首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献，搜索用时 31 毫秒
1.
Macropores developed in barrier layers in soil covers overlying acid-generating waste rock may produce preferential flow through the barrier layers and compromise cover performance. However, little has been published on the effects of preferential flow on water balance in soil covers. In the current study, an inclined, layered soil cover with a 10-cm-wide sand-filled channel pathway in a silty clay barrier layer was built over reactive waste rock in the laboratory. The channel or preferential flow pathway represented the aggregate of cracks or fissures that may occur in the barrier during compaction and/or climate-induced deterioration. Precipitation, runoff, interflow, percolation, and water content were recorded during the test. A commercial software VADOSE/W was used to simulate the measured water balance and to conduct further sensitivity analysis on the effects of the location of the channel and the saturated hydraulic conductivity of the channel material on water balance. The maximum percolation, 80.1% of the total precipitation, was obtained when the distance between the mid-point of the channel pathway and the highest point on the slope accounted for 71% of the total horizontal length of the soil cover. The modeled percolation increased steadily with an increase in the hydraulic conductivity of the channel material. Percolation was found to be sensitive to the location of the channel and the saturated hydraulic conductivity of the channel material, confirming that proper cover design and construction should aim at minimizing the development of vertical preferential flow in barrier layers. The sum of percolation and interflow was relatively constant when the location of the channel changed along the slope, which may be helpful in locating preferential flow pathways and repairing the barrier.  相似文献   

2.
At the Kristineberg mine, northern Sweden, sulphidic mine tailings were remediated in an 8-year pilot-scale experiment using sewage sludge to evaluate its applicability as a sealing layer in a composite dry cover. Sediment, leachate water, and pore gas geochemistry were collected in the aim of determining if the sludge was an effective barrier material to mitigate acid rock drainage (ARD) formation. The sludge was an effective barrier to oxygen influx as it formed both a physical obstruction and functioned as an organic reactive barrier to prevent oxygen to the underlying tailings. Sulphide oxidation and consequential ARD formation did not occur. Sludge-borne trace elements accumulated in a reductive, alkaline environment in the underlying tailings, resulting in an effluent drainage geochemistry of Cd, Cu, Pb and Zn below 10 μg/L, high alkalinity (810 mg/L) and low sulphate (38 mg/L). In contrast, the uncovered reference tailings received a 0.35-m deep oxidation front and typical ARD, with dissolved concentrations of Cd, Zn and sulphate, 20.8 μg/L, 16,100 μg/L and 1,390 mg/L, respectively. Organic matter degradation in the sludge may be a limiting factor to the function of the sealing layer over time as 85 % loss of the organic fraction occurred over the 8-year experimental period due to aerobic and anaerobic degradation. Though the cover may function in the short to medium term (100 years), it is unlikely to meet the demands of a long-term remedial solution.  相似文献   

3.
Phosphate deposits have been outlined in Falcón State (Northern Venezuela) and Táchira State (Southwestern Venezuela) using geochemical soil methods.The phosphate deposits located in Falcón State constitute lenses and masses interbedded with Tertiary limestone and shales. The area is covered by a thick soil with few outerops and the region is characterized by typical tropical rain forest. Soil samples taken every 1000 m across complete stratigraphic sequences were analyzed for P2O5 content. An anomalous area with a P2O5 content ranging from 3.19% to 9.04% was outlined accompanied by areas with less than 0.83% of P2O5. More than 11 million metric tons of commercial phosphatic rock were associated with this anomaly.In Táchira State several stratigraphic sequences of potentially phosphatic rocks with a thick cover of black soil were geochemically investigated. Soil samples taken each 10 m were analyzed for P2O5. A sequence of phosphatic rock was outlined showing a P2O5 content varying between 7.3% and 9.2%. Apparently the sequence is interbedded with phosphate-poor siliceous rocks showing a P2O5 content below 2%.As result of this preliminary investigation, expensive trenching, pitting and drilling works can be carefully planned.  相似文献   

4.
《Applied Geochemistry》2006,21(1):184-202
Sulfide mineral oxidation in mine tailings deposits poses a long term threat to surrounding ground water and surface waters. Soil or water cover remediation aims at reducing the rate of sulfide mineral oxidation by decreasing the O2 ingress rate. In this study, the authors addressed the rate of sulfide oxidation and pH buffering in ∼33 months long, well-controlled laboratory studies of water saturated columns of sulfidic mine tailings from the Kristineberg site in Sweden at reduced O2 availability. The element discharge rates slowly declined towards a quasi-steady state over hundreds of days. Non-reactive tracer tests showed an anomalously large dispersion, indicating strong flow heterogeneity, possibly including preferential flow and/or stagnant water zones. Congruent dissolution of pyrite and sphalerite by injected oxidants (dissolved O2 and Fe(III)) adequately explained the discharge rate of Fe, S and Zn at quasi-steady state. Arsenic, Pb and Cu were partly retained in the tailings. Base cation discharge rates, and thus pH buffering, were apparently controlled by the rate of acidity production, with actual pH levels, available mineral surface area, and water residence times being of less importance.  相似文献   

5.
Over time periods of 106 years and longer, atmospheric carbon dioxide content is largely controlled by a balance between silicate rock weathering and CO2 sources (degassing from the Earth plus net organic carbon oxidation). Vegetation cover can affect silicate rock weathering rates by increasing soil CO2 content, stabilizing soil cover, and producing organic acids. Forests absorb more solar radiation than most other ecosystems; this tends to warm Earth's climate, especially outside of the tropics; this warmth would tend to increase silicate rock weathering rates. Here, we develop preliminary parameterizations of this effect that could be incorporated into carbonate–silicate cycle models, based on the results of general circulation model simulations.  相似文献   

6.
The net result of acid-generating and-neutralizing reactions within mining wastes is termed acid rock drainage (ARD). The oxidation of sulfide minerals is the major contributor to acid generation. Dissolution and alteration of various minerals can contribute to the neutralization of acid. Definitions of alkalinity, acidity, and buffer capacity are reviewed, and a detailed discussion of the dissolution and neutralizing capacity of carbonate and silicate minerals related to equilibium conditions, dissolution mechanism, and kinetics is provided. Factors that determine neutralization rate by carbonate and silicate minerals include: pH, PCO 2, equilibrium conditions, temperature, mineral composition and structure, redox conditions, and the presence of foreign ions. Similar factors affect sulfide oxidation. Comparison of rates shows sulfides react fastest, followed by carbonates and silicates. The differences in the reaction mechanisms and kinetics of neutralization have important implications in the prediction, control, and regulation of ARD. Current static and kinetic prediction methods upon which mine permitting, ARD control, and mine closure plans are based do not consider sample mineralogy or the kinetics of the acid-generating and-neutralizing reactions. Erroneous test interpretations and predictions can result. The importance of considering mineralogy for site-specific interpretation is highlighted. Uncertainty in prediction leads to difficulties for the mine operator in developing satisfactory and cost-effective control and remediation measures. Thus, the application of regulations and guidelines for waste management planning need to beflexible.  相似文献   

7.
Several methods were evaluated and compared for the estimation of pyrite oxidation rates (POR) in waste rock at Mine Doyon, Quebec, Canada. Methods based on data collected in situ, such as the interpretation of temperature and oxygen concentration profiles (TOP) measured in the waste rock pile and pyrite mass balance (PMB) on solid phase samples were compared with the oxygen consumption measurements (OCM) in closed chamber in the laboratory. A 1-D analytical solution to a gas and heat transport equation used temperature and oxygen profiles (TOP) measured in the pile for the preliminary POR estimates at a site close to the slope of the pile (Site 6) and in the core of the pile (Site 7). Resulting POR values were 1.1 × 10− 9 mol(O2) kg− 1 s− 1 and 1.0 × 10− 10 mol(O2) kg− 1 s− 1 for the slope site and the core site, respectively. Oxidation rates based on pyrite mass balance (PMB) calculations for solid samples were 2.21 × 10− 9 mol(O2) kg− 1 s− 1 and 2.03 × 10− 9 mol(O2) kg− 1 s− 1, respectively, for the same slope and core sites, but the difference between sites was within the error margin. The OCM measurements in the laboratory on fresh waste rock samples yielded higher POR values than field methods, with average oxidation rate of 6.7 × 10− 8 mol(O2) kg− 1 s− 1. However, the OCM results on weathered and decomposed material from the rock stockpile (average oxidation rate 3.4 × 10− 9 mol(O2) kg− 1 s− 1) were consistent with results from the field-based estimates. When POR values based on fresh material are excluded, the remaining POR values for all methods range from 1.0 × 10− 10 to 3.4 × 10− 9 mol(O2) kg− 1 s− 1. The lowest estimated value (1.0 × 10− 10 mol(O2) kg− 1 s− 1) was based on TOP estimates in the interior of the pile where oxygen transport was limited by diffusion from the surface. These results suggest that small-scale OCM laboratory experiments may provide relatively representative values of POR in the zones of waste rock piles in which oxygen transport is not dominated by diffusion.  相似文献   

8.
The use of covers with capillary barrier effects (CCBEs) for reducing acid mine drainage (AMD) from sulphidic mine tailings is simulated using the MIN3P finite volume model for coupled groundwater flow, O2 diffusion and multi-component reactive transport. The model is applied to simulate five pilot-scale in situ test cells containing reactive tailings from the Manitou mine site, Val d’Or, Que., Canada. Four of the cells were constructed with CCBEs over the tailings, while the fifth tailings cell was left uncovered. Observed and simulated discharge from the base of each cell showed that the capillary barrier covers significantly reduced sulphide oxidation and AMD. Compared to acidic discharge from the uncovered cell, discharge from the four CCBE-covered cells had neutral pH levels and 1–7 orders of magnitude lower concentrations of SO4, Fe, Zn, Cu and Al. The simulations showed that the moisture retaining layer of the CCBEs reduced AMD by inhibiting O2 diffusion into the underlying reactive wastes. Provided the moisture-retention layer of the CCBE remains close to saturation, its thickness had a relatively minor effect. Under such near-saturated conditions, O2 availability is limited by its diffusion rate through the bulk porous medium and not by the diffusion rate through the oxidized grain shells. The model is providing important new insights for comparing design alternatives for reducing or controlling AMD.  相似文献   

9.
This paper reports detailed O2 measurements of pyrite bearing sediments in a column study and their interpretation based on a hydrogeochemical modelling approach. The research focuses on the quantitative effects of effective diffusion and microbiologic activity on pyrite weathering and acidification. A column experiment was set up and O2 saturation and moisture contents were monitored over 100 days. The anoxic material used for the column experiment was taken from a sediment core of a mining waste dump in the southern periphery of the Lohsa storage system in the Lusatia region of Germany. The measured O2 breakthrough curves were modelled using the simulator SAPY, a one-dimensional reactive transport code which considers the kinetics of chemical reactions and the delivery of O2 into the sediment. The simulation yielded a strong dependence of pyrite oxidation on the moisture content which was quantified by an empirical equation. It was shown that the oxidation rate was catalysed by microbial activity exceeding the rate of diffusive O2 delivery. In order to develop a management tool for predictive issues the results have already been applied to natural environments in another study using the adapted model.  相似文献   

10.
《Applied Geochemistry》2004,19(7):1075-1084
The biogeochemical cycling of Fe in acid rock drainage (ARD) streams has presented ongoing challenges to reactive solute transport modeling. Previous studies have relied on the pH-dependent solubility of Fe oxides as the main control of the mid-day Fe(II) maxima concentration in ARD streams. In this study, the authors assess the potential for Fe(II)-oxidizing reactions, including the Fenton and microbial oxidation reactions, to constrain the mid-day Fe(II) maxima concentration. At mid-day, pseudo-equilibrium between Fe(II) oxidizing reactions and photoreduction was assumed in order to evaluate the observed Fe(II) maxima and develop an equation to represent this steady state scenario. This steady state condition is assumed only while light intensity, reactivity of oxides and dissolved organic matter (DOM), and microbial populations remain approximately constant. Three Rocky Mountain ARD streams with known values for Fe(II) were evaluated and average photoreduction rates ranging from 5.56×10−4 to 1.39×10−3 μM/s were found during mid-day steady state Fe(II) maxima. Application of Fe redox biogeochemistry to reactive solute transport modeling may improve predictive capabilities of various trace metal and solute interactions incorporated with the cycling of Fe within ARD streams. Further, model improvement of Fe cycling may enable more accurate remediation predictions for ARD streams.  相似文献   

11.
Acid rock drainage (ARD) is a longstanding problem often associated with the resulting corrosion due to the acidity generated from sulfidic oxidation. To evaluate characteristics of ARD and corrosion, samples from the road side rock mass of Boeun and Mujoo were analysed using X-ray diffraction, acid/base accounting and Leaching tests. The results indicated that many samples had a pyritic origin and can be regarded as acid-generating rocks. The Leaching test showed that the average pH of the leachates of samples from both Boeun and Mujoo were moderately acidic, ranging from 3 to 4. Interestingly, as acidity increases from pH 4, the SO4−, Fe, Al and Mg concentrations increase abnormally. Samples from roadside slope of Mujoo showed high corrosive potential. Maximum sulfide oxidation rate of a sample taken from Mujoo was as high as 5,166 mg/kg/week.  相似文献   

12.
A new model for upward transport of buoyant fluid released during metamorphism is proposed. The model is fluid transport by buoyancy-driven propagation of isolated fluid-filled cracks. The mechanical behavior of a two-dimensional, isolated, vertical, and fluid-filled crack in impermeable rock is investigated using linear fractire mechanics and fluid dynamics. The results show that steady-state crack propagation which causes long-distance transport of the fluid occurs when the vertical cross-sectional area of the crack exceeds a critical value. Propagation velocity and average thickness of the crack under the steady-state propagation regime are expressed explicitly by the following seven parameters: vertical crack length; rigidity, Poisson's ratio, and fracture toughness of the rock; fluid viscosity; density difference between the rock and the fluid; gravitational acceleration. An isolated H2O-filled crack of vertical length 100 m, for example, propagates upwards in the crust at 0.3 m/s with the average thickness 0.2 mm when the following likely values are assumed: 0.1 mPa s for the H2O viscosity; 3 MPa m1/2 for the fracture toughness of the crustal rock. The application of the obtained results to the transport of H2O released during metamorphism suggests that the number density of isolated cracks propagating in the crust is very low. Since the propagation velocity is high, our model is suitable particularly for fluid transport through hot quartz-rich rock where fluid-filled cracks have geologically short lifetimes.  相似文献   

13.
Soil cover systems are widely used for containment of municipal solid waste, hazardous and mine waste, with the objective of limiting the ingress of precipitation and oxygen. The ability to predict their long-term performance is crucial, as their failure would result in the release of contaminants to the environment. However, monitoring covers over the long term to derive the information needed to aid in design is impractical and there are no large-scale covers that have been in use for a long enough period to generate the data needed. Numerical models have been particularly useful as design tools. To improve their reliability these models may be calibrated to field data and then used to make long-term predictions of cover performance. The field performance of two resistive test soil covers on a 20% sloping waste rock platform is predicted using the two-dimensional soil–atmosphere model Vadose/W. Input data for the model included soil, climate and vegetation data obtained either in the field or laboratory. Model results were compared to field data to assess the validity of the program. The model reasonably simulated field response patterns for soil water storage and suction. Divergence between field performance data and model predictions were significantly influenced by snowmelt, interflow and flow through preferential pathways.  相似文献   

14.
微波酸溶消解方法是测定固体废物中金属元素最主要的前处理方法,消解时使用不同的酸体系对测定结果有较大的影响。本文以国家土壤标准样品、固体废物标准样品和固体废物实际样品为材料,比较了在硝酸-盐酸、硝酸-氢氟酸、硝酸-盐酸-双氧水、硝酸-盐酸-氢氟酸-双氧水4种酸体系下,16种金属元素测定结果的差异以及在硝酸-盐酸和硝酸-盐酸-氢氟酸-双氧水酸体系下各元素的精密度和准确度。研究表明:一些土壤基体中加入氢氟酸能使Mo和Sb的回收率提高40%左右,固体废物样品中只有Sb的回收率能提高33%~50%。对于含氢氟酸的酸消解体系,改变硝酸和盐酸的比例,其测定结果没有明显差异;对于元素含量相差悬殊的铬渣样品,由于空间电荷效应,高浓度的Cr对V的测定有抑制作用。从方法的准确度和精密度来看,硝酸-氢氟酸-盐酸-双氧水的消解效果最好。  相似文献   

15.
Jarosite [KFe3(SO4)2(OH)6] is a mineral that is common in acidic, sulphate-rich environments, such as acid sulphate soils derived from pyrite-bearing sediments, weathering zones of sulphide ore deposits and acid mine or acid rock drainage (ARD/AMD) sites. The structure of jarosite is based on linear tetrahedral-octahedral-tetrahedral (T-O-T) sheets, made up from slightly distorted FeO6 octahedra and SO4 tetrahedra. Batch dissolution experiments carried out on synthetic jarosite at pH 2, to mimic environments affected by ARD/AMD, and at pH 8, to simulate ARD/AMD environments recently remediated with slaked lime (Ca(OH)2), suggest first order dissolution kinetics. Both dissolution reactions are incongruent, as revealed by non-ideal dissolution of the parent solids and, in the case of the pH 8 dissolution, because a secondary goethite precipitate forms on the surface of the dissolving jarosite grains. The pH 2 dissolution yields only aqueous K, Fe, and SO4. Aqueous, residual solid, and computational modelling of the jarosite structure and surfaces using the GULP and MARVIN codes, respectively, show for the first time that there is selective dissolution of the A- and T-sites, which contain K and SO4, respectively, relative to Fe, which is located deep within the T-O-T jarosite structure. These results have implications for the chemistry of ARD/AMD waters, and for understanding reaction pathways of ARD/AMD mineral dissolution.  相似文献   

16.
Continuous monitoring of a 15 m high heavily instrumented experimental waste rock pile (0.053 wt.% S) since 2006 at the Diavik diamond mine in northern Canada provided a unique opportunity to study the evolution of fresh run-of-mine waste rock as it evolved over annual freeze–thaw cycles. Samples were collected from soil water solution samplers to measure pore water properties, from twelve 4 to 16 m2 basal collection lysimeters to measure basal leachate properties in the region underlying the crest of the pile (the core), and from basal drains to measure aggregate total pile leachate properties. By 2012, monitoring of pore water geochemistry within the core structure of the test pile revealed an apparent steady state with respect to weathering geochemistry, represented by (i) a flush of pre-existing blasting residuals and applied tracers, (ii) declining pH, (iii) a stepwise progression and subsequent equilibrium with acid-neutralizing phases (depletion of available carbonates; equilibrium with respect to aluminum hydroxide phases and subsequent iron (III) hydroxide phases), and (iv) concordant release of SO4, major cations (Ca, Mg, K, Na, Si), and trace metals (Al, Fe, Ni, Co, Cu, Zn). Distinct, high concentration ‘spring flushes’, characteristic of drainage in northern environments and primarily explained by a combination of fluid residence time and the build-up of oxidation products over the winter, were released from core drainage each season. Following the initial flush, the concentration of all dissolved constituents steadily declined, with distinct minimums prior to freeze-up. The opposite trend was observed in the cumulative pile drainage, in which early season leachate dominated by snowmelt and batter flow had low concentrations and late season leachate dominated by contributions from the core of the pile (indicated by season end merging of core and cumulative drainage geochemistry) had higher concentrations. Northern waste rock pile drainage geochemistry is strongly influenced by freeze–thaw cycling and varying core and batter subsystem contributions to total drainage. A comprehensive understanding of thermal cycling in waste rock piles is an important component of temporal predictions of drainage water composition based on up-scaling or reactive transport modeling.  相似文献   

17.
 Oxygen-18 (18O) and deuterium (D, or 2H) are routinely used in hydrologic, climatologic and geothermal studies. In hydrology, stable isotopes provide information on the type and topology (altitude and latitude) of the recharge waters and the historical effects on water, related to such physical processes as evaporation (in ponds), melting (of snow or ice), condensation, evapotranspiration and mixing. In geothermal studies, stable isotopes provide key information related to recharge and the various temperature-dependent water/rock isotope exchange reactions. The latter is assessed through the oxygen shift in the 18O/D correlation. At acid rock drainage (ARD) sites, water/rock interactions are primarily controlled by pH and oxidation potential. Using the isotopic characteristics of the rocks and the recharge waters as a basis, the relative oxygen shift of the ARD effluent can provide information on: (1) the residence time, (2) the rate of water/rock reactions, and (3) the actual pH at the rock/water interface. This paper offers a methodology for conducting oxygen and hydrogen isotope studies related to ARD and other mineral effluent problems. The methodology is based on: (1) comprehensive sampling of regional waters, ARD effluent and major contributing minerals and rocks, (2) isotopic and elemental analysis, and (3) data interpretation on the basis of a zero-dimensional (mass balance), multi-component mixing model. Received: 15 January 1999 · Accepted: 3 May 1999  相似文献   

18.
The composition of humic acids (HAs) isolated from an agricultural soil and a lignite deposit was examined via H2O2 and RuO4 oxidation. The oxidation digests were separated into lipophilic and hydrophilic components. Information with regard to the source, degree of humification and preservation of easily degradable constituents of the HAs was obtained and results were compared with those obtained earlier for base hydrolysates of solvent-extracted fractions.H2O2 oxidation of both HAs afforded lipophilic fractions containing high molecular weight compounds. The composition of the base hydrolysates of the lipophilic fractions strongly differed with the origin of the HA. The lipophilic components of the soil HA derived mainly from the higher plant polyesters cutin and suberin. The lipophilic components of the lignite HA predominantly comprised long chain alkanoic acids and alkanols. The patterns for the hydrophilic components released upon H2O2 oxidation were found to be identical irrespective of the origin of the HA. The hydrophilic fractions comprised aliphatic (poly)carboxylic acids related to carbohydrate moieties and benzene polycarboxylic acids. The relative abundance of benzene polycarboxylic acids increased with the degree of humification.For both HAs, RuO4 oxidation resulted in a lipophilic fraction containing low molecular weight products identical to those found in the base hydrolysate of the lipophilic fraction released upon H2O2 oxidation. The hydrophilic components released upon RuO4 oxidation were independent of the HA origin and consisted mainly of monosaccharides and disubstituted aromatic compounds. In agreement with the greater aromaticity of lignite HA, the aromatic compound/carbohydrate ratio was higher for lignite HA than soil HA. The results show that the fused aromatic structures had a small size and that carbohydrates could escape degradation during the humification process.  相似文献   

19.
《Applied Geochemistry》2001,16(9-10):1215-1230
Oxidation rates of low sulphide (<0.5 wt.%) gneissic waste rock from the Cluff lake U mine, northern Saskatchewan, Canada were determined using 3 independent methods: O2 consumption rates in kinetic cells, SO4 measurements of kinetic cell effluent and humidity cell SO4 release rates. The O2 consumption measurements demonstrated that the oxidation of pyrite was strongly dependent on grain size and moderately dependent on water content, temperature and microbiology. Oxygen consumption rates were highest at water contents of 5–10 wt.% (12–25% saturation). Measured SO4 release rates (3.1–91 mg SO4 kg−1 wk−1) for the kinetic cells were comparable to rates calculated from the O2 consumption values (6.9–70 mg SO4 kg−1 wk−1). Sulphate release rates determined from humidity cells were generally higher than those obtained from the kinetic cells, ranging from 6 to 64 mg SO4 kg−1 wk−1 for the coarsest and finest fraction, respectively. These differences were attributed to sample heterogeneity.  相似文献   

20.
Fresh nephelinitic rocks and hydrothermally altered rocks at Mount Etinde (Cameroon Volcanic Line, West Africa) have been studied by combined whole rock geochemistry (ICP-MS), mineralogy and mineral chemistry (SEM-EDS, WDS, XRD) techniques. The nephelinites have feldspathoids, clinopyroxene, perovskite and titanomagnetite as the principal minerals in the mode with subsidiary apatite and sphene. The mineralogy of their hydrothermally altered counterparts includes phillipsite, calcite and analcime which are secondary phases developed in response to hydrothermal fluid events. Correspondingly, the bulk rock geochemical data show elevated SiO2, CaO, Na2O and K2O concentrations with increasing alteration and Al2O3 and Fe2O3 depletion while MgO, MnO and TiO2 concentrations are largely unaffected. The nephelinites also have high concentrations of LILLE, HFSE and REE and upon hydrothermal alteration they show an enrichment of LREE and MREE over HREE. Phillipsite is the principal alteration mineral in the rocks and it occurs along cracks, vesicles and also forms alteromorphs after feldspathoids. The Ce content of these categories of phillipsite varies. Phillipsite along cracks is richer in Ce while phillipsite associated with calcite has lower Ce concentration and the phillipsite alteromorphs very little or no Ce. Various stages of fluid circulation are proposed hereby to explain the variations in phillipsite generation and composition.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号