Current continental palaeoclimatic research in the Nordic region (100 years since Gunnar Andersson 1909) – Introduction     

HEIKKI SEPPÄ  H. JOHN B. BIRKS  ANNE E. BJUNE  ATLE NESJE 《Boreas: An International Journal of Quaternary Research》2010,39(4):649-654

Seppä, H., Birks, H. J. B., Bjune, A. E. & Nesje, A. 2010: Current continental palaeoclimatic research in the Nordic region (100 years since Gunnar Andersson 1909) – Introduction. Boreas, Vol. 39, pp. 649‐654. 10.1111/j.1502‐3885.2010.00170.x. ISSN 0300‐9483.  相似文献   

Late‐Quaternary palaeoclimatic research in Fennoscandia – A historical review     

H. JOHN B. BIRKS  HEIKKI SEPPÄ 《Boreas: An International Journal of Quaternary Research》2010,39(4):655-673

Birks, H. J. B. & Seppä, H. 2010: Late‐Quaternary palaeoclimatic research in Fennoscandia – A historical review. Boreas, Vol. 39, pp. 655–673. 10.1111/j.1502‐3885.2010.00160.x. ISSN 0300‐9483. Ideas and understanding of Late‐Quaternary climatic history, especially in the Lateglacial and the postglacial, were initiated in Fennoscandia in the 19th century with pioneering studies on peat stratigraphy, megafossils and macrofossils. This review traces the history of palaeoclimatic research and the development of current ideas about climatic changes, with particular reference to the Lateglacial and its rapid climatic fluctuations, such as the Younger Dryas period, and to the Holocene, with its thermal maximum and shifts in precipitation.  相似文献   

A multi-proxy palaeoecological study of Alanen Laanijärvi, a boreal-forest lake in Swedish Lapland     

MARKUS L. HEINRICHS  SYLVIA M. PEGLAR  CHRISTIAN BIGLER  H. JOHN B. BIRKS 《Boreas: An International Journal of Quaternary Research》2005,34(2):192-206

Heinrichs, M. L., Peglar, S. M., Bigler, C. & Birks, H. J. B. 2005 (May): A multi-proxy palaeoecological study of Alanen Laanijärvi, a boreal-forest lake in Swedish Lapland. Boreas , Vol. 34, pp. 192–206. Oslo. ISSN 0300–9483.
Chironomids, pollen and spores were used to reconstruct Holocene aquatic and terrestrial environments at Alanen Laanijärvi, northern Sweden. Chironomid analysis revealed a pattern of limnological evolution from oligotrophic conditions in a relatively deep lake during 8.6 to 5.5 cal. kaBP, followed by a period of lake shallowing from 5.5 to 2.7 cal. ka BP. Increases in acidity and littoral habitat complexity may have occurred from 2.7cal. kaBP to the present, though some compositional changes may have resulted from human disturbance. Chironomid-inferred mean July air temperatures range between 9.8C in the Early Holocene to 11.3C in the Late Holocene. Limitations on chironomid-based quantitative temperature interpretations may exist because of low taxon richness. Diatoms were recovered from the upper sediments only, from about AD 1800. Pollen and spore analysis revealed an early colonizing vegetation of juniper, sedges and birch soon after local deglaciation, followed by birch forests until about 8.3 cal. kaBP. Alder stands occurred locally to 5.5 cal. kaBP, when pine and spruce forests developed and remain to the present day. These results suggest that little major terrestrial vegetation change may occur in some northern environments with predicted future global warming, where it is predicted to be most severe. Aquatic environments may, however, be greatly affected by a shift in precipitation regime, causing changes in allochthonous organic input, lake depth and possibly the amount of human activity or disturbance in the watershed.  相似文献   

Developing a modern pollen–climate calibration data set for Norway     

ANNE E. BJUNE  H. JOHN B. BIRKS  SYLVIA M. PEGLAR  ARVID ODLAND 《Boreas: An International Journal of Quaternary Research》2010,39(4):674-688

Bjune, A. E., Birks, H. J. B., Peglar, S. M. & Odland, A. 2010: Developing a modern pollen–climate calibration data set for Norway. Boreas, Vol. 39, pp. 674–688. 10.1111/j.1502‐3885.2010.00158.x. ISSN 0300‐9483. Modern pollen–climate data sets consisting of modern pollen assemblages and modern climate data (mean July temperature and mean annual precipitation) have been developed for Norway based on 191 lakes and 321 lakes. The original 191‐lake data set was designed to optimize the distribution of the lakes sampled along the mean July temperature gradient, thereby fulfilling one of the most critical assumptions of weighted‐averaging regression and calibration and its relative, weighted‐averaging partial least‐squares regression. A further 130 surface samples of comparable taphonomy, taxonomic detail and analyst became available as a result of other projects. These 130 samples, all from new lakes, were added to the 191‐lake data set to create the 321‐lake data set. The collection and construction of these data sets are outlined. Numerical analyses involving generalized linear modelling, constrained ordination techniques, weighted‐averaging partial least‐squares regression, and two different cross‐validation procedures are used to asses the effects of increasing the size of the calibration data set from 191 to 321 lakes. The two data sets are used to reconstruct mean July temperature and mean annual precipitation for a Holocene site in northwest Norway and a Lateglacial site in west‐central Norway. Overall, little is to be gained by increasing the modern data set beyond about 200 lakes in terms of modern model performance statistics, but the down‐core reconstructions show less between‐sample variability and are thus potentially more plausible and realistic when based on the 321‐lake data set.  相似文献   

Lateglacial and early Holocene vegetation and climate gradients in the Nordfjord–Ålesund area,western Norway     

HILARY H. BIRKS  MARIEKE VAN DINTER 《Boreas: An International Journal of Quaternary Research》2010,39(4):783-798

Birks, H. H. & van Dinter, M. 2010: Lateglacial and early Holocene vegetation and climate gradients in the Nordfjord–Ålesund area, western Norway. Boreas, Vol. 39, pp. 783–798. 10.1111/j.1502‐3885.2010.00161.x. ISSN 0300‐9483. Modern climate in western Norway shows a strong west–east gradient in oceanicity–continentality (coast to inner fjord) and altitudinal temperature gradients that control the regional and altitudinal zonation of vegetation. To discover if similar gradients existed during the Lateglacial and early Holocene, plant‐macrofossil analyses were made from five lacustrine sediment sequences in the Nordfjord–Ålesund region selected to sample the present climatic gradients. The macrofossil assemblages could be interpreted as analogues of the present vegetation, thus allowing reconstruction of past vegetation and climates. When the five sites were compared, climatic gradients could be detected. During the Lateglacial interstadial, mid‐alpine assemblages with Salix herbacea and S. polaris occurred at the lowland coast and upland inland sites, whereas the inland lowland site had low‐alpine dwarf‐shrub heath dominated by Betula nana, demonstrating a strong west–east gradient in temperature and precipitation and an altitudinal gradient inland. During the Younger Dryas stadial, assemblages at the lowland coast and upland inland sites resembled high‐alpine vegetation, whereas the inland lowland site was warmer with mid‐alpine vegetation, demonstrating west–east and altitudinal temperature gradients. Gradients became less pronounced in the Holocene. The early abundance of Betula nana in the inner fjord sites but its rarity at the coast is striking and reflects the oceanicity gradient. All sites became forested with Betula pubescens a few centuries into the Holocene. This forest was probably close to tree line at 370 m a.s.l. at the coast. Inland, there was no detectable altitudinal gradient, with the tree line well above 400 m a.s.l. reflecting the present pattern of tree‐line elevation.  相似文献   

Early Weichselian (MIS 5d and 5c) temperatures and environmental changes in northern Fennoscandia as recorded by chironomids and macroremains at Sokli,northeast Finland     

STEFAN ENGELS  KARIN F. HELMENS  MINNA VÄLIRANTA  STEPHEN J. BROOKS  H. JOHN B. BIRKS 《Boreas: An International Journal of Quaternary Research》2010,39(4):689-704

Engels, S., Helmens, K. F., Väliranta, M., Brooks, S. J. & Birks, H. J. B. 2010: Early Weichselian (MIS 5d and 5c) temperatures and environmental changes in northern Fennoscandia as recorded by chironomids and macroremains at Sokli, northeast Finland. Boreas, Vol. 39, pp. 689–704. 10.1111/j.1502‐3885.2010.00163.x. ISSN 0300‐9483. A 25‐m‐long sediment record spanning the time from the Eemian to the Holocene was recovered from Sokli, northeast Finland. This study focuses on a 6‐m‐long sediment interval that is dated to the Early Weichselian period (MIS 5d and 5c) and consists of lacustrine and fluvial deposits. Using chironomid remains, botanical and zoological macroremains as well as sediment lithology, we were able to reconstruct past changes in the environment, including climate. The results indicate that the site was situated on a flood‐plain during the latter stages of MIS 5d (Herning Stadial) and that summer temperatures might have been ～6 °C lower than at present. Although this value should be treated with caution, as numerical analysis shows that it has a very poor fit‐to‐temperature, this low reconstructed value concurs with several other reconstructions that are available from western Europe. During MIS 5c (Brørup interstadial), the depositional environment changed into a lake system, initially with stratification of the water and subsequently with complete mixing and a strong influence of streams. Both chironomid‐based and macroremain‐based temperature inferences indicate past July air temperatures that were significantly higher than at present. This result is in contrast to other (low‐resolution) reconstructions from northern Fennoscandia that indicate past temperatures 6–7 °C lower than present using fossil coleopteran assemblages. However, several central European sites indicate that there was a phase during the Brørup interstadial that was characterized by high summer temperatures, and a comparison between the high‐resolution reconstructions from western Europe and the results presented in this study suggests that the north–south July air temperature gradient between the mid‐ and high‐latitudes was much weaker during the Brørup interstadial than it is at present. High solar insolation values (particularly the obliquity) during the Brørup interstadial might explain the low summer temperature gradient over the European continent. A return to fluvial conditions occurred in the upper parts of the sediment sequence, and, after a brief interval of gyttja deposition under cooling conditions, the site became glaciated during MIS 5b.  相似文献   

地下水硝酸盐污染源解析及氮同位素分馏效应研究进展     

于璐  郑天元  郑西来 《现代地质》2022,36(2):563-573

地下水硝酸盐污染已成为世界范围内最严重的环境地质问题之一。全面并准确识别硝酸盐污染源,对地下水的有效管理及污染防治具有重要的指导意义。从地下水硝酸盐来源、同位素检测方法、污染源同位素特征、定量解析模型构建、硝酸盐主要转化过程及同位素分馏效应等方面进行总结,比较不同解析方法在硝酸盐溯源中的应用与发展,建议采用多学科、多方法相结合的方式,提高对硝酸盐污染源的全面理解。同位素富集系数是定量解析硝酸盐污染源的重要参数,在源解析过程中探讨硝酸盐转化及同位素分馏机制,能够更好地诠释地下水硝酸盐来源和迁移转化过程,提高源解析的准确性,为地下水硝酸盐污染的准确溯源与有效防治提供参考。  相似文献   

高氯酸盐自然衰减的柱实验研究     

梁凯旋  刘菲  张莉 《地学前缘》2022,29(3):207-216

高氯酸盐( {\mathrm{ClO}}_4^{-})是一种小分子量、有毒的无机络阴离子,普遍存在于环境中。由于其分子大小与碘离子相似,会干扰人体甲状腺的正常功能,因此其环境污染问题引起了广泛的关注。本文选取污染场地的天然河沙为试验材料,主要通过柱实验对地下水中 {\mathrm{ClO}}_4^{-}自然衰减过程进行研究,考察了铁氧化物、 {\mathrm{NO}}_3^{-}对 {\mathrm{ClO}}_4^{-}自然衰减过程产生的影响。结果表明,高氯酸盐自然衰减过程主要由微生物驱动,天然河沙可去除2 mg/L的 {\mathrm{ClO}}_4^{-},但其过程缓慢且还原量有限,长期去除率不超过10%,其限制因素为缺乏电子供体;铁氧化物可以促进 {\mathrm{ClO}}_4^{-}自然衰减,但当溶解性铁的浓度低于5.5 mg/L时,衰减过程开始受到影响;地下水中的 {\mathrm{NO}}_3^{-}会抑制 {\mathrm{ClO}}_4^{-}的降解,当 {\mathrm{NO}}_3^{-}低至10 mg/L或以下时, {\mathrm{ClO}}_4^{-}才开始明显降解。  相似文献   

压力对淤泥中C-N-S-Fe-H2O体系的影响     

彭子琪  马腾  刘妍君  陈娟  邱文凯  刘锐 《地学前缘》2021,28(5):79-89

C、N、S、Fe是地下水中控制氧化-还原反应的主要元素,淤泥是黏土的演化初期,淤泥演化为黏土过程中会影响含水层水量水质,可能会造成地下水污染;其中的水岩相互作用可以概化为C-N-S-Fe-H₂O体系的相互作用。淤泥演化过程的实质是淤泥在压力的作用下孔隙度不断变小,逐渐固结成岩;淤泥内部不断发生生物地球化学反应,C-N-S-Fe-H₂O体系驱动各种物质的形态结构不断发生改变,其中加压速率和加压模式会影响淤泥里的C、N、S、Fe重要组分固液相的转化。本研究运用自主研发设计的增压装置,探究在3种加压速率(0.04 MPa/12 h、0.04 MPa/24 h、0.04 MPa/36 h)和加压模式(0.040.02 MPa/12 h、0.04 MPa/12 h、0.040.06 MPa/12 h)的情况下,固体介质中C、N、S、Fe向孔隙水释放的规律。结果表明:(1)匀速加压速率越慢,加压初期溶解性有机碳(DOC)、 {\mathrm{SO}}_4^{2-}释放速率越快, {\mathrm{NO}}_3^{-}和Fe²⁺浓度变化增大;DOC、 {\mathrm{SO}}_4^{2-}、 {\mathrm{NO}}_3^{-}、Fe²⁺释放总量越多。(2)不同的加压模式,加速加压(0.040.06 MPa/12 h)下 {\mathrm{NO}}_3^{-}、Fe²⁺的浓度波动较大;DOC、 {\mathrm{NO}}_3^{-}、 {\mathrm{SO}}_4^{2-}和Fe²⁺的总释放量为加速加压(0.040.06 MPa/12 h)大于匀速加压(0.04 MPa/12 h)。(3)加压过程中,DOC和 {\mathrm{SO}}_4^{2-}呈显著正相关,改变加压速率会改变DOC, {\mathrm{NO}}_3^{-}、 {\mathrm{SO}}_4^{2-}和Fe²⁺的相关性。本研究表明改变加压速率和加压模式会对DOC、 {\mathrm{NO}}_3^{-}、 {\mathrm{SO}}_4^{2-}和Fe²⁺的释放速率、释放总量和C、N、S、Fe的转化造成影响,其本质为氧化-还原反应和水岩相互作用的强弱发生了变化;本研究为地质演化过程中压力导致的主要元素变化提供了新的认识,认识到了隔水层会影响含水层的水质和水量,为原生劣质地下水的成因和地下水污染防治提供了新思路。  相似文献   

Review of the Study on the Stable Isotopes of Nitrogen and Oxygen in Atmospheric Nitrate     

Rui Qin  Guitao Shi  Zhenlou Chen 《地球科学进展》2019,34(2):124-139

Due to the emissions from intensive human activities and rapid development of industry and agriculture, atmospheric nitrate (NO {}_3^{-} ) contamination is becoming more serious and now is a worldwide environmental problem. The isotopic compositions of NO {}_3^{-} (δ¹⁵N, δ¹⁸O and Δ¹⁷O) can deliver more information than the concentration alone, i.e., the nitrogen and oxygen isotopes can suggest the sources of NO {}_3^{-} and oxidation capability of the atmosphere, providing a powerful tool for investigating atmospheric nitrogen cycling and atmospheric NO {}_3^{-} pollution control. The δ¹⁵N of different sourced NO {}_3^{-} in the atmosphere, as well as the seasonal variation of δ¹⁵N (NO {}_3^{-} ) and the associated mechanisms were reviewed. In addition, the oxygen isotopes of various oxidants and NO {}_3^{-} (δ¹⁸O and Δ¹⁷O) in the atmosphere were summarized, and the global distribution patterns of the oxygen isotopes of NO {}_3^{-} were discussed. Lastly, the available analysis techniques of isotopic compositions of NO {}_3^{-} were reviewed. Based on the research progress of NO {}_3^{-} isotopes in the atmosphere, it was suggested that further investigations should focus on measuring the isotopic compositions of oxidants and NOx from different sources, characterizing the production mechanisms of NO {}_3^{-} , as well as investigating chemical recycling between NOx and NO {}_3^{-} with the aid of atmospheric chemical models.  相似文献   

火山渣吸附地下水中大肠杆菌噬菌体特性研究     

张玉玲  尹斯琦  司超群  王茜  初文磊 《地学前缘》2021,28(5):167-174

为了分析火山渣吸附去除地下水中大肠杆菌噬菌体作用特性,通过室内实验,考察火山渣吸附地下水中vB_EcoM-ep3大肠杆菌噬菌体效果,同时用等量沸石与石英砂做对照,进一步分析地下水中水化学因素(Fe²⁺、Fe³⁺、Mn²⁺、 {\mathrm{SO}}_4^{2-}、 {\mathrm{NH}}_4^{+}、 {\mathrm{NO}}_3^{-}、 {\mathrm{NO}}_2^{-}、Ca²⁺、Mg²⁺、 {\mathrm{CO}}_3^{2-}、 {\mathrm{HCO}}_3^{-}和pH值)对其吸附效果影响;通过微观检测技术,分析大肠杆菌噬菌体生物学特性和火山渣吸附前后微观结构变化。研究结果表明:火山渣吸附效率优于沸石和石英砂,最大饱和吸附量达到2.245×10⁵ pfu/g;水化学因素对火山渣吸附效果影响存在差异性,其中Fe²⁺、Fe³⁺起到促进作用, {\mathrm{SO}}_4^{2-}、三氮和碱度起到抑制作用,低浓度Mn²⁺( C_{\mathrm{M}{\mathrm{n}}^{2+}}<10 mg/L)和Ca²⁺( C_{\mathrm{C}{\mathrm{a}}^{2+}}<100 mg/L)起到轻微促进作用,超过该浓度则表现为抑制作用;pH值对火山渣吸附效果影响较大,pH值越大,吸附效果越差。vB_EcoM-ep3大肠杆菌噬菌体头部为等边六角形,全身直径约为(53±2) nm,尾部长约为(107±3) nm,由尾管和尾丝组成,可伸缩。具有蜂窝状结构的火山渣吸附大肠杆菌噬菌体后表面孔隙大部分被填充。  相似文献   

天津平原区加油站地下水石油烃污染特征及其生物降解机理研究     

刘学娜  李海明  李梦娣  章卫华  肖瀚 《地学前缘》2022,29(3):227-238

加油站地下水中石油烃污染是较为普遍的现象,本文对研究区位于不同水文地质条件的加油站地下水进行取样分析,分析加油站地下水中石油烃的污染特征和地下水化学类型特征,并运用因子分析、相关性分析和多元回归分析揭示加油站地下水中石油烃潜在的生物降解机制。研究结果表明,地下水化学类型主要可划分为Cl-Na型、HCO₃-Na型、HCO₃-Ca型和SO₄-Na型4类。加油站地下水中石油烃的检出率为85.71%,检出浓度为0.020.35 mg/L。因子分析结果表明影响地下水化学组成的因素主要以水-岩相互作用和石油烃的生物降解为主。TPH与地下水化学指标间的相关关系表明:TPH与K⁺、Na⁺、Cl^-、Mn、Mg²⁺、 {\mathrm{SO}}_4^{2-}呈现负相关的关系,与pH值、 {\mathrm{HCO}}_3^{-}、 {\mathrm{NO}}_3^{-}、 {\mathrm{NO}}_2^{-}、Ca²⁺、Fe不存在显著的相关关系。加油站地下水环境中可能存在嗜盐或耐盐微生物,导致随着盐度的升高,总石油烃(total petroleum hydrocarbon,TPH)生物降解率加快,TPH浓度呈现出降低的趋势。微生物利用电子受体( {\mathrm{SO}}_4^{2-}、Mn、 {\mathrm{NO}}_3^{-}、Fe)降解TPH的过程中,电子受体的贡献率为:铁还原(64.88%)>锰还原(24.86%)>硫酸根还原(5.78%)>硝酸盐还原(4.46%),即加油站地下水中铁锰还原菌的石油烃生物降解为优势反应。  相似文献   

江汉盆地潜江凹陷地下卤水地球化学特征和分布规律     

牛新生  黄华  郑绵平 《地学前缘》2021,28(6):56-65

江汉盆地潜江凹陷潜江组赋存有丰富的地下卤水,因其有较高的经济价值,是江汉盆地油气资源之外的又一种重要的战略资源。然而,长期的油田注水开采也对地下卤水产生了一定的影响,为进一步评估这种影响并探讨地下卤水微量元素的分布情况,通过采集和分析潜江组第一至第四卤水组的地下卤水样品开展其地球化学特征和分布规律的研究。结果表明,潜江凹陷潜江组地下卤水受油田生产影响,虽然普遍发生了淡化,但仍然拥有较高的TDS含量,淡化影响有限。卤水储层从上至下,第一卤水组至第四卤水组,随着深度的增加,硫酸钠亚型卤水和碳酸盐型水逐渐变少,氯化物型水逐渐增多。尽管区内地下卤水普遍经受油田注水生产的影响,但是卤水中Li、B、Br等元素依然保持较高的含量,大部分样品达到或超过边界工业品位,尤其以第二、第三卤水Li、B、Br品位较高,第四卤水组次之,第一卤水组最低。潜江凹陷地下卤水样品的钠氯系数接近于1,具备溶滤卤水特征,属于非海相地层的卤水,氯溴系数分析揭示区内现存地下卤水是溶滤卤水和沉积卤水混合以后的结果,卤水的脱硫系数和钙镁系数反映卤水的储集空间封闭性相对较差,凹陷内从第一至第三下卤水储集体的空间的封闭性逐渐变好,第四卤水组略变差。平面上,Li、B、Br具有相似的分布特征,凹陷内,卤水的浓集中心从下至上具有明显的迁移特征,钟市、浩子口、王场、周矶所围限的区域是高浓度卤水分布中心地带,其分布明显受控于卤水储集体的分布。  相似文献   

古物源体系多方法表征     

杨棵  朱筱敏  杨怀宇  朱世发  董艳蕾  金磊  申婷婷  叶蕾 《沉积学报》2022,40(6):1542-1560

古物源体系是深时“源—汇”系统研究的重要环节。随着沉积学理论和技术的发展,物源示踪的表征方法已从单一迈向综合、由定性走向定量,这将有助于更全面地揭示母岩发育特征、物源区构造背景、沉积物路径系统等,进而建立更可靠的古物源体系发育模式。碎屑锆石U-Pb定年等多方法物源体系表征研究表明,沾化凹陷渤南洼陷沙四下亚段（Es4x）砂岩样品主要发育岩浆成因的锆石,这些锆石颗粒自形程度较好,具有清晰的岩浆环带,其Th/U>0.4,稀土元素普遍具有“Ce正异常、Eu负异常”特征。微量/稀土元素地球化学指标和砂岩岩石学特征揭示了研究区沙四下亚段陆源碎屑具有岩浆岛弧/活动大陆边缘酸性花岗质源岩的属性。母岩的发育与华北克拉通在新太古代—古元古代及晚古生代—中生代的地球动力学背景密切相关。综合优势年龄贡献、母岩属性、岩石学特征、地球动力学背景,最终建立了渤南洼陷沙四下亚段古物源体系发育模式,即渤南洼陷沙四下亚段同时发育“近源堆积”和“远源供给”两类路径系统,发育东侧中生界岩浆岩主导型物源系、南侧新太古界/古元古界/上古生界/中生界母岩联合控制型物源系、中部混合物源系。其中,东侧物源系和中部物源系的关联性较大,应属于同一沉积物路径系统,南侧物源系相对独立。  相似文献   

塔里木盆地北部上震旦统葡萄状白云岩的发现及成因探讨^*          下载免费PDF全文

钱一雄  何治亮  李慧莉  陈跃  金婷  沙旭光  李洪全 《古地理学报》2017,19(2):197-210

“皮壳—葡萄状”白云岩是一种非常特殊结构的白云岩。文中报道了塔里木盆地西北缘东二沟及塔北星火101井上震旦统奇格布拉克组中皮壳—葡萄状白云岩特征,并对其成因进行了探讨。皮壳状—葡萄状白云石中发育明、暗纤状白云石或纹层条带的含少量细晶的纤状—细粒状白云石以及肾状和葡萄状粉细晶白云石;由球形、杆形、孢子形等蓝细菌构成泡沫状结构;明暗、环带状橙红色光或中等橙红色光、核部发光较暗或不发光;与基质白云石相比,葡萄—皮壳状白云石δ13CPDB相似;但δ18OPDB正偏, ⁸⁷Sr/⁸⁶Sr 相对高(0.70887~0.70939)、但与震旦纪海水(0.7087~0.7094)相似,从皮壳边缘、暗色(蓝细菌)至核部,微区δ18OPDB、δ13CPDB显示了环带内变化较小、环带外的强烈负漂移;云化程度的增加,δ18OPDB、δ13CPDB负偏明显, ⁸⁷Sr/⁸⁶Sr 增加。皮壳—葡萄状白云岩中Al₂O₃ 、Fe₂O₃ 、MnO、LREE/HREE值均低于基质泥粉晶云岩对应值、稀土总量介于基质与粉细晶云岩之间,而Na₂O+K₂O、P₂O₅、 Sr、Hg、Cu、Sr/Ba、Sr/Mn、δCe值均高于基质泥粉晶云岩对应值;且随着云化程度的提高,总体呈现出Mn含量增加,Al₂O₃ 、Fe₂O₃ 、Na₂O+K₂O、P₂O₅、Sr/Ba、Fe/Mn等值递减的趋势;由此判断皮壳状—葡萄状白云石可能是弱还原、保存较好的海水中形成,或在成岩早期或浅埋藏孔隙海水为主的流体中形成、部分经历了较强的大气水作用改造。  相似文献   

贵州草海近21 ka以来有机地球化学记录反映的古环境变化^*          下载免费PDF全文

龚晓飞  陈聪  汤永杰  黄康有  乐远福  梁凯璇  郑卓 《古地理学报》2019,21(6):1025-1034

草海位于黔滇交界,主要受印度夏季风的影响,其湖沼沉积物记录了中—晚第四纪的环境变化历史,是研究第四纪环境和季风演变的良好载体。本研究选取的南屯NT03钻孔,岩心长405 cm,在放射性碳同位素(AMS¹⁴C)测年基础上建立了年代序列,并进行了沉积物的色差值(L^*)、烧失量(LOI550)、总有机碳(TOC)、碳氮比(C/N)和有机稳定碳同位素(δ13Corg)等古环境替代指标的测试。实验结果显示,L^*、LOI550和TOC等3个有机碳含量指标同步变化,共同指示该钻孔序列经历了3个沉积环境演变阶段,即末次盛冰期晚期(21—15 cal ka BP)河流—冲积相沉积阶段、冰消期至早中全新世(15—4 cal ka BP)高湖面湖泊—沼泽相沉积阶段和晚全新世(4 cal ka BP以来)洪冲积相沉积阶段。近2万年以来草海湖沼面积经历的收缩→扩张→收缩演变过程与石笋氧同位素变化基本吻合,表明季风降雨是引起草海湖泊水体和周边生态系统变化的主要因素。δ13Corg指标变化范围为-29.28‰~-24.19‰,表明草海盆地周围植被组成在末次盛冰期以来C4草本虽然略有增加,但均以C3植物为主。同时,TOC和δ13Corg指标证明了B/A冰消期暖事件对盆地边缘区的湿地泥炭富集起到关键作用,而多指标揭示了近4 ka以来水域变浅并发展成为冲积环境的过程,也可能与石笋记录的夏季风减弱所带来的降水量减少有关。  相似文献   

鄂尔多斯盆地陇东地区长8致密砂岩油藏地层水化学特征成因及其油气指示意义     

斯扬  张文选  罗安湘  孙勃  朱玉双 《现代地质》2019,33(5):1106-1117

国内对地层水与油藏的关系研究多集中在断块坳陷内,在岩性油藏中此类研究相对较少。基于鄂尔多斯盆地陇东地区长8致密砂岩油藏大量的地层水化学分析及薄片和扫描电镜资料,对长8地层水化学特征及其成因进行了分析,并结合油藏地质条件,探讨其油气指示意义。长8致密砂岩岩性油藏地层水矿化度平均为33.6 g/L,地层水类型以Ca Cl2型为主,整体为封闭的水文地质环境,有利于油气保存。长8地层水中的离子特征与砂岩成岩具有良好的对应关系。Mg2+亏损、Na+轻微亏损及富集主要与绿泥石化、斜长石的钠长石化及溶解作用有关;Ca2+富集不仅与斜长石的钠长石化及溶解作用有关,还与泥岩中火山灰大量释放的Ca2+有关;SO42-与HCO3-含量则主要受脱硫酸作用和碳酸盐胶结作用控制。此外,由于长8砂岩成岩作用受烃类充注影响较大,研究区西部与中部及东部地层水化学特征存在差异,西部地层水中的钠氯系数整体小于中部及东部,SO42-平均含量及脱硫系数平均值大于中部和东部等特征都与长8油藏在平面上充注条件差异有着很大联系。  相似文献   

不同因素对砂岩含水层介质吸附铀的影响     

惠淑君  杨冰  郭华明  连国玺  孙娟 《地学前缘》2021,28(5):68-78

铀矿开采过程中及井场退役后,含铀浸出液的扩散会对地下水造成一定影响,该影响范围和程度决定了铀的天然衰减特征。本文以北方某地浸铀矿区砂岩含水介质为研究对象,研究了溶液化学特征和黄铁矿含量对砂岩吸附和转化铀的影响。结果表明,砂岩颗粒对U(VI)的吸附基本在12 h可达平衡。线性等温吸附模型可以很好地描述吸附特征;砂岩颗粒对U(VI)的吸附率总体随着粒径增大而减小,当岩石粒径增大到0.200.25 mm时,吸附率趋于稳定。溶液pH值是影响吸附的主要因素,通过控制溶液中U(VI)的络合形态和岩石颗粒表面带电荷情况,在库仑力的作用下促进或者抑制吸附,在pH=6时,达到最佳吸附状态。共存离子对U(VI)吸附的抑制程度是: {\mathrm{HCO}}_3^{-}>Ca²⁺>Mg²⁺> {\mathrm{SO}}_4^{2-}。 {\mathrm{HCO}}_3^{-}主要通过与 {\mathrm{UO}}_2^{2+}络合形成带负电荷的络合阴离子抑制U(VI)吸附。近中性pH值试验条件下,黄铁矿含量的增加对U的去除起到显著的促进作用,这种促进作用体现在吸附和还原作用,被吸附的Fe²⁺在吸附剂表面通过电子转移还原吸附态的U(VI),还原产物是UO_2+x,吸附和还原是个相互促进的过程;在弱碱性pH值试验条件下,黄铁矿对U(VI)去除的影响不明显,水解沉淀作用和较低的吸附率抑制了还原反应的发生。  相似文献   

鄂尔多斯盆地奥陶系马五₅亚段沉积微相与古地理演化     

苏中堂  佘伟  罗静兰  马国伟  张帅 《沉积学报》2021,39(6):1344-1356

碳酸盐岩微相分析有利于认识沉积相展布特征和古地理演化规律,对油气勘探具有指导意义。通过大量薄片、岩心资料在鄂尔多斯盆地奥陶系马五₅亚段划分出MFT1—MFT7七种沉积微相类型及MA1—MA4四种沉积微相序列,沉积微相与生物遗迹化石指示马五₅亚段为潮坪环境。结合沉积前古地形及古海平面变化信息,以单因素图件为基础,采用优势相法编制马五52层（Ⅰ）、马五51层（Ⅱ）岩相古地理图,沉积环境受沉积前古地形控制而分异:潮上带、潮间上带、潮间下带及潮下带自西向东依次分布,盆地东部高地形处发育潮间带沉积;随古海平面下降,马五51期沉积相带向东迁移,东部潮间带连片分布。  相似文献   

砂岩含水介质中铀的吸附和迁移行为研究     

崔迪  杨冰  郭华明  连国玺  孙娟 《地学前缘》2022,29(3):217-226

地浸铀矿山退役后,含水层中残留的含铀浸出液随着地下水的运动向下游迁移扩散,存在对周边地下水污染的风险。本文设计了若干组批实验和柱实验,研究铀在北方某地浸铀矿山砂岩含水介质中的吸附和迁移行为。实验结果表明,砂岩对铀的吸附在12 h以内达到平衡,铀初始浓度越高,砂岩的铀吸附容量越大;砂岩对铀的吸附为吸热反应,温度升高有利于吸附反应的进行。溶液pH值和共存 {\mathrm{HCO}}_3^{-}浓度会对铀的吸附作用产生强烈的影响:pH值在7左右时,铀的吸附量最高; {\mathrm{HCO}}_3^{-}浓度越高,铀的吸附量越低。这些影响是通过改变溶液中铀的络合形态和砂岩矿物表面的电荷性质实现的。柱实验表明,pH值、铀浓度、流速和 {\mathrm{HCO}}_3^{-}浓度是影响铀在饱和砂岩含水介质中迁移的重要因素。pH值≤7时,pH值越高,砂岩柱越不易被铀穿透;而铀浓度、流速、 {\mathrm{HCO}}_3^{-}浓度越高,砂岩柱越易被铀穿透。两点非平衡模型可以很好地拟合不同条件下铀在砂岩柱中的迁移过程。批实验获得的分配系数是柱实验的1.16.6倍。通过对比实验条件、含水层特性和地下水化学特征,确定分配系数为48.1 mL/g时,较适合描述研究区内砂岩含水层中的铀迁移。上述认识为地浸铀矿山地下水铀的反应运移过程和天然自净化机理提供了理论依据。  相似文献