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1.
N-m-Tolyl-o-methoxybenzohydroxamic acid (N-m-T-o-MBHA) was used for the simultaneous extraction and direct spectrophotometric determination of vanadium at microgram concentration from phosphorites. Vanadium (V) was extracted as a deep violet complex with 5 ml of 0.1N-m-T-o-mMBHA in chloroform. The extraction was quantitative and obeys Beer's law in the range of 0.05–15 μg/ml of vanadium at 550 nm and the molar absorptivity was 6.4 × 103.This method is selective and vanadium could be determined in the presence of various ions.  相似文献   

2.
A study was undertaken in order to understand the kinetics and mechanism of the chemical oxidation of N,N-diethyl-m-toluamide, an insect repellent, by sulfate radical. In this experiment, sulfate radical was generated using peroxymonosulfate with iron(II) and cobalt(II) as activator. The second-order rate constant for the reaction of the sulfate radical with N,N-diethyl-m-toluamide was found to be (1.9 ± 0.1) × 109 M?1 s?1 at pH 7 and a temperature of 25 °C. Experiments for the chemical oxidation of N,N-diethyl-m-toluamide in river water and secondary wastewater revealed that the percentage of the removal of N,N-diethyl-m-toluamide was slightly influenced by the water matrices. However, the selected oxidation systems are not effective for the removal of N,N-diethyl-m-toluamide in seawater. Transformation by-products of N,N-diethyl-m-toluamide generated using peroxymonosulfate/iron(II) sulfate, peroxymonosulfate/iron(II) chloride, peroxymonosulfate/cobalt(II) sulfate and peroxymonosulfate/cobalt(II) chloride systems were identified. The results indicated that there are slight differences in the distributions of the transformation by-products detected depending on the activator. The common transformation by-products detected in all selected oxidation systems are N,N-diethylbenzamide, N-ethyl-m-toluamide, N,N-dimethyl-m-toluamide, N-ethyl-N-acetyl-m-toluamide, 2-(diethylamino)-1-m-tolylethanone, monohydroxylated N-ethyl-m-toluamide, and dihydroxylated N,N-diethyl-m-toluamide. Monohydroxylated N,N-diethyl-m-toluamide were detected only when the peroxymonosulfate/iron(II) system was applied. For the peroxymonosulfate/cobalt(II) systems, additional isomers of monohydroxylated N-ethyl-m-toluamide were detected. Peroxymonosulfate/cobalt(II) also transformed 2-(diethylamino)-1-m-tolylethanone into N-ethyl-N-(2-oxo-2-m-tolylethyl)acetamide and monohydroxylated 2-(ethyl(vinyl)amino)-1-m-tolylethanone as transformation by-products.  相似文献   

3.
《地学前缘(英文版)》2018,9(6):1795-1807
The high-to ultrahigh-pressure metamorphic rocks of the Atbashy complex were petrologically investigated. The eclogites of the Choloktor Formation show a prograde evolution from epidote-blueschist facies(P = 17-21 kbar and T = 450-515 ℃) to peak eclogite-UHP conditions(P = 26-29 kbar and T = 545-615 ℃) with a subsequent epidote-amphibolite and greenschist facies overprint. The micaschists of the Choloktor Formation also show a clockwise P-T path from blueschist/epidote-blueschist facies conditions through peak eclogite facies conditions(P = 21-23 kbar and T = 530-580 ℃) to retrograde epidote-amphibolite and greenschist facies stages. A comparison of the P-T paths in the eclogites and mica-schists of Choloktor Formation reveal that they may have shared their P-T history from peak to retrograde stages. The mica-schists of the Atbashy Formation record peak metamorphism of P = 10-12 kbar and T = 515-565 ℃, which indicates that the highest grade of regional metamorphism in the Atbashy Ridge was epidote-amphibolite facies.The newly obtained P-T conditions for the mica-schists of Choloktor Formation indicate that sheets of sedimentary rocks were brought to great depths along the subduction zone and they metamorphosed under eclogite facies HP conditions. The eclogite blocks were amalgamated with mica-schists of Choloktor Formation in the eclogite facies HP conditions and together they experienced isothermal decompression to ～40 km. During this path, the eclogites and mica-schists of Choloktor Formation docked with mica-schists of Atbashy Formation at 10-12 kbar and 515-565 ℃, and from this depth(～40 km) the whole sequence was exhumed together. These new results improve our understanding of high-pressure metamorphism in subduction-related accretionary prism zones and the exhumation processes of deeply-seated rocks in the Atbashy HP-UHP complex.  相似文献   

4.
Estimation of mean trace length of discontinuities   总被引：18，自引：0，他引：18  
Summary Trace lengths of discontinuities observed on finite exposures are biased due to sampling errors. These errors should be corrected in estimating mean trace length. A technique, which takes into account the sampling errors, is proposed for estimating the mean trace length on infinite, vertical sections from the observations made on finite, rectangular, vertical exposures. The method is applicable to discontinuities whose orientation is described by a probability distribution function. The method requires that the numbers of discontinuities with both ends observed, one end observed, and both ends censored be known. The lengths of observed traces and the density function of trace length are not required. The derivation assumes that midpoints of traces are uniformly distributed in the vertical plane. Also independence between trace length and orientation is assumed. Data on a Pennsylvania shale in Ohio, U. S. A., were used as an example.Notations dip direction - direction of sampling plane - acute angle between dip direction and sampling plane - dip angle - A apparent dip angle - mean density of trace mid-points per unit area - mean trace length - D diameter of discontinuity - f (.),g (.) probability density function - h height of rectangular window - estimator of mean trace length - m sample size, number of discontinuities intersecting window - m 0 number of discontinuities intersecting window with both ends censored - m 2 number of discontinuities intersecting window with both ends observed - n, N expected number of discontinuities intersecting the window - n 0,N 0 expected number of discontinuities intersecting the window with both ends censored - n 2,N 2 expected number of discontinuities intersecting the window with both ends observed - Pr (.) probability - w width of rectangular window - x trace length  相似文献   

5.
Unpolarized absorption spectra of single crystals of Cr3+ doped Al2O3 (synthetic ruby) have measured using a new, time-resolving, dispersive, streak photographic system over the range ～350 to ～700 nm during a series of shock loading experiments. The crystal field absorptions assigned to the transition 4 A 2g→4 T 2g were observed to shift in a series of experiments from 555±1 nm at atmospheric pressure to 503±5 nm at 46 GPa. In a single experiment at 32 GPa the 4 A 2g→4 T 1g transition was observed to shift from 405±1 to 386±5 nm. The present data extrapolate downwards in compression toward the 10 GPa data of Stephens and Drickamer (1961) although both crystal field absorption energies increase considerably less with compression than predicted by the simple ionic point charge model. The single datum observed for the Racah parameter B, 588±38 cm?1 at 32 GPa, is consistant with previous results to 10 GPa and the trend of decreasing B, with compression expected from the divergence of the data from the point charge model due to increasing covalancy.  相似文献   

6.
The shape of a plume conduit produced by melting solid paraffin block above a local heat source was studied experimentally as a function of the relative thermal power of the plume Ka= N/N1, where N1 is the power of the plume source and N1 is the power corresponding to the amount of heat transferred by conduction through the plume conduit to the surrounding solid paraffin block. The limiting power of the plume source at which the plume erupts at the Earth’s surface (Nlim1= (1.35–1.60) × 1010 W) and the power at which the mushroom-shaped plume head formed at the base of the refractory layer (Nlim2= (1.78–1.90) × 1010 W) with no horizontal mantle flow were determined. The dependence of the diameter of the base of the plume on the Ka number was established. The Ka value and the diameter of the plume base were determined for the Hawaiian and Iceland plumes, for the plume responsible for the formation of the Tunguska syneclise and for the McKenzie and Central Atlantic continental plateau-basalt provinces and for the Ontong Java and Manihiki oceanic lava plateaus.  相似文献   

7.
Nitrous oxide (N2O) is a potent greenhouse gas. Mitigating N2O emission is critical for combating global climate change and improving the ecological environment. Many studies have focused on factors affecting N2O emission from agricultural soils, but rarely on the relationship among these factors. In the present study, continuous measurement on N2O emission was conducted in a maize system in Griffith, Australia and the relationships between N2O emission, soil properties and weather conditions were examined. Principal component analysis and path analysis were used to analyze these data in correlation coefficient and the direct and indirect effects to N2O emission. Results indicated that (1) the major factors affecting N2O emission were WFPS, mineralized nitrogen (Mineral N), daily mean temperature (T mean) and CO2 concentration. The factors of direct influence N2O emission were following Mineral N, CO2, WFPS, and T mean. The indirect influence N2O emission was following T mean, WFPS, Mineral N, and CO2 concentration. (2) The standard multiple regression describing the relationship between N2O emission and its major factors were Y = ?37.162 + 0.5267 X 1 + 0.4331 X 2 + 0.3014 X 3 + 0.2392 X 4 (r = 0.924, p < 0.01, n = 151), where Y is N2O emission, X 1 is Mineral N, X 2 is CO2, X 3 is WFPS and X 4 is T mean. (3) N2O emission from agricultural soils can be monitored and mitigated through improved management practices such as irrigation, straw retention and fertilizer application.  相似文献   

8.
Comprehensive nitrogen biogeochemical cycle has been reconstructed for representative lacustrine organic-rich sedimentary rock in China, namely the Triassic Yanchang Formation (YF, 199–230 Ma) in Ordos and the Cretaceous Qingshankou Formation (QF, 86–92 Ma) in Songliao basins, by evaluating the organic and inorganic nitrogen isotopic compositions rather than only organic or bulk nitrogen isotopic compositions. The results indicate that the nitrogen isotope values of bulk rock (δ15Nbulk) in the non-metamorphic stage are significantly different from that of kerogen, which challenge the conceptual framework of sedimentary nitrogen isotope interpretation. The δ15Nbulk from the YF and QF were lower than their respective the nitrogen isotope values of kerogen (δ15Nker), with offsets up to ～5.1‰, which have the inverse relationship for the metamorphosed rock. Thermal evolution did not significantly modify the δ15N of bulk rock and kerogen. The δ15N of sediments from the YF (δ15Nbulk, 1.6‰–5.6‰) were lower than that of rock from the QF (δ15Nbulk, 10.2‰–15.3‰). The nitrogen isotope values of silicate incorporated nitrogen (δ15Nsil) were slightly lower than those of the δ15Nker in the YF and obviously lower for the QF. The fact that different nitrogen cycles occur in the YF and QF due to the different depositional redox conditions leads to different isotopic results. The YF water environment dominated by oxic conditions is not conducive to the occurrence of denitrification and anammox, and no abundant N2 loss leads to the relatively light δ15Nbulk. In the stratified water for the QF, redox transition zone promotes denitrification and anammox, resulting in the heavy δ15Nbulk of rock and promotes the DNRA, resulting in heavy δ15Nker and low δ15Nsil.  相似文献   

9.
The Paleozoic granitoids of the Sierra de San Luis comprise the Ordovician tonalite suite (OTS; metaluminous to mildly peraluminous calcic tonalite–granodiorites) and granodiorite–granite suite (OGGS; peraluminous calcic to calc-alkaline granodiorite–monzogranites), as well as the Devonian granite suite (DGS; peraluminous alkali-calcic monzogranites) and monzonite–granite suite (DMGS; metaluminous alkali-calcic quartz monzonite–monzogranite ± granodiorite, mildly peraluminous alkalicalcic monzogranites). The OTS has relatively high K2O, CaO, and YbN and low Cr, Ni, Ba, Sr, Rb/Sr, Sr/Y, and (La/Yb)N, as well as negative Eu/Eu1, high 87Sr/86Sr (0.70850–0.71114), and unradiogenic εNd(470Ma) (−5.3 to −6.0), which preclude an origin of variably fractionated mantle melts and favour a mafic lower crustal source. The OGGS consists of two granitoids: (1) high-temperature characterized by low Al2O3/TiO2, Rb/Sr, and (La/Yb)N, a smooth negative Eu/Eu1, and relatively high CaO and (2) low-temperature with high Al2O3/TiO2 and Rb/Sr, low CaO, (La/Yb)N, and Sr/Y, and negative Eu/Eu1. Melting of metagreywackes at pressures below 10 kbar with a variable supply of water could account for the chemistry of the high-T OGGS, whereas dehydration melting of biotite-bearing metasedimentary sources at low pressures is proposed for the low temperature OGGS. Melting of crustal sources relates to a contemporaneous mafic magmatism.Devonian magmatism is characterized by high Ba, Sr, K2O, Na2O, Sr/Y, and (La/Yb)N. Sources for the DGS include metasedimentary or metatonalitic protoliths. Biotite dehydration melting triggered by the addition of heat, supplied by mantle-derived magmas, is proposed. High Ba, Sr, LREE, MgO, Cr, Ni, Zr, and V of the monzonites suggest an enriched lithospheric mantle source. Low Yb and Y and high Sr and (La/Yb)N indicate a garnet-rich residual assemblage (P ⩾ 10 kbar). Melts for the peraluminous rocks may have derived from a metasedimentary or metaigneous source at lower pressures in a process dominated by biotite consumption and plagioclase in the residue.The Ordovician granitoids are synkinematic with compressive deformation related to the early stages of Famatinian convergence. The Devonian magmatism is synkinematic with a system of shear zones that were active during the Achalian cycle.  相似文献   

10.
Changes of stomatal conductance (g s), net photosynthetic rates (P N) and water use efficiency (WUE) were investigated in Populus euphratica grown on sites with different groundwater depths (GDs) under two CO2 concentrations in the lower reaches of Tarim River, Xinjiang, northwestern China. P N in P. euphratica only slightly decreased when the groundwater depth increased from 4.12 to 7.74 m below the ground surface. P N values significantly increased in response to an elevated CO2 concentration at all GDs except at GD of 4.12 m for its good availability of groundwater. WUE values decreased with an initial increase in the groundwater depth, but increased when the groundwater depth reached 7.74 m especially under the elevated CO2 concentration. The g s values measured at 4.12 and 4.74 m both decreased indistinctively by only 3% due to CO2 enrichment; however, when GDs increased to 5.54 and 7.74 m, the g s values decreased significantly by about 10%. It shows that the response of g s in P. euphratica to elevated CO2 is weaker under lower groundwater depth (mild drought stress) but stronger under deeper groundwater depth (moderate drought stress). Results from this study suggest that groundwater depth could determine the response of photosynthesis to future CO2 enrichment in P. euphratica in arid desert areas.  相似文献   

11.
We study the phase relations and mineral chemistry in the systems muscovite–NH3–N2-H2O and eclogite + muscovite–NH3–N2-H2O at 6.3–7.8 GPa, 1000–1200 °C, and oxygen fugacity (fO2) from ∼IW (Fe–FeO) to ∼ NNO (Ni–NiO) equilibria. The quenched H2O-bearing fluids differ in nitrogen speciation from NH3-rich to N2–rich, and the respective N2/(NH3+N2) ratio varies from <0.1 to ∼ 1. N-bearing K-cymrite is obtained in association with a kyanite-garnet-jadeite ± muscovite ± corundum assemblage in the muscovite–NH3–N2-H2O system and coexists with pyrope-almandine garnet and omphacite in the eclogite + muscovite–NH3–N2-H2O system. The presence of an N-bearing fluid in the studied systems stabilizes the K-cymrite structure. Muscovite does not convert to K-cymrite in the absence of NH3–N2-bearing fluid up to 7.8 GPa and 1070–1120 °C. According to FTIR and Raman spectroscopy, K-cymrite in equilibrium with an N-rich fluid can capture a huge amount of nitrogen in cages of its framework, mainly as N2 molecules at fO2 ∼NNO and predominantly as NH3 molecules at fO2 ∼IW. The storage capacity of K-cymrite with respect to nitrogen increases from 2.9 to 6.3 wt% with increase of fO2. FTIR spectroscopy of muscovite equilibrated with K-cymrite shows that the clathrate mechanism of nitrogen entrapment by aluminosilicates (as neutral N2 and NH3 molecules) is much more efficient than the K+ → (NH4)+ substitution. The structure of N-bearing K-cymrite (K,(NH4+))[AlSi3O8]·(N2,NH3,H2O) determined using X-ray single-crystal diffraction is very similar to that of H2O-bearing K- and Ba-cymrites. It includes aluminosilicate layers consisting of double six-membered tetrahedral rings and cation sites statistically occupied with K+, Ba2+ and (NH4)+ on the six-fold symmetry axis in interlayer space. The N2 and NH3 molecules are located near the cage centers and, unlike H2O molecules, are included in the coordination environment of the cations. Our study confirms that NH3- and N2-rich K-cymrite may be stable in metapelites and can act as a redox insensitive carrier of nitrogen to >250 km mantle depths in downgoing slabs. The stability field of N-rich K-cymrite in the presence of an N2–H2O–NH3-bearing fluid is inferred to be P ≥ 4 GPa in metasediments rich in K-feldspar and P ≥ 6 GPa in those containing phengite. As the slab material sinks deeper than 250–300 km where N-bearing K-cymrite may lose stability, the releasing nitrogen may migrate to metal-saturated mantle and become stored there in γ−Fe, Fe3C, metal melt, or even iron nitride phases.  相似文献   

12.
For many years, information on the solar mean magnetic field (SMMF) of the Sun—an important heliophysical and astrophysical parameter—was restricted to magnetographic measurements in only one spectral line, FeI λ525.02 nm. More informative observations of the Stokes-meter parameters of the SMMF were first initiated on a regular basis at the Sayan Solar Observatory. The availability of I and V data obtained simultaneously in several spectral lines has made it possible to study fundamentally new physical problems. In this paper, based on a comparison of SMMF observations in several spectral lines, we find high correlations in the data and important systematic differences in the magnetic-field strength B, which we interpret as a manifestation of kilogauss magnetic fields in fine-structure magnetic elements. Results of theoretical modeling of the SMMF strength ratios for the FeI λ525.02 nm-FeI λ524.70 nm and FeI λ630.15 nm-FeI λ630.25 nm lines are presented. The asymmetries of the V profiles of four lines near the FeI λ525.02 nm line are examined; these lines are important diagnostics for studies of small-scale dynamical processes. The Sayan Solar Observatory SMMF measurements are in good consistency with the Wilcox Solar Observatory data for 2003: for a comparison of N = 137 pairs of points in the two data sets, the correlation coefficient ρ is 0.92 for the linear regression between the datasets BWSO = 0.03(±0.05) + 0.93(±0.03)BSSO.  相似文献   

13.
In order to investigate the effect of standard penetration test (SPT) hammer impact on the energy transfer ratio (ETR) and sampler penetration, the behavior of hammer and anvil is monitored by using a high-speed digital line-scan camera and the stress wave is measured by using a pile driving analyzer during SPTs. By analyzing the motions of the hammer and anvil, which are digitized using the image processing algorithm, two types of secondary impact are observed to exist. Type-I secondary impact is caused by the rapid downward anvil movement at time t 1 + 2L/c and the re-contact of the following hammer on the rebounding anvil. Type-I secondary impact is dominant for N value smaller than 25 and it contributes to the ETR and additional sampler penetration. The time elapsed to type-I secondary impact decreases as N value increases. Type-II secondary impact is induced by the restrike of the pushed-up hammer on the resting anvil. Type-II secondary impact is dominant for N value greater than 50 and it has no influence on the ETR and the sampler penetration. The time elapsed to type-II secondary impact increases with the increase in N value.  相似文献   

14.
Rapid temperature change causes fractionation of isotopic gaseous species in air in firn (snow) by thermal diffusion, producing a signal that is preserved in trapped air bubbles as the snow forms ice. Using a model of heat penetration and gas diffusion in the firn, as well as the values of appropriate thermal diffusion constants, it is possible to reconstruct the magnitude of a particular paleoclimate change. Isotopic nitrogen in air serves as a convenient tracer for such paleoreconstruction, because the ratio 29N2/28N2 has stayed extremely constant in the atmosphere for ≥106 years. However, prior to this work no data were available for thermal diffusion of 29N2/28N2 in air, but only in pure N2. We devised a laboratory experiment allowing fractionation of gases by thermal diffusion in a small, tightly controlled temperature difference. A mass spectrometer was employed in measuring the resulting fractionations yielding measurement precision greater than was attainable by earlier thermal diffusion investigators.Our laboratory experiments indicate that the value of the thermal diffusion sensitivity (Ω) for 29N2/28N2 in air is +(14.7 ± 0.5) × 10−3 per mil/°C when the average temperature is -30.0°C. The corresponding value for 29N2/28N2 in pure N2 that we find is +(15.3 ± 0.4) × 10−3 per mil/°C at -30.6°C, in agreement with the previously available literature data within their large range of uncertainty. We find that an empirical equation, Ω = (8.656/TK − 1232/T K2) ± 3% per mil/°C, describes the slight variation of the sensitivity values for 29N2/28N2 in air with temperature in the range of -60 to 0°C. A separate set of experiments also described in this paper rules out adsorption as a candidate for producing additional temperature change-driven fractionation of 29N2/28N2 in the firn air. The combined newly obtained data constitute a calibration of the fossil-air paleothermometer with respect to isotopic nitrogen and will serve to improve the estimates of the magnitudes of past abrupt climate changes recorded in ice cores.  相似文献   

15.
The stress characteristics method (SCM) has been used to compute the bearing capacity of smooth and rough ring foundations. Two different failure mechanisms for a smooth footing, and four different mechanisms for a rough footing have been considered. For a rough base, a curvilinear non-plastic wedge has been employed below the footing. The analysis incorporates the stress singularities at the inner as well as outer edges of the ring footing. Bearing capacity factors, Nc, Nq and Nγ are presented as a function of soil internal friction angle (ϕ) and the ratio (ri/ro) of inner to outer radii of the footing.  相似文献   

16.
A garnet-bearing schist from the southernmost such exposure along the Himalaya in east central Nepal records prograde metamorphism at 32.4 ?± ?0.3 ?Ma. Phase equilibria modelling, combined with Ti-in-biotite and quartz c-axis thermometry, outline a tight-to-hairpin pressure-temperature (P-T) path extending from ~515 ?°C and 5.5 ?kbar to peak conditions at ~575 ?°C and 7 ?kbar followed by deformation during the retrograde phase at 480–515 ?°C and 6–7 ?kbar. The new geochronology data place an upper bound on the evolution of metamorphism and deformation in the frontal-most part of the Himalaya, which lasted until 17.5 ?Ma, as indicated by previously published 40Ar/39Ar data. The P-T-time data from this part of the Himalaya, as well as that from more hinterland-ward portions of the orogen, outline a progressive, stepwise, commonly out-of-sequence evolution. Further data from along the orogen indicates that this evolution is not a local phenomenon, but instead characterizes the tectonics of this system as a whole.  相似文献   

17.
Interactions in a Fe–C–O–H–N system that controls the mobility of siderophile nitrogen and carbon in the Fe0-saturated upper mantle are investigated in experiments at 6.3–7.8 GPa and 1200–1400 °C. The results show that the γ-Fe and metal melt phases equilibrated with the fluid in a system unsaturated with carbon and nitrogen are stable at 1300 °C. The interactions of Fe3C with an N-rich fluid in a graphite-saturated system produce the ε-Fe3N phase (space group P63/mmc or P6322) at subsolidus conditions of 1200–1300 °C, while N-rich melts form at 1400 °C. At IW- and MMO-buffered hydrogen fugacity (fH2), fluids vary from NH3- to H2O-rich compositions (NH3/N2?>?1 in all cases) with relatively high contents of alkanes. The fluid derived from N-poor samples contains less H2O and more carbon which mainly reside in oxygenated hydrocarbons, i.e., alcohols and esters at MMO-buffered fH2 and carboxylic acids at unbuffered fH2 conditions. In unbuffered conditions, N2 is the principal nitrogen host (NH3/N2?≤?0.1) in the fluid equilibrated with the metal phase. Relatively C- and N-rich fluids in equilibrium with the metal phase (γ-Fe, melt, or Fe3N) are stable at the upper mantle pressures and temperatures. According to our estimates, the metal/fluid partition coefficient of nitrogen is higher than that of carbon. Thus, nitrogen has a greater affinity for iron than carbon. The general inference is that reduced fluids can successfully transport volatiles from the metal-saturated mantle to metal-free shallow mantle domains. However, nitrogen has a higher affinity for iron and selectively accumulates in the metal phase, while highly mobile carbon resides in the fluid phase. This may be a controlling mechanism of the deep carbon and nitrogen cycles.  相似文献   

18.
Comparisons of the brightness distributions of the white corona observed at distances of several solar radii with solar wind velocities derived from interplanetary-scintillation observations, as well as analyses of solar wind data obtained on spacecraft from December 1994 to June 1995, indicate that the fast solar wind can contain plasma with velocities V ≈ 300–450 km/s, approaching those typical for the slow solar wind that flows in the streamer belt and chains of streamers. At the same time, certain other parameters, first and foremost the plasma density N and ratio T/N 0.5 (where T is the temperature), indicate that these two flows differ considerably. The slow solar wind flowing in the streamer belt and chains displays high densities N > 10 ± 2 cm?3 and low T/N 0.5 < 1.7 × 104 K cm3/2 at the Earth’s orbit. The number of slow solar-wind sources observed in chains can be comparable with the number observed in the belt. The fast solar wind flowing from coronal holes always displays low densities N≤ 8 cm?3 and high T/N 0.5 > 1.7 × 104 K cm3/2. These properties probably indicate different origins of the fast and slow solar winds.  相似文献   

19.
Solubility experiments for nitrogen and noble gases (Ar and Ne) in silicate melts were conducted using two experimental configurations: one was conducted at 1 atmospheric pressure, T =1300°C and oxygen fugacity (fO2) of IW + 0.9 (i.e., 0.9 log units higher than the iron-wüstite buffer) and the other at high pressures (Ptotal ∼ 2 × 108 Pa), 1500°C and fO2 ∼ IW + 6. For the former experiment, isotopically labeled-nitrogen (15N15N-enriched) was used to distinguish dissolved nitrogen from contaminating atmospheric or organic nitrogen and to examine dissolution mechanisms of nitrogen in silicate melts. The results obtained for the two series of experiments are consistent with each other, suggesting that Henry's law is satisfied for fN2 of up to ∼250 atm (2.5 × 107 Pa). The results are also consistent with our earlier results (Miyazaki et al., 1995) obtained at highly oxidizing conditions (fO2 ∼ IW + 10). All these results support physical dissolution of nitrogen as N2 molecules in silicate melts for fO2 from ∼IW + 10 down to ∼IW. The observed solubility (Henry's constant) of nitrogen (3-5 × 10−9 mol/g/atm) is comparable to that of Ar (2-4 × 10−9 mol/g/atm), and much lower than that of Ne (11-14 × 10−9 mol/g/atm) at 1300°C. A preliminary experiment was also performed for partitioning of nitrogen and noble gases between clinopyroxene (cpx) and basaltic melt using a piston cylinder-type apparatus at 1.5 GPa and at 1270 to 1350°C. The obtained cpx/melt partition coefficient of nitrogen is 0.06, slightly lower than those of noble gases (∼0.1 for Ne to Xe), suggesting that nitrogen is as incompatible as or even slightly more incompatible than noble gases. The present results imply that a large nitrogen/Ar fractionation would not be produced by magmatic processes. Therefore, the two orders of magnitude difference between the N2/36Ar ratios in the Earth's atmosphere (∼104) and that in the mantle (∼106) must be explained by some other processes, such as incomplete segregation of metal blobs into the core and their later oxidation.  相似文献   

20.
The optical absorption and luminescence spectra of MgAl2O4:Cr3+ natural spinel (from Ural) have been measured at 77 K and 293 K. The luminescent emission from 4 T 2g , 2 E g covers wide region of 600–750 nm. The emission spectrum at 77 K shows a very rich vibrational structure which can be mainly explained through the vibrational modes of the oxygen octahedron.  相似文献   

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