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1.
亚甲基蓝在水体系中的光化学降解研究 总被引：1，自引：0，他引：1
研究水体系中亚甲基蓝的光化学降解.结果表明,在高压汞灯照射下,亚甲基蓝在人工海水中降解得最快,蒸馏水次之,而在天然海水中降解得最慢.通过对比研究发现.重金属离子(Cu2+,Zn2+,Cd2+,Hg2+)和腐殖酸能够在一定程度上抑制亚甲基蓝的光降解;而丙酮能促进亚甲基蓝的光降解.由此可见,重金属离子和腐殖酸可能是造成亚甲基蓝在天然海水中降解缓慢的主要因素之一. 相似文献
2.
Joan D. Willey 《Marine Chemistry》1975,3(3):241-251
Amorphous silica can polymerize in distilled water, in 0.6 N NaCl solution and in seawater to form a colloidal suspension that contains approximately 200 ppm Si. Solid amorphous alumina can prevent this polymerization in seawater and in 0.6 N NaCl, and can inhibit but not prevent it in distilled water. This prevention of polymerization may be an important factor in authigenic mineral formation.The presence of solid amorphous alumina with solid silica in the same solutions causes the final concentrations of dissolved silica to be lower than those attained by solid silica in the absence of solid alumina. The effects are similar whether the final levels are approached from above or below the saturation concentration for amorphous silica. This indicates that the observed concentration of dissolved silica will be a function of available alumina as well as of the silica solubility.The presence of solid amorphous alumina with quartz in seawater, 0.6 N NaCl solution and distilled water causes dissolved silica levels to remain below 0.7 ppm Si for at least 38 days. The same systems in the absence of alumina approach the solubility levels of quartz within that time period. 相似文献
3.
A. V. Dubinin T. P. Demidova V. V. Kremenetskii N. M. Kokryatskaya M. N. Rimskaya-Korsakova E. V. Yakushev 《Oceanology》2012,52(2):181-190
The report presents the results of the studies of the reduced sulfur species in the water of the anoxic zone of the Black
Sea. The content of hydrogen sulfide was determined by means of spectrophotometry using dilution with oxygen-free distilled
water. The detection limit of the H2S amounted to 0.3 μM with the method’s precision below 3%. The accuracy of the spectrophotometric determination was verified
by iodometry after the fixation of the hydrogen sulfide in zinc acetate under the distillation with argon from the acidified
seawater sample. 相似文献
4.
Constant M.G. Van den Berg 《Marine Chemistry》1985,16(2):121-130
A novel technique to determine complexing capacities for zinc is presented. The free zinc concentration is determined by cathodic stripping voltammetry preceded by adsorptive collection of complexes of zinc with ammonium pyrrolidine dithiocarbamate (APDC). The reduction peak of zinc is depressed as a result of ligand competition by natural organic material in the sample. Sufficient time is allowed to reach equilibrium between this material and added APDC, and equilibrium is maintained during the measurement. Both electrochemically reversible and irreversible complexes can therefore be investigated. Values for KZnAPDC′ are calibrated against NTA and EDTA in seawater of several salinities; log KZnAPDC′ was found to be 4.40 at 36‰, 4.36 at 24‰, 4.43 at 12‰, and 4.87 at 2.3‰. The ligand concentration and conditional stability constant, KZnL′, for complexing ligands in a sample from the Irish Sea were determined in the presence of 4 × 10?5 M APDC and with added zinc concentrations between 5 × 10?9 and 3 × 10?7 M. The data best fitted a complexation model containing two ligands with concentrations of 2.6 and 6.2 and 10?8 M, and with values for log KZnL′ of 8.4 and 7.5, respectively. These results are comparable to those obtained with other equilibrium techniques, but the values of the constants are greater than those from ASV measurements. 相似文献
5.
C.M.G Van Den Berg 《Marine Chemistry》1982,11(4):323-342
The MnO2 adsorption method combined with voltammetry is proposed for the direct determination of metal complexation in seawater of various salinities as a more satisfactory alternative to direct voltammetric measurements and bioassay methods. A small quantity of MnO2 is equilibrated with copper ions in filtered seawater. Natural organic ligands in the seawater compete for copper with the MnO2. Total dissolved copper is measured by differential pulse anodic stripping voltammetry after filtration and acidification of the sample. Preconcentration of natural water samples is unnecessary and measurement is performed at the natural equilibrium pH of the aerated sample. The analytical limit of detection of the method depends on contamination from the filtration step, and for copper complexation a ligand concentration of 5 × 10?8 M was obtained. The sensitivity can be increased by use of radioisotopes as tracers. The method is very versatile in that complexation of various metals may be determined by any analytical method that measures total dissolved metal concentrations. Neither organic ligands nor their complexes with copper adsorb on the MnO2 at pH8, but at pH 1.8 MnO2 is an efficient scavenger for electroactive organic material.Samples of surface water from the Irish Sea and the Atlantic Ocean were found to contain ligand concentrations of 1.7 × 10?7 and 1.1 × 10?7 M, with conditional stability constants (log values) of 9.84 ± 0.13 and 9.86 ± 0.23, respectively, at pH 8.0. 相似文献
6.
Joan D. Willey 《Marine Chemistry》1975,3(3):227-240
Dissolved alumina can coprecipitate with dissolved silica from seawater enriched with both compounds. This coprecipitation is almost complete within 1h and maintains the concentration of dissolved alumina near naturally occurring oceanic concentrations, well below the alumina concentration of 0.50 ppm A1 found to be stable in filtered Sargasso seawater at 2°C. Only 0.5 ppm Si is necessary to initiate this coprecipitation, which indicates that the concentrations of dissolved alumina that occur in seawater and in interstitial water are a function of the concentration of dissolved silica as well as of the alumina solubility.Dissolved alumina is also quickly removed by solid amorphous silica from solutions of seawater enriched in dissolved alumina and also by several marine sediments in contact with the solution. This process may be an important factor in authigenic mineral formation in marine sediments. 相似文献
7.
1. The adsorption action of basic zinc carbonate adsorbent on uranium in natural seawater can be expressed with the following formula of adsorption isotherm:C=k(U*)n = 8.51× 10-1(U*)0.49,where C is the concentration of uranium on adsorbent; U* is content of uranium in natural seawater employed.2. when the quantity of basic zinc carbonate adsorbent (T) is constant, with the increase of natural seawater quantity through the adsorption column (G), also increased are the adsorption content of uranium of the adsorbent (U), the concentration of uranium on the adsorbent (C) and the concentration of residual uranium (C0*) in natural seawater after adsorbing uranium, while the rate of recovery of uranium (R) is decreased. With the increase of (G) the coefficient of distribution (Kd) decreases to a certain value and then a little rises again. 相似文献
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9.
稀土元素已越来越多地应用于示踪各类地球化学体系的物质来源与岩石矿物形成等演化过程。但在进行海水样品的稀土元素检测时，由于样品的高盐特征和稀土元素的痕量特征又使得分析具有相当的挑战性。本研究旨在从高盐的海水基质中有效分离并富集痕量的稀土元素，同时结合电感耦合等离子体质谱（Inductively Coupled Plasma Mass Spectrometry, ICP-MS）技术对海水中的稀土进行定量分析。通过对海水样品稀土元素的定量限分析、加标回收实验和梯度加标回收实验，验证了方法的准确性，评估方法的分离富集效率。通过共沉淀过程中的pH比较、氢氧化钠与氨水作为共沉淀剂的比较，确定了富集过程中共沉淀剂用量、种类等影响因素。通过稀土元素配分曲线的绘制与类似样品结果进行比对，以及标准海水的检测结果，验证了方法在实际样品中的可行性。本研究探索了共沉淀富集法在分离富集海水中稀土元素的实验条件，实现高盐背景下痕量稀土的准确定量，并将其用于近岸海水与孔隙水的实际检测。 相似文献
10.
Pentachlorophenol (PCP) and 3,4-dichloroaniline (DCA) were used as models to examine photochemical reactions in seawater.The photolysis of PCP in seawater differed in both rate and product distribution from that in distilled water; rates were slower in seawater due to the photonucleophilic interaction of PCP with chloride ions, demonstrated by the formation of 36Cl-labeled PCP in irradiated PCP solutions containing Na36Cl. DCA showed no rate change and gave identical products in both systems. Both PCP and DCA yielded greater amounts of photoreduction products in seawater than in distilled water, and tetrachloromuconic acid was isolated and identified as a new and unstable PCP photoproduct resulting from ringfission. This study demonstrates the operation of photooxidation, photonucleophilic substitution, and photoreduction reactions which differ in detail between seawater and distilled water and suggests that photochemical reactions can be a major factor in the breakdown of organic pollutants and other chemicals in the marine environment. 相似文献
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12.
C.M.G. Van Den Berg 《Marine Chemistry》1982,11(4):307-322
The theory is discussed which describes the distribution of copper ions between a weak ion exchanger, as exemplified by MnO2, and natural organic complexing material in seawater. Application of this theory and experimental procedures are outlined in part II of this series. It is apparent from the theory that titration with Cu2+ of one or more organic complexing ligands can be graphically represented by straight lines; slope and y-axis intercept provide information on the conditional stability constants and the ligand concentrations. Model calculations show that measurement of metal complexation at ligand concentrations higher than normally present in seawater may produce erroneous results because of possible changes in the metal to ligand ratio in the complexes. It is therefore advisable to measure metal complexation in the original, unaltered, water sample. 相似文献
13.
Iver W. Duedall 《Progress in Oceanography》1977,7(3):91-133
Hydration, ion-water interactions, and water structure effects in seawater were studied by determining differences (Δβ) between the compressibilities of test salt solutions and the compressibilities of reference solutions. The reference solutions were distilled water and seawater (35%0), and the test salt solutions were either 0.13 m or 0.26m with respect to one of the following test salts: LiCl, NaCl, KCl, CsCl, NaF, NaI, MgCl2, CaCl2, BaCl2, Na2SO4, K2SO4, and MgSO4. The compressibility measurements (to 900 bars) were carried out at 2°C and also at 15°C using a differential method in which a pressure increase or a temperature increase causes Δβ to become less negative. At 1 bar and 15°C, the Δβ (0.26 m, distilled water reference) values ranged from ?1.14 × 10?6 bar? for NaI to ?3.84 × 10?6 bar?1 for Na2SO4, and the Δβ (0.26 m, seawater reference) values ranged from ?1.30 × 10?6 bar?1 for NaCl to ?3.04 × 10?6 bar?1 for Na2SO4. The Δβ values were used to calculate hydration numbers. Entropy of transfer, excess hydrogen bond breaking (determined by NMR), and effective radii of ions are properties which can be used to describe the influence of ions on water structure. The extent to which these properties correlate with Δβ values depends upon whether the ion is an anion or a cation, and this correlation forms the thesis that anions alter water structure in a different way than do cations. 相似文献
14.
Vertical and seasonal characteristics of biogenic silica (BSi) dissolution in seawater were investigated by multiple dissolution experiments using seawater collected from surface and mesopelagic layers in Suruga Bay during the period 2002–2004. The dissolution rate coefficients calculated based on temporal changes of BSi concentration varied with the season of sample collection. They ranged from 0.023–0.057 day− 1 for surface samples and 0.0018–0.0025 day− 1 for mesopelagic samples for temperatures approaching in situ conditions. Experiments at various temperatures confirmed that BSi dissolution depends on temperature in natural seawater. Dissolution rate coefficient (day− 1) of BSi correlated significantly with temperature (°C), and Q10 was 2.6. Addition of bioavailable organic matter to low-bioactivity seawater enhanced the protease activity and abundance of bacteria, and increased BSi dissolution rate by a factor of 1.4–2.0. There is clear evidence that BSi dissolution is accelerated by bacterial activity and potentially limited by bioavailable organic matter in natural seawater. Dissolution rates and total decreases of BSi concentration were lower during experiments using mesopelagic samples than in those using surface samples. This suggests that dissolution of BSi varies with depth and that BSi in the mesopelagic water is more resistant to the dissolution than that in the surface water. This lower dissolution rate was caused by lower temperature and lower bacterial activity due to less bioavailable organic matter in mesopelagic water. Our results provide a mechanistic understanding of variations in silica cycling within the seasonally and vertically differing marine environment. 相似文献
15.
Hasan Firat Pulat 《Marine Georesources & Geotechnology》2013,31(5):466-472
The present study examines the suction characteristics and swelling behavior of clayey soils when exposed to natural seawater with respect to distilled water. The effects of saline waters on the engineering behavior of soils need to be determined since the salinity of the pore fluid of soils near coastal areas increases continuously. Six clayey soil samples with different mineralogy and characteristics were gathered and tested to determine the suction and swelling characteristics in the presence of natural seawater and distilled water. The results show that the total suction values of the samples are higher in the presence of seawater than in distilled water. The samples with high swelling potential have lower matric suction values than nonswelling soils. Moreover, in contrast to swelling-type soils, the matric suction values of the nonswelling soils remain similar in the presence both distilled water and seawater. The modified free swell index (MFSI) of the samples is well correlated with the liquid limit (LL), plasticity index (PI), and cation exchange capacity (CEC) in distilled water. However, coefficients of determination decreased in the presence of seawater. Also, there is no significant correlation existing between total and matric suction values and the MFSI values of the samples. 相似文献
16.
To clarify the nature of organic metal complexes dissolved in seawater, a ligand exchange reaction between ligands of natural origin and an aminopolycarboxylic acid (EDTA) was used to determine the conditional stability constants of organic metal complexes. The results indicate that more than two organic molecules complexed with copper and zinc exist in surface seawater. It is found that the conditional stability constants of these naturally-occurring organic metal complexes are 1–3 orders of magnitude higher than those of EDTA-Cu and EDTA-Zn complexes. These estimates of the conditional stability constants for the dominant species of organic copper and zinc complexes are 1011.8 and 109.3, respectively, at pH 8.1. The results indicate that these naturally-occurring organic metal complexes are stable species and not easily dissociated or displaced with others in the marine environment. 相似文献
17.
A method is described for the determination of Th isotopes (232Th,230Th,228Th and227Th) in seawater through analysis of Th adsorbed on MnO2-impregnated fiber that has been moored in the deep sea for up to 10 months. Since the MnO2-fiber adsorbs Th from seawater at a constant rate, natural234Th can be used as a yield monitor by making a correction for its decay during the period of deployment. The results obtained by the method showed good reproducibility and accuracy. The method has the advantage over the chemical coprecipitation method that the time and labor for sampling and processing a large-volume of seawater is reduced. 相似文献
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19.
本研究提出了一种用于检测海水中锌离子(Zn2+)含量的电化学检测方法。该方法首先应用水热法合成SiO2@PDA-Sb复合材料,然后将该复合材料修饰到玻碳电极上制备SiO2@PDA-Sb-Nafion/GCE,利用差分脉冲阳极溶出伏安法(DPASV)对珠江口海水水样中Zn2+进行测定。研究结果表明,Zn2+在SiO2@PDA-Sb-Nafion/GCE上具有较强的溶出峰。在最优条件下,SiO2@PDA-Sb-Nafion/GCE对Zn2+浓度在1～1 000 nmol/L范围内可实现灵敏、准确的检测,Zn2+的检测出限为0.71 nmol/L。加标回收率实验显示Zn2+加标回收率为93.19%～100.12%,表明该方法可应用于现场海水样品Zn2+测定。本方法具有电极制作简单、稳定性和抗干扰性良好,能够提高现有测定方法的检测限和精确度,在现场海水检测... 相似文献
20.
The aqueous photochemical transformation of acrylic acid 总被引：3，自引：0，他引：3
Acrylic acid in sea water is thought to occur mostly as the product of microbial cleavage of dimethylsulphoniopropionate (DMSP), but could also be a pollutant introduced by waste waters of the organic chemical industry. Solutions of acrylic acid in natural and artificial sea water, and distilled and riverine water were photolyzed using a photochemical reactor and exposure to sunlight. The transformation of acrylic acid comprises the decarboxylation of the carboxylic group and subsequent polymerization to a polyethylene type molecule. Kinetic studies showed the lowest reaction rate in distilled water and somewhat higher and very similar rates in other aqueous media. The approximately similar reaction rates in all natural waters studied suggest that inorganic ions, especially Na+, Mg2+ and halides, and dissolved organic matter (probably humics) enhance the reaction rates. On studying the influence of different concentration ranges on the reaction kinetics, an exponential increase of rates with decreasing concentration was found. The reaction rate in the sea water solution in field conditions is rather slow. In thirty days exposure about 15% of the reactant was transformed. This reaction seems to be important in the marine environment in specific conditions, especially in phycospheres and macroaggregates where higher concentrations of acrylic acid inhibit the bacterial metabolism. 相似文献