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1.
Dissolved organic carbon (DOC), dissolved organic nitrogen (DON) and dissolved organic phosphorus (DOP) measured in deep profiles in the N-E Atlantic and in the N-W Mediterranean in the period 1984–2002 are described. After accurate validation, they show close agreement with those previously published.Classic profiles were obtained, with concentrations decreasing in deep waters. In the Mediterranean and in the Atlantic comparable concentrations were found in the 1500–2000 m waters, 44–46 μmol l−1 DOC, 2.6–2.8 μmol l−1 DON and 0.02–0.03 μmol l−1 DOP. In the surface layers, DOC concentrations were higher, but DON and DOP concentrations lower, in the Mediterranean than in the Atlantic, leading to higher element ratios in the Mediterranean. In autumn, values were, respectively, DOC:DON 17 vs. 14, DOC:DOP 950 vs. 500 and DON:DOP 55 vs. 35. The data suggest an increase in DOC and DON in the North Atlantic Central Water over 15 years, which may be linked to the North Atlantic climatic oscillations.Refractory DOM found in the 1500–2000 m layer exhibited C:N:P ratios of 1570:100:1. The labile+semi-labile (=non-refractory) DOM (nrDOM) pool was computed as DOM in excess of the refractory pool. Its contribution to total DOM above the thermocline in the open sea amounted to 25–35% of DOC, 30–35% of DON, and 60–80% of DOP. Element ratios of the nrDOM varied among stations and were lower than those of refractory DOM, except for C:N in the Mediterranean: nrDOC:nrDON 10–19, nrDOC:nrDOP 160–530 and nrDON:nrDOP 15–38. The specific stoichiometry of DOM in the Mediterranean led us to postulate that overconsumption of carbon is probably a main process in that oligotrophic sea.By coupling non-refractory DOM stoichiometry and relationships between the main DOM elements in the water column, the relative mineralization of C, N and P from DOM was studied. Below the thermocline, the preferential removal of phosphorus with regard to carbon from the semi-labile DOM can be confirmed, but not the preferential removal of nitrogen. In the ocean surface layers, processes depend on the oceanic area and can differ from deep waters, so preferential carbon removal seems more frequent. Bacterial growth efficiency data indicate that bacteria are directly responsible for mineralization of a high proportion of DON and DOP in the deep water.  相似文献   

2.
New and published data on the distribution and speciation of manganese and iron in seawater are analyzed to identify and parameterize major biogeochemical processes of their cycling within the suboxic (15.6σt16.2) and anoxic layers (σt16.2) of the Black Sea. A steady-state transport-reaction model is applied to reveal layering and parameterize kinetics of redox and dissolution/precipitation processes. Previously published data on speciation of these elements in seawater are used to specify the nature of the transformations. Two particulate species of iron (Fe(III) hydroxide and Fe(II) sulfide) are necessary to adequately parameterize the vertical profile of suspended iron, while three particulate species (hydrous Mn(IV) oxide, Mn(II) sulfide, and Mn(II) carbonate) are necessary to describe the profile of suspended manganese. In addition to such processes as mixing and advection, precipitation, sinking, and dissolution of manganese carbonate are found to be essential in maintaining the observed vertical distribution of dissolved Mn(II). These results are used to interpret the observed difference in the form of vertical distribution for dissolved Mn(II) and Fe(II). Redox transformations of iron and manganese are coupled via oxidation of dissolved iron by sinking suspended manganese at σt16.2±0.2 kg m−3. The particulate manganese, necessary for this reaction, is supplied through oxidation of dissolved Mn(II). The best agreement with observations is achieved when nitrate, rather than oxygen, is set to oxidize dissolved Mn(II) in the lower part of the suboxic layer (15.90σt16.2). The results support the idea that, after sulfides of these metals are formed, they sink with particulate organic matter. The sinking rates of the particles and specific rates of individual redox and dissolved-particulate transformations have been estimated by fitting the vertical profile of the net rate.  相似文献   

3.
From observations of ice cover, temperature, salinity, currents and nitrate, it is evident that along-shelf variability was significant over the middle shelf of the eastern Bering Sea, but less distinct than that observed in the cross-shelf domains. Along the 70-m isobath, three zones were evident in the summer: the southeastern cold pool (centered at 57°N); an intermediate zone, consisting of warmer water, with weaker stratification; and the northern cold pool, extending northward from 58°N. Small-scale (20 km) horizontal features that persisted for months were common. Nutrient concentrations were related to salinity and were replenished more uniformly over the southern shelf, than north of the Pribilof Islands. Although mean currents were weak (1 cm s−1), short energetic advective events impacted the temperature and salinity structure.  相似文献   

4.
The dissolved organic carbon pool (DOC) is among the largest reservoir of reduced carbon on our planet. The demonstration that DOC polymers remain in assembly/dispersion equilibrium forming microscopic hydrogels has a broad range of critical implications. Previous studies estimate that  10% of DOC could be assembled as gels, yielding values of  7 × 1016 g of organic carbon present as microscopic hotspots of high substrate concentration. This huge mass of reduced carbon emphasizes the need to develop reliable methods to systematically investigate the budget of self-assembled marine gels (SAG), and their role in biogeochemical cycling. However, a quantitative method to measure SAG in seawater has not been available. Here we present the validation of a simple assay to measure the mass of organic carbon assembled as microgels in native seawater. This method is based on the ratio of Chlortetracycline (CTC) fluorescence quenching between Ca bound to non-assembled organic molecules and molecules assembled as microgels. This assay can be readily implemented on board using a low cost fluorometer and provisions to measure TOC.  相似文献   

5.
This study presents a sea-level curve from 9500 to 6500 cal BP for the farfield location of Singapore, on the Sunda Shelf in southeast Asia. The curve is based on more than 50 radiocarbon dates from elevations of +1.43 m to −15.09 m representing sea-level index points in intertidal mangrove and shallow marine sediments deposited by sea-level rise accompanying deglaciation. The results indicate that mean sea level rose rapidly from around −17 m at 9500 cal BP to around −3 m by 8000 cal BP. After this time, the data suggest (but do not unequivocally prove) that the rate of sea-rise slowed for a period of 300–500 years centred on 7700 cal BP, shortly after the cessation of meltwater input to the oceans from the northern hemisphere. Renewed sea-level rise amounting to 3–5 m began around 7400 cal BP and was complete by 7000 cal BP. The existence of an inflection in the rate of sea-level rise, with a slow-down centred on 7700 cal BP, is broadly consistent with other available sea-level curves over this interval and is supported by evidence of stable shorelines and delta initiation elsewhere at this time, as well as evidence of comparatively rapid retreat of the West Antarctic ice sheet beginning around 7500 cal BP. ‘Stepped’ sea-level rise occurring shortly after 7500 cal BP and also earlier during deglaciation may have served to focus significant post-glacial episodes of human maritime/coastal dispersal, into comparatively narrow time intervals.  相似文献   

6.
The Wadden Sea (North Sea, Europe) is a shallow coastal sea with high benthic and pelagic primary production rates. To date, no studies have been carried out in the Wadden Sea that were specifically designed to study the relation between pelagic respiration and production by comparable methods. Because previous studies have suggested that the import of primary-produced pelagic organic matter is important for benthic Wadden Sea carbon budgets, we hypothesised that on an annual average the northern Wadden Sea water column is autotrophic. To test this hypothesis, we studied annual dynamics of primary production and respiration at a pelagic station in a shallow tidal basin (List Tidal Basin, northern Wadden Sea). Since water depth strongly influences production estimates, we calculated primary production rates per unit area in two ways: on the basis of the mean water depth (2.7 m) and on the basis of 1 m depth intervals and their respective spatial extent in the List Tidal Basin. The latter more precise estimate yielded an annual primary production of 146 g C m− 2 y− 1. Estimates based on the mean water depth resulted in a 40% higher annual rate of 204 g C m− 2 y− 1. The total annual pelagic respiration was 50 g C m− 2 y− 1. The P/R ratio varied between seasons: from February to October the water column was autotrophic, with the highest P/R ratio of 4–5 during the diatom spring bloom in April/May. In autumn and winter the water column was heterotrophic. On an annual average, the water column of the List Tidal Basin was autotrophic (P/R 3). We suggest that a large fraction of the pelagic produced organic matter was respired locally in the sediment.  相似文献   

7.
The spatial distributions of dissolved manganese and nutrients were examined in the Columbia River plume off Oregon and Washington during the summer of 2004 and 2005 as part of the River Influence on Shelf Ecosystems (RISE) program. Factors influencing the hydrochemical characteristics of the freshly formed and aged Columbia River plume were investigated. Hydrographic data and nutrient concentrations were used to delineate three distinct water sources for the Columbia River Plume: California Current surface water, coastal upwelled water, and Columbia River water. The warm, intermediate salinity, nutrient poor California Current water contains low levels of dissolved manganese (< 5 nM) and silicic acid (< 5 μM), and is depleted in nitrate. The cold, high salinity, nutrient rich, freshly upwelled water is highly variable (2–20 nM) in dissolved manganese and can be as high as  45 μM in silicic acid and  30 μM nitrate. The variable Columbia River has summer temperatures ranging from  13 to 24 °C, high silicic acid concentrations (ranging from  120 to 200 μM), and lower nitrate concentrations (ranging from  2 to 20 μM). During the summer, the concentrations of silicic acid and dissolved manganese can exceed 100 μM and 200 nM, respectively, in near-field Columbia River plumes. These values are markedly greater than those of surface coastal waters (even during upwelling conditions). As the plume advects and mixes, the concentrations of these two constituents remain relatively high within plume waters. The concentrations of dissolved manganese in the near-field plume vary with tidal amplitude, exhibiting much higher concentrations for a given salinity during spring tides than during neap tides. For example, the Columbia River plume at a salinity of 20 has a concentration of dissolved manganese of  240 nM during spring tides, as compared to only  60 nM during low amplitude tides. Silicic acid concentrations in the near-field plume remain relatively constant throughout the tidal month. Calculations indicate there is roughly an equivalent yearly delivery of dissolved manganese and silicic acid to the coastal waters off Oregon and Washington by upwelled waters and by the Columbia River plume.  相似文献   

8.
In this study, seasonal and annual variability in the use of estuarine and ocean beaches by young-of-the-year bluefish, Pomatomus saltatrix, was evaluated by indices of abundance in coastal areas of southern New Jersey (1998–2000). Biological and physical factors measured at specific sites were correlated with bluefish abundance to determine the mechanisms underlying habitat selection. In addition, integrative and discrete indicators of bluefish growth were used to examine spatio-temporal dynamics in habitat quality and its effect on habitat selection by multiple cohorts of bluefish. Intra-annual recruitment to coastal areas of southern New Jersey was episodic, and resulted from the ingress of spring-spawned bluefish (hatch-date April) to estuarine beaches in late May to early June, followed by the recruitment of summer-spawned fish (hatch-date early July) to ocean beaches from July to October. Bluefish utilized estuarine and ocean beaches in a facultative manner that was responsive to dynamics in prey composition and temperature conditions. The recruitment and residency of bluefish in the estuary (1998–1999) and ocean beaches (1998), for example, was coincidental with the presence of the Atlantic silverside Menidia menidia and bay anchovy Anchoa mitchilli, the principal prey species for bluefish occupying these respective habitat-types. Bluefish abundance in the estuary (2000) and ocean beaches (1999–2000) was also correlated with water temperature, with the greatest catches of juveniles coinciding with their optimal growth temperature (24 °C). Bluefish growth, estimated as the slope of age–length relationships and daily specific growth rates, equaled 1.27–2.63 mm fork length (FL) d−1 and 3.8–8.7% body length increase d−1, respectively. The growth of sagittal otoliths was also used as a proxy for changes in bluefish size during and shortly before their time of capture. Accordingly, otolith growth rates of summer-spawned bluefish were greater at ocean beaches relative to the estuary and were explained by the more suitable temperature conditions found at ocean beaches during the mid- to late summer. Notwithstanding the fast growth of oceanic summer-spawned bluefish, individuals spawned in the spring were still larger in absolute body size at the end of the summer growing season (240 and 50–200 mm FL for spring- and summer-spawned bluefish, respectively). The size discrepancy between spring- and summer-spawned bluefish at the onset of autumn migrations and during overwintering periods may account for the differential recruitment success of the respective cohorts.  相似文献   

9.
Geochemical estimates of N2 fixation in the North Atlantic often serve as a foundation for estimating global marine diazotrophy. Yet despite being well-studied, estimations of nitrogen fixation rates in this basin vary widely. Here we investigate the variability in published estimates of excess nitrogen accumulation rates in the main thermocline of the subtropical North Atlantic, testing the assumptions and choices made in the analyses. Employing one of these previously described methods, modified here with improved estimates of excess N spatial gradients and ventilation rates of the main thermocline, we determine a total excess N accumulation rate of 7.8 ± 1.7 × 1011 mol N yr− 1. Contributions to excess N development include atmospheric deposition of high N:P nutrients (adding excess N at a rate of 3.0 ± 0.9 × 1011 mol N yr− 1 for  38% of the total), high N:P dissolved organic matter advected into and mineralized in the main thermocline (adding excess N at 2.2 ± 1.1 × 1011 mol N yr− 1 for  28% of the total), and, calculated by mass balance of the excess N field, N2 fixation (adding excess N at 2.6 ± 2.2 × 1011 mol N yr− 1 for  33% of the total). Assuming an N:P of 40 and this rate of excess N accumulation due to the process, N2 fixation in the North Atlantic subtropical gyre is estimated at  4 × 1011 mol N yr− 1. This relatively low rate of N2 fixation suggests that i) the rate of N2 fixation in the North Atlantic is greatly overestimated in some previous analyses, ii) the main thermocline is not the primary repository of N fixed by diazotrophs, and/or iii) the N:P ratio of exported diazotrophic organic matter is much lower than generally assumed. It is this last possibility, and our uncertainty in the N:P ratios of exported material supporting excess N development, that greatly lessens our confidence in geochemical measures of N2 fixation.  相似文献   

10.
Mesoscale eddies and tropical instability waves in the eastern tropical Pacific, first revealed by satellite infrared imagery, play an important role in the dynamics and biology of the region, and in the transfer of mass, energy, heat, and biological constituents from the shelf to the deep ocean and across the equatorial currents.From boreal late autumn to early spring, four to 18 cyclonic or anticyclonic eddies are formed off the coastal region between southern Mexico and Panama. The anticyclonic gyres, which tend to be larger and last longer than the cyclonic ones, are the best studied: they typically are 180–500 km in diameter, depress the pycnocline from 60 to 145 m at the eddy center, have swirl speeds in excess of 1 m s−1, migrate west at velocities ranging from 11 to 19 cm s−1 (with a slight southward component), and maintain a height signature of up to 30 cm. The primary generating agents for these eddies are the strong, intermittent wind jets that blow across the isthmus of Tehuantepec in Mexico, the lake district in Nicaragua and Costa Rica, and the Panama canal. Other proposed eddy-generating mechanisms are the conservation of vorticity as the North Equatorial Counter Current (NECC) turns north on reaching America, and the instability of coastally trapped waves/currents.Tropical Instability Waves (TIWs) are perturbations in the SST fronts on either side of the equatorial cold tongue. They produce SST variations on the order of 1–2 °C, have periods of 20–40 days, wavelengths of 1000–2000 km, phase speeds of around 0.5 m s−1 and propagate westward both north and south of the Equator. The Tropical Instability Vortices (TIVs) are a train of westward-propagating anticyclonic eddies associated with the TIWs. They exhibit eddy currents exceeding 1.3 m s−1, a westward phase propagation speed between 30 and 40 km d−1, a signature above the pycnocline, and eastward energy propagation. Like the TIWs, they result from the latitudinal barotropically unstable shear between the South Equatorial Current (SEC) and the NECC with a potential secondary source of energy from baroclinic instability of the vertical shear with the Equatorial Undercurrent (EUC).This review of mesoscale processes is part of a comprehensive review of the oceanography of the eastern tropical Pacific Ocean.  相似文献   

11.
Quasi-synoptic observations of the horizontal and vertical structure of a cold-core cyclonic mesoscale eddy feature (Cyclone Noah) were conducted in the lee of Hawai’i from November 4–22, 2004 as part of the E-Flux interdisciplinary collaborative research program. Cyclone Noah appears to have spun up to the southwest of the ‘Alenuihaha Channel (between Maui and Hawai’i) as a result of strong and persistent northeasterly trade winds through the channel. Shipboard hydrographic surveys 2.5 months later suggest that Noah weakened and was in a hypothesized spin-down phase of its life cycle. Although the initial surface expression of Noah was limited in scale to 40 km in diameter and, as evidenced by surface temperatures, 2–3 °C cooler than the surrounding waters, depth profiles revealed a fully developed semi-elliptical shallow feature (200 m), 144 km long and 90 km wide (based on sigma-t=23 kg m−3) with tangential speeds of 40–80 cm s−1, and substantial isopycnal doming. Potential vorticity distribution of Noah suggests that radial horizontal flow of the core water was inhibited from the surface to depths of 75 m, with high vorticity confined above the sigma-t=23.5 kg m−3 isopycnal surface. Upward displacements of isopycnal surfaces in the eddy's center (50 m) were congruent with enhanced pigment concentrations (0.50 mg m−3). Comparisons of the results obtained for E-Flux I (Noah) and E-Flux III (Opal) suggest that translation characteristics of cyclonic Hawaiian lee eddies may be important in establishing the biogeochemical and biological responses of the oligotrophic ocean to cyclonic eddies.  相似文献   

12.
Benthic foraminiferal biomass, density, and species composition were determined at 10 sites in the Gulf of Mexico. During June 2001 and 2002, sediment samples were collected with a GoMex box corer. A 7.5-cm diameter subcore was taken from a box core collected at each site and sliced into 1-cm or 2-cm sections to a depth of 2 or 3 cm; the >63-μm fraction was examined shipboard for benthic foraminifera. Individual foraminifers were extracted for adenosine triphosphate (ATP) using a luciferin–luciferase assay, which indicated the total ATP content per specimen; that data was converted to organic carbon. Foraminiferal biomass and density varied substantially (2–53 mg C m−2; 3600–44,500 individuals m−2, respectively) and inconsistently with water depth: although two 1000-m deep sites were geographically separated by only 75 km, the foraminiferal biomass at one site was relatively low (9 mg C m−2) while the other site had the highest foraminiferal biomass (53 mg C m−2). Although most samples from Sigsbee Plain (>3000 m) had low biomass, one Sigsbee site had >20 mg foraminiferal C m−2. The foraminiferal community from all sites (i.e. bathyal and abyssal locales) was dominated by agglutinated, rather than calcareous or tectinous, species. Foraminiferal density never exceeded that of metazoan meiofauna at any site. Foraminiferal biomass, however, exceeded metazoan meiofaunal biomass at 5 of the 10 sites, indicating that foraminifera constitute a major component of the Gulf's deep-water meiofaunal biomass.  相似文献   

13.
The study on dissolved organic ligands capable to complex copper ions (LT), surface-active substances (SAS) and dissolved organic carbon (DOC) in the Northern Adriatic Sea station (ST 101) under the influence of Po River was conducted in period from 2006–2008. The acidity of surface-active organic material (Acr) was followed as well. The results are compared to temperature and salinity distributions. On that way, the contribution of the different pools of ligands capable to complex Cu ions could be determined as well as the influence of aging and transformation of the organic matter. The LT values in the investigated period were in the range of 40–300 nmol l−1. The range of DOC values for surface and bottom samples were 0.84–1.87 mg l−1 and 0.80–1.30 mg l−1, respectively. Total SAS concentrations in the bottom layer were 0.045–0.098 mg l−1 in equiv. of Triton-X-100 while those in the surface layer were 0.050–0.143 mg l−1 in equiv. of Triton-X-100. The majority of organic ligands responsible for Cu binding in surface water originate from new phytoplankton production promoted by river borne nutrients. Older, transformed organic matter, possessing higher relative acidity, is the main contributor to the pool of organic ligands that bind copper in the bottom samples. It was estimated that 9% of DOC in surface samples and 12% of DOC in the bottom samples are present as ligands capable to complex copper ions.  相似文献   

14.
Different estimates were used to assess the diversity of the total macrofauna and its major taxonomic groups separately from a broad bathymetric range at a site in the NE Atlantic. In the Goban Spur region, a transect was sampled from the shelf to the abyssal plain over a depth range from 200 to 4500 m and in the Porcupine Sea Bight two stations were sampled (at 3670 m and 4115 m). Species diversity (the number of species per number of individuals) increased with increasing water depth, both when expressed as Hurlbert's E(Sn) and as Shannon's H′log e. The expected number of species in a 100-individual sample E(S100) of total macrofauna increased from 30 on the shelf to 68 on the abyssal plain. Evenness (the proportional abundance of species), estimated with Shannon's J′, also increased with water depth from 0.66 to 0.91, whereas dominance (Simpson's D) decreased from 0.09 to 0.01. Species richness (the number of species per unit of area), however, showed a parabolic pattern with a peak at the upper slope. The largest number of species was found at the slope station at 1425 m (232 species within 0.66 m2). It is argued that species richness is not a synonym of species diversity, but that species richness depends both on species density (which decreases with increasing water depth) and on species diversity. Across the whole bathymetric range (200 to 4500 m) a total of 696 species within 8327 specimens in a total sampled area of 4.12 m2 were counted, yielding mean values of 12 individuals per species and 169 species per m2. Different communities were found to exist on the shelf, slope and abyss. It is suggested that this could have been caused by different selection processes. Differences in life-history strategies and organic-matter supply could (at least partly) explain the different community structures and diversity patterns found along the depth gradient.  相似文献   

15.
The stable isotopes of dissolved organic carbon (DOC) are a powerful tool for distinguishing sources and inputs of organic matter in aquatic systems. While several methods exist to perform these analyses, no labs routinely utilize a high temperature combustion (HTC) instrument. Advantages of HTC instruments include rapid analysis, small sample volumes and minimal sample preparation, making them the favored devices for most routine oceanic DOC concentration measurements. We developed a stable carbon DOC method based around an HTC system. This method has the benefit of a simple setup, requiring neither vacuum nor high pressures. The main drawback of the method is a significant blank, requiring careful accounting of all blank sources for accurate isotopic and concentration values. We present here a series of experiments to determine the magnitude, source and isotopic composition of the HTC blank. Over time, the blank is very stable at  20 ng of carbon with a δ13C of − 18.1‰ vs. VPDB. The similarity of the isotopic composition of the blank and seawater samples makes corrections relatively minor. The precision of the method was determined by oxidizing organic standards with a wide isotopic and concentration range (− 9‰ to − 39‰; 18 μM to 124 μM). Analysis of seawater samples demonstrates the accuracy for low concentration, high salinity samples. The overall error on the measurement is approximately ± 0.8‰.  相似文献   

16.
Jingfeng Wu   《Marine Chemistry》2007,103(3-4):370-381
A low-blank pre-concentration procedure is described for the analysis of picomolar iron (Fe) in seawater by isotope dilution high-resolution inductively coupled plasma mass-spectrometry (HR-ICPMS). The procedure uses a two-step Mg(OH)2 co-precipitation procedure to extract Fe from a 50 ml seawater sample into a 100 μl 4% nitric acid (HNO3) solution followed by HR-ICPMS measurement. The high pre-concentration ratio ( 500:1) achieved by the procedure minimizes the Fe blank due to ICPMS instrumental Fe background and results in a detection limit of  2 pM and a precision of  4% at the 50 pM Fe level. The measurement of a low-Fe seawater sample spiked with gravimetric Fe standard shows that the method can clearly distinguish 0.01 nM Fe from 0.02 nM Fe in seawater with high accuracy. The method is demonstrated by the analysis of dissolved Fe in the equatorial Pacific Ocean.  相似文献   

17.
A new deep-sea laser Raman spectrometer (DORISS—Deep Ocean Raman In Situ Spectrometer) is used to observe the preferential dissolution of CO2 into seawater from a 50%–50% CO2–N2 gas mixture in a set of experiments that test a proposed method of CO2 sequestration in the deep ocean. In a first set of experiments performed at 300 m depth, an open-bottomed 1000 cm3 cube was used to contain the gas mixture; and in a second set of experiments a 2.5 cm3 funnel was used to hold a bubble of the gas mixture in front of the sampling optic. By observing the changing ratios of the CO2 and N2 Raman bands we were able to determine the gas flux and the mass transfer coefficient at 300 m depth and compare them to theoretical calculations for air–sea gas exchange. Although each experiment had a different configuration, comparable results were obtained. As expected, the ratio of CO2 to N2 drops off at an exponential rate as CO2 is preferentially dissolved in seawater. In fitting the data with theoretical gas flux calculations, the boundary layer thickness was determined to be  42 μm for the gas cube, and  165 μm for the gas funnel reflecting different boundary layer turbulence. The mass transfer coefficients for CO2 are kL = 2.82 × 10− 5 m/s for the gas cube experiment, and kL = 7.98 × 10− 6 m/s for the gas funnel experiment.  相似文献   

18.
Biogeochemical processes in sediments under the influence of the Rhône River plume were studied using both in situ microelectrodes and ex situ sediment core incubations. Organic carbon (OC) and total nitrogen (TN) content as well as stable carbon isotopic composition of OC (δ13COC) were analysed in 19 surface sediments to determine the distribution and sources of organic matter in the Rhône delta system. Large spatial variations were observed in both the total O2 uptake (5.2 to 29.3 mmol m−2 d−1) and NH4+ release (−0.1 to −3.5 mmol m−2 d−1) rates at the sediment–water interface. The highest fluxes were measured near the Rhône River mouth where sedimentary OC and TN contents reached 1.81% and 0.23% respectively. Values of δ13COC ranged from −26.83‰ to −23.88‰ with a significant seawards enrichment tracing the dispersal of terrestrial organic matter on the continental shelf. The amount of terrestrial-derived OC reaches 85% in sediments close to the Rhône mouth decreasing down to 25% in continental shelf sediments. On the prodelta, high terrestrial OC accumulation rates support high oxygen uptake rates and thus indicating that a significant fraction of terrestrial OC is remineralized. A particulate organic carbon (POC) mass balance indicates that only 3% of the deposited POC is remineralized in prodelta sediments while 96% is recycled on the continental shelf. It was calculated that a large proportion of the Rhône POC input is either buried (52%) or remineralized (8%), mostly on the prodelta area. The remaining fraction (40%) is either mineralized in the water or exported outside the Rhône delta system in dissolved or particulate forms.  相似文献   

19.
Particulate matter in aquatic systems is an important vehicle for the transport of particulate organic carbon (POC). Its accurate measurement is of central importance for the understanding of marine carbon cycling. Previous work has shown that GF/F-filter-based bottle-sample-derived concentration estimates of POC are generally close to or higher than large-volume in-situ-pump-derived values (and in some rare cases in subzero waters are up to two orders of magnitude higher). To further investigate this phenomenon, water samples from the surface and mid-water Northeast Atlantic and the Baltic Sea were analyzed. Our data support a bias of POC concentration estimates caused by adsorption of nitrogen-rich dissolved organic material onto GF/F filters. For surface-ocean samples the mass per unit area of exposed filter and composition of adsorbed material depended on the filtered volume. Amounts of adsorbed OC were enhanced in the surface ocean (typically 0.5 μmol cm− 2 of exposed filter) as compared to the deep ocean (typically 0.2 μmol cm− 2 of exposed filter). These dependencies should be taken into account for future POC methodologies. Bottle/pump differences of samples that were not corrected for adsorption were higher in the deep ocean than in the surface ocean. This discrepancy increased in summer. It is shown that POC concentration estimates that were not corrected for adsorption depend not only on the filtered volume, true POC concentration and mass of adsorbed OC, but also on the filter area. However, in all cases we studied, correction for adsorption was important, but not sufficient, to explain bottle/pump differences. Artificial formation of filterable particles and/or processes leading to filterable material being lost from and/or missed by sample-processing procedures must be considered. It can be deduced that the maximum amounts of POC and particulate organic nitrogen (PON) that can be artificially formed per liter of filtered ocean water are  3–4 μM OC (5–10% of dissolved OC) and  0.2–0.5 μM ON (2–10% of dissolved ON), respectively. The relative sensitivities of bottle and pump procedures, and of surface- and deep-ocean material, to artificial particle formation and the missing/losing of material are evaluated. As present procedures do not exist to correct for all possible biasing effects due to artificial particle formation and/or miss/loss of filterable material, uncertainties of filtration-based estimates of POC concentrations need further testing. The challenge now is to further constrain the magnitude of the biasing effects that add to the adsorption effect to reduce the uncertainties of estimates of POC concentrations, inventories and fluxes in the ocean.  相似文献   

20.
Methods are described for the rapid (11 min) automated shipboard analysis of dissolved sulfur hexafluoride (SF6) in small volume (200 cm3) seawater samples. Estimated precision for the SF6 measurements is 2% or 0.02 fmol kg−1 (whichever is greater). The method also allows for the simultaneous measurement of chlorofluorocarbon-11 (CFC11) and chlorofluorocarbon-12 (CFC12) on the same water sample, with significantly improved sensitivity over previous analytical methods.  相似文献   

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