首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献，搜索用时 31 毫秒
1.
We investigated the characteristics of the alkenones produced by a bloom of Emiliania huxleyi in the eastern Bering Sea in 2000. Alkenones were detected in surface waters between 57°N and 63°N, where phosphate concentrations were low and the ammonium/nitrate ratio was high. The total alkenone content (C37:2, C37:3, and C37:4) ranged from 22.0 to 349 μg g−1 in suspended particles and from 0.109 to 1.42 μg g−1 in surface sediments. This suggests that a large proportion of the particulate alkenones synthesized in the surface water rapidly degraded within the water column and/or at the water-sediment interface of the Bering Shelf. The change in the stable carbon isotopic composition (δ13C) of C37:3 alkenone could not be explained only by variation in [CO2(aq)] in the surface water but also depended on the growth rate of E. huxleyi. The alkenone unsaturation index (UK′37) was converted into an alkenone “temperature” with three equations [Prahl et al 1988], [Sikes et al 1997] and [Müller et al 1998]; Sikes et al.’s (1997) equation gave the best correlation with the observed sea surface temperature (SST) in the eastern Bering Sea. However, some temperatures estimated by Sikes et al.’s (1997) equation from the UK′37 varied from the observed SST, possibly because of the rapidly changing rate of alkenone synthesis in the logarithmic growth stage or the low rate of alkenone synthesis when nutrients were limiting. Temperatures estimated from UK′37 in the surface sediments (6.8-8.2°C) matched the observed SST in September (7-8°C) but differed from the annual average SST of 4 to 5°C, suggesting that most of the alkenone in the eastern Bering Sea was synthesized during limited periods, for instance, in September. The relative amounts of C37:4 alkenone as proportions of the total alkenones (referred to as C37:4%) were high, ranging from 18.3 to 41.4%. Low-salinity water (<32 psu) within the study area would have contributed to the high C37:4% because a negative linear relationship between C37:4% and salinity was found in this study.  相似文献   

2.
Long-chain alkenones in lacustrine settings are potentially excellent biomarkers for the reconstruction of past terrestrial environmental conditions, and have been found in many different types of lakes around the globe. A wider range of factors influence the occurrence and distribution of alkenones in lake sediments and waters when compared to marine systems. Lake environmental conditions, such as temperature (in particular) and salinity, are among the key factors controlling alkenone distributions in lacustrine settings. Here we investigated alkenone distribution patterns in lakes of the northern Qinghai-Tibetan Plateau, China, and their possible relationship with environmental conditions, by analyzing paired samples of suspended particulate matter in surface waters and surface sediments. Salinity of investigated lake waters ranges from almost 0 to ∼100 g/L, while temperature variation among the lakes is minimal, effectively eliminating temperature effects on the alkenone distribution patterns observed here. We show that (1) alkenone concentrations vary substantially between the lakes, yet controlling mechanisms remain elusive; (2) C37/C38 ratios are substantially lower in the lakes of the Qaidam Basin than in the Lake Qinghai region, probably indicating different alkenone producers in the two regions; and (3) large variations in %C37:4 (the percentage of the C37:4 alkenone), determined from both surface waters and sediments, are negatively correlated with salinity. We suggest that the %C37:4 index could be used as a salinity indicator at least on a regional scale, with careful considerations of other potentially complicating factors. However, potential reasons for why salinity could significantly affect %C37:4 values need further investigation.  相似文献   

3.
The alkenone unsaturation index UK′37 has been applied to reconstruct past temperature changes in both marine and lacustrine systems. However, few studies have addressed whether the relative abundance of the C37:4 alkenone to the total C37 production (%C37:4) can reflect surface salinity changes in lacustrine systems. Here we present long-chain C37 alkenone distribution patterns in surface sediments from Lake Qinghai, China. Surface sediments were sampled over a large range of surface salinity changes (1.7-25 g/l) within Lake Qinghai and its surrounding lakes, while temperature differences at these sampling locations should be relatively small. We have found that %C37:4 varies from 15% to 49% as surface salinity decreases. We tentatively describe this %C37:4-salinity link with a general linear regression: %C37:4 = 53.4 (±7.8) − 1.73 (±0.45) × S (n = 28, r2 = 0.62), although step-wise %C37:4 changes in response to salinity variation may exist. UK′37 values vary between 0.10 and 0.16 at these sites and the inferred range of lake water temperature changes is ∼2-3 °C, suggesting that UK′37 largely reflects temperature signal across a large salinity range, consistent with previous findings that UK′37 can indicate temperature changes over a large diversity of environmental settings. We have also found that UK′37 values are correlated with salinity changes (r2 = 0.4), and thus cannot exclude potential temperature effect on %C37:4 and salinity effect on UK′37 in this study. However, even extreme estimates of temperature differences within the lake are still unable to explain the observed %C37:4 changes. We therefore suggest that %C37:4 could be used to infer past lake salinity changes at a regional scale.  相似文献   

4.
The successful reconstruction of sea surface temperatures using alkenone paleothermometry (U37k′) has relied on the premise that there is no significant differential degradation of alkenones with different states of unsaturation during diagenetic processes. To test this assumption, we conducted a comparative study of contemporary sediments in oxic and anoxic bottom waters from the Santa Monica Basin, offshore California. Long-chain alkenones were quantified and sea surface temperature were calculated using the calibrated U37k′–T relationship of Prahl et al. (1988). Our results show that temperature record from the oxic sediments is higher by as much as 4°C compared to those from time-equivalent anoxic sediments as a result of differential degradation of long-chain unsaturated alkenones and bioturbation mixing in the oxic sediments. The differential degradation of C37:3 vs. C37:2 alone could account for up to 2.5°C difference between these two records. This finding has significant implication in the interpretation of paleo–sea surface temperature data using alkenone paleothermometry.  相似文献   

5.
We compare alkenone unsaturation ratios measured on recent sediments from the Indian Ocean (20°N–45°S) with modern sea oceanographic parameters. For each of the core sites we estimated average seasonal cycles of sea surface temperature (SST) and salinity, which we then weighted with the seasonal productivity cycle derived from chlorophyll satellite imagery. The unsaturation index (U37K′) ranges from 0.2 to 1 and correlates with water temperature but not with salinity. TheU37K′versus SST relationship for Indian Ocean sediments (U37K′= 0.033 SST + 0.05) is similar to what has been observed for core tops from the Pacific and Atlantic oceans and the Black Sea. A global compilation for core tops givesU37K′= 0.031 T + 0.084 (R= 0.98), which is close to a previously reported calibration based on particulate organic matter from the water column. For temperatures between 24° and 29°C, however, the slope seems to decrease to about 0.02U37K′unit/°C. For Indian Ocean core tops, the ratios of total C37alkenones/total C38alkenones and the slope of theU37K′-SST relationship are similar to those previously observed for cultures ofEmiliania huxleyibut different from those previously published forGephyrocapsa oceanica.EitherE. huxleyiis a major producer of alkenones in the Indian Ocean or strains ofG. oceanicaliving in the northern Indian Ocean behave differently from the one cultured. In contrast with coccolithophorid assemblages, the ratios of C37alkenones to total C38alkenones lack clear geographic pattern in the Indian Ocean.  相似文献   

6.
The large (∼20‰) hydrogen isotopic gradient in surface waters of the northwest Atlantic Ocean is exploited to track changes in the source of alkenones to the Bermuda Rise sediment drift. Cultures of the predominant alkenone-producing coccolithophorid, E. huxleyi, were grown in deuterium-enriched seawater and shown to possess alkenones with a D/H ratio that closely tracked the water D/H ratio (r2 = 0.999, n = 5 isotopic enrichments) with a fractionation factor (α) between 0.732 and 0.775. A hydrogen isotopic depletion of -193 ± 3‰ (n = 9) was measured in alkenones from suspended particles relative to seawater in the subpolar and subtropical northwest Atlantic Ocean. This value was used to calculate the water δD values in which alkenones from Bermuda Rise sediment were synthesized, and by extension, the water mass in which they were produced. Applying this technique we find that 60% to 100% of the alkenones in late Holocene Bermuda Rise sediment were produced in deuterium-depleted subpolar water to the northwest of the drift. To reconcile values of the alkenone unsaturation ratio (Uk′37), a widely used proxy for sea surface temperature, with the δD values of alkenones in late Holocene sediments from the Bermuda Rise at least three sources of sediment must be invoked: a cold, very isotopically depleted source, almost certain to be the Scotian Margin; a warm, moderately isotopically-depleted source, likely to be the northwestern edge of the subtropical gyre; and a cold, isotopically enriched source, which we hypothesize to be the subpolar waters overlying the main branch of North Atlantic Deep Water flowing southwest from the Nordic Seas.  相似文献   

7.
We investigated the effect of CO2 and primary production on the carbon isotopic fractionation of alkenones and particulate organic matter (POC) during a natural phytoplankton bloom dominated by the coccolithophore Emiliania huxleyi. In nine semi-closed mesocosms (∼11 m3 each), three different CO2 partial pressures (pCO2) in triplicate represented glacial (∼180 ppmv CO2), present (∼380 ppmv CO2), and year 2100 (∼710 ppmv CO2) CO2 conditions. The largest shift in alkenone isotopic composition (4-5‰) occurred during the exponential growth phase, regardless of the CO2 concentration in the respective treatment. Despite the difference of ∼500 ppmv, the influence of pCO2 on isotopic fractionation was marginal (1-2‰). During the stationary phase, E. huxleyi continued to produce alkenones, accumulating cellular concentrations almost four times higher than those of exponentially dividing cells. Our isotope data indicate that, while alkenone production was maintained, the interaction of carbon source and cellular uptake dynamics by E. huxleyi reached a steady state. During stationary phase, we further observed a remarkable increase in the difference between δ13C of bulk organic matter and of alkenones spanning 7-12‰. We suggest that this phenomenon is caused mainly by a combination of extracellular release of 13C-enriched polysaccharides and subsequent particle aggregation induced by the production of transparent exopolymer particles (TEP).  相似文献   

8.
Hydrogen isotope ratios of individual alkenones from haptophyte algae were measured in suspended particles and surface sediment from the Chesapeake Bay (CB) estuary, eastern USA, in order to determine their relationship to water δD values and salinity. δD values of four alkenones (MeC37:2, MeC37:3, EtC38:2, EtC38:3) from particles and sediments were between −165‰ and −221‰ and increased linearly (R2 = 0.7-0.9) with water δD values from the head to the mouth of the Bay. Individual alkenones were depleted in deuterium by 156-188‰ relative to water. The MeC37 alkenones were consistently enriched by ∼12‰ relative to the EtC38 alkenones, and the di-unsaturated alkenones of both varieties were consistently enriched by ∼20‰ relative to the tri-unsaturated alkenones. All of the increase in alkenone δD values could be accounted for by the water δD increase. Consequently, no net change in alkenone-water D/H fractionation occurred as a result of the salinity increase from 10 to 29. This observation is at odds with results from culture studies with alkenone-producing marine coccolithophorids, and from two field studies, one with a dinoflagellate sterol in the CB, and one with a wide variety of lipids in saline ponds on Christmas Island, that indicate a decline in D/H fractionation with increasing salinity. Why D/H fractionation in alkenones in the CB showed no dependence on salinity, while D/H fractionation in CB dinsoterol decreased by 1‰ per unit increase in salinity remains to be determined. Two hypotheses we consider to be valid are that (i) the assemblage of alkenone-producing haptophytes changes along the Bay and each species has a different sensitivity to salinity, such that no apparent trend in αalkenone-water occurs along the salinity gradient, and (ii) greater osmoregulation capacity in coastal haptophytes may result in a diminished sensitivity of alkenone-water D/H fractionation to salinity changes.  相似文献   

9.
Our specimen of the cultured Emiliania huxleyi strain (CCMP1742, also known as NEPCC55a) that provides the benchmark for -based paleothermometry has started producing, for reasons yet unclear, major amounts of three new alkenones identified as ω15,22-C35 methyl ketone, ω15,22-C36 ethyl ketone and ω16,23-C36 methyl ketone. Comparison of these structures with those established now by the same OsO4 derivatization method applied to the di-unsaturated C37, C38 and C39 alkenones typically found in this organism provides insight into the possible pathway for their biosynthesis. Isothermal batch culture experiments also show the content and composition of these new compounds change systematically and quite significantly in cells when subjected to environmental conditions such as nutrient depletion, variation in light availability and prolonged darkness. Alkenones of similarly unusual short-chain length are evident in suspended particulate materials from present day surface waters in the Ligurian Sea (Mediterranean) and in two different Holocene time horizons (Unit I and Unit II deposits) in Black Sea sediments. However, the positions of the double bonds are different from those that we now report in our culture, implying a different biosynthetic sequence. These alkenones are most likely derived from another, as yet unknown, haptophyte species. If this other organism accounts for all documented occurrences of these compounds in natural samples, then either it has a capacity for growth over a remarkably wide salinity range or surface water salinity in the early Holocene Black Sea may not have been as low as is currently believed.  相似文献   

10.
We investigated alkenones recorded in suspended particles and a settling particle time series collected at three stations, 40N (40°N, 165°E), KNOT (44°N, 155°E), and 50N (50°N, 165°E), in the northwestern North Pacific from December 1997 to May 1999. Emiliania huxleyi, the most abundant alkenone producer in this area, is present in surface to subsurface (to ∼50 m depth) waters. The alkenone concentrations recorded in the suspended particles indicated that the seasonal alkenone particle distribution differed significantly interannually. Alkenone export fluxes at the three sediment-trap stations ranged from 0.16 to 49.3 μg m−2 day−1, and the maximum export flux, which occurred in summer to fall (July-November), was associated with a high organic carbon export flux. The amount of alkenone produced during the maximum export season accounted for 60-80% of the total annual amount of alkenone, and the alkenones accumulated in the sediment below the traps had characteristics corresponding to subsurface waters during the summer-autumn season. Alkenone-derived temperatures recorded in suspended particles corresponded to the in situ temperature within ∼2 °C. Although alkenone-derived temperatures corresponded approximately to the temperatures observed in the stratified subsurface waters at the three trap stations during the high-export season, large differences were observed during the low-export (winter-spring) period. For example, the alkenone-derived temperatures observed at stations KNOT and 50N were much higher than the in situ subsurface temperatures reported in the World Ocean Atlas 2001. Relatively large differences between alkenone-derived temperatures and in situ temperatures in the subarctic might be due to (1) a low-light limitation or (2) contributions of allochthonous alkenones in particulate material transported from subtropical areas within a warm-core ring.  相似文献   

11.
The Baltic Sea is an intra‐continental brackish water body. Low saline surface water, the so‐called Baltic outflow current, exits the Baltic Sea through the Kattegat into the Skagerrak. Ingressions of saline oxygen‐rich bottom water enter the Baltic Sea basins via the narrow and shallow Kattegat and are of great importance for the ecological and ventilation state of the Baltic Sea. Over recent decades, progress has been made in studying Holocene changes in saline water inflow. However, reconstructions of past variations in Baltic Sea outflow changes are sparse and hampered because of the lack of suitable proxies. Here, we used the relative proportion of tetra‐unsaturated C37 ketones (C37:4 %) in long‐chain alkenones produced by coccolithophorids as a proxy for outflowing Baltic Sea water in the Skagerrak. To evaluate the applicability of the proxy, we compared the biomarker results with grain‐size records from the Kattegat and Mecklenburg Bay in addition to previously published salinity reconstructions from the Kattegat over the last 5000 years. All Skagerrak records showed an increase in C37:4 % that is accompanied by enhanced bottom water currents in the Kattegat and western Baltic Sea over the past 3500 cal. a BP, indicating an increase in Baltic Sea outflow. This probably reflects higher precipitation in the Baltic Sea catchment area owing to a re‐organization of North Atlantic atmospheric circulation with an increased influence of wintertime Westerlies over the Baltic catchment from the mid‐ to the late Holocene.  相似文献   

12.
Long-chain alkenones (LCK) of lacustrine surface sediments were analyzed in 37 lakes from China. The results obtained were complemented by published data from 13 other Chinese lakes. These lakes are located across large temperature and precipitation gradients, therefore allowing for an assessment of the distribution pattern of LCK and their temperature dependency. Different distribution patterns of LCK (C37 predominant pattern and C38 predominant pattern) were detected in the surface sediment samples. The ratio of C37:4 methyl ketone to the sum of C37 alkenones observed in the different lakes is highly variable (5%-96%, with mean value of 55%), and more than that seen in marine systems. The finding that some of the ocean LCK precursor algae (Gephyrocapsa oceanica, Coccolithus pelagicus) were also present in the limnic systems suggested that both systems might have similar biosynthetic sources. Empirical relationships between the alkenone unsaturation index U37k′ and different temperature sets (mean annual air temperature, mean annual air temperature in different seasons, and lake surface water temperature of July) were tested. The best correlation between U37k′ and temperature was obtained using mean annual air temperature. A general linear regression of U37k′ and MAAT can be expressed as U37k′ = 0.0328 × T + 0.126 (n = 38, r2 = 0.83). Although questions such as species-uncertainty and other unknown factors for U37k′ temperature dependence still remain, the equation might be representative of the average contribution of LCK to sediments for these data over a wide range of surface temperatures, water chemistry and different alkenones-producer algal populations. The general relationship of U37k′ and mean annual air temperature is consistent with that in marine systems. It supports the suggestion that the biosynthetic pathway of alkenones and the mechanism of their temperature signal may be similar in both marine and limnic systems. LCK might be used as an important paleotemperature proxy in limnic environment.  相似文献   

13.
Long chain alkenones (LCA) are temperature-sensitive lipids with great potential for quantitative reconstruction of past continental climate. We conducted the first survey for alkenone biomarkers from 55 different lakes in the Northern Great Plains and Nebraska Sand Hills of the United States. Among those surveyed, we found 13 lakes that contain LCAs in the surface sediments. The highest concentrations of alkenones in sediments are found in cold (mean annual air temperature ∼11 °C versus 17 °C in our warmest sites), brackish to mesosaline (salinity = 8.5-9.7 g/L), and alkaline (pH = 8.4-9.0) lakes with high concentrations of sodium and sulfate. The dynamics of stratification and nutrient availability also appear to play a role in LCA abundance, as early spring mixing promotes a bloom of alkenone-producing haptophytes. Four of the alkenone-containing sites contain the C37:4 alkenone; however, we discovered an unprecedented lacustrine alkenone distribution in a cluster of lakes, with a total absence of C37:4 alkenone. We attribute this unusual composition to a different haptophyte species and show that the sulfate:carbonate ratio may control the occurrence of these two distinct populations. We created a new in-situ temperature calibration for lacustrine sites that contain C37:4 using a water-column calibration from Lake George, ND and show that is linearly correlated to lake water temperature (R2 = 0.74), but is not. A number of lakes contain an unidentified compound series that elutes close to the LCAs, highlighting the importance of routine GC-MS examination prior to using lacustrine LCAs for paleotemperature reconstructions.  相似文献   

14.
Three methods are presented on how to purify acetylated sterols, acetylated triterpenols and individual alkenones for hydrogen isotope analysis from marine and lacustrine sediments using reverse-phase high performance liquid chromatography (RP-HPLC). The main advantages over previous HPLC methods are reduced operator time, increased automation and the ability to simultaneously purify multiple target compounds from a sample. These gains are achieved primarily by acetylating compounds prior to purification rather than after, and also by using a fraction collector with semi-preparatory rather than analytic configuration. The effectiveness of the method is demonstrated for (i) dinosterol and taraxerol in sediment from the brackish pond Poza del Diablo, Galápagos, (ii) for di- and tri-unsaturated C37 and C38 alkenones in cultured Emiliania huxleyi, (iii) for brassicasterol, and di-, tri- and tetra-unsaturated C37 alkenones in sediment from Manito Lake, Saskatchewan, Canada, and (iv) for brassicasterol, dinosterol and di-, tri- and tetra-unsaturated C37 alkenones in sediment from the Great Salt Lake, Utah. The purification process yields 80–90% recoveries and results in no measurable hydrogen isotope alteration.  相似文献   

15.
  相似文献   

16.
The UK37′ index has proven to be a robust proxy to estimate past sea surface temperatures (SSTs) over a range of time scales, but like any other proxy, it has uncertainties. For instance, in reconstructions of the Last Glacial Maximum (LGM) in the northern North Atlantic, UK37′ indicates higher temperatures than those derived from foraminiferal proxies. Here we evaluate whether such warm glacial estimates are caused by the advection of reworked alkenones in ice‐rafted debris (IRD) to deep‐sea sediments. We have quantified both coccolith assemblages and alkenones in sediments from glaciogenic debris flows in the continental margins of the northern North Atlantic, and from a deep‐sea core from the Reykjanes Ridge. Certain debris flow deposits in the North Atlantic were generated by the presence of massive ice‐sheets in the past, and their associated ice streams. Such deposits are composed of the same materials that were present in the IRD at the time they were generated. We conclude that ice rafting from some locations was a transport pathway to the deep sea floor of reworked alkenones and pre‐Quaternary coccolith species during glacial stages, but that not all of the IRD contained alkenones, even when reworked coccoliths were present. We speculate that the ratio of reworked coccoliths to alkenone concentration might be useful to infer whether significant reworked alkenone inputs from IRD did occur at a particular site in the glacial North Atlantic. We also observe that alkenones in some of the debris flows contain a colder signal than estimated for LGM sediments in the northern North Atlantic. This is also clear in the deep‐sea core studied where the warmest intervals do not correspond to the intervals with large inputs of reworked coccoliths or IRD. We conclude that any possible bias to UK37′ estimates associated with reworked alkenones is not necessarily towards higher values, and that the high SST anomalies for the LGM are unlikely to be the result of a bias caused by IRD inputs. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

17.
  相似文献   

18.
Over the last decade, sea surface temperature (SST) reconstructed from the Mg/Ca ratio of foraminiferal calcite has increasingly been used, in combination with the δ18O signal measured on the same material, to calculate the δ18Ow, a proxy for sea surface salinity (SSS). A number of studies, however, have shown that the Mg/Ca ratio is also sensitive to other parameters, such as pH or , and salinity. To increase the reliability of foraminiferal Mg/Ca ratios as temperature proxies, these effects should be quantified in isolation. Individuals of the benthic foraminifera Ammonia tepida were cultured at three different salinities (20, 33 and 40 psu) and two temperatures (10-15 °C). The Mg/Ca and Sr/Ca ratios of newly formed calcite were analyzed by Laser Ablation ICP-MS and demonstrate that the Mg concentration in A. tepida is overall relatively low (mean value per experimental condition between 0.5 and 1.3 mmol/mol) when compared to other foraminiferal species, Sr being similar to other foraminiferal species. The Mg and Sr incorporation are both enhanced with increasing temperatures. However, the temperature dependency for Sr disappears when the distribution factor DSr is plotted as a function of calcite saturation state (Ω). This suggests that a kinetic process related to Ω is responsible for the observed dependency of Sr incorporation on sea water temperature. The inferred relative increase in DMg per unit salinity is 2.8% at 10 °C and 3.3% at 15 °C, for the salinity interval 20-40 psu. This implies that a salinity increase of 2 psu results in enhanced Mg incorporation equivalent to 1 °C temperature increase. The DSr increase per unit salinity is 0.8% at 10 °C and 1.3% at 15 °C, for the salinity interval 20-40 psu.  相似文献   

19.
C37–C39 ketones containing 2–4 double bonds and similarly-unsaturated C38–C40 ethyl ketones have been detected for the first time in lacustrine sediments. Tetra-unsaturated compounds are relatively more abundant than in marine sediments. The similar molecular composition of methyl ketones and cooccurring ethyl ketones containing one additional carbon atom indicates that the two classes are biosynthetically related.No source of these potential biological markers in lacustrine sediments has been identified. The abundance and unsaturation pattern of alkenones in lacustrine sediments may reflect the relative input and species composition, respectively, of algae presumed to belong to the Phylum Chrysophyta, by analogy with the marine source.  相似文献   

20.
We investigated relationships between sedimentary solvent-extractable long-chain alkenone (LCA) concentration and composition and environmental factors in a suite of endorheic lakes from inland Spain. LCAs were found in 14 of the 54 lakes examined, with concentrations comparable with those from previously published lacustrine settings. The composition of LCAs in our sites, however, contrast from the majority of those previously reported from lake environments; in our study the tri-unsaturated component is the most abundant component at most sites where LCAs are detected, and C38:3 is the most abundant LCA in the majority of sites. LCA occurrence appears to be restricted to brackish-hypersaline sites and C37 LCAs are absent above a salinity of ∼40 g L−1 suggesting a salinity control on LCA-producing organisms in these sites. Low concentrations of C37 LCA components means and temperature indices are generally not applicable. Instead we find good relationships between C38 components and (in particular mean autumn) temperature and the strongest LCA-temperature relationships are found when using a combination of all C37 and C38 compounds. We propose a new alkenone temperature index for lakes with elevated salinity and where the C38 components dominate the LCA distributions. This is expressed as (r2 = 0.80, n = 13). In this paper, we provide the first account of sedimentary LCA distributions from lakes in inland Spain, extending the range of environments within which these compounds have been found and highlighting their significance as indicators of both salinity and temperature in saline, endorheic lake environments. This has important implications for extending the potential role of LCAs as palaeoclimatic indicators in lacustrine environments.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号