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1.
The paper reports data on the Nd isotopic composition and the evaluated composition of the sources of magmatism that produced massifs of alkali and basic rocks of the Khaldzan-Buregtei group. The massifs were emplaced in the terminal Devonian at 392–395 Ma in the Ozernaya zone of western Mongolia. The host rocks of the massifs are ophiolites of the early Caledonian Ozernaya zone, which were dated at 545–522 Ma. The massifs were emplaced in the following succession (listed in order from older to younger): (1) nordmarkites and dolerites syngenetic with them; (2) alkali granites and syngenetic dolerites; (3) dike ekerites; (4) dike pantellerites; (5) rare-metal granitoids; (6) alkali and intermediate basites and quartz syenites; and (7) miarolitic rare-metal alkali granites. Our data on the Nd isotopic composition [? Nd(T)] and conventionally used (canonical) ratios of incompatible elements (Nb/U, Zr/Nb, and La/Yb) in rocks from the alkaline massifs and their host ophiolites indicate that all of these rocks were derived mostly from mantle and mantle-crustal enriched sources like OIB, E-MORB, and IAB with a subordinate contribution of N-MORB (DM) and upper continental crustal material. The variations in the ? Nd(T) values in rocks of these massifs suggest multiple mixing of the sources or magmas derived from them when the massifs composing the Khaldzan-Buregtei group were produced. The OIB and E-MORB sources were mixed when the rocks with mantle signatures were formed. The occurrence of nordmarkites, alkali granites, and other rocks whose isotopic and geochemical signatures are intermediate between the values for mantle and crustal sources testifies to the mixing of mantle and crustal magmas. The crustal source itself, which consisted of rocks of the ophiolite complex, was obviously isotopically and geochemically heterogeneous, as also were the magmas derived from it. The model proposed for the genesis of alkali rocks of the Khaldzan-Buregtei massifs implies that the magmas were derived at two major depth levels: (1) mantle, at which the plume source mixed with an E-MORB source, and (2) crustal, at which the ophiolites were melted, and this gave rise to the parental magmas of the nordmarkites and alkali granites. The basites were derived immediately from the mantle. The mantle syenites, pantellerites, and rare-metal granitoids were produced either by the deep crystallization differentiation of basite magma or by the partial melting of the parental basites and the subsequent crystallization differentiation of the generated magmas. Differentiation likely took place in an intermediate chamber at depth levels close to the crustal (ophiolite) level of magma generation. Only such conditions could ensure the intense mixing of mantle and crustal magmas. The principal factor initiating magma generation in the region was the mantle plume that controlled within-plate magmatism in the Altai-Sayan area and the basite magmas related to this plume, which gave rise to small dikes and magmatic bodies in the group of intrusive massifs. 相似文献
2.
为加深对东昆仑区域构造演化和成矿规律的认识,选取祁漫塔格鸭子沟地区花岗岩类岩石开展岩相学、年代学和岩石地球化学研究,探讨其岩石成因、构造背景及与铅锌矿成矿的关系。结果表明,黑云石英二长闪长岩的SIMS锆石U-Pb年龄为(415.5±2.6) Ma,属早泥盆世早期。正长岩、二长花岗岩和石英二长岩与闪长岩相比,具有硅、钾、全碱含量高,低钙、镁、全铁和钛,铝含量相当,闪长岩K 2O含量小于Na 2O,其他岩石K 2O含量大于Na 2O的特点。岩石为准铝质-弱过铝质岩石,既有亚碱性系列也有碱性系列。∑REE平均为305×10 -6; δEu为0.26~1.03,平均为0.61,多数岩石具有Eu负异常;稀土元素球粒陨石标准化配分模式图上呈轻稀土元素富集的右倾型曲线,轻、重稀土发生了分馏作用;岩体明显富集大离子亲石元素Cs、Rb、K,活泼的不相容元素U、Th,轻稀土元素和Pb;相对亏损高场强元素Nb、Ta、Zr、P和Ti,大离子亲石元素Ba和Sr。鸭子沟花岗岩类岩石为以幔源分异为主、少量壳源物质加入的壳幔混合成因,应该是加里东造山期后陆缘裂陷幔源物质上侵形成的岩浆岩。结合区域构造特征和地质背景,推测该岩体形成于后碰撞陆内伸展阶段,并与区域铅锌矿成矿密切相关;在今后的矿产勘查中应重视华力西早期花岗岩类岩石。 相似文献
3.
羌塘东部治多县直根尕卡一带二叠纪栖霞期火山岩主要由中基性火山碎屑岩及熔岩组成,火山岩地球化学研究表明,其主元素表现为高TiO_2和低TiO_2两种特征,球粒陨石标准化稀土配分模式为LREE富集型.MORB标准化的微量元素配分型式为大洋隆起型,显示岩浆形成于板内裂谷构造环境.Sr、Nd、Pb同位素地球化学研究表明火山岩显示明显的亏损地幔源区特征.综合研究表明直根尕卡一带二叠纪栖霞期火山岩形成于大陆边缘拉张构造(或陆缘始裂谷)环境,岩浆起源于地幔,属地幔柱作用的产物. 相似文献
4.
Field relations, mineralogy, major- and trace-element contents (including REE analyses of whole-rock samples and minerals) of three Proterozoic granites and their associated molybdenite mineralized aplites have been studied at Allebuoda, Munka and Kåtaberget in northern Sweden. The granites crystallized from melts that were not saturated with water. The mineralized potassic aplites formed by quenching of residual melts caused by sudden pressure drop, H 2O saturation and vapour escape during tectonic rupturing. Leucogranites with higher Na 2O/K 2O ratios from Allebuoda and Munka crystallized during H 2O-saturated equilibrium conditions in which the exsolved vapour could continuously migrate away. The pressure was probably 3 kbar at Munka, and somewhat lower at Allebuoda. The granites have REE patterns characterized by LREE enrichments and negative Eu anomalies. In comparison, the potassic aplites and the more sodic leucogranites are depleted in LREE, enriched in HREE and have larger negative Eu anomalies. Allanite and monazite are the most important REE carriers in the granites. These minerals are strongly enriched in LREE, whereas fluorite and xenotime, which are more abundant in the aplites, are most enriched in HREE. Due to the strong control of accessory minerals on the REE balance, REE are of limited use in petrogenetic modelling of highly evolved granitic systems. 相似文献
5.
The migmatites from Punta Sirenella (NE Sardinia) are layered rocks containing 3–5 vol.% of centimeter-sized stromatic leucosomes which are mainly trondhjemitic and only rarely granitic in composition. They underwent three deformation phases, from D 1 to D 3. The D 1 deformation shows a top to the NW shear component followed by a top to the NE/SE component along the XZ plane of the S 2 schistosity. Migmatization started early, during the compressional and crustal thickening stage of Variscan orogeny and was still in progress during the following extensional stage of unroofing and exhumation. The trondhjemitic leucosomes, mainly consisting of quartz, plagioclase, biotite ± garnet ± kyanite ± fibrolite, retrograde muscovite and rare K-feldspar, are locally bordered by millimeter-sized biotite-rich melanosomes. The rare granitic leucosomes differ from trondhjemitic ones only in the increase in modal content of K-feldspar, up to 25%. Partial melting started in the kyanite field at about 700–720 °C and 0.8–0.9 GPa, and was followed by re-equilibration at 650–670 °C and 0.4–0.6 GPa, producing fibrolite–biotite intergrowth and coarse-grained muscovite. The leucosomes have higher SiO2, CaO, Na2O, Sr and lower Al2O3, Fe2O3, MgO, TiO2, K2O, P2O5, Rb, Ba, Cr, V, Zr, Nb, Zn and REE content with respect to proximal hosts and pelitic metagreywackes. Sporadic anomalous high content of calcium and ferromagnesian elements in some leucosomes is due to entrainment of significant amounts of restitic plagioclase, biotite and accessory phases. The rare granitic leucosomes reveal peritectic K-feldspar produced by muscovite-dehydration melting. Most leucosomes show low REE content, moderately fractionated REE patterns and marked positive Eu anomaly. Proximal hosts and pelitic metagraywackes are characterized by higher REE content, more fractionated REE patterns and slightly negative Eu anomaly. The trondhjemitic leucosomes were generated by H2O-fluxed melting at 700 °C of a greywacke to pelitic–greywacke metasedimentary source-rock. The disequilibrium melting process is the most reliable melting model for Punta Sirenella leucosomes. 相似文献
6.
对大石寨组火山岩的形成时代和形成背景的认识存在较大的分歧。对采自建组剖面底部英安岩样品中的锆石进行阴极发光照相、微区原位LA-ICP-MS微量元素分析和U-Pb测年。锆石U-Pb同位素分析结果显示,锆石发育典型的岩浆震荡环带, 高Th/U(0.51~1.57),轻稀土元素亏损,重稀土元素富集,具有强烈的正Ce异常和强烈的负Eu异常等特征,表明锆石均属于岩浆成因。22个分析点获得的谐和年龄为(314±1)Ma(MSWD=0.88),代表了大石寨组火山岩的形成时代。结合前人的资料,认为大石寨组火山岩为裂陷早期的产物,而晚古生代的沉积岩石组合为在这一基础上发展起来的具有裂陷盆地性质的沉积组合。 相似文献
7.
对大石寨组火山岩的形成时代和形成背景的认识存在较大的分歧。对采自建组剖面底部英安岩样品中的锆石进行阴极发光照相、微区原位LA—ICP—MS微量元素分析和U-Pb测年。锆石U—Pb同位素分析结果显示,锆石发育典型的岩浆震荡环带,高Th／U（0．51～1．57）,轻稀土元素亏损,重稀土元素富集,具有强烈的正Ce异常和强烈的负Eu异常等特征,表明锆石均属于岩浆成因。22个分析点获得的谐和年龄为（314±1）Ma（MSWD=0．88）,代表了大石寨组火山岩的形成时代。结合前人的资料,认为大石寨组火山岩为裂陷早期的产物,而晚古生代的沉积岩石组合为在这一基础上发展起来的具有裂陷盆地性质的沉积组合。 相似文献
8.
Petrochemical studies on acid plutonic (granite, microgranite) and volcanic (rhyolite, trachyte) rocks occurring in the Siner area of the Siwana Ring Complex, Malani Igneous Suite have been carried out. These rocks are characterized by high concentrations of SiO 2, Na 2O, K 2O, Zr, Nb, Y and REE (except Eu) but low in MgO, Fe 2O 3(t), CaO, Cr, Ni, Sr; indicating their A-type affinity. Field studies in conjunction with the geochemical characteristic indicate that the magmatism in the Siner area is generally represented by peralkaline suite of rocks which are formed due to rift tectonics. It is also suggested that these acidic rocks could have been derived by low degree partial melting of crustal material. Characteristics of certain pathfinder elements such as Rb, Ba, Sr, K, Zr, Nb, REE and the ratios of K/Rb, Zr/Rb, Ba/Rb along with the multi elemental primitive mantle normalized spidergrams suggest that the Siner peralkaline granites and microgranites have the potential for rare metal and rare earth mineralizations. 相似文献
9.
Rare earth elements (REE) were determined in 39 groundwater samples collected at 14 sites under low- and high-flow conditions. Water samples derived from aquifers hosted in crystalline, molasse, flysch, carbonate and evaporite rocks located in Western Switzerland. The concentration of REE in groundwater circulating in different rocks showed large variations: lowest concentrations (ΣREE≤10 ng/L) occurred in groundwater from evaporite aquifers; highest concentrations (ΣREE up to 516 ng/L) were observed in carbonate aquifers, although REE in these waters do vary under different hydrological conditions; groundwater from other aquifers had ΣREE from 10 to 100 ng/L. Distinct REE signatures were observed in waters draining specific rocks. The REE patterns in groundwater from crystalline, molasse and flysch aquifers showed heavy-REE enrichment at different degrees. Groundwaters circulating in crystalline rocks were distinguished by negative anomalies in Ce and Eu, whereas those from carbonate aquifers were nearly flat with ΣREE and the magnitude of negative anomaly in Ce is likely to be controlled by iron concentrations. The REE-Post-Archean Australian Shales (PAAS) normalized patterns appear useful to recognize the aquifer type and suggest the possibility to use the REE as geochemical tracers. 相似文献
10.
The Nd, O and Sr isotopic characteristics of Precambrian metasedimentary, metavolcanic and granitic rocks from the Black Hills of South Dakota are examined. Two late-Archean granites (2.5-2.6 Ga) have Tdm ages of 3.05 and 3.30 Ga, suggesting that at least one of the granites was derived through the melting of significantly older crust. Early-Proterozoic metasedimentary rocks have Tdm ages that range from 2.32 to 2.45 Ga. These model ages, in conjunction with probable stratigraphic ages ranging from 1.9 to 2.2 Ga, indicate that mantle-derived material was added to the continental crust of this region during the early-Proterozoic. Previous studies of the Harney Peak Granite complex have reported U-Pb and Rb-Sr ages of about 1.71 Ga and most granite samples examined in this study have Sr isotopic compositions consistent with that age. Two granite samples taken from the same sill, however, give two-point Rb-Sr and Sm-Nd ages of 2.08 ±0.08 and 2.20 ±0.20 Ga (∑ 2200Nd = −15.5), respectively. In addition, whole-rock and apatite samples of the spatially associated Tin Mountain pegmatite give a Sm-Nd isochron age of 2000 ±100 Ma (∑ 2200Nd = −5.8 ±1.8). The Sm-Nd, O and Rb-Sr isotopic systematics of these granitic rocks have been complicated to some degree by both crystallization and post-crystallization processes, and the age of the pegmatite and parts of the Harney Peak Granite complex remain uncertain. Processes that probably complicated the isotopic systematics of these rocks include derivation from heterogeneous source material, assimilation, mixing of REE between granite and country rock during crystallization via a fluid phase and post-crystallization mobility of Sr. The Nd isotopic compositions of the pegmatite and the Harney Peak Granite indicate that they were not derived primarily from the exposed metasedimentary rocks. 相似文献
11.
五台地区高凡群对于华北克拉通早前寒武纪变质地层层序建立具有重要意义。本文对高凡群磨河组开展了地球化学和锆石年代学研究。变质沉积岩稀土总量为(132.78~231.84)×10 -6(样品W1927的稀土总量为1016.55×10 -6),轻重稀土分离弱((La/Yb) N=4.5~12.5),具明显负铕异常( δEu=0.37~0.62),稀土模式与太古宙后泥砂质碎屑沉积岩十分类似。一个白云石英片岩样品(D004)的变质原岩中存在大量2.7 Ga、2.54~2.5 Ga、2.3 Ga和2.18 Ga碎屑锆石,最年轻锆石可能来自同时代火山岩。一个含黄铁矿白云片岩样品(W1927)的最年轻锆石年龄为2194 Ma,被认为代表了岩石形成时代。结合前人研究,可把高凡群形成时代限定在<2176 Ma和2350 Ma之间,碎屑物质主要来自恒山、五台、阜平、云中山、吕梁地区新太古代—古元古代变质基底或更远的地区。 相似文献
12.
报道了甘肃金川正长花岗岩体的岩石学、锆石U-Pb年代学和全岩地球化学资料,以确定岩体的形成时代、岩石成因及其构造属性。正长花岗岩样品中岩浆锆石SHRIMP U-Pb加权平均年龄为(425.7±2.5) Ma(MSWD=1.07),属晚志留世,与金川地区出露的辉绿岩脉年龄相近。正长花岗岩低硅(SiO 2 66.71%~70.05%),富碱(Na 2O+K 2O 10.00%~10.7%),K 2O/Na 2O比值为1.88~2.41,高全铁(FeO T 1.79%~2.62%),低钛(TiO 2 0.34%~0.52%),A/CNK=0.82~1.05。岩石学及化学成分显示其属于准铝质碱性系列A1型花岗岩,具有较高的锆石饱和温度( TZr=878~1 015 ℃);稀土元素含量高,ΣREE含量为374.4×10 -6~529.4×10 -6(平均428.7×10 -6),稀土元素配分曲线呈现轻稀土元素相对富集、重稀土相对亏损的右倾分布特征,(La/Yb) N=28.07~41.28,具Eu负异常( δEu=0.53~0.66)。原始地幔标准化微量元素蛛网图显示Nb、Ta、Ti和P的亏损。岩石具有较高的Rb/Sr值(介于0.81~1.27之间,平均值为1)和Rb/Nb值(介于4.72~9.75之间,平均值为7.15),显示壳源岩浆的成分特征。结合区域地质背景及构造判别认为,金川正长花岗岩形成于上地壳长英质物质在高温条件下的部分熔融,同时代出露的辉绿岩脉与其组成的双峰式侵入岩形成于伸展的板内裂谷环境,与约426 Ma阿拉善地块和祁连-柴达木地块导致的俯冲板片断裂、折返以及软流圈地幔的上涌有关,金川地区“I6隐伏矿体”形成以后所经历的构造活动及热液成矿作用的叠加可能与该双峰式岩浆活动有关。 相似文献
13.
南方不同红土的化学蚀变指数(CIA),硅铝系数 、铝铁系数 硅铁铝系数 反映红土的形成经历了脱钙、脱碱基和初级脱硅富铝富铁3个主要的 风化阶段;稀土在前两个阶段中主要发生淋失,而在后一阶段中富集,其配分曲线具Eu亏损的轻稀土显著富集型特征。红土中稀土元素的赋存状态以晶格相为主,主要与基岩密切有关,而其它赋存状态则与红土化过程紧密相连。红土中可溶态稀土含量的高低是风化作用强度的有效指标。 相似文献
14.
长江源区的新生代火山岩系包括高钾钙碱性系列和钾玄岩系列.高钾钙碱性火山岩形成于始新世, 钾玄岩系列火山岩形成于中、上新世.总体而言, 该区火山岩富碱高钾, 富集大离子亲石元素, 稀土元素含量高且轻稀土相对富集.相对而言, 高钾钙碱性火山岩富集SiO 2、Al 2O 3, 无负Eu异常, 属于壳源岩浆系列, 其原始岩浆由加厚陆壳的榴辉岩质下地壳经部分熔融产生.钾玄岩系列火山岩富集K 2 O、TiO 2、P 2 O 5、MgO、FeO, ∑REE、HFSE、I Sr值均较高, 弱负Eu异常, 属于幔源岩浆系列, 其原始岩浆由EMⅡ型富集地幔的部分熔融生成.2个系列的火山岩均是大陆碰撞造山后期岩浆作用的产物.始新世以来, 随着该区由碰撞、挤压作用发展到出现走滑, 应力环境由挤压转变为张性, 导致依次喷发高钾钙碱性火山岩和钾玄岩系列火山岩. 相似文献
15.
Tertiary basaltic magmatism in Serbia occurred through three episodes: (i) Paleocene/Eocene, when mostly east Serbian mafic alkaline rocks (ESPEMAR) formed, (ii) Oligocene/Miocene, dominated by high-K calc–alkaline basalts, shoshonites (HKCA–SHO) and ultrapotassic (UP) rocks, and (iii) Pliocene episode when rocks similar to (ii) originated. In this study, the geodynamics inferred from petrogenesis of the (i) and (ii) episodes are discussed. The ESPEMAR (62–39 Ma) occur mainly as mantle xenolith-bearing basanites. Their geochemical features, such as the REE patterns, elevated HFSE contents and depleted Sr–Nd isotope signatures, indicate a relatively small degree of melting of an isotopically depleted mantle source. Their mantle-normalized trace element patterns are flat to concave and “bell-shaped”, characteristic of an OIB source free of subduction component. 87Sr/86Sri and 143Nd/144Ndi isotope ratios (0.7030–0.7047 and 0.5127–0.5129, respectively) indicate a depleted source for the ESPEMAR similar to the European Asthenospheric Reservoir (EAR). The HKCA–SHO rocks (30–21 Ma) occur as basalts, basaltic andesites and trachyandesites. They show enrichment in LILE and depletion in HFSE with all the distinctive features of calc–alkaline arc-type magmatism. This is coupled with somewhat enriched Sr–Nd isotope signature (87Sr/86Sri=0.7047–0.7064, 143Nd/144Ndi=0.5124–0.5126). All these features are characteristic of subduction-related metasomatism and fluxing of the HKCA–SHO mantle source with fluids/melts released from subducted sedimentary material. UP rocks (35–21 Ma) appear as (i) Si-rich lamproites and related rocks and (ii) olivine leucitites and related rocks. UP rocks have high-LILE/HFSE ratios with enrichment for some LILE around 1000× primitive mantle, troughs at Nb and Ti, and peaks of Pb in their mantle-normalized patterns. They also show highly fractionated REE patterns (La/Yb up to 27, LaN up to 400). The isotopic ratios approach crustal values (87Sr/86Sri=0.7059–0.7115 and 143Nd/144Ndi=0.5122–0.5126), and that signature is typical for ultrapotassic rocks worldwide. The Paleocene/Eocene episode and formation of the ESPEMAR is referred to as asthenospheric-derived magmatism. This magmatism originated through passive riftlike structures related to possible short relaxational phases during predominantly collisional and compressional conditions. The Oligocene/Miocene episode and formation of HKCA–SHO and UP rocks were dominated by lithospheric-controlled magmatism. Its origin is connected with the activity of a wide dextral wrench corridor generated along the axis of the Dinaride orogen which collapsed in response to thickened crust caused by earlier compressional processes. To explain conditions of these two magmatic events, a three-stage geodynamic model has been proposed: (1) subduction–termination/collision stage (Paleocene/Eocene), (2) collision stage (Eocene) and (3) postcollision/collapse stage (Oligocene/early Miocene). 相似文献
16.
鸡街碱性超基性杂岩体产出于攀西古裂谷南段,地处云南省境内的罗茨地区,空间上与峨嵋山玄武岩紧密伴生。岩体的主体由霞霓钠辉岩、霓霞岩和磷霞岩组成,三类岩石具有相似的微量元素和稀土元素(REE)配分,富集大离子亲石元素K、Rb、Sr、Ba,过渡族元素Sc、Cr和Ni相对亏损,Nb/Ta、Zr/Hf比值在幔源岩的范围内,Sr-Nd同位素沿"幔源趋势"线分布。鸡街碱性超基性岩中不相容元素总体亏损,含量与EMORB相当,稀土总量ΣREE=32.86～70.07偏低,(La/Yb)N=3.03～4.47,HREE亏损,指示源区的适度亏损。微量元素和同位素信息共同指示鸡街碱性超基性岩为地幔岩高压条件下低程度部分熔融的产物(<10%),岩浆演化过程中经历了橄榄石、辉石和少量磁铁矿的结晶分异。霞霓钠辉岩、霓霞岩与磷霞岩来自同一地幔源区,岩浆源区的相对亏损,可能与中-晚二叠纪大量的玄武质岩浆从深部地幔抽取有关。攀西古裂谷的多期次活动为峨嵋地幔柱提供了岩浆通道,地幔柱活动的早期阶段或晚期阶段岩石圈地幔(或混合地幔)低程度部分熔融的碱性岩浆沿此构造薄弱带上侵,形成了攀西古裂谷内呈带状分布的各碱性杂岩体。 相似文献
17.
A series of soil and stream sediments developed during intense weathering on the metaluminous Danburg granite, northeastern Georgia, U.S.A., have been analyzed mineralogically and chemically. The concentrations of Ba, Na, Rb and Cs in the silt and coarser fractions are controlled mainly by feldspars and biotite. Hf is controlled by zircon, and the REE (rare-earth elements) and Th are largely controlled by sphene. Variations in feldspar, sphene and zircon may produce small variations in Eu/Sm and La/Lu ratios. Ferromagnesian minerals control Ta, Fe, Co, Sc and Cr concentrations. The mineralogical and chemical composition of the Danburg granite is more closely reflected in the silt than in the sand or gravel fractions of stream sediments. In the silt, the contents of Rb, REE, Th, Ta, Fe, Co and Sc and the ratios of La/Sc, Th/Sc, La/Co, Th/Co, Eu/Sm and La/Lu are similar to those in the unweathered granite. In contrast, these element contents or ratios in the sands and gravels are 0.05−3× the concentration in the unweathered granite. Ta and Ba contents are an exception to the above. The Ta and Ba contents of the sands and gravels are similar to those of the granite. In the kaolinite-halloysite clays, the content of Na is depleted relative to the source. Rb, Cs, Ba, Hf and Ta are depleted or enriched in the clays relative to the source, while the REE, Th, Fe, Co, Sc and Cr are enriched. The Eu/Sm (Eu anomaly size) and La/Lu ratios, and the REE patterns of the clays are similar to those of the source. Thus, the mineralogy and element contents of a siltstone developed from metaluminous, granitic sources during intense weathering would be expected to be more similar to the source rock than the sandstones and conglomerates. Claystones should contain similar REE patterns and Eu/Sm ratios as the source rock, but such fine-grained sediments might represent much larger areas of source rocks than the more locally derived sandstones or conglomerates. 相似文献
18.
A suite of early Proterozoic basic to granitic rocks exposed near St. Cloud, Minnesota are cut by northeast-trending basaltic dikes. Pb isotope data for all of these rocks overlap and plot about an 1800 Ma PbPb correlation line. The basic rocks, which are light REE enriched, have ϵNd values between +0.4 and −4.8. Petrogenetic considerations suggest that the basic rocks were derived from a light REE enriched source which had an Fe/Mg ratio greater than that for pyrolite. The enrichment in Fe/Mg is probably a result of the addition of basic melts to the source. The light REE enrichment may have a mantle origin by the addition of mantle-derived, light REE enriched basic melts or fluids; or a sedimentary origin by the addition of light REE enriched fluids or melts derived from subducted sediments with an early Proterozoic provenance. In either case, the Nd isotopes suggest that the light REE enriched component existed since c. 2300 Ma. The igneous complex may have formed at a convergent margin. An anorthositic gabbro near Mora, has an ϵ Nd of +5 indicating that it was derived from a mantle source with a history of light REE depletion. This gabbro may have been part of an early Proterozoic ocean crust. 相似文献
19.
Rare earth elements (REE) in the clay fraction (< 2μ) of the Quaternary deposits in the Numedal area, southern Norway, have been determined by a spark source mass spectrometric method. The REE content was studied in relation to weathering and sedimentological factors. The total REE content varies from 100 to 1300 ppm. An average of the similar fraction of 16 non-marine clays, mostly tillitic, gave 527 ppm REE. An average of 38 glacial and postglacial marine clays from the lower part of the Numedal valley gave 335 ppm REE (max. 781 ppm). After removal of adsorbed ions the average total REE content of morainian and marine clays decreased to 186 ppm. The content and distribution of the REE in the Numedal clays are strongly influenced by environmental factors. Under neutral and alkaline conditions the REE are accumulated by adsorption on clay minerals, and by increasing the hydrogen ion concentration the adsorbed ions are readily removed. 相似文献
20.
The Haldzan-Buregtey group of alkali granitoid massifs with an age of 391–395 Ma is located among the Early Caledonides of the Ozernaya zone of western Mongolia and consists of seven intrusive phases, including two rare-metal phases with Zr, Mn, Y, and REE mineralization. In order to identify the magma sources of the massifs, the abundances and canonical ratios of incompatible trace elements in the rocks of various intrusive phases are analyzed and compared with those in the volcanic rocks of Pantelleria island. The latter rocks were taken as the reference association of rocks linked through crystallization differentiation. The rocks of the Haldzan-Buregtey Complex were formed by mixing an OIB source (with participation of MORB) and host ophiolites, while alkali granitoids of phase 2 originated via mixting these sources with the host non-alkaline granitoids. Practically all rocks have mixed sources, with all transitional varieties from OIB, MORB to ophiolites. OIB was the main source for the rocks, while the host ophiolites could serve as sources for anatectic magmas or contaminants of the magmas of other considered rocks. The rare-metal granitoids were produced from the same sources as the barren magmatic rocks of the Haldzan-Buregtey Complex. The rocks of the Haldzan-Buregtey Complex show a bimodal distribution, with the practically complete absence of intermediate varieties between basite dikes and syenite-granite rocks. This seems to be related to the formation of the least differentiated sialic rocks (nordmarkites, pantellerites, some alkali granites) by anatexis of their own parental basite rocks (dolerites and basites), their cumulates, or ophiolites. Most of the phase-2 alkali granites likely resulted from the differentiation of the phase-1 nordmarkites coupled with assimilation of the host ophiolites. Ekerites are geochemically similar to the nordmarkites and can be interpreted as their residual in situ melts or their anatectic melts. 相似文献
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