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1.
. Riverine water samples were collected from the lower reach hydrometric station Makou of the Xijiang River, in four hydrological seasons during 1997 and 1998. The samples were analyzed for their particulate and dissolved organic carbon. The contents of riverine particulate and dissolved organic carbon changed synchronously during different hydrological processes. The contents of organic carbon and total suspended substances in the riverine water increased with increasing discharge. The mass of organic carbon in the total suspended substances decreased logarithmically with increasing total suspended substances. The transported flux of organic carbon in the Xijiang River drainage is about 10.18᎒6 g of C km–2 year–1, which is two to three times larger than that of the average value in other river systems. Particulate organic carbon is the main component of riverine organic carbon, with a flux of about 8.30᎒6 g of C km–2 year–1.  相似文献   

2.
High water and organic content of sewage sludge constricts its reuse and disposal. It is often necessary to solidify/stabilize the dewatered sludge with solidifying agents before landfill disposal. In this study, the sewage sludge was conditioned with skeleton builders, i.e., fly ash and lime combined with ferric chloride for the purpose of improving the dewatering efficiency. The dewatered sewage sludge was then directly reused as landfill cover materials since the skeleton builders also play a role in solidification of sludge. The geotechnical properties of the dewatered sewage sludge were investigated. The results show that the plasticity index of the dewatered sludge increases compared to that of the dewatered sludge without any conditioner, and the permeability coefficient changes from 10?8 to 10?5 cm s?1. Furthermore, the strength of specimens increase with curing days. Microstructure analyses reveal that the main hydrated products are calcium silicate hydrate and ettringite, which contribute to the solidification/stabilization of the dewatered sludge. The results indicate that the dewatered sewage sludge conditioned with skeleton builders can be used as landfill covers. This study provides an alternative for traditional sewage sludge treatment and disposal.  相似文献   

3.
浩婷  王曦  周颜  吴燕 《岩土力学》2015,36(11):3187-3192
采用自主改装的变压头黏土渗透仪,模拟疏浚淤泥脱水过程中水分在淤泥颗粒多孔介质中的迁移运动过程,通过测定疏浚淤泥脱水过程中渗透系数与过滤常数、渗水量与滤液量、泥饼含水率与孔隙率,探究了负载压力为100 kPa时,不同负载方式（负载时间及负载压力梯度变化）对疏浚淤泥脱水过程中过滤和渗流规律的影响。研究发现：负载下的过滤和渗流同时进行,负载1 h期间,前期0～40 min内过滤占主导地位,后期40～60 min内渗流起关键作用。负载压力梯度由原来1 h内间隔变化1次,变为以20 kPa为梯度递增变化5次,随着压力变化梯度减小,渗透系数、过滤常数增加,淤泥脱水性能得到较明显的改善,并且前期负载压力越小,脱水效果越好。  相似文献   

4.
Lead distribution on a public shotgun range   总被引：1，自引：0，他引：1  
. A detailed study has been made of the distribution of lead on a public shotgun range in the George Washington – Jefferson National Forests in southwestern Virginia. Sampling of more than 100 sites has yielded data on the distribution pattern of the lead shot. Since opening in 1993 through 2000, 11.1 metric tons (t) of lead have been accumulated over an area 220쑼 m (66,000 m2) with an average rate of accumulation of 1.4 t/year. More than 85% of the total dispersed lead lies scattered in the forest that surrounds the approximately 60Ꮔ-m cleared shooting surface. Lead is irregularly distributed because of the use of stationary targets and the general trajectory of launched clay targets. Maximum concentrations occur at distances of ~28, ~80, and ~180 m, and reach a maximum value of more than 5,000 g/m2. Significant amounts of fine particulate lead, generated during shooting and as a result of impact occur close to the shooting box, but are absent at distances beyond 50 m.  相似文献   

5.
In this research, a novel laboratory scale anaerobic/upflow sludge blanket filtration combined bioreactor was designed and operated to improve the efficiency of the upflow sludge blanket filtration process for the simultaneous removal of phosphorus and nitrogen from wastewater. The anaerobic/upflow sludge blanket filtration technique was developed by adding an anaerobic reactor to its influent and operated by varying the main process parameters in order to gain the optimum conditions. The results showed that biological removal efficiency of nitrogen and preservation of sludge blanket strongly depend on wastewater characteristics, hydraulic retention time, sludge age and process controlling parameters. The combined bioreactor performed a total nitrogen removal efficiency of 96.6 % with the sludge age of 25 days, total hydraulic retention time of 24 h and optimum “chemical oxygen demand/nitrogen/phosphorus” ratio of 100/ 5/1. This ratio also improved the compaction quality of sludge blanket in the upflow sludge blanket filtration clarifier. The average specific nitrification and denitrification rates occurred during the process can be expressed as 4.43 mg NOx-N produced/g VSS.d and 5.50 mg NOx-N removed/g VSS.d at the optimum ratio, respectively. To avoid sludge rising due to denitrification process, the optimum total hydraulic retention time of 16 to 24 h was achieved based on the effluent quality. This study suggested that the anaerobic/upflow sludge blanket filtration bioreactor at the optimum operational conditions can be an effective process for removal of nutrients from municipal wastewater.  相似文献   

6.
. Naphthalenesulfonates and their condensation products with formaldehyde are manufactured in the chemical industry for broad application as tanning agents, dispersing agents, and as superplasticizers for concrete. With the disposal of waste they have found their way into the aquatic environment. Five monomeric naphthalenesulfonates and a group of dimeric sulfonated naphthalene-formaldehyde condensates (SNFC) were identified in the leachate and in groundwater observation wells downstream in the plume of the Karlsruhe-West landfill, situated in the Upper Rhine Valley in southwest Germany. For the main monomer of technical SNFC products, 2-naphthalenesulfonate (2-NS), the concentration in the leachate was 170 µg l–1, which decreased to 9.5 µg l–1 at a distance of about 300 m from the boundary of the landfill. In the Merdingen tracer test field, the transport of these compounds was studied under more controlled conditions in two tracer experiments with (1) two model compounds, and (2) a technical SNFC product and uranine as a reference tracer. In these experiments, the monomeric naphthalenesulfonates and the SNFC with n=2 behave as conservative tracers. Thus, the findings of the landfill study were supported by these results. Higher molecular SNFC were strongly retarded, which is attributed to adsorption to soil particles. The results of the second tracer experiment suggest a degradation of 2-NS and 2,6-naphthalenedisulfonate (2,6-NDS) after adaptation of the microorganisms in the groundwater aquifer as a consequence of the first tracer experiment.  相似文献   

7.
Hydro-mechanical evaluation of stabilized mine tailings   总被引：3，自引：0，他引：3  
. In this study, mine tailings waste was stabilized using a combination of lime, fly ash type "C", and aluminum. Treated samples were subjected to mineral identification for evaluating the formation of ettringite and gypsum. Also, unconfined compression, hydraulic conductivity, and cyclic freeze and thaw tests were performed to evaluate the hydro-mechanical properties of the stabilized samples. Experimental results have shown that the application of lime and fly ash type "C" to high sulfate content tailings has improved its plasticity, workability, and volume stability. Moreover, upon addition of aluminum to lime and fly ash in a sulfate-rich environment, ettringite and calcium sulfo-aluminate hydrate are formed in these samples. Application of 5% lime, 10% fly ash type "C", in combination with 110 ppm aluminum, resulted in the formation of a solid monolith capable of producing more than 1,000 kPa of unconfined compressive strength, and reduced tailings permeability to 1.96᎒–6 cm s–1, which is less than the recommended permeability of 10–5 cm s–1 by most environmental protection agencies for reusability of solidified/stabilized samples. The permeability of the treated tailings samples remained below the recommended permeability, even after exposing the treated samples to 12 freeze and thaw cycles. Therefore, based on the experimental results, it is concluded that treatment of high sulfate-content tailings with lime and fly ash, combined with the availability of aluminum for reactions, is a successful method of solidifying highly reactive mine tailings.  相似文献   

8.
. Acid atmospheric deposition may enter an environmental ecosystem in a variety of forms and pathways, but the most common components include sulfuric and nitric acids formed when rain water interacts with sulfur (SOx) and nitrogen (NOx) emissions. For many soils and watersheds sensitive to acid deposition, the predominant chronic effect appears to be a low pH, loss of base cations, and a shift in the mineral phase controlling the activity of Al3+ and/or SO42– in solution. Soil solutions from lysimeters at various depths were taken at two sites in the Daniel Boone National Forest, Kentucky, USA, to evaluate potential impacts caused by acid deposition. The sites chosen were in close proximity to coal-burning power plants near Wolfe and McCreary counties and contained soils from the Rayne and Wernock series, respectively. Physicochemical characteristics of the soils revealed that both sites contained appreciable amounts of exchangeable acidity in the surface horizons, and that their base saturation levels were sufficiently low to be impacted adversely by acidic inputs. Soil solution data indicated that the sites were periodically subjected to relatively high NO3– and SO42– inputs, which may have influenced spatial and temporal variation in Al and pH. As a consequence, the formation of Al-hydroxy-sulfate minerals such as jurbanite, alunite and basaluminite were thermodynamically favored over gibbsite. Given these conditions, long-term changes in soil solution chemistry from acid deposition are acknowledged.  相似文献   

9.
. This paper deals with sorption and anaerobic biodegradation of the soluble aromatic fraction of jet fuel and how it is influenced by pore-water velocity during transport in a groundwater aquifer. The study was carried out as controlled laboratory column experiments. A binary mixture of toluene and 1,2,4-trimethylbenzene with a concentration ratio of 2:1 was used through the entire investigations. The column experiments were conducted with contaminated sediments and groundwater, taken from wells at a field research site. The columns were operated anaerobically under continuous-flow conditions at 10 °C in a temperature-controlled refrigerator. Two percent sodium azide was added to the injection solution of two of the columns to prevent biodegradation of the studied organic mixture. Chloride was used as a conservative tracer to characterize the hydrodynamic parameters such as dispersivity and porosity of the columns. The results showed that both compounds in the mixture were attenuated because of sorption and biodegradation processes in the columns. 1,2,4-trimethylbenzene was attenuated more significantly than toluene. Biodegradation of toluene was coupled mainly with the microbial reduction of ferric iron, whereas 1,2,4-trimethylbenzene, in contrast, was mostly sorbed. Their sorption and biodegradation were studied with different pore-water velocities, and a mass balance approach was applied to calculate biodegradation rates. The biodegradation rates of toluene were –0.16, –0.21, and –0.26 (unit: mM day–1) for pore-water velocities of 96, 82.4, and 54.9 (unit: cm day–1), respectively. This indicates that a decrease in the pore-water velocity significantly enhanced the biodegradation of toluene, consistent with other reports in the literature. For 1,2,4-trimethylbenzene the biodegradation rates were –0.05, –0.13 (unit: mM day–1) for pore-water velocities of 96 and 82.4 (unit: cm day–1), respectively. The biodegradation rate of 1,2,4-trimethylbenzene did not increase at the lowest pore water velocity as expected. This might be a result of substrate competition.  相似文献   

10.
Sediment masses and heavy-metal accumulation rates for the recent deposits of the Göta älv estuary were calculated using a GIS. Total masses of 4,000 t Zn and >20 t Hg were recorded, of which 367 t Zn and >0.72 t Hg occur in the inner estuary, the Göteborg harbour, and 3,657 t Zn and 19 t Hg are in the outer estuary, suggesting a high trapping efficiency of the estuary. The accumulation rates are 5 g m-2 year-1 Zn and 0.01 g m-2 year-1 Hg in the harbour, and 1.5 g m-2/year-1 Zn and 0.007 g m-2 year-1 Hg in the outer estuary. The Zn and Hg accumulation rates are highest close to the outlet of a sewage treatment plant, and decrease by a factor of 5 for Zn, and a factor of 2 for Hg in the outer estuary. The accumulation rates in the outer estuary decrease after 1980 A.D.  相似文献   

11.
本文报道了一种以天然矿物钠基蒙脱石(Montmorillonite.简写 MTR)制备的锂型蒙脱石(MTR:Li+)的离子导电性能。在室温下(25℃),MTR:(Pc)的离子电导率为1.53×10-3Ω-1·cm-1,MTR:Li+(DMF)离子电导率为1.31～1.85×10-3Ω-1·cm-1,电子电导率在总电导率的1%以下,激活能0.14eV,分解电压2.6—3.3V,电化学性能稳定。  相似文献   

12.
. Since the late 1940s sand mining has been developing in the Paraíba do Sul River, especially in its floodplain. Today, sand extraction exceeds 15 million tons per year causing the relevant environmental problems. To examine the evolution over a 35-year time span of these environmental impacts, land cover data from a 31-km2 floodplain were compiled from large-scale vertical aerial photographs from 1962, 1986/1988, and 1997/1998. These data were analyzed using a geographical information system (GIS). A number of environmental impact indicators were identified and measured through the application of aerial photo/GIS methodology. These include (1) total mining areas, (2) former agricultural land converted into open pits, open water ponds and mining ancillary installations, (3) deforested areas, (4) channel river morphology modification, (5) vegetation growth in reclaimed areas, and (6) mining encroachment on the legally protected riverside zone. Most indicators show a great increase in impact magnitude over the period.  相似文献   

13.
Arsenic pollution in groundwater from Hetao Area,China   总被引：3，自引：0，他引：3  
. Hetao Area, China is a district where arsenic concentrations in drinking water are elevated. The 180,000 people that inhabit the 6,100 km2 of the seven counties in the area show symptoms of arsenic poisoning. In this paper, the distribution and origin of arsenic in groundwater were studied. The results demonstrate that the affected district boundaries encompass an area with high contents of As in well water, which the local inhabitants drink and use in daily life. This district is labeled as a population pathological change area. The isotope ratios of 87Sr/86Sr (0.7100–0.7164), 206Pb/204Pb (18.3817–19.1871), and 207Pb/204Pb (15.7581–15.9578) in groundwater of the population pathological change area are close to the ratios measured in water from mine areas (87Sr/86Sr=0.7196, 206Pb/204Pb=19.1940, 207Pb/204Pb=15.9574), and are somewhat close to ratios in Yellow River, water which is used to irrigating in Hetao Area (87Sr/86Sr=0.7168, 206Pb/204Pb=18.3495, 207Pb/204Pb=15.5969). The average content of As in the drinking water is as high as four times more than the environmental standard of As in drinking water. The study suggests that the origin of the As in groundwater of the population pathological change area in Hetao Area is transported from higher elevations where mineral deposits exist. Mining of some of the deposits has occurred for a long time. Mining practices can result in release of toxic elements, which can then be transported from the mining district down gradient.  相似文献   

14.
Sludge samples taken from different sources and times may have different characteristics that could affect dewatering performance. In this study, 20 sludge samples from five wastewater treatment plants and different seasons in 1 year were characterized. Pearson correlation analysis indicated that solid content (SC), total suspended solid (TSS), polysaccharides and proteins contents had positive correlations with the capillary suction time (CST), whereas volatile suspended–solid/total suspended solid (VSS/TSS) exhibited negative correlations with CST. Moreover, no correlations between CST and specific resistance to filtration were found among these different sludge samples. The principal component analysis confirmed that only two group variables could represent most of the sludge characteristic parameters. The first set of variables represents the particulate nature of the biotic factors (SC, VSS/TSS, SCOD, TSS, polysaccharides and proteins), and the second set is the pH. CST could not be a reasonable indicator of dewaterability in sludge deep dewatering by Fe2+/S2O8 2?-phosphogypsum composite conditioning. Furthermore, the results of diaphragm filter press dewatering showed that initial SC and VSS/TSS were the most dominant sludge characteristics affecting the solid content of dewatered cake (R p = 0.610, p = 0.016; R p = ?0.838, p = 0.000, respectively) with Fe2+/S2O8 2?-phosphogypsum composite conditioning. Results from this study suggest that dewatering performance is predictable by sludge characteristics parameters for Fe2+/S2O8 2?-phosphogypsum conditioning.  相似文献   

15.
Vertical electrical sounding (VES) and hydrochemical data have been used to examine the extent of saltwater intrusion into shallow aquifers (depth<300 m) beneath the coastal plains of southeastern Nigeria underlain by siliciclastic sedimentary rocks of the Cenozoic Niger Delta. The VES data indicate that the coastal regions not affected by saltwater are characterised by K-and H-type geoelectrical curves and models in which high-layer resistivities (in excess of about 100 ohm-m) reflect the presence of freshwater aquifers at depths greater than 5 m below the surface. By contrast, Q-type curves and models denote saltwater-infiltrated islands with the upper boundary of the saline zone at depths of about 25 to 30 m. Chemical analysis results of precipitation and ground water show that, compared to coastal and continental sites, island localities have higher concentrations of major ions (Na+, K+, Ca2+, Mg2+, Cl-, HCO3-, SO42-, NO3) due to saltwater intrusion. In addition, these ions, which also characterise seawater, show very good correlations (>0.70). Furthermore, the coastal sites are marked by Ca-Cl and Ca-HCO3 water types whereas Na-Cl dominated both the islands ( at depths greater than 20 m) and the seawater. This gives an indication of seawater contamination. Seawater contamination is also indicated by the results of five assessment parameters as follows: high chloride concentration (>500 mg/l), high saturation index (halite>10-6), high ionic strength (>0.05), low formation resistivity (<25 ohm-m), and low formation factor (<0.05). Two of these parameters (chloride concentration, ionic strength) have been used to compose an assessment scheme with five major classes (AA, BB, CC, DD, EE) corresponding to various degrees of salinity. Generally in the study area, saltwater contamination is a feature of island locations at depths greater than about 20 m. Water within the inland coastal regions is fresh.  相似文献   

16.
Metamorphic isograds and time-integrated fluid fluxes were mappedover the 1500 km2 exposure of the Waits River Formation, easternVermont, south of latitude 4430'N. Isograds based on the appearanceof oligoclase, biotite, and amphibole in metacarbonate rocksdefine elongated metamorphic highs centered on the axes of twolarge antiforms. The highest-grade isograd based on the appearanceof diopside is closely associated spatially with synmetamorphicgranitic plutons. Pressure, calculated from mineral equilibria,was fairly uniform in the area, 7 1.5 kb; calculated temperatureincreases from {small tilde} 480C at the lowest grades in thearea to {small tilde} 575C in the diopside zone. CalculatedXco2f equilibrium metamorphic fluid increases from <0-03at the lowest grades to 0.2 in the amphibole zone and decreasesto 0.07 in the diopside zone. Time-integrated fluid fluxesincrease with increasing metamorphic grade, with the followingmean values for each metamorphic zone (in cm3/cm2): ankerite-oligoclasezone, 1 x 104; biotite zone, 7 x 104; amphibole zone, 2 x 105;diopside zone, 7 x 105. The mapped pattern of time-integrated fluxes delineates twolarge deep-seated ({small tilde} 25-km depth) regional metamorphichydrothermal systems, each centered on one of the major antiforms.Fluid flowed subhorizontally perpendicular to the axis of theantiforms from their low-temperature flanks to their hot axialregions and drove prograde decarbonation reactions as they went.Along the axes of the antiforms fluid flow was further focusedaround synmetamorphic granitic intrusions. In the hot axialregion fluid changed direction and flowed subvertically outof the metamorphic terrane, precipitating quartz veins. Estimatesof the total recharge, based on progress of prograde decarbonationreactions, nearly match estimates of the total discharge, basedon measured quartz vein abundance, (2-10) x 1012 cm3 fluid percm system measured parallel to the axes of the antiforms. Withinthe axial regions fluids had lower XCO2 and rocks record greatertime-integrated fluxes close to the intrusions than at positionsmore than {small tilde} 5 km from them. The differences in bothfluid composition and time-integrated flux can be explainedby mixing close to the intrusions of regional metamorphic fluidsof XCO2/ with fluids from another source with XCO2{small tilde}0 in the approximate volume ratio of 1:2.  相似文献   

17.
FERRY  JOHN M. 《Journal of Petrology》1995,36(4):1039-1053
Contact-mctamorphic assemblages in ophicarbonate from the Bergellaureole correspond either to model isobaric invariant T-XCO2points [Atg-Cal-Di-Tr-Fo (6 samples) and Atg-Cal-Tr-Fo-Dol (2)]or to isobaric univariant T-XCO2, curves [Tr-Cal-Di-Atg (18),Tr-Dol-Atg-Cal (1), Atg-Cal-Fo-Di (1), and Atg-Cal-Tr-Fo (1)].Calcite-dolomite thermometry and mineral-fluid equilibria inthe invariant assemblages record T=440–540C at P=3•5kbar. Equilibrium metamorphic fluids were very H2O rich withX CO2,=0•001–0•027. In the invariant assemblagesTr + Fo were produced by prograde decarbonation-dehydrationreactions. In contrast, measured modes and reaction texturesin samples with univariant assemblages indicate thai Tr wasproduced by carbonation reactions. The apparent paradox of simultaneousdecarbonation reactions in the model isobaric invariant assemblagesand carbonation reactions in univariant assemblages is resolvedby local mineral-fluid equilibrium and fluid flow through ophicarbohatesin the direction of decreasing temperature as the aureole heated.Time-integrated flux (q) was computed from measured reactionprogress in 28 samples for models of both horizontal and verticaldown-temperature flow. Results are similar, with q decreasingrapidly from (0•2–5•1) 105 cm3 fluid/cm2 rock1•3–1•7 km from the intrusion to 0–0•6105cm3/cm2 at 1•8–4•0 km. The decrease in q ismore consistent with vertical than horizontal flow. Variationsin time-integrated flux of more than an order of magnitude arerecorded by samples from the same outcrop. The absence of carbonatein adjacent metaperidotite indicates that flow was confinedto the ophicarbonate. Channelized, spatially heterogeneous,vertical flow can be explained by the brecciation and strongvertical foliation of the ophicarbonate relative to surroundingmassive metaperidotite. Generation of metamorphicfluids by decarbonation-dehydrationreactions within the ophicarbonates explains larger averageflux 1–2 km from the intrusion compared with more distalpoints. KEY WORDS: Bergell; contact metamorphism; fluid flow; ophicarbonate *Telephone: (410) 516-8121. Fax: (410) 516-7933  相似文献   

18.
The adsorption and desorption behaviors of 17??-ethinylestradiol on various sludges derived from different treatment units of a sewage treatment plant were investigated using batch equilibration experiments. The results showed that adsorption process could be well described by pseudo-second-order kinetic model and fast adsorption played a main role. Adsorption ability varied as the order of aerobic sludge????anoxic sludge????primary sludge?>?sludge cake?>?anaerobic sludge. Adsorption/desorption isotherms were well fitted by the modified Freundlich model, and $ K_{f}^{\prime } $ values increased with the organic matter content. Thermodynamic analysis indicated that 17??-ethinylestradiol adsorption/desorption was exothermic and conducted spontaneously. After heat treatment for removing the organic carbon, $ K_{f}^{\prime } $ values decreased by more than 78%, but organic carbon normalized adsorption constant was 7.76?C29.51?mg/g. The 17??-ethinylestradiol adsorption capacity was found to decrease from 0.95?C1.39 to 0.44?C0.49?mg/g with sludge concentration increasing from 500 to 4,000?mg/L, being almost unchanged at pH 3?C10 and sharply decreasing with pH?>?10. The adsorption capacity was also found to fluctuate in the range of 2.0?C3.0?mg/g when Ca2+ concentration was <0.5?mol/L and increased rapidly above 0.5?mol/L. Addition of methanol and acetonitrile could improve 17??-ethinylestradiol desorption effect, which increased with the content of organic solvents, and the desorption degree of acetonitrile was higher than methanol.  相似文献   

19.
Ultrafine coal dewatering is of great importance to the coal industry due to its impacts on the handling and utilization characteristics of coal products. Commercially available filtration techniques are either ineffective or costly for dewatering of ultrafine coal to the desired moisture level of about 20%. Considerable efforts have been devoted to understanding the dewatering process and developing new technologies for applications in the coal industry. Most of the previous work on ultrafine coal filtration was focused on the final filter cake moisture and few studies have been conducted to investigate the filtration kinetics. The present investigation was undertaken to better understand the kinetics of vacuum filtration of ultrafine coal under various conditions. The filtrate weight was continuously monitored using a precise load cell during the entire filtration process. Operating parameters such as vacuum pressure and reagent conditioning time were examined for their impacts on filtration kinetics. Use of cationic and anionic flocculants showed significant improvement in filtration kinetics. Kinetic data obtained from the study were used to determine the fundamental parameters of filtration such as cake permeability, specific cake resistance, and filter medium resistance using the integrated form of the Darcy's law.  相似文献   

20.
A new thermobarometer, based on the equilibrium: has been calibrated with experiments carried out in the piston-cylinderapparatus. Reversed equilibria were obtained using well-calibrated2.54 cm NaCl furnace assemblies and Ag80Pd20capsules with fO2bufferedat or near iron-wustite. The equilibrium is located between5.2–5.4, 6.6–6.8, and 8.6–8.8 kb at 880, 940,and 1020?C, respectively, and at 5.2 and 8.8 kb between 865–880and 1020–1030?C, respectively. X-ray refinement data indicate that the hercynite (a = 8.15546?) has approximately 18 per cent inverse character. M?ssbauerspectra reveal that 4 mol per cent of the Fe is ferric (2 percent magnetite component). Broad Mossbauer lines and a Fe2+energy level splitting of 3.7 kJ mol–1 calculated fromthe Mossbauer spectra are consistent with the X-ray determineddegree of inversion, although no separate octahedral Fe2+ spectraldoublet is resolved. Calibration of this equation allows calculation of the equilibrium: Thermobarometers based on the above equilibria are widely applicablein granulite fades rocks and yield pressure/temperature datathat are consistent with other well-calibrated barometers andthermometers.  相似文献   

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