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1.
川西龙泉山白垩系泥质岩的元素地球化学特征 总被引：1，自引：0，他引：1
龙泉山作为四川前陆盆地的前陆隆起带,记录了龙门山造山带地质构造演化的重要信息。本文对川西平原东侧龙泉
山白垩系泥质岩样品的进行了常量元素、微量元素和稀土元素测试,根据泥质岩的地球化学特征讨论了物源区的性质、构
造背景及风化等特征,为探讨龙门山与四川盆地的盆山耦合过程提供了地球化学方面的资料。研究区泥质岩的K2O/Al2O3,
Al2O3/TiO2,Cr/Zr 和Th/Sc 的比值均表明其物源区以长英质岩石为主;REE 配分模式中,（La/Yb）N 的均值为8.99,δEu的均
值为0.70,表现出轻、重稀土分馏程度较高并呈中等负Eu异常的特征;La-Th-Sc 和Th-Sc-Zr/10 三角图表明物源区经历了
大陆岛弧、活动大陆边缘和被动大陆边缘的地质构造演化过程;指示化学风化程度的CIA指数及成分成熟度的ICV指数的
平均值分别为71 和1.43,表明物源区经历了中等的风化作用,揭示了白垩纪时期物源区及四川盆地均属炎热的半干旱- 干
旱气候环境。 相似文献
2.
沙木罗组分布于班公湖-怒江缝合带内部,其沉积背景、源区性质与班-怒特提斯洋的演化息息相关。为了研究班怒带西段沙木罗组泥质岩的物源特征,探讨沉积盆地的构造背景和班-怒特提斯洋的俯冲消减时限,对泥质岩开展了全岩主量元素、微量元素地球化学的研究。地球化学组成特征显示,泥质岩的ICV、CIA、Al2O3/TiO_2、Th/Sc、Rb/Cs、(Gd/Yb)N、La、Ce、∑REE、La/Yb、(La/Yb)N、Eu/Eu*N和LREE/HREE均值分别为0. 80、72、21、0. 88、13. 5、1.58、42. 47×10-6、84. 81×10-6、200. 02×10-6、14. 22、9. 61、0. 65和9. 04,具有中等的Th、U、Hf含量(分别为16. 34×10-6、2. 85×10-6和4. 81×10-6)和Th/U、La/Th值(分别为5. 78和2. 61)。泥质岩的K2O/Na2O-SiO2、La-Th-Sc、ThCo-Zr/10、Th-Sc-Zr/10、TiO_2-Zr、Co/Y-Ti/Zr、La-Th-Sc、Th-Sc、La/Sc-Co/Th、REE-La/Yb、A-CN-K等关系图解具较好的指示意义,稀土元素特征亦具有一定的规律性。上述地球化学特征表明,泥质岩为成熟的泥质岩,源区矿物组成以斜长石、碱性长石为主,源区母岩主要为后太古宙花岗闪长岩、花岗岩、安山岩等中酸性岩浆岩和碎屑岩。泥质岩源区母岩经历了中等程度的化学风化作用,沉积物沉积时气候较温暖、湿润。不同层位的泥质岩地球化学特征指示了班怒带西段沙木罗组沉积于活动大陆边缘的构造背景,从剖面下部到上部可能反映了板块俯冲加剧、岩浆活动加强的地质过程,至少在141 Ma左右班-怒特提斯洋西段正在向北俯冲消减。 相似文献
3.
焦作煤田石炭-二叠纪泥质岩地球化学特征及古环境意义 总被引：2，自引：0，他引：2
泥质岩的地球化学特征蕴含了大量地质信息,在物源和沉积环境分析中的应用十分广泛。利用X射线荧光光谱仪和电感耦合等离子体质谱仪（ICP-MS）对华北板块南缘焦作煤田石炭-二叠纪泥质岩样品进行常量元素、微量元素（包括稀土元素）进行分析,并据此讨论泥质岩的物源性质、物源区岩石风化作用强度及当时古环境特征。研究区泥质岩的高Al2O3/TiO2值及低Cr/Zr和K2O/Al2O3值特征,以及泥质岩Zr-TiO2和Th/Co-La/Sc源岩判别图、Ni-Cr图和（Gd/Yb）N-Eu/Eu*图等的判别分析结果,都揭示了研究区泥质岩物源主要为后太古宙长英质岩石;Al2O3-CaO*+Na2O-K2O（A-CN-K）图和较高的黏土矿物成分反映了泥质岩源区受到钾交代作用的影响,致使CIA（化学蚀变指数）值被低估;高CIW（化学风化指数）值和Al2O3-CaO*-Na2O（A-C-N）判别图分析结果表明泥质岩物源区母岩在石炭-二叠纪经历了强烈的风化作用;Sr/Ba和B/Ga比值变化指示本溪组沉积时期到太原组沉积早期为海相为主的沉积环境,太原组沉积中期到山西组沉积早期为海陆过渡相为主的沉积环境,山西组沉积中期到上石盒子组沉积时期为陆相沉积环境。 相似文献
4.
西湖凹陷是东海陆架盆地重要的富生烃凹陷之一，平湖组是主要烃源岩和油气富集层系。为了探讨平湖组沉积期构造背景、源区性质及古环境，本文对平湖组泥质岩地球化学特征进行了研究。地球化学分析结果表明，平湖组沉积期同时具有大陆岛弧和活动大陆边缘构造背景。平湖组泥质岩的物源区母岩主要由上地壳岩石演化而来，并通过对比周围隆起区母岩特征，认为西侧的海礁隆起为西湖凹陷西部斜坡区平湖组沉积期的主要物源区，母岩主要以上地壳的长英质火成岩为主，并受到少量来自幔源岩浆和上地壳古生界变质岩系的影响，母岩类型主要为花岗闪长岩和英安质凝灰岩，少量安山岩和变质岩。泥质岩CIA分析表明，平湖组泥质岩的母岩经历了中等—强烈的风化作用，结合Sr/Cu值分析，推断西湖凹陷在平湖组沉积期古气候较为温暖湿润。微量元素和古盐度分析结果以及对盆地古地貌特征分析表明，西湖凹陷平湖组沉积期自北向南沉积背景有明显的地区差异性，北部（A- 1）沉积水体为淡水，主要发育河控三角洲沉积体系，而中部（A- 2）和南部（B- 1）表现为淡水和半咸水交替演化的特征，主要发育受潮汐影响三角洲沉积体系。平湖组泥质岩主要形成于含氧环境中。 相似文献
5.
本文以塔里木盆地西北缘苏盖特布拉克组泥质岩为对象,对其进行了主微量元素和稀土元素地球化学分析测试,并据此探讨苏盖特布拉克组的古沉积环境、物源属性及古构造背景。结果表明,泥岩中的Al、Fe、K、Ti、Li、Sc、Th、U、Ga、Cu元素明显富集;轻稀土元素富集且分馏程度强烈,重稀土相对亏损,且具明显的Eu负异常;泥岩的化学蚀变指数为60~80,多数样品的成分变异指数大于1.0。研究表明,研究区泥质岩形成于温暖湿润的浅海氧化环境,水体盐度较低;泥质岩为初次旋回沉积物,经历了中-低程度的化学风化作用,其母岩主要为上地壳长英质岩石,并混入了少量的基性岩、碱性岩与古老沉积物;源区构造背景以大陆岛弧环境为主,兼有活动大陆边缘特征。 相似文献
6.
利用泥质岩化学蚀变指数分析物源区风化程度时的限制因素 总被引：3，自引：2，他引：1
近年来,根据泥质岩中常量元素的摩尔数计算出的化学蚀变指数(CIA:Chemical index of alteration)、化学风化指数(CIW:Chemical index of weathering)和斜长石蚀变指数(PIA:Plagioclase index of alteration)被广泛用来反映物源区的风化程度及物源区古气候,这些指数在应用时都有一些严格的限制因素,应给予足够重视。CIA计算公式未排除成岩作用过程中钾交代作用的影响,需要采用A-CN-K[Al_2O_3-(CaO*+Na_2O)-K_2O]三角图进行判断,对发生钾交代作用的样品利用A-CN-K三角图或CIAcorr计算公式进行校正。CIW计算公式中去掉了K_2O,但没有排除钾长石中的Al元素。PIA计算公式中考虑了钾长石中的Al元素,但只适用于判断母岩中仅含有斜长石而不含钾长石的物源区风化程度。综合分析表明,在判断物源区风化程度及古气候时,CIA的干扰因素相对较少,值得推广。但即使利用从泥质岩常量元素获得的CIA值来判断物源区的风化程度时,仍需要考虑沉积分异作用、再旋回作用、沉积区进一步风化作用以及成土作用、成岩期的钾交代作用的影响,建议首先依据泥质岩常量元素的摩尔数计算出成分变异指数(ICV:Index of compositional variability),然后对ICV1的样品进行CIA的计算,并利用A-CN-K三角图或CIAcorr计算公式对CIA值进行钾交代作用的校正,该校正过的CIAcorr计算值可用来判断物源区的风化程度。 相似文献
7.
为探讨下扬子地区下寒武统幕府山组底部富有机质黑色岩系的物源属性及源区构造背景特征,在南京幕府山剖面幕府山组底部系统的采集样品,并对其进行地球化学测试与分析。Th/Sc?Zr/Sc图解表明幕府山组黑色岩系未曾经历沉积再循环;通过分析主量元素比值特征、稀土元素（REE）配分模式、δEu、（La/Yb）N及La/Th?Hf和La/Yb?∑REE判别图解,认为幕府山组黑色岩系源岩主要是花岗岩和富含长英质矿物的沉积岩等上地壳长英质岩石,存在基性岩的混入。从物源属性、地质年代关系、华南大陆构造演化历程等多方面考虑,源岩中花岗岩成分主要为新元古时期岩浆活动形成的岩浆岩,物源区为江南古陆（江南造山带）。通过分析K2O+Na2O?SiO2、K2O/Na2O?SiO2/Al2O3、La?Th?Sc、Th?Co?Zr/10和Th?Sc?Zr/10图解,认为幕府山组黑色岩系源区构造背景为被动大陆边缘。 相似文献
8.
广元恐龙化石埋藏地是四川盆地中侏罗世重要的恐龙化石点,恐龙化石埋藏于中侏罗统沙溪庙组之中。笔者对该恐龙化石埋藏地沙溪庙组泥质岩的常量元素、微量元素和稀土元素特征进行了研究,并根据泥质岩的地球化学特征讨论了物源区性质、构造背景以及物源区的风化特征。主量元素和稀土元素表明其物源区以长英质岩石为主,构造背景为被动大陆边缘:指示化学风化程度的CIA指数及成分成熟度的ICV指数,表明物源区经历了中等的化学风化作用,反映了中侏罗世恐龙生活在半干旱的古气候环境之中。 相似文献
9.
对佳木斯—兴凯地块西南缘的黄松群进行其物源区特点、古风化条件和构造背景等分析结果显示,该套变质碎屑岩源岩为泥砂质沉积岩,源区母岩以中酸性火成岩为主。风化作用相关指数CIA、CIW及PIA,由杨木组到阎王殿组逐渐增高,而ICV值则呈递减趋势,体现了风化作用由弱到强,成分成熟度逐渐升高的特点。主量元素特征值SiO_2=69.95%、TiO_2=0.58%、TFe_2O_3+MgO=5.34%、Al_2O_3/SiO_2=0.21,微量元素特征值La=37.54×10~(-6)、Ce=72.83×10~(-6)、δEu=0.60、ΣREE=182.29×10~(-6)。REE配分模式与活动大陆边缘碎屑沉积物类似,并且在不同构造环境判别图解中,绝大多数样品投影点落入活动大陆边缘区。地球化学特征表明,黄松群碎屑岩可能沉积于活动大陆边缘环境。 相似文献
10.
嫩江组泥岩的地球化学分析结果表明:泥岩中含有一定量的铁镁质组分和较多的稳定组分。微量元素和稀土元素分析结果显示,嫩江组含油页岩段沉积时期存在多个物源。CIA和PIA值没有随着埋深的减少而增加,说明嫩江组泥岩受后期风化影响很小。CIA值为70.5~77.0,Th/U值为2.67~3.98,说明泥岩源区经历了中等强度风化作用。Zr/Sc—Th/Sc图解表明泥岩的化学成分受源岩成分控制。通过源岩和构造背景判别图以及前人资料可知,松辽盆地嫩江组母岩主要为海西期花岗岩,源岩的构造背景为大陆边缘造山带火山岛弧岩系。物源中输入较多的铁镁及含钙物质,促进油页岩的形成。 相似文献
11.
Geochemical characteristics of the Middle Permian mudstones from the Longge Formation in the Jiaomuri area, central uplift zone of Qiangtang Basin have been analysed to constrain their provenance, tectonic setting, depositional redox condition and palaeoclimate. Based on the geochemical parameters like CIA, PIA, ICV values and Th/U, K/Rb ratios indicate that the source rocks were affected by low degree weathering conditions. The U/Th, V/Cr, Ni/Co, V/Sc ratios and Uau, C‐values of samples suggest that the mudstones were formed in an oxic environment, with arid palaeoclimate. Bulk‐rock geochemistry analysis indicates that they are mainly arkose and subarkose, derived from dominantly andesitic rocks, probably a mixing of felsic and mafic provenance. The CIA, PIA and ICV values of these samples suggest that the Longge mudstones are compositionally immature and related to moderate weathering. The tectonic discrimination diagrams, as well as critical trace and REE characteristic parameters imply an oceanic arc or continental arc setting for the depositional basin of mudstones from the Longge Formation, probably back‐arc basin. This study supports an occurrence of archipelagic oceanic basins in the Jiaomuri area in the Middle Permian, which provides evidence for the research of the Longmu Co–Shuanghu–Lancangjiang Suture. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
12.
The mineralogical and geochemical characteristics of the Upper Triassic Baluti shale from the Northern Thrust Zone (Sararu section) and High Folded Zone (Sarki section) Kurdistan Region, Iraq, have been investigated to constrain their paleoweathering, provenance, tectonic setting, and depositional redox conditions. The clay mineral assemblages are dominated by kaolinite, illite, mixed layers illite/smectite at Sararu section, and illite > smectite with traces of kaolinite at Sarki. Illite, to be noted, is within the zone of diagenesis. The non-clay minerals are dominated by calcite with minor amounts of quartz and muscovite in Sararu shale; and are dominated by dolomite with amounts of calcite and quartz in Sarki shale. Baluti shale is classified as Al-rich based on major and minor elements. The chemical index of alteration (CIA) is significantly higher in the Sararu than the Sarki shales, suggesting more intense weathering of the Sararu than the Sarki shales. The index of compositional variability (ICV) of the Sararu shale is less than 1 (suggesting it is compositionally mature and was deposited in a tectonically quiescent setting). More than 1 for Sarki shales (suggest it is less mature and deposited in a tectonically active setting). Most shale of the Baluti plot parallel and along the A-K line in A-CN-K plots suggest intense chemical weathering (high CIA) without any clear-cut evidence of K-metasomatism. Clay mineral data, Al enrichment, CIA values, and A-CN-K plot suggest that the source area experienced high degree of chemical weathering under warm and humid conditions, especially in Sararu. Elemental ratios critical of provenance (La/Sc, Th/Sc, Th/Cr, Th/Co, Ce/Ce*PN, Eu/Eu*PN, and Eu/Eu*CN) shows slight difference between the Sararu and Sarki shales; and the ratios are similar to fine fractions derived from the weathering of mostly felsic rocks. The Eu/Eu* CN, Th/Sc, and low K2O/Al2O3 ratios of most shales suggest weathering from mostly a granodiorite source rather than a granite source, consistent with a source from old upper continental crust. Discrimination diagrams based on major and trace element content point to a role of the felsic-intermediate sources for the deposition of Baluti Formation, and probably mixed with mafic source rocks at Sararu section. The chondrite-normalized rare earth elements (REE) patterns are similar to those of PAAS, with light REE enrichment, a negative Eu anomaly, and almost flat heavy REE pattern similar to those of a source rock with felsic components. The source of sediments for the Baluti Formation was likely the Rutba Uplift and/or the plutonic-metamorphic complexes of the Arabian Shield located to the southwest of the basin; whereas the Sararu shale was affected by the mafic rocks of the Bitlis-Avroman-Bisitoun Ridge to the northeast of Arabian Plate. The tectonic discrimination diagrams, as well as critical trace and REE characteristic parameters imply rift and active setting for the depositional basin of the shale of Baluti Formation. The geochemical parameters such as U/Th, V/Cr, V/Sc, and Cu/Zn ratios indicate that these shales were deposited under oxic environment and also show that Sarki shale was deposited under more oxic environment than Sararu. 相似文献
13.
The characteristics of source rocks and weathering of Palaeoproterozoic phyllitic rock of Mahakoshal Group and Mesoproterozoic shales and siliciclastics of Vindhyan Supergroup exposed in Son Valley, Central India have been investigated by analyzing their chemical compositions. The investigations pertaining to the relationship between major-elements were carried out along Parshoi, Chitrangi, and Markundi areas of Son valley, Central, India. The studied rock strata have been classified into three categories namely phyllitic rocks, shales and sandstone.The A-CN-K ternary diagram, CIW, CIA, MIA, and ICV values indicate about the similar provenance or source rocks subjected to severe chemical weathering, under dry and hot-humid climates in a basic and acidic environment with changing lower to higher PCO2 of continental flora. Various geochemical discriminantts diagrams, elemental ratios suggest that rocks are derived from post-Archaean-Proterozoic igneous source. The igneous source was mainly granite with a minor contribution of granodioritic rock, in a passive margin setting. The sediments responsible for formation of shale and sandstones were most likely deposited in the interglacial period in between the Mesoproterozoic and Neoproterozoic glacial times. Compositionally the sandstones is distinctive of cratonic environments with their passive continental margin setting. However, the phyllities of Mahakoshal Group suggests their formation under lower weathering conditions in dry climatic conditions which were operating on more intermediate to basic igneous rocks with abundance of mafic minerals. 相似文献
14.
《Chemie der Erde / Geochemistry》2019,79(2):384-398
Geochemical compositions of the Lower Cambrian Niutitang Formation shales in the southeastern Yangtze Platform margin were investigated for provenance, tectonic setting, and depositional environment. The shale samples are characterized by higher abundances of large ion lithophile elements (Cs, Ba, and Pb), lower abundances of high field strength elements (Cr, Sc, and Co) and transition elements (Th, Zr, Hf, Nb, and Ta) relative to average shale. North American shale composition (NASC) -normalized rare earth element (REE) patterns are observed, with negative Ce anomalies, negative Eu anomalies, and positive Y anomalies. The chemical index of alteration (CIA) varies from 68.67–74.93. Alkali and alkaline element contents and CIA values suggest that the source rocks have undergone moderate weathering. The index of compositional variability (ICV), Zr/Sc and Th/Sc ratios vary from 0.53 to 1.07, 5.31 to 8.18 and 0.52–1.02, respectively. ICV values and relationships between Zr/Sc and Th/Sc ratios indicate negligible sedimentary recycling. The Al2O3/TiO2 (14–26) and TiO2/Zr (56–77) ratios imply that the source rocks of the investigated shales had intermediate igneous compositions. However, Cr/V ratios and a La/Th–Hf discrimination diagram suggest that the intermediate compositional signal of the source rocks was derived from a mixture of 75% mafic and 25% felsic igneous rocks rather than intermediate igneous rocks. The major source was the Jiangnan continental island arc with bimodal igneous rocks, lying to the south of the study area, together with a contribution from granites and gneisses uplifted and eroded in the Yangtze Block. Discrimination of tectonic setting using major and trace elements indicates that the source rocks originated in a transitional setting from active continental to passive margin, consistent with the failed intracontinental rift model for the evolution of the South China plate. The Niutitang Formation shales were deposited in a rift basin setting under conditions of anoxic bottom water in a redox-stratified water column, with organic-rich shales prospective for shale-gas production being found in deep-water downslope and basin environments rather than the shallow-water shelf. 相似文献
15.
Cigdem Saydam Eker 《Geochemistry International》2012,50(8):683-701
Subaerial weathering level, source area and tectonic environments were interpreted by using petrographic and geochemical characteristics of Eocene age sandstones found in the eastern Pontides. The thickness of Eocene age clastic rocks in the eastern Pontides ranges from 195 to 400 m. Mineralogical components of sandstones were mainly quartz, feldspar, rock fragments, and opaque and accessory minerals. Depending on their matrix and mineralogical content, Eocene age sandstones are identified as arkosic arenite-lithic arenite and feldspathic wacke-lithic wacke. CIA (Chemical Index of Alteration) values observed in the Eocene age sandstones (43–55) suggest that the source terrain of the sandstones was not affected by intense chemical weathering. Low CIW/CIA (Chemical Index of Weathering/Chemical Index of Alteration) values of the sandstones studied here suggest only slightly decomposed material and having undergone little transport until final deposition. Zr/Hf, Th/Sc, La/Sc and CIA ratios are low and demonstrate a mafic source; on the other hand, high LREE/HREE ratios and a slightly negative Eu anomaly indicate a subordinate fclsic source. Modal mineralogical and SiO2/Al2O3 and K2O/Na2O and Th, Zr, Co, Sc of Eocene age sandstone contents indicate that they are probably magmatic arc originated and deposited in the back arc basin. 相似文献
16.
The Upper Kaimur Group of the Vindhyan Supergroup in Central India, primarily consists of three rock types-DhandraulSandstone,
Scarp Sandstone and Bijaigarh Shale. Mineralogically and geochemically, they are quartz arenite, sublitharenite to litharenite
and litharenite to shale in composition, respectively. The A-CN-K ternary plot and CIA and ICV values suggest that the similar
source rocks suffered severe chemical weathering, under a hot-humid climate in an acidic environment with higher P
CO
2, which facilitated high sediment influx in the absence of land plants. Various geochemical discriminants, elemental ratios
like K2O/Na2O, Al2O3/TiO2, SiO2/MgO, La/Sc, Th/Sc, Th/Cr, GdN/YbN and pronounced negative Eu anomalies indicate the rocks to be of post-Archean Proterozoic granitic source, with a minor contribution
of granodioritic input, in a passive margin setting. The sediments of the Upper Kaimur Group were probably deposited in the
interglacial period in between the Paleoproterozoic and Neoproterozoic glacial epochs. 相似文献
17.
中元古代常州沟组是华北克拉通北缘燕山地区变质结晶基底上的第一套沉积盖层,不整合覆盖于新太古代各类片麻岩之上。为了解常州沟组时期的古环境、古气候及其物质来源、构造环境和盆地性质,在野外地质调查的基础上,对常州沟组砂岩进行了粒度分析和地球化学分析测试。岩石组合、沉积构造和粒度分析结果指示区内常州沟组沉积环境演化由下至上依次为冲积扇、辫状河和碎屑潮坪。常州沟组砂岩地球化学特征具有高SiO2、Al2O3和K2O,低TiO2、Fe2O3、FeO、MgO含量的特点,成熟度较高,化学蚀变指数(CIA)介于52.00～73.23之间,化学风化作用指数(CIW)范围为93.04～98.68。由于岩石遭受钾交代作用影响,结合A-CN-K图解、Th/U-Th图解和古气候判别图综合分析,认为源区可能经历了较强的风化作用,古气候温暖、潮湿。Cr/Zr、Th/Sc、Ba/Sr、Rb/Sr值和La/Th-Hf图解指示常州沟组源区属性主要为上地壳环境,原岩成分以长英... 相似文献
18.
S.M. Moosavirad M.R. Janardhana M.S. Sethumadhav M.R. Moghadam M. Shankara 《Chemie der Erde / Geochemistry》2011,71(3):279-288
Lower Jurassic shales of the Shemshak Formation of Kerman Province, Central Iran, were analyzed for major and selected trace elements to infer their provenance, intensity of palaeoweathering of the source rocks and tectonic setting. Plots of shales on Al2O3 wt.% versus TiO2 wt.% diagram and Cr (ppm) versus Ni (ppm) diagram indicate that acidic (granitic) rocks constitute the source rocks in the provenance. Average CIA, PIA and CIW values (84%, 92%, 93%, respectively) imply intense weathering of the source material. Plots of shales on bivariate discriminant function diagram reveal an active continental margin setting for the provenance. The inferred tectonic setting for the Lower Jurassic shales of the Shemshak Formation of Kerman Province is in agreement with the tectonic evolutionary history of the Central Iran during the Jurassic period. 相似文献