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1.
苏鲁仰口超高压岩石SHRIMP锆石U/Pb定年与部分熔融时限   总被引:5,自引:4,他引:1  
在大型碰撞造山带中,在陆壳物质深俯冲或快速折返早期,在超高压-高压条件下,易熔组分可能发生水致或脱水部分熔融,形成花岗质熔体。在超高压-高压条件下,苏鲁超高压岩石发生过部分熔融作用,形成长英质多晶体包裹体和不同尺度的花岗质岩石, 导致可观的地球化学效应。为确定苏鲁超高压岩石部分熔融的时限,对山东仰口超高压副片麻岩和其中平行片麻理的同构造钾质花岗岩脉进行了SHRIMP锆石U/Pb地质年代学、全岩地球化学和锆石内矿物包裹体的研究。副片麻岩的锆石具有典型的核-幔-边结构。核部锆石为碎屑锆石,206Pb/238U年龄大于282Ma,可能反映了副片麻岩的原岩包含不同成因的物质;幔部和边部的Th/U比都小于0.1,分别给出233±3Ma和214±4Ma的206Pb/238U 年龄,分别对应于超高压变质和角闪岩相退变质年龄。同构造花岗岩脉是富钾过铝质花岗岩(A/CNK=1.2),锆石也具有核-幔-边结构;核部锆石年龄与副片麻岩的核部锆石年龄相当,反映了该花岗岩脉的源区可能是变沉积岩;除幔部锆石的一个点具有206Pb/238U年龄为234.6±3.9Ma之外,其它幔部锆石位于谐和线附近,给出206Pb/238U年龄为220.8±2.9Ma, 该年龄代表着该花岗岩脉的形成年龄。上述数据表明,在仰口地区,超高压岩石的部分熔融作用早于角闪岩相退变质作用。  相似文献   

2.
Coesite‐bearing eclogites from >100 km2 in the southern Dulan area, North Qaidam Mountains (NQM) of western China, contain zircon that records protolith crystallization and ultra high pressure (UHP) metamorphism. Sensitive High‐Resolution Ion Microprobe (Mass Spectrometer) and Laser Ablation Inductively Coupled Plasma Mass Spectrometry U–Pb analyses from cathodoluminescence (CL)‐dark zircon cores in a coesite‐bearing eclogite yield an upper intercept age of 838 ± 50 Ma, and oscillatory zoned cores in a kyanite‐bearing eclogite gave a weighted mean 206Pb/238U age of 832 ± 20 Ma. These zircon cores yield steep heavy rare earth element (HREE) slopes and negative Eu anomalies that suggest a magmatic origin. Thus, c. 835 Ma is interpreted as the eclogite protolith age. Unzoned CL‐grey or ‐bright zircon and zircon rims from four samples yield weighted mean ages of 430 ± 4, 438 ± 2, 446 ± 10 and 446 ± 3 Ma, flat HREE patterns without Eu anomalies, and contain inclusions of garnet, omphacite, rutile, phengite and rare coesite. These ages are interpreted to record 16 ± 5 Myr of UHP metamorphism. These new UHP ages overlap the age range of both eclogite and paragneiss from the northern Dulan area, suggesting that all UHP rock types in the Dulan area belong to the same tectonic unit. Our results are consistent with slow continental subduction, but do not match oceanic subduction and diapiric exhumation UHP model predictions. These new data suggest that, similar to eclogites in other HP/UHP units of the NQM and South Altyn Tagh, protoliths of the eclogites in the Dulan area formed in a continental setting during the Neoproterozoic, and then subducted to mantle depth together with continental materials during the Early Palaeozoic.  相似文献   

3.
A variety of eclogites from an east-west transect across the North-East Greenland eclogite province have been studied to establish the timing of high pressure (HP) and ultrahigh-pressure (UHP) metamorphism in this northern segment of the Laurentian margin. Garnet + omphacite ± amphibole + whole rock Sm-Nd isochrons from a quartz eclogite, a garnet + omphacite + rutile eclogite and a partially melted zoisite eclogite in the western HP belt are 401±2, 402±9 and 414±18 Ma, respectively. Corresponding sensitive high-resolution ion microprobe (SHRIMP) 206Pb/238U ages of metamorphic zircon in the same samples are 401±7, 414±13, and 393 ±10 Ma. Metamorphic zircon domains were identified using morphology, cathodoluminescence (CL) imaging, U, Th, Th/U and trace element contents. Zircon from the quartz eclogite and the garnet + omphacite + rutile eclogite are typical of eclogite facies zircon with rounded to subhedral shapes, patchy to homogenous CL domains, low U, and very low Th and Th/U. The partially melted eclogite contains euhedral zircons with dark, sector-zoned, higher U, Th and Th/U inherited cores. Three cores give a Paleoproterozoic 207Pb/206Pb age of 1,962±27 Ma, interpreted as the age of the leucogabbroic protolith. CL images of the bright overgrowths show faint oscillatory zoning next to homogenous areas that indicate zircon growth in the presence of a HP melt and later recrystallization. Additional evidence that zircon grew during eclogite facies conditions is the lack of a Eu anomaly in the trace element data for all the samples. These results, combined with additional less precise Sm-Nd ages and our earlier work, point to a Devonian age of HP metamorphism in the western and central portions of the eclogite province. An UHP kyanite eclogite from the eastern part of the transect contains equant metamorphic zircon with homogeneous to patchy zoning in CL and HP inclusions of garnet, omphacite and kyanite. These zircons have slightly higher U, Th and Th/U values than the HP ones, no Eu anomaly, and are thus comparable to UHP zircons in the literature. The 206Pb/238U age of these zircons is 360±5 Ma, much younger than the HP eclogites. The same sample gives a Sm-Nd age of 342±6 Ma. Unlike the HP eclogites, the Sm-Nd age of the UHP rock is ca. 20 Ma younger than the U-Pb zircon age and most likely records slow cooling through the closure temperature, since peak temperatures were in excess of 900°C. Widespread HP metamorphism of both the Laurentian and Baltica continental margins marks the culmination of this continent–continent collision in the Devonian. Carboniferous UHP conditions, though localized in the east, suggest a prolonged collisional history rather than a short-lived Scandian orogeny. The traditional Silurian Scandian orogeny should thus be extended through the Devonian.  相似文献   

4.
本文报道了安徽洪镇地区董岭群片麻岩中高精度的独居石SIMS U-Th-Pb定年结果,以~(207)Pb含量为基准对普通Pb进行校正后得到~(206)Pb/~(238)U的加权平均年龄为128.4±0.7 Ma(MSWD=1.6),~(208)Pb/~(232)Th年龄的加权平均值为128.6±0.4 Ma(MSWD=1.4)。作者认为独居石的SIMS U-Th-Pb年龄(128.4±0.7 Ma)代表了董岭群片麻岩的前进变质年龄。综合区域地质资料,提出董岭群片麻岩为新元古代沉积物在中生代经岩浆热动力接触变质的产物。这一发现不仅否定了前人提出的董岭群为前寒武纪区域变质地体的观点,而且否定了这一地区的"洪镇变质核杂岩",对进一步研究中国东部零星出露的中高级片麻岩的大地构造属性和构造演化具有借鉴意义。  相似文献   

5.
We report SHRIMP U–Pb age of zircons in four samples of eclogite and one sample of orthogneiss from Sulu ultrahigh-pressure (UHP) zone in Yangkou area, eastern China. UHP rocks are distributed along the Sulu orogenic belt suturing North China Block with South China Block. In Yangkou area, UHP unit is well exposed for about 200 m along Yangkou beach section and consists mainly of blocks or lenses of ultramafic rocks and eclogite together with para- and orthogneiss which are highly sheared partly. Zircon grains examined in this study from eclogite show oscillatory zoning and overgrowth texture in CL images, and most of the grains have high Th/U ratio ranging from 0.8 to 2.1 indicating an igneous origin. The weighted mean 206Pb/238U ages of zircons from the four samples range from 690 to 734 Ma. These ages can be correlated to the magmatic stage of the protoliths. In rare cases, zircon grains possess a narrow rim with very low Th/U ratio (< 0.02). EPMA U–Th-total Pb dating of such rim yields younger ages that range from 240 to 405 Ma marking the metamorphic stage. On the other hand, zircons from the orthogneiss show irregular shape and zoning with inclusion-rich core and inclusion-free rim. These grains of zircon yield U–Pb discordia intercept ages of 226 ± 63 Ma and 714 ± 110 Ma (MSWD 0.78). Bulk of the areas of the rims rim of the zircons demonstrate younger 206Pb/238U ages close to the upper intercept, with low Th/U ratio (< 0.20) indicating their metamorphic origin. In contrast, the cores show older 206Pb/238U ages close to lower intercept and high Th/U ratio of (0.14–5.25) indicating their igneous origin. The upper intercept age is also commonly noted in zircons from eclogite. Our results suggest a bimodal igneous activity along this zone during the Neoproterozoic, probably related to the rifting of the Rodinia supercontinent.  相似文献   

6.
道伦达坝矿床位于大兴安岭南段,是一个铜钨锡矿床,其铜、钨、锡储量均达中型。矿体呈脉状,主要产于二叠系砂板岩中的断裂破碎带中,华力西期黑云母花岗岩中的断裂破碎带中亦赋存有矿体。文章选取2件石英-萤石-白云母-电气石-锡石-黑钨矿阶段的矿石样品对其中的进行了LA-ICP-MS U-Pb定年,获得2件样品的~(207)Pb/~(206)Pb-~(238)U/~(206)Pb谐和年龄分别为(134.7±6.6)Ma(MSWD=1.4)和(136.8±7.4)Ma(MSWD=1.7),~(206)Pb/~(207)Pb-~(238)U/~(207)Pb等时线年龄分别为(132±12)Ma(MSWD=0.76)和(135±13)Ma(MSWD=0.9)。锡石定年结果表明,道伦达坝矿床形成于早白垩世。对矿区外围张家营子岩体中的斑状细粒花岗岩进行了LA-ICP-MS锆石U-Pb测年,获得的~(206)Pb/~(238)U加权平均年龄为(135±1)Ma(MSWD=1.3),该岩体的形成年龄与道伦达坝矿床的成矿年龄在误差范围内一致。本次定年结果表明道伦达坝矿床形成于早白垩世,与同期的花岗质岩浆活动有密切的成因联系,该矿床属于与花岗岩有关的岩浆热液脉型矿床。  相似文献   

7.
In this study, we link mineral inclusion data, trace element analyses, U-Pb age and Hf isotope composition obtained from distinct zircon domains of complex zircon to unravel the origin and multi-stage metamorphic evolution of amphibolites from the Sulu ultrahigh-pressure (UHP) terrane, eastern China. Zircon grains separated from amphibolites from the CCSD-MH drill hole (G12) and Niushan outcrop (G13) were subdivided into two main types based on cathodoluminescence (CL) and Laser Raman spectroscopy: big dusty zircons with inherited cores and UHP metamorphic rims and small clear zircons. Weakly zoned, grey-white luminescent inherited cores preserve mineral inclusions of Cpx + Pl + Ap ± Qtz indicative of a mafic igneous protolith. Dark grey luminescent overgrowth rims contain the coesite eclogite-facies mineral inclusion assemblage Coe + Grt + Omp + Phe + Ap, and formed at T = 732-839 °C and P = 3.0-4.0 GPa. In contrast, white luminescent small clear zircons preserve mineral inclusions formed during retrograde HP quartz eclogite to LP amphibolite-facies metamorphism (T = 612-698 °C and P = 0.70-1.05 GPa). Inherited zircons from both samples yield SHRIMP 206Pb/238U ages of 695-520 Ma with an upper intercept age of 800 ± 31 Ma. The UHP rims yield consistent Triassic ages around 236-225 and 239-225 Ma for G12 and G13 with weighted means of 229 ± 3 and 231 ± 3 Ma, respectively. Small clear zircons from both samples give 206Pb/238U ages around 219-210 Ma with a weighted mean of 214 ± 3 Ma, interpreted as the age of retrograde quartz eclogite-facies metamorphism. Matrix amphibole from both samples indicate Ar-Ar ages of 209 ± 0.7 and 207 ± 0.7 Ma, respectively, probably dating late amphibolite-facies retrogression. The data suggest subduction of Neoproterozoic mafic igneous rocks to UHP conditions in Middle Triassic (∼230 Ma) times and subsequent exhumation to an early HP (∼214 Ma) and a late LP stage (∼208 Ma) over a period of ∼16 and 6 Myr, respectively. Thus, early exhumation from a mantle depth of 120-100 km to about 60 km occurred at an average rate of 0.3 cm/y, while subsequent exhumation to a middle crustal level took place at approximately 0.54 cm/y. These exhumation rates are considerably slower than those obtained for UHP rocks in the Dora Maira and Kokchetav massifs (2-3 cm/y).Based on similar P-T estimates and trace element and Hf isotope compositions, Sulu amphibolites can be identified as retrograde UHP eclogites. The εHf(800) of +8 implies a significant input from the depleted mantle to the Sulu-Dabie terrane during the middle Neoproterozoic. Overgrown rims are characterized by a distinct trace element composition with low Lu/Hf and Th/U and significantly higher 176Hf/177Hf ratios than inherited cores, consistent with formation during/after garnet (re-)crystallization and fractionation of the Lu-Hf system during UHP metamorphism. The combined dataset suggests homogenization of the 176Hf/177Hf ratio within the metamorphic mineral assemblage and during protolith formation. Observed variations are explained by mixing of material from both domains during laser ablation, e.g., due to partial recrystallization of inherited cores.  相似文献   

8.
吉林省塔东群以含大型磁铁矿床而著称,塔东铁矿是吉黑成矿省内最大的火山喷流沉积-变质改造型铁矿.由于塔东群地质特征复杂,多种地质作用复合叠加,使其形成时代归属一直存在争议.通过LA-ICP-MS锆石定年,确定了吉林省塔东群黑云斜长片麻岩和磁铁透辉斜长变粒岩中锆石年代.黑云斜长片麻岩中锆石呈长柱状,Th/U值为0.17~0.65,206Pb/238U加权平均年龄为517.6±2.7 Ma,代表了其原岩火山岩形成的年龄.磁铁透辉斜长变粒岩中共有两组锆石年龄,其中一组短柱状,Th/U值介于0.78~1.00,加权平均年龄为249.8±4.0 Ma,代表后期热事件年龄;另一组锆石半自形短柱状晶形,异常高的U、Th, Th最高含量可达17 422 μg/g,206Pb/238U加权平均年龄为518.3±3.8 Ma,表示热液活动年龄,显示该区518.3 Ma左右经历了一次热液作用,可能与该区的岩浆作用以及塔东铁矿的成矿有关.据此,塔东群内塔东铁矿可能存在一期早寒武世 (±520 Ma) 的成矿作用.   相似文献   

9.
本文对福建东山县澳角村澳角群花岗质石榴黑云片麻岩中17颗锆石进行了SHRIMP U-Pb同位素年龄测定。结果显示锆石Th/U比值变化于0.31~1.01,平均值为0.48,为典型的岩浆锆石;其中16个分析点在谐和图上分布较为集中,206Pb/238U年龄加权平均值为(152.8±1.6)Ma(n=17,MSWD=1.12);结合锆石自形、发育岩浆环带等特点,该年龄被解释为澳角群亲营山组花岗质石榴黑云片麻岩的形成年龄。其所指示的地质意义:(1)福建东山县澳角村澳角群亲营山组花岗质石榴黑云片麻岩形成于晚侏罗纪,而非前泥盆纪;(2)福建东山县澳角村澳角群亲营山组应解体为表壳岩与变质侵入体。  相似文献   

10.
关于额尔古纳地块基底性质和东界的讨论   总被引:9,自引:0,他引:9       下载免费PDF全文
中国东北地区是解决东亚大陆构造演化的关键地区,备受众多学者关注。近年来,关于额尔古纳地块基底性质和东界问题一直存在争议。本文对太平林场花岗片麻岩进行了锆石LA-ICP-MS U-Pb测年,锆石年龄主要集中在840~830 Ma、800~780 Ma和730~720 Ma的3个时间段内,可能为新元古代时期的3期岩浆热事件时间。其中21个锆石测点 206Pb/238U 年龄的加权平均值为779±20 Ma(MSWD=8.3),表明原岩在新元古代就已侵位结晶; 1个锆石测点U-Pb同位素年龄为494±10 Ma,Th/U比值为0.06,暗示了锆石应为变质成因,可能为花岗片麻岩的变质年龄。结合前人已报道额尔古纳地块和兴安地块上花岗质岩石年龄数据,对比发现仅额尔古纳地块经历了新元古代岩浆热事件作用; 同时对比两地块上花岗岩Hf同位素特征发现,二者具有不同的地壳早期演化阶段。因此,在早古生代早期二者应该沿塔河-喜桂图缝合带拼合并共同经历了古生代以来的岩浆作用改造,而不是传统观点认为的德尔布干断裂作为两地块的边界。  相似文献   

11.
The Dabaoshan polymetallic deposit in northern Guangdong Province contains iron, copper, lead, zinc, molybdenum, tungsten and sulfur mineral resources. Porphyry-type Mo(W) and skarn-type Mo-W mineralization occurs along the internal and external contact zones of the granodioritic porphyry, respectively. LA-ICP-MS U–Pb dating of zircons from two granodioritic porphyry samples yielded a weighted mean 206Pb/238U age of 175.8 ± 1.5 Ma (MSWD = 0.037) and 175.0 ± 1.7 Ma (MSWD = 0.41). They can be pooled together to yield a combined weighted age of 175.4 ± 1.6 Ma (MSWD = 0.26), which is interpreted as the emplacement age of the granodioritic porphyry. Re–Os dating of three molybdenite samples from porphyry and skarn ores yielded consistent model ages of 163.2 ± 2.3 Ma to 165.2 ± 2.4 Ma, with a weighted mean of 163.9 ± 1.3 Ma (MSWD = 0.81), which is the age of Mo–W mineralization. These ages are consistent with the molybdenite Re–Os model age (164.7 ± 3 Ma) measured by Mao et al. (2004a) for the stratiform Cu–Pb–Zn orebody, and they can yield a weighted mean of 164.0 ± 2.5 Ma (MSWD = 0.16). This implies that Mo–W and Cu–Pb–Zn mineralization in the Dabaoshan polymetallic deposit are the products of one mineralization event. The mineralization in the deposit coincides closely with that of Mo-polymetallic mineralization (164–149 Ma) elsewhere in the Nanling region, comprising an important polymetallic metallogenic belt of south China, and corresponds to the second episode of Mesozoic metallogenesis in South China. Combined with previous studies, we suggest that the Dabaoshan polymetallic deposit is related to post-collisional lithosphere extension in the Nanling region of South China. Geological data and Pb isotopic evolution diagrams, together with stable isotopic data of fluid inclusions (δ18O = − 3.75–7.0‰, δD = − 50.7 to − 56.1‰) and ore sulfides (δ34S = − 2–3‰), suggest a genetic relationship between the Dabaoshan polymetallic deposit, the granodioritic porphyry and the dacitic porphyry. These data, combined with the Re content (64.7 to 102.4 ppm) of molybdenite, indicate that the ore-forming components were derived from mixed crustal and mantle sources.  相似文献   

12.
We present the results of a comparative study of several geochronometer minerals (baddeleyite, zircon, apatite, phlogopite and tetraferriphlogopite) and isotopic systems (U-Pb, Th-Pb and Rb-Sr) from phoscorites (magnetite-forsterite-apatite-calcite rocks) and carbonatites of the Kovdor ultramafic-alkaline-carbonatite massif, Kola Peninsula, Russia. Uranium, thorium and their decay products are extremely fractionated by minerals that crystallise from carbonatite and phoscorite magma. We obtain high-precision ages from different chronometers, compare their accuracy, and evaluate the role of geochronological pitfalls of initial radioactive disequilibrium, differential migration of radiogenic isotopes, and inaccurate decay constants.Apatite yielded concordant U-Th-Pb ages between 376 and 380 Ma. The accuracy of the apatite 238U-206Pb ages is, however, compromised by uncertainty in the amount of radiogenic 206Pb produced from initial excess 230Th. The 235U-207Pb ages are relatively imprecise due to large common Pb correction and the uncertainty in the initial Pb isotopic composition. The Th-Pb system yields a more precise age of 376.4 ± 0.6 Ma.Zircon from two carbonatite samples is characterised by moderate to low U contents, high Th contents, and very high Th/U ratios up to 9000. The 206Pb*/238U systems in the zircon are strongly affected by the presence of excess 206Pb*, produced by decay of initial 230Th. The 208Pb*/232Th ages of zircon from both carbonatite samples are uniform and yield a weighted average of 377.52 ± 0.94 Ma.Baddeleyite U-Pb analyses are 3 to 6% normally discordant and have variable 207Pb*/206Pb* apparent ages. Eleven alteration-free baddeleyite fractions from three samples with no evidence for Pb loss yield uniform 206Pb*/238U ages with a weighted average of 378.54±0.23 Ma (378.64 Ma after correction for initial 230Th deficiency), which we consider the best estimate for age of the phoscorite-carbonatite body of the Kovdor massif. The 206Pb*/238U ages of baddeleyite fractions from five other samples spread between 378.5 and 373 Ma, indicating a variable lead loss up to 1.5%. The anomalously old 207Pb/235U and 207Pb/206Pb ages are consistent with the presence of excess radiogenic 207Pb* in the baddeleyite. We interpret this as a result of preferential partitioning of 231Pa to baddeleyite.Fifteen phlogopite and tetraferriphlogopite fractions from five carbonatite and phoscorite samples yielded precise Rb-Sr isochron age of 372.2 ± 1.5 Ma, which is 5 to 7 m.y. younger than our best estimate based on U-Th-Pb age values. This difference is unlikely to be a result of the disturbance or late closure of Rb-Sr system in phlogopite, but rather suggests that the accepted decay constant of 87Rb is too high.Comparative study of multiple geochronometer minerals from the Kovdor massif has revealed an exceptional complexity of isotopic systems. Reliable ages can be understood through systematic analysis of possible sources of distortion. No single geochronometer is sufficiently reliable in these rocks. Th-Pb and Rb-Sr can be a very useful supplement to U-Pb geochronometry, but the routine use of these geochronometers together will require more precise and accurate determination of decay constants for 232Th and 87Rb.  相似文献   

13.
西藏东部类乌齐一带吉塘岩群中新识别出一套花岗质片麻岩。花岗质片麻岩中锆石Th/U比值较高(Th/U0.49),阴极发光图像显示锆石内部韵律环带明显,具典型岩浆锆石成因的特征。Cameca锆石U-Pb同位素加权平均年龄为282.1Ma±0.9Ma,表明花岗岩岩体形成于早二叠世,暗示澜沧江结合带在早二叠世存在岩浆增生事件。  相似文献   

14.
The Spessart Crystalline Complex, north-west Bavaria contains two orthogneiss units of granitic to granodioritic composition, known as the Rotgneiss and Haibach gneiss, respectively, which are structurally conformable with associated metasediments. The igneous origin of the Rotgneiss is apparent from field and textural evidence, whereas strong deformation and recrystallization in the Haibach gneiss has obscured most primary textures. New geochemical data as well as zircon morphology prove the Haibach gneiss to be derived from a granitoid precursor, which was chemically similar to the Rotgneiss protolith, thus suggesting a genetic link between those two rock units. Both gneiss types have chemical compositions typical of anatectic two-mica leucogranites. They show characteristics of both I- and S-type granites. Rb-Sr whole rock data on the Haibach gneiss provide an isochron age of 407±14 Ma (IR = 0.7077±0.0007; MSWD 2.2), which is slightly younger than the published date for the Rotgneiss (439±15 Ma; IR=0.7048±0.0026; MSWD 4.9). Single zircon dating of six idiomorphic grains, using the evaporation method, yielded a mean 207Pb/206Pb age of 410±18 Ma for the Haibach gneiss and 418±18 Ma for the Rotgneiss. Both zircon ages are within analytical error of the Rb-Sr isochron dates and are interpreted to reflect the time of protolith emplacement in Silurian times. Three xenocrystic zircon grains from the Rotgneiss yielded 207Pb/206Pb ages of 2278±12, 2490±13 and 2734±10 Ma, respectively, suggesting that late Archaean to early Proterozoic crust was involved in the generation of the granite from which the Rotgneiss is derived. Although it is assumed that the granitic protoliths of the two gneisses were formed through anatexis of older continental crust, the relatively low 87Sr/86Sr initial ratios of both gneisses may also indicate the admixture of a mantle component. The Rotgneiss and the Haibach gneiss thus document granitic magmatism at an active continental margin during late Silurian times.  相似文献   

15.
The U-Pb geochronology of perovskite is a powerful tool in constraining the emplacement age of silica-undersaturated rocks. The trace-element and U-Pb isotopic compositions of perovskite from clinopyroxenite and silicocarbonatite from the Afrikanda plutonic complex (Kola, Russia) were determined by laser-ablation inductively-coupled mass-spectrometry (LA-ICP-MS). In addition, the Sr isotopic composition of perovskite was measured by isotope-dilution mass-spectrometry to better constrain the relations between its host rocks. Perovskite from the two rock types shows a different degree of enrichment in Na, Mg, Mn, Pb, Fe, Al, V, rare-earth elements, Zr, Hf, Th, U and Ta. The perovskite 87Sr/86Sr values are within analytical uncertainty of one another and fall within the range of mantle values. The 206Pb/238U ages (corrected for common lead using 207Pb-method) of perovskite from silicocarbonatite statistically yield a single population with a weighted mean of 371?±?8 Ma (2σ; MSWD?=?0.071). This age is indistinguishable, within uncertainty, to the clinopyroxenite weighted mean 206Pb/238U age of 374?±?10 Ma (2σ; MSWD?=?0.18). Our data are in good agreement with the previous geochronological study of the Afrikanda complex. The observed variations in trace-element composition of perovskite from silicocarbonatite and clinopyroxenite indicate that these rocks are not related by crystal fractionation. The Sr isotopic ratios and the fact that the two rocks are coeval suggest that they were either produced from a single parental melt by liquid immiscibility, or from two separate magmas derived at different degrees of partial melting from an isotopically equilibrated, but modally complex mantle source.  相似文献   

16.
Cathodoluminescence-controlled radiometric dating (U–Pb SHRIMP) was carried out on zircon domains from metabasic rocks of the Chiavenna unit, a major mafic/ultramafic-bearing unit in the Central Alps. Co-magmatic zircon domains from amphibolites near Chiavenna and Prata areas yielded weighted mean 206Pb/238U ages at 93.0±2.0 and 93.9±1.8 Ma, respectively, interpreted as the age of crystallization of the magmatic protoliths. These ages fit well with the time of late spreading in the Valais Ocean, as suggested by previous paleogeographic reconstructions. Inherited zircon grains and/or core domains (Permo-Triassic, Carboniferous, Proterozoic) are abundant, indicating proximity of the Chiavenna unit to thinned continental crust. This is in line with the origin of this unit from subcontinental mantle sources, as suggested previously on petrological and structural grounds. Metamorphic zircon domains from one amphibolite near Chiavenna yielded a weighted mean 206Pb/238U age at 37.1±0.9 Ma, identical to the 38.5±0.9 Ma SHRIMP age of an amphibolitized eclogite of the Antrona ophiolites (Valais domain, Western Alps). Precise metamorphic ages were difficult to obtain from the composite (poly)metamorphic rim domains of the Prata amphibolite. This is attributed to the location of the Prata area close to the granulite-facies Gruf unit (metamorphosed at ca. 33 Ma) and to the 24–25 Ma old Novate granite, where metamorphic/fluid events probably caused multiple resetting to various degrees. The ca. 93 Ma old magmatism, identified for the first time in the Chiavenna unit, is the youngest basic oceanic magmatism reported in the Alps. The 37.1±0.9 Ma old metamorphism in the Chiavenna unit, attributed to the Valais domain, confirms the model suggesting stepwise younging of metamorphic ages from the south (Adriatic plate) to the north (European plate). It is older than metamorphism in the European margin (ca. 35–31 Ma) lying to the north of the Valais domain and younger than that in the Piemont–Ligurian Ocean (ca. 44–45 Ma) lying to the south of the Valais domain.Editorial responsibility: W. Schreyer  相似文献   

17.
浙西北平水铜矿细碧角斑岩成岩年龄及其地质意义   总被引:2,自引:0,他引:2       下载免费PDF全文
文章对浙西北平水铜矿赋矿围岩双溪坞群平水组细碧角斑岩中锆石进行了LA-ICP-MS U-Pb同位素年龄测定。结果显示锆石Th/U比值为0.42~2.28,明显高于Th/U比值小于0.1的变质成因的锆石,为典型岩浆成因锆石。几乎所有的锆石颗粒样品都投影在谐和曲线上及其附近,细碧岩年龄加权平均值为(952±5)Ma(n=18,MSWD=0.19),角斑岩年龄加权平均值为(954±8)Ma(n=15,MSWD=0.51);结合锆石自形、发育岩浆环带等特点,该年龄是平水组细碧角斑岩的形成年龄。结合前人研究及地质事实,本次研究确定双溪坞群平水组细碧角斑岩的成岩年龄为新元古代(950 Ma左右);认为江南造山运动发生的上、下限虽还没有最终限定,但它东端的造山运动很可能介于1.0~0.9 Ga;钦杭成矿带北东段地区有寻找同类矿床的潜力。  相似文献   

18.
On the basis of internal structures, laser ablation U–Pb ages and trace element compositions, the origin of zircon in jadeitite in the Nishisonogi metamorphic rocks was examined. The zircon comprises euhedral zoned cores overgrown by euhedral rims. The cores contain inclusions of muscovite, quartz, albite and possibly K‐feldspar, yield 238U–206Pb ages of 126 ± 6 Ma (±2 SD, n = 45, MSWD = 1.0), and have Th/U ratios of 0.48–1.64. The rims contain inclusions of jadeite, yield 238U–206Pb ages of 84 ± 6 Ma (±2 SD, n = 14, MSWD = 1.1), and have Th/U ratios of <0.06. The cores are richer in Y, Th, Ti and rare earth elements (REEs), but the rims are richer in Hf and U. Chondrite‐normalized REE patterns of the cores indicate higher SmN/LaN ratios, lower YbN/GdN ratios and larger positive Ce anomalies compared with those of the rims. Thus, the cores and rims have different 238U–206Pb ages and trace element compositions, suggesting two stages of zircon growth. Although the 238U–206Pb ages of the rims are consistent with the reported 40Ar/39Ar spot‐fusion ages of matrix muscovite in the jadeitite, the 238U–206Pb ages of the cores are older. The mineral inclusions and high Th/U ratios in the cores are best explained by crystallization from felsic magma. Therefore, the cores are considered relicts from igneous precursor rocks. The rims surrounding the inherited cores possibly precipitated from aqueous fluids during jadeitite formation. The elevated U concentrations in the rims suggest that infiltration of external fluids was responsible for the precipitation. This study provides an example of jadeitite formation by metasomatic replacement of a protolith.  相似文献   

19.
大兴安岭扎兰屯地区前寒武纪变质岩系年龄及其构造意义   总被引:2,自引:0,他引:2  
大兴安岭扎兰屯地区出露较多的前寒武纪变质岩系,包括先前认为是古元古代的兴华渡口群、新元古代的佳疙瘩组和新元古代—早寒武世的倭勒根岩群,但一直缺少精确的年代学依据。通过LA-ICP-MS锆石U-Pb同位素测年,对这3个变质岩群的原岩时代进行了厘定。结果显示,兴华渡口群中绿泥石白云母片岩的锆石~(206)Pb/~(238)U年龄加权平均值为520.1±4.3Ma(n=11,MSWD=1.6),佳疙瘩组中长英质糜棱岩锆石~(206)Pb/~(238)U年龄加权平均值为512.0±2.9Ma,倭勒根岩群中绿泥绢云片岩最年轻锆石~(206)Pb/~(238)U年龄加权平均值为491.7±11.9Ma,年龄最密集区加权平均值为516.7±4.5Ma。锆石图像特征及Th/U值均显示岩浆型锆石特征。综上所述,扎兰屯地区出露的兴华渡口群、佳疙瘩组和倭勒根群形成时代均为早古生代早期,而非先前认为的"前寒武纪"。同时,上述年龄谱系表明,该地区在480~500Ma和500~530Ma存在2期强烈的岩浆活动,应与东北地区晚泛非期岩浆-变质事件有关。  相似文献   

20.
桐柏造山带深熔作用:混合岩LA-ICPMS锆石U-Pb年代学证据   总被引:2,自引:1,他引:1  
刘小驰  吴元保  彭敏  汪晶  王浩  彭德才 《岩石学报》2011,27(4):1163-1171
桐柏造山带是研究秦岭-桐柏-大别-苏鲁变质带演化的关键地区。由于桐柏高级变质杂岩深熔作用发生时间还缺乏准确的限定,这一区域的构造演化仍存在较大的争议。本文对桐柏杂岩中的一个混合岩的中色体和两个混合岩浅色体样品中的锆石进行了LA-ICPMS年代学测定。中色体中锆石分析点获得的上下交点分别为859±73Ma和135±250Ma。接近上交点的6个谐和分析点给出的206Pb/238U加权平均结果为828±7Ma (MSWD=0.57)。这一年龄结果同上交点在误差范围内一致,代表混合岩原岩结晶年龄,对应扬子板块北缘出现的中-新元古代的岩浆事件。另一方面,混合岩浅色体中的新生锆石具有面状分带或是弱的振荡环带,低的Th/U比值,锆石形态学和内部结构也表明新生锆石结晶于与深熔作用有关的熔体中,它们的206Pb/238U加权平均值分别为135±4Ma和131±3Ma。这一年龄范围代表桐柏高级变质地体发生深熔作用时间,区域上与桐柏-大别变质带广泛出现的碰撞后岩浆事件的时代相同。桐柏造山带出现造山后伸展的时间应不晚于135Ma。  相似文献   

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