low-frequency radio astronomy. 相似文献
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《Applied Geochemistry》1993,8(3):301-304
MacGowan and Surdam (1990a) suggested some modifications to the model of Lundegard and Land (1989) to make it more geologically and geochemically reasonable. The predictive power of such a geochemical model is wholly dependent on the species modeled and the constants used; any model that excludes important species or important thermodynamic data, or one that couples certain reactions in an unrealistic way, may produce results which are not geologically or geochemically reasonable (W. K. Harrison, pers. commun., 1988; Y. K. Kharaka, pers. commun., 1991). We have long recognized that, under early-burial diagenetic conditions, aluminosilicate hydrolysis generally controls formation water pH (Surdam and Eugster, 1976; Mariner and Surdam, 1970; Taylor and Surdam, 1981) and that, during intermediate burial, either aqueous CO2 or CAA species (in the absence of aqueous S species or other weak conjugate acid-base pairs) will dominate formation water alkalinity and control pH (Surdam et al., 1989c). We reassert that the model of Lundegard and Land (1989) does not take into account the relative importance of PCO2 and of concentrations of both Ca2+ and CAA and their relative organic metal complexes to carbonate mineral stability in sandstones in the zone of intermediate burial clastic diagenesis (cf. the models of Surdam et al., 1984 and Surdam and Crossey, 1985). The usefulness of such models is predicted on the completeness of the model and the use of the best, most accurate thermodynamic data. Also, geologically realistic concentrations of critical species are required for reasonable modeling to be done. Although their model is vigorously defended in the discussion of Lundegard and Land, 1989, Lundegard and Land, 1993, we continue to disagree that their analysis of their model conditions are either geologically or geochemically satisfying.We agree with the fundamental approach and philosophy of Lundegard and Land, 1989, Lundegard and Land, 1993. It is of the utmost importance to determine from experimental, geochemical, petrographic, and geological data what the controls on pH and alkalinity in formation waters are, as well as the exact thermodynamic speciation of aqueous moieties and the stability of detrital and authigenic minerals. Lundegard and Land (1993) raise an additional point about CAA reaction with carbonate minerals in shales, although Fisher and Lewan (1989), Lewan (1989) and MacGowan and Surdam (1990b) have demonstrated that CAA generated in shale likely migrate in the oil phase along incipient shale microfractures to the sandstone reservoir, and thus are likely to not react much with the shale. Finally, we agree with Lundegard and Land that these areas require much additional experimental and field analysis, and petrographic study. 相似文献
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B. K. Bhadra A. K. Gupta J. R. Sharma 《Journal of the Geological Society of India》2009,73(6):875-877
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Kevin H. Johannesson W. Berry Lyons Suey Huey Georgia a. Doyle Eric E. Swanson Ed Hackett 《Aquatic Geochemistry》1997,3(1):61-97
Water samples were collected from the Truckee River-Pyramid Lake system, the Walker River-Walker Lake system, and the Carson River, all located in eastern California and western Nevada, U.S.A., at three different times (i.e., summer 1991, spring 1992, and autumn 1992) over a two year period. The concentrations of As, Na, Cl, PO4, and pH were measured in these river samples and the associated terminal lakes. Arsenic values ranged from below 13 nmol/kg near Truckee, California to 160 nmol/kg at Nixon, Nevada in the Truckee River, from 40 nmol/kg in the headwaters of both West and East Walker Rivers to 270 nmol/kg below Weber Reservoir on the main branch of the Walker River, and from <27 nmol/kg to 234 nmol/kg for the lower Carson River system. Arsenic concentrations in Steamboat Creek (0.91 mol/kg–1.80 mol/kg) in the Truckee River catchment are above the U.S. EPA drinking water maximum contaminant level of 0.67 mol/kg, as are the As concentrations in both Pyramid Lake (1.33 mol/kg–1.57 mol/kg ) and Walker Lake (13.7 mol/kg–18.7 mol/kg). Sources of As for all three rivers include weathering of As-rich rocks and/or regolith and input of high-As geothermal spring waters, both processes primarily, although not exclusively, adding As to the headwater regions of these rivers. Steamboat Hot Springs (29 mol/kg As 54.5 mol/kg), for example, is identified as a source of As to the Truckee River via Steamboat Creek. The high As concentrations in Pyramid and Walker Lakes are likely due to (1) desorption of arsenate from aquatic particulate matter in these high pH waters (9.0 pH 9.5), (2) limited biologic uptake of arsenate, and (3) evaporative concentration of the lake waters. Evaluation of molar PO4}/As ratios of river waters and geothermal spring waters (e.g., Steamboat Hot Springs), indicates that phosphate is substantially enriched in Steamboat Creek as well as the mid to lower reaches of the Walker and Carson Rivers. These regions of each river are dominated by agricultural interests and, additionally, in the case of Steamboat Creek, residential areas and golf courses. Our data strongly imply that phosphate-rich agricultural return flow has likely added P to these streams and, consequently, increased their respective P:As ratios. 相似文献
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Ju Y. Zhu R.-Z. Ni P. Wang G.-G. Ding J.-Y. Kang N. Zhu A.-D. Huang B. Zhou H. 《矿物岩石地球化学通报》2016,(6):1217-1225
The spinel coexisting with diamonds is often used as indicator mineral to evaluate the diamond-bearing potentiality of the kimberlite. In order to figure out the characteristics of spinels in the No. 30 kimberlite pipe, this paper has carried out detailed morphological observation and electron probe analysis on the spinels. The results show that spinels are elliptical and sub-Angular grains, with large particle diameter( 5(H)-1000 μm). A small amount of spinels shows erosional embay men t shape. With high contents of Cr2O3( up to 66. 56% ) and MgO ( 8. 88% - 16. 68% ) , and low TiO2, contents (mostly相似文献
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