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1.
Pseudotachylite veins have been found in the mylonite zone of the Hidaka metamorphic belt, Hokkaido, northern Japan. They are associated with faults with WNW-ESE to ENE-WSW or NE-SW trends which make a conjugate set, cutting foliations of the host mylonitic rocks with high obliquity. The mylonitic rocks comprise greenschist facies to prehnite-pumpellyite facies mineral assemblages. The mode of occurrence of the pseudotachylite veins indicates that they were generated on surfaces of the faults and were intruded as injection veins along microfractures in the host rocks during brittle deformation in near-surface environments. An analysis of the deformational and metamorphic history of the Hidaka Main Zone suggests that the ambient rock temperature was 200–300° C immediately before the formation of the Hidaka pseudotachylite. Three textural types of veins are distinguished: cryptocrystalline, microcrystalline and glassy. The cryptocrystalline or glassy type often occupies the marginal zones of the microcrystalline-type veins. The microcrystalline type is largely made up of quench microlites of orthopyroxene, clinopyroxene, biotite, plagioclase and opaque minerals with small amounts of amphibole microlites. The interstices of these microlites are occupied by glassy and/or cryptocrystalline materials. The presence of microlites and glasses in the pseudotachylite veins suggests that the pseudotachylites are the products of rapid cooling of silicate melts at depths of less than 5 km. The bulk chemical composition of the pseudotachylite veins is characterized by low SiO2 and a high water content and is very close to that of the host mylonitic rocks. This indicates that the pseudotachylite was formed by virtual total melting of the host rocks with sufficient hydrous mineral phases. Local chemical variation in the glassy parts of the pseudotachylite veins may be due to either crystallization of quench microlites or the disequilibrium nature of melting of mineral fragments and incomplete mixing of the melts. Pyroxene microlites show a crystallization trend from hypersthene through pigeonite to subcalcic augite with unusually high Al contents. The presence of pigeonite and high-Al pyroxene microlites, of hornblende and biotite microlites and rare plagioclase microlites may indicate the high temperature and high water content of the melt which formed the pseudotachylite veins. The melt temperatures were estimated to be up to 1100° C using a two-pyroxene geothermometer. Using published data relating water solubilities in high-temperature andesitic magmas to pressure, a depth estimate of about 4 km is inferred for the Hidaka pseudotachylites. Evidence derived from pseudotachylites in the Hidaka metamorphic belt supports the conclusion that pseudotachylite is formed by frictional melting along fault surfaces at shallow depths from rocks containing hydrous minerals.  相似文献   

2.
Pseudotachylites occur in the form of thin glassy veins quenched from frictional melts along the fault planes of major earthquakes. They contain finely grained magnetite and often exhibit a high natural remanent magnetization (NRM). High NRM values imply strong local electric currents. These currents must persist for some time, while the pseudotachylite veins cool through the Curie temperature of magnetite around 580 °C. There is no generally accepted theory explaining how such powerful, persistent currents may be generated along the fault plane. Data presented here suggest the activation of electronic charge carriers, which are present in igneous rocks in a dormant, inactive form. These charge carriers can be “awakened” by the application of stress. They are electrons and defect electrons, also known as positive holes or p-holes for short. While p-holes are capable of spreading out of the stressed rock volume into adjacent p-type conductive unstressed rocks, electrons require a connection to the hot, n-type conductive lower crust. However, as long as the (downward) electron flow is not connected, the circuit is not closed. Hence, with the outflow of p-holes impeded, no current can be sustained. This situation is comparable to that of a charged battery where one pole remains unconnected. The friction melt that forms coseismically during rupture, provides a conductive path downward, which closes the circuit. This allows a current to flow along the fault plane. Extrapolating from laboratory data, every km3 of stressed igneous rocks adjacent to the fault plane can deliver 103–105 A. Hence, the current along the fault plane will not be limited by the number of charge carriers but more likely by the (electronic) conductivity of the cooling pseudotachylite vein. The sheet current will produce a magnetic field, whose vectors will lie in the fault plane and perpendicular to the flow direction.  相似文献   

3.
大别造山带东部假玄武玻璃的显微构造特征及其意义   总被引:2,自引:0,他引:2  
最近,在大别造山带东部发现了广泛的地震成因假玄武玻璃,这些假玄武玻璃主要呈简单脉状沿NE-SW向走滑断裂带或剪切带发育,后者大多与郯庐断裂带平行并穿切了包括白垩纪花岗岩在内的地质体。某些假玄武玻璃内发育由暗色石英条纹构成的糜棱质条带。本文通过普通光学显微镜和扫描电镜观察分析,详细研究对比了不同断裂带内部发育的假玄武玻璃及其围岩在显微构造特征上的差异及联系。根据岩石的组构特征,证实所发现的这些假玄武玻璃主要是由母岩的超碎裂岩化形成的,但在点1发育的假玄武玻璃基质的扫描电镜影象特征上,沿某些残斑矿物(钾长石、斜长石、黄铁矿)的边缘可以看到些许代表摩擦熔融成因的熔蚀状港湾结构,说明假玄武玻璃形成过程中曾经发生了程度较低的局部熔融作用。肉眼所见到的糜棱质石英条纹在显微镜下证实为早期的糜棱面理。同时,岩石组构的叠加显示,含假玄武玻璃的断裂带及假玄武玻璃本身普遍具有多期性,且晚期构造产物(或假玄武玻璃)总是较早期产物(或假玄武玻璃)碎裂岩化作用更加强烈,说明先期存在的构造软化带在控制假玄武玻璃形成过程中起着非常重要的作用,即构造带抬升过程中伴随的多期构造及细粒化是形成假玄武玻璃的基础。岩石的变形序列总体上显示为韧性-韧脆性-脆性的演化过程,从而证实了这些假玄武玻璃总体上形成于造山带抬升过程,而不是早期的俯冲过程。  相似文献   

4.
Metapelitic country rocks were contact- and pyro-metamorphosed by the Tertiary Skaergaard Intrusion, East Greenland. In an initial stage of heating, while they were probably still in place within the host rock contact aureole, they overstepped a range of equilibrium and disequilibrium melting reactions and produced both a granitic melt and very refractory spinel+cordierite+plagioclase±corundum residuals. Parts of these refractory rocks were then subjected to another melting event after being entrained as xenoliths into the Skaergaard Marginal Border Group, where they experienced a temperature of about 1,000°C at a pressure of about 650 bars and at an oxygen fugacity about 0.2–0.5 log units below the FMQ buffer. Here, they underwent bulk melting, but did not mix with the Skaergaard magma, presumably because of the high viscosity contrast. The Al-rich melts crystallized to an assemblage of corundum+mullite+sillimanite+ plagioclase+spinel+rutile±tridymite±cordierite and they reacted with the surrounding basalt producing a strongly cryptically zoned rim of plagioclase (An55 close to the basalt to An90 close to the Al-rich melt). The assemblage in the inner parts of the xenoliths provides textural evidence for disequilibrium growth due to slow diffusivities in the highly viscous, probably water-free Al-rich melt. Later interaction of lower temperature ferrobasaltic to granophyric melts with the xenoliths along their margins and along cracks led to consumption of corundum and mullite and to the stable assemblage of spinel+cordierite+plagioclase+quartz+K-feldspar +magnetite+ilmenite at about 800°C.  相似文献   

5.
Cordierite–quartz and plagioclase–quartz intergrowths in a paragneiss from northern Labrador (the Tasiuyak Gneiss) were studied using SEM, STEM and TEM. The gneiss experienced granulite facies conditions and partial melting during both regional and, subsequently, during contact metamorphism. The microstructures examined all results from the contact metamorphism. Cordierite–quartz intergrowths occur on coarse and fine scales. The former sometimes exist as a ‘geometric’ intergrowth in which the interface between cordierite and quartz appears planar at the resolution of the optical microscope and SEM. The latter exists in several microstructural variants. Plagioclase is present as a minor component of the intergrowth in some examples of both the coarse and fine intergrowth. Grain boundaries in cordierite–quartz intergrowths are occupied by amorphous material or a mixture of amorphous material and chlorite. Cordierite and quartz are terminated by crystal faces in contact with amorphous material. Chlorite is sometimes found on cordierite surfaces and penetrating into cordierite grains along defects. Quartz contains (former) fluid inclusions 10–20 nm in maximum dimension. The presence of planar interfaces between cordierite and the amorphous phase is reminiscent of those between crystals and glass in volcanic rocks, but in the absence of compelling evidence that the amorphous material represents former melt, it is interpreted as a reaction product of cordierite. Plagioclase–quartz intergrowths occur in a number of microstructural variants and are commonly associated with cordierite–quartz intergrowths. The plagioclase–quartz intergrowths display simple, non‐planar interfaces between plagioclase and quartz. Quartz contains (former) fluid inclusions of dimensions similar to those observed in cordierite–quartz intergrowths. The boundary between quartz and enclosing K‐feldspar is cuspate, with quartz cusps penetrating a few tens of nanometres into K‐feldspar, commonly along defects in K‐feldspar and sometimes with very low dihedral angles at their tips. This cuspate microstructure is interpreted as melt pseudomorphs. The plagioclase–quartz intergrowths share some features with myrmekite, but differ in some respects: the composition of the plagioclase (An37Ab62Or1–An38Ab61Or1); the association with cordierite–quartz intergrowths; and microstructures that are atypical of myrmekite (e.g. quartz vermicules shared with cordierite–quartz intergrowths). It is inferred that the plagioclase–quartz intergrowths may have formed from, or in the presence of, melt. Inferred melt‐related microstructures preserved on the nanometre scale suggest that melt on grain boundaries was more pervasive than is evident from light optical and SEM observations.  相似文献   

6.
The textures and kinetics of reaction between plagioclase and melts have been investigated experimentally, and origin of dusty plagioclase in andesites has been discussed. In the experiments plagioclase of different compositions (An96, An61, An54, An23, and An22) surrounded by glasses of six different compositions in the system diopside-albite-anorthite was heated at temperatures ranging from 1,200 to 1,410° C for 30 min to 88 h. Textures were closely related to temperature and chemical compositions. A crystal became smaller and rounded above the plagioclase liquidus temperature of the starting melt (glass) and remained its original euhedral shape below the liquidus. Whatever the temperature, the crystal-melt interface became rough and often more complicated (sieve-like texture composed of plagioclase-melt mixture in the scale of a few m was developed from the surface of the crystal inward; formation of mantled plagioclase) if the crystal is less calcic than the plagioclase in equilibrium with the surrounding melt, and the interface remained smooth if the crystal is more calcic than the equilibrium plagioclase. From these results the following two types of dissolution have been recognized; (1) a crystal simply dissolves in the melt which is undersaturated with respect to the phase (simple dissolution), and a crystal is partially dissolved to form mantled plagioclase by reaction between sodic plagioclase and calcic melt (partial dissolution). The amount of a crystal dissolved and reacted increased proportional to the square root of time. This suggests that these processes are controlled by diffusion, probably in the crystal.Mantled plagioclase produced in the experiments were very similar both texturally and chemically to some of the so-called resorbed plagioclase in igneous rocks. Chemical compositions and textures of plagioclase phenocrysts in island-arc andesites of magma mixing origin have been examined. Cores of clear and dusty plagioclase were clacic (about An90) and sodic (about An50), respectively. This result indicates that dusty plagioclases were formed by the partial melting due to reaction between sodic plagioclase already precipitated in a dacitic magma and a melt of intermediate composition in a mixed magma during the magma mixing.  相似文献   

7.
The Were Ilu ignimbrites are unlike other Oligocene rhyolites from the Ethiopian continental flood basalt province, in that they consist of plagioclase (An19–54), augite, pigeonite and Ti-magnetite, instead of anorthoclase, sodic sanidine, aegirine-augite and ilmenite. The minerals occur as (micro-)phenocrysts isolated within a glassy matrix or forming gabbroic and dioritic cumulophyric clots. Plagioclase is partially re-melted (sieve-textures with infilling glass). It is zoned with sudden changes in composition. However, the bulk zoning is normal with An-rich core (An45–54) and more sodic rim (An19–28). Ba and Sr concentration profiles of two plagioclase phenocrysts show a bulk rimward increase with compositions ranging from 250 ppm to 1,060 ppm and from 400 ppm to 1,590 ppm, respectively. The matrix glass has low CaO content (0.1–0.5 wt.%), a peralkalinity index of 0.79–1.04 and average Sr and Ba contents of 48±22 and 525±129 ppm, respectively. Geochemical modelling of Ba and Sr zoning profiles of plagioclase, based on experimental constraints, suggests that the cumulophyric clots can be derived from fractional crystallisation associated with limited assimilation (8 wt.%) from melts slightly less evolved than their rhyolitic matrix glass. These clots are not witnesses of intermediate magmas allowing the Daly Gap to be filled, but are cumulates differentiated from rhyodacitic melt. This indicates that parental magmas were stored in crustal magma chambers where they differentiated before being erupted at the surface.  相似文献   

8.
Different processes have been proposed to explain the variety of igneous layering in plutonic rocks. To constrain the mechanisms of emplacement and crystallization of ascending magma batches in shallow plutons, we have studied comb layers and orbicules from the Fisher Lake Pluton, Northern Sierra Nevada. Through a detailed study of the mineralogy and bulk chemistry of 70 individual layers, we show that comb layers and orbicule rims show no evidence of forming through a self-organizing, oscillatory crystallization process, but represent crystallization fronts resulting from in situ crystallization and extraction of evolved melt fractions during decompression-driven crystallization, forming a plagioclase-dominated cres-cumulate at the mm- to m-scale. We propose that the crystal content of the melt and the dynamics of the magmatic system control the mechanisms responsible for vertical igneous layering in shallow reservoirs. As comb layers crystallize on wall rocks, the higher thermal gradients will increase the diversity of comb layering, expressed by inefficient melt extraction, thereby forming amphibole comb layers and trapped apatite + quartz saturated evolved melt fractions. High-An plagioclase (An90–An97.5) is a widespread phase in Fisher lake comb layers and orbicule rims. We show that a combination of cooling rate, latent heat of crystallization and pressure variations may account for high-An plagioclase in shallow melt extraction zones.  相似文献   

9.
Partial melting experiments on plagioclase (An60) and diopside have been carried out using pairs of large crystals to investigate textures and kinetics of melting. The experiments were done at one atmosphere pressure as a function of temperature (1,190–1,307° C) and time (1.5–192 h). Melting took place mainly at the plagioclase-diopside contact planes. Reaction zones composed of fine mixtures of calcic plagioclase and melt were developed from the surface of the plagioclase crystal inward. There exists a critical temperature, below which only a few % melting can occur over the duration of the experiments. This sluggish melting is caused by slow NaSi-CaAl diffusion in plagioclase, because the plagioclase crystal must change its composition to produce albite-rich cotectic melts. Diffusion in the solid also affects the chemical composition of the melts. During initial melting, potassium is preferentially extracted from plagioclase because K-Na diffusion in plagioclase is faster than that of NaSi-CaAl. This also causes a shift in the cotectic compositions. Above the critical temperature, on the other hand, melting is promoted by a metastable reaction in which the plagioclase composition does not change, and which produces melts with compositional gradients along the original An60-diopside tie line. The critical temperature is determined by the intersection of the cotectic and the An60-diopside tie line. Interdiffusion coefficients of plagioclase-diopside components in the melt are estimated from melting rates above the critical temperature by using a simplified steady-state diffusion model (e.g., 10–8 cm2/sec at 1,300° C).Many examples of reaction zones due to partial melting have been described as spongy or fingerprint-like textures in xenoliths. Metastable melting above the critical temperature is considered to take place in natural melting where there is a high degree of melting. However, we cannot exclude the possibility of disequilibrium created by sluggish melting controlled by diffusion in the minerals. If melting occurs close to the solidus, this process can be important even for partial melting in the upper mantle.  相似文献   

10.
Crystal-rich materials (scoriae and lava flows) emitted during the 1985–2000 activity of Stromboli were taken into consideration for systematic study of bulk rock/matrix glass chemistry and in particular for the study of chemical and textural zoning of plagioclase, the most abundant mineral phase. Over the considered time period, bulk rock composition remained fairly constant in both major (SiO2 49.2–50.9 wt% and K2O 1.96–2.18 wt%) and trace elements. The quite constant chemistry of matrix glasses also indicates that the degree of crystallization of magma was maintained at around 50 vol%. Plagioclase ranges in composition between An62 and An88 and is characterized by alternating, <10–100 m thick, bytownitic and labradoritic concentric layers, although the dominant and representative plagioclase of scoriae is An68. The labradoritic layers (An62–70) show small-scale (1–5 µm), oscillatory zoning, are free of inclusions, and appear to record episodes of slow crystal growth in equilibrium with a degassed liquid having the composition of the matrix glass. In contrast the bytownitic layers (An70-An88) are patchy zoned, show sieve structure with abundant micrometric glass inclusions and voids, and are attributed to rapid crystal growth.A key to understanding the origin of bytownitic layers can be retrieved from the texture and composition of the coronas of plagioclase xenocrysts, inherited from crystal-rich magma, in nearly aphyric pumice which are erupted during more energetic events and represent a deep, volatile-rich, HK-basaltic magma. They show a continuum from fine-sieve to evident skeletal texture from the inner to the outer part of the corona associated with normal compositional zoning from An90 to An75. In the light of these observations, we propose that input of H2O-rich melt blobs, and their mixing with the residing magma, causes partial dissolution of the labradoritic layers followed by the growth of bytownitic composition whose sieve texture attests of rapid crystallization occurring under undercooling conditions mainly induced by degassing. As a whole, the zoning of plagioclase in the scoriae records successive and discrete intrusions of volatile-rich magma blobs, its degassing and mixing with the resident degassed magma at shallow level.Editorial responsibility: T.L. GroveAn erratum to this article can be found at  相似文献   

11.
Finely cellular plagioclase intergrowths have been studied in xenocrystic andesine (An32) and andesine mantled K-feldspars within mafic magmatic enclaves in a quartz-feldspar porphyry from the Proterozoic subvolcanic Hammarudda complex, Åland rapakivi batholith, SW Finland. The cellular intergrowths usually occur as 0.2–2.0 mm mantles around xenocrysts but also as entirely cellular grains, and are built up of a network of two distinct phases: one relatively Na-rich (An31) and one relatively Ca-rich (An50). The grains are also covered by a thin (0.08–0.12 mm), continuous, normally zoned rim outside the cellular mantle. Small inclusions (0.01–0.05 mm) of Fe–Mg minerals are concentrated in the Ca-rich part of the network. Compositionally, the Na-rich phase of the network is close to the inner non-cellular andesine of the xenocrysts. However, it has a lower Or- and a slightly lower An-content. The Ca-rich phase has the same composition as the inner part of the normally zoned rim, which outwards grades into lower An-contents that overlap the An-content of the matrix plagioclases. The cellular network was developed after the andesine xenocrysts (or andesine mantled K-feldspars) were engulfed in mafic magmatic enclaves during a mixing event. The xenocrysts became heated to a temperature just below the liquidus of the mafic magma. Dissolution of the xenocrysts developed a spongy cellular texture which was penetrated by enclave magma. Ca-rich plagioclase crystallized in the cells in equilibrium with the enclave magma, trapping Fe–Mg-rich melt. As the enclaves cooled the outermost thin rim and matrix plagioclases crystallized from the mafic melt. These processes operated in fairly large enclaves, as the one studied here, which has a diameter of 70cm. Smaller enclaves, on the other hand, were cooled more rapidly to temperatures close to the solidus of the enclave magma, and consequently had no time to dissolve the xenoxrysts.  相似文献   

12.
The very fine-grained (1 m) polygonal microcrystalline texture occurring in the groundmass of pseudotachylite veins in the Harris meta-anorthosite and its variation with position are described and an origin by crystallization from a melt at very large undercooling suggested. The intrusive nature of the veins is shown by their geometry and internal structures. Clasts, which are almost always only plagioclase, are generally concentrated towards the centres of veins. Flow of tens of millimetres can account for this concentration in millimetre-thick veins as a result of the Bagnold effect. The veins are generally thin (5 m to 5 mm or more), are frequently zoned and always contain transparent granules of high relief (probably Al-rich pyroxene) and opaque granules of magnetite up to a few micrometres in size. The granules are either uniformly distributed in microcrystalline textures or concentrated locally giving cellular textures. In some veins, spherulitic or bow-tie textures occur. The coarsest textures are found in the centres of the thickest veins. The groundmass of the pseudotachylite is never completely isotropic but consists of a mosaic of transparent plagioclase crystals decreasing in size from the centres of thick veins to less than 1 m in thin veins or in the margins of thicker veins. This fine microcrystalline texture was studied by both scanning and transmission electron microscopy and consists of polyhedral crystals of regular size in the range 0.2–1.5 m, which show little sign of deformation. The local composition of the pseudotachylites varies little from the average compositions of the rocks in optically homogeneous veins, the variation being within the compositional space defined by the minerals of the host rock. This shows that homogenization of the pseudotachylite has occurred. In cellular veinsdifferentiation has occurred as the compositions of the cell centres lie outside those of the minerals of the host rock. This was produced by segregation of the granules, pyroxene being absent from the host rock. The plagioclase in the pseudotachylite is more disordered than that in the host rock. All the microtextures described are absent from the associated cataclasites and cannot be due to recrystallization of a fine-grained and intensely strained rock powder. The physical state on and after intrusion was that of a melt and injection was followed by crystallization. The melt was produced by more or less total fusion of the host rock minerals at shallow depth by heat produced during local faulting and perhaps during crack propagation. The fine microcrystalline texture very closely resembles that produced during hypercooling of molten metals and alloys. It thus possibly formed not by devitrification but from a melt at much greater degrees of undercooling than the spherulitic and bow-tie textures.  相似文献   

13.
The gold mineralization of the Hutti Mine is hosted by nine parallel, N–S trending, steeply dipping, 2–10 m wide shear zones, that transect Archaean amphibolites. The shear zones were formed after peak metamorphism during retrograde ductile D2 shearing in the lower amphibolite facies. They were reactivated in the lower to mid greenschist facies by brittle–ductile D3 shearing and intense quartz veining. The development of a S2–S3 crenulation cleavage facilitates the discrimination between the two deformation events and contemporaneous alteration and gold mineralization. Ductile D2 shearing is associated with a pervasively developed distal chlorite–sericite alteration assemblage in the outer parts of the shear zones and the proximal biotite–plagioclase alteration in the center of the shear zones. D3 is characterized by development of the inner chlorite-K-feldspar alteration, which forms a centimeter-scale alteration halo surrounding the laminated quartz veins and replaces earlier biotite along S3. The average size of the laminated vein systems is 30–50 m along strike as well as down-dip and 2–6 m in width.Mass balance calculations suggest strong metasomatic changes for the proximal biotite–plagioclase alteration yielding mass and volume increase of ca. 16% and 12%, respectively. The calculated mass and volume changes of the distal chlorite–sericite alteration (ca. 11%, ca. 8%) are lower. The decrease in δ18O values of the whole rock from around 7.5‰ for the host rocks to 6–7‰ for the distal chlorite–sericite and the proximal biotite–plagioclase alteration and around 5‰ for the inner chlorite-K-feldspar alteration suggests hydrothermal alteration during two-stage deformation and fluid flow.The ductile D2 deformation in the lower amphibolite facies has provided grain scale porosities by microfracturing. The pervasive, steady-state fluid flow resulted in a disseminated style of gold–sulfide mineralization and a penetrative alteration of the host rocks. Alternating ductile and brittle D3 deformation during lower to mid greenschist facies conditions followed the fault-valve process. Ductile creep in the shear zones resulted in a low permeability environment leading to fluid pressure build-up. Strongly episodic fluid advection and mass transfer was controlled by repeated seismic fracturing during the formation of laminated quartz(-gold) veins. The limitation of quartz veins to the extent of earlier shear zones indicate the importance of pre-existing anisotropies for fault-valve action and economic gold mineralization.  相似文献   

14.
In the contact aureole of the Lilesville granite and comagmatic Pee Dee gabbro, N.C., greenschist-facies phyllites of the Carolina slate belt have been overprinted by a series of metamorphic reactions producing opx-bearing hornfelses and migmatitic gneisses. In the exterior aureole the slate belt assemblage (chl+ms+ep+ab+qz) gives way to the continuous reaction assemblages (chl+bt+cd+ ms+ab±ep+qz), (bt+cd+ms+An8–29+qz), (bt+cd+ kf+ms+pl+qz), (bt+cd+als±ms+kf+pl+qz), and (bt+cd+ga+kf+pl+qz), from lowest to highest grade. The interior aureole, interpreted as part of the floor of the granite, bears the continuous and discontinuous reaction assemblages (bt+cd+als+kf+pl+qz),(bt+cd+kf+ pl+qz), and, near the gabbro, (bt+cd+ga+opx+kf+ pl+qz). The leucosomes of the migmatitic interior aureole are predominantly trondhjemites with the assemblage (An35–45+qz±bt±cd±kf). Restites in the migmatitic interior aureole contain the AFM assemblages (bt), (bt + cd), (bt+cd+als), and (bt+cd+ga), plus kf, An40–50, and qz. Contact metamorphism was isobaric at 4.0–5.1 or 2.0–3.5 kb depending on choice of aluminosilicate triple point; temperatures reached 650° C in the migmatitic interior aureole and approached 750° C near the gabbro; was less than 0.8 in the migmatites, and was lower in the interior aureole and in the high grade exterior aureole. Partial melting in the migmatitic interior aureole took place during dynamothermal metamorphism caused by the magmatic diapir. Incipient melting occurred by the reaction bt+cd+kf+pl+qz+w = liquid. The melt was H2O-undersaturated and coefficients of the reactants were weighted heavily toward the felsic minerals; the proportion of felsic minerals in the leucosomes was controlled in part by modal abundance of kf, pl, and qz available for melting. The incorporation of K into biotite by subsolidus reactions, coupled with the high thermal stability and low solubility of biotite in a felsic melt, are responsible for the trondhjemitic composition of the early anatectic liquids.Abbreviations als Al2SiO5 - ab albite - An8–29 plagioclase with anorthite contents in the range indicated - bt biotite - cd cordierite - chl chlorite - ep epidote - ga garnet - kf K feldspar - ms muscovite - opx orthopyroxene - pl plagioclase undefined - qz quartz - w water  相似文献   

15.
Partition coefficients (DBemineral/melt) for beryllium between hydrous granitic melt and alkali feldspars, plagioclase feldspars, quartz, dark mica, and white mica were determined by experiment at 200 MPa H2O as a function of temperature (650-900°C), activity of Be in melt (trace levels to beryl saturation), bulk composition, and thermal run direction. At trace levels, Be is compatible in plagioclase of An31 (1.84 at 700°C) and muscovite (1.35 at 700°C) but incompatible in biotite (0.39-0.54 from 650-800°C), alkali feldspar (0.38-0.19 from 680-850°C), quartz (0.24 at 800°C), and albite (0.10 at 750°C). The partition coefficients are different at saturation of the melt in beryl: lower in the case of plagioclase of An31 (0.89 at 700°C), muscovite (0.87 at 700°C), biotite (0.18-0.08 from 675-800°C), alkali feldspar (0.18-0.14 from 680-700°C), and quartz (0.17-0.08 from 750-800°C), but higher in the case of albite (0.37 at 750°C).With other data sources, these new partition coefficients were utilized to track, first, the distribution of Be between aluminous quartzofeldspathic source rocks and their anatectic melts, and second, the dispersion or concentration of Be in melt through igneous crystal fractionation of different magma types (e.g., S-type, I-type) up to beryl-saturated granitic pegmatites and, finally, into their hydrothermal aureoles. Among the rock-forming minerals, cordierite, calcic oligoclase, and muscovite (in this order) control the fate of Be because of the compatibility of Be in these phases. In general, beryl-bearing pegmatites can arise only after extended crystal fractionation of large magma batches (to F, fraction of melt remaining, ≤0.05); granitic magmas that originate from cordierite-bearing protoliths or that contain large modal quantities of calcic oligoclase will not achieve beryl saturation at any point in their evolution.  相似文献   

16.
The melting of plagioclase and quartz has been investigated at P H2O =2kb. A single crystal of plagioclase was surrounded by quartz powder and water. A reaction rim consisting of glass and of An-rich plagioclase developed around unchanged starting plagioclase. Microprobe determinations of melt and coexisting plagioclase compositions reveal a strong fractionation of plagioclase components between melt and new plagioclase. For example at 850° C the approximate X An of melt is 0.3 and that of plagioclase is 0.8. The temperature interval between beginning of melting and complete melting of cotectic compositions is 100° C or more for quartz-plagioclase mixtures with plagioclases between An 40 and An 75. In comparison to the system Ab-An-H2O the plagioclase melting loop is somewhat wider in the investigated system Qz-Ab-An-H2O but the temperature interval is much smaller (100° C) than in the system Ab-An-H2O (200° C). The solidus data indicated by the new plagioclase compositions are practically identical with those observed in beginning of melting experiments. The results show that fractionation of plagioclase components between partial melts and restite plagioclase can be more pronounced in multi-component rocks than in the pure plagioclase system. This finding is important for the development of albite rich rocks from more basic compositions.  相似文献   

17.
Andesite and dacite from Barren and Narcondam volcanic islands of Andaman subduction zone are composed of plagioclase, orthopyroxene, clinopyroxene, olivine, titanomagnetite, magnesio-hornblende and rare quartz grains. In this study, we use the results of mineral chemical analyses of the calc-alkaline rock suite of rocks as proxies for magma mixing and mingling processes. Plagioclase, the most dominant mineral, shows zoning which includes oscillatory, patchy, multiple and repetitive zonation and ‘fritted’ or ‘sieve’ textures. Zoning patterns in plagioclase phenocrysts and abrupt fluctuations in An content record different melt conditions in a dynamic magma chamber. ‘Fritted’ zones (An55) are frequently overgrown by thin calcic (An72) plagioclase rims over well-developed dissolution surfaces. These features have probably resulted from mixing of a more silicic magma with the host andesite. Olivine and orthopyroxene with reaction and overgrowth rims (corona) suggest magma mixing processes. We conclude that hybrid magma formed from the mixing of mafic and felsic magma by two-stage processes – initial intrusion of hotter mafic melt (andesitic) followed by cooler acidic melt at later stage.  相似文献   

18.
Robert J. Stull 《Lithos》1978,11(3):243-249
Mantled feldspars that formed by resorption, development of skeletal plagioclase crystals, and filling with alkali feldspar are common in the Golden Horn batholith, Washington. Subhedral plagioclase mantles have weak normal zoning from An17 to An10. Plagioclase zoning and twinning are crosscut by resorption channels. Resorption cavities and channels are coated with albite (An10). Anhedral, perthitic orthoclase within the plagioclase is optically continuous with orthoclase in channels and on the mantle exterior.This texture resulted from resorption of calcic cores of plagioclase as pressure decreased when water-undersaturated granite magma intruded to a shallow crustal level. At shallow level, only alkali feldspar and quartz crystallized and were available to fill the skeletal plagioclase.  相似文献   

19.
Ten specimens of plagioclase feldspars (An100 to An25) have been examined by transmission electron microscopy using dark field and direct lattice imaging. The specimens are classified into two groups: (i) those that have been quenched from the melt (synthetic An100, An95, An66 and An50) and (ii) those that have been cooled relatively slowly (An94, An77, An75, An52, An32 and An26). The observed contrast is interpreted in detail using the two-beam dynamical theory of electron diffraction contrast. The fault vectors of the antiphase boundaries (APBs) observed in An100 and An77 are determined. Direct resolution of the sublattice and superlattice in specimens of intermediate composition (An75 to An25) indicates that the superlattice is not a regular array of out-of-step faults and is probably due to a simple sinusoidal distortion of the structure. Only three specimens (An100, An77 and An50) exhibited a single structural type. All the remaining specimens consisted of intergrowths of two structural types. The structural type present in any particular specimen depends upon its An-content and thermal history. The rate of transformation from any structural type to a lower-temperature structural type appears to decrease with decreasing An-content.  相似文献   

20.
The transmission electron microscope and the electron microprobe are used to characterize calcic plagioclase (An65 to An85) from a variety of geological environments. The cooling histories of samples from volcanic, plutonic and metamorphic environments are estimated and the transformation and exsolution sequence is inferred from observations in the transmission electron microscope. Several distinctive textural modifications occur depending both on bulk composition and cooling history. (1) Exsolution occurs in increasingly calcic bulk compositions upon slower cooling, and the coexisting phases are An66 intermediate plagioclase and An85–90 P¯1, c=14 Å plagioclase in the sample from the metamorphic environment, (2) the morphology of b antiphase boundaries (APBs) in An75 to An85 plagioclase changes from smoothly curving (rapid cooling and calcic compositions) to zig-zag (slower cooling or sodic compositions). (3) The concentration of defects in the intermediate plagioclase superstructure changes from a high density in rapidly cooled plagioclase to a lower density in slowly cooled plagioclase. In all plagioclases except for the rapidly cooled, volcanic specimens there is evidence in images and diffraction patterns for short-range ordered domains with P¯1 symmetry. The observations allow the microstructure of a single zoned plagioclase to be used as an indication of the geologic environment under which it cooled.  相似文献   

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