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1.
Detailed magnetic and geochemical measurements were performed on urban roadside soils collected from Lishui city, China, to establish a possible link between the enhanced concentration of traffic-related magnetic particles and heavy metals. Relatively higher magnetic susceptibility (mean: 124.1 × 10−8 m3 kg−1) and concentrations of metals (Cd, Cu, Pb and Zn) were observed for roadside soils. Concentration-dependent magnetic parameters (χ and SIRM) are highly significantly positively correlated to the concentration of metals (Ca, Cr, Ni, Cu, Zn, Cd, Pb, Fe, and V), but not significantly correlated with As, Mn, Co, Mg, and K. The principal component analysis showed that χ and SIRM significantly correspond to elements Ca, Cd, Cu, Pb, and Zn. The χ and SIRM also have significant linear correlation with integrated pollution index, indicating that χ and SIRM can be used as effective proxy indicators for the pollution of heavy metals. Magnetite in the pseudo-single-domain/multidomain (PSD/MD) grain size was identified as the dominant magnetic carrier by temperature-dependent measurements of saturation magnetization (Ms–T curve), XRD and hysteresis loops. Field emission scanning electron microscopy and energy dispersive X-ray spectroscopy (EDS) analysis of the magnetic particles revealed the presence of large traffic-related angular-subangular, blocky, and spherical iron oxide particles. These iron oxide particles are typical for particles produced by traffic-related anthropogenic activities. It is concluded that vehicle emissions may be the major source of elevated heavy metals and magnetic particles in roadside soils. The results proved the applicability of magnetic method in detecting roadside pollution derived from vehicle emissions.  相似文献   

2.
Multivariate statistical analysis has been used for detailed examination of the relationship between the magnetic properties of Xuzhou urban topsoil, for example concentration-dependent properties (mass magnetic susceptibility (χ), susceptibility of anhysteretic remanent magnetization (χ ARM), saturation isothermal remanent magnetization (SIRM), soft remanent magnetization (SOFT), and frequency-dependent magnetic susceptibility (χ FD)) and feature-dependent properties (S −100 mT ratio, SIRM/χ ratio and F 300 mT ratio), and the concentrations of metals (Ti, Fe, Cr, Al, Ga, Pb, Sc, Ba, Li, Cd, Be, Co, Cu, Mn, Ni, V, Zn, Mo, Pt, Pd, Au, As, Sb, Se, Hg, Bi, Ag, and Sn), S, and Br in the soil. The results show that SIRM/χ ratios correlate best with the heavy metals (Hg, Cr, Sb, As, and Bi) which are mainly derived from coal-combustion emissions whereas χ FD correlates best with the metals (Al, Ti, V, Be, Co, Ga, Mn, and Li) which principally originate from soil parents. Concentration-dependent magnetic properties (χ ARM, χ, SIRM, and SOFT) correlate well with elements (Se, Pb, Cu, Zn, Fe, Ag, Sc, Ba, Mo, Br, S, Cd, Ni, etc.) which are mainly derived from road-traffic emissions. For the same chemical element, χ ARM, SIRM, and SOFT values are frequently better correlated than χ values, and χ ARM values are the best indicators of the concentrations of these elements associated with traffic emissions in this study area. In addition, S −100 mT ratios significantly correlate positively with Se, Sc, Pb, Cu, Zn, Mo, and S whereas F 300 mT ratios only correlate positively with Pt and negatively with Fe. These results confirm the suitability of different magnetic properties for characterizing the concentrations of heavy metals, S, and Br in Xuzhou urban topsoil.  相似文献   

3.
In this study, environmental magnetic, heavy metal and statistical analyses were conducted on 21 surface sediments collected from Chennai coast, India, to examine the feasibility of heavy metal pollution using magnetic susceptibility. The Chennai coastal sediment samples are dominated by ferrimagnetic minerals corresponding to magnetite-like minerals. The percentage of frequency dependent magnetic susceptibility reflects the presence of super-paramagnetic/single domain magnetic minerals in Chennai harbour, Cooum and Adayar rivers sediments. High pollution load index in sample E1, E2, CH7, C11, C12 and A16 is mainly due to anthropogenic activities such as, harbour activities, Cooum and Adayar rivers input and industrial effluent. Factor analysis shows that the magnetic concentration dependent parameters (χ, χ ARM and SIRM) covary with the heavy metal concentrations, suggesting that the input of magnetic minerals and heavy metals in Chennai coastal sediments are derived from the same anthropogenic sources. Strong correlation obtained between pollution load index (PLI) and concentration dependent parameters (χ, χ ARM and SIRM) for the polluted samples with magnetic susceptibility excess of 50×10 − 8 m3kg − 1. Significant correlations between heavy metals and magnetic susceptibility point out the potential of magnetic screening/monitoring for simple and rapid proxy indicator of heavy metal pollution in marine sediments.  相似文献   

4.
Phosphorus (P) application in excess of plant requirement may result in contamination of drinking water and eutrophication of surface water bodies. The phosphorous buffer capacity (PBC) of soil is important in plant nutrition and is an important soil property in the determination of the P release potential of soils. Phosphorus sorption greatly affects both plant nutrition and environmental pollution. For better and accurate P fertilizer recommendations, it is necessary to quantify P sorption. This study was conducted to investigate available P and P sorption by calcareous soils in a semi-arid region of Hamadan, western Iran. The soil samples were mainly from cultivated land. Olsen’s biocarbonate extractable P (Olsen P) varied among soils and ranged from 10 to 80 mg kg−1 with a mean of 36 mg kg−1. Half of the soils had an Olsen P > 40 mg kg−1 and >70% of them had a concentration >20 mg kg−1, whereas the critical concentration for most crops is <15 mg P kg−1. Greater average Olsen P in soils occurred under garlic (56 mg kg−1) and potato (44 kg kg−1) fields than in dry-land wheat farming (24 mg kg−1), pasture (30 mg kg−1), and wheat (24 mg P kg−1) fields. A marked increase in fertilizer P rates applied to agricultural soils has caused P to be accumulated in the surface soil. Phosphate sorption curves were well fitted to the Freundlich equation. The standard P requirement (SPR) of soils, defined as the amount of P sorbed at an equilibrium concentration of 0.2 mg l−1 ranged from 4 to 102 mg kg−1. Phosphorus buffer capacity was relatively high and varied from 16 to 123 l kg−1 with an average of 58 l kg−1. In areas of intensive crop production, continual P applications as P fertilizer and farmyard manure have been used at levels exceeding crop requirements. Surface soil accumulations of P are high enough that loss of P in surface runoff and a high risk for P transfer into groundwater have become priority management concerns.  相似文献   

5.
This investigation represented the preliminary study to characterize Pt and Pd concentrations and enrichment ratios in urban roadside soils. Roadside soil samples were analyzed by ICP-MS. Data from 21 roadside topsoil samples show medians of Pt and Pd concentrations are 2.9 and 2.8 ng g−1, respectively. These values are higher than those of upper crust that average 0.4 and 0.4 ng g−1, respectively. The relatively lower Pt and Pd concentrations are expected due to recent introduction of catalysts to China compared to the prolonged use of catalysts in Europe. Hierarchical clustering analysis indicates that Pt and Pd in Xuzhou urban roadside soils were mainly from the traffic emissions. Computation of enrichment ratios using the upper crust values as background levels suggests that the roadside soils had enrichment medians of 6.4 for Pt (range 2.5–11.75) and of 6.75 for Pd (range 2.75–9.25). Lower Pt/Pd ratios (range 0.35–2.86) in relation to similar studies in other countries were observed due to the different automobile catalytic converters. In general, fine fraction (<250 μm) contains higher Pt and Pd concentrations compared to the coarse fraction (250–500 μm).  相似文献   

6.
Three sediment cores in a north-south transect (3°N to 13°S) from different sediment types of the Central Indian Ocean Basin (CIOB) are studied to understand the possible relationship between magnetic susceptibility (χ) and Al, Fe, Ti and Mn concentrations. The calcareous ooze core exhibit lowest χ (12.32 × 10−7 m3 kg−1), Al (2.84%), Fe (1.63%) and Ti (0.14%), terrigenous clay core with moderate χ (29.93 × 10−7 m3 kg−1) but highest Al (6.84%), Fe (5.20%) and Ti (0.44%), and siliceous ooze core with highest χ (38.06 × 10−7 m3 kg−1) but moderate Al (4.49%), Fe (2.80%) and Ti (0.19%) contents. The distribution of χ and detrital proxy elements (Al, Fe, and Ti) are identical in both calcareous and siliceous ooze. Interestingly, in terrigenous core, the behaviour of χ is identical to only Ti content but not with Al and Fe suggesting possibility of Al and Fe having a non-detrital source. The occurrence of phillipsite in terrigenous clay is evident by the Al-K scatter plot where trend line intersects K axis at more than 50% of total K suggesting excess K in the form of phillipsite. Therefore, the presence of phillipsite might be responsible for negative correlation between χ and Al (r = −0.52). In siliceous ooze the strong positive correlations among χ, Alexc and Feexc suggest the presence of authigenic Fe-rich smectite. High Mn content (0.5%) probably in the form of manganese micronodules is also contributing to χ in both calcareous and siliceous ooze but not in the terrigenous core where mean Mn content (0.1%) is similar to crustal abundance. Thus, χ systematically records the terrigenous variation in both the biogenic sediments but in terrigenous clay it indirectly suggests the presence of authigenic minerals.  相似文献   

7.
2 study area was assessed with respect to its heavy-metal load on the basis of the current guideline values. The heavy-metal loads of the soils in the study area have ranges of <0.2–200 mg kg−1 for Cd, <10–30,000 mg kg−1 for Pb, 7–10,000 mg kg−1 for Cu and 50–55,000 mg kg−1 for Zn. Mobility of the heavy metals was determined by extraction at different pH values. The acid neutralisation capacity (ANCx) at these pH values was also determined to estimate the probability that the pH can drop to pH=x. The ANC values in the study area ranged from 6 to 3000 mmol H+ kg−1, from −33 to 800 mmol H+ kg−1 and from −74 to 160 mmol H+ kg−1 for ANC3.5, ANC5.0 and ANC6.2, respectively. Together with pedological data, the extraction experiments permit differentiation between soil units that have been placed in the same environmental hazard class on the basis of total heavy-metal loads. Received: 10 August 1998 · Accepted: 14 August 1999  相似文献   

8.
The organic fraction in soils has a significant influence on heavy metal transport. In this study, the organic carbon content was measured by dry oxidation procedure from 21 Xuzhou urban roadside soils to assess the relationships between the concentrations of heavy metals (Pb, Cu, Zn, and Cr) and the amount of organic carbon. The anthropogenic heavy metals (e.g. Pb, Cu, Zn) were strongly correlated with organic carbon (denoted by Corg−c) extracted by dry oxidation while natural heavy metal (e.g. Cr) showed no correlation to the Corg−c. The anthropogenic heavy metals were also strongly correlated with the amount of the total carbon. These results show that the anthropogenic heavy metals are mainly enriched in the organic matter in the Xuzhou urban roadside soils.  相似文献   

9.
Coal handling, crushing, washing, and other processes of coal beneficiation liberate coal particulate matter, which would ultimately contaminate the nearby soils. In this study, an attempt was made to determine the status of soil bio-indicators in the surroundings of a coal beneficiation plant, (in relation to a control site). The coal beneficiation plant is located at Sudamudih, and the control site is 5 km away from the contaminated site, which is located in the colony of Central Institute of Mining and Fuel Research Institute, Digwadih, Dhanbad. In order to estimate the impact of coal deposition on soil biochemical characteristics and to identify the most sensitive indicator, soil samples were taken from the contaminated and the control sites, and analyzed for soil organic carbon (SOC), soil N, soil basal respiration (BSR), substrate-induced respiration (SIR), and soil enzymes like dehydrogenase (DHA), catalase (CAT), phenol oxidase (PHE), and peroxidase (PER). Coal deposition on soils improved the SOC from 10.65 to 50.17 g kg−1, CAT from 418.1 to 804.11 μg H2O2 g−1 h−1, BSR from 8.5 to 36.15 mg CO2–C kg−1 day−1, and SIR from 24.3 to 117.14 mg CO2–C kg−1 day−1. Soils receiving coal particles exhibited significant decrease in DHA (36.6 to 4.22 μg TPF g−1 h−1), PHE (0.031 to 0.017 μM g−1 h−1), PER (0.153 to 0.006 μM g−1 h−1), and soil N (55.82 to 26.18 kg ha−1). Coal depositions significantly (P < 0.01) decreased the DHA to 8.8 times, PHE to 1.8 times, and PER to 25.5 times, but increased the SOC to 4.71 times, CAT to 1.9 times, SIR to 4.82 times, and BSR to 4.22 times. Based on principal component analysis and sensitivity test, soil peroxidase (an enzyme that plays a vital role in the degradation of the aromatic organic compounds) is found to be the most important indicator that could be considered as biomarkers for coal-contaminated soils.  相似文献   

10.
Structural, morphological, magnetic, and thermal properties have been investigated for a novel post-perovskite oxide CaPtO3 synthesized under high pressure. By comparing obtained structural parameters with those for known post-perovskite compounds, we argue that the chemical bond has a strong covalent character. Precise measurements of the Langevin susceptibility χ 0 = −9.6 × 10−5 emu/mol and Debye temperature θ ∼ 470 K provide a good opportunity to confirm the reliability of first-principle calculations on predicting physical properties of the Earth’s D” layer.  相似文献   

11.
An expressway-side soil profile 22 cm long was sampled from the grassland of the expressway linking Beijing and the Capital International Airport. Magnetic measurements, geochemical and multivariate statistic analyses were performed on the soil samples. The results reveal that the soil profile can be divided into two parts with significant difference in magnetic proxies and heavy metal concentration. The uppermost soil horizon (0–8 cm) represents the pollution-rich layer with higher concentration of ferrimagnetic phases and metallic elements. The values of xare very high with an average of 141.60 × 10−8 m3·kg−1 in the layer. We explain that the anthropogenic dust input from traffic is the predominant cause for strong signals of magnetic phases and heavy metals. Below the profile depth of 8 cm, there is minor pollution in the soil with lower concentration of magnetic minerals and heavy metals compared to the natural background values. χ remains quite stable and relatively low with an average of 49.44 × 10−8 m3·kg−1. S-ratio also generally decreases with depth, and it changes from 0.93 in the 0–8 cm layer to 0.87 below the depth of 8 cm. It indicates that the soil samples are overwhelmingly predominated by ferrimagnetic minerals in the upper part soil, while the contribution of imperfect antiferromagnetic components is stronger in the lower part. Rock magnetic experiments show MD magnetite as the main magnetic carrier both in the upper and lower parts. Themagnetic grain size in the upper part is, however, a bit coarser than that in the lower part. Cluster analysis shows a positive correlation between magnetic properties (χ, ARM, SIRM) and heavy metal pollutants of Pb, Zn, Cu. Fuzzy C-means cluster analysis can clearly help divide the soil profile into two different layers and distinguish their characteristics. It can be concluded that these magnetic concentration-related parameters can be used as proxies for pollution investigation in a fast, sensitive, low-cost and highly efficient approach to screening heavy metal pollution. __________ Translated from Quaternary Sciences, 2007, 27(6): 1113-1120 [译自:第四纪研究]  相似文献   

12.
Concentration and distribution of heavy metals (Cd, Cu, Pb and Zn) in urban soils of Hangzhou, China, were measured based on different land uses. The contamination degree of heavy metals was assessed on the basis of pollution index (PI), integrated pollution index (IPI) and geoaccumulation index (I geo). The 0.1 mol l−1 HCl extraction procedure and gastric juice simulation test (GJST) were used to evaluate the potential mobility and environmental risk of heavy metals in urban soils. The average concentration of Cd, Cu, Pb and Zn in urban soils was measured at 1.2 (with a range of 0.7–4.6), 52.0 (7.4–177.3), 88.2 (15.0–492.1) and 206.9 (19.3–1,249.2) mg kg−1, respectively. The degree of contamination increased in the order of industrial area (IA) > roadside (RS) > residential and commercial areas (RC) > public park and green areas (PG). The PIs for heavy metals indicated that there is a considerable Cd, Cu, Pb and Zn pollution, which originate from traffic and industrial activities. The IPI of these four metals ranged from 1.6 to 11.8 with a mean of 3.5, with the highest IPI in the industrial area. The assessment results of I geo also supported that urban soil were moderately contaminated with Cd and to a lesser extent also with Cu, Pb and Zn. The IP and I geo values reveal the pollution degree of heavy metal was the order of Cd > Pb > Zn ≈ Cu. It was shown that mobility and bioavailability of the heavy metals in urban soils increased in the order of Cd > Cu > Zn ≈ Pb. Owing to high mobility of Cd and Cu in the urban soils, further investigations are needed to understand their effect on the urban environment and human health. It is concluded that industrial activities and emissions from vehicles may be the major source of heavy metals in urban contamination. Results of this study present a rough guide about the distribution and potential environmental and health risk of heavy metals in the urban soils.  相似文献   

13.
The atmospheric levels of carbon dioxide (CO2) and other greenhouse gases (GHGs) have increased dramatically since the industrial revolution. The atmospheric enrichment with CO2 and other GHGs has resulted in multiple negative consequences: such as the increase in the average temperature and the rise of the sea level. Hence, there is a growing interest in developing feasible methods to reduce the atmospheric levels of these gases. One of these strategies is to enhance C sequestration through the increase of soil organic carbon (SOC) pool by the amendment of agricultural soils with sewage sludge. However, there is considerable uncertainty about the effects (positive or negative) of sewage sludge applications on the SOC pool. Thus, a simple approach developed under laboratory conditions is presented to discern the effect of a single sewage sludge application of 50 t ha−1 on the short-term SOC pool in 60 contrasting agricultural soils. The role of soil factors in the C sequestration of the recently added carbon was also studied. The application of sewage sludge supposed a mean increase of 1.7 ± 1.6 g SOC kg−1, with peak increases of up to 3.8 g SOC kg−1 and decreases of up to 4.6 g SOC kg−1. The initial SOC contents conditioned the C sequestration after sewage sludge application, and no other soil property was related.  相似文献   

14.
Detailed magnetic measurements and geochemical analyses were performed on 114 sediment samples collected from the East Lake, Wuhan city, China, to establish a possible link between the enhanced concentration of anthropogenic magnetic particles and heavy metals with known sources. Relatively higher magnetic susceptibility values (mass-specific, χ, >150 × 10−8 m3 kg−1) were observed for samples near the pollution sources: e.g. the Wuhan Iron and Steel Company (WISC), the Qingshan Thermal Power Plant (QTPP), the banks (driveways) of the lake and near the sightseeing route of yachts on the lake. Moreover, χ is positively correlated to the concentration of Pb (correlation coefficient r = 0.682), but negatively or weakly correlated with both Zn and Cu. In contrast, anhysteretic remanent magnetization (ARM) is significantly correlated with these major heavy metals (r = 0.645 for Zn–ARM, 0.699 for Pb–ARM and 0.841 for Cu–ARM, respectively), which indicate that ARM serves a better indicator for the pollution of heavy metals in this lake. Thermomagnetic analysis combined with magnetic hysteresis measurements revealed that magnetites in the pseudo-single-domain/multidomain grain-size regions are dominant. Scanning electron microscopy and energy dispersive X-ray examinations of the magnetic extracts showed that these Fe-rich particles have different morphologies: orange-peel structure, hollow structure with adhered smaller particles, Zr-rich melted-like irregular particles, pear-shaped spherules and spherules with slick surfaces. These features are typical for particles produced by anthropogenic activities. Because of the genetic relationship between the environmental setting of the East Lake and the nearby pollution sources, this study suggests that in situ magnetic surveys are sensitive to evaluate the environmental pollution on the lake bottom.  相似文献   

15.
Copper contamination in soils and vegetables in the vicinity of an abandoned copper mine in China was investigated. The Cu concentrations of 93 soil samples ranged from 30.4 to 3,191 mg kg−1 soil for a mean of 816.8 mg kg−1 soil. Among 15 samples from a 0 to 20-cm soil layer used for the toxicity characteristic leaching procedure (TCLP) test, the highest value of Cu-TCLP was 133.8 mg kg−1 soil and the TCLP values were positively correlated with the total Cu content of the soils. The sequential extraction of soils in the 0–20-, 20–40-, and 40–60-cm soil layers showed that Cu existed mainly in the Fe–Mn oxide fraction, sulfide/organic fraction, and residual fraction. The copper contamination of 21 species of vegetables from in situ sampling was also examined. Cu concentrations in the edible portions of Brassica chinensis and Solanum melongena were higher than the FAO/WHO standard (40 mg kg−1 DW). The health risk of copper for local inhabitants from consuming these vegetables was assessed on the basis of the target hazard quotient. Enriched concentrations of copper were also found in situ in eight cultivars of B. chinensis planted in the fields, with two levels of Cu concentration. The results showed that there is severe copper contamination in this mine area, and the pollutant in soils show a high risk of leaching into the groundwater and diffusing through the food chain.  相似文献   

16.
Natural radioactivity in sediment of Wei River,China   总被引：1，自引：0，他引：1  
The concentrations of natural radionuclides in sediment of Wei River of China were measured using γ-ray spectrometry with the aim of estimating the radiation hazard as establishing a database for radioactivity levels of river sediment of China. The activity concentrations of 226Ra, 232Th and 40K in sediment samples ranged from 10.4 to 39.9 Bq kg−1, 15.3 to 54.8 Bq kg−1 and 514.8 to 1,175.5 Bq kg−1, respectively. The concentrations of these radionuclides were compared with the typical world values and the average activities of Chinese soil and Shaanxi soil. Radium equivalent activity (Raeq), external hazard index (H ex) and representative level index (I γr) were calculated for the samples to assess the radiation hazards arising due to the use of these sediment samples in the construction of dwellings. All the sediment samples have Raeq lower than the limit of 370 Bq kg−1, H ex less than unity and I γr close to 1 Bq kg−1. The overall mean outdoor terrestrial gamma dose rate is 64.8 nGy h−1 and the corresponding outdoor annual effective dose is 0.079 mSv. None of the studied location is considered a radiological risk and sediment can be safely used in construction.  相似文献   

17.
The structural attributes and zonation patterns of mangrove forests in a dry environmental setting were evaluated in relation to gradients of soil resources, soil regulators, and hydroperiod between October 2000 and August 2001 in the Gulf of Fonseca, Honduras. Transects perpendicular to the edge of tidal channels were established at four mangrove sites, each sectioned into three mangrove zones (fringe, transition, and scrub) based upon distinct tree-height gradients. Porewater sulfide concentrations among zones were normally below levels of detection (<0.03 mM) and mean redox values ranged from 163.4±9.9 to −42.4±15.8 mv, indicating slightly reducing conditions in all zones. Mean porewater NOx − and PO4 3− concentrations were not significantly different among zones and ranged from 3.3±0.5 to 4.5±0.4 μM and from 0.05 ±0.02 to 0.18±0.04 μM, respectively. Soil nitrogen concentrations were 1–3 mg g−1 in all zones, and mean nitrogen:phosphorus atomic ratios were <20 (range: 12.9–14.9), indicative of fertile wetland soils. Mean basal areas were significantly different among mangrove zones (fringe > transition) and were coupled with differences in height within species and zones.Avicennia germinans occupied areas with higher elevations associated with higher salinities ranging from 80 to 140 g kg−1 in the dry season.Rhizophora mangle dominated lower elevations where salinities ranged from 38 to 57 g kg−1 in both the dry and wet seasons. Spatial analysis on mangrove seedlings along transects confirmed that seedling distribution along the intertidal profile was statistically correlated with conspecific adults, indicating that survival and growth of seedlings in different intertidal locations are closely matched to canopy membership. The sharp transition (<100 m) in forest structure and distribution of mangrove species along the intertidal zone of subhumid coastal environments demonstrate common zonation patterns where species distribution and species-specific habitat suitability are mediated closely with tolerance to soil regulators (high soil salinity) rather than resource availability.  相似文献   

18.
A barrier system based on the hydraulic trap design concept for a landfill was proposed. To study the field scenario in which a clay liner is underlain by a granular layer functioning as a secondary leachate drain layer, a laboratory advection–diffusion test was performed to investigate factors controlling the transport of contaminants in a two-layer soil system. The soils used for this study were Ariake clay and, the underlying layer, Shirasu soil from the Kyushu region of Japan. Potassium (K+) was selected as the target chemical species with an initial concentration of 905 mg L−1. The effective diffusion coefficients (D e) of K+ for Ariake clay and Shirasu soil were back-calculated using an available computer program, Pollute V 6.3. Values of D e derived from this experiment are consistent with previously published ones. The Ariake clay has lower D e than the Shirasu soil. The hypothesis that mechanical dispersion can be considered negligible is reasonable based on both the observation that the predicted values well fit the experimental data and the analyses of two dimensionless parameters. Parametric analyses show that transport of K+ through soils is controlled by advection–diffusion rather than diffusion only, whereas at low Darcy velocity (i.e., ≤10−9 m s−1), transport of K+ will be controlled by diffusion. Applications of the test results and parametric analysis results in practical situations were reviewed.  相似文献   

19.
Anthropogenic influence, mainly due to urban and industrial activities and traffic exhaust, may affect urban topsoil via atmospheric contamination and solid waste. Magnetic susceptibility measurements were conducted on 21 urban topsoil samples from the city of Xuzhou, China. High intensities of magnetic susceptibility were detected in the majority of the samples. SEM analysis shows that magnetic minerals are in the form of spherules and mainly due to anthropogenic inputs. The heavy metals Pb, Cu, Zn, Se, Sc, Mo, Fe, and Bi show strong correlations with magnetic susceptibility, and Ag, Ba, Cd, Ni, Cr, Sb, and Sn, on the other hand, show a weak correlation with magnetic susceptibility. Whereas, of these metals studied, only Hg has no significant correlation with the susceptibility. The Tomlinson pollution load index (PLI) also shows significant correlation with the susceptibility (χ). The present study shows that magnetic susceptibility is a fast, inexpensive, and non-destructive method for the detection and mapping of contaminated soils.  相似文献   

20.
We investigated the effects on phosphorus (P) release of the addition of potato, wheat, and sunflower residues and fruit compost to five calcareous soils. Residue was added at the rate of 20 g kg−1. After 2 months of incubation, P values in control and amended soils were used for kinetic studies and fractionated by a sequential extraction procedure. The relative contribution of available P fraction (KCl-P) increased from 1.4% in control soils to 1.8%, 1.9%, 2.2%, and 2.3% in soils amended by fruit, wheat, potato, and sunflower residue addition, respectively, indicating that organic residues increased P in this fraction. In soils amended with different residues, the percentage of Olsen-P released over 86-h successive extractions with 0.01 M CaCl2 ranged from 57.6% for fruit residue addition (average of five soils) to 60.5% for potato residue addition. The ability of residues to release P depended on the soil properties, with 21.9 mg kg−1 (average of all residues) released to soil 2 and 77.4 mg kg−1 released to soil 4. Also residues behaved differently, with 31.5 mg kg−1 (average of five soils) released by fruit residues and 40.0 mg kg−1 released by sunflower residues. Release of P was best described by a parabolic diffusion model. The corresponding rate constant (mg kg−1 h−1/2) for P release for amended soils, defined as the release rate averaged for five soils, was found to decrease in the order: potato (2.73) > sunflower (2.61) > wheat (2.56) > fruit (2.50). The present study demonstrates that addition of residues improves P availability of these calcareous soils by increasing extractable P and the release rate and could be an alternative, indigenous source of P. However, the increase in P availability and the release rate following organic residue application suggests high potential mobility to water sources.  相似文献   

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