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1.
Trace metals in seawater and copepods in the ocean outfall area off the northern Taiwan coast 总被引：3，自引：0，他引：3
The distribution, partitioning and concentrations of trace metals (Cd, Cr, Cu, Fe, Mn, Pb and Zn) in seawater, including dissolved and particulate phases, and in copepods in the ocean outfall area off the northern coast of Taiwan were investigated. Normalization of metal concentrations to the background metal concentration to yield relative enrichment factors (EF), which were used to evaluate the contamination of dissolved and particulate trace metals in seawater around the ocean outfall. The EF results indicated that the outfall area was significantly contaminated by dissolved Fe and Zn, and by particulate Fe, Cr, Cu, Pb and Zn. In addition, most trace metals were chiefly in the particulate phase. The average percentage of total metal concentrations (dissolved plus particulate phases) bound by suspended particulate matter followed the sequence Al(95%) = Mn(95%) > Pb(88%) > Cu(86%) > Fe(72%) > Zn(32%) > Cr(17.5%) > Cd(3.4%). Therefore, metal contamination is better evaluated in solid phase than in the dissolved phase. The concentration ranges of trace metals in the copepods, Temora turbinata, Oncaea venusta and Euchaeta rimana, near the outfall were: Cd, 0.23-1.81 microg g(-1); Cr, 16.5-195 microg g(-1); Cu, 14-160 microg g(-1); Fe, 256-7255 microg g(-1); Mn, 5.5-80.8 microg g(-1); Pb, 2.6-56.2 microg g(-1); Zn, 132-3891 microg g(-1); and Al, 0.21-1.13%. Aluminum, and probably Fe, seemed to be the major elements in copepods. The concentrations of trace metals in copepods, especially Temora turbinata, near the outfall were generally higher than those obtained in the background station. The mean increase in bioconcentration factor of metals in copepods ranged from 4 to 7 and followed the sequence Al(6.4) > Cu(6.2) > Fe(6.0) > Zn(5.7) > Pb(5.6) > Cr(5.5) > Cd(5.1) > Mn(4.7). Therefore, marine copepods in the waters of northern Taiwan can accumulate trace metals over background concentrations and act as contamination indicators. 相似文献
2.
《Marine Chemistry》2001,73(2):153-171
Particles from the Whites Point/JWPCP outfalls operated by the Los Angeles County Sanitation District (LACSD) have been discharged onto the Palos Verdes (PV) shelf, Southern California, since the late 1930s. Since the early 1950s, they have made a significant contribution to the sedimentary deposits on the shelf. In order to study the transport and diagenesis of organic carbon (OC) and associated trace metals, replicate sediment cores were collected during 1996 and 1997 at four different sites at the ∼60 m isobath on the PV shelf, and analyzed for OC, Ag, Al, Cd, Cr, Cu, Mn, Ni, Pb, and Zn. We conclude from these results that a significant fraction of OC and associated heavy metals were transported laterally on silt particles from shallower environments. Cross-shelf transport of sediments caused multiple peaks in measured profiles of OC and trace metals at site 6C, 2 km away from the outfall. The same mechanism is likely to contribute to a concentration decrease that is smaller than that expected from decreases from the Whites Point outfall emissions. Based on Pb/OC ratios in sediments, deposited in 1971, and comparisons to the outfall from the same year, we estimate that 50±10% of the OC deposited in the early 1970s, now buried at 30–50 cm depth, had oxidized since that time, implying a half-life of about 26 years for the outfall-OC, as an upper limit. The average OC oxidation rate at peak depth (about 2 mg C cm−2 year−1) is, however, only about 10% of the present-day OC accumulation rate (20 mg C cm−2 year−1), which itself is adding not much more than 1% per year to the post-1950s OC inventory (∼1500 mg cm−2). We furthermore estimate that the OC inventory in PV shelf sediments in 1971 was equivalent to about 35% of that emitted by the outfall. OC and trace metal inventories did not decrease in the period 1981 to 1997, contrary to those of other contaminants such as DDTs and PCBs. 相似文献
3.
Concentrations of selected heavy metals (Cr, Cu, Ni, Pb and Zn) from surface sediments, suspended particulate matter and settling particles in the southern Barcelona continental margin were studied in order to evaluate the environmental impact of the anthropogenic metals discharged by the Llobregat River in this Mediterranean area. The temporal variation of heavy metals discharged by this river onto the continental shelf is clearly related to the river water flow. Part of the fine sediment and associated heavy metals transported by the Llobregat River during periods of low river flow accumulate on the river bed, and they are totally removed and discharged onto the Barcelona continental shelf during sporadic river water flow increases. Metals produce significant anomalies of chromium (×2.5), copper (×3.4) and zinc (×3.7) in the surface sediments of the Llobregat prodelta and tend to be transported along the continental shelf following the mean flow. Metals associated with the finest suspended flocs transferred to the slope are controlled by the shelf-slope density front and are transported along slope by the general geostrophic current, instead of accumulating and becoming concentrated in the slope bottom sediments. Settling particulate matter collected in sediment traps on the Barcelona continental slope offshore of the shelf-slope front shows low heavy metal concentrations except in a few sediment trap samples that are significantly metal-enriched in chromium (×4.5) and zinc (×6.8). This enrichment is associated with very short and sporadic river flow increases and is only recorded inside the Foix submarine canyon, which acts as a preferential conduit for the shelf-slope sediment transfer. 相似文献
4.
2004年7~8月在台湾浅滩周边水域进行了两个断面的水体悬浮物浊度、叶绿素a荧光调查,通过对该区域夏季悬浮物质浊度、叶绿素a荧光的分布变化特征研究,结合水文相关要素分析,初步揭示了该区域海洋沉积和再悬浮过程对悬浮体浊度、叶绿素a荧光分布的影响.悬浮物质浊度在近岸与陆架外缘主要受再悬浮作用影响,而浅滩区再悬浮作用不明显;在陆架外缘区浮游植物的聚集作用对浊度有一定的贡献作用,而近岸区则不明显. 相似文献
5.
Anthropogenic organic contaminants in the effluent of a combined sewer overflow: impact on Boston Harbor 总被引：2，自引：0，他引：2
Effluent from a large combined sewer overflow (CSO) in Boston and receiving waters near the CSO outfall were sampled during dry and wet weather conditions. Surficial sediments were also collected from the vicinity of the CSO and at nearby sites. The samples were analyzed for a variety of organic constituents including organic carbon and nitrogen, linear alkylbenzenes (LABs), coprostanol and polychlorinated biphenyls (PCBs). As judged by the presence of waste-specific markers (LABs, coprostanol), the CSO effluent contains sewage under both dry and wet weather conditions. When rainfall occurs, the concentration of suspended solids and all organic constituents in the particulate phase increase, ultimately approaching those characteristic of untreated sewage. The concentrations of LABs and PCBs in the effluent are strongly correlated, indicating that PCBs in the CSO are derived from sewage inputs. During heavy rainfall, the vast majority (> 90%) of the hydrophobic organic substances are associated with suspended particulate matter, whereas during dry weather, a significant fraction resides in the operationally defined 'dissolved' phase. Estimates of the mass emission rates of CSO constituents show that > 70% of the suspended particles and > 90% of the particulate organic carbon, hydrocarbons and trace organics are discharged during wet weather. Particles in the receiving water appear to be strongly influenced by the CSO effluent during wet weather. Concentrations of PCBs in surficial sediments near the CSO are correlated with those of coprostanol and the LABs, indicating that these compounds are derived from similar sources. Based on the observed correlations, approximately 60-80% of the sedimentary PCBs originate from sewage. Comparison of sigma LAB/coprostanol ratios of effluent particles, surficial sediments and sewage sludges suggest that the vast majority of the marker compounds and the PCBs in sediments are not from the CSO, but are derived from one of two sewage treatment plants that discharged sludge into the harbor until 1991. The sludge-derived contaminants were probably carried by tidal currents into Dorchester Bay and deposited in shallow, quiescent embayments where sedimentation is favored. These results illustrate the potential importance of long-range transport of waste-derived contaminants in urban harbors and their rapid accumulation in localized depocenters. 相似文献
6.
Metal concentrations of Cu, Fe, Mn, Ni, Pb and Zn in an infaunal facultative deposit-feeding bivalve, the Baltic clam Macoma balthica, in the Gulf of Gdansk (southern Baltic Sea) were assessed and compared to selected concentrations of metals in the environment. Between October 1996 and September 1997, dissolved and easy extractable (by 1M HCl) metal fractions of total suspended particulate matter (TPM) in the overlying water and of surficial sediments (<63 microm) were measured monthly at five sublittoral sites in the Gulf of Gdansk, and accumulated tissue metal concentrations in M. balthica were determined simultaneously. The study highlights the importance of sediment geochemistry as a factor modifying ambient trace metal bioavailabilities. Surficial sediments appeared to contribute most to the accumulation of Cu and Pb in M. balthica, reflecting the high metal availability in the Gulf. Assimilation of Cu from sediments is controlled by Mn components possibly through an inhibitory effect of Mn oxyhydroxides, while Pb accumulation from sediments depends on the organic content of the sediment. A dual metal uptake pathway, with a suspended particulate-bound fraction and surficial sediments, was apparent for Mn and Zn. Partitioning of Mn in sediments was related to the concentration of labile Fe, with increased levels of Fe tending to inhibit the accumulation of Mn by the clam. Tissue accumulated Zn might have been altered by the clam's internal regulation, making Zn tissue concentrations, to some degree, independent of its environmental level. The principal source of Ni accumulated by the clams exists in the soluble phase. 相似文献
7.
2004年7～8月在台湾浅滩周边水域进行了两个断面的水体悬浮物浊度、叶绿素a荧光调查，通过对该区域悬浮物质浊度、叶绿素a荧光的夏季分布变化特征研究，结合水文相关要素分析，初步揭示了区域海洋沉积和再悬浮过程对悬浮体浊度、叶绿素a荧光分布的影响。指出悬浮物质浊度在近岸与陆架外缘主要受再悬浮作用影响，而浅滩区再悬浮作用不明显：在陆架外缘区浮游植物的聚集作用对浊度有一定的贡献作用，而近岸区则不明显。 相似文献
8.
罗纳河中悬浮物质的痕量元素的研究 总被引：5，自引：0，他引：5
于1989年5月－1990年4月间,在罗纳河下游近河口处进行每月一次为期间个月的样品采集工作,并且样品用HNO3－HF－HCIO4湿法消化后,用原子吸收分光光度法测定了悬浮颗粒物中的Co,Cr,Cu,Mn和Pb含量。结果表明,在不同月份之间悬浮物中的痕量元素组成具有显著地差别,其中一些元素的浓度随流量的增加而减少,而另外一些似乎与流量之间没有显著的关联。在稳定体系的假设下,所估计的人文活动对痕量元素的贡献可占观测浓度的10％－50％。当与其它河流对比时,发现罗纳河中的颗粒态痕量元素的浓度明显高于那些受人文活动影响较小的体系,而与北美的河流系统接近,表明罗纳河流域的人文活动对河流中颗粒态痕量元素的影响是显著的。 相似文献
9.
Sediment input to SMB appears to be associated with at least two point sources on the shelf, with Malibu Creek and the Hyperion sewage outfall being the most significant. Sediment contributions are sufficient to support apparent mass accumulation rates near these sources up to approximately 1.8 g/cm(2) year, which with distance decrease to approximately 0.5 g/cm(2) year near the shelf break (approximately 80-100 m water depth). Sequestering of material on the shelf and decreasing sediment supply to the slope is evident as rates decrease between 100 and 200 m water depths to less than 0.2 g/cm(2) year. Below 100-200 m water depth, rates are relatively slow throughout a broad region of the slope (0.07-0.14 g/cm(2) year). These slower rates are in general agreement with rates determined on the flanks of the California Borderland basins. Sediment texture fines from approximately 3.5 phi to approximately 7 phi with distance offshore. Texture does not exhibit significant changes from surficial values with depth in the seabed at any given site or between sites on the slope. This similarity in rates and downcore texture over such a broad extent suggests that hemiplegic sedimentation is the dominant mechanism of sediment delivery in water depths >200 m. Seabed distributions of radionuclides suggest that apparent accumulation rates in SMB may be twice the actual accumulation rates. A sediment budget documents that over the past century at least, SMB has served as a sink for 50-100% of the natural and anthropogenic inputs to the coastal ocean. 相似文献
10.
东海陆架晚第四纪沉积物化学成分及物源示踪 总被引：11，自引：0，他引：11
东海陆架EA1孔和EA5孔沉积物化学成分变化范围较大。与东海陆架表层沉积物相比，钻孔沉积物的Si,Al,Mg,Mn,Ti,P,Ba,Zr,Co,Ni,Cu,Zn,Cr明显偏高，而Fe,Na,Ca,Sr,Li,U明显偏低，与全球大陆地壳化学组成相比，钻孔沉积物的Si,Li,Rb,Ba,Th,Zr,Hf,Cu,Zn,Pb偏高，而Al,Na,Ca,Mg,Fe,Mn,Ti,P,Sr,U,Co,Ni,V,Cr偏低，钻孔沉积物的化学成分在垂向上具有明显变化，主要受岩性和沉积环境的控制，钻孔沉积物中元素的富集因子（EF）均小于10，接近于1，表明钻孔沉积物主要来自大陆地壳，一些元素因分异或外来物质加入而富集，一些元素则因分异带出而亏损，钻孔沉积物源区的DF值判别表明，钻孔沉积物与现代黄河，长江沉积物均有亲缘关系，可能是在末次冰期最盛期，由于气候带南移，干旱区域扩大，在古长江搬运沉积物中类似现今黄河沉积物的干旱组分明显增加，从而导致了地球化学示踪结果的长江与黄河双重性，或者说古气候的变化导致了古长江搬运物质成分的变化。 相似文献
11.
Ana P. Mucha M. Teresa S. D. Vasconcelos Adriano A. Bordalo 《Estuarine, Coastal and Shelf Science》2004,59(4):663
Vertical distribution (0–15 cm) of the macrobenthic community and its relationships to natural sediment characteristics and trace metal contents and bioavailability were studied at five locations in the lower Douro estuary, Portugal. An analysis of vertical metal distribution, for the interpretation of anthropogenic impact on the estuarine sediments, was also investigated. Sediment characterisation included organic matter, grain size, metals (Al, Fe, Cu, Pb, Cr, Ni, Cd, Zn and Mn), acid volatile sulphide (AVS) and simultaneously extracted metals (SEM). The macrobenthic community had low diversity (14 species), was dominated by small size opportunists and seemed to be controlled mainly by natural factors such as grain size distribution, Al and Fe contents and sediment depth. The vertically heterogeneous distribution of macrobenthic community appears to affect redox status of the sediments and consequently metal bioavailability. Despite anthropogenic contamination in terms of Zn, Cu, Pb, Cr and Ni having already been detected in the north bank, the analysis of vertical distribution was essential for the identification of current anthropogenic contamination in terms of Zn, Pb and Cd in the south bank. 相似文献
12.
J. M. Jouanneau C. Garcia A. Oliveira A. Rodrigues J. A. Dias O. Weber 《Progress in Oceanography》1998,42(1-4)
The Portuguese margin in front of the Tagus and Sado rivers is characterized by a narrow shelf incised by numerous canyons and by a large mud deposit. The two estuaries that feed this continental margin have distinct impact. The suspended particulate matter concentration values in the mouth of the Tagus are four times higher than in the Sado. During the summer the surface nepheloid layer is always larger than during the winter when it is restricted near the mouth of the estuary. This nepheloid layer may reach 30 km in length extending westward. The bottom nepheloid layer usually shows higher nephelometer values, and has a typical distribution: it is usually diverted southward in the direction of the Lisbon Submarine Canyon. We estimate the amount of suspended matter being discharged annually from the Tagus estuary to be between 0.4 and 1×106 t. The area covered by fine deposits is about 560 km2. Hence the thickness of sediments deposited annually should be between 0.07 and 0.18 cm. The sedimentation rates calculated from the 210Pb excess vary between 0.16 and 2.13 cm y−1 which correspond to the maximum rate. For a layer of 1 cm thick, 81,000 t of particulate organic carbon (POC) should be trapped. That would represent, with a minimum sedimentation rate between 0.07 and 0.18 cm y−1, an entrapment of 6000–15,000 t POC y−1. The trace metals content of box core samples clearly shows the anthropogenic impact in the uppermost level (5 cm thick) in the Tagus estuary and in all the sedimentary deposits (15 cm thick) on the shelf muddy area. Despite the narrowness of the shelf, a significant part of continental fluxes fails to reach the deep ocean. 相似文献
13.
The distribution and geochemical composition of suspended-particulate matter (SPM) in the East China Sea (ECS) were investigated
during the summer period of high continental runoff to elucidate SPM sources, distribution and cross-shelf transport. The
spatial variability of SPM distribution (0.3–6.5 mg l−1) and geochemical composition (POC, Al, Si, Fe, Mn, Ca, Mg and K) in the ECS was pronounced during summer when the continental
fluxes of freshwater and terrestrial materials were highest during the year. Under the influences of Changjiang runoff, Kuroshio
intrusion, surface production and bottom resuspension, the distribution generally showed strong gradients decreasing seaward
for both biogenic and lithogenic materials. Particulate organic carbon was enriched in surface water (mean ∼18%) due to the
influence of biological productivity, and was diluted by resuspended and/or laterally-transported materials in bottom water
(mean 9.4%). The abundance of lithogenic elements (Al, Si, Fe, Mn) increased toward the bottom, and the distribution correlations
were highly significant. Particulate CaCO3 distribution provided evidence that the SPM of the bottom water in the northern part of the study area was likely mixed with
sediments originally derived from Huanghe. A distinct benthic nepheloid layer (BNL) was present in all seaward transects of
the ECS shelf. Sediment resuspension may be caused by tidal fluctuation and other forcing and be regarded as the principal
agent in the formation of BNL. This BNL was likely responsible for the transport of biogenic and lithogenic particles across
or along the ECS shelf. Total inventories of SPM, POC and PN are 46, 2.8 and 0.4 Tg, respectively, measured over the total
area of 0.45 × 106 km2 of the ECS shelf. Their mean residence times are about 27, 13 and 11 days, respectively. The inventory of SPM in the water
column was higher in the northernmost and southernmost transects and lower in the middle transects, reflecting the influences
of terrestrial inputs from Changjiang and/or resuspended materials from Huanghe deposits in the north and perhaps from Minjiang
and/or Taiwan’s rivers in the south. The distribution and transport patterns of SPM and geochemical elements strongly indicate
that continental sources and cross-shelf transport modulate ECS particulate matter in summer. 相似文献
14.
Budgets of anthropogenically-derived Cr, Zn and Pb in the Santa Monica-San Pedro Basin and the Palos Verdes Shelf are estimated from profiles of these metals in a large number of sediment cores. Comparisons of inventories in the deep basin with combined emissions from the responsible sewage outfalls indicate that no more than 7% of the Cr, 2% of the Zn and 5% of the Pb derived from the sewage source are buried in the nearshore basin. A similar comparison of metal accumulation on the Palos Verdes Shelf with discharges from the nearby JWPCP outfall indicates that 12% of the Zn and 20% of the Cr and Pb are deposited locally. The annual percentages of sewage-derived Pb retained should be significantly lower, because surface runoff and atmospheric fallout are also important input pathways for anthropogenic Pb. Offshore variations in sediment metal composition suggest that Cr is most strongly attached to sewage particles while Zn and Pb are more labile. We conclude that the majority of anthropogenic metals are exported offshore beyond the inner basin. 相似文献
15.
Surface sediments from the Saronikos Gulf were analyzed for their aliphatic hydrocarbon (AHC) and polycyclic aromatic hydrocarbon (PAH) content by gas chromatography – mass spectrometry (GC/MS). The concentrations of Fe, Cr, As, Sb, Co and Sc were also determined by neutron activation analysis (NAA). The survey was performed at the beginning of the operation of Athens’ sewage primary treatment unit and the results can be used to monitor the unit's long-term effects in the area. The composition of aliphatic hydrocarbons indicated a chronic oil-pollution in the Saronikos Gulf sediments. The industrially impacted Elefsis Bay sediments suffered from heavy petroleum pollution, while the sediments near the sewage outfall had a moderate degree of pollution. Mixed source patterns of polycyclic aromatic hydrocarbons with dominant pyrolytic inputs have been identified in the sediments. Total concentrations of Fe, As and Sb along with their Sc normalized values presented elevated values in Elefsis Bay sediments. Chromium was found enriched in the sediments near the Athens sewage outfall. Factor analysis results showed that a part of As and Sb in Elefsis Bay sediments could be associated with organic or sulphidic phases. In addition, the lithogenic fraction of the sediments and the Fe oxides/hydroxides were important trace element carriers. Chromium and PAH inputs from the sewage outfall were also detected. Comparison of PAH and trace element concentrations with internationally-used sediment quality guidelines (SQG) revealed that Elefsis Bay sediments had the greatest potential of causing adverse effects in benthic organisms. 相似文献
16.
《Oceanologica Acta》1999,22(6):627-640
To evaluate the impact of land-based contaminants on benthic faunas, as part of the Land-Ocean Contamination Study (LOCS), a study transect was established in Jakarta Bay, Indonesia during the 1996 southeasterly monsoon. The transect extended 72 km between the city's main port, Tanjung Priok, and the Pilau Seribu Island chain in the Java Sea. The dissolved concentrations of Pb, Cu, Zn, Cr and Ni in seawater, in suspended particulate matter (SPM) and surficial sea bed sediments were measured along the transect at nine sites. In addition, metal concentrations were measured in tissues of the corals Goniopora lobata and Lobophyllia hemprichii at five sites, and of the green mussel, Perna viridis at six sites. An assessment of the impact of contaminants on the faunas was made using a biomarker approach, employing coral community analysis and lysosomal stability with Perna viridis. The results of the study showed two main trends. The distributions of metals dissolved in seawater, in SPM, and in the coral and mussel tissues were similar, and failed to show a consistent graded response from inshore to offshore sites. This suggests that the concentration of metals in waters is the primary route for metal uptake by the coral and mussel tissues. By way of contrast, a clear offshore increase in coral generic diversity, coral cover, coral colony numbers and neutral-red retention time (lysosomal stability) was observed, suggesting increasing nearshore stress. Whilst the coral community stucture may reflect the seasonally-averaged metal distributions in the bay (shown by the metal content of sea bed sediments which increase shorewards), it is more likely that the coral community structure and lysosomal biomarker are responding principally to other nearshore stresses, such as sediment and nutrient loading of water (sewage) or, more likely, organic contaminants such as oils and other hydrocarbons. 相似文献
17.
In 1984, on a transect covering the whole Baltic Sea and parts of the adjacent North Sea, 160 water samples were taken and analysed for their concentrations of particulate and dissolved metals. In addition, the suspended materials were investigated for their elemental bulk composition.The particulate fractions represented from about 5% (Cd, Cu and Ni) to 50% (Fe and Pb) of the total (particulate plus dissolved) concentrations. For some elements (Ba, Cd, Cu, Pb and Zn), the particulate matter from the surface microlayer was enriched with respect to those suspended materials taken from 0.2 m depth. This could reflect the atmospheric input of metal-rich aerosols. In anoxic deep waters, maximum contents of Zn (6400 μg g−1), Cu (1330 μg g−1) and Cd (12 μg g−1) were observed in the particulate matter, indicating sulphidic forms. On the other hand, under oxic conditions the distribution coefficients (Kd) decreased with the water depth (Cd, Fe and Pb).Relative to global background levels, the particulate matter contained metal “excesses” amounting to more than 90% of the total contents (Cd, Mn, Pb and Zn). Automated electron probe X-ray microanalysis (EPXMA) revealed that the elemental composition of sediments is mainly governed by post-depositional processes of early diagenesis and is only weakly related to the composition of suspended matter in the overlying water body. For instance, in relation to surface mud sediments of the central Baltic net-sedimentation basins, Zn, Cd, Cu and Mn had 30–100% higher levels in the suspended materials. The general pattern of metal contents of particulate matter taken from 10 m depth on a transect between the Bothnian Bay and the North Sea were—possibly as a result of anthropogenic inputs—rather similar for Pb, Zn and Cu. For Fe and Mn, the distribution patterns along the transect were probably governed by the natural loading characteristics and by the biogeochemistry of those elements. 相似文献
18.
青岛近海秋末冬初悬浮颗粒物中部分金属元素的组成与影响因素研究 总被引：2，自引：0，他引：2
2008年11月末在青岛近海和胶州湾11个站点采集表层和底层海水中的悬浮颗粒物(SPM)样品,经消解后用等离子体发射光谱法测定了Al、Ca、Fe、Mg、Mn、Ti和Ba、Co、Cr、Cu、Ni、Pb、Sr、V、Zn共15个金属元素以及P的含量,结合SPM和元素含量聚类分析的结果探讨了秋末冬初青岛近海SPM的来源以及金属元素组成的影响因素.SPM含量范围在1.7～16.1mg/L之间,平均为7.9 mg/L;SPM来源以陆源风化产物为主,生物生产有较小的贡献.SPM中Ti、Fe、Mn、Mg、Al、V、Co、Sr和Ni的含量相对恒定,且主要受陆源输入的控制;Ca和P除受陆源影响外,生物生产亦有附加贡献.离陆地相对较远的区域表层海水SPM中Pb、Zn和Ba、Cr、Cu的含量较高,特别是Pb和Zn的富集因子较大,可能受到了潜在的污染影响.Ti的恒定性以及与SPM的良好相关性代表着在青岛近海可用Ti作为颗粒物陆源指示元素,且优于Al. 相似文献
19.
东海颗粒碳的垂直转移过程 总被引：7，自引：3，他引：7
在１９９３年和１９９４年两个航次中，利用震动式取样从东海陆架取得３个柱状岩芯样品。对其进行了ＰＯＣ，ＰＩＣ，ＰＯＮ含量和粒度分析，并同其上覆水体的ＰＯＣ，ＰＩＣ以及总颗粒物的垂直通量和悬浮体作了比较。 相似文献
20.
《Deep Sea Research Part I: Oceanographic Research Papers》2006,53(8):1423-1438
The distribution of nepheloid layers across the outer shelf and upper continental slope off Namibia was studied during a cruise with R.V. Meteor in late austral summer 2003. Optical measurements, carried out with a transmissometer and a backscattering fluorometer, are correlated with suspended particulate matter (SPM) and particulate organic carbon (POC) values from water sample filtration. Conductivity-temperature-depth and oxygen data are used to relate the nepheloid layers to hydrographic structures. The particle content of surface water at the continental slope is controlled primarily by the offshore extension of highly productive upwelling filaments. A pronounced bottom nepheloid layer (BNL) covers the entire area of study with maximum intensity above the outer shelf and at the shelf break—an area where erosional forces dominate. The detachment of this BNL at the shelf break feeds a major intermediate nepheloid layer (INL) at 25.5°S. This INL is positioned at 250–400 m depth, at the lower boundary of an oxygen minimum zone, and is likely connected to the poleward flow of South Atlantic Central Water (SACW) across the shelf break. Together, these strong subsurface nepheloid layers are indicators of intensive lateral particle transport from the outer shelf towards a depocenter of organic matter on the upper continental slope. 相似文献