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1.
本文以高渗透压渗流试验装置模拟已被污染的浅层地下水越流通过弱透水层污染深层地下水的过程,研究了有机污染物(菲)通过饱和粘性土弱透水层时的自然衰减特征,以及非生物因子-配位体对于弱透水层中菲迁移转化的影响作用。研究表明,菲的衰减曲线明显分为三阶段:初期吸附截留显著期,中期微生物降解旺盛期,后期微生物降解稳定期;溶液中共存离子HCO 3-、Ca2+与菲形成络合物,SO42-参与菲的生物降解;溶液中主要配位体不同时,菲与阴、阳离子之间相互作用的方式也不同,以络合作用为主。渗透水中菲含量有99%以上被衰减,仅有极少量菲穿透弱透水层。 相似文献
2.
天津市宁河北奥陶系灰岩水源地的水文地球化学模拟 总被引：8，自引：3，他引：5
天津市宁河北水源地属埋藏型地下水源地,其开采层奥陶系灰岩含水层呈北东向的向斜展布,隐伏于石炭系-二叠系砂页岩之下,并被新近系覆盖,仅在东北部与第四系含水层有水力联系,地下水的补给主要来自浅层第四系含水层的越流补给。应用水文地球化学模拟方法,研究从第四系含水层到奥陶系含水层地下水经历的水-岩作用,包括方解石、白云石、萤石和硬石膏的溶解或沉淀、二氧化碳气体的溶解或逸出等,地下水硬度、矿化度总体上有下降趋势,这是由于含Ca2+、Mg2+和HCO-3的矿物相发生溶解,迁入溶液的比率要小于发生沉淀迁出溶液的比率,具体表现在从第四系含水层到奥陶系含水层Ca2+、和HCO-3浓度的降低幅度较大。通过模拟计算,可以定量确定从补给区到研究区沿水流路径上的水-岩相互作用及质量交换,有助于揭示该区地下水化学环境的演化机制。 相似文献
3.
为支撑滇东富源县古敢水族乡热水塘温泉旅游的开发和可持续利用,笔者等通过采集区内水样进行水化学及环境同位素分析,对温泉的形成机理及其理疗价值进行了研究。结果表明：热水塘温泉温度为37.8～42.2℃,pH值为7.24～7.75,TDS(溶解固态物质总量)的质量浓度为1245～1840 mg/L,属于中低温弱碱性热矿水。温泉水中偏硅酸的质量浓度为48.20～60.57 mg/L,F为2.86～2.94 mg/L,Sr为8.60～14.40 mg/L,均达到了硅水、氟水、锶水的理疗水质标准,此外温泉水中222Rn浓度达到了129.4 Bq/L,接近于氡水的理疗水质标准,具有较大的开发利用价值。热水塘温泉水中阳离子以Ca2+、Mg2+为主,阴离子以SO42-、HCO-3为主,水化学类型为SO42-—Ca2+·Mg2+型。石膏和碳酸盐岩矿物的溶解是控制热水塘... 相似文献
4.
利用水化学方法识别岩溶水文系统中的径流 总被引：2，自引：0，他引：2
通过暴雨中的野外观测,确认了桂林丫吉试验场S31泉岩溶水文系统中多种径流形式：表层岩溶带管道流、回归流、坡面流和壤中流。现场测量发现不同形式径流的水化学特征(pH、电导率、Ca2+、HCO-3)存在差异,Ca2+的质量浓度相差最大可以达到3倍。从CaCO3-H2O-CO2平衡体系来看,CO2分压（pCO2）对径流的水化学特征具有控制作用。在大气pCO2影响下的岩溶水矿化度较低,而土壤空气pCO2达到2.7%,是大气的近百倍,其影响的径流矿化度较高。鉴于大气中和土壤中pCO2的显著差异,从水化学特征上将径流分为2类,并且认为它们构成了系统出口洪水的2个主要来源。在此基础上利用水化学方法计算出S31岩溶泉洪水时的径流构成。结果表明,在暴雨的情形,由大气pCO2环境产生形成的岩溶水的比例占到泉水总量的70%,进一步证明了快速流在岩溶水中的重要作用。 相似文献
5.
宁夏吴忠市金积水源地地下水水质影响因素的多元统计分析 总被引：2，自引：0，他引：2
根据吴忠市金积水源地地下水饮用水用途选择11项水化学指标,采集32个地下水水样进行测试分析及处理。在分析金积水源地地下水流场及水化学特征基础上,综合利用因子分析法和系统聚类分析方法对水质影响因素进行评价,2种方法评价结果基本一致。结果表明,该区地下水水质影响因素主要有：以Cl-、SO2-4、Mg2+、NO-3、Ca2+质量浓度为代表变量的溶滤作用,该作用表现为西强东弱,综合主成分贡献率48.40%;以EC、总硬度及TDS、Na+、HCO-质量浓度为代表变量的蒸发浓缩作用,沿补给区和排泄区作用较强,综合主成分贡献率39.66%;以NH4-N质量浓度为主要载荷变量的人类活动影响因素,因子得分较高区域与企业分布及排污范围分布一致,综合主成分贡献率11.94%。水质影响因素分布总体表现为黄河沿岸蒸发浓缩作用相对较强;汉渠以北主要受溶滤作用及地下水蒸发浓缩共同影响;南干沟及南干沟入黄河口附近氨氮污染较明显。 相似文献
6.
从化温泉位于广州东北部,出露于燕山期花岗岩地区,位于北东向广州-从化断裂带北东段;热水中阳离子以K+、Na+、Ca2+为主,阴离子以HCO-3为主,水化学类型为HCO3-Na及HCO3-Na·Ca型。利用NETPATH程序对泉区热水进行水化学模拟,发现从化温泉各泉点的水化学特征相似,径流过程中发生的化学反应也相似;从初始水点到终端水点,发生的各种反应交换量很低;在径流过程中各矿物的净反应可能为钾长石、高岭石、赤铁矿、萤石沉淀,CO2、斜长石、黑云母溶解;SiO2的溶解/沉淀在各泉点不同;径流过程中发生了Ca2+/Na+、Mg2+/Na+离子交换作用。 相似文献
7.
广东丰顺丰良地区出露的地热水温度高达96℃,热储层为裂隙发育的下侏罗统的英安斑岩,F-含量较高。但关于其地热流体的补给来源、循环演化过程及热储温度研究较少。笔者等基于早期开展的勘探工作和补充采集、测试的地热水和气体数据,探讨了该地热系统的流体成因及热储温度。结果表明,丰良地区地热水存在2类,A类地热水温度普遍低于40℃,Ca2+含量高,Na+和K+含量低,以HCO-3—Ca2+型为主;B类地热水Na+含量高,Ca2+含量低,为HCO-3—Na+型。A类地下水可能受浅层地下水混入影响,但缺少直接证据。B类地下水由周边山区的大气降水补给,沿裂隙或者断裂系统进入英安斑岩储层,循环深度和水—岩相互作用时间分别可达5200～6300 m和22 ka;储层温度条件下铝硅酸盐矿物的溶解以及阳离子交换作用促进了富N2、S... 相似文献
8.
广西红水河中下游澄江地区地下水地球化学特征 总被引：1，自引：0，他引：1
以西南岩溶地下水污染调查评价中广西红水河中下游澄江地区地下水数据为基础,对该地区26件样品的水化学类型、化学成分含量特征、成分间相关特征以及化学成分的空间分布特征及影响因素进行了研究。结果表明：该地区地下水水化学类型为Ca-HCO3型或Ca·Mg-HCO3型;地下水中测试指标背景含量均未超过Ⅲ类水标准;大部分测试指标在该地区地下水中分布较均匀,只有Zn、Se和Hg在局部富集,分布不均匀;该地区地下水中元素含量与pH值没有明显的相关关系,而总硬度、HCO-3、Ca2+、Mg2+、K+、Na+、SO2-4、NO-3、I-等元素间则显示出一定的相关关系,地下水中起决定性作用的是HCO-3、Ca2+、Mg2+;该地区地下水中元素含量空间上具有片状分布特点,主要受地质背景、地理条件和人类活动的综合作用所制约。 相似文献
9.
2008年10月和2009年10月在祁连山老虎沟12号冰川积累区采集了2个雪坑样品, 通过样品中δ18O、可溶性离子、不溶性微粒的变化特点划分了雪坑季节. 2008年雪坑季节变化信号明显, 而2009年雪坑不明显, 微粒浓度、Ca2+与Mg2+含量在春季较高. 离子平衡、pH值、电导率及同期气象记录观测资料均显示, 2009年雪坑受淋溶影响较大. 淋溶强烈时, 受融水造成的粉尘溶解及离子淋溶的影响, 雪坑中微粒与Ca2+、Mg2+变化趋势不甚一致; 与Ca2+相比, Mg2+变化能够较好表征微粒的变化; d>5 μm的微粒可能更易于溶解迁移. 通过分析室内雪冰样品在液态下的变化, 发现伴随静置过程微粒的质量浓度呈下降的趋势, 期间Ca2+、Mg2+却呈现增加的变化, 可能与碳酸盐矿物的溶解有关. 相似文献
10.
以牡丹江市主城区为研究区,对该区采集的24组第四系地下水样品中常规离子进行检测和分析,利用数理统计、Piper三线图、Gibbs模型、离子比例关系等方法识别地下水主要离子成因。结果表明,研究区第四系地下水中主要离子含量变化均具有较强的离散性,阴离子平均浓度HCO3->SO42->Cl-,阳离子平均浓度Ca2+>Na+>Mg2+>K+,地下水整体为淡水,呈中性偏弱酸性,水化学类型以HCO3—Na·Ca型水为主;水中的化学组分主要来源于岩石风化溶解,其中,Na+和K+主要来源于硅酸盐矿物的溶解,Ca2+和Mg2+主要受碳酸盐、硫酸盐和硅酸盐矿物风化溶解作用共同控制,同时水中阳离子间存在一定交换作用。 相似文献
11.
Unconsolidated sand, gravel and clay deposits near Beihai and in the Leizhou Peninsula in southern China form an unconfined
aquifer, aquitard and a confined aquifer. Water and soil samples were collected from the two aquifers in the coastal Beihai
area for the determination of chemical compositions, minerals and soluble ions. Hydrogeochemical modeling of three flow paths
through the aquitard are carried out using PHREEQC to determine water–rock interactions along the flow paths. The results
indicate that the dissolution of anorthite, fluorite, halite, rhodochrosite and CO2, and precipitation of potash feldspar and kaolinite may be occurring when groundwater leaks through the aquitard from the
unconfined aquifer to the confined aquifer. Cation exchanges between Na and Ca can also happen along the flow paths. 相似文献
12.
考虑非达西流的弱透水层固结计算 总被引：13，自引：1，他引：12
由于成岩作用的影响,深部弱透水层中的黏性土较为坚硬、致密,在这种黏土层中的孔隙渗流规律有偏离达西定律的现象,而在现有的地面沉降研究中,对深部弱透水层的固结变形计算始终沿用以达西定律为基础的固结方程进行,这显然是与实际情况不相符的。鉴于此,以孔隙渗流为非达西流为基础,对太沙基一维固结方程进行了重新推导,并采用半解析法对非达西流-太沙基一维固结方程进行了求解。分别采用达西流-太沙基固结方程和非达西流-太沙基固结方程对同一固结问题进行了计算,结果表明,考虑非达西流后土层达到某一固结度所需的固结时间较之不考虑非达西流时明显增加了,而且固结时间增长的趋势与实测的增长趋势较为一致。 相似文献
13.
Evaluation of heterogeneity and field-scale groundwater flow regime in a leaky till aquitard 总被引：2，自引：1，他引：2
Recent work in southern Ontario, Canada, demonstrates anomalously high vertical groundwater flow velocities (>1 m/year) through
a thick (as much as 60 m), sandy silt till aquitard (Northern till), previously assumed to be of very low permeability (hydraulic
conductivity <10–10 m/s). Rapid recharge is attributed to the presence of fractures and sedimentary heterogeneities within the till, but the
field-scale flow regime is poorly understood. This study identifies the nature of physical groundwater pathways through the
till and provides estimates of the associated groundwater fluxes. The aquitard groundwater flow system is characterized by
integrating details of the outcrop and subsurface sedimentary characteristics of the till with field-based hydrogeologic investigation
and numerical modeling. Outcrop and subsurface data identify a composite internal aquitard stratigraphy consisting of tabular
till beds (till elements) separated by laterally continuous sheet-like sands and gravels (interbeds) and boulder pavements. Individual till elements
contain sedimentary heterogeneities, including discontinuous sand and gravel lenses, vertical sand dikes, and zones of horizontal
and vertical fractures.
Hydrogeologic field investigations indicate a three-layer aquitard flow system, consisting of upper and lower zones of more
hydraulically active and heterogeneous till separated by a middle unit of relatively lower hydraulic conductivity. Groundwater
pathways and fluxes in the till were evaluated using a two-dimensional aquitard/aquifer flow model which indicates a step-wise
flow mechanism whereby groundwater moves alternately downward along vertical pathways (fractures, sedimentary dikes) and laterally
along horizontal sand interbeds within the till. This model is consistent with observed hydraulic-head and isotope profiles,
and the presence of tritiated pore waters at various depths throughout the till. Simulations suggest that a bulk aquitard
vertical hydraulic conductivity on the order of 1×10–9 m/s is required to reproduce observed hydraulic-head and tritium profiles.
Electronic Publication 相似文献
14.
Samantha Murphy Thomas Ouellon Jean-Marc Ballard Ren�� Lefebvre Ian D. Clark 《Hydrogeology Journal》2011,19(1):195-207
Tritium?Chelium groundwater dating was carried out in a trichloroethylene (TCE)-contaminated valley-fill aquifer system in Quebec, Canada, where a numerical groundwater flow model was developed. Forty seven discrete groundwater and dissolved gas samples were obtained along two flow paths originating from known TCE source zones whose related plumes converge down gradient to form a single plume. Sampling points in monitoring wells were projected onto vertical sections showing particle tracks along the two flow paths. At these points, simulated advective ages obtained from particle tracking were matched to tritium?Chelium ages using different porosity values; the best match was 0.35. Ages were also obtained above and below a prodeltaic silty aquitard in a portion of the aquifer where some source zones are located, which provide groundwater and TCE transit times through the aquitard as well as a mean vertical hydraulic conductivity that agrees with previous estimates used in the model. In certain locations, anomalously old ages associated with high terrigenic 4He indicate areas where groundwater from the underlying proglacial unit flows upward into the deltaic sand aquifer through aquitard windows. Upflow locations correspond with increased TCE concentrations, suggesting significant TCE provenance through the proglacial unit originating from a previously unrecognized TCE source zone. 相似文献
15.
为了研究硝酸盐在不同Eh条件下通过弱透水层的迁移机理及转化形式,用天然黏土作为渗透介质弱透水层,在高渗透压条件下进行室内实验,模拟地下水中硝酸盐通过弱透水层的迁移转化过程。结果表明：单位质量黏土截污容量为1.45 mg/g,阻截率R=92%,不同Eh条件下（Eh分别为0、-100、-200 mV）弱透水层对硝酸盐的阻截能力都很强;低氧化还原电位有利于弱透水层吸附硝酸盐。弱透水层中硝酸盐的转化途径表明,弱透水层对硝酸盐的阻截能力很强,是微孔隙截留作用、机械过滤、离子吸附、协同吸附以及较弱的微生物共同作用的结果。 相似文献
16.
17.
Anthony C. Runkel Robert G. Tipping Jessica R. Meyer Julia R. Steenberg Andrew J. Retzler Beth L. Parker Jeff A. Green John D. Barry Perry M. Jones 《Hydrogeology Journal》2018,26(7):2133-2159
A hydrogeologic conceptual model that improves understanding of variability in aquitard integrity is presented for a fractured sedimentary bedrock unit in the Cambrian-Ordovician aquifer system of midcontinent North America. The model is derived from multiple studies on the siliciclastic St. Lawrence Formation and adjacent strata across a range of scales and geologic conditions. These studies employed multidisciplinary techniques including borehole flowmeter logging, high-resolution depth-discrete multilevel well monitoring, fracture stratigraphy, fluorescent dye tracing, and three-dimensional (3D) distribution of anthropogenic tracers regionally. The paper documents a bulk aquitard that is highly anisotropic because of poor connectivity of vertical fractures across matrix with low permeability, but with ubiquitous bed parallel partings. The partings provide high bulk horizontal hydraulic conductivity, analogous to aquifers in the system, while multiple preferential termination horizons of vertical fractures serve as discrete low vertical hydraulic conductivity intervals inhibiting vertical flow. The aquitard has substantial variability in its ability to protect underlying groundwater from contamination. Across widespread areas where the aquitard is deeply buried by younger bedrock, preferential termination horizons provide for high aquitard integrity (i.e. protection). Protection is diminished close to incised valleys where stress release and weathering has enhanced secondary pore development, including better connection of fractures across these horizons. These conditions, along with higher hydraulic head gradients in the same areas and more complex 3D flow where the aquitard is variably incised, allow for more substantial transport to deeper aquifers. The conceptual model likely applies to other fractured sedimentary bedrock aquitards within and outside of this region. 相似文献
18.
Carlos José Freire Machado Maria Marlúcia Freitas Santiago Luiz Alberto Ribeiro Mendonça Horst Frischkorn Josué Mendes Filho 《Aquatic Geochemistry》2007,13(2):187-196
Flow modeling and hydrogeochemical inversion calculations were performed on the aquifer systems of the Crato-Juazeiro Graben
in the Araripe Sedimentary Basin of the Cariri Valley, Northeast Brazil, in order to assess aquifer interconnections through
an aquitard of the Araripe Plateau. Steady state hydraulic head numeric calculations with the finite difference method used
Modflow software with hydrologically based boundary conditions and a piezometric surface as initial condition. Hydrogeochemical
inversion with PHREEQC was performed for two water samples representing typical initial and final waters along the flow path.
Flow simulation shows that approximately 20% of all recharge water from the superior aquifer system passes through the Santana
aquitard reaching the middle aquifer system. Quantification of mineral dissolution/precipitation processes, ion exchange and
microbiological redox reactions taking place in the aquifer systems also indicates hydraulic interconnection of the superior
and middle aquifer systems through the Santana aquitard. 相似文献
19.
Groundwater flow in a peninsula or an elongated island is influenced by tidal fluctuations on both sides of the peninsula or island, which is named as dual tidal fluctuations. In this study, semianalytical solutions of transient groundwater flow in response to dual tidal fluctuations in an aquifer–aquitard system were presented for cases with and without the aquitard storage. These solutions were first derived using the Laplace transform and subsequently computed by the Fourier series numerical inverse Laplace transform. The derived solutions were found to agree very well with the results of numerical simulations by MODFLOW. The solution ignoring the aquitard storage approached the quasi‐steady state solution quickly when the mean sea level initial condition was used. The solutions with and without the aquitard storage were nearly the same at the early time and were separated from each other during the intermediate time, and the difference of solutions became constant at late time for small aquifer/aquitard storativity ratio and large tidal frequency. The propagation bias, which is the departure from the theoretical ratio of tidal attenuation to tidal lag, was enhanced not only with increase of the dimensionless specific leakage (aquitard/aquifer hydraulic conductance ratio) but also with decrease of the aquifer/aquitard storativity ratio and with the increase of the dimensionless tidal frequency. The solution with the aquitard storage was more sensitive to these three parameters. The newly developed solutions were capable of handling realistic initial conditions that might be approximated by piecewise linear functions. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献