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1.
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2.
We present ab initio calculations of the zero-temperature iron high- to low-spin crossover in (Mg1 ? xFex)SiO3 perovskite at pressures relevant to Earth's lower mantle. Equations of state are fit for a range of compositions and used to predict the Fe spin transition pressure and associated changes in volume and bulk modulus. We predict a dramatic decrease in transition pressure as Fe concentration increases. This trend is contrary to that seen in ferropericlase, and suggests the energetics for spin crossover is highly dependent on the structural environment of Fe. Both Local Density Approximation (LDA) and Generalized Gradient Approximation (GGA) exchange-correlation methods are used, and both methods reproduce the same compositional trends. However, GGA gives a significantly higher transition pressure than LDA. The spin transition is made easier by the decreasing spin-flip energy with pressure but is also driven by the change in volume from high to low spin. Volume trends show that high-spin Fe2+ is larger than Mg2+ even under pressure, but low-spin Fe2+ is smaller at ambient conditions and approximately the same size as Mg2+ under high pressure, indicating that low-spin Fe2+ is less compressible than high-spin Fe2+. We find large changes between high- and low-spin in the slope of volume with Fe concentration. Although these changes are small in absolute magnitude for small Fe content, they are still important when measured per Fe and could be relevant for calculating partitioning coefficients in the lower mantle.  相似文献   

3.
L-band (1.5 GHz) and VHF (244 MHz) amplitude scintillations observed from Kolkata (22.58°N lat, 88.38° E long, 32°N dip), over a solar cycle 1996–2006 are presented in this paper. Situated near the northern crest of the equatorial anomaly, it is an excellent platform for scintillation studies. Based on 11 years’ data, an attempt is made to develop models of hourly percentage occurrence of scintillations for the rising and declining phases of solar cycle using Neural Network. The relation between fading rate at VHF with the S4 index at L-band is also investigated.  相似文献   

4.
We present a new, impulsive, horizontal shear source capable of performing long shot profiles in a time-efficient and repeatable manner. The new shear source is ground-coupled by eight 1/2″ (1.27 cm) × 2″ (5.08 cm) steel spikes. Blank shotshells (12-gauge) used as energy sources can be either mechanically or electrically detonated. Electrical fuses have a start time repeatability of < 50 μs. This source can be operated by a single individual, and takes only ~ 10 s between shots as opposed to ~ 30 s for six stacked hammer blows. To ensure complete safety, the shotshell holder is surrounded by a protective 6″ (15.24 cm)-thick barrel, a push-and-twist-locked breach, and a safety pin.We conducted field tests at the 17th Street Canal levee breach site in New Orleans, Louisiana (30.017° N 90.121° W) and at an instrumented test borehole at Millsaps College in Jackson, Mississippi (32.325° N 93.182° W) to compare our new source and a traditional hammer impact source. The new shear source produces a broader-band of frequencies (30–100 Hz cf. 30–60 Hz). Signal generated by the new shear source has signal-to-noise ratios equivalent to ~ 3 stacked hammer blows to the hammer impact source. Ideal source signals must be broadband in frequency, have a high SNR, be consistent, and have precise start times; all traits of the new shear source.  相似文献   

5.
Culturally significant oral tradition involving Pele, the Hawaiian volcano deity, and her youngest sister Hi'iaka may involve the two largest volcanic events to have taken place in Hawai'i since human settlement: the roughly 60-year-long ‘Ailā’au eruption during the 15th century and the following development of Kīlauea's caldera. In 1823, Rev. William Ellis and three others became the first Europeans to visit Kīlauea's summit and were told stories about Kīlauea's activity that are consistent with the Pele–Hi'iaka account and extend the oral tradition through the 18th century. Recent geologic studies confirm the essence of the oral traditions and illustrate the potential value of examining other Hawaiian chants and stories for more information about past volcanic activity in Hawai‘i.  相似文献   

6.
Ocean Dynamics - The analysis of a 28-year-long (1989–2016) series of monthly measurements of chlorophyll concentrations and primary production rates at a shelf station off A Coruña (NW...  相似文献   

7.
At the appropriate times, silica diffusion in clay is possibly the rate determining process for the dissolution of vitrified waste disposed of in a clay layer. For testing this hypothesis, combined glass dissolution/silica diffusion experiment are performed. SON68 glass coupons doped with the radioactive tracer 32Si are sandwiched between two cores of humid Boom Clay, heated to 30 °C. Due to glass dissolution, 32Si is released and diffuses into the clay. At the end of an experiment, the mass loss of the glass coupon is measured and the clay core is sliced to determine the diffusion profile of the 32Si released from the glass in the clay.Both mass loss and the 32Si diffusion profile in the clay are described well by a model combining glass dissolution according to a linear rate law with silica diffusion in the clay. Fitting the experiments to this model leads to an apparent silica diffusion coefficient in the clay between 7 × 10−13 m2/s and 1.2 × 10−12 m2/s. Previously determined values from diffusion experiments at 25 °C are around 6 × 10−13 m2/s (In-Diffusion experiments) and 2 × 10−13 m2/s (percolation experiments). The maximal glass dissolution rate for glass next to clay is around 1.6 × 10−7 g glass/m2 s (i.e. 0.014 g glass/m2 day). In undisturbed clay, the measured silica concentration is around 5 mg/L. Combining these values with the previously measured (In-Diffusion experiments) product of accessible porosity and retardation factor, leads in two ways to a silica glass saturation concentration in clay between 8 and 10 mg Si/L.Another candidate for the rate determining process of the dissolution of vitrified waste disposed in a clay layer is silica precipitation. Although silica precipitation due to glass dissolution has been shown experimentally at 90 °C, extending the model with silica precipitation does not lead to much better fits, nor could meaningful values of a possible precipitation rate be obtained.  相似文献   

8.
Aluminum incorporation into the high pressure polymorph of TiO2 with the structure of α-PbO2 has been studied from 10 to 20 GPa and 1300 °C by XRD, high-resolution 27Al MAS-NMR and TEM. Al-doped α-PbO2 type TiO2 can be recovered at atmospheric pressure. Al2O3 solubility in α-PbO2 type TiO2 increases with increasing the synthesis pressure. The α-PbO2 type TiO2 polymorph is able to incorporate up to 35 wt.% Al2O3 at 13.6 GPa and 1300 °C, being the substitution of Ti4+ by Al3+ on normal octahedral sites the mechanism of solubility. The transition to the higher pressure TiO2 polymorph with the ZrO2 baddeleyite structure, Akaogiite, has not been observed in the quenched samples at room pressure. The microstructure of the recovered sample synthesized at 16 GPa and 1300 °C points to the existence of a non-quenchable aluminum titanium oxide phase at these conditions.  相似文献   

9.
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10.
The MS 6.9 Menyuan earthquake in Qinghai Province, west China is the largest earthquake by far in 2022. The earthquake occurs in a tectonically active region, with a background b-value of 0.87 within 100 ?km of the epicenter that we derived from the unified catalog produced by China Earthquake Networks Center since late 2008. Field surveys have revealed surface ruptures extending 22 ?km along strike, with a maximum ground displacement of 2.1 ?m. We construct a finite fault model with constraints from InSAR observations, which showed multiple fault segments during the Menyuan earthquake. The major slip asperity is confined within 10 ?km at depth, with the maximum slip of 3.5 ?m. Near real-time back-projection results of coseismic radiation indicate a northwest propagating rupture that lasted for ～10 ?s. Intensity estimates from the back-projection results show up to a Mercalli scale of IX near the ruptured area, consistent with instrumental measurements and the observations from the field surveys. Aftershock locations (up to January 21, 2022) exhibit two segments, extending to ～20 ?km in depth. The largest one reaches MS 5.3, locating near the eastern end of the aftershock zone. Although the location and the approximate magnitude of the mainshock had been indicated by previous studies based on paleoearthquake records and seismic gap, as well as estimated stressing rate on faults, significant surface-breaching rupture leads to severe damage of the high-speed railway system, which poses a challenge in accurately assessing earthquake hazards and risks, and thus demands further investigations of the rupture behaviors for crustal earthquakes.  相似文献   

11.
本文利用WRF模式及其伴随模式研究了2005年发生在西北太平洋的一对双台风玛娃和古超的移动路径与强度的伴随敏感性特征,一方面探讨了环境场对双台风的影响,另一方面也讨论了双台风之间的相互影响过程的差异.首先,利用双台风初始化技术准确地模拟了双台风的演变过程,并以此模拟结果为背景场计算了台风的中心扰动气压和引导气流的伴随敏感性.研究结果表明：伴随敏感性不但能反映环境场对双台风的影响,还能指示双台风之间相互影响过程的差异.从台风强度的敏感性来看,影响台风强度变化的高影响区均位于台风中心附近,弱台风古超的强度敏感性的量级要大于强台风玛娃的强度敏感性,表明双台风中较弱的那个更容易受到外部环境变化的影响.台风引导气流的敏感性分布也存在较大差异,强台风玛娃的移动主要受到其西北侧的高空槽,其自身环流以及台风古超的影响,而弱台风古超的引导气流的敏感性主要位于其自身环流附近以及双台风之间的区域.最后,通过在理想试验中增加初始时刻高空槽的强度以及弱台风古超的强度,证实了台风玛娃的移动路径的变化与伴随敏感性的分析一致.  相似文献   

12.
K–Ar ages of young basalts (<500 ka) are often higher than the actual eruption age, due to low potassium contents and the frequent presence of excess Ar in olivine and pyroxene phenocrysts. Geological studies in the San Francisco and Uinkaret volcanic fields in Arizona have documented the presence of excess 40Ar and have concluded that K–Ar ages of young basalts in these fields tend to be inaccurate. This new study in the San Francisco volcanic field presents 3Hec and 21Nec ages yielded by olivine and pyroxene collected from three Pleistocene basalt flows – the South Sheba (∼190 ka), SP (∼70 ka), and Doney Mountain (∼67 ka) lava flows, – and from one Holocene basalt, the Bonito Lava Flow (∼1.4 ka) at Sunset Crater. These data indicate that, in two of three cases, 40Ar/39Ar and K–Ar ages of the young basalts agree well with cosmic-ray surface exposure ages of the same lava flow, thus suggesting that excess 40Ar is not always a problem in young basalt flows in the San Francisco volcanic field. The exposure age of the Bonito lava flow agrees within uncertainty with dendrochronological and archeological age determinations. K–Ar and cosmogenic 3He and 21Ne ages from the SP flow are in agreement and much older than the OSL age (5.5–6 ka) reported for this lava flow. Furthermore, if the non-cosmogenic ages are assumed to be accurate, the subsequent calculated production rates at South Sheba and SP flow sample sites agree well with values in the literature.  相似文献   

13.
The pervasive application of the Null Hypothesis Significance Test in geomorphic research runs counter to widespread, long running, and often severe criticism of the method in the broader scientific literature. The application of the methodology typically leads to a binary separation of evidence into ‘significant’ and ‘not significant’ results based on a p‐value that is dependent on the null hypothesis being true. The method should not therefore be used to provide statistical support for substantive hypotheses, and is unsuitable for scientific inference in open systems where confirmation can only ever be partial. Alternative approaches based on Bayesian statistics can importantly be applied to measure partial support for hypotheses, conditional on the available data. Though not without their own assumptions, wider application of such methods can help facilitate a transition towards a broader approach to statistical, and in turn, scientific inference in geomorphic systems. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

14.
A detailed tephrochronological study was undertaken in three deep-sea cores collected in the Tyrrhenian and Ionian Seas. The age and the origin of the marine tephra were inferred from oxygen isotope records of foraminifera and from major element compositions of glass-shards. Seventy-one eruptions were detected in the time interval 90,000–200,000 yrs during which the volcanoes of the Roman and Campanian regions and of the southern Italy were in activity. This is attested by the consistency of the geochemical compositions of both marine and terrestrial deposits. Most of the marine tephra consisted in trachytes and phonolites characterizing a Roman and Campanian origin. Several tephra were proposed as key-horizons for proximal and distal sediments. Among them, one tephra originating from Mount Etna (149,300 yrs) and five tephra from Pantelleria island (130,000 yrs, 163,600 yrs, 192,500 yrs, 197,400 yrs and 198,400 yrs) were northerly dispersed. Several other key horizons originated from the Campanian or Roman provinces were detected as far as 1000 km from the vents.  相似文献   

15.
A dielectric model for thawed and frozen Arctic organic-rich soil (50% organic matter) has been developed. The model is based on soil dielectric measurements that were collected over ranges of gravimetric moisture from 0.03 to 0.55 g/g, dry soil density from 0.72 to 0.87 g/cm3, and temperature from 25 to −30 °C (cooling run) in the frequency range of 0.05–15 GHz. The refractive mixing dielectric model was applied with the Debye multi-relaxation equations to fit the measurements of the soil’s complex dielectric constant as a function of soil moisture and wave frequency. The spectroscopic parameters of the dielectric relaxations for the bound, transient bound, and unbound soil water components were derived and were complimented by the thermodynamic parameters to obtain a complete set of parameters for the proposed temperature-dependent multi-relaxation spectroscopic dielectric model for moist soils. To calculate the complex dielectric constant of the soil, the following input variables must be assigned: (1) density of dry soil, (2) gravimetric moisture, (3) wave frequency, and (4) temperature. The error of the dielectric model was evaluated and yielded RMSEε′ values of 0.348 and 0.188 for the soil dielectric constant and the loss factor, respectively. These values are on the order of the dielectric measurement error itself. The proposed dielectric model can be applied in active and passive microwave remote sensing techniques to develop algorithms for retrieving the soil moisture and the freeze/thaw state of organic-rich topsoil in the Arctic regions.  相似文献   

16.
We have determined the post-perovskite phase transition boundary in MgSiO3 in a wide temperature range from 1640 to 4380 K at 119–171 GPa on the basis of synchrotron X-ray diffraction measurements in-situ at high-pressure and -temperature in a laser-heated diamond-anvil cell (LHDAC). The results show a considerably high positive Clapeyron slope of + 13.3 ± 1.0 MPa/K and a transition temperature of about 3520 ± 70 K at the core–mantle boundary (CMB) pressure. The thermal structure in D″ layer can be tightly constrained from precisely determined post-perovskite phase transition boundary and the depths of paired seismic discontinuities. These suggest that temperature at the CMB may be around 3700 K, somewhat lower than previously thought. A minimum bound on the global heat flow from the core is estimated to be 6.6 ± 0.5 TW.  相似文献   

17.
To understand physical mechanisms of generation of abnormally high peak ground acceleration (PGA; >1g) during the Tohoku earthquake, models of nonlinear soil behavior in the strong motion were constructed for 27 KiK-net stations located in the near-fault zones to the south of FKSH17. The method of data processing used was developed by Pavlenko and Irikura, Pure Appl Geophys 160:2365–2379, 2003 and previously applied for studying soil behavior at vertical array sites during the 1995 Kobe (М w ?=?6.8) and 2000 Tottori (М w ?=?6.7) earthquakes. During the Tohoku earthquake, we did not observe a widespread nonlinearity of soft soils and reduction at the beginning of strong motion and recovery at the end of strong motion of shear moduli in soil layers, as usually observed during strong earthquakes. Manifestations of soil nonlinearity and reduction of shear moduli during strong motion were observed at sites located close to the source, in coastal areas. At remote sites, where abnormally high PGAs were recorded, shear moduli in soil layers increased and reached their maxima at the moments of the highest intensity of the strong motion, indicating soil hardening. Then, shear moduli reduced with decreasing the intensity of the strong motion. At soft-soil sites, the reduction of shear moduli was accompanied by a step-like decrease of the predominant frequencies of motion. Evidently, the observed soil hardening at the moments of the highest intensity of the strong motion contributed to the occurrence of abnormally high PGA, recorded during the Tohoku earthquake.  相似文献   

18.
A survey of dayside aurora excitation at 557.7 nm, which was acquired from an all-sky imager at Yellow River Station in Ny-Ålesund, Svalbard, shows that there are 4 intense emission maxima in the dayside oval, centered near 0630/76, 0830/76, 1400/75, and 1600/75 (unit: MLT/MLAT), respectively. Tracing the magnetospheric sources of these cores along geomagnetic field lines, the 0830- and 1400-MLT cores correspond with the prenoon and postnoon magnetospheric boundary layers (MBLs), and the 0630- and 1600-MLT cores are located at the dusk and dawn MBLs, respectively. The potential solar wind-magnetosphere dynamic processes resulting in these auroral features are discussed.  相似文献   

19.
亚洲中东部地区塑性流动波(“慢波”)与地震活动   总被引：4，自引：0，他引：4       下载免费PDF全文
王绳祖  张宗淳 《地震地质》2004,26(1):91-101
根据先前相似模型实验的结果 ,在板块边界驱动下 ,沿岩石圈下层 (含下地壳和岩石圈地幔 )传播的塑性流动波包括“快波”和“慢波” ,二者均属于黏性重力波 ,并分别由主波和辅波叠加而成。“快波”以 10 0 ～ 10 2 km/a量级的速度传播 ,已为塑性流动波控制下地震迁移的研究所证实。文中根据 7级以上强震的条带状分布图像 ,证明在喜马拉雅弧驱动下还存在着波速仅为 10 0 ～ 10 1m/a量级的“慢波” ,其中对 7级以上强震起控制作用的主要是“慢波”的辅波 ,其平均波长为 4 45km ,波速为 0 81～ 2 80m/a ,周期为 0 .16～ 0 .5 5Ma。“慢波”的边界起波时间距今约 1.34～ 4 .6 6Ma ,相当于上新世中期至早更新世中期 ,与喜马拉雅构造运动的主要活跃期 (幕 )之一相吻合。以喜马拉雅弧西段和东段为波源所形成的2个“慢波”系统的波峰带相互重叠 ,为 7级以上强震的发生提供了必要的能量背景  相似文献   

20.
The algorithm for monitoring the magnetotelluric field has been briefly described, and the experimental data, obtained at the Bishkek geodynamic site, have been analyzed. The regularities in the seasonal behavior of the variations in the field vertical magnetic component have been revealed.  相似文献   

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