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1.
本文采用电动势法对318.15 K下三元体系KBr-K2SO4-H2O的热力学性质进行研究。首先,测定了KBr-H2O溶液中KBr的电动势,线性回归出电极响应斜率κ和电极常数E0,结果表明实验所用离子选择性电极具有良好的能斯特响应。然后,对318.15 K下三元体系KBr-K2SO4-H2O混合溶液中KBr的平均活度系数进行了研究,绘制了离子强度I及离子强度分数yb与KBr的平均活度系数关系图,由图可得,当离子强度I一定,随着离子强度分数 yb增大,KBr平均活度系数逐渐减小,且减小的趋势越来越大。当离子强度分数yb是个定值时,KBr平均活度系数随着离子强度I的增大而减小。应用活度系数数据通过多元线性回归拟合出该温度条件下Pitzer模型混合离子作用参数θBr,SO4和ψK,Br,SO4,并计算了混合溶液中K2SO4的平均活度系数、渗透系数Φ,水活度aw,超额吉布斯自由能GE。应用拟合的Pitzer混合离子相互作用参数和Pitzer模型计算了该三元体系在318.15 K下的溶解度数据,并对计算结果和其他温度下已经报道的KBr-K2SO4-H2O三元体系的共饱和点处的溶解度数据进行比较,对比结果表明,溶解度计算结果可靠,拟合的离子相互作用参数具有较好的精度,可用于计算相关体系的热力学参数和相平衡的预测。  相似文献   

2.
b
The effect of anisotropy on the distribution of Earth's conductivity is evaluated by calculating the electromagnetic response of multilayered 2-D structures. The electric and magnetic fields are expanded in terms of Fourier series, the coefficients being obtained by applying the corresponding boundary conditions on each interface, given by arbitrary analytical functions. Then the results are used to analyse some particular structures.  相似文献   

3.
Summary. A method for the determination of the electrical conductivity of the Earth is developed when the components of the response function on the basis of spherical harmonics for a fixed frequency are known. By writing the differential equation for the field inside a spherically symmetric conductor as a finite difference equation, it is shown that the formal solution of the latter for the response function has a Thiele representation in the degree of the harmonics. This property enables one to calculate the conductivity at a finite number of points using a continued-fraction expansion of the response function.  相似文献   

4.
Summary. Geomagnetic time-variations observed at several sites on the island of Hawaii are analysed for the effects of island bathymetry as well as for the inductive response of the deeper mantle. The data are generally consistent with the deep conductivity profile derived using lower frequency, electromagnetic data from the Island of Oahu. Hawaii data fit better if that model is modified to give the upper 200 km of the mantle a lower conductivity of 0.02 S/m compared to 0.1 S/m for Oahu. The data are represented by a complex, frequency-dependent function of location, T u, relating the vertical variation Z to a component U of the horizontal variation ( Tu = Z/U ). The direction of U is nearly frequency independent at each site but is different for each site. Below a frequency of about 30 cycles per day, the functions, T u, at any two sites are found to be related by a real constant. This suggests that the deeper conductivity structure is the same beneath each site. This result is consistent with quasi-static induction in a non-uniformly conducting thin sheet above a stratified conductivity structure. The response of such a model can be written as T u= Aq , where q is a quasi-uniform, complex, frequency-response function characterizing the effect of the deep conductivity and A is a spatially dependent parameter parameterizing the effect of variable conductivity in the thin sheet. The parameter A may be estimated by fitting observational estimates of T u to models of deep conductivity structure.  相似文献   

5.
Summary. From consideration of the higher order terms, it is shown that the magneto-telluric response is Fréchet differentiable with respect to conductivity; this result remains valid for discontinuous profiles, which is not so in the case of the corresponding free-oscdlation problem for the elastic earth. The remainder term in the Fréchet formula is shown to be O|δσ|2 and a numerical estimate is made of the bounding constant for a restricted class of conductivity models.  相似文献   

6.
Summary. We demonstrate a method of performing linear programming optimizations of functionals of subsurface temperature, when thermal conductivity is a known piecewise-constant function. Data comprise heat flow measurements on the flat isothermal surface of this structure, within which heat transfer is by steady-state conduction. Two-dimensionality is assumed. The approach involves establishing constraints which demand the continuity of temperature and the normal component of heat flow across all internal boundaries. These unknown functions are expanded as truncated Fourier series whose coefficients become unknowns of the linear programming solution vector; linear relations are established between these coefficients which guarantee harmonicity of temperature in each region of uniform conductivity, as well as the continuity requirements. Variations of the formalism are detailed for three simple types of geometry. As an example the method is applied to a heat flow data set from Sass, Killeen & Mustonen over the Quirke Lake Syncline of Ontario, Canada.  相似文献   

7.
Semi-parametric geographically weighted generalized linear models (S-GWGLMs) are a useful tool in modeling a regression relationship where the impact of certain explanatory variables on a non-Gaussian distributed response variable is global while that of others is spatially varying. In this article, we propose for S-GWGLMs a new estimation method, called two-stage geographically weighted maximum likelihood estimation, and further develop a likelihood ratio statistic-based bootstrap test to determine constant coefficients in the models. The performance of the estimation and test methods is then evaluated by simulations. The results show that the proposed estimation method performs as well as the existing method in estimating both constant and spatially varying coefficients but it is more efficient in terms of computation time; the bootstrap test is of accurate size under the null hypothesis and satisfactory power in identifying spatially varying coefficients. A real-world data set is finally analyzed to demonstrate the application of the proposed estimation and test methods.  相似文献   

8.
FIR filter effects and nucleation phases   总被引：1，自引：0，他引：1  
The symmetric impulse response of linear phase Finite Impulse Response (FIR) filters most commonly used in modern seismic recording systems produces precursory signals to impulsive arrivals. These acausal filter-generated artefacts may result in misinterpretations of various onset properties. Prior to any onset interpretation, these effects have to be removed from the seismic record. This can be achieved without loss of bandwidth by post-filtration of the digital seismograms if the filter coefficients and the decimation ratios are known. We have analysed numerous signals from different instruments and sampling rates for precursory phases and found that—in contrast to commonly held beliefs—FIR-filter-related precursory signals are not always easy to recognize visually from their waveform signature. Furthermore, they can exhibit surprisingly similar properties to those reported for nucleation phases, although the majority of nucleation phases reported in the past have been obtained on instruments with a causal response. We demonstrate examples of filter-related precursory signals for events scanning nine orders of moment, from 1010 N m to 1019 N m. Surprisingly, the lower bound of the artefact durations as a function of seismic moment scales close to the cube root of the seismic moment. We interpret this as being caused by the fact that above a certain seismic moment, the attenuated source signal acts as a causal lowpass filter of a smaller bandwidth than the FIR filter. Assuming an ω-2 source model, constant stress drop and an empirical relationship between the maximum artefact duration and the cut-off frequency of the FIR filter, the artefact durations are expected to scale proportional to the 1/2.5 power of the seismic moment, in comparison to 1/3 as proposed for nucleation phases.  相似文献   

9.
王芳  杨美芳 《盐湖研究》2007,15(3):14-18
用电动势法测定了KI在甲醇含量为0%、20%、60%、100%的甲醇-水混合溶剂中的电动势,用幂级数展开方法、扩展的Debye-Hückel方程及Pitzer方程关联不同溶剂组成下电动势的实验值,得到电池的标准电动势E°和KI在混合溶剂中的活度系数。结果表明,在一定的溶剂比例下,KI的平均活度系数先随它的浓度增加而下降,经过一个最低点后上升,或者随浓度增加而单调递减。当KI浓度固定时,它的平均活度系数随溶剂中甲醇的含量增加而下降,表明KI在甲醇中有微弱的缔合。  相似文献   

10.
The C -response connects the magnetic vertical component and the horizontal gradient of the horizontal components of electromagnetic variations and forms the basis for deriving the conductivitydepth profile of the Earth. Time-series of daily mean values at 42 observatories typically with 50 years of data are used to estimate C -responses for periods between 1 month and 1  yr. The Z : Y method is applied, which means that the vertical component is taken locally whereas the horizontal components are used globally by expansion in a series of spherical harmonics.
In combination with results from previous analyses, the method yields consistent results for European observatories in the entire period range from a few hours to 1  yr, corresponding to penetration depths between 300 and 1800  km.
1-D conductivity models derived from these results show an increase in conductivity with depth z to about 2  S  m-1 at z =800  km, and almost constant conductivity between z =800 and z =2000  km with values of 310  S  m-1, in good agreement with laboratory measurements of mantle material. Below 2000  km the conductivity is poorly resolved. However, the best-fitting models indicate a further increase in conductivity to values between 50 and 150  S  m-1.  相似文献   

11.
通过拉曼光谱、同步辐射X射线散射和密度泛函理论(DFT)模拟,研究了质量分数为1.0 %-28.0 %的NH4Cl水溶液的微观结构变化。同时在室温下测量了粘度、接触角和电导率。由拉曼光谱和密度泛函理论模拟结果可知,当溶质浓度升高至10.0 %时,在2900 cm-1和3100 cm-1附近出现了明显的N-H作用峰,且随着质量分数的升高,NH4Cl水溶液中的氢键类型发生了转变。X射线散射结果表明,当NH4Cl水溶液质量分数升高至10.0 %时,差值对分布函数G(r)在2.98 ?附近出现明显双峰,表明在该浓度下溶液中NH4+-Cl-接触离子对开始成为主要微观作用形式。对NH4Cl水溶液的宏观物性研究表明,粘度、接触角和电导率均随着NH4Cl水溶液质量分数的增加而增大。作者推断,NH4Cl水溶液中氢键类型的转变、O-H...N键占比增多以及逐渐增加的NH4+-Cl-接触离子对,是粘度和接触角随溶质浓度增加而增加的微观本质因素;电导率的增加与溶液中有效导电离子数量增加有关。  相似文献   

12.
在HCl-NiSO4-H2 O混合溶液中 ,以标准氢电极和银—氯化银电极组成无液接电池 ,恒定溶液总离子强度I和NiSO4在溶液中的离子强度分数yB 的条件下 ,在 2 78 1 5～ 3 2 3 1 5K温度范围内测定下列电池的电动势Pt,H2 ( 1 0 1 3 2 5kPa) |HCl(mA) ,NiSO4(mB) ,H2 O|AgCl-Ag由于体系存在硫酸的二级解离 ,应用数学迭代方法确定平衡体系氢离子的浓度 ,计算了混合溶液中HCl的活度系数γA,结果表明 ,在溶液总离子强度保持恒定时 ,HCl的活度系数服从Harned规则。在溶液组成恒定时 ,盐酸的活度系数logγA 对热力学温度l/T作图 ,是一条直线  相似文献   

13.
对雷州半岛土壤渗透性进行了分析,并结合地形地貌、降雨入渗补给情况,识别地下水潜在补给区。雷州半岛土壤渗透性空间差异较大,饱和渗透系数变化范围为 0.04~8.83 m/d。总体而言,半岛南部、遂溪西北部渗透性较好,中部较差。土壤渗透系数受到土地利用类型、土壤粒径、土壤有机质等的影响。随着土壤中值粒径和有机质含量的增加,土壤渗透系数增加。不同土地利用类型,其土壤平均渗透性优劣表现为：荒地＞桉树林＞甘蔗＞菜地＞菠萝＞其他林地＞香蕉＞苗圃＞坡稻＞水稻田。降雨入渗补给系数南北高、中间低,随着土壤渗透系数增加而提高。半岛南部石茆岭和石板岭一带,地势高,坡度较缓,同时土壤渗透性和降雨入渗补给系数相对较高,为雷州半岛地下水潜在补给区。  相似文献   

14.
Urbanization improves our lives but also threatens human health and sustainable development. Revealing the spatiotemporal pattern of urban expansion and spatiotemporal relationships with driving forces, especially in terms of the ubiquitous and fast growing small city, is a crucial prerequisite to solving these problems and realizing sustainable development. Kunshan, China was used as a case study here. Eleven variables from four aspects covering physical, socioeconomic, accessibility and neighborhood were selected, and logistic regression and geographically weighted logistic regression modeling were employed to explore spatiotemporal relationships from 1991-2014. Results reveal that urban expansion in Kunshan shows an accelerating tendency with annual expansion from 2000-2014 four times higher than for 1991-2000. More importantly, the annual expansion rate of Kunshan of 28.42% in 2000-2014 is higher than that of a large city. Urban expansion and related factors have spatiotemporal varying relationships. From a global perspective, the closer to a city, town, main road and the higher the GDP, the more likely a region will undergo urbanization. Interestingly, the effect of population on urban expansion is decreasing, especially in developed areas, and the effect of distance to lake is enhanced. From a local perspective, the magnitude and even the sign of the coefficients vary across the study area. However, the range of the coefficient of GWLR is around that of the corresponding variable in LR, and the sign of most variables in GWLR is consistent with that of corresponding variables in LR. GWLR surpasses LR with the same explanatory variables in revealing regional differences and improving model reliability. Based on these findings, more attention should be given to small cities in China. Promoting the connotation of city culture and public services to realize New-type Urbanization and regional diversity policy in order to manage urban expansion scientifically are also recommended.  相似文献   

15.
We present a spectral-finite-element approach to the 2-D forward problem for electromagnetic induction in a spherical earth. It represents an alternative to a variety of numerical methods for 2-D global electromagnetic modelling introduced recently (e.g. the perturbation expansion approach, the finite difference scheme). It may be used to estimate the effect of a possible axisymmetric structure of electrical conductivity of the mantle on surface observations, or it may serve as a tool for testing methods and codes for 3-D global electromagnetic modelling. The ultimate goal of these electromagnetic studies is to learn about the Earth's 3-D electrical structure.
Since the spectral-finite-element approach comes from the variational formulation, we formulate the 2-D electromagnetic induction problem in a variational sense. The boundary data used in this formulation consist of the horizontal components of the total magnetic intensity measured on the Earth's surface. In this the variational approach differs from other methods, which usually use spherical harmonic coefficients of external magnetic sources as input data. We verify the assumptions of the Lax-Milgram theorem and show that the variational solution exists and is unique. The spectral-finite-element approach then means that the problem is parametrized by spherical harmonics in the angular direction, whereas finite elements span the radial direction. The solution is searched for by the Galerkin method, which leads to the solving of a system of linear algebraic equations. The method and code have been tested for Everett & Schultz's (1995) model of two eccentrically nested spheres, and good agreement has been obtained.  相似文献   

16.
New magnetotelluric data from the Münchberg Gneiss complex in Southern Germany reveal a zone of extremely high electrical conductivity. 1-D modelling of the data is justified in the period range 0.01 to 10  s. At least three layers are required to explain the steepness of the apparent resistivity curves, and the best-fitting models comprise four layers with successively higher conductivities. The layers of highest conductivity at depths between 2.2 and 3.6  km correlate with pronounced bands of high seismic reflectivity (profile DEKORP 85-4N). The Münchberg complex is today widely recognized as a tectonic klippe, consisting of rocks whose metamorphic and stratigraphic order is inverted rather than overturned. The material was transported into its present position by predominantly horizontal tectonic forces along shear zones. We interpret the high conductivity and high reflectivity as remnants of this transport process.  相似文献   

17.
A series solution of the plane SH-waves incident on a partially filled semi-circular alluvial valley imbedded in a half-space is presented. Based on the region-matching method, the analysed region is decomposed into two subregions by the interface between two media. The antiplane displacement field of each subregion is expressed in terms of an infinite series of cylindrical wavefunctions with unknown expansion coefficients. After imposing the traction-free condition on the curved valley surface and the matching conditions on the interface with the aid of Graf's addition theorem, the unknown coefficients are obtained. Both the frequency- and time-domain responses are evaluated. In the theoretical derivation of this work, two classical exact series solutions are also included, so the present series solution is more general than those given before. Visible effects of different physical parameters on ground surface motions are illustrated in graphical form.  相似文献   

18.
Summary. A striking feature of the day-side response of the Moon to periodic fluctuations in the solar wind is the rapid rise, and subsequent fall, in the amplitude of the transfer function as the inducing field frequency increases. This behaviour can be characterized by the amplitude values at the two frequencies 24 and 40 mHz. Before the response of a conductivity model representing the Moon can be calculated at a given frequency, the parameters (ν, θ) (where ν is the solar wind speed and θ is the angle between the solar wind velocity and the magnetic field propagation direction) have to be specified. By applying some results due to Parker (1972) to the above two data points, we have determined constraints on the parameter space (ν, θ). In particular, we determine the region of the (ν, θ) space in which conductivity models may be found that satisfy our data pair. Outside this region, there are no conductivity models satisfying the data pair, and hence many (ν, θ) values are inconsistent with the original data and the model assumptions.  相似文献   

19.
This paper analyzes panel data from 2003-2012 to identify the factors driving the expansion of construction land in Ningbo city; it uses panel data, regional-level, and year-by-year regression models. The results indicate the following: (1) For each 1% increase in the size of the economy, urban population, and industrial structure adjustment coefficient, the amount of construction land increased by 0.35%, 0.52% and -1%, respectively. (2) The factors driving the expansion of urban construction land differed across regions. In more highly developed areas such as Yuyao, Cixi, Fenghua and the downtown area, population growth was the most obvious driving factor with coefficients of 4.880, 1.383, 3.036 and 0.583, respectively, in those areas. Here, the impact of industrial structure adjustment was lower than that of population growth (with coefficients of 1.235, 0.307, 0.145 and -0.242), while economic development was an increasingly insignificant factor (with coefficients of -0.302, 0.071, 0.037 and 0.297). On the other hand, economic development was the most important factor for the expansion of construction land in relatively less developed areas such as Xiangshan and Ninghai counties with coefficients of 0.413 and 0.195, respectively. Here, population growth (with coefficients of -0.538 and 0.132) and industrial structure adjustment (with coefficients of -0.097 and 0.067) were comparatively weaker driving factors. (3) The results of the year-by-year regression indicate the increased impact of economic development as a driving factor (from -1.531 in 2005 to 1.459 in 2012). The influence of the population growth factor slowly declined (from 1.249 in 2005 to 0.044 in 2012) and from 2009 on was less influential than the economic development factor. The industrial structure coefficient remained negative and its influence diminished from year to year (from -5.312 in 2004 to -0.589 in 2012).  相似文献   

20.
Urban expansion models are useful tools to understand urbanization process and have been given much attention. However, urban expansion is a complicated socio-economic phenomenon that is affected by complex and volatile factors involving in great uncertainties. Therefore, the accurate simulation of the urban expansion process remains challenging. In this paper, we make an attempt to solve such uncertainty through a reversal process and view urban expansion as a process wherein the urban landscape overcomes resistance from other landscapes. We developed an innovative approach derived from the minimum cumulative resistance (MCR) model that involved the introduction of a relative resistance factor for different source levels and the consideration of rigid constraints on urban expansion caused by ecological barriers. Using this approach, the urban expansion ecological resistance (UEER) model was created to describe ecological resistance surfaces suitable for simulating urban expansion and used to simulate urban expansion in Guangzhou. The study results demonstrate that the ecological resistance surface generated by the UEER model comprehensively reflects ecological resistance to urban expansion and indicates the spatial trends in urban expansion. The simulation results from the UEER-based model were more realistic and more accurately reflected ecological protection requirements than the conventional MCR-based model. These findings can enhance urban expansion simulation methods.  相似文献   

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