共查询到20条相似文献，搜索用时 31 毫秒
1.
Systematic magnetic and crystallographic studies were made on 57 titanomaghemite samples produced from sintered titanomagnetites with x values of 0.0, 0.2, 0.4, 0.6, 0.8 and 1.0. Curie temperature and lattice parameter values are often significantly different from results of previous studies (Ozima and Sakamoto, 1971; Readman and O'Reilly, 1972; Nishitani, 1979), particularly for x values of 0.4 and 0.6. Other important results are: (1) Oxidation of titanomagnetite is mainly a function of temperature. Atmosphere and Ti content have little influence. (2) Progressive oxidation of homogeneous titanomaghemites can take place in the presence of a rhombohedral phase. The amount of rhombohedral phase produced during oxidation increases with increasing temperature and (less conclusively) with decreasing Ti content. (3) Saturation magnetization measurements at low temperatures show both P- and Q-type ferrimagnetic behavior in titanomaghemites, and also show the Verwey (?) transition in titanomaghemites with composition x=0.0. (4) The temperature of spinel inversion increases with degree of oxidation. Slightly oxidized samples invert near 300°C; for samples with z > 0.8 the inversion temperature is above 450°C. This last result, although neither expected nor understood, is supported by results of thermomagnetic studies on some oceanic basalts. 相似文献
2.
We studied the change of magnetic behaviour upon laboratory heating of altered mid-ocean ridge basalt (MORB) samples in the age range of 16-35 Ma to determine the influence of titanomaghemite inversion on the thermal demagnetisation of natural remanent magnetisation (NRM) of these basalts. MORB samples were heated to successively higher temperatures and at the same time the temperature dependence of either saturation magnetisation or NRM was monitored continuously. After each heating step, hysteresis loops and remanent magnetisation curves between 10 K and room temperature were measured. With this procedure, it is shown that the dominant magnetic remanence carrier in our MORB samples is cation deficient titanomaghemite. Moreover, it is demonstrated that the titanomaghemite is gradually changing to a Ti-poor titanomagnetite as the final inversion product. During inversion, both the Curie temperature as well as the maximum unblocking temperature of the NRM are gradually increasing. We show that the paradox of unblocking temperatures above the Curie temperatures often observed for altered MORBs is an artefact of this gradual, heating induced inversion process. 相似文献
3.
Bruce M. Moskowitz 《Earth and Planetary Science Letters》1981,53(1):84-88
Methods for determining the Curie temperature (Tc) of titanomaghemites from experimental saturation magnetization-temperature (Js-T) data are reviewed.Js-T curves for many submarine basalts and synthetic titanomaghemites are irreversible and determining Curie temperatures from these curves is not a straightforward procedure. Subsequently, differences of sometimes over 100°C in the values ofTc may result just from the method of calculation. Two methods for determiningTc will be discussed: (1) the graphical method, and (2) the extrapolation method. The graphical method is the most common method employed for determining Curie temperatures of submarine basalts and synthetic titanomaghemites. The extrapolation method based on the quantum mechanical and thermodynamic aspects of the temperature variation of saturation magnetization nearTc, although not new to solid state physics, has not been used for estimating Curie temperatures of submarine basalts. The extrapolation method is more objective than the graphical method and uses the actual magnetization data in estimatingTc. 相似文献
4.
利用一件采自河北汉诺坝周坝地区变泥质岩包体样品,结合系统的低温和高温磁性测量结果,探讨了应用热磁实验鉴别样品中所含原生磁性矿物的多解性问题. 结果表明, 饱和等温剩余磁化强度（SIRM）在室温～250℃以及280℃～380℃的降低分别由高钛钛磁铁矿的剩磁解阻过程（一种物理过程）以及由磁赤铁矿转换成赤铁矿（一种矿物相变）引起.样品在500℃以后磁化率的升高则是由磁铁矿从钛磁赤铁矿中出溶所致.因此,κ T（即磁化率随温度变化）曲线中呈现约580℃居里点是由加热过程中次生的磁铁矿引起,而并非代表原始（即加热前）样品中的磁铁矿成分. 相似文献
5.
Because of the difficulties of laboratory simulation of maghemitization, few studies have been carried out and the results of such studies are not in good agreement. Of particular interest is the evolution of the cation distribution with degree of non-stoichiometry. This indicates how the maghemitization process takes place at the atomic level. In the present study a suite of titanomagnetite specimens containing a range of concentration of Mg2+ ions were maghemitized and the possible cation distribution inferred from saturation magnetization measurements. Although a unique cation distribution cannot be obtained from such measurements, the observed data are consistent with the following model, except for high degrees of oxidation and high Mg concentration: (1) Ti4+ and vacancies in B sites only; (2) a random distribution of Mg2+ which remains frozen in during maghemitization; (3) availability for oxidation of tetrahedral site Fe2+ 20% of that of octahedral site Fe2+; and (4) deficient moment of the oxidized specimens due to small particle size. 相似文献
6.
7.
Peter J. Wasilewski 《Physics of the Earth and Planetary Interiors》1977,15(4):349-362
An iron ore which behaves as a permanent magnet is lodestone. The intrinsic magnetic properties and the microstructual characteristics which are responsible for the permanent-magnet properties of the lodestone have never been described or explained. Iron ores capable of being charged sufficiently strongly to behave as permanent magnets are defined here as proto-lodestones and fall into two categories — Class I which contains Fe as the only significant cation, and Class II which contains considerable Ti, Mg and Al as well. Proto-Lodestones are magnetically hardened by oxidation and precipitation processes which produce the microstructure responsible for the permanent-magnet properties. Lodestones are charged proto-lodestone iron ores. Lodestones have RH values (ratio of remanent coercive force, HR, to coercive force, HC) between 2.0 and 2.5; RI values (ratio of saturation remanence, ISR, to saturation magnetization, IS) >0.1–0.25 and the ratio of NRM/SIRM (natural remanence to saturation remanence) is 0.15–0.7. The intrinsic magnetic properties and microstructural characteristics of proto-lodestones and other iron ores are described and explained. The mechanism of charging the proto-lodestone appears to be either transient magnetic fields associated with lightning-discharge currents or presently obscure aspects of magnetization intensity enhancement associated with maghemitization of massive iron ores. 相似文献
8.
V. I. Belokon O. I. Dyachenko P. V. Kirichenko 《Izvestiya Physics of the Solid Earth》2018,54(1):121-127
In this paper, we analyze the self-reversal of magnetization in titanomagnetites as a function of the Ti content and the distribution of Fe3+ to Fe2+ ion transitions in sublattices (which is associated with the law of charge conservation). The dependence of the Curie point on the Ti concentration and the temperature dependence of the mean magnetic moment per iron atom at different Ti concentrations and different cation distributions in sublattices are calculated. 相似文献
9.
Iqbal Hasnain 《Pure and Applied Geophysics》1971,90(1):131-137
Summary The magnetic properties of some dykes from Mysore State, India, have been studied in detail. The rocks were found to have aQ
n
ratio varying from 1.5 to 11.6, a remanent coercive force varying from 100 to 250 Oersteds, Curie temperature varying from 250 to 480°C and were found to have lamellae of ilmenite oriented in (111) plane of magnetite. The stable natural remanent magnetization of the rock seems to be of TRM origin with titanomagnetite and low grade titanomaghemite being the main carrier of remanent magnetization.N.G.R.I. Contribution No. 70-215. 相似文献
10.
Bertha Aguilar Reyes Francisco Bautista Avto Goguitchaichvili Ofelia Morton 《Studia Geophysica et Geodaetica》2011,55(2):377-388
This paper focuses on the study of the correlation between magnetic parameters with the level of contamination by heavy metals
in urban soils. We report a magnetic investigation of urban soil samples from Merida, state of Yucatan, Southern Mexico. It
appears that most of our samples contain ferrimagnetic minerals as the magnetic carriers, probably coming from the titanomagnetites/titanomaghemites
series. This is inferred by the acquisition of isothermal remanent magnetization, which shows that most of samples are almost
completely saturated at about 200 mT. The S−200 value (factor characterizing stability of remanent magnetization) is between 0.8 and 1.0, characteristic of ferrimagnetic
minerals. The susceptibility vs. temperature measurements also point to some titanomaghemites and titanomagnetites as probable
responsible for magnetization. On the other hand, measurements of magnetic susceptibility at high and low frequencies helped
us to determine the high content of superparamagnetic grains in the majority of the samples, although not all of these showed
high values of magnetic susceptibility. We found that the most contaminated samples by Pb and Zn showed the higher saturation
isothermal remanent magnetization values, whereas the higher values in magnetic susceptibility correspond to samples contaminated
by Cr. Finally, we noted that a high level in Sr decreases the magnetic susceptibility. 相似文献
11.
Ulrich Bleil 《Pure and Applied Geophysics》1976,114(2):165-175
Summary Analysis of saturation magnetization measurements and data from the literature indicate that the cation distribution in the titanomagnetite solid solution series is temperature dependent. The ionic configuration of ferric and ferrous ions on both lattice sites of their spinel structure can be described by a modified Boltzmann relation in agreement with theoretical consideratios. Thermodynamic equilibrium isotherms for the cation distribution and the resulting variation of saturation magnetization are calculated on the basis of the experimental values. These results should be especially valuable for the interpretation of magnetic properties of rapidly cooled igneous rock units where a respective high-temperature metastable state may exist in the magnetic ore component.Further measurements of the Curie temperature and lattice constant did not confirm a similar effect. Both these parameters should therefore be qualified for the identification of naturally occurring titanomagnetites. 相似文献
12.
Single crystals of approximate composition Fe2.4Ti0.6O4 were prepared from which spherical samples of diameters 1–2 mm were obtained. The measured values of the Königsberger ratio, the ratio of saturation remanence to saturation magnetization and a Lowrie-Fuller test showed that they were multidomain in character. The temperature variation of the coercive force and saturation magnetization was measured between room temperature and the Curie point. The field dependence of intensity of acquired thermoremanent magnetization (TRM) was determined. The predictions of some of the theoretical models for multidomain TRM, which, of necessity, apply to simplifications of real materials (either natural or synthetic), compare favourably with the results of the present study. The validity of the assumptions made in this comparison is discussed. 相似文献
13.
热磁测量,包括高温磁化率和高温磁化强度测量,是根据热磁曲线转折点的温度(居里点、尼尔点或相变点)鉴定样品中磁性矿物种类的有效方法.本文选取两个人工合成磁赤铁矿样品,利用四种热磁测量仪器分析不同的条件下测得的热磁曲线.依据样品与空气接触程度,将测量环境设为开放、封闭、封闭(通入氩气或氮气)三类.结果表明:热磁测量环境的开放程度对居里点和曲线可逆程度产生极大的影响.封闭环境下测得的居里点较开放环境下的低,分别对应磁铁矿和磁赤铁矿;开放系统的热磁曲线不可逆程度高于封闭系统.造成这些差异的原因是氧化还原条件的不同.本文的磁赤铁矿样品在封闭的条件下,加热至250 ℃左右开始转化为磁铁矿,因此无法通过居里点被正确识别;在开放的氧化环境下,加热的最终产物为赤铁矿,能够测得正确的居里点.本实验结果启发人们:在不同的加热环境下,磁性矿物可能表现出不同的热磁行为,根据单一的热磁曲线,很容易对样品中磁性矿物的种类造成误判.全面对比不同条件下的测量结果,才能够得出更为准确的结果. 相似文献
14.
Azimuthally averaged power spectra are widely used in the Curie point depth (CPD) estimation with the implicit assumption that the magnetization distribution is random and uncorrelated. However, the marine magnetic anomalies are caused by bands of normal and reverse magnetization and show obvious trends. To investigate the effects of the anisotropy of marine magnetic anomalies on the CPD estimates, we develop 3D fractal striped magnetization models to produce lineated marine magnetic anomalies for the first time. We analyze the spectra anisotropy of the lineated magnetic anomalies of the synthetic fractal striped magnetization models and investigate its effects on the CPD estimates. The synthetic models and actual data show that the spectra of the lineated marine magnetic anomalies are directionally anisotropic. The amplitude response is strong and the slope of the logarithmic spectrum is large in a direction perpendicular to the stripes of magnetic anomalies, whereas the amplitude response is weak and the slope of the logarithmic spectrum is small in a direction parallel to the stripes of magnetic anomalies. The depth estimates in the perpendicular direction are close to the actual values, whereas the depths estimates in the parallel direction are significantly lower than the actual values. The actual marine magnetic anomalies of the South China Sea exhibit an anisotropic power spectrum that is consistent with the spectral anisotropy of magnetic anomalies of the synthetic fractal striped magnetization models. 相似文献
15.
New paleomagnetic result from the Ethiopian flood basalts in the Abbay (Blue Nile) and Kessem gorges
Tesfaye Kidane Bekele AbebeVincent Courtillot Emilio Herrero 《Earth and Planetary Science Letters》2002,203(1):353-367
New paleomagnetic investigations on the Ethiopian trap series have been undertaken at the Abbay and Kessem gorges in an attempt to better constrain the 30 Ma paleomagnetic pole of Africa. We sampled six thick massive basaltic lava flows, totaling 230 m, from Abbay Gorge and 10 lava flows, 180 m in thickness, from Kessem Gorge. Detailed paleomagnetic analyses disclosed that the carriers of the characteristic remanent magnetization (ChRM) are different in different lava flows. These are mostly titanomagnetites, titanomaghemites, and magnetite minerals with a broad range of coercive force and blocking temperatures. The heating and cooling susceptibility vs. temperature curves, many of which are irreversible, may indicate chemical remagnetization, notably low temperature maghemitization. Only one flow (KS04) with a clear 580°C Curie temperature was apparently unaffected by chemical remagnetization. The ChRM direction of this flow is identical to that in other flows, which suggests that if and when remagnetization occurred, this was shortly after emplacement of the lava flows. All of the flows sampled have normal polarity. However, a reversed component of low to medium coercive force and low to medium unblocking temperature occurs in flow KS01 at Kessem Gorge. The ChRM directions for the 16 sites are D=3.1°, I=5.8° (α95=12.7°). The paleomagnetic pole obtained from these is at λ=83.0°N, φ=193.3°E (A95=9.0°). Comparison with three previous studies of the traps shows remarkable consistency and a number of means are derived and discussed. Two final preferred poles for the traps are at λ=79.0°N, φ=196.9°E (A95=2.8°) when all 112 published flows are used, and λ=78.7°N, φ=209.4°E (A95=3.4°) when only the 76 flows from the four more recently analyzed sections are included. Both are compatible with the recent reference synthetic pole for Africa of Courtillot and Besse [J. Geophys. Res. (2002) in press]. In that sense, the Ethiopian trap pole is not anomalous and does not require more of a non-dipolar contribution than indicated by analyses of the global paleomagnetic data base covering the last few million years. 相似文献
16.
强剩磁的存在通常导致了总磁化强度方向未知,进而影响了磁异常的反演和解释.磁异常模量是一种受磁化方向影响小的转换量,可以在强剩磁条件下通过反演三维磁化强度大小分布来推测场源分布状态.我们提出了一种数据空间磁异常模量反演算法来减少剩磁的影响.与标准的模型空间L2范数正则化反演方法相比,我们的方法有两个优点:一是无需搜索正则化参数(需要反复求解非线性反演问题),因而可以减少计算时间;二是反演结果更加聚焦,深度分辨率更高,我们对此进行了原因分析.通过模型和实测数据测试证明了该算法的有效性和更好的反演效果. 相似文献
17.
An equivalent layer magnetization model for Australia and adjacent oceanic areas is presented. The model is obtained by linear inversion of Magsat anomaly data measured in the altitude range 325–550 km. The anomaly data set has been isolated from the raw data set by use of models of the core field and very long wavelength external fields, and is internally consistent. Certain major structural features of the Australian continent are geographically associated with magnetization anomalies. A first-order difference is seen between the Tasman Zone and the Precambrian cratonic areas: magnetization anomalies are much more subdued in the former, possibly reflecting a shallowing of the Curie isotherm within the crust. A profile of the vertical integral of magnetization is presented for a crustal section extending from the Gawler Block to the southeast coast. It is shown that the magnetization variations are probably due partly, but not wholly, to depth to Curie isotherm variations; gross magnetization variations among at least three distinct crustal units must be involved. 相似文献
18.
The oxide mineralogy and magnetic properties were examined in a suite of fifteen olivine-normative diabase dike samples from western South Carolina in an attempt to elucidate their magnetic petrology. Titanomagnetite (1–2 vol.%) is the dominant Fe-Ti oxide mineral. Ilmenite and secondary magnetite are generally present in very minor amounts. Chromite constitutes up to 0.5 vol.%; its abundance and composition correlate with bulk rock Cr. Various types of fine-scale microstructure are evident in titanomagnetite crystals. The most important are patterned anisotropism and the development of trellis-type ilmenite lamellae. Microprobe analyses indicate: (1) titanomagnetite compositions, x, are mostly between 0.4 and 0.55, and (2) low analytical totals are characteristic of most titanomagnetites. Curie temperatures of the diabases are 500–540°C, which are several hundred degrees higher than predicted from the observed titanomagnetite x's (150–300°C). We attribute these higher Curie temperatures to oxidation of the titanomagnetites, which has produced “titanomaghemites” having visible microstructure and yielding low analyses (because they are cation deficient). Natural remanence magnetization and REM (ratio of natural remanence to saturation remanence) vary between 4 and 100 × 10−4 A m2 kg−1 and 0.0019 and 0.032, respectively. These properties inversely correlate with Cr content and demonstrably contrast Cr-rich and Cr-poor samples. Initial susceptibility, saturation magnetization and coercivity values show a two- to three-fold range. Variations in initial susceptibility and coercivities appear to be largely related to the type and extent of oxidation-induced microstructure in the titanomagnetites. 相似文献
19.
We investigated the natural remanent magnetization (Jr) of hydrothermally altered basalts from two drill cores KH1 (200 m) and KH3 (400 m) situated at the rim of the Krafla caldera in NE Iceland, where a geothermal field (>150°C) is still active. Low temperature oxidation along with mineral reactions in the chlorite zone (<350°C) is the prevailing cause for the maghemitization and a strong decrease of Jr to occur in our study. Despite a significant decrease of Jr with respect to fresh basalts in surface outcrops of the same area, the stepwise demagnetization analyses of Jr show the presence of a stable magnetic component with the expected inclination of 77° in Iceland. Because the alteration temperature (<350°C) is above the Curie temperatures of most of the original titanomagnetite (40°?C350°C), we suggest that a normal direction of remanence is chemically acquired during the low temperature alteration. We observed only one reliable negative inclination at 293.2 m in the KH3 core, which we rather interpret to be acquired during a geomagnetic excursion with reverse polarity than caused by a self-reversal mechanism. 相似文献