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1.
淮南煤田深部A组煤中有害微量元素地球化学特征   总被引:1,自引:0,他引:1       下载免费PDF全文
以淮南煤田深部A 组煤为研究对象,全层刻槽采集了煤、夹矸和顶底板岩石样品,采用电感耦合等离子质谱仪 (ICP-MS) 测试分析了样品中13 种有害微量元素的含量,对比研究了其分布特征,结合Tessier 五步形态提取法和相关性分 析探讨了煤中有害微量元素的赋存形态。结果表明:(1) 与中国上陆壳中各种微量元素含量均值相比,淮南深部A 组煤中 B,As,Se,Mo,Cd,Pb,Hg 的富集系数均大于1,在A 组煤中表现为富集;A 组煤中B,As,Se,Cd 的含量均高于淮南煤 田上部B 组煤、华北煤以及中国煤中的含量均值;(2) 相关性分析和逐级提取实验结果表明,A 组煤中微量元素主要以残 渣态和铁锰氧化物结合态存在,两者质量分数之和达到55%~98%,其中Ni,Mo,Cd,Hg,Cu,Pb 和Zn 主要赋存于硫化物 矿物中,Mn 主要赋存于碳酸盐矿物中,V,Cr,Se,B 和As 主要赋存于硅铝酸盐等黏土矿物中。(3) B 元素示踪物源及沉 积环境结果显示,淮南煤田深部A 组煤成煤环境为海相咸水沉积环境,稳定的咸水沉积环境以及受海水影响等因素导致A 组煤中微量元素出现不同程度的富集。  相似文献   

2.
More than 130 Mt of Pennsylvanian coal is produced annually from two coal fields in Kentucky. The Western Kentucky Coal Field occurs in part of the Illinois Basin, an intercratonic basin, and the Eastern Kentucky Coal Field occurs in the Central Appalachian Basin, a foreland basin. The basins are only separated by 140 km, but mined western Kentucky coal beds exhibit significantly higher sulfur values than eastern Kentucky coals. Higher-sulfur coal beds in western Kentucky have generally been inferred to be caused by more marine influences than for eastern Kentucky coals.Comparison of strata in the two coal fields shows that more strata and more coal beds accumulated in the Eastern than Western Kentucky Coal Field in the Early and Middle Pennsylvanian, inferred to represent greater generation of tectonic accommodation in the foreland basin. Eastern Kentucky coal beds exhibit a greater tendency toward splitting and occurring in zones than time-equivalent western Kentucky coal beds, which is also inferred to represent foreland accommodation influences, overprinted by autogenic sedimentation effects. Western Kentucky coal beds exhibit higher sulfur values than their eastern counterparts, but western Kentucky coals occurring in Langsettian through Bolsovian strata can be low in sulfur content. Eastern Kentucky coal beds may increase in sulfur content beneath marine zones, but generally are still lower in sulfur than mined Western Kentucky coal beds, indicating that controls other than purely marine influences must have influenced coal quality.The bulk of production in the Eastern Kentucky Coal Field is from Duckmantian and Bolsovian coal beds, whereas production in the Western Kentucky Coal Field is from Westphalian D coals. Langsettian through Bolsovian paleoclimates in eastern Kentucky were favorable for peat doming, so numerous low-sulfur coals accumulated. These coals tend to occur in zones and are prone to lateral splitting because of foreland tectonic and sedimentation influences. In contrast, Westphalian D coal beds of western Kentucky accumulated during low differential tectonic accommodation, and therefore tend to be widespread and uniform in characteristics, but exhibit higher sulfur values because they accumulated in seasonally drier paleoclimates that were unfavorable for peat doming. Hence, basin analyses indicate that many differences between the mined coals of Kentucky's two coal fields are related to temporal changes in paleoclimate and tectonic accommodation, rather than solely being a function of marine influences.  相似文献   

3.
贵州省六枝新华煤矿区上二叠统含煤岩系及煤质特征   总被引:1,自引:0,他引:1  
袁月琴  张盛泽 《贵州地质》2007,24(2):110-113
贵州六枝特区新华煤矿上二叠统含煤岩系属于一套海陆交互相含煤建造。本文通过区域地质构造、地层背景及地球物理资料分析,探讨了该区含煤岩系基本特征、煤岩特征及煤的化学性质,认为该区煤质属于低-中灰,中-高硫煤,高-特高热值。通过脱硫处理,该区煤可满足电厂锅炉用煤之要求。  相似文献   

4.
About 7 Mt of high volatile bituminous coal are produced annually from the four coal zones of the Upper Paleocene Marcelina Formation at the Paso Diablo open-pit mine of western Venezuela. As part of an ongoing coal quality study, we have characterized twenty-two coal channel samples from the mine using organic petrology techniques. Samples also were analyzed for proximate–ultimate parameters, forms of sulfur, free swelling index, ash fusion temperatures, and calorific value.Six of the samples represent incremental benches across the 12–13 m thick No. 4 bed, the stratigraphically lowest mined coal, which is also mined at the 10 km distant Mina Norte open-pit. Organic content of the No. 4 bed indicates an upward increase of woody vegetation and/or greater preservation of organic material throughout the life of the original mire(s). An upward increase in telovitrinite and corresponding decrease in detrovitrinite and inertinite illustrate this trend. In contrast, stratigraphically higher coal groups generally exhibit a ‘dulling upward’ trend.The generally high inertinite content, and low ash yield and sulfur content, suggest that the Paso Diablo coals were deposited in rain-fed raised mires, protected from clastic input and subjected to frequent oxidation and/or moisture stress. However, the two thinnest coal beds (both 0.7 m thick) are each characterized by lower inertinite and higher telovitrinite content relative to the rest of Paso Diablo coal beds, indicative of less well-established raised mire environments prior to drowning.Foreland basin Paleocene coals of western Venezuela, including the Paso Diablo deposit and time-correlative coal deposits of the Táchira and Mérida Andes, are characterized by high inertinite and consistently lower ash and sulfur relative to Eocene and younger coals of the area. We interpret these age-delimited coal quality characteristics to be due to water availability as a function of the tectonic control of subsidence rate. It is postulated that slower subsidence rates dominated during the Paleocene while greater foreland basin subsidence rates during the Eocene–Miocene resulted from the loading of nappe thrust sheets as part of the main construction phases of the Andean orogen. South-southeastward advance and emplacement of the Lara nappes during the oblique transpressive collision of the Caribbean and South American tectonic plates in the Paleocene was further removed from the sites of peat deposition, resulting in slower subsidence rates. Slower subsidence in the Paleocene may have favored the growth of raised mires, generating higher inertinite concentrations through more frequent moisture stress. Consistently low ash yield and sulfur content would be due to the protection from clastic input in raised mires, in addition to the leaching of mineral matter by rainfall and the development of acidic conditions preventing fixation of sulfur. In contrast, peat mires of Eocene–Miocene age encountered rapid subsidence due to the proximity of nappe emplacement, resulting in lower inertinite content, higher and more variable sulfur content, and higher ash yield.  相似文献   

5.
晋北-宁北煤中痕量元素的地球化学特征   总被引:2,自引:1,他引:2  
应用仪器中子活化 (INAA)、电感耦合等离子体原子发射光谱 (ICP- AES)和原子吸收光谱 (AAS)等方法测定了晋北-宁北一线 5对矿井、 2个露天矿、 5个电厂和 3个洗煤厂煤中环境敏感性痕量元素的含量;通过与中国土壤、其他地区煤以及世界范围煤中痕量元素含量进行对比,总结了研究区痕量元素的分布、富集特征,得知部分地区煤中 Hg、 Cd和 Se的含量较高,在燃烧利用过程中可能对环境造成影响.通过分析痕量元素与灰分、挥发分的相关性以及痕量元素间、痕量元素与 Al、 Fe和 Sp的相关、聚类特性,探讨了痕量元素间及其与矿物质间的亲合性及赋存特征.  相似文献   

6.
西南寒武、二叠系富硒碳质岩中硒结合态的比较研究   总被引:6,自引:0,他引:6  
使用硒的7步连续化学提取技术,对采自贵州寒武纪牛蹄塘组和湖北恩施二叠纪茅口组富硒碳质岩中的水溶态、可交换态、有机态、元素态、酸性提取态、硫化物/硒化物态和残渣态硒进行了比较研究,应用氢化物-原子荧光法测定了岩石总硒和各结合态硒。结果表明,恩施二叠纪沙地新鲜富硒碳质硅质岩和碳质页岩中的硒主要以有机结合态和硫化物/硒化物态硒为主,残渣态硒较低;遵义松林早寒武世碳质硅质岩中的硒主要以有机结合态和硫化物态硒为主,碳质页岩与镍钼矿层中则以有机结合态、残渣态和硫化物态硒为主,斑脱岩中主要以有机结合态、元素态和可交换态硒为主。根据硒结合态的这种分布特征,推测二叠纪、寒武纪富硒碳质岩中硒初始富集的生物地球化学过程略有差异:前者碳质硅质岩中主要以微生物还原为主,碳质页岩中则是微生物还原作用和生物同化吸收或吸附兼而有之;后者主要以生物同化吸收或吸附为主,微生物还原次之。  相似文献   

7.
煤中硫是多种有害微量元素的重要载体。基于形态硫分析、电感耦合等离子质谱及X射线衍射等方法分析沁水盆地晚古生代煤中硫和有害微量元素的分布规律,探讨了煤中硫对有害微量元素富集的影响,运用带能谱的扫描电镜和光学显微镜划分煤中硫化物的微观赋存特征。结果表明,沁水盆地煤中硫整体上以有机硫为主,平均占全硫的78%,只有在太原组个别高硫煤中以黄铁矿硫为占优势。显微镜和扫描电镜下可识别出煤中黄铁矿的微观赋存状态包括莓球状、薄膜状、晶粒状、结核状、团窝状黄铁矿和细粒黄铁矿集合体,白铁矿的微观赋存特征包括聚片状、板状和矛头状白铁矿,部分白铁矿与黄铁矿共生。沁水盆地煤中有害微量元素含量整体较低,黄铁矿是有害微量元素As、Se和Hg的重要载体,而有机硫决定了煤中U的富集。研究认为,成煤时期海水对泥炭沼泽的影响导致太原组煤中全硫和黄铁矿硫较高,太原组煤中硫的来源具有多样性,煤中黄铁矿具有多阶段演化的特点。  相似文献   

8.
Sulfur is one of the havardous elements in coal The concentrations of sulfur are relatively high in coal.The major forms of sulfur in coal are pyritic,organic and sulfate.Pyritic and organic sulfur generally account for the bulk of sulfur in coal.Elemental sulfur also occurs in coal,but only in trace to minor amounts.When coals are burned,leached and washed,sulfur will be released in the form of sulfide and H2S,which then reach with O2,water and other substances to change into vitriol,and in some places it may form acid rain.And they will impact water environment,acidify the soil and do great harm to plants and human health.In this paper,on the basis of the data from the Yanzhou mining district,the distribution and concentrations of sulfur are analyzed and the existing forms of sulfur are studied.The variation of sulfur and its impact on the environments also are described when coal is used.  相似文献   

9.
The producibility of methane at economic rates from thick and very gassy coals in the Canadian Foothills and Mountains remains a major challenge. These structurally deformed, and often sheared, coals are generally characterized by low permeabilities, which is the main limiting factor restricting the flow of gas through natural fractures. A preliminary evaluation of the cleating in the coals and of the jointing in the interburden clastics was carried out in the Elkview mine of SE British Columbia. Field observations were supplemented by microscopic evidence on coal microtextures produced by shearing and their impact on coal permeability. Permeability of the coals tested at simulated in situ stress conditions and parallel to bedding surfaces was highly variable, ranging from 2.09 md in Seam 3, Greenhills mine, to less than 0.001 md in the sheared Seam 10, Elkview mine. This variation may be rationalized based on variations in maceral composition, stress history, degree of shearing, and the mode of deformation of the coal seams in these tectonically complex regions. Shearing gave rise to a variety of complex textures in coal, such as slickensides, shear cones and striated features, small-scale thrusts in the hangingwall, and brittle and ductile microtextures. Furthermore, the coal seams act as aquitards to the flow of water, most likely because of low permeability. Water flow occurs at the contact between coal and interbedded coarser clastics and within the highly fractured and jointed sandstone units. The cone of effective depressurization required for coal gas drainage to occur in the study area is influenced by: (a) the development of a joint system in the more competent clastic beds that would provide the high permeability pathways for water and gas, and (b) the ability of the rocks above the coals to re-pressurize as a result of either surface recharge or water flow both laterally and vertically within the succession. Therefore, multidisciplinary studies of hydrology, coalification history, and structure would help increase our understanding of the mechanisms and timing of cleat development, effect of shearing on coal permeability, and presence of systematic fractures in the non-coaly lithologies.  相似文献   

10.
本文通过对测水组岩石学、生物学、地球化学等方面的综合研究,认为测水组形成于障壁沙坝-潮坪-泻湖沉积体系中,并详细论述了各沉积环境的沉积特征。同时提出了测水组煤层形成的三种环境,并且对不同环境中形成的煤层特征进行了论述。  相似文献   

11.
根据地质勘探资料和煤心煤样的分析结果,对贵州金沙安洛区北段煤中硫的时空分布以及煤中硫与沉积环境的关系进行了研究。结果表明,该区形成于以潮坪为主的过渡相环境,由于沉积过程中受海水影响,煤中硫的质量分数总体偏高;但由于海水对煤层作用的强度不一,使不同煤层或同一煤层不同部位硫的质量分数差异很大,而且煤中硫的质量分数变化与煤层顶底板的古地理环境有关。   相似文献   

12.
潘集煤矿二叠纪主采煤层中微量元素亲和性研究   总被引:5,自引:0,他引:5  
安徽淮南煤田位于华北地台南端 ,发育了华北地区二叠纪含煤岩系中层位最高的可采煤层。采用仪器中子活化分析法 (INAA)测试了淮南煤田潘集煤矿二叠纪主采煤层 13个样品的 36个微量元素的浓度分布 ,并对其共生组合特点、地球化学特征及稀土元素配比模式作了初步分析 ,结果表明 ,煤中不同微量元素显示出不同的亲和性质。元素Br,As ,Sb ,Ni和Co等趋于在煤中富集 ,其中Br的有机亲和性最大。元素Na ,K ,Rb ,Th ,Hf,Zr ,Ta和REE则在煤层与顶底板接触带的碳质泥岩中富集 ,表现出与细粒陆源碎屑物更强的亲和性。其它元素倾向性不甚明显 ,但Fe ,Ca ,Sr ,HREE等元素在海水影响强度增大的煤层中含量增加。元素As,Cs,Ni,Fe和Ca在煤层中含量变化较大 ,其变异系数大于 1,其它元素则相对稳定 ,表明同一矿区煤层中微量元素含量在不受其它地质作用明显叠加影响时具有一定的稳定性。本区煤层稀土元素配比模式与华北其它地区C—P纪煤基本类似 ,普遍存在Eu亏损现象。 ∑REE在煤中分布范围为30× 10 -6~ 95× 10 -6,在顶板泥岩中超过 2 0 0× 10 -6。煤层中部 ∑REE降低 ,HREE相对富集。聚类分析表明 ,元素As ,Se ,Ag和Fe关系密切 ,这与煤中黄铁矿等成岩矿物有直接关系 ,泥炭沼泽演化期间或之后海水的直接或间接影响会促使这  相似文献   

13.
中国煤中硫的地球化学研究   总被引:16,自引:0,他引:16  
燃烧过程中,煤中硫会以硫氧化物等形式释放出来,污染大气以至形成酸雨,对环境造成极大的影响。本文在对中国煤中硫全面分析的基础上.总结并分析了中国煤中硫在不同地区、不同煤层和不同形成环境中的含量与分布规律,阐述煤中硫形成的地质成因和影响因素.以及育机硫、无机硫和元素硫的赋存状态.概述了煤利用过程中硫的转化机理及其对环境的影响.提出了对煤中硫的研究趋势和今后研究方向与热点问题。  相似文献   

14.
Carbohydrates react with hydrogen sulfide under low temperature (100° to 200°C) yielding a variety of organosulfur compounds including thiophenes, thiols, sulfides and sulfones. A polymer is also produced, whose elemental composition is within the range of natural coals. When reductive dehydration is carried out in the presence of hydrocarbon, organosulfur compounds are formed in the carbon number range of the hydrocarbon used. In these processes, an active hydrogen transfer catalyst is produced which facilitates the passage of hydrogen between normal paraffins and saccharide units, distributing sulfur between these two families primarily in the form of thiophene rings. The simplicity of these systems—H2S, carbohydrates, H2O, hydrocarbon—and the facility of the chemistry would suggest that the carbohydrates and hydrogen sulfide may be important agents in the diagenetic processes leading to petroleum and coal. Carbohydrate reduction by hydrogen sulfide may constitute an important route through which certain organosulfur compounds found in petroleum and coal entered these materials in early diagenesis.  相似文献   

15.
The genesis of the Sullivan orebody is reviewed in terms of current concepts of stratiform ore formation. The source of metals and sulfur, the environment and time of ore formation, and the imprint of subsequent metamorphic events are explained in terms of a model which views the ore as one component of a chemical and clastic sequence formed within a rift basin above a thermal anomaly. Classic primary sedimentary structures are displayed in both the chemical (sulfide) and the clastic (silicate) rocks. Fractures and breccia zones beneath the western section of the mine provided passage-ways for boron and metal-rich sulfur-poor brines. Sulfides formed when the metals combined with reduced marine sulfur. The pattern of metal zoning is a reflection of the location of brine vents. The boron-rich solutions produced the tourmaline alteration zone. The sodium-rich brine produced albite within the ore sequence and in the hanging wall perhaps by the modification of analcite. The manganese variation of sulfide minerals between ore bands and laminations reflect changes in the chemistry of solutions during sedimentation and some degree of partitioning during metamorphism. The metamorphism has modified both the sulfide and silicate assemblages.  相似文献   

16.
为了探讨中国西南地区二叠系乐平统(上二叠统)龙潭组中下部煤系不同煤组分中砷、硒的含量和演化及古环境意义,对近10年来采集于中国西南扬子地台的二叠系乐平统龙潭组主采煤层的原煤、亮煤、煤矸石、黄铁矿结核等样品中砷、硒元素含量进行了测定和分析,并与中国华北地台一些煤矿的上石炭统-下二叠统太原组、山西组的原煤、镜煤、亮煤、煤矸石、黄铁矿结核等样品中砷、硒含量进行对比分析。结果表明:西南地区乐平统龙潭组煤的砷、硒含量变化较大,但总体高于华北晚石炭世和早二叠世煤的砷、硒含量;西南二叠系乐平统龙潭组大多数的亮煤中砷、硒含量高于原煤全煤样(刻槽样)中的砷、硒含量,也远远高于同煤层煤矸石的含量,龙潭组部分亮煤的砷含量尤其高,为55~338 mg/kg,还发现砷含量为89 mg/kg的亮煤。但华北上石炭统-下二叠统的镜煤中的砷、硒含量与之相反,低于原煤全煤样的砷、硒含量,其中砷含量非常低,为063~129 mg/kg。说明西南地区上二叠统煤中的砷和硒与煤的有机质密切相关,可能主要来源于成煤古植物。在西南乐平世早、中期第Ⅰ幕陆生生物集群灭绝事件期间,陆生动物的食物--植物中有毒有害元素砷、硒含量明显增加,陆生环境或泥炭沼泽中可溶性砷、硒含量增加。  相似文献   

17.
Selenium (Se) is a trace element that can cause human physical deformations due to selenosis, and mutagenic changes on a range of sensitive macro-organisms. Previous studies indicated that Se enrichment is significantly greater in coal than in other rock units, suggesting a correlation between Se and coal bed proximity. Since coal extraction can cause a release of Se, some regulatory authorities have responded by requiring sampling of coal seams and adjacent rock for Se prior to issuing coal mining permits. This sampling is done under the assumption that Se in a small number of samples will be correlated to the Se concentrations throughout the strata they represent. For example, in one case a single continuous deep rock core was sampled for Se to estimate the concentrations of Se across a 2.52 km2 proposed surface coal mine. This project examined the adequacy of such an approach using univariate statistics and variograms to determine the spatial variability and correlation of Se concentrations collected from six Appalachian coal seams. The results from all analyses showed no significant spatial correlation of Se within any coal seam examined. Given this lack of measured Se spatial correlation in Appalachian coal seams for scales as small as 0.10 km, it is unlikely that a Se spatial correlation exists in adjacent rock units at similar scales either, which is currently the assumption being made for sampling to minimize Se pollution from surface coal mining.  相似文献   

18.
The quantitative relationships between lithological variables of Early Permian Barakar coal measures of western Singrauli Gondwana sub-basin are investigated using principal component analysis in an attempt to reveal simple relationships undetected by conventional quantitative methods. The results not only confirm and amplify those of the simple regression analysis described in Casshyap et.al. (1988), but are also interpreted in terms of evolution of coal swamps. If the total thickness of strata, total thickness of clastic sediments, total thickness of coal seams, number of sandstone beds, number of shale beds, number of coal seams and clastic ratio are considered, the first three components accounts for 80% of the total variance and the lithological variables generally fall into two groups. One group contains the first four variables, namely, total thickness of strata, total thickness of sandstone, total thickness of shale and total thickness of coal seams, all of which have basin-like regional patterns of sedimentation linked to net subsidence. The other group of variables, which are somewhat less closely related to net subsidence such as number of sandstone beds, number of shale beds and number of coal seam. The sand/shale ratio and clastic ratio are dependent on the other variables and seem to be unrelated to net subsidence. The principal component results, at best in geological term, may be explained by the to and fro lateral migration of a river channel across its flood plain coupled with a gradual isostatic adjustment of the basin floor in response to the weight of the sediments and differential subsidence through space and time.  相似文献   

19.
Sulfur occurs in multiple mineral forms in coals, and its fate in coal combustion is still not well understood. The sulfur isotopic composition of coal from two coal mines in Indiana and fly ash from two power plants that use these coals were studied using geological and geochemical methods. The two coal beds are Middle Pennsylvanian in age; one seam is the low-sulfur (< 1%) Danville Coal Member of the Dugger Formation and the other is the high-sulfur (> 5%) Springfield Coal Member of the Petersburg Formation. Both seams have ash contents of approximately 11%. Fly-ash samples were collected at various points in the ash-collection system in the two plants. The results show notable difference in δ34S for sulfur species within and between the low-sulfur and high-sulfur coal. The δ34S values for all sulfur species are exclusively positive in the low-sulfur Danville coal, whereas the δ34S values for sulfate, pyritic, and organic sulfur are both positive and negative in the high-sulfur Springfield coal. Each coal exhibits a distinct pattern of stratigraphic variation in sulfur isotopic composition. Overall, the δ34S for sulfur species values increase up the section in the low-sulfur Danville coal, whereas they show a decrease up the vertical section in the high-sulfur Springfield coal. Based on the evolution of δ34S for sulfur species, it is suggested that there was influence of seawater on peat swamp, with two marine incursions occurring during peat accumulation of the high-sulfur Springfield coal. Therefore, bacterial sulfate reduction played a key role in converting sulfate into hydrogen sulfide, sulfide minerals, and elemental sulfur. The differences in δ34S between sulfate sulfur and pyritic sulfur is very small between individual benches of both coals, implying that some oxidation occurred during deposition or postdeposition.The δ34S values for fly ash from the high-sulfur Springfield coal (averaging 9.7‰) are greatly enriched in 34S relative to those in the parent coal (averaging 2.2‰). This indicates a fractionation of sulfur isotopes during high-sulfur coal combustion. By contrast, the δ34S values for fly-ash samples from the low-sulfur Danville coal average 10.2‰, only slightly enriched in 34S relative to those from the parent coal (average 7.5‰). The δ34S values for bulk S determined directly from the fly-ash samples show close correspondence with the δ34S values for SO4− 2 leached from the fly ash in the low-sulfur coal, suggesting that the transition from pyrite to sulfate occurred via high-temperature oxidation during coal combustion.  相似文献   

20.
Selenium in Chinese coals: distribution,occurrence, and health impact   总被引:2,自引:0,他引:2  
Selenium (Se) is one of the volatile elements in coal. During mining and utilization of coal, Se is largely released into the environment, which influences environmental quality, and consequently impacts on human health. This paper is a review of current knowledge on the distribution, occurrence and environmental impact of Se in Chinese coals. This study includes the following aspects: distribution and abundance of Se in coals of different provinces of China, different coal-forming periods, modes of occurrence of Se in coals, formation mechanism of Se in coals, migration processes and transformation of Se during coal combustion and leaching and their environmental effects. The available data show that Se content in Chinese coals is highly variable in different coalfields, different coal-forming periods, and different coal seams from individual coalfields. The average Se content in Chinese coal is 3.91 mg/kg.  相似文献   

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