首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献，搜索用时 31 毫秒
1.
Salmonid fishes are typically anadromous, that is, they achieve the bulk of their growth in the sea, and migrate into rivers to reproduce. As juveniles, they may arrive in the estuary almost immediately after emergence from a gravel bed in the river, or after a few days, weeks, months, or years in fresh water, according to species and developmental opportunity. Thereafter, the length of estuarine residence depends on the estuary’s size, shape, and productivity; on water flow patterns and velocities; on salinity and temperature; and on the species and size of the salmon. It is supposed that estuaries offer salmonids three primary advantages: productive foraging, relative refuge from predators, and a physically intermediate environment for transition from fresh water to marine physiological control systems. The present paper finds the evidence for the foraging advantage strong, for the predator refuge equivocal, and for the physiological transition function applicable particularly to Pacific species migrant at the fry stage.  相似文献   

2.
Groups of embryonic grass shrimp,Palaemonetes pugio, were exposed to 0.1 and 0.3 mg/l cadmium at 30 ppt salinity and 25°C for the last 1, 4 or 8 days prior to hatching. Other groups of embryos were cultured in uncontaminated seawater. Prehatch exposure to cadmium was found to have no additive effect on the sensitivity of the larvae to cadmium exposure and salinity stress for 14 days after hatching. Only one group of larvae, exposed to 0.1 mg/l cadmium for 4 days before hatching, and transferred to 10 ppt salinity water containing 0.1 mg/l cadmium after hatching, showed a significant (X 2, P<0.05) decrease in survival, compared to control survival. No significant decreases in survival were observed for any larvae transferred to 15 and 30 ppt salinity at a pre- and posthatch cadmium concentration of 0.1 mg/l. At a pre- and posthatch cadmium concentration of 0.3 mg/l, significant decreases in survival were observed for all of the larvae transferred to 10 and 15 ppt salinity after hatching. Significant decreases in survival were observed for only 2 of the groups exposed before hatching and transferred to 30 ppt salinity and 0.3 mg/l cadmium after hatching.  相似文献   

3.
A large assemblage of salmon bones excavated 50 yr ago from an ∼10,000-yr-old archaeological site near The Dalles, Oregon, USA, has been the primary evidence that early native people along the Columbia River subsisted on salmon. Recent debate about the human role in creating the deposit prompted excavation of additional deposits and analysis of archaeologic, geologic, and hydrologic conditions at the site. Results indicate an anthropogenic source for most of the salmonid remains, which have associated radiocarbon dates indicating that the site was occupied as long ago as 9300 cal yr B.P. The abundance of salmon bone indicates that salmon was a major food item and suggests that migratory salmonids had well-established spawning populations in some parts of the Columbia Basin by 9300-8200 yr ago.  相似文献   

4.
Evolution of the shallow groundwater quality under saline intrusion in porous aquifer system has been studied with environmental isotopes and geochemistry in the Laizhou Bay area, China. Two campaigns of water sampling from various sources were carried out in spring and winter for environmental isotopic and chemical analyses. The origin of groundwater salinity from intrusion of both modern seawater and deep brine water was identified by analysing the correlations between 18O, D, T, Cl−, SO42− and electrical conductivity. The results indicate that the brine is originated from evaporating and concentrating of intruded seawater and its δD and δ18O are different from modern seawater but similar to those of mixture of seawater with fresh groundwater. It is hard to distinguish the salinity origin in this area by the δD–δ18O relationship alone. The relations between δ18O and conductivity, Cl− and SO42− have been used to identify the salinity origin due to the distinct difference in salinity between the brine and seawater, conjunctively with use of T. A threshold of T = 12 TU was adopted to identify the origin of saline groundwater.  相似文献   

5.
Calcium and magnesium concentrations in seawater have varied over geological time scales. On short time scales, variations in the major ion composition of seawater influences coccolithophorid physiology and the chemistry of biogenically produced coccoliths. Validation of those changes via controlled laboratory experiments is a crucial step in applying coccolithophorid based paleoproxies for the reconstruction of past environmental conditions. Therefore, we examined the response of two species of coccolithophores, Emiliania huxleyi and Coccolithus braarudii, to changes in the seawater Mg/Ca ratio (≈0.5 to 10 mol/mol) by either manipulating the magnesium or calcium concentration under controlled laboratory conditions. Concurrently, seawater Sr/Ca ratios were also modified (≈2 to 40 mmol/mol), while keeping salinity constant at 35. The physiological response was monitored by measurements of the cell growth rate as well as the production rates of particulate inorganic and organic carbon, and chlorophyll a. Additionally, coccolithophorid calcite was analyzed for its elemental composition (Sr/Ca and Mg/Ca) as well as isotope fractionation of calcium and magnesium (Δ44/40Ca and Δ26/24Mg). Our results reveal that physiological rates were substantially influenced by changes in seawater calcium rather than magnesium concentration within the range estimated to have occurred over the past 250 million years when coccolithophores appear in the fossil record. All physiological rates of E. huxleyi decreased at a calcium concentration above 25 mmol L−1, whereas C. braarudii displayed a higher tolerance to increased seawater calcium concentrations. Partition coefficient of Sr was calculated as 0.36 ± 0.04 (±2σ) independent of species. Partition coefficient of Mg2+ increased with increasing seawater Ca2+ concentrations in both coccolithophore species. Calcium isotope fractionation was constant at 1.1 ± 0.1‰ (±2σ) and not altered by changes in seawater Mg/Ca ratio. There is a well-defined inverse linear relationship between calcium isotope fractionation and partition coefficient of Sr2+ in all experiments, suggesting similar controls on both proxies in the investigated species. Magnesium isotope ratios were relatively stable for seawater Mg/Ca ratios ranging from 1 to 5, with a higher degree of fractionation in Emiliania huxleyi (by ≈0.2‰ in Δ26/24Mg). Although Mg/Ca ratios in the calcite of coccolithophores and foraminifera are similar, the former have considerably higher Δ26/24Mg (by >+3‰), presumably due to differences in calcification mechanisms between the two taxa. These observations suggest, a physiological control over magnesium elemental and isotopic fractionation during the process of calcification in coccolithophores.  相似文献   

6.
This study presents magnesium stable-isotope compositions of various biogenic carbonates of several marine calcifying organisms and an algae species, seawater samples collected from the western Dutch Wadden Sea, and reference materials. The aim of this study is to explore the influence of mineralogy, taxonomy and environmental factors (e.g., seawater isotopic composition, temperature, salinity) on magnesium-isotopic (δ26Mg) ratios of skeletal carbonates. Using high-precision multi-collector inductively coupled plasma mass spectrometry, we observed that the magnesium-isotopic composition of seawater from the semi-enclosed Dutch Wadden Sea is identical to that of open marine seawater. We further found that a considerable component of the observed variability in δ26Mg values of marine skeletal carbonates can be attributed to differences in mineralogy. Furthermore, magnesium-isotope fractionation is species-dependent, with all skeletal carbonates being isotopically lighter than seawater. While δ26Mg values of skeletal aragonite and high-magnesium calcite of coralline red algae indicate the absence or negligibility of metabolic influences, the δ26Mg values of echinoids, brachiopods and bivalves likely result from a taxon-specific level of control on Mg-isotope incorporation during biocalcification. Moreover, no resolvable salinity and temperature effect were observed for coralline red algae and echinoids. In contrast, Mg-isotope data of bivalves yield ambiguous results, which require further validation. The data presented here, point to a limited use of Mg isotopes as temperature proxy, but highlight the method’s potential as tracer of seawater chemistry through Earth’s history.  相似文献   

7.
Gaza central seawater desalination plant is a promising solution to alleviate the problem of water crisis in the Gaza Strip. The plant in the short term, phase (I), will desalinate seawater for potable uses with a capacity of 55 million cubic meters per year, while in the long term, phase (II), the plant capacity will be doubled to 110 million cubic meters per year of freshwater. As a product from the reverse osmosis process, a huge amount of brine with salinity reaches to 75,000 mg/L will be redirected to seawater; nearly 12,200 m3/h of brine will be rejected from phase (I) while in the long term, a brine flow rate of 24,400 m3/h will be disposed from phase (II). In order to minimize the negative impacts of the rejected brine on the marine environment, it is urgent to modeling numerically the impact of the discharged brine through various disposal systems to define the most environmental system. Various scenarios were defined and simulated using CORMIX model to study the efficiencies of onshore surface open channel, offshore submerged single port as well as offshore submerged multiport outfalls taking salinity variations as an indicator. Sensitivity analysis was conducted to identify the most influencing input parameters on the simulation results as well as to evaluate the optimal environmental disposal system which can mitigate the adverse impacts of brine on the marine ecosystem as much as possible in the worst seawater conditions. The simulation results showed that the discharge via surface open channel is not environmentally feasible where the seawater salinity rose by more than 2000 mg/L at RMZ. The single-port scenario can meet the regulations at RMZ but the standard at GMZ was not met, where the rejected brine from phase (I) through single port at 1500 m offshore raises the seawater salinity at GMZ by more than 600  mg/L. The staged multiport outfall, capped by 24 ports, achieves acceptable brine dilution at seawater depth of about 7.5  m, and in the worst ambient conditions in the case of phase (II) in operation, the brine’s excess salinity was 536, 497, and 379 mg/L above the salinity of seawater at RMZ, GMZ, and ROI, respectively.  相似文献   

8.
A sediment core from Hulun Lake, Inner Mongolia was analyzed for species assemblages and shell chemistry of ostracodes to investigate changes in the hydrology and climate of the East Asian summer monsoon margin during the Holocene. Darwinula stevensoni was abundant, Ilyocypris spp. scarce, littoral ostracodes absent and Mg/Ca, Sr/Ca and δ18O were low 11,100 to 8300 yr ago, indicating high lake levels and cool/fresh waters. Darwinula stevensoni declined largely, Ilyocypris spp. throve, littoral ostracodes were rare and chemical indicators remained in low values 8300 to 6200 yr ago, suggesting that the lake continued high stands but water became warm. The lake then contracted and water became cool/brackish 6200 to 4300 yr ago. Littoral ostracodes flourished 4300 to 3350 yr ago, marking the lowest lake levels of the entire Holocene. The lake level recovered and water salinity decreased 3350 to 1900 yr ago. From 1900 to 500 yr ago, the lake maintained the preceding status albeit lowered stands and increased salinities 1100 to 800 yr ago. During the recent 500 yr, the lake expanded and water salinity decreased. The data imply that the East Asian summer monsoon did not intensify until 8300 yr ago and weakened dramatically 4300 to 3350 yr ago.  相似文献   

9.
The objectives of this study were to determine the tolerance of various life stages of zebra mussels to salinity; determine the extent to which acclimation events in estuarine systems, affect tolerance of zebra mussels; and determine the effects of salinity on health or condition of adult zebra mussels. At high temperatures (18–20°C), the condition of zebra mussels is reduced at salinities above 1%.. However, at lower temperatures (3–12°C), the optimum salinity for zebra mussels is 2–4%.. The incipient lethal salinity of post-veligers is near 2%., of larger adults (5–15 mm) between 2%. and 4%., and of veliger larvae near 4.5%.. Zebra mussels are able to acclimate to slowly changing salinities (i.e., 1%. d?1) such that the time to 50% mortality of a population should be greater than 1 yr at temperatures near 20°C and salinites up to 8%.  相似文献   

10.
Understanding groundwater salinity sources in the Gulf Coast Aquifer System (GCAS) is a critical issue due to depletion of fresh groundwater and concerns for potential seawater intrusion. The study objective was to assess sources of groundwater salinity in the GCAS using ～1,400 chemical analyses and ～90 isotopic analyses along nine well transects in the Texas Gulf Coast, USA. Salinity increases from northeast (median total dissolved solids (TDS) 340 mg/L) to southwest (median TDS 1,160 mg/L), which inversely correlates with the precipitation distribution pattern (1,370– 600 mm/yr, respectively). Molar Cl/Br ratios (median 540–600), depleted δ2H and δ18O (?24.7‰, ?4.5‰) relative to seawater (Cl/Br ～655 and δ2H, δ18O 0‰, 0‰, respectively), and elevated 36Cl/Cl ratios (～100), suggest precipitation enriched with marine aerosols as the dominant salinity source. Mass balance estimates suggest that marine aerosols could adequately explain salt loading over the large expanse of the GCAS. Evapotranspiration enrichment to the southwest is supported by elevated chloride concentrations in soil profiles and higher δ18O. Secondary salinity sources include dissolution of salt domes or upwelling brines from geopressured zones along growth faults, mainly near the coast in the northeast. The regional extent and large quantities of brackish water have the potential to support moderate-sized desalination plants in this location. These results have important implications for groundwater management, suggesting a current lack of regional seawater intrusion and a suitable source of relatively low TDS water for desalination.  相似文献   

11.
The Japan Sea was profoundly different during glacial times than today. Available δ18O evidence indicates that sea surface salinity was lower by several per mil. This probably increased the stability of the water column and caused anoxic sedimentary conditions in the deep sea, as shown by the absence of benthic microfossils and the presence of laminated sediment. These changes are likely related to the effects of late Quaternary sea-level change on the shallow sills (ca. 130 m) across which the Japan Sea exchanges with the open ocean. The Hwang He (Yellow River) has previously been implicated as the source of fresh water to the Japan Sea during glaciation, but the possible roles of the Amur River and excess precipitation over evaporation must also be considered. Ambiguous radiocarbon chronologies for the latest Quaternary of Japan Sea cores do not adequately constrain the timing of salinity lowering. Previous studies have suggested that lowest sea surface salinity was achieved 27,000 to 20,000 14C yr B.P. However, if global sea-level fall restricted exchange with the open ocean circulation, then lowest salinity in the Japan Sea may have occurred as recently as 15,000 to 20,000 yr ago when sea level was lowest. If this alternative is correct, then as sea level abruptly rose about 12,000 yr ago, relatively fresh water must have been discharged to the open Pacific. This might have affected the dynamics of outflow, local faunal and floral expression of the polar front, and stable isotope ratios in foraminifera. These environmental changes could be misinterpreted as evidence for the cooling of Younger Dryas age, which has not been identified in nearby terrestrial records.  相似文献   

12.
Eggwaters from the chambered cephalopod Nautilus are depleted in both 18O and deuterium relative to ambient seawater. Eggwaters from six other species, including the related chambered cephalopod Sepia, do not show such depletion. These observations indicate that the previously observed step towards more positive δ18O values in calcium carbonate laid down after Nautilus hatches, relative to carbonate precipitated prior to hatching, can be explained by equilibration of the carbonate with water in the egg before hatching and with seawater after hatching. The presence of an oxygen isotope difference between eggwater and seawater for Nautilus and its absence for Sepia suggest that hatching will be recorded in the δ18O values of shell carbonates for some but not all extinct and extant chambered cephalopods.The δ13C values of the organic fraction of the siphuncle in Nautilus do not show any consistent pattern with regard to the time of formation before or after hatching. This observation suggests that the minimum in δ13C values previously observed for calcium carbonate precipitated after Nautilus hatches is not caused by a change in food sources once the animal becomes free-swimming, as has been suggested.  相似文献   

13.
Records of stable carbon isotopes (δ13C) are presented from cores collected from four San Francisco Bay marshes and used as a proxy for changes in estuary salinity. The δ13C value of organic marsh sediments are a reflection of the relative proportion of C3 vs. C4 plants occupying the surface, and can thus be used as a proxy for vegetation change on the marsh surface. The four marshes included in this study are located along a natural salinity gradient that exists in the San Francisco Bay, and records of vegetation change at all four sites can be used to infer changes in overall estuary paleosalinity. The δ13C values complement pollen data from the same marsh sites producing a paleoclimate record for the late Holocene period in the San Francisco Bay estuary. The data indicate that there have been periods of higher-than-average salinity in the Bay estuary (reduced fresh water inflow), including 1600-1300 cal yr B.P., 1000-800 cal yr B.P., 300-200 cal yr B.P., and ca. A.D. 1950 to the present. Periods of lower-than-average salinity (increased fresh water inflow) occurred before 2000 cal yr B.P., from 1300 to 1200 cal yr B.P. and ca. 150 cal yr B.P. to A.D. 1950. A comparison of the timing of these events with records from the California coast, watershed, and beyond the larger drainage of the Bay reveals that the paleosalinity variations reflected regional precipitation.  相似文献   

14.
Enteromorpha intestinalis is a bloom-forming species of macroalgae associated with eutrophication. The objective of this study was to investigate how this alga performs osmoregulation and nutrient uptake in order to proliferate under environmental conditions that covary with eutrophication. We quantified the response ofE. intestinalis to salinity, light, and nutrients. We performed two short-term (48 h) laboratory experiments (salinity alone and salinity × nutrients × light) to examine the algal responses of tissue water, potassium (K+), and nutrient (NO 3 − and total N) content. Tissue water content decreased with increasing salinity, and although K+ concentration decreased from the initial concentration, it decreased less with increased salinity treatment demonstrating two mechanisms to withstand short-term salinity fluctuation. The salinity × nutrient × light experiment showed that, in the short term, light had an interaction with tissue K+. Total tissue N content was positively related to N treatment level, and light did not affect total nutrient concentration. The effect of light was present whether the nutrients were present in the tissue as inorganic or organic forms. With reduced light, we hypothe size that the assimilation of inorganic to organic N was energy limited. The ability of this alga to take up available nutrients rapidly for growth and short-term osmoregulation, even under low light and salinity levels, helps to explain the bloom potential ofE. intestinalis.  相似文献   

15.
The growth, morphology, and chemical composition ofHydrilla verticillata, Myriophyllum spicatum, Potamogeton perfoliatus, andVallisneria americana were compared among different salinity and light conditions. Plants were grown in microcosms (1.2 m5) under ambient photoperiod adjusted to 50% and 8% of solar radiation. The culture solution in five pairs of tanks was gradually adjusted to salinities of 0, 2, 4, 6, and 12‰. With the exception ofH. verticillata, the aquatic macrophytes examined may be considered eurysaline species that are able to adapt to salinities one-third the strength of sea water. With increasing salinity, the inflorescence production decreased inM. spicatum andP. perfoliatus, yet asexual reproduction in the latter species by underground buds remained constant. Stem elongation increased in response to shading inM. spicatum, while shadedP. perfoliatus had higher concentrations of chlorophylla. In association with high epiphytic mass, chlorophylla concentrations in all species were greatest at 12‰. The concentration of sodium increased in all four species of aquatic macrophytes examined here, indicating that these macrophytes did not possess mechanisms to exclude this ion. The nitrogen content (Y) of the aquatic macrophytes tested increased significantly with higher sodium concentration (X), suggesting that nitrogen may be utilized in osmoregulation (Y = X × 0.288 + 6.10, r2 = 0.71). The tolerance ofV. americana andP. perfoliatus to salinity was greater in our study compared to other investigations. This may be associated with experimental methodology, whereby macrophytes were subjected to more gradual rather than abrupt changes in salinity. The two macrophytes best adapted to estuarine conditions in this study by exhibiting growth up to 12‰, includingM. spicatum andV. americana, also exhibited a greater degree of response in morphology, tissue chemistry (including chlorophyll content and total nitrogen), and reproductive output in response to varying salinity and light conditions.  相似文献   

16.
Physical and chemical parameters were measured in a subtropical estuary with a blind river source in southwest Florida, United States, to assess seasonal discharge of overland flow and groundwater in hydrologic mixing. Water temperature, pH, salinity, alkalinity, dissolved inorganic carbon (DIC), δ18O, and δ13CDIC varied significantly due to seasonal rainfall and climate. Axial distribution of the physical and chemical parameters constrained by tidal conditions during sampling showed that river water at low tide was a mixture of freshwater from overland flow and saline ground-water in the wet season and mostly saline groundwater in the dry season. Relationships between salinity and temperature, δ18O, and DIC for both the dry and wet seasons showed that DIC was most sensitive to seawater mixing in the estuary as DIC changed in concentration between values measured in river water at the tidal front to the most seaward station. A salinity-δ13CDIC model was able to describe seawater mixing in the estuary for the wet season but not for the dry season because river water salinity was higher than that of seawater and the salinity gradient between seawater and river water was small. A DIC-δ13CDIC mixing model was able to describe mixing of carbon from sheet flow and river water at low tide, and river water and seawater at high tide for both wet and dry seasons. The DIC-δ13CDIC model was able to predict the seawater end member DIC for the wet season. The model was not able to predict the seawater end member DIC for the dry season data due to secondary physical and biogeochemical processes that altered estuarine DIC prior to mixing with seawater. The results of this study suggest that DIC and δ13CDIC can provide additional insights into mixing of river water and seawater in estuaries during periods where small salinity gradients between river water and seawater and higher river water salinities preclude the use of salinity-carbon models.  相似文献   

17.
Groundwater suitability for agriculture in an island with limited recharge area may easily be influenced by seawater intrusion. The aim of this study was to investigate seawater intrusion to the suitability of the groundwater for oil palm cultivation at the ex-promontory land of Carey Island in Malaysia. This is the first study that used the integrated method of geo-electrical resistivity and hydro-geochemical methods to investigate seawater intrusion to the suitability of groundwater for oil palm cultivation at two different land cover condition. The relationship between earth resistivity, total dissolved solids and earth conductivity was derived with crop suitability classification according to salinity, used to identify water types and also oil palm tolerance to salinity. Results from the contour conductivity maps show that area facing severe coastal erosion and area still intact with mangrove forest exhibits unsuitable groundwater condition for oil palm at the unconfined aquifer thickness of 15 and 31 m, respectively. Based on local sea-level rise prediction and Ghyben–Herzberg assumption (sharp interface), the condition in the study area, especially in severe erosion area, by the twenty-first century will no longer be suitable for oil palm plantation. The application of geo-electrical method combined with geochemical data, aided with the information on environmental history and oil palm physiography, has demonstrated that the integration of techniques is an effective tool in defining the status of agricultural suitability affected by salinity at the coastal aquifer area.  相似文献   

18.
The relationships between electrical conductivity, temperature, salinity, and density are studied for brackish Lake Issyk-Kul. These studies are based on a newly determined major ion composition, which for the open lake shows a mean absolute salinity of 6.06 g kg−1. The conductivity-temperature relationship of the lake water was determined experimentally showing that the lake water is about 1.25 times less conductive than seawater diluted to the same absolute salinity as that of the lake water. Based on these results, an algorithm is presented to calculate salinity from in-situ conductivity measurements. Applied to the field data, this shows small but important vertical salinity variations in the lake with a salinity maximum at 200 m and a freshening of the surface water with increasing proximity to the shores. The algorithm we adopt to calculate density agrees well with earlier measurements and shows that at 20°C and 1 atm Lake Issyk-Kul water is about 530 g m−3 denser than seawater at the same salinity. The temperature of maximum density at 1 atm is about 0.15°C lower than that for seawater diluted to the same salinity. Despite its small variations, salinity plays an important role, together with temperature changes, in the static stability and in the production of deep-water in this lake. Changes in salinity may have had important consequences on the mixing regime and the fate of inflowing river water over geological time. Uncharged silicic acid is negligible for the stability of the water column except near an ∼15 m thick nepheloid layer observed at the bottom of the deep basin.  相似文献   

19.
Surface seawater samples from Kamaran Strait of Yemen were collected for physical and chemical parameter determinations. This work reports the results of air and surface seawater temperature, salinity, pH, and total alkalinity measurements. The air temperature ranged from 29.9°C to 36.5°C with an average value of 31.5?±?1.5°C, whereas the seawater surface temperature ranged from 34.0°C to 36.0°C with a mean value of 34.5?±?0.5°C. The salinity was observed to be high, ranging from 38.03 to 38.81 with an average value of 38.45?±?0.22. The pH ranged from 7.74 to 8.27 with a mean value of 8.11?±?0.10. The total alkalinity was found to range from 2.3860 to 2.5000 meq L?1 with an average value of 2.4288?±?0.0351 meq L?1. The result of the study showed that there was a negative correlation between the pH and surface seawater temperature and salinity. The surface seawater of the Kamaran Strait was found to be several fold supersaturated with respect to calcium carbonate. The measured percent degree of saturation ranged from 454% to 668% with respect to calcite and from 246% to 361% with respect to aragonite. The lowest value of supersaturation with respect to both calcite and aragonite were found in front of as-Salif port, where human and developmental activities are intensively increased. The visual inspection of coral reefs distribution and their intensity were obviously observed in areas of high value of supersaturation with respect to both minerals, high transparency of seawater column, and low human activities. Further studies are needed to investigate the occurrence, distribution, and mineralogy of corals and the effects of physical and chemical parameters upon their growth in the region.  相似文献   

20.
Forty-nine aragonitic and calcitic shells from 14 species of marine tropical molluscs (Bivalvia, Gastropoda, Polyplacophora) and ambient waters from Martinique have been analyzed for their carbon and oxygen isotope compositions. Mineralogy of shells was systematically determined by Raman spectroscopy that reveals composite shell structures and early processes of diagenetic alteration. In mangrove, brackish waters result from the mixing between 89±1% of seawater and 11±1% of freshwater, a hydrological budget quantified by both oxygen isotope and salinity mass balance calculations. Mollusc shells from the mangrove environment (S=31‰; δ18O=0.5‰) are characterized by mean δ13C values (−1.2‰) lower than those (+2.6‰) living in the open sea (S=35‰; δ18O=1‰). These low carbon isotope compositions result from the oxidation of organic matter into bicarbonate ions used in the building of mollusc shells. The oxygen isotope compositions of the studied mollusc species are mainly controlled by the temperature and composition of seawater whereas the role of the so-called “vital effects” is negligible. Contrasting with carbon isotopes, variability in the δ18O values among and within species of mollusc shells is very low (1σ=0.15) for a given littoral environment. Using ambient temperatures of seawater (28-30 °C), oxygen isotope fractionations between all studied living species and environmental waters match those extrapolated from the fractionation equation established for molluscs by Grossman and Ku [Chem. Geol., Isot. Geosci. Sect. 59 (1986) 59] in the range 3-20 °C. By analyzing calcite and aragonite layers from the same shell or by comparing shells from different species living in the same environment, there is no evidence that oxygen isotope fractionation between aragonite and water differs from that between calcite and water. On the basis of these results, we conclude that the oxygen isotope compositions of shells from most fossil mollusc species are suitable to estimate past seawater temperatures at any paleolatitude.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号