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1.
This investigation has shown that quartz can be activated for polyacrylic acid adsorption by hydrolyzing metal cations, similar to activation in flotation. Detailed experiments on activation phenomena with ferric ions have been performed. The flocculation of activated quartz can be prevented by suitable additions of disodium EDTA, sodium hexametaphosphate or potassium fluoride. Selective flocculation of hematite with polyacrylic acid from a hematite/quartz mixture can be achieved in the pH range 3 to 9, but the process is not selective in the presence of ferric ions. Suitable additions of EDTA or KF are particularly successful in preventing quartz activation by ferric ions and the facilitating selective flocculation of hematite in artificial mixtures of quartz and hematite. 相似文献
2.
The selective flocculation of hematite from silica has been studied from a chemical standpoint. Flocculation was induced in a stirred vessel under various reagent dosages, flocculant, dispersant and electrolyte, various pHs and slurry densities. The effectiveness of a given treatment was examined by the resulting grade of material reaching the outlet of a setting tube compared with the quantity.It was confirmed that selective flocculation is more favourable with more highly charged anionic polyacrylamide flocculants and with higher molecular weight. The process appears insensitive to dosage of flocculant in the range 1.5 to 10 ppm, but slurry densities must be kept low.Under such conditions the use of redispersion produced little gain in grade of hematite fraction but considerable loss in recovery. 相似文献
3.
The role of the presence of active groups in polymers and operating variables such as conditioning time in producing flocculation in single and mixed mineral slimes made of hematite, quartz and chalcopyrite is examined at different conditions of pH. Selective flocculation was achieved on the basis of results obtained for single mineral systems as, for example, in the case of hematite—quartz mixtures using sulfonated polymer. Flocculation was found to go through a maximum as the mineral was conditioned with the polymer solution. Interestingly, the times of maximum flocculation for various minerals were sufficiently different from each other so that it could be considered as a potential factor for achieving selectivity. Also, cleaning of the selectively flocculated product by simple redispersion in water improved the separation. Electrokinetic studies conducted to study the mechanisms involved provided indication for the shift of shear plane. 相似文献
4.
粘土矿物特征与沉积环境关系的初步探讨 总被引：8，自引：1，他引：8
采取同一盆地中含有不同指相化石的泥岩和现代已知不同环境中的泥质沉积物样品分别作为海水、半咸水和淡水沉积的代表,进行电镜、X光衍射和差热分析。发现不同环境样品中粘土组构、粘土矿物组合和自生粘土矿物类型均不相同,这些差异可能主要是由不同环境中的不同水介质条件所引起的。因此,粘土矿物的这些特征有可能成为指相标志。 相似文献
5.
Pradeep Pandey Jyotsana Chabbra G. B. Joshi P. S. Parihar 《Journal of the Geological Society of India》2014,83(1):5-12
Presence of Early Tertiary pyroclastic material (tephra) has been documented petrographically, for the first time, in the Mandi-Bilaspur Sector from Tileli area, Dharamsala basin of Himachal Pradesh. The tephra is reported from the red shale, identified as tuffaceous siltstone belonging to lower Dharamsala Formation that lies above the uraniferous sandstone body and occurs as thin layers of over 300m along the strike, close to the contact of lower and upper Dharamsala formations. The tuffaceous material shows crude but preferred orientation of minerals like biotite, muscovite, chlorite, clay, hematite and specularite. Various features indicating presence of tephra are, glass shards altered to clay but retaining ‘U’ shaped outline, spindle-shaped hematite with preferred orientation, spherical to sub-spherical clay and altered Feoxide rich balls, clay groundmass with flow pattern, flaky minerals in association with clast depicting asymmetrical ramp structure. A zone of approximately 300 m length containing tuffaceous material has been established at Tileli overlying the uraniferous sandstone body. Identification of tephra at Tileli has significant implications as it enabled in demarcating the boundary between the upper and lower Dharamsala formations in central part of the basin in Bilaspur-Mandi Sector of HP Himalaya and also in guiding the uranium exploration programme in the lower Dharamsala Formation. 相似文献
6.
Thomas Mutschler Utz Kramar Maximiliano R. Vergara Theodoros Triantafyllidis 《Rock Mechanics and Rock Engineering》2013,46(4):835-847
The fraction of swelling-type clay minerals (smectites) is a first measure to estimate the swelling potential of natural rocks. This swelling potential is only activated if water can be incorporated in the sheet silicates. The samples studied in this work are volcanic rocks from the Southern Andes. According to the petrographic and mineralogical studies, the rocks are characterized as vulcanite with high content of smectite. Undisturbed samples showed minor swelling behaviour in conventional swelling tests, although X-ray diffraction and differential thermal analysis revealed swelling clay contents of more than 70 % in some samples. Powder swelling tests were performed on ground and recompacted rock samples. The results of these tests show a better agreement with those expected according to the mineralogical composition of the samples. The reason for the non-activation of the swelling potential in undisturbed samples was suspected to be the influence of the iron-oxide/hydroxide content, which was on average around 11 %. Scanning electron microscope images showed that the edge terminations of the clay particles are coated with hematite. The hydrophobic properties of hematite impede the access of water between the interlayers of the clay minerals and, in addition, hematite cementation prevents the expansion. In a further series of swelling tests water was replaced by a reducing solution (0.1 molar hydroxylammonium chloride) which removes the Fe-oxide coating. It can be shown that thus the swelling potential of the clay minerals in such undisturbed rocks can be activated. 相似文献
7.
洛川黄土-红粘土序列铁氧化物组成及其古气候指示 总被引：2，自引：0，他引：2
对洛川黄土、古土壤和红粘土中磁性矿物组成、成因和相关系进行了研究。结果表明:黄土磁性矿物以风尘磁铁矿为主,少量的成土赤铁矿和成土磁赤铁矿;古土壤磁性矿物以成土磁赤铁矿为主,成土赤铁矿次之,少量的风尘磁铁矿和赤铁矿;红粘土磁性矿物以成土赤铁矿为主,风尘磁铁矿和成土磁赤铁矿次之,少量风尘赤铁矿。黄土、古土壤和红粘土磁性矿物组成差异,反映了其形成期不同的古气候特性以及不同气候条件下生物地球化学作用强度的差异。干冷的冰期,黄土弱成土作用形成了以粗颗粒的风尘磁铁矿核 赤铁矿边的磁化率载体。间冰期的温暖湿润的古气候最有利于生物活动,强烈生物活动导致古土壤中大量纳米超细磁赤铁矿/磁铁矿产生,形成以磁赤铁矿为主,风尘磁铁矿核 赤铁矿边为辅的磁化率载体。红粘土成壤期,强降雨强蒸发的长干短湿的高温炎热的古气候使得红粘土化学风化强烈,生物地球化学活动较弱,形成以磁铁矿核 赤铁矿边和磁赤铁矿核 赤铁矿边的磁化率载体。黄土、古土壤和红粘土磁性矿物组成、磁性矿物相关系是其形成期独特的古气候指示。 相似文献
8.
Certain factors influencing the incorporation, transport and release of fatty acids by clay minerals, calcite and marine sediments have been investigated.Salinity was found to be an important factor. The adsorption of heptadecanoic acid by bentonite clay at 4%. was nearly triple that at 0%.. However, from 4%. to 35%., only a minor adsorption increase occurred. This behavior is believed to be related to flocculation of the clay at the lower salinity range. The pH over the range of 6.0–8.5 has a small influence on fatty acid-clay association, depressing it somewhat as the basicity increases.When the temperature of the fatty acid solution was increased from 0°C to 50°C, a decrease in adsorption on to clay was found. This effect may be due to increased water solubility of the acid at higher temperatures, since solubility is very important in controlling the degree of fatty acid-mineral interaction. Furthermore, apparent solubilization of fatty acids by indigenous dissolved organic matter in sea water reduces adsorption on to clay minerals.Based upon the heat of adsorption of ?14.6 kcal/mole, fatty acids are physically bound to clay minerals by weak van der Waals forces and hydrogen bonds.Bentonite and kaolinite were found to be the most adsorptive minerals investigated, followed in order by illite, montmorillonite and calcite. Sediments from Narragansett Bay were found to lie between illite and montmorillonite in adsorptive capacity after indigenous sediment organic matter had been removed. Sediment organic matter reduced fatty acid uptake by a factor of 1.6. 相似文献
9.
Efraïm Mendelovici Rafael Villalba Amaya Sagarzazu 《International Journal of Mineral Processing》1983,11(2):131-138
A dry grinding process at several periods has been used successfully in order to differentiate among the different minerals forming a natural diaspore clay. This is achieved by selective and incongruent destruction of the clay minerals of this admixture, on the basis of their disparate structural stability, hardness and relative amount present. Kaolin clays (represented mainly by kaolinite + halloysite) are destroyed after >3 hr grinding, anatase after ～40 hr, whereas the structure of α-AlOOH is still preserved after >250 hr, as ascertained from XRD. From IR spectroscopy analysis it is inferred that as a consequence of grinding prototropy takes place in some of the clay hydroxyls. This is supported by water losses results at 600°C. 相似文献
10.
D.F. Bagster 《International Journal of Mineral Processing》1985,14(1):21-32
Having previously established a system of hematite and silica which can be separated effectively using long-chain polyacrylamide flocculants (Part 1) a stirred tank system was chosen to enable physical variables of flocculant concentration, impeller speed, time of flocculation, slurry concentration, ratio of hematite to quartz in the feed and particle size distribution to be studied.It was concluded that the time of flocculation allowed should be kept short and that there is an optimum of impeller speed though not a sharp one. Slurry concentration must be kept to 1% w/w to prevent serious performance deterioration. A clear optimum flocculant concentration was not found under present circumstances though very low concentrations (< 1 ppm) gave poor results while high concentrations gave no improvement on the results at about 2 ppm.Comparison between an impeller and a propeller of the same diameter and location in the tank pointed to the possibility of critical agitation configurations and the need for caution in scaling up results.The grade of material settling from a selective aggregation process is heavily dependent on the particle size distributions of the mineral species. Larger flocculated minerals produce richer flocs. 相似文献
11.
贵州碳酸盐岩红土中的粘土矿物及其形成机理 总被引：13，自引：2，他引：13
本文运用Ｘ射线衍射、红外光谱、差热、透射电镜和扫描电镜等方法对贵州碳酸盐岩红土中的粘土矿物进行了系统研究。高岭石和０．７ｎｍ埃洛石是碳酸盐岩红土中的主要粘土矿物，其次为伊利石、蛭石、绿泥石、绿泥石／蛭石混层矿物，水铝英石和三水铝石等。 相似文献
12.
粘土矿物保存海洋沉积有机质研究进展及其碳循环意义 总被引：3，自引：0，他引：3
海洋沉积物吸附有机质的量和有机质循环周期与粘土矿物类型和吸附方式密切相关,并在全球碳循环中扮演着不同的角色。粘土吸附有机质有物理吸附和化学吸附之分,前者主要存在于粘土的微孔隙中,参与年、十年或百年尺度的循环;后者主要存在于粘土矿物层间和外表面,稳定性较好,有机质易于保存,可参与百万年或更长时间的循环,这种不同时间尺度内的碳循环,将会改写海洋沉积物有机碳“源”、“汇”的关系。不同类型粘土矿物的性质存在差异,决定了吸附有机质量的多寡,蒙脱石的吸附量远大于伊利石的吸附量,这可能是造成全球不同海域中有机碳“源”、“汇”变化的原因。海洋沉积物处于水圈、生物圈和岩石圈的交汇地带,有机碳的差异和变化,都会对全球碳循环及气候变化产生重要的影响。 相似文献
13.
为了海洋粘土的开发应用,利用FTIR和XRD衍射对其进行了矿物成分分析。结果表明,海洋粘土样品中粘土矿物含量较高,其主要矿物组成为伊/蒙混层和伊利石并含有少量其它矿物,同时证实样品中有磁铁矿和赤铁矿存在。粘土沉积物的化学成分分析显示,粘土中Fe2O3质量分数较高,约为7%。采用酸溶氢气还原法对东太平洋的粘土样品进行了化学增白试验,并探讨了酸种类及其浓度、药剂用量、反应时间、煅烧温度等因素对除铁增白效果的影响,优选出最佳除铁增白方案,使海洋粘土的白度由原来的23.8%提高到73.1%。另外,对增白前后样品的粒度、比表面积和分散性的测试表明,在增白的同时样品的活性也得到了提高。 相似文献
14.
Arieh Singer 《Earth》1984,21(4):251-293
The application of paleoclimatic interpretation to clay minerals from continental and marine sediments is reviewed and the advantages of this method are indicated. Levels relatively rich in chlorite, illite, palygorskite and quartz are interpreted as corresponding to relatively dry periods, while more humid periods lead to more intensive weathering and consequently to the dominance of clay minerals more advanced in the relative stability scale, such as kaolinite. Smectite is taken to indicate a climate with contrasting seasons and a pronounced dry season.Using this and similar schemes, the paleoclimates of areas adjoining the Mediterranean Basin, North Sea, North Atlantic, Southern Arctic, Equatorial and North-West Pacific, and North Phillipine Sea are reconstructed.Clay minerals in sediments, particularly marine sediments, can be useful indicators of paleoclimatic conditions. While they do not produce direct indications of climatic parameters, they provide integrated records of overall climatic impact. Occasionally, they may be superior to the more conventional paleoclimatic methods, such as pollen or oxygen-isotope analysis.The limitations imposed on the paleoclimatic interpretation of clay minerals in sediments are discussed on the basis of examples. The distinction between authigenic and detrital clay minerals is shown to be problematic, particularly with regard to smectite. The relationship between climatic parameters and clay-mineral formation is complicated by the intervention of extra-climatic factors such as topography, geomorphology, lithology and time. Post-depositional diagenetic changes may not be recognized. Differentiation during transport, due to size sorting or differential flocculation may overlap climate-induced differentiation. The association of clay-mineral assemblages with specific source areas presents difficulties due to dispersal pathways that are affected by type of transport agency, i.e., water, ice or wind. Transport agencies are not constant with time. By an interdisciplinary approach, with the paleoclimatic information derived from clay minerals being correlated with that obtained from the analysis of microfossils and oxygen isotope data, many of these limitations can be overcome. 相似文献
15.
The average contents of REE, Y, Fe, Mn, and clay minerals were determined in the subcolloid fraction of bottom sediments from the northern part of Amur Bay. The positive correlation of REE and Y contents with Fe and Mn is related to their flocculation and sorption on Fe, Mn oxyhydroxides and clay minerals (hydromica, smectites). The sediments are subdivided into three groups (sediments from the influence zone of the Razdol’naya River, sediments located along the eastern and western shores of the bay, and sediments weakly subjected to the river influence) with different average contents of REE, Y, Fe, and Mn. It is shown that REE and Y are mainly incorporated (98–100%) in clay minerals. 相似文献
16.
朱立军 《矿物岩石地球化学通报》1996,(3)
碳酸盐岩红土中１．４ｎｍ间层矿物及其环境意义朱立军（贵州工学院，贵阳５５０００３）关键词红土，间层矿物，土壤环境１．４ｎｍ间层矿物是指由绿泥石晶层与２：１型含水膨胀层交互连生所构成的不规划间层粘土矿物，其中２：１型含水晶层可以是蒙脱石层，也可以是蛭石... 相似文献
17.
The in situ alteration of Fe redox states in subsurface soils by bacteria, otherwise known as bioreduction, may play a key role in the immobilization of hazardous redox active metals such as U, Tc, and Cr. The objective of this study was to characterize changes in Fe mineralogy occurring in a subsurface soil as a result of biostimulation in order to evaluate the bioremediation potential of this approach. Biostimulation was achieved by injecting glucose into the soil through a small well next to a sampling well. Cores taken from the sampling well were analyzed by variable-temperature 57Fe Mössbauer spectroscopy. Results revealed that biostimulation resulted in an overall loss of Fe from the system and major changes in the distribution of its oxide and oxyhydroxide mineral forms. Compared to the non-biostimulated soil, the spectral components assigned to goethite were greatly diminished in intensity in the samples that had been biostimulated, whereas the hematite component was appreciably increased. The Fe(II):Fe(III) ratio in the non-oxide phase (aluminosilicate clay minerals) also increased, indicating that the bioreduction processes in the soil also affected the redox state of Fe in the constituent clay minerals. 相似文献
18.
19.
SM Salem 《Arabian Journal of Geosciences》2017,10(7):166
The ironstone succession at El Gedida-Ghorabi-Naser area of El Bahariya depression is subdivided into lagoonal manganiferous mud and fossiliferous ironstone consisting mainly of hematite and goethite-hydrogoethite. The application of the ASD field spectroradiometer measurements (spectral range) in the ASTER data led to the interpretation of the presence of ferruginous units as quartzitic sandstone, gluconitic sandy clay, and pink marly limestone. The existing iron ore minerals in the iron ore localities were also classified into high Mn hematite, low Mn hematite, goethite, hydrogoethite as well as low- and high-grade Hematite and Barite. Quartz, feldspars, rutile, and clay minerals (e.g., kaolinite and illite) are mainly associated with the iron ore. Accessory minerals of manganese, e.g., psilomelane and pyrolusite, were also present. The Barite mineral is recorded as a common mineral association with the iron ore deposits at El Gedida and Ghorabi localities. The stratigraphical units investigated in the study area include the oldest gravely clayey sandstones of the Bahariya Formation overlain by the fossiliferous and oolitic limestones of the El-Hamra, Qazzun, and Naqb Formations. Quartztic sandstones and clayey sandstones of the Radwan Formation and youngest Quaternary sediments of sandy-clayey materials were often found as intermittent cover and overburden in unconformity surfaces over the iron ore bands. 相似文献
20.
Experiments have shown that it is possible to obtain a concentrate containing 65% iron, 1.8% alumina and 1.4% silica with an iron recovery of 80% from the tailings of Barsuan iron ore plant containing 52.5% iron, 7.4% alumina and 7.8% silica through selective flocculation employing starch. Key to such success lies in the manner in which the flocculant is desired from the parent starch. Barsuan deposit being a limiting case of typical fine-grained high-alumina iron ores, the results open up technical possibilities of better utilization of such deposits. 相似文献