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1.
Water quality in less-developed countries is often subject to substantial degradation, but is rarely studied in a systematic way. The concentration and flux of major ions, carbon, nitrogen, silicon, and trace metals in the heavily urbanized Bagmati River within Kathmandu Valley, Nepal, are reported. The concentrations of all chemical species increased with distance downstream with the exceptions of protons and nitrate, and showed strong relationships with population density adjacent to the river. Total dissolved nitrogen (TDN), dominated by NH4, was found in high concentrations along the Bagmati drainage system. The export of dissolved organic carbon (DOC) and TDN were 23 and 33 tons km?2 year?1, respectively, at the outlet point of the Kathmandu Valley, much higher than in relatively undeveloped watersheds. The cationic and silica fluxes were 106 and 18 tons km?2 year?1 at the outlet of the Bagmati within Kathmandu Valley, and 36 and 32 tons km?2 year?1 from the relatively pristine headwater area. The difference between headwaters and the urban site suggests that the apparent weathering flux is three times higher than the actual weathering rate in the heavily urbanized Bagmati basin. Fluxes of cations and silica are above the world average, as well as fluxes from densely populated North American and European watersheds. End-member composition of anthropogenic sources like sewage or agricultural runoff is needed to understand the drivers of this high rate of apparent weathering.  相似文献   

2.
Field measurements conducted 4 years after the construction of a new portion of the Weixi?CShangri-La road in Yunnan, China, reveal that unprecedented rates of mass wasting occurred along the road with much of this sediment directly impacting the headwaters of the Mekong River. Landslide erosion (including dry ravel) exceeded 33,000 t ha?1 year?1 along the most severely eroded sections of the road and averaged more than 9,600 t ha?1 year?1 along the surveyed 23.5 km of road; these values are the highest ever reported for road-related landslides. While surface erosion was only about 7% of the total erosion from the road, it is still more than an order of magnitude higher than typical surface erosion rates from disturbed lands in Southeast Asia. Combined landslide and surface erosion from this road delivered an estimated 19 times more sediment to the river than the remaining 99.6% of the contributing catchment. These sediment inputs are aggrading local channels, promoting downstream sediment transport, degrading aquatic habitat, and creating the possibility for a future debris flood or hyperconcentrated flow.  相似文献   

3.
Biotite is a common constituent of silicate bedrock. Its weathering releases plant nutrients and consumes atmospheric CO2. Because of its stoichiometric relationship with its transformational weathering product and sensitivity to botanical activity, calculating biotite weathering rates using watershed mass-balance methods has proven challenging. At Coweeta Hydrologic Laboratory the coupling of biotite to its transformational weathering product is only valid if the stoichiometric relationship for the two phases is known; this relationship is unlikely layer-for-layer. Rates of biotite weathering and transformation of its secondary weathering product at the Coweeta Hydrological Laboratory are comparable with other Appalachian watersheds. The magnitude and sign of the difference between field- and laboratory-determined biotite weathering rates are similar to those of other silicate minerals. The influence of major-cation proportions in biomass on the rates of biotite weathering and transformational weathering product is greatest for watersheds with high biomass aggradation rates. The watershed with the lowest bedrock reactivity and highest flushing rate yielded the highest gibbsite formation rate of ~500 mol ha?1 year?1 and lowest kaolin-group mineral formation rates of 4–78 mol ha?1 year?1. The kaolin-group mineral formation rate increases as bedrock reactivity increases and flushing rate decreases to a maximum of ~300 mol ha?1 year?1, with a similar minimum gibbsite formation rate. The relative differences in bedrock reactivity and flux of water through Coweeta Hydrological Laboratory watersheds studied appear to be invariant over geologic timescales.  相似文献   

4.
Langat River drains a tropical watershed in the southwest of the Malaysian Peninsula. The watershed is heavily urbanized in its downstream portion. Water samples were collected from May 2010 to December 2011, at three localities along the main stem river, 1 location at its Semenyih tributary and from an upstream groundwater source. Concentration and δ13C data of riverine DIC and DOC indicate the dominance of C3 plant-derived material as the primary source of carbon, with δ13CDIC values enriched in 13C relative to that of the C3 source. This enrichment is likely due to CO2 outgassing, as calculated concentrations of riverine CO2 are significantly higher than ambient atmospheric values, with methanogenic activity a theoretically possible contributing factor, particularly at the upstream location. The Langat River therefore acts as a net source of CO2, with a total sub-basin flux of 19.7 × 103 t C year?1. This is comparable to the sum of riverine DOC, DIC and POC loss rates from the sub-basin, calculated as 24.5 × 103 t C year?1, and highlights the significance of CO2 evasion from water bodies to the atmosphere for balancing the budget of the terrestrial carbon cycle. The DIC and DOC concentration and δ13C data also suggests that in the more urbanized downriver areas, much of the organic carbon input may be anthropogenicaly derived due to ubiquity of sewage treatment plants and landfill sites. Such human-induced perturbations to riverine carbon cycling should be taken into account in future studies of urbanized watersheds.  相似文献   

5.
Soil losses and siltation of the hydrological system (watershed–dam) of K’sob were obtained using direct and indirect methods. The Wadi K’sob watershed of 1,484 km2, average slope of 0.14, and average elevation of 1,060 m is located in a semiarid climate. The average annual rainfall is 341 mm and the mean annual water discharge is 0.89 m3/s. Data from the Medjez gauging station located 6 km upstream of the dam, are the daily liquid flow and instantaneous concentrations of suspended sediments. Over a time period from 1973 to 2010, the relationship between water and sediment discharges is quantified by the equation: Q s?=?5.6 Q 1.31. Thus, in view of the availability data on a daily scale, the assessment of soil erodibility of the K’sob watershed was used to estimate specific soil losses of 203 t?km?2?year?1or 301,000 t eroded annually from the K’sob basin. The bathymetric measurements of the sediment volumes deposited in the K’sob dam, has quantified the annual siltation of 0.8 hm3, corresponding to an average erodibility of the K’sob watershed of 809 t?km?2?year?1. However, when adding the volume of sediment removed by the dredging operation and de-silting by the valves during heavy floods, the value of soil losses is 2,780 t?km?2?year?1. The indirect assessment of soil erodibility of the basin was obtained by applying two models: the quantitative geomorphological analysis (QGA) and PISA model (prediction of silting in the artificial reservoirs, in Italian: Previsioni dell’Interimento nei Serbatoi Artificiali) using physical and climatic factors in the watershed. The obtained results by QGA method underestimate specific soil losses of 524 t?km?2?year?1. The PISA model gives a value of 2,915 t?km?2?year?1, which is close to the value obtained by bathymetric measurements. This study concludes that PISA model is most suitable to estimate soil loss and siltation of the K’sob hydrological system.  相似文献   

6.
To quantify chemical weathering and biological uptake, mass-balance calculations were performed on two small forested watersheds located in the Blue Ridge Physiographic Province in north-central Maryland, USA. Both watersheds, Bear Branch (BB) and Fishing Creek Tributary (FCT), are underlain by relatively unreactive quartzite bedrock. Such unreactive bedrock and associated low chemical-weathering rates offer the opportunity to quantify biological processes operating within the watershed. Hydrologic and stream-water chemistry data were collected from the two watersheds for the 9-year period from June 1, 1990 to May 31, 1999. Of the two watersheds, FCT exhibited both higher chemical-weathering rates and biomass nutrient uptake rates, suggesting that forest biomass aggradation was limited by the rate of chemical weathering of the bedrock. Although the chemical-weathering rate in the FCT watershed was low relative to the global average, it masked the influence of biomass base-cation uptake on stream-water chemistry. Any differences in bedrock mineralogy between the two watersheds did not exert a significant influence on the overall weathering stoichiometry. The difference in chemical-weathering rates between the two watersheds is best explained by a larger proportion of reactive phyllitic layers within the bedrock of the FCT watershed. Although the stream gradient of BB is about two-times greater than that of FCT, its influence on chemical weathering appears to be negligible. The findings of this study support the biomass nutrient uptake stoichiometry of K1.0Mg1.1Ca0.97 previously determined for the study site. Investigations of the chemical weathering of relatively unreactive quartzite bedrock may provide insight into critical zone processes.  相似文献   

7.
In recent times, soil erosion interlocked with land use and land cover (LULC) changes has become one of the most important environmental issues in developing countries. Evaluation of this complex interaction between LULC change and soil erosion is indispensable in land use planning and conservation works. This paper analysed the impact of LULC change on soil erosion in the north-western highland Ethiopia over the period 1986–2016. Rib watershed, the area with dynamic LULC change and severe soil erosion problem, was selected as a case study site. Integrated approach that combined geospatial technologies with revised universal soil loss equation model was utilized to evaluate the spatio-temporal dynamics of soil loss over the study period. Pixel-based overlay of soil erosion intensity maps with LULC maps was carried out to understand the change in soil loss due to LULC change. Results showed that the annual soil loss in the study area varied from 0 to 236.5 t ha?1 year?1 (tons per hectare per year) in 1986 and 0–807 t ha?1 year?1 in 2016. The average annual soil loss for the entire watershed was estimated about 40 t ha?1 year?1 in 1986 comparing with 68 t ha?1 year?1 in 2016, a formidable increase. Soil erosion potential that was estimated to exceed the average soil loss tolerance level increased from 34.5% in 1986 to 66.8% in 2016. Expansion of agricultural land at the expense of grassland and shrubland was the most detrimental factor for severe soil erosion in the watershed. The most noticeable change in soil erosion intensity was observed from cropland with mean annual soil loss amount increased to 41.38 t ha?1 year?1 in 2016 from 26.60 in 1986. Moreover, the most successive erosion problems were detected in eastern, south-eastern and northern parts of the watershed. Therefore, the results of this study can help identify the soil erosion hot spots and conservation priority areas at local and regional levels.  相似文献   

8.
The relative contributions of dolomite to calcite weathering related to riverine fluxes are investigated on a highly resolved spatial scale in the diverse watersheds of Slovenia, which previous work has shown have some of the highest carbonate-weathering intensities in the world and suggests that dolomite weathering is favored over limestone weathering in mixed carbonate watersheds. The forested Sava and So?a River watersheds of Slovenia with their headwaters in the Julian Alps drain alpine regions with thin soils (<30 cm) and dinaric karst regions with thicker soils (0 to greater than 70 cm) all developed over bedded Mesozoic carbonates (limestone and dolomite), and siliclastic sediments is the ideal location for examining temperate zone carbonate weathering. This study extends previous work, presenting geochemical data on source springs and documenting downstream geochemical fluctuations within tributaries of the Sava and So?a Rivers. More refined sampling strategies of springs and discrete drainages permit directly linking the stream Mg2+/Ca2+ ratios to the local bedrock lithology and the HCO3 ? concentrations to the relative soil depths of the tributary drainages. Due to differences in carbonate source lithologies of springs and tributary streams, calcite and dolomite weathering end members can be identified. The Mg2+/Ca2+ ratio of the main channel of the Sava River indicates that the HCO3 ? concentration can be attributed to nearly equal proportions by mass of dolomite relative to calcite mineral weathering (e.g., Mg2+/Ca2+ mole ratio of 0.33). The HCO3 ? concentration and pCO2 values increase as soil thickness and alluvium increase for discrete spring samples, which are near equilibrium with respect to calcite. Typically, this results in approximately 1.5 meq/l increase in HCO3 ? from the alpine to the dinaric karst regions. Streams in general do not change in HCO3 ?, Mg2+/Ca2+, or Mg2+/HCO3 ? concentrations down course, but warming and degassing of CO2 produce high degrees of supersaturation with respect to calcite. Carbonate-weathering intensity (mmol/km2-s) is highest within the alpine regions where stream discharge values range widely to extreme values during spring snowmelt. Overall, the elemental fluxes of HCO3 ?, Ca2+, and Mg2+ from the tributary watersheds are proportional to the total water flux because carbonates dissolve rapidly to near equilibrium. Importantly, dolomite weathers preferentially over calcite except for pure limestone catchments.  相似文献   

9.
We estimated CO2 and CH4 emissions from mangrove-associated waters of the Andaman Islands by sampling hourly over 24 h in two tidal mangrove creeks (Wright Myo; Kalighat) and during transects in contiguous shallow inshore waters, immediately following the northeast monsoons (dry season) and during the peak of the southwest monsoons (wet season) of 2005 and 2006. Tidal height correlated positively with dissolved O2 and negatively with pCO2, CH4, total alkalinity (TAlk) and dissolved inorganic carbon (DIC), and pCO2 and CH4 were always highly supersaturated (330–1,627 % CO2; 339–26,930 % CH4). These data are consistent with a tidal pumping response to hydrostatic pressure change. There were no seasonal trends in dissolved CH4 but pCO2 was around twice as high during the 2005 wet season than at other times, in both the tidal surveys and the inshore transects. Fourfold higher turbidity during the wet season is consistent with elevated net benthic and/or water column heterotrophy via enhanced organic matter inputs from adjacent mangrove forest and/or the flushing of CO2-enriched soil waters, which may explain these CO2 data. TAlk/DIC relationships in the tidally pumped waters were most consistent with a diagenetic origin of CO2 primarily via sulphate reduction, with additional inputs via aerobic respiration. A decrease with salinity for pCO2, CH4, TAlk and DIC during the inshore transects reflected offshore transport of tidally pumped waters. Estimated mean tidal creek emissions were ～23–173 mmol m?2 day?1 CO2 and ～0.11–0.47 mmol m?2 day?1 CH4. The CO2 emissions are typical of mangrove-associated waters globally, while the CH4 emissions fall at the low end of the published range. Scaling to the creek open water area (2,700 km2) gave total annual creek water emissions ～3.6–9.2?×?1010 mol CO2 and 3.7–34?×?107 mol CH4. We estimated emissions from contiguous inshore waters at ～1.5?×?1011 mol CO2?year?1 and 2.6?×?108 mol CH4?year?1, giving total emissions of ～1.9?×?1011 mol CO2?year?1 and ～3.0?×?108 mol CH4?year?1 from a total area of mangrove-influenced water of ～3?×?104 km2. Evaluating such emissions in a range of mangrove environments is important to resolving the greenhouse gas balance of mangrove ecosystems globally. Future such studies should be integral to wider quantitative process studies of the mangrove carbon balance.  相似文献   

10.
In order to examine the fluxes of methane (CH4) from the Indian estuaries, measurements were carried out by collecting samples from 26 estuaries along the Indian coast during high discharge (wet) and low water discharge (dry) periods. The CH4 concentrations in the estuaries located along the west coast of India were significantly higher (113?±?40 nM) compared to the east coast of India (27?±?6 nM) during wet and dry periods (88?±?15 and 63?±?12 nM, respectively). Supersaturation of CH4 was observed in the Indian estuaries during both periods ((0.18 to 22.3?×?103 %). The concentrations of CH4 showed inverse relation with salinity indicating that freshwater is a significant source. Spatial variations in CH4 saturation were associated with the organic matter load suggesting that its decomposition may be another source in the Indian estuaries. Fluxes of CH4 ranged from 0.01 to 298 μmol m?2 day?1 (mean 13.4?±?5 μmol m?2 day?1) which is ~30 times lower compared to European estuaries (414 μmol m?2 day?1). The annual emission from Indian estuaries, including Pulicat and Adyar, amounted to 0.39?×?1010 g CH4?year?1 with the surface area of 0.027?×?106 km2 which is significantly lower than that in European estuaries (2.7?±?6.8?×?1010 g CH4?year?1 with the surface area of 0.03?×?106 km2). This study suggests that Indian estuaries are a weak source for atmospheric CH4 than European estuaries and such low fluxes were attributed to low residence time of water and low decomposition of organic matter within the estuary. The CH4 fluxes from the Indian estuaries are higher than those from Indian mangroves (0.01?×?1010 g CH4?year?1) but lower than those from Indian inland waters (210?×?1010 g CH4?year?1).  相似文献   

11.
We developed a synthesis using diverse monitoring and modeling data for Mattawoman Creek, Maryland, USA to examine responses of this tidal freshwater tributary of the Potomac River estuary to a sharp reduction in point-source nutrient loading rate. Oligotrophication of these systems is not well understood; questions concerning recovery pathways, threshold responses, and lag times remain to be clarified and eventually generalized for application to other systems. Prior to load reductions Mattawoman Creek was eutrophic with poor water clarity (Secchi depth <0.5 m), no submerged aquatic vegetation (SAV), and large algal stocks (50–100 μg L?1 chlorophyll-a). A substantial modification to a wastewater treatment plant reduced annual average nitrogen (N) loads from 30 to 12 g N m?2 year?1 and phosphorus (P) loads from 3.7 to 1.6 g P m?2 year?1. Load reductions for both N and P were initiated in 1991 and completed by 1995. There was no trend in diffuse N and P loads between 1985 and 2010. Following nutrient load reduction, NO2?+?NO3 and chlorophyll-a decreased and Secchi depth and SAV coverage and density increased with initial response lag times of one, four, three, one, and one year, respectively. A preliminary N budget was developed and indicated the following: diffuse sources currently dominate N inputs, estimates of long-term burial and denitrification were not large enough to balance the budget, sediment recycling of NH4 was the single largest term in the budget, SAV uptake of N from sediments and water provided a modest seasonal-scale N sink, and the creek system acted as an N sink for imported Potomac River nitrogen. Finally, using a comparative approach utilizing data from other shallow, low-salinity Chesapeake Bay ecosystems, strong relationships were found between N loading and algal biomass and between algal biomass and water clarity, two key water quality variables used as indices of restoration in Chesapeake Bay.  相似文献   

12.
In this study, the hydro-climatic trends (1964–2006) of Tangwang River basin (TRB) were examined using the Kendall’s test. Moreover, the impacts of climate variability and land use change on streamflow in each sub-basin were assessed using the Soil and Water Assessment Tools (SWAT) model. The results indicated that annual mean flow and peak flow showed insignificant decreasing trends (?0.14 m3 s?1 year?1, 1 %; ?8.67 m3 s?1 year?1, 40 %), while annual low flow exhibited a slightly increasing trend (0.02 m3 s?1 year?1, 11 %). Correspondingly, the annual precipitation for the entire basin decreased by 0.02 mm year?2, while the annual means of daily mean, maximum and minimum temperature increased significantly by 0.07, 0.10 and 0.02 °C year?1, respectively. On the other hand, with the implementation of “Natural Forest Protection Project” and “Grain for Green Project”, the forests in TRB totally increased by 744.5 km2 (4.00 %) from 1980 to 2000. Meanwhile, the grasslands and the farmlands decreased by 378.0 km2 (?1.98 %) and 311.9 km2 (?1.63 %), respectively. Overall, land use changes played a more important role for the streamflow reduction than climate change for SUB1, SUB2 and SUB3, in which the primary conversions were from grassland, farmland and bare land to forests. Conversely, in SUB4, the influence of climate variability was predominant. The results obtained could be a reference for water resources planning and management under changing environment.  相似文献   

13.
Sediment accretion was measured at four sites in varying stages of forest-to-marsh succession along a fresh-to-oligohaline gradient on the Waccamaw River and its tributary Turkey Creek (Coastal Plain watersheds, South Carolina) and the Savannah River (Piedmont watershed, South Carolina and Georgia). Sites included tidal freshwater forests, moderately salt-impacted forests at the freshwater–oligohaline transition, highly salt-impacted forests, and oligohaline marshes. Sediment accretion was measured by use of feldspar marker pads for 2.5 year; accessory information on wetland inundation, canopy litterfall, herbaceous production, and soil characteristics were also collected. Sediment accretion ranged from 4.5 mm year?1 at moderately salt-impacted forest on the Savannah River to 19.1 mm year?1 at its relict, highly salt-impacted forest downstream. Oligohaline marsh sediment accretion was 1.5–2.5 times greater than in tidal freshwater forests. Overall, there was no significant difference in accretion rate between rivers with contrasting sediment loads. Accretion was significantly higher in hollows than on hummocks in tidal freshwater forests. Organic sediment accretion was similar to autochthonous litter production at all sites, but inorganic sediment constituted the majority of accretion at both marshes and the Savannah River highly salt-impacted forest. A strong correlation between inorganic sediment accumulation and autochthonous litter production indicated a positive feedback between herbaceous plant production and allochthonous sediment deposition. The similarity in rates of sediment accretion and sea level rise in tidal freshwater forests indicates that these habitats may become permanently inundated if the rate of sea level rise increases.  相似文献   

14.
The Northeast USA is experiencing severe impacts of a changing climate, including increased winter temperatures and accelerated relative sea level rise (RSLR). The sediment-poor, organic-rich nature of many Southern New England salt marshes makes them particularly vulnerable to these changes. In order to assess how marsh accretion has changed over time, we returned to Narragansett Bay, RI where salt marsh vertical accretion rates were documented almost 30 years ago. Using radionuclide tracers (210Pb and 137Cs), we observe no significant change in overall accretion rates (0.27–0.69 cm year?1) compared to historical averages (0.24–0.60 cm year?1), but we document a shift in how these marshes maintain elevation. Organic matter now plays a smaller role in contributing to vertical accretion across all study sites, declining by 22 % on average. We attribute this reduction to potentially higher decomposition rates fueled by higher water temperature. Inorganic matter also contributes less to accretion (declining by 44 % on average at marshes located more internal to the estuary), likely due to diminishing sediment supply in this region. With organic and inorganic solids accounting for less of the total accretion, several of the marshes are experiencing symptoms of swelling, with water and porespace contributing more towards accretion compared to historical values. Accretion rates (0.27–0.45 cm year?1) at these organic-rich (>40 % sediment organic matter) marshes are predominantly lower than the current (30 years) rate of RSLR (0.41?±?0.07 cm year?1). These results, combined with the increased rate of RSLR and the hardened shorelines inhibiting landward migration, call into question the long-term survivability of these marshes.  相似文献   

15.
Increased nitrogen (N) input to ecosystems could alter soil organic carbon (C) dynamics, but the effect still remains uncertain. To better understand the effect of N addition on soil organic C in wetland ecosystems, a field experiment was conducted in a seasonally inundated freshwater marsh, the Sanjiang Plain, Northeast China. In this study, litter production, soil total organic C (TOC) concentration, microbial biomass C (MBC), organic C mineralization, metabolic quotient (qCO2) and mineralization quotient (qmC) in 0–15 cm depth were investigated after four consecutive years of N addition at four rates (CK, 0 g N m?2 year?1; low, 6 g N m?2 year?1; moderate, 12 g N m?2 year?1; high, 24 g N m?2 year?1). Four-year N addition increased litter production, and decreased soil organic C mineralization. In addition, soil TOC concentration and MBC generally increased at low and moderate N addition levels, but declined at high N addition level, whereas soil qCO2 and qmC showed a reverse trend. These results suggest that short-term N addition alters soil organic C dynamics in seasonally inundated freshwater marshes of Northeast China, and the effects vary with N fertilization rates.  相似文献   

16.
Three sediment stations in Himmerfjärden estuary (Baltic Sea, Sweden) were sampled in May 2009 and June 2010 to test how low salinity (5–7 ‰), high primary productivity partially induced by nutrient input from an upstream waste water treatment plant, and high overall sedimentation rates impact the sedimentary cycling of methane and sulfur. Rates of sediment accumulation determined using 210Pbexcess and 137Cs were very high (0.65–0.95 cm?year?1), as were the corresponding rates of organic matter accumulation (8.9–9.5 mol C?m?2?year?1) at all three sites. Dissolved sulfate penetrated <20 cm below the sediment surface. Although measured rates of bicarbonate methanogenesis integrated over 1 m depth were low (0.96–1.09 mol?m?2?year?1), methane concentrations increased to >2 mmol?L?1 below the sulfate–methane transition. A steep gradient of methane through the entire sulfate zone led to upward (diffusive and bio-irrigative) fluxes of 0.32 to 0.78 mol?m?2?year?1 methane to the sediment–water interface. Areal rates of sulfate reduction (1.46–1.92 mol?m?2?year?1) integrated over the upper 0–14 cm of sediment appeared to be limited by the restricted diffusive supply of sulfate, low bio-irrigation (α?=?2.8–3.1 year?1), and limited residence time of the sedimentary organic carbon in the sulfate zone. A large fraction of reduced sulfur as pyrite and organic-bound sulfur was buried and thus escaped reoxidation in the surface sediment. The presence of ferrous iron in the pore water (with concentrations up to 110 μM) suggests that iron reduction plays an important role in surface sediments, as well as in sediment layers deep below the sulfate–methane transition. We conclude that high rates of sediment accumulation and shallow sulfate penetration are the master variables for biogeochemistry of methane and sulfur cycling; in particular, they may significantly allow for release of methane into the water column in the Himmerfjärden estuary.  相似文献   

17.
Measurements of groundwater-dissolved inorganic nitrogen (nitrate?+?nitrite?+?ammonia) and phosphate concentrations were combined with recent, radium-based, submarine groundwater discharge (SGD) fluxes and prior estimates of SGD determined from Darcy’s Law, a hydrologic model, and total recharge to yield corresponding SGD nutrient fluxes to Ninigret, Point Judith, Quonochontaug, and Winnapaug ponds, located in southern Rhode Island. Results range from 80 to279 mmol N m?2 year?1 and 4 to 15 mmol P m?2 year?1 for Ninigret, 48 to 265 mmol N m?2 year?1 and 4 to 23 mmol P m?2 year?1 for Point Judith, 31 to 62 mmol N m?2 year?1 and 1 to 2 mmol P m?2 y?1 for Quonochontaug, and 668 to 1,586 mmol N m?2 year?1 and 29 to 70 mmol P m?2 year?1 for Winnapaug ponds, respectively. On a daily basis, the SGD supply of dissolved inorganic nitrogen and phosphorus is estimated to represent ～1–6 % of the total amount of these nutrients in surface waters of Ninigret, Point Judith, and Quonochontaug ponds and up to 84 and 17 % for Winnapaug, respectively, which may reflect a greater SGD nutrient supply to this pond because of the proximity of fertilized golf courses. With regard to the total external input of these essential nutrients, SGD represents 29–45 % of dissolved inorganic nitrogen input to Ninigret, Point Judith, and Quonochontaug ponds and as much as 93 % for Winnapaug pond. For phosphorus, the contribution from SGD represents 59–85 % of the total external input for Ninigret, Point Judith, and Quonochontaug ponds and essentially all of the phosphorus input to Winnapaug pond. Estimated rates of primary productivity potentially supported by the average supply of dissolved inorganic nitrogen from SGD range from 10 g C m?2 year?1 for Ninigret, 13 g C m?2 year?1 for Point Judith, 4 g C m?2 year?1 for Quonochontaug, and as high as 84 g C m?2 y?1 for Winnapaug pond. The imputed SGD-derived rates of primary productivity represent 4–9 % of water column primary production for Ninigret, Point Judith, and Quonochontaug ponds, and 74 % for Winnapaug pond, a result that is reasonably comparable to several other coastal environments where estimates of SGD nutrient supply have been reported. The implication is that SGD represents an ecologically significant source of dissolved nutrients to the coastal salt ponds of southern Rhode Island and, by inference, other coastal systems.  相似文献   

18.
The Wenchuan earthquake has caused abundance of loose materials supplies for debris flows. Many debris flows have occurred in watersheds in area beyond 20 km2, presenting characteristics differing from those in small watersheds. The debris flows yearly frequency decreases exponentially, and the average debris flow magnitude increases linearly with watershed size. The rainfall thresholds for debris flows in large watersheds were expressed as I?=?14.7 D ?0.79 (2 h?<?D?<?56 h), which is considerably higher than those in small watersheds as I?=?4.4 D ?0.70 (2 h?<?D?<?37 h). A case study is conducted in Ergou, 39.4 km2 in area, to illustrate the formation and development processes of debris flows in large watersheds. A debris flow develops in a large watershed only when the rainfall was high enough to trigger the wide-spread failures and erosions on slope and realize the confluence in the watershed. The debris flow was supplied by the widely distributed failures dominated by rill erosions (14 in 22 sources in this case). The intermittent supplying increased the size and duration of debris flow. While the landslide dam failures provided most amounts for debris flows (57 % of the total amount), and amplified the discharge suddenly. During these processes, the debris flow velocity and density increased as well. The similar processes were observed in other large watersheds, indicating this case is representative.  相似文献   

19.
We investigated spatial and temporal changes in spectral irradiance, phytoplankton community composition, and primary productivity in North Inlet Estuary, South Carolina, USA. High concentrations of colored dissolved organic matter (CDOM) were responsible for up to 84 % of the attenuation of photosynthetically available radiation (PAR). Green-yellow wavelengths were the predominant colors of light available at the two sampling sites: Clam Bank Creek and Oyster Landing. Vertical attenuation coefficients of PAR were 0.7–2.1 m?1 with corresponding euphotic zone depths of 1.5–6.7 m. Phytoplankton biomass (as chlorophyll a [chl a]) varied seasonally with a summer maximum of 16 μg chl a l?1 and a winter minimum of 1.4 μg chl a l?1. The phytoplankton community consisted mainly of diatoms, prasinophytes, cryptophytes and haptophytes, with diatoms and prasinophytes accounting for up to 67 % of total chl a. Changes in phytoplankton community composition showed strongest correlations with temperature. Light-saturated chl a-specific rates of photosynthesis and daily primary productivity varied with season and ranged from 1.6 to 14 mg C (mg chl a) ?1?h?1 (32–803 mg C m?3?day?1). Calculated daily rates added up to an annual carbon fixation rate of 84 g C m?3?year?1. Overall, changes in phytoplankton community composition and primary productivity in North Inlet showed a strong dependence on temperature, with PAR and spectral irradiance playing a relatively minor role due to short residence times, strong tidal forcing and vertical mixing.  相似文献   

20.
Groundwater survey has been carried out in the area of Gummanampadu sub-basin located in Guntur District, Andhra Pradesh, India for assessing the factors that are responsible for changing of groundwater chemistry and consequent deterioration of groundwater quality, where the groundwater is a prime source for drinking and irrigation due to non-availability of surface water in time. The area is underlain by the Archaean Gneissic Complex, over which the Proterozoic Cumbhum rocks occur. The results of the plotting of Ca2+ + Mg2+ versus HCO3 ? + CO3 2?, Ca2+ + Mg2+ versus total cations, Na+ + K+ versus total cations, Cl? + SO4 2? versus Na+ + K+, Na+ versus Cl?, Na+ versus HCO3 ? + CO3 2?, Na+ versus Ca2+ and Na+: Cl? versus EC indicate that the rock–water interaction under alkaline condition is the main mechanism in activating mineral dissociation and dissolution, causing the release of Ca2+, Mg2+, Na+, K+, HCO3 ?, CO3 2?, SO4 2? and F? ions into the groundwater. The ionic relations also suggest that the higher concentrations of Na+ and Cl? ions are the results of ion exchange and evaporation. The influences of anthropogenic sources are the other cause for increasing of Mg2+, Na+, Cl?, SO4 2? and NO3 ? ions. Further, the excess alkaline condition in water accelerates more effective dissolution of F?-bearing minerals. Moreover, the chemical data plotted in the Piper’s, Gibbs’s and Langelier–Ludwig’s diagrams, computed for the chloro-alkaline and saturation indices, and analyzed in the principal component analysis, support the above hypothesis. The groundwater quality is, thus, characterized by Na+ > Ca2+ > Mg2+ > K+: HCO3 ? + CO3 2? > Cl? > SO4 2? > NO3 ? > F? facies. On the other hand, majority of groundwater samples are not suitable for drinking with reference to the concentrations of TDS, TH, Mg2+ and F?, while those are not good for irrigation with respect to USSL’s and Wilcox’s diagrams, residual sodium carbonate, and magnesium hazard, but they are safe for irrigation with respect to permeability index. Thus, the study recommends suitable management measures to improve health conditions as well as to increase agricultural output.  相似文献   

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