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1.
The understanding of the thermo-hydro-mechanical behaviour of a clay barrier is needed for the prediction of its final in situ properties after the hydration and thermal transient in a radioactive waste repository. As part of the CEC 1990–1994 R&D programme on radioactive waste management and storage, the CEA (Fr), CIEMAT (Sp), ENRESA (Sp), SCK · CEN (B), UPC (Sp) and UWCC (UK) have carried out a joint project on unsaturated clay behaviour (Volckaert et al., 1996). The aim of the study is to analyse and model the behaviour of a clay-based engineered barrier during its hydration phase under real repository conditions. The hydro-mechanical and thermo-hydraulic models developed in this project have been coupled to describe stress/strain behaviour, moisture migration and heat transfer. A thermo-hydraulic model has also been coupled to a geochemical code to describe the migration and formation of chemical species. In this project, suction-controlled experiments have been performed on Boom clay (B), FoCa clay (Fr) and Almeria bentonite (Sp). The aim of these experiments is to test the validity of the interpretive model developed by Alonso and Gens (Alonso et al., 1990), and to build a database of unsaturated clay thermo-hydro-mechanical parameters. Such a database can then be used for validation exercises in which in situ experiments are simulated. The Boom clay is a moderately swelling clay of Rupellian age. It is studied at the SCK · CEN in Belgium as a potential host rock for a radioactive waste repository. In this paper, suction-controlled experiments carried out on Boom clay by SCK · CEN are described. SCK · CEN has performed experiments to measure the relation between suction, water content and temperature and the relation between suction, stress and deformation. The applied suction-control techniques and experimental setups are detailed. The results of these experiments are discussed in the perspective of the model of Alonso and Gens. The influence of temperature on water uptake was rather small. The measured swelling-collapse behaviour can be explained by the Alonso and Gens model. 相似文献
2.
Sorption results obtained with Boom clay for Am, Pu, Eu, Tc and Np under near in-situ conditions are presented, and the significance of Kd values in Boom clay is discussed. Clay humic acids are shown to be a controlling factor in the sorption of Am, Eu, Np. Results with Tc and Pu are different and need further examination. Experiments to determine the mobility of light molecular weight organic material in compacted Boom clay is discussed. 相似文献
3.
Boom Clay is extensively studied as a potential candidate to host underground nuclear waste disposal in Belgium. To guarantee the safety of such a disposal, the mechanical behaviour of the clay during gallery excavation must be properly predicted. In that purpose, a hollow cylinder experiment on Boom Clay has been designed to reproduce, in a small-scale test, the Excavation Damaged Zone (EDZ) as experienced during the excavation of a disposal gallery in the underground. In this article, the focus is made on the hydro-mechanical constitutive interpretation of the displacement (experimentally obtained by medium resolution X-ray tomography scanning). The coupled hydro-mechanical response of Boom Clay in this experiment is addressed through finite element computations with a constitutive model including strain hardening/softening, elastic and plastic cross-anisotropy and a regularization method for the modelling of strain localization processes. The obtained results evidence the directional dependency of the mechanical response of the clay. The softening behaviour induces transient strain localization processes, addressed through a hydro-mechanical second grade model. The shape of the obtained damaged zone is clearly affected by the anisotropy of the materials, evidencing an eye-shaped EDZ. The modelling results agree with experiments not only qualitatively (in terms of the shape of the induced damaged zone), but also quantitatively (for the obtained displacement in three particular radial directions). 相似文献
4.
The ATLAS III small scale in situ heating test aimed at assessing the thermo-hydro-mechanical (THM) effects on the Boom clay of the significant temperature gradients generated in this host rock as a consequence of the geological disposal of radioactive, heat-emitting wastes. This paper presents data on temperature, pore water pressure and total stress measured during the experiment and highlights several interesting observations regarding the thermal anisotropy and THM coupling in the Boom clay. The test has a simple geometry and well defined boundary conditions, which facilitates the comparison between measurement and numerical modeling studies. These studies included three dimensional coupled THM modeling of the test. The good agreement between measurement and numerical modeling of temperature and pore water pressure yields a set of THM parameters and confirms the thermo-mechanical anisotropy of the Boom clay. 相似文献
5.
Around galleries excavated at depth in geological media, the creation of a damaged zone with significant irreversible deformation is generally unavoidable. In the case of a geological disposal system for high-level radioactive waste, the resulting change in the host rock properties in this damaged zone may potentially be important with respect to the long-term evolution and the performance of that system. In this context, predicting the extent of the so-called Excavation Damaged Zone (EDZ) and, possibly, the fractures’ network topology remains a challenge. This study is aimed to simulate numerically the extension of this zone at the large scale’s excavation, around the Connecting gallery (HADES URL, Mol, Belgium), in Boom clay host rock through analyzing the evolution of strain localization in shear bands mode. To realistically model the involved phenomena, the concrete lining is considered on the gallery wall highlighting its impacts on the evolution of convergence and EDZ around the gallery. The focus of the current paper is made on analyzing the coupled hydro-mechanical behavior of Boom clay host rock during and after the gallery excavation with respect to the evolution of localized shear bands around the gallery. This study is accompanied by the analysis of the contact mechanism on the interface between the clay massive and the lining. The obtained results reveal some interesting features regarding the contact phenomenon relatively to the evolution pattern of shear bands within the clay around the gallery. To assess the reliability of the proposed approach, a discussion on some in-situ observations during the gallery’s construction is also performed based on which a good agreement is found between the in-situ evidence and simulated results. 相似文献
6.
Belgium is considering a clay formation as a possible disposal medium for the storage of conditioned radioactive waste.The clay rheology at great depth is studied by laboratory tests and in situ experiments performed from an underground laboratory build at 223 m depth in the Boom clay formation present in the N-E part of Belgium under the nuclear site Mol-Dessel. The aim of this research consists in simulating the excavation, in unfrozen clay, of large diameter galleries to be dug for the final disposal site.A finite element program using Vyalov's creep law was chosen as a first approach. The determination of the rheological parameters was made on the basis of the available laboratory experiments. Different numerical simulations were performed in order to reproduce in situ experiments, making possible a first refinement of the parameters.A shaft and gallery excavation are now being simulated, and numerical displacements will be compared to experimental observations. 相似文献
7.
For the disposal of high-level waste (HLW) in a deep geological formation as Boom Clay, safety assessment studies have shown that long lived 79Se is one of the more critical fission products. Therefore, the knowledge of its migration properties (diffusion, retention) through the geological barrier (Boom Clay) is of paramount importance. The migration behaviour of selenium strongly depends on its speciation. Under reducing conditions, selenide would be the dominant species and selenium migration would mainly be controlled by the low solubility of Se(−II)-bearing minerals. However Se species are often found in redox disequilibrium and more oxidized species might also coexist. Therefore, the study of selenate migration requires attention, as it might be the most mobile selenium species in the host rock. Electromigration experiments performed with a 75Se-labeled selenate in Boom Clay indicate a high mobility for this species. The apparent diffusion coefficient ( Dapp) of selenate in Boom Clay is estimated from electromigration experiments performed under different electric fields. Using two independent approaches, the value of Dapp for selenate is shown to fall in the range from 1.7×10 −11 to 6.2×10 −11 m 2 s −1. Moreover, no reduction of selenate in Boom Clay was observed. 相似文献
8.
The water retention capacity of geomaterials, and especially clayey soils, is sensitive to temperature changes as the physical mechanisms of retention, such as capillarity or adsorption, are affected by it. It is therefore a major issue to be able to define temperature-dependent behaviour of materials, especially for geo-energy and geo-environmental applications involving non-isothermal conditions. This paper presents results of experiments conducted on two representative materials: a hard clay (Opalinus clay) and a plastic clay (Boom clay), both of which have been considered as buffer materials for underground radioactive waste disposal, in Switzerland and Belgium, respectively. Two new devices were developed for this purpose to permit the analysis of water retention behaviour at different temperatures. The behaviour of these two materials at ambient (20 °C) and high temperature (80 °C) was observed and described through the evolution of the degree of saturation, the water content and the void ratio with respect to suction. It appears that the retention capability of the clays reduces significantly with an increase in temperature; on the other hand, the change in temperature had less of an effect on the total volume variation. 相似文献
9.
Deep low-permeability clay layers are considered as suitable environments for disposal of high-level radioactive waste. In Belgium, the Boom Clay is the reference host formation and the Ypresian Clay an alternative host formation for research and safety and feasibility assessment of deep disposal of nuclear waste. In this study, two hydrogeological models are built to calculate the radionuclide fluxes that would migrate from a potential repository through these two clay formations. Transport parameter heterogeneity is incorporated in the models using geostatistical co-simulations of hydraulic conductivity, diffusion coefficient and diffusion accessible porosity. The calculated radionuclide fluxes in the two clay formations are compared. The results show that in the Ypresian Clay larger differences between the fluxes through the lower and the upper clay boundary occur, larger total output radionuclide amounts are calculated and a larger effect of parameter heterogeneity on the calculated fluxes is observed, compared to the Boom Clay. 相似文献
10.
The Boom Clay formation (Oligocene) is studied as a reference host rock for methodological studies on deep geological disposal of radioactive waste. During excavation of galleries within the Clay formation (HADES underground research facility, Mol, Belgium), the physico-chemical conditions are significantly modified as an air–clay interface is created. In order to study the long-term impact of the air–clay contact on the organic matter contained in the Boom Clay, two types of samples were studied: (1) a reference series of clay samples having been in contact with the atmosphere of the HADES gallery for increasing times up to several years and (2) unaltered clay samples submitted to artificial oxidation in a ventilated oven at 80 °C. The evolution of geochemical data of the two series was compared using Rock-Eval pyrolysis, GC–MS and size exclusion chromatography. The organic matter of the unaltered clays sampled in the HADES galleries is dominated by type III kerogen (terrestrial) with some contribution of type II (marine) and is thermally immature. The evolution of geochemical parameters during air alteration for the two series are very similar. They show progressive oxidation of kerogen accompanied by the release of bitumen enriched in low molecular weight constituents. Molecular analysis evidences the presence of a complex mixture of aliphatic and aromatic O-bearing compounds, inherited from the degradation of kerogen as well as from the clay catalyzed oxidation of the bitumen. These results show that (1) air oxidation is a major process in the in situ alteration of the organic matter of Boom Clay within the HADES galleries, (2) laboratory oxidation experiments at 80 °C yield similar results as in situ air alteration of Boom Clay and (3) artificial air oxidation may be used to assess the long term exposure of the organic matter to air. 相似文献
11.
Summary The mechanical behaviour of reconstituted normally consolidated Boom clay was examined in a series of laboratory triaxial stress path tests. The aim was to establish some basic characteristics of this soil. The compressibility of the reconstituted Boom clay was found to be moderate, corresponding to the soils of the same plasticity. The results indicated also that the destructured Boom clay exhibited a brittle behaviour. The undrained secant stiffness was found to vary with strain level and also to be dependent on the consolidation pressure. 相似文献
12.
Boom Clay is currently viewed as a reference host formation for studies on deep geological disposal of radioactive waste in Belgium. The interactions between bulk rock Boom Clay and 0.1 M KOH, 0.1 M NaOH, 0.1 M Ca(OH) 2, young cement water and evolved cement water solutions, ranging in pH from 12.5 to 13.2, were examined as static batch experiments at 60 °C to simulate alkaline plume perturbations, which are expected to occur in the repository due to the presence of concrete. Both liquids and solids were investigated at specific times between 90 and 510 days in order to control the elemental budget and to search for potential mineralogical alterations. Also, the clay fraction was separated from the whole-rock Boom Clay at the end of each run and characterized for its mineralogical composition. Thereby, the importance of the mineral matrix to buffer the alkaline attack and the role of organic matter to protect clay minerals were also addressed. The results indicate that the degree of geochemical perturbation in Boom Clay is dependent on the initial pH of the applied solution together with the nature of the major cation in the reactant fluids. The higher the initial pH of the media, the stronger its interaction with Boom Clay. No major non-clay mineralogical alteration of the Boom Clay was detected, but dissolution of kaolinite, smectite and illite occurred within the studied experimental conditions. The dissolution of clays is accompanied by the decrease in the layer charge, followed by a decrease in the cation-exchange capacity. The highest TOC values coincide with the highest total elemental concentrations in the leachates, and correspondingly, the highest dissolution degree. However, no quantitative link could be established between the degree of organic matter decomposition and clay dissolution. 相似文献
13.
In the context of nuclear waste disposal in clay formations, laboratory experiments were performed to study at reduced scale the excavation damaged zone (EDZ) induced by the construction of galleries in the Boom clay formation. For this purpose, thick-walled hollow cylindrical samples were subjected (after recovery of in situ stress conditions) to a decrease in the inner confining pressure aiming at mimicking a gallery excavation. X-ray computed tomography (XRCT) scans of the specimens were carried out through the testing cell before and after the mechanical unloading and allowed to quantify the displacements undergone by the clay as a result of the mechanical unloading. The deformation of the hollow cylinders and the inferred extent of the damaged zone around the central hole are found to depend on the orientation of the specimen with respect to the bedding planes and show a great similarity with in situ observations around galleries and boreholes at Mol URL in the Boom clay formation. In the experiments performed on samples cored parallel to the bedding, the damaged zone is not symmetrical with respect to the hole axis and extends more in the direction parallel to the bedding. It is the same for the radial convergence of the hole walls which is larger in the direction parallel to bedding than in the perpendicular one. In contrast, a test on a sample cored perpendicularly to the bedding did not show any ovalisation of the central hole after the mechanical unloading. These observations confirm the significance of the pre-existing planes of weakness (bedding planes) in Boom clay and the need for a correct consideration of the related mechanical anisotropy. 相似文献
14.
在连续损伤力学理论基础上,将塑性损伤演化及渗流相互耦合的概念引入Mohr-Coulomb 破坏准则,用于分析在孔隙压力和塑性损伤演化共同作用下岩石损伤演化机制,建立了相应的有限元损伤数值分析模型,并应用于比利时核废料库开挖过程中泥岩隧道附近围岩发生损伤演化、渗流场和应力场耦合过程分析中,得到了开挖引起的围岩损伤特性、孔隙压力以及渗透性的变化规律,为进一步研究隧道流变过程水力耦合特性合理的数值计算模型建立方法提供基础。 相似文献
15.
In 1989 a small-scale exercise conducted by the CEC as part of its research programme into the underground storage of radioactive waste highlighted the difficulty of making accurate predictions a priori, of the geomechanical behaviour of clay. Given source data about the Boom clay from the underground research facility at Mol, three organisations independently performed f.e. analyses of two somewhat hypothetical problems. While the results were very broadly in agreement, they were shown to be sensitive to both the type of constitutive model used and the way data was fitted to the model. Subsequently, the CEC sponsored a more comprehensive benchmark exercise called INTERCLAY II. This involves eleven organisations from various member states of the EC in a project encompassing the three aspects of software development for predictive modelling: verification, validation on the laboratory scale and the treatment of in-situ tests. The paper briefly describes the exercise currently in progress and presents the main results achieved to date concentrating on validation aspects. 相似文献
16.
BACCHUS2 in situ isothermal wetting experiment has been analysed by means of a coupled flow-deformation approach. Backfill material, a mixture of Boom clay powder and high density pellets, has been extensively tested in the laboratory in order to determine its hydraulic and mechanical properties. Parameters of constitutive equations were derived from this experimental data base. Two mechanical constitutive models have been used in the simulation of the ‘ in situ’ experiment: a state surface approach and an elastoplastic model. Calculations have shown several features of the hydration process which help to understand the behaviour of expansive clay barriers. Predictions using both models have been compared with each other and with actual measurement records. This has allowed a discussion of the comparative mertis of both approaches and the identification of some critical parameters of backfill behaviour. Overall agreement between calculations and field measurements is encouraging and shows the potential of the methods developed to model the behaviour of engineered clay barriers in the context of nuclear waste disposal. © 1998 by John Wiley & Sons, Ltd. 相似文献
17.
Deep low-permeability clay layers are considered as safe environments for disposal of high-level radioactive waste. In Belgium,
the Boom Clay is a candidate host rock for deep geological disposal. In this study, we analyze the effects of fractures and
spatially variable hydraulic conductivity on radionuclide migration through the clay. Fracture geometry and properties are
simulated with Monte Carlo simulation. The heterogeneity of hydraulic conductivity is simulated by direct sequential co-simulation
using measurements of hydraulic conductivity and four types of secondary variables. The hydraulic conductivity and fracture
simulations are used as input for a transport model. Radionuclide fluxes computed with this heterogeneous model are compared
with fluxes obtained with a homogeneous model. The output fluxes of the heterogeneous model differ at most 8% from the homogeneous
model. The main safety function of the Boom Clay is thus not affected by the fractures and the spatial variability of hydraulic
conductivity. 相似文献
18.
The Canadian Nuclear Fuel Waste Management Program (CNFWMP) is evaluating the concept of disposal of nuclear fuel waste in an engineerted vault at a depth of 500 to 1000 m in the plutonic rock of the Canadian Shield. In common with engineered barrier system designs being developed in other countries, the waste would be contained within durable containers that, in turn, would be isolated from the host rock by clay-based materials. The objective of the CNFWMP is to develop a disposal concept that will protect human health and the natural environment far into the future. Assessments of the conceptual vault designs are based on system theory in which an attempt is made to correlate experiences with theoretical concepts of planned systems in such a way that the resulting coordination is sound and convincing. By necessity, since experiments with a total disposal system can never be performed, both the design and the performance assessment rely on experiments performed on physical models of vault elements over relatively short times and on information inferred from calculations (mathematical models) that simulate the probable behaviour of the system in the space-time domainof interest. For a simulation model to be successful, that is applied within a real world situation, the model must provide information regarding the behaviour of the system of interest that is clearly better, in some way, than the mental image or other abstract model that would be used instead. The results of a series of tests performed within the activity known as validation serve as tangible evidence regarding the success of a model in representing the system of interest. This paper focusses on the validation of the models that describe the hygro-thermo-mechanical behaviour of the engineered clay-barriers proposed for application in the Canadian disposal system concept. The strategy being used to address the key issues in modelling to minimize the model error and to maximize the usefulness of the simulation model, based on testing procedures, is reviewed. Finally, a concept of the validation of codes/models that describe the unsaturated behaviour of engineered clay barriers, is described. 相似文献
19.
SKB (Svensk Kärnbränslehantering AB) is responsible for all handling, transport and storage of the nuclear wastes outside the Swedish nuclear power stations. According to Swedish law, SKB is responsible for an R&D-programme needed to take care of the radwastes. The programme comprises, among others, a general supportive geo-scientific R&D and the Äspö Hard Rock Laboratory (HRL) for more in-situ specific tasks. Sweden is geologically located in the Fennoscandian shield which is dominated by gneisses and granitoids of Precambrian age. The Swedish reference repository concept thus considers an excavated vault at ca. 500 m depth in crystalline rocks. In this concept (KBS-3), copper canisters with high level waste will be emplaced in deposition holes from a system of tunnels. Blocks of highly compacted swelling bentonite clay are placed in the holes leaving ample space for the canisters. At the final closure of the repository, the galleries are backfilled with a mixture of sand and bentonite. This repository design aims to make the disposal system as redundant as possible. Although the KBS-3 concept is the reference concept, alternative concepts and/or repository lay-outs are also studied. The main alternative, currently under development at SKB, is disposal in boreholes with depths of 4–5 km. The geoscientific research will to a great extent be guided by the demands posed by the performance and safety assessments, as well as the constuctability issues. Some main functions of the geological barrier are fundamental for the long-term safety of a repository. These are: bedrock mechanical stability, a chemically stable environment as well as a slow and stable groundwater flux. The main time-table for the final disposal of long-lived radioactive waste in Sweden foresees the final selection of the disposal system and site during the beginning of next decade. 相似文献
20.
Interstitial water from the Boom clay Formation around the HADES (high activity disposal experimental site, an underground research facility belonging to the Nuclear research centre, SCK·CEN, at Mol-Dessel, Belgium.) underground research facility at Mol, Belgium, and waters sampled at different locations in the Rupelian aquifer, underlying the clay formation, have been studied. The Boom clay is a Tertiary mudrock containing about 55 % clay and the Rupelian aquifer is located in a silty layer. Special care was taken to adapt or improve measurement, sampling, conservation and analysis methods to get a reliable regional and local database, for the purpose of testing a general model describing the regulation and acquisition of the composition of these fluids. The isotopic and chemical composition of the waters allows them to be assigned to a common origin, namely mixing between a marine endmember and the clay interstitial water, followed by reequilibration with the host rock through dissolution–precipitation reactions involving identified secondary minerals. Oxidation–reduction state and trace element behavior are also discussed and the limits of the model are outlined. 相似文献
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