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1.
Several types of growth morphologies and alteration mechanisms of zircon crystals in the high-grade metamorphic Ivrea Zone (IZ) are distinguished and attributed to magmatic, metamorphic and fluid-related events. Anatexis of pelitic metasediments in the IZ produced prograde zircon overgrowths on detrital cores in the restites and new crystallization of magmatic zircons in the associated leucosomes. The primary morphology and Th-U chemistry of the zircon overgrowth in the restites show a systematic variation apparently corresponding to the metamorphic grade: prismatic (prism-blocked) low-Th/U types in the upper amphibolite facies, stubby (fir-tree zoned) medium-Th/U types in the transitional facies and isometric (roundly zoned) high-Th/U types in the granulite facies. The primary crystallization ages of prograde zircons in the restites and magmatic zircons in the leucosomes cannot be resolved from each other, indicating that anatexis in large parts of the IZ was a single and short lived event at 299 ± 5 Ma (95% c. l.). Identical U/Pb ages of magmatic zircons from a metagabbro (293 ± 6 Ma) and a metaperidotite (300 ± 6 Ma) from the Mafic Formation confirm the genetic context of magmatic underplating and granulite facies anatexis in the IZ. The U-Pb age of 299 ± 5 Ma from prograde zircon overgrowths in the metasediments also shows that high-grade metamorphic (anatectic) conditions in the IZ did not start earlier than 20 Ma after the Variscan amphibolite facies metamorphism in the adjacent Strona–Ceneri Zone (SCZ). This makes it clear that the SCZ cannot represent the middle to upper crustal continuation of the IZ. Most parts of zircon crystals that have grown during the granulite facies metamorphism became affected by alteration and Pb-loss. Two types of alteration and Pb-loss mechanisms can be distinguished by cathodoluminescence imaging: zoning-controlled alteration (ZCA) and surface-controlled alteration (SCA). The ZCA is attributed to thermal and/or decompression pulses during extensional unroofing in the Permian, at or earlier than 249 ± 7 Ma. The SCA is attributed to the ingression of fluids at 210 ± 12 Ma, related to hydrothermal activity during the breakup of the Pangaea supercontinent in the Upper Triassic/Lower Jurassic. Received: 7 July 1998 / Accepted: 4 November 1998  相似文献   

2.
Summary Integration of new mineral chemical, geochronological and structural data from the Texel Complex yielded information on (re)crystallization and deformation processes in metapelites, eclogites and tonalitic orthogneisses during eclogite facies metamorphism. Maximum P–T conditions reached 1.2 to 1.4 GPa and 540–620 °C in the Upper Cretaceous. In tonalitic orthogneisses and metapelites, substantial garnet growth took place prior to eclogite facies metamorphism and Sm–Nd data indicate the presence of pre-Cretaceous mineral relics. In contrast, complex garnet-growth and -resorption processes are inferred for eclogites, which produced characteristic atoll microstructures and occurred close to the pressure peak of a single, coherent high pressure event. Garnet Sm–Nd data indicate eclogite facies crystallization at 85 ± 5 Ma. While eclogites retained information on the maximum burial stage, matrix phases in metapelites and orthogneisses were intensely recrystallized during the amphibolite facies metamorphic decompression. All the meso- and macro-scale deformation structures formed during the high pressure event and subsequent exhumation. The major mylonitic foliation is represented by the high pressure phases but was refolded during amphibolite facies exhumation. A biotite-whole-rock Rb–Sr age of 70–80 Ma indicates that cooling below about 300 °C occurred in the Upper Cretaceous. Supplementary material to this paper is available in electronic form at Appendix available as electronic supplementary material  相似文献   

3.
The Gruinard Bay area of the mainland Lewisian complex comprises a metamorphosed suite of Archaean trondhjemites and minor granites enclosing remnants of older tonalitic gneiss and mafic to ultramafic enclaves. The U-Pb zircon dating yields ages of 2731 ±14 Ma and 2728 ±2 Ma for two trondhjemite and 2732 ±4 Ma for one granite sample, also revealing the presence of large amounts of inherited xenocrystic zircons. Although the region has been pervasively overprinted by retrogressive events in amphibolite to greenschist facies, the textural relations between biotite, hornblende, quartz and titaniferous minerals indicate that these minerals are pseudomorphs of pyroxene and high-Ti amphibole formed in hornblende-granulite facies. Structural relations link this metamorphism to a steep northeast-trending fabric coeval with the intrusion of the trondhjemites, dated at 2730 Ma. Dating of zircon in amphibolite and tonalite enclaves yields complex internal isotopic relations with apparent ages ranging from 2825 to 2740 Ma. This age range reflects new growth during the 2730 Ma metamorphic/metasomatic events, superimposed on older zircon phases which include combinations of xenocrystic cores, and magmatic and/or metamorphic growth phases whose mode of formation cannot clearly be resolved by imaging techniques (e.g. cathodoluminescence) alone. A pegmatitic vein that escaped the D3 strain and related isotopic disturbances yields a precise age of 2792 ±2 Ma, which constrains to some degree the earliest orogenic events in the area. Age relationships displayed in the central block at Scourie–Badcall, and in the Gruinard Bay area indicate that petrogenetic events in both areas were comparable about 2800 Ma and that both areas underwent trondhjemitic magmatism about 2730 Ma. In contrast, at Gruinard Bay there is no isotopic evidence for a period of high-grade metamorphism and magmatism at 2490–2480 Ma that drastically affected the Scourie block indicating that at this stage the two regions occupied different levels of the crust. Received: 23 October 1997 / Accepted: 20 July 1998  相似文献   

4.
Petrology of eclogites from north of Shahrekord, Sanandaj-Sirjan Zone, Iran   总被引：1，自引：0，他引：1  
Summary Metabasic rocks were recently found within a ductile shear zone in the north of Shahrekord, being a part of the structural zone of Sanandaj-Sirjan, SW Iran. The rocks give evidence of a so far unrecognized eclogite facies metamorphic event and testify to high pressure metamorphism in the Sanandaj-Sirjan Zone, near the Main Zagros Reverse Fault, which is the assumed suture zone between the Arabian plate and the Iranian block. The eclogites occur as lenses or blocks within ortho- and paragneisses. The petrographic features and reaction textures display at least two main metamorphic stages: (1) a peak eclogite facies stage, and (2) a subsequent amphibolite facies stage. The eclogite facies metamorphism is indicated by omphacite + garnet + sodic-calcic amphiboles (barroisite, magnesiokatophorite and magnesiotaramite) + phengite + rutile + (clino-)zoisite + quartz ± dolomite. The garnets are mainly almandine-rich, which fits with the C-type eclogite classification. Calcic amphiboles (hornblende, tschermakite and pargasite) + plagioclase are secondary phases formed during the retrograde amphibolite-facies metamorphism. P-T estimates for the eclogite facies give pressures of 21–24 kbar and temperatures of 590–630 °C (geothermometry) and 470–520 °C (THERMOCALC), respectively. Geothermobarometry for the amphibolite-facies metamorphism yields 10–11 kbar and 650–700 °C. Author’s address: Ali Reza Davoudian, Department of Natural Resources, Shahrekord University, Shahrekord, Iran  相似文献   

5.
 Petrological and chemical variations, as well as oxygen and strontium isotopic data are presented for metagabbros from the Romanche and Vema fracture zones. These rocks were affected by several types and degrees of alterations ranging from slight hydrothermal alteration to complete amphibolitization. Five major kinds of alteration processes ranging from late-magmatic deuteric alteration (stage I) to low temperature (<150 °C) alteration (stage V) were identified. Water-rock interactions between 300 and 650 °C are the most dominant interactions resulting in the most prevailing secondary mineralogical assemblages which characterize the amphibolite and/or greenschist facies (amphibole ± plagioclase ± epidote ± titanite ± chlorite ± prehnite). Hydrothermal alteration of these gabbroic rocks results in isotopic exchanges between rocks and seawater-derived fluids. These exchanges lead to decrease of gabbroic δ18O toward values as low as +3.9‰, and larger Sr isotopic variations than other oceanic gabbroic rocks (87Sr/86Sr ratios shift to 0.7029–0.7051). Calculation of a chemical budget indicates that metagabbros are hydrated and enriched in Fe and probably in Mg and Cl, while Si, Ca and Ti are released to the hydrothermal fluids. In addition to metamorphic recrystallization and geochemical transformation, hydrothermal alteration of oceanic gabbros contributes to the control of the global ocean geochemistry. Received: 8 March 1999 / Accepted: 12 July 1999  相似文献   

6.
We report an extensive field-based study of zircon and monazite in the metamorphic sequence of the Reynolds Range (central Australia), where greenschist- to granulite-facies metamorphism is recorded over a continuous crustal section. Detailed cathodoluminescence and back-scattered electron imaging, supported by SHRIMP U–Pb dating, has revealed the different behaviours of zircon and monazite during metamorphism. Monazite first recorded regional metamorphic ages (1576 ± 5 Ma), at amphibolite-facies grade, at ∼600 °C. Abundant monazite yielding similar ages (1557 ± 2 to 1585 ± 3 Ma) is found at granulite-facies conditions in both partial melt segregations and restites. New zircon growth occurred between 1562 ± 4 and 1587 ± 4 Ma, but, in contrast to monazite, is only recorded in granulite-facies rocks where melt was present (≥700 °C). New zircon appears to form at the expense of pre-existing detrital and inherited cores, which are partly resorbed. The amount of metamorphic growth in both accessory minerals increases with temperature and metamorphic grade. However, new zircon growth is influenced by rock composition and driven by partial melting, factors that appear to have little effect on the formation of metamorphic monazite. The growth of these accessory phases in response to metamorphism extends over the 30 Ma period of melt crystallisation (1557–1587 Ma) in a stable high geothermal regime. Rare earth element patterns of zircon overgrowths in leucosome and restite indicate that, during the protracted metamorphism, melt-restite equilibrium was reached. Even in the extreme conditions of long-lasting high temperature (750–800 °C) metamorphism, Pb inheritance is widely preserved in the detrital zircon cores. A trace of inheritance is found in monazite, indicating that the closure temperature of the U–Pb system in relatively large monazite crystals can exceed 750–800 °C. Received: 7 April 2000 / Accepted: 12 August 2000  相似文献   

7.
Metabasites with eclogite facies relics occur in northern Sardinia as massive to strongly foliated lenses or boudins embedded within low- to medium-grade rocks (Anglona) and migmatites (NE Sardinia). U–Pb zircon dating yielded 453 ± 14, 457 ± 2 and 460 ± 5 Ma as the protolith ages; 400 ± 10 and 403 ± 4 Ma have been interpreted as the ages of the HP event and 352 ± 3 and 327 ± 7 Ma as the ages of the main Variscan retrograde events. A pre-eclogite stage is documented by the occurrence of tschermakite, zoisite relics within garnet porphyroblasts (Punta de li Tulchi) and an edenite–andesine inclusion within a relict kyanite porphyroblast (Golfo Aranci). Four main metamorphic stages have been distinguished in the eclogite evolution: (1) eclogite stage, revealed by the occurrence of armoured omphacite relics within garnet porphyroblasts. The Golfo Aranci eclogites also include kyanite, Mg-rich garnet and pargasite; (2) granulite stage, producing orthopyroxene and clinopyroxene–plagioclase symplectites replacing omphacite. At Golfo Aranci, the symplectitic rims around relict kyanite consist of sapphirine, anorthite, corundum and spinel; (3) amphibolite stage, leading to the formation of amphibole–plagioclase kelyphites between garnet porphyroblasts and pyroxene–plagioclase symplectites and to the growth of cummingtonite on orthopyroxene. Tschermakite to Mg-hornblende, plagioclase, cummingtonite, ilmenite, titanite and biotite are coexisting phases; (4) greenschist to sub-greenschist stage, defined by the appearance of actinolite, chlorite, epidote ss, titanite, sericite and prehnite. The following P–T ranges have been estimated for the different stages. Eclogite stage 550–700°C; 1.3–1.7 GPa; granulite stage 650–900°C; 0.8–1.2 GPa, clustering in the range 1.0–1.2 GPa; amphibolite stage 550–740°C; 0.3–0.7 GPa; greenschist stage 300–400°C; 0.2–0.3 GPa. Comparable ranges characterise the other Variscan massifs in Europe; eclogite stage: T = 530–800°C; P from 0.7–1.1 to 1.7 ± 0.3 GPa; granulite stage T = 760–870°C and P from 1.1–1.4 to 7.2–9.9 GPa, clustering around 1.0–1.2 GPa. Whole-rock chemistry: Sardinian eclogites are N- to T-MORB; European ones N- to E-MORB or calc-alkaline.  相似文献   

8.
Summary The rocks of the crystalline basement of the East European Craton in southern Estonia show effects of partial melting under granulite facies conditions. Zircons extracted from partial melting products (tonalite from the Tapa Zone – 1824 ± 26, tonalite from the South Estonian Zone – 1788 ± 16 Ma and charnockite from the Tapa Zone – 1761 ± 11 Ma) yield U–Pb crystallisation ages that span over approximately 80 Ma, suggesting a prolonged high-grade metamorphism or several separate events. U–Pb zircon age of one sample of charnockite is concordant with the Nd model age of partial melting of its host mafic granulite facies gneiss (intercept at 1.76 Ga). Linear geochemical trends and similar initial Nd isotopic compositions of mafic granulites and charnockites suggest their possible genetic relationship. From our new and previously published data it follows that the peak granulite metamorphic conditions and formation of tonalites and charnockites (850 °C and 6 kbar) in the Estonian basement occurred at 1788–1778 Ma. Then, the rocks cooled down, passing through the garnet closure temperature of approximately 650–700 °C at 1728 ± 24 Ma. The age of metamorphism of the Estonian granulites is lower than the metamorphic ages known from southern Finland, but it is similar to the age of metamorphism reported from the Belarus-Baltic Granulite Belt in Latvia.  相似文献   

9.
In the Itsaq Gneiss Complex south of the Isua supracrustal belt (West Greenland) some areas of early Archaean tonalite and quartz-diorite are non-gneissic, free of pegmatite veins, and in rarer cases are undeformed with relict igneous textures and hence were little modified by heterogeneous ductile deformation under amphibolite facies conditions in several Archaean events. Such well-preserved early Archaean rocks are extremely rare. Tonalites are high Al, and have bulk compositions close to experimental liquids. Trace element abundances and modelling suggest that they probably originated as melts derived from basaltic compositions at sufficiently high pressures to require residual garnet + amphibolites ± clinopyroxene in the source. The major element characteristics of the quartz-diorites suggest these were derived from more mafic magmas than the tonalites, and underwent either igneous differentiation or mixing with crustal material. As in modern arc magmas, high relative abundances of Sr, Ba, Pb, and alkali elements cannot be generated simply from a basaltic source formed by large degrees of melting of a depleted mantle. This may indicate an important role for fluids interacting with mafic rocks in generating the earliest preserved continental crust. The high Ba/Th, Ba/Nb, La/Nb and low Nb/Th, Ce/Pb, and Rb/Cs ratios of these tonalites are also observed in modern arc magmas. SHRIMP U-Pb zircon geochronology was undertaken on seven tonalites, one quartz-diorite, a thin pegmatitic vein and a thin diorite dyke. Cathodoluminescence images show the zircon populations of the quartz-diorite and tonalites are dominated by single-component oscillatory-zoned prismatic grains, which gave ages of 3806 ± 5 to 3818 ± 8 Ma (2σ) (quartz-diorite and 5 tonalites) and 3795 ± 3 Ma (1 tonalite). Dating of recrystallised domains cutting oscillatory-zoned zircon indicates disturbance as early as 3800–3780 Ma. There are rare ca. 3600 Ma and 3800–3780 Ma (very high U and low Th/U) ≤ 20 μm wide partial overgrowths on the prismatic grains. Given likely Zr-undersaturation of precursor melts and evidence of zircon recrystallisation and metamorphic regrowth as early as 3800–3780 Ma, the age determinations on the prismatic oscillatory-zoned zircon populations give the igneous crystallisation age of the tonalite and quartz-diorite protoliths. When the coherency of the geochemistry is considered, these samples represent the best preserved suites of ca. 3800 Ma felsic igneous rocks yet documented. Received: 1 December 1998 / Accepted: 23 July 1999  相似文献   

10.
Sapphirine-bearing orthopyroxene-kyanite (Opx-Ky) and -sillimanite (Opx-Sil) granulites have been found in the Lewisian complex of South Harris in northwest Scotland. In the Opx-Ky granulites, orthopyroxene and kyanite are intergrown in a stable mineral assemblage, which indicates metamorphic condition at 800–900 °C >12 kbar. Sillimanite inclusions within orthopyroxene suggest that sillimanite formed earlier; conditions are estimated at 950 ± 30 °C at 10 kbar from orthopyroxene isopleths for aluminous orthopyroxene (<9.7 wt%). In the Opx-Sil granulite, the orthopyroxene + sillimanite + garnet + sapphirine assemblage is stable at the peak metamorphic stages, indicating P-T condition of 930–950 °C, >8 kbar according to the FMAS petrogenetic grid, and similar conditions were obtained by using orthopyroxene-garnet geothermobarometers. The two types of orthopyroxene-aluminosilicate granulites indicate that the peak metamorphic conditions were over 900 °C, compatible with ultra-high temperature metamorphism. As accessory sapphirine occurs in several assemblages and with different compositions; it is interpreted to be formed at different stages of the metamorphism. These granulites were formed during Early Proterozoic high-grade metamorphism due to the emplacement of the South Harris Igneous Complex at c. 2170–1870 Ma, and are not related to the major metamorphic episode of the Badcallian/Inverian metamorphism at c. 2700–2500 Ma in the mainland Lewisian. Received: 17 July 1998 / Accepted 8 March 1999  相似文献   

11.
The Elzevir Terrane of the Grenville Orogen in southern Ontario contains metapelites and abundant graphitic marbles that were regionally metamorphosed from the upper greenschist to upper amphibolite facies. Comparative thermometry was undertaken with widely used calibrations for the systems garnet-biotite, calcite-dolomite, and calcite-graphite. Temperatures that are obtained from matrix biotites paired with prograde garnet near-rim analyses are usually consistent with those determined using calcite-graphite thermometry. However, calcite-graphite thermometry occasionally yields low temperatures due to lack of equilibration of anomalously light graphite. Application of calcite-graphite and garnet-biotite systems may yield temperatures up to 70 °C higher than calcite-dolomite in amphibolite facies rocks. Calcite-dolomite temperatures most closely approach those from calcite-graphite and garnet-biotite when the samples contain a single generation of dolomite and calcite grains contain no visible dolomite exsolution lamellae. However, some of these samples yield temperatures considerably lower than temperatures calculated from calcite-graphite and garnet-biotite thermometry, indicating that the calcite-dolomite thermometer may have been partially reset during retrogression. Estimated peak metamorphic temperatures of regional metamorphism between Madoc (upper greenschist facies) and Bancroft (upper amphibolite facies) range from 500 to 650 °C. These results place the chlorite-staurolite isograd at 540 °C, the kyanite-sillimanite isograd at 590 °C, and the sillimanite-K-feldspar isograd at 650 °C. Although each thermometer may have an absolute uncertainty of as much as ±50 °C, the 50 to 60 °C temperature differences between the isograds are probably accurate to 10 to 20 °C. An incomplete picture of the thermal gradients can result from the application of only one thermometer in a given area. Simultaneous application of several systems allows one to recognize and overcome the inherent limitations of each thermometer. Received: 26 March 1997 / Accepted: 15 April 1998  相似文献   

12.
 The Aracena metamorphic belt (AMB), southwest Iberian peninsula, is characterized by the following geological elements: (a) a high-temperature/low-pressure (HT/LP) metamorphic belt a few kilometres wide and more than 200 km long; (b) a linear belt of oceanic amphibolites with a low-pressure inverted metamorphic gradient; (c) crustal-scale ductile shear zones; and (d) mafic, noritic intrusions of high-Mg andesite (boninite) composition. The relationships between these elements led to the proposal of a model of ridge subduction for this sector of the Hercynian belt of Europe. This interpretation is supported by the age relationships displayed between the main rock units considered representative of the main tectonic and petrological processes responsible for the geological elements mentioned previously. The results of a geochronological study (Ar–Ar, Rb–Sr and Sm–Nd) clearly support a Late Paleozoic tectonic evolution at an active continental margin. The time evolution of the metamorphism in the oceanic domain, ranging from 342.6±0.6 Ma in the west to 328.4±1.2 Ma in the east, over a distance of 70 km along the metamorphic belt, support a tectonic model of triple-junction migration responsible for the creation at depth of a slab-free window with decisive consequences for the thermal evolution of the region. The origin of the linear metamorphic belt of HT/LP regime may be explained by the migration along a continental margin of a punctual thermal anomaly induced by the creation of a triple-junction at the continental margin. Received: 9 March 1998 / Accepted: 9 December 1998  相似文献   

13.
Summary High-grade blocks in the Franciscan complex at Tiburon, California, record relatively low temperature eclogite-facies metamorphism and blueschist-facies overprinting. The eclogite-facies mineral assemblage contains prograde-zoned garnet + omphacite + epidote ± hornblende (katophoritic and barroisitic Ca–Na amphibole) ± glaucophane + phengite (∼3.5 Si p.f.u.) ± paragonite + rutile + quartz. The blueschist-facies mineral assemblage contains chlorite + titanite + glaucophane + epidote ± albite ± phengite (∼3.3 Si p.f.u.). Albite is not stable in the eclogite stage. New calculations based on garnet-omphacite-phengite thermobarometry and THERMOCALC average-P–T calculations yield peak eclogite-facies P–T conditions of P = 2.2–2.5 GPa and T = 550–620 °C; porphyroclastic omphacite with inclusions of garnet and paragonite yields an average-P–T of 1.8 ± 0.2 GPa at 490 ± 70 °C for the pre-peak stage. The inferred counterclockwise hairpin P–T trajectory suggests prograde eclogitization of a relatively “cold” subducting slab, and subsequent exhumation and blueschist-facies recrystallization by a decreasing geotherm. Although an epidote-garnet amphibolitic assemblage is ubiquitous in some blocks, P–T pseudosection analyses imply that the epidote-garnet amphibolitic assemblage is stable during prograde eclogite-facies metamorphism. Available geochronologic data combined with our new insight for the maximum pressure suggest an average exhumation rate of ∼5 km/Ma, as rapid as those of some ultrahigh pressure metamorphic terranes.  相似文献   

14.
Four massif-type anorthosite bodies 25–100 km2 in area occur within high-pressure granulite facies supracrustal gneisses in southwestern Madagascar. Two of these bodies (Ankafotia and Saririaky) appear to have been pulled apart by 40 km in a ductile shear zone, but structural features such as sub-vertical stretching lineations indicate an origin by intense west-directed flattening and pure shear. Country rocks (Graphite Series) include abundant graphite schist (some with >60% graphite), marble, quartzite, and minor amphibolite and leucogneiss. Comagmatic granitoids (e.g. charnockites) are conspicuously absent. The anorthosite bodies are dominated by coarse grained anorthosites and leuconorites (feldspars typically 3–5 cm, up to 1 m); minor norites and oxide-rich ferrogabbros occur near the margins, but ultramafic rocks are absent. Typical mineralogy of the anorthositic rocks is: plagioclase (An41–54) + orthopyroxene (En38–66) ± augite (Mg♯ = 32–68) ± ilmenite ± magnetite ± apatite. High-alumina (to 6.1 wt% Al2O3) orthopyroxene megacrysts are widespread; most have exsolutions of calcic plagioclase (An72–85) but some contain garnet lamellae. Metamorphism has produced abundant recrystallization and sporadic coronitic garnet (Mg ♯=12–36) + clinopyroxene assemblages. Rb-Sr isotopic analyses of whole-rocks and minerals reveal no meaningful age relationships. The age of late Neoproterozoic metamorphism is best constrained at 559 ± 50 Ma by a 6-point Sm-Nd mineral isochron (whole rock, plag, pyx, ilm, apat, gar) from a Saririaky oxide-rich gabbro. The igneous crystallization age of the anorthosites is estimated at 660 ± 60 Ma by a 19-point combined whole-rock and mineral Sm-Nd isochron for samples from both the Ankafotia and Saririaky bodies. Initial isotopic ratios calculated at 0.66 Ga among 13 whole rocks are: Nd=+2.6 to +5.2 (mean=+3.7) and ISr=0.70328–0.70407 (mean=0.70347), indicating derivation of the Malagasy anorthosites from a depleted mantle source, and little, if any, contamination with Archean crustal material. One anorthosite sample with Nd=−1.4 and ISr=0.70344 (calculated at 0.66 Ga) probably reflects the effects of assimilation of Early to Middle Proterozoic crustal basement, but typical surrounding graphite schist (Nd=+0.3, ISr=0.70636, both at 0.66 Ga; TDM= 1131 Ma) represents only a minor potential contaminant for the anorthosite bodies. TDM model ages of the Malagasy anorthosites (797–1280 Ma; mean of 14 samples=949 Ma), as those of most other massif-type anorthosites, are older than the true crystallization age, because of crustal contamination effects. Our isotopic data, together with recent U-Pb data from the anorthosites and surrounding country rocks, are consistent with emplacement of the Malagasy anorthosite bodies at or before the start of a protracted, high-grade metamorphic event or series of events between about 630 and 550 Ma. This period coincides with the collision between, and amalgamation of, East and West Gondwana. Received: 19 December 1997 / Accepted: 12 June 1998  相似文献   

15.
P–T conditions during skarn formation in the 75.5 Ma old Ocna de Fier-Dognecea (SW Romania) ore district are assessed in this work using a combination of petrogenetic grids, Berman's TWEEQU programme, and several independent geothermobarometers. These were applied both to hornfelses surrounding the skarn and to the granodiorite which caused the skarn and contact metamorphism. The results are consistent and point to a peak metamorphic temperature of 700 ± 50 °C, decreasing away from the contact, and to a pressure of 2.8 ± 1 kbar, equivalent to ∼10 km depth in the region. These results quantify the qualitative idea that skarn mineralisation normally forms in a high T, low P contact metamorphic environment. Received: 13 February 1998 / Accepted: 8 April 1999  相似文献   

16.
Ion microprobe (SHRIMP) dating was carried out on different zircon domains from metamorphic rocks of the HP-HT terrane of central Rhodope, northern Greece, to constrain the timing of prograde and retrograde stages within a single tectono-metamorphic cycle. A well determined P-T-t(relative) path for the metamorphic rocks of this terrane was used as a petrological basis for the geochronological investigations. Ion microprobe work was assisted by cathodoluminescence (CL) images of the zircon crystals. The geochronological results revealed that Hercynian continental crust was subducted during the Eocene. Several stages of the Eocene tectono-metamorphic cycle – including both the prograde and retrograde parts of the P-T path above ca 300 °C, 0.3 GPa – were dated using zircons from the following rock types: (1) A deformed quartz vein probably formed at ca 300 °C, 0.3 GPa. Zircons in this vein precipitated from a hydrothermal fluid; they yielded an age of 45.3 ± 0.9 Ma which corresponds to the time of a low-T prograde stage of metamorphism. (2) In kyanite eclogites, zircons were entirely reset during eclogite-facies metamorphism. Resetting was very probably enhanced by the presence of fluids derived by H2O liberating reactions close to the P-peak. They yielded an age of 42.2 ± 0.9 Ma. (3) Orthogneisses surrounding the kyanite eclogites contained zircons with magmatic oscillatory zoned cores, which yielded Hercynian ages of 294 ± 8 Ma (age of granitic protolith formation), whereas CL-bright, metamorphic rims yielded, like the eclogite zircons, ages of 42.0 ± 1.1 Ma. Therefore, both the eclogites and orthogneisses are interpreted to have approached maximum depth at around 42 Ma. (4) In a leucosome of a migmatized orthogneiss, oscillatory zoned zircons yielded an age of 40.0 ± 1.0 Ma. At this time the rocks reached maximum temperatures during early decompression. (5) A late pegmatite crosscutting the schistosity of amphibolites contained oscillatory zoned zircons that yielded a crystallization age of 36.1 ± 1.2 Ma. Thus, the whole tectono-metamorphic cycle above ca 300 °C, 0.3 GPa lasted from 45.3 ± 0.9 Ma to 36.1 ± 1.2 Ma, that is 9.2 Ma with an extreme error value of 2.1 Ma. Based on combined SHRIMP and petrological data, the average rates of heating and burial during subduction (above ca 300 °C, 0.3 GPa) are >94 °C/Ma and >15 mm/a, respectively. Rates of cooling and exhumation (also above 300 °C, 0.3 GPa) are calculated to be >128° C/Ma and >7.7 mm/a. The Eocene age of metamorphism in central Rhodope implies that the terrane of, at least, central Rhodope and the Cyclades very probably was part of the same continental crust. Received: 5 October 1998 / Accepted: 18 January 1999  相似文献   

17.
The Bleikvassli massive sulfide ore deposit is hosted by Proterozoic pelitic, quartzofeldspathic, and amphibolitic rocks of the Uppermost Allochthon of the Scandinavian Caledonides. Staurolite-garnet-biotite and kyanite-staurolite-biotite assemblages indicate that metamorphism reached the kyanite zone of the amphibolite facies. Geothermobarometry was conducted on rocks in and around the deposit using a variety of silicate and sulfide calibrations. Temperature determinations are most reliant on the garnet-biotite exchange reaction, with analyses obtained from 259 garnet rims and adjacent biotite. Results from nine calibrations of the garnet-biotite geothermometer are considered, but compositional limitations of many calibrations involving high Ca and Mn contents in garnet and AlVI and Ti in biotite make many of the coexisting mineral pairs unsuitable. Average temperatures calculated from the two calibrations that most closely address the garnet-biotite compositions observed at Bleikvassli are 584 °C ± 49 °C and 570 °C ± 40 °C. The application of two calibrations of the garnet-staurolite geothermometer on a limited number of samples yields 581 °C ± 2 °C and 589 °C ± 12 °C, assuming a H2O=0.84, based upon calculations of the modal proportions of gaseous species. Pressure determinations are less constrained. Phengite and plagioclase-biotite-garnet-muscovite geobarometers give average pressures of approximately 5.0 kbar and 8.5 ± 1.2 kbar, respectively. Pressures obtained from the sphalerite-hexagonal pyrrhotite-pyrite barometer average 7.7 ± 1.0 kbar. In consideration of these results, the peak metamorphic conditions at the Bleikvassli deposit are estimated to be 580 °C and 8 kbar. Received: 18 June 1997 / Accepted: 14 May 1998  相似文献   

18.
For a long time the Moslavačka Gora Massif in Croatia has been regarded as a major outcrop of Variscan crystalline basement of the South Tisia block. However, new geochronological data indicate that this massif consists of a Cretaceous S-type granite pluton intruding a Cretaceous low-pressure/high-temperature (LP/HT) metamorphic envelope. The age of the LP/HT metamorphism is estimated at ~90–100 Ma using the method of electron microprobe based monazite dating. The Central Granite was dated at 82 ± 1 Ma (LA-SF-ICP-MS zircon age). The metamorphic complex comprises mainly felsic anatexites and orthogneisses of granitic composition, some metapelites (paragneisses and mica schists) and amphibolites. Zircons from three different samples of metagranite were dated at 486 ± 6, 483 ± 6, and 491 ± 1 Ma, suggesting that most of the metamorphic complex represents an Early Ordovician granitic series. The Cretaceous regional metamorphism culminated in granulite facies conditions of ~750°C and 3–4 kbar. A retrograde metamorphic event at lower amphibolite facies conditions overprinted the metamorphic complex. This event is probably related to the intrusion of the Central Granite. The southeastern sector of the massif was additionally affected by post-granitic, predominantly NE oriented shearing at greenschist facies conditions. As yet there is no clear evidence for Variscan events in the Moslavačka Gora Massif. Mineral relics of a medium-pressure amphibolite facies metamorphism are preserved in amphibolites. They are older than the Cretaceous LP/HT regional metamorphism, but their age is presently unknown. Some indications for a Permian regional metamorphic event are provided by inherited zircons in the Central Granite that have been dated with a Permian age, and by Permian monazite relics in metapelites. The Cretaceous high heat flow regime recorded in the Moslavačka Gora Massif is unique in the subcrop of the Pannonian Basin and may be a local feature triggered by a mafic intrusion in the lower crust.  相似文献   

19.
Petrological and isotopic investigations were undertaken on high pressure granulites of granitic to mafic composition from the Prachatice and Blansky les granulite complexes of southern Bohemia, Czech Republic. The predominant felsic granulites are quartz + ternary feldspar (now mesoperthite)-rich rocks containing minor garnet, kyanite and rutile, and most show a characteristic mylonitic fabric formed during retrogression along the exhumation path. Three high temperature reaction stages at distinctly different pressures are recognized. Rare layers of intermediate to mafic composition, containing clinopyroxene, best record a primary high pressure–high temperature stage (>15 kbar, >900 °C), and a well-defined overprint at medium pressure granulite facies conditions (6–8 kbar, 700–800 °C) during which orthopyroxene (+plagioclase) formed from garnet and clinopyroxene. A further high temperature overprint at lower pressure (ca. 4 kbar) is reflected in the development of cordierite- and/or andalusite-bearing partial-melt patches in some felsic granulites. Conventionally separated zircons from the granulites were measured on a SHRIMP II ion microprobe. Near-spherical, multifaceted grains interpreted to be metamorphic, and short prismatic grains from the cordierite-bearing melt patch, are all concordant and yielded indistinguishable results producing an average age, for 83 individual grain spots, of 339.8 ± 2.6 Ma (2σ). Metamorphic grains from a meta-granodiorite associated with the granulites gave the same age (339.6 ± 3.1 Ma, mean of 9), whereas inherited magmatic grains of the same sample yielded 367.8 ± 1.4 Ma. A mean age of 469.3 ± 3.8 Ma was obtained for two short prismatic concordant grains in one of the granulites, whereas several of the rounded grains with ca. 340 Ma metamorphic zircon overgrowths had much older (207Pb/206Pb minimum ages up to 1771 Ma) discordant cores. In addition to analysis of conventionally separated grains, ion-microprobe measurements were also made on zircons extracted from thin sections (drilled-out, mounted and repolished) such that a direct relationship between the dated zircons and petrographic position could be made. Identical results were obtained from both preparation methods, thus showing that the considerable advantage in petrological control is not offset by any appreciable lack of precision when compared to conventionally prepared ion-microprobe samples. All these isotopic results are identical to those previously obtained by conventional multigrain and single-grain evaporation techniques, but rather than allowing a greater resolution of the age of the petrographically obvious different metamorphic stages the results document, for the first time, the apparent short time scale for high, medium and low pressure metamorphism in the granulites. The short time period between the 340 Ma age for the high pressure granulites, as derived here and from studies of similar rocks elsewhere in the European Variscides, and the 320–330 Ma ages for regional low pressure–high temperature metamorphism, migmatization and granite magmatism, strongly suggests an important link between these two high temperature processes. Received: 25 February 1999 / Accepted: 27 September 1999  相似文献   

20.
Summary ?Diffusion modeling of zoning profiles in garnet rims from mafic granulites is used to estimate cooling rates in the Proterozoic basement of Sri Lanka, which represents a small, but important fragment of the Gondwana super-continent. Metamorphic peak temperatures and pressures, estimated with two-pyroxene thermometry and garnet–clinopyroxene–plagioclase–quartz (GADS) barometry, yield 875±20 °C and 9.0±0.1 kbar. These peak metamorphic conditions are slightly higher than results obtained by garnet-biotite Fe–Mg exchange thermometry of 820±20 °C. Reset flat zoning profiles were observed in most garnets. Only narrow garnet rims touching biotite exhibit retrograde zoning in terms of Fe and Mg exchange. The garnet zoning observed requires a slow cooling history. Equilibrium was achieved along grain boundaries during or close to peak metamorphism. During subsequent cooling to lower temperatures, only local exchange between garnet and biotite occurred. A cooling rate of 1–5 °C/Ma is estimated. The estimated temperature-time history from garnet profiles is in good agreement with the cooling history inferred from mineral radiogenic ages in the literature. Received December 11, 2001; revised version accepted August 28, 2002  相似文献   

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