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1.
The present work investigated the biosorption of nickel from synthetic and electroplating industrial effluents using a green marine algae Ulva reticulata. Preliminary batch results imply that pH 4.5 was optimum for nickel uptake and the isotherm experiments conducted at this pH condition indicated that U. reticulata can biosorb 62.3 mg g–1 nickel ions from synthetic solutions, according to the Langmuir model. Desorption was effective and practical using 0.1 M CaCl2 (pH 2.5, HCl) and the biomass was regenerated and reused for three cycles. Continuous biosorption experiments were performed in an upflow packed column (2 cm I.D and 35 cm height). Among the two electroplating effluents used, effluent‐1 is characterized by excess co‐ions and high nickel ion content. This influenced the column nickel uptake with U. reticulata exhibiting 52.1 mg g–1 in the case of effluent‐1 compared to 56.5 mg g–1 in the case of synthetic solution. On the other hand U. reticulata performed well in effluent‐2 with uptakes of 53.3 and 54.3 mg g–1 for effluent‐2 and synthetic solution, respectively. Mathematical modeling of column experimental data was performed using nonlinear forms of the Thomas‐ and modified dose‐response models, with the latter able to simulate breakthrough curves with high correlation coefficients.  相似文献   

2.
We present a comparative study of soil CO2 flux () measured by five groups (Groups 1–5) at the IAVCEI-CCVG Eighth Workshop on Volcanic Gases on Masaya volcano, Nicaragua. Groups 1–5 measured using the accumulation chamber method at 5-m spacing within a 900 m2 grid during a morning (AM) period. These measurements were repeated by Groups 1–3 during an afternoon (PM) period. Measured ranged from 218 to 14,719 g m−2 day−1. The variability of the five measurements made at each grid point ranged from ±5 to 167%. However, the arithmetic means of fluxes measured over the entire grid and associated total CO2 emission rate estimates varied between groups by only ±22%. All three groups that made PM measurements reported an 8–19% increase in total emissions over the AM results. Based on a comparison of measurements made during AM and PM times, we argue that this change is due in large part to natural temporal variability of gas flow, rather than to measurement error. In order to estimate the mean and associated CO2 emission rate of one data set and to map the spatial distribution, we compared six geostatistical methods: arithmetic and minimum variance unbiased estimator means of uninterpolated data, and arithmetic means of data interpolated by the multiquadric radial basis function, ordinary kriging, multi-Gaussian kriging, and sequential Gaussian simulation methods. While the total CO2 emission rates estimated using the different techniques only varied by ±4.4%, the maps showed important differences. We suggest that the sequential Gaussian simulation method yields the most realistic representation of the spatial distribution of , but a variety of geostatistical methods are appropriate to estimate the total CO2 emission rate from a study area, which is a primary goal in volcano monitoring research.Editorial responsibility: H Shinohara  相似文献   

3.
This study examined ${\rm NH}_{{\rm 4}}^{{\rm + }} $ , ${\rm PO}_{{\rm 4}}^{{\rm 3}- } $ recovery and the concentration of residual ions from anaerobic effluent of the potato processing industry through magnesium ammonium phosphate (MAP) precipitation using a Box–Behnken design. The regression model was statistically significant in terms of ${\rm NH}_{{\rm 4}}^{{\rm + }} $ and ${\rm PO}_{{\rm 4}}^{{\rm 3}- } $ removal efficiency and residual ion concentrations. Optimum ${\rm NH}_{{\rm 4}}^{{\rm + }} $ and ${\rm PO}_{{\rm 4}}^{{\rm 3}- } $ removal was obtained at pH 9.50 and at Mg2+/${\rm NH}_{{\rm 4}}^{{\rm + }} $ /${\rm PO}_{{\rm 4}}^{{\rm 3}- } $ molar ratio of 1.8:1:1.8. Under these conditions, Mg, Ca, K, Fe, and Cl concentrations required for plant growth significantly decreased with MAP precipitation, which was supported by EDX analysis of dry MAP precipitate. The fertilizer effect of MAP on the growth of corn and tomato plants was compared with chemical fertilizers through pot trials. Nutrient element uptake levels of plants were examined in different fertilizer sources. While Mg, Fe, Cu, Mn, and Zn nutrient element uptake levels were sufficient in MAP pots, Ca uptake exceeded sufficient level. Average levels of N, P, K, Mg, Cu, and Mn of corn plant were higher in MAP than other pots. The average N, P, and Mg levels of tomato plant in MAP pots were higher than other pots. N/K ratio, which is important in tomato plants, was better optimized in MAP pots. Only Ni, Cr, and Pb heavy metals were found in plants.  相似文献   

4.
Artificial recharge is a practical tool available for increasing the groundwater storage capacity. The efficiency of artificial recharge is related to various hydrogeological factors of the target area. In this study, a variable saturated groundwater flow model, FEMWATER, was used to evaluate the arrival times of recharged water that infiltrates from an artificial recharge pond to the groundwater table under various hydrogeological conditions. Forty-five arrival times were generated by FEMWATER. The relationships between the arrival times and hydrogeological factors used in the simulation of FEMWATER were analyzed by the grey correlation method. The results show the order of importance of the factors as they influence the arrival time. In order from high to low importance, they are α, D g, θ e, D p, K S and β. D g and D p are interpreted as the potential for movement of the recharge water; θe is the water storage capacity of soil, and K S represents the ability of soil to transport water. α and β describe the characteristic curve of the unsaturated soil. The method was applied to evaluate a suitable site for artificial recharge in the Yun-Lin area. Grey correlation analysis was performed to obtain the grey correlation grade using the minimum arrival time as a reference sequence. An index is proposed herein to determine the recharge efficiency of 20 sampling sites. A contour mapping of index values at the 20 sampling sites identified three areas for artificial aquifer recharge in Yun-Lin. Area A in the upper plain is considered more appropriate for groundwater recharge than areas B and C in the coast.  相似文献   

5.
The tannery industry influences the gross domestic product/economic activity of any country, but the uncontrolled release of tannery effluents causes environmental degradation and increases health risks to human. The reason for the toxicity of tannery effluents is the presence of high concentrations of organic and inorganic chemicals used in the production of leather goods. Untreated or partially treated effluents discharged into surface water results in an increase in both chemical and biological oxygen demand as well as in an increase in the levels of total suspended solids, dissolved solids, and toxic metals in environmental bodies, especially in soil, water bodies, and water sediments. Various treatment techniques, such as physicochemical, biological, and advanced oxidation methods, which include chemical precipitation, electrocoagulation, aerobic or anaerobic treatment, wetland construction, and Fenton, electro-Fenton, and photo-Fenton processes are also described. This review also discusses the technical appropriateness and economic feasibility of reducing the effluent pollution load and solid waste emanating from the tannery industry. Considering the enhanced health risks in the tannery waste treatment and management regime, some green and advanced technologies should be explored. A sustainable green technology that avoids the use of toxic chemicals in the tanning process is seen well for ecological health.  相似文献   

6.
Magnetite nanoparticles were applied to remove Ni(II) from aqueous solutions as a function of pH, contact time, supporting electrolyte concentration, and analytical initial Ni(II) concentration. The highly crystalline nature of the magnetite structure with diameter of around 10 nm was characterized with transmission electron microscopy (TEM) and X‐ray diffractometry (XRD). The surface area was determined to be 115.3 m2/g. Surface chemical properties of magnetite at 25°C in aqueous suspensions were investigated. The point of zero charge (pHzpc) was found to be 7.33 and the intrinsic acidity constants (${\rm p}K_{{\rm a}1}^{{\rm s}} $ and ${\rm p}K_{{\rm a}2}^{{\rm s}} $ ) were found to be 9.3 and 5.9, respectively. The surface functional groups were investigated with Fourier transform‐infrared spectroscopy (FTIR) as well. Batch experiments were carried out to determine the adsorption kinetics and mechanism of Ni(II) by these magnetite nanoparticles. The adsorption process was found to be pH dependent. In NaCl solutions, Ni(II) adsorption increased with increasing ionic strength while in NaClO4 solutions, Ni(II) adsorption exhibited little dependence on the ionic strength of the solution. The adsorption process better followed the pseudo‐second order equation and Freundlich isotherm.  相似文献   

7.
In many streams, microbial growth largely relies on terrigenous organic carbon that has been initially stored in soils and that is generally believed to be recalcitrant to microbial metabolism. The various mechanisms that underlie the availability of terrigenous organic carbon as it enters streams remain poorly understood. One possible mechanism can be photodegradation of terrigenous dissolved organic carbon (DOC) upon exposure to sunlight in streamwater. To explore this, we experimentally exposed streamwater, shallow groundwater and soil water from a clear-water Alpine headwater stream, and both soil and algal extracts, to UV-radiation and studied the effects on DOC optical properties and implications for microbial growth. Our results on the apparent quantum yield suggest that DOC from groundwater and soil water is more resistant to photodegradation than DOC in the streamwater itself. This would highlight the relevance of the exposure history of DOC to sunlight. Overall, UV-radiation decreased the aromaticity (as SUVA254) of the DOC and reduced its molecular weight as indicated by the slope ratio, S R (S 275–295/S 350–400). UV-treatment significantly increased bacterial growth rate and bacterial growth efficiency in the streamwater, soil water, groundwater and soil extract but not in algal extract. Our findings suggest photodegradation as one mechanism that contributes to the microbial utilisation of terrigenous DOC even in clear-water streams.  相似文献   

8.
The White method is a simple but the most frequently applied approach to estimate groundwater evapotranspiration (ETg) from groundwater level diurnal signals. Because of a lack of direct measurements of ETg, it is difficult to evaluate the performance of the White method, particularly in field environments with variable groundwater fluctuations. A 2‐year field observation in a hyper‐arid riparian tamarisk (Tamarix spp.) stand with deep groundwater depth in the lower Tarim River basin of China was conducted to measure the surface evapotranspiration (ETs) and groundwater table. The performance of the White method and the influences of the variable groundwater fluctuations on the determinations of the specific yield (Sy) and recharge rate of groundwater (r) in the White method were investigated. The results showed that the readily available Sy determined by Loheide's method was feasible but must be finely determined based on the soil textures in the layers in which the groundwater level fluctuated. A constant Sy value for a defined porous medium could be assumed regardless of the discharge or recharge processes of groundwater. The time span of 0000 h to 0600 h for r estimation for the White method worked best than other time spans. A 2‐day moving average of r values further enhance ETg estimation. Slight effects of environmental or anthropogenic disturbances on the diurnal fluctuations of groundwater level did not influence the ETg estimations by the White method. Our results provide valuable references to the application of the White method for estimating daily ETg in desert riparian forests with deep groundwater depth. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

9.
The ability of seven hyperaccumulator macrophytes which grow naturally in the heavy metal contaminated channels of three different industries (Hindustan Aeronautical Ltd., Eveready Ltd., and Scooter India Ltd.) to accumulate heavy metals was recorded. All these industries use electroplating processes in their manufacturing and are located in the inner area of Lucknow City, U.P., India. Of the three industries monitored, effluent released from Eveready Ltd. contained the highest concentration of heavy metals. In general, accumulations of heavy metals depend upon the plant species and the metal concentration in the media. All plant samples showed heterogeneous metal accumulations, except for Fe or Cd. It was observed that some plant species accumulated high level of metals, e. g., Eichhornnia crassipes for Fe (4052.44 μg/g), Mn (788.42 μg/g), and Cu (315.50 μg/g), and Spirodela polyrhiza for Cd (12.75 μg/g), Pb (20.25 μg/g), and Cr (128.27 μg/g), even when the metal concentrations were not high in the effluent. In summary, these two plants were found to be the best accumulators at each contaminated site. The results will be helpful in the selection of plant species which can be used as bioaccumulators or bioindicators.  相似文献   

10.
On a bench scale the treatment of electroplating effluents (ZnCl2, NiCl2, NH4Cl, NH3 and two polyether compounds) with Wofatit CA20 is investigated. If the capacity of the resin is utilized to a high degree for the heavy metal ions, the organic matter remains in the filtrate. The results are discussed with regard to the recovery and waste-disposal technology on a large scale.  相似文献   

11.
Acid mine drainage (AMD) is one of the most significant environmental challenges facing the mining industry worldwide. For this reason, many methods for AMD treatment are developed, being wetlands a good option for metal elements removal from these mining effluents. The efficiency of Peruvian native plants such as Schoenoplectus californicus (S. californicus) to remove metal elements in effluents through artificial wetlands is studied. Batch removal tests are carried out with different effluents containing copper, zinc, lead, and iron. For iron-metal binary effluents, copper, zinc, and lead are removed by 82%, 75%, and 88%; while in the effluent containing all metals, the removal rate is 90% and 92% for copper and lead, respectively. According to the preliminary results, it is concluded that iron interferes more in the removal of zinc and lead than in copper from binary effluents. The use of S. californicus turns out to be an efficient, attractive, and economical alternative for the treatment of effluents contaminated with copper, zinc, lead, and iron.  相似文献   

12.
Rapid magnitude estimate procedures represent a crucial part of proposed earthquake early warning systems. Most of these estimates are focused on the first part of the P-wave train, the earlier and less destructive part of the ground motion that follows an earthquake. Allen and Kanamori (Science 300:786–789, 2003) proposed to use the predominant period of the P-wave to determine the magnitude of a large earthquake at local distance and Olivieri et al. (Bull Seismol Soc Am 185:74–81, 2008) calibrated a specific relation for the Italian region. The Mw 6.3 earthquake hit Central Italy on April 6, 2009 and the largest aftershocks provide a useful dataset to validate the proposed relation and discuss the risks connected to the extrapolation of magnitude relations with a poor dataset of large earthquake waveforms. A large discrepancy between local magnitude (ML) estimated by means of $\tau_p^{{\rm max}}$ evaluation and standard ML (6.8 ± 1.5 vs. 5.9 ± 0.4) suggests using caution when ML vs. $\tau_p^{{\rm max}}$ calibrations do not include a relevant dataset of large earthquakes. Effects from large residuals could be mitigated or removed introducing selection rules on τ p function, by regionalizing the ML vs. $\tau_p^{{\rm max}}$ function in the presence of significant tectonic or geological heterogeneity, and using probabilistic and evolutionary methods.  相似文献   

13.
Shallow groundwater plays a key role in agro‐hydrological processes of arid areas. Groundwater often supplies a necessary part of the water requirement of crops and surrounding native vegetation, such as groundwater‐dependent ecosystems. However, the impact of water‐saving irrigation on cropland water balance, such as the contribution of shallow groundwater to field evapotranspiration, requires further investigation. Increased understanding of quantitative evaluation of field‐scale water productivity under different irrigation methods aids policy and decision‐making. In this study, high‐resolution water table depth and soil water content in field maize were monitored under conditions of flood irrigation (FI) and drip irrigation (DI), respectively. Groundwater evapotranspiration (ETg) was estimated by the combination of the water table fluctuation method and an empirical groundwater–soil–atmosphere continuum model. The results indicate that daily ETg at different growth stages varies under the two irrigation methods. Between two consecutive irrigation events of the FI site, daily ETg rate increases from zero to greater than that of the DI site. Maize under DI steadily consumes more groundwater than FI, accounting for 16.4% and 14.5% of ETa, respectively. Overall, FI recharges groundwater, whereas DI extracts water from shallow groundwater. The yield under DI increases compared with that under FI, with less ETa (526 mm) compared with FI (578 mm), and irrigation water productivity improves from 3.51 kg m?3 (FI) to 4.58 kg m?3 (DI) through reducing deep drainage and soil evaporation by DI. These results highlight the critical role of irrigation method and groundwater on crop water consumption and productivity. This study provides important information to aid the development of agricultural irrigation schemes in arid areas with shallow groundwater.  相似文献   

14.
Soil effects on peak ground acceleration, velocity and elastic response spectra (5% damping) are expressed by simple approximate relations in terms of five key parameters: (a) the fundamental vibration period of the non‐linear soil, TS, (b) the period of a bedrock site of equal thickness, Tb, (c) the predominant excitation period, Te, (d) the peak seismic acceleration at outcropping bedrock, a, and (e) the number of significant excitation cycles, n. Furthermore, another relation is proposed for the estimation of TS in terms of the soil thickness H, the average shear wave velocity of the soil V?S,o and a. The aforementioned parameters were first identified through a simplified analytical simulation of the site excitation. The multivariable approximate relations were then formulated via a statistical analysis of relevant data from more than 700 one‐dimensional equivalent‐linear seismic ground response analyses, for actual seismic excitations and natural soil conditions. Use of these relations to back‐calculate the numerical results in the database gives an estimate of their error margin, which is found to be relatively small and unbiased. The proposed relations are also independently verified through a detailed comparison with strong motion recordings from seven well‐documented case studies: (a) two sites in the San Fernando valley during the Northridge earthquake, and (b) five different seismic events recorded at the SMART‐1 accelerometer array in Taiwan. It is deduced that the accuracy of the relations is comparable to that of the equivalent‐linear method. Hence, they can be readily used as a quick alternative for routine applications, as well as for spreadsheet computations (e.g. GIS‐aided seismic microzonation studies) where numerical methods are cumbersome to implement. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

15.
Better knowledge regarding internal soil moisture and piezometric responses in the process of rainfall-induced shallow slope failures is the key to an effective prediction of the landslide and/or debris flow initiation. To this end, internal soil moisture and piezometric response of 0.7-m-deep, 1.5-m-wide, 1.7-m-high, and 3.94-m-long semi-infinite sandy slopes rested on a bi-linear impermeable bedrock were explored using a chute test facility with artificial rainfall applications. The internal response time defined by the inflection point of the soil moisture and piezometric response curves obtained along the soil–bedrock interface were closely related to some critical failure states, such as the slope toe failure and extensive slope failures. It was also found that the response times obtained at the point of abrupt bedrock slope decrease can be used as indicators for the initiation of rainfall-induced shallow slope failures. An investigation of spatial distributions of soil water content, ω (or degrees of saturation, Sr), in the slope at critical failure states shows that the 0.2 m – below – surface zone remains unsaturated with Sr 40–60%, regardless of their distances from the toe and the rainfall intensity. Non-uniform distributions of ω (or Sr) along the soil–bedrock interface at critical failure states were always associated with near-saturation states (Sr 80–100%) around the point of bedrock slope change or around the transient ‘toe’ upstream of the slumped mass induced by the retrogressive failure of the slope. These observations suggest the important role of the interflow along the soil–bedrock interface and the high soil water content (or high porewater pressure) around the point of bedrock slope deflection in the rainfall-induced failure of sandy slopes consisting of shallow impermeable bedrocks. The present study proposes an ‘internal response time’ criterion to substantiate the prediction of rainfall-induced shallow slope failures. It is believed that the ‘internal response time’ reflects the overall characteristics of a slope under rainfall infiltration and can be as useful as the conventional meteorology-based threshold times. The ‘internal response time’ theory can be generalized via numerical modeling of slope hydrology, slope geology and slope stability in the future.  相似文献   

16.
Significant efforts have been expended for improved characterization of hydraulic conductivity (K) and specific storage (Ss) to better understand groundwater flow and contaminant transport processes. Conventional methods including grain size analyses (GSA), permeameter, slug, and pumping tests have been utilized extensively, while Direct Push-based Hydraulic Profiling Tool (HPT) surveys have been developed to obtain high-resolution K estimates. Moreover, inverse modeling approaches based on geology-based zonations, and highly parameterized Hydraulic Tomography (HT) have also been advanced to map spatial variations of K and Ss between and beyond boreholes. While different methods are available, it is unclear which one yields K estimates that are most useful for high resolution predictions of groundwater flow. Therefore, the main objective of this study is to evaluate various K estimates at a highly heterogeneous field site obtained with three categories of characterization techniques including: (1) conventional methods (GSA, permeameter, and slug tests); (2) HPT surveys; and (3) inverse modeling based on geology-based zonations and highly parameterized approaches. The performance of each approach is first qualitatively analyzed by comparing K estimates to site geology. Then, steady-state and transient groundwater flow models are employed to quantitatively assess various K estimates by simulating pumping tests not used for parameter estimation. Results reveal that inverse modeling approaches yield the best drawdown predictions under both steady and transient conditions. In contrast, conventional methods and HPT surveys yield biased predictions. Based on our research, it appears that inverse modeling and data fusion are necessary steps in predicting accurate groundwater flow behavior.  相似文献   

17.
Ten reaction vessels containing 1 m3 were used as the experimental arrangement. They were filled with coarse sand or fine gravel and installed 60 cm below the floor. The pore volume (water saturation) was 227… 260 l. Anaerobic conditions were established by the addition of 6 g glucose at storage. The reactors were given tap water with 50 and 200 mg/l NO from KNO3 in such a way that a volumetric rate of flow of 0.2, 0.4 and 0.8 l/d was created. The volumetric rates of flow corresponded to the natural recharge of groundwater, the recharge of groundwater under the conditions of irrigation and the conditions of an intensive wastewater ground treatment. In the effluent from the reaction vessels the nitrate concentration was determined every month. It was stationary from the 7th to the 55th month after the beginning of the experiment. The experiments are evaluated by means of a model which takes into account the diffusion, convection and kinetics of the nitrate degradation according to Michaelis-Menten. A simple method for solving homogeneous non-linear differential equations of the second order is proposed. The experimental and model results show a good agreement and prove the very slow nitrate degradation in the groundwater with kM = 210 mg/l, vmax = 1.5 mg/l · d or k1 = 0.005 d?1.  相似文献   

18.
Unstable density‐driven groundwater flow and solute transport (i.e., free convection) leads to spatiotemporal variations in pressure. Specific storage (So) indicates the capability of a confined aquifer to release or store groundwater associated with a pressure change. Although So is known to dampen pressure propagation, So has been implicitly assumed to have a negligible impact on the unstable free convective process in prior studies. This work explores the effect of So on both the classic onset criterion and the fingering process using numerical models. Results show that the classic onset criterion is applicable when So is smaller than 10–1 m–1. Results also demonstrate that So does not play a significant role in the free convective fingering process unless it is greater than 10–3 m–1. For most practical purposes in hydrogeology (large Rayleigh number and small So), the implicit assumption of small or zero So is appropriate.  相似文献   

19.
Summary The stress sensitivitiesS x andS R of susceptibility and remanence for titanomagnetite-bearing rocks are calculated in terms of magnetostriction constants 100 and 111 and anisotropy constantsK 1,K 2 of the magnetic minerals.S x andS R are represented by quite different algebraic expressions but happen to have comparable numerical values over the whole range of titanomagnetite compositions. Both increase strongly with titanium content. This leads to more optimistic calculations of tectonomagnetic effects than with the previously assumed stress sensitivity for pure magnetite.  相似文献   

20.
Assessment and Modification of Arsenic Mobility in Contaminated Soil Arsenic concentration in the seepage of contaminated soils of an old tannery site is assessed using batch and column experiments. The effect of reducing conditions, pH, and ionic strength is also investigated. The iron oxide rich subsoil (C‐horizon) is the main source of groundwater pollution with arsenic. In this horizon, mobilization can increase as a result of reducing conditions upon periodical water saturation. Therefore, the potentially mobile arsenic is determined by a reductive dissolution of the poorly crystalline iron oxide fraction using 0.1 M ascorbic acid. Arsenic concentration can be reduced from 100 μg/L to below 20 μg/L by an increase of ionic strength (e.g. by a 0.01 M CaCl2 solution). Arsenic contaminated soils should be limed regularly in order to maintain the highest possible calcium concentration in the soil solution.  相似文献   

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