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1.
Experimental results of pressure-induced changes in mean magnetic susceptibility of rock samples from the main KTB borehole are reported. It was found that susceptibility values of rocks from depths between 5200 and 7000 m show unstable behaviour upon application of pressure, showing an increase in susceptibility of between 20 and 120%. This unstable behaviour was only detected in samples from the above mentioned depth interval, which contain both ferrimagnetic and antiferromagnetic phases of pyrrhotite. On the basis of thermomagnetic analysis, magnetic field treatment, optical microscopy and domain observations of undeformed and deformed samples, reasons for this instability are discussed and interpreted in relation to redistribution of internal stresses within the ferrimagnetic phase, resulting in changes in domain wall mobility.  相似文献   

2.
The x-ray diffraction analysis of samples of the Siberian platform traps (doleritic outcrops of the Stolbovaya River) containing spinodally decomposed titanomagnetite is carried out. It is shown that the method of x-ray powder diffraction fails to determine the lattice parameter (and, accordingly, the composition) of the finely dispersed high-Ti titanomagnetite decomposition region, which is due to a significant elastic strain of the crystal lattice of this phase in the plane separating it from the low-Ti magnetite phase and to a coherent character of x-ray scattering by the phases under consideration. The results of this study do not exclude the possibility of applying x-ray diffractometry to the diagnosis of phase stratification of titanomagnetites at the stage of coarsening of spinodal decomposition structures.  相似文献   

3.
In this paper magnetic property of the Delhi topsoil has been used to characterize the potentially polluted areas in terms of magnetic minerals and grain (Magnetic Domain) concentration as a factor of toxic metals and other mutagenic pollutant concentration. The Saturation magnetisation (Ms) and Saturation remanence (Mrs) has been taken as proxy for ferrimagnetic mineral concentration. However, delineation of anthropogenic magnetic fraction from lithogenic (geogenic) magnetic fraction has been done by the paramagnetic/diamagnetic contribution of soil with the fact that the fresh soil contains higher paramagnetic and diamagnetic minerals than polluted. Predominantly, the topsoils of Delhi are dominated with ferrimagnetic minerals (Magnetite and Maghemite phase). Significantly the industrial areas contain highest concentration of the ferrimagnetic minerals with negligible paramagnetic/diamagnetic fraction which leads to anthropogenic contribution. Heavy traffic and densely populated areas of the Delhi exhibit moderate to low soil pollution while green areas show lowest with higher paramagnetic/diamagnetic contribution. The soils in Delhi are dominated with Pseudo-Single Domain (PSD) magnetic grain, though the industrial areas in Delhi show coarser Multidomain (MD) grains in comparison to Stable Single Domain (SSD) in forest areas. Our study reveals that the fine grain particle does not show significant link with higher concentration of ferrimagnetic minerals at least in soils. The presence of the lithogenic magnetite crystal in the forest soil and anthropogenically produced spherules in industrial areas and higher concentration of the heavy metal in Delhi soil strengthen our findings.  相似文献   

4.
Frequency-dependent magnetic susceptibility, its anisotropy (AMS), its temperature variation, natural remanent magnetization and time-dependent isothermal remanent magnetization as well as M?ssbauer spectroscopy of a small collection of Celtic and Mediaeval graphitic pottery from Southern Bohemia were investigated. The mineral composition of the pottery is dominated by fragments of quartz, accompanied mainly by various silicates from granitoids and paragneisses, or by calcite, within the plastic component being probably illite but also graphite. No ferrimagnetic minerals were found in optical microscope, among Fe-oxides only limonite was observed, even though the bulk susceptibility of the pottery varies in the orders of 10?4 to 10?2 [SI]. This may indicate presence of ferromagnetic particles in the ultrafine (superparamagnetic, SP) state, which is confirmed by frequency-dependent susceptibility ranging from 3% to almost 16%. The low temperature susceptibility vs. temperature curves are only moderately sloped, showing the Verwey transition only in one case. The high temperature curves mostly show presence of two magnetic phases, maghemite and magnetite. Cooling curves show distinctly lower susceptibilities than the heating curves indicating instability of the assemblage of ferrimagnetic minerals, particularly in temperatures slightly under 700 °C. M?ssbauer spectroscopy confirmed the results of the frequency-dependent susceptibility, showing the increase of ferrimagnetic sextets in the spectra measured at 4.2K, likely indicating maghemite as the distinct ferrimagnetic phase. The frequency-dependent AMS indicates preferred orientation of SP1,16 particles, coaxiality between SP1,16 grain AMS and whole specimen AMS indicate that all grains, ultrafine and coarser ones, were oriented by the same process, i.e. copying the pottery structure created during wheel-turning.  相似文献   

5.
The chemical composition of riverine suspended sediment is the integration of the weathering crust minerals, soil organic matter and erosion agency within a specific drainage basin, which has been largely disturbed by the human activities. Selected metal elements of the riverine suspended sediment in the Zhujiang River were analysed using inductively coupled plasma–atomic emission spectrometry (ICP–AES) in three different hydrological phases from 1997 to 1998 at Makou and Sanshui hydrographic gauge stations, located at the lower reaches of the two main tributaries of the Zhujiang River, i.e. the Xijiang and the Beijing Rivers respectively. Organic carbon and nitrogen were also analysed using a conventional element analyser. The results demonstrate that the chemical composition of the riverine suspended sediment show obvious variability in different hydrological phases, which closely correlate to the organic matter content in suspended sediment. Intensified erosion in the flood phase results in lower concentration of the organic matter than that in the lower water level phase. The riverine suspended sediment with rich organic matter in the lower water level phase adsorbs some metal elements from the river water. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

6.
The magnetic properties of the infill of the Karaïn cave in Turkey were compared to the results of a sedimentological study on three longitudinal sections. The sediments of this site, namely cavity E, cover a period of ca. 500 ka and correspond to a large part of the Middle and Upper Pleistocene. The evolution observed for the various magnetic parameters is mainly related to climatic changes which followed one another during the infilling history of the cave. Two preconditions are necessary to understand the environmental magnetism, namely both the identification and the quantification of different magnetic phases (components) in the sediments, expressed by the ratio of the various magnetic parameters and the analysis of the magnetization curves. The results obtained through the study of the different magnetic parameters (low-field initial bulk (κlf) and mass (χlf) magnetic susceptibility, frequency dependence of the magnetic susceptibility (χfd), anhysteretic remanent magnetization (ARM), hysteresis parameters, anhysteretic susceptibility, ...) on 171 samples allowed us: 1 — to follow the nature, size and source of the grains at each level, and 2 — to identify six alternating levels, having different magnetic susceptibility signatures during warm, damp periods, in which the contribution of prehistorical hominidae (Homo Sapiens or Homo Neandertalensis) and animals, could have modified the original sedimentary structures.This study, in agreement with the sedimentological results, suggests a significant difference between sandy or sandy-silty levels (3 and 5) and those rich in clays and concretions. The sandy or sandy-silty levels are mainly characterized by a low amount of antiferromagnetic type grains, likely goethite and hematite, dominated by single-domain size (SD) and a small content of ferrimagnetic type grains, likely magnetite of multidomain size (MD), inherited from the host rock. Antiferromagnetic grains did not develop and were a priori drifted by the wind. They could be contemporaneous with a cold climate.The clays and clayey-silty levels are characterized by a large amount of superparamagnetic (SP) and SD grains, and a high content of low coercivity magnetic grains (magnetite, maghemite and Ti-magnetite). The saturation remanent magnetization (SIRM) of clayey levels is 5 to 10 times higher than that of sandy levels. The clayey levels are contemporaneous with a humid climate, which favoured the formation of secondary iron oxides, of stalagmitic floors and calcite concretions and of the emplacement of local pedogenesis phenomena, mainly at the top of the infill, i.e. in Level 6.  相似文献   

7.
Iron sulfide (FeS) was investigated using first-principles calculations up to a pressure of 400 GPa. A number of new phase transitions were found. An antiferromagnetic MnP-type structure, FeS II, was confirmed to be stable at low pressures, whereas at high pressures (40–135 GPa) we find a new stable phase, with a non-magnetic MnP-type structure, FeS VI. The observed first-order change in the cell shape between the two phases can be explained by the difference in magnetic configurations. The calculated cell parameters, atomic coordinates, and bulk modulus of non-magnetic MnP-type phase are consistent with those determined from experiment. The upper pressure limit of the stability of the non-magnetic MnP-type phase was calculated to be 135 GPa. A hitherto unsuspected phase transition from the non-magnetic MnP-type to a phase with Pmmn symmetry, FeS VII, was identified using the evolutionary crystal structure prediction (USPEX) method. The structure of the Pmmn phase has no known analogues, but can be described as a distortion of the NaCl-type structure. The Pmmn phase with the distorted NaCl-type structure is stable from 135 GPa at least up to 400 GPa. According to previous experiments and the present study, the transition sequence of FeS at low temperatures is as follows: troilite ➔ antiferromagnetic MnP-type phase ➔ monoclinic phase ➔ non-magnetic MnP-type phase ➔ Pmmn phase. The calculated volume reduction from the monoclinic to the non-magnetic MnP-type phase is 1.0% at 40 GPa, which is in good agreement with experimental observations. The calculated volume reduction from the non-magnetic MnP-type to the Pmmn phase is 3.7% at 135 GPa.  相似文献   

8.
The natural remanent magnetization of andesitic pumice emitted during the 1985 eruption of the Nevado del Ruiz volcano (Colombia) has a direction opposite to the present geomagnetic field. The self-reversing mechanism can be re-activated in the laboratory during cycles of heating and subsequent cooling in air and zero magnetic field. Laboratory-produced thermoremanent magnetization is dominated by the same self-reversal process in fields up to several mT. Microchemical, optical and Curie temperature analyses indicate that the ferromagnetic minerals are members of the magnetite-ulvöspinel and hematite-ilmenite series with average compositions of Fe2.73Ti0.27O4 and Fe1.38Ti0.62O3, respectively. In analogy with the magnetic behaviour of synthetically grown antiferromagnetic-ferromagnetic FeMn-FeNi films, the self-reversal can probably be interpreted in terms of an exchange field acting between a Ti-poor canted antiferromagnetic and a Ti-rich ferrimagnetic phase in the hemoilmenite grains.  相似文献   

9.
Mn-Zn ferrite powders were produced from low-grade manganese ore(LMO) via the chemical coprecipitation method combined with the ceramic method,after the LMO was leached in sulfuric acid and the obtained solution was purified.The effect of the pH on the magnetic properties of Mn-Zn ferrite was investigated by the varying pH of the co-precipitation system.The crystal structure and phases of the samples were characterized by X-ray diffraction and infrared spectrum,respectively.The magnetic measurements were carried out on a vibrating sample magnetometer.The optimal sample was obtained with a saturation magnetization of 55.02 emu/g,a coercivity of 8.20 G and a remanent magnetization of1.71 emu/g when pH is 7.5.  相似文献   

10.
Rock-magnetic investigations of environmental samples, such as soils, dust and leaves, can provide useful information on environmental stress. Aim of this paper is to report on the first magnetic survey carried out on environmental samples from Bogotá, Colombia, which is the fifth most populated city of Latin America. We studied three kinds of samples in order to evaluate their potential as pollution markers: soils, urban dust and leaves of the Sauco (Sambucus nigra) tree. Standard magnetic methods were used to analyze the three groups of samples, with special emphasis on leaves investigated here for the first time for environmental purposes. Samples were collected along two perpendicular transects in an area of the city presumably unpolluted, with two different systems of public transportation. Thermomagnetic curves obtained from soils and atmospheric dust show clearly defined ferrimagnetic phase (probably magnetite) as the main magnetic carrier. Curves of acquisition of isothermal remanent magnetization confirm the ferrimagnetic character of magnetic particles. Frequency-dependent magnetic susceptibility was found between 0 and 10%, suggesting less-important contribution of ultrafine super-paramagnetic magnetite. The apparent contradictory results between soils and the rest of samples may reflect different accumulation period for magnetic particles, being shorter for leaves and urban dust than for soils.  相似文献   

11.
The magnetic susceptibility (MS) of Chinese loess showing a general proportional relationship to pedogenic grade has been widely recognized and used for reconstruction of paleoclimate by Quaternary scientists. The in-situ pedogenic enhancement of ferrimagnetic content is normally believed to be the main reason for the increase of susceptibility in soil units. However, this pattern of high magnetic susceptibility in palaeosols, and low values in loess, are not replicated in some loess deposits. Siberian loess deposits display a completely opposite susceptibility behavior: high values in loess and low values in palaeosols. This inverse relationship has been explained by the idea that magnetic susceptibility is reflecting the magnitude of an aeolian ferrimagnetic component of consistent mineralogy, the grain size of which is related to average wind velocity. Our magnetic study of Siberian samples in this paper suggests that there are notable differences in magnetic properties between Siberian loess and developed palaeosols, not only in magnetic grain-size and concentration but also in magnetic mineralogy. This evidence is difficult to explain fully through variation in wind strength alone, but implies that the low magnetic susceptibility values in the Siberian paleosol units are a reflection, at least in part, of the alteration of the ferrimagnetic content by post-depositional processes. The Loess Plateau is a very arid area where potential evaporation is always higher than precipitation; pedogenesis occurs under dry oxidising conditions. The Siberian Kurtak region is located on the edge of the tundra where it is always wet and saturation during interglacials will lead to a reducing pedogenic environment. Ferrimagnetic minerals under this condition will be destroyed, resulting in lower magnetic susceptibility. Therefore, great care should be taken when using susceptibility values for paleoclimatic reconstruction.  相似文献   

12.
Morphological characteristics and microstructures of magnetic minerals extracted from Chinese loess and paleosols were investigated using powder X-ray diffraction (XRD) and high-resolution transmission electron microscopy (HRTEM). Our results indicate that maghemite in loess–paleosol sequences was transformed from magnetite through oxidation of magnetite. Maghemite transformed from eolian magnetite during chemical weathering has low-angle grain boundaries among maghemite nano-crystals. Some nano-crystalline maghemites with nanoporous texture resulted from microbe-induced precipitation of magnetite or transformation of poorly crystalline ferric Fe (oxy)hydroxides in presence of Fe-reducing bacteria. Aggregates of euhedral maghemite nano-crystals were transformed from magnetite magnetosomes. Both microbe-induced nanoporous magnetite and microbe-produced magnetite magnetosomes are directly related to microbial activities and pedogenesis of the paleosols. It is proposed that the formation of nano-crystalline maghemite with superparamagnetic property in paleosol results in the enhancement of magnetic susceptibility, although the total amount (weight percent) of magnetic minerals in both paleosol and loess units is similar. Our results also show that nano-crystalline and nanoporous magnetite grains prefer to transform into maghemite in semi-arid soil environments instead of hematite, although hematite is a thermodynamically stable phase. This result also indicates that a decrease in crystal size will increase stability of maghemite. It is also inferred that surface energy of maghemite is lower than that of hematite.  相似文献   

13.
Systematic magnetic and crystallographic studies were made on 57 titanomaghemite samples produced from sintered titanomagnetites with x values of 0.0, 0.2, 0.4, 0.6, 0.8 and 1.0. Curie temperature and lattice parameter values are often significantly different from results of previous studies (Ozima and Sakamoto, 1971; Readman and O'Reilly, 1972; Nishitani, 1979), particularly for x values of 0.4 and 0.6. Other important results are: (1) Oxidation of titanomagnetite is mainly a function of temperature. Atmosphere and Ti content have little influence. (2) Progressive oxidation of homogeneous titanomaghemites can take place in the presence of a rhombohedral phase. The amount of rhombohedral phase produced during oxidation increases with increasing temperature and (less conclusively) with decreasing Ti content. (3) Saturation magnetization measurements at low temperatures show both P- and Q-type ferrimagnetic behavior in titanomaghemites, and also show the Verwey (?) transition in titanomaghemites with composition x=0.0. (4) The temperature of spinel inversion increases with degree of oxidation. Slightly oxidized samples invert near 300°C; for samples with z > 0.8 the inversion temperature is above 450°C. This last result, although neither expected nor understood, is supported by results of thermomagnetic studies on some oceanic basalts.  相似文献   

14.
Summary The paper deals with the magnetic properties of the natural minerals haematite, ilmenite and pyrrhotite. The natural remanent magnetization Jn, the volume susceptibility , the specific magnetization of saturation so, the Curie temperature , the A.C. demagnetization of natural remanent magnetization, the thermal demagnetization Jn, the temperature dependence of the specific magnetization of saturation, and several other parameters were determined for the individual sets of minerals. Since natural minerals can and do contain various heterogeneous and isomorphic admixtures, their magnetic properties may change depending on the content and type of these admixtures. Therefore, all the investigations of the magnetic properties described in this paper were carried out with extensive sets of minerals, representing various Czechoslovak and world localities. A number of interesting results were obtained from the executed experiments, e.g., the different stability of the natural remanent magnetization of haematite with respect to A.C. demagnetization, the presence and type of heterogeneous inclusions in ilmenite, the phase changes connected with the -transition in natural pyrrhotites, etc. The types of distributions of the investigated values of the magnetic properties were also determined.  相似文献   

15.
A planetary pattern of substorm development in auroral precipitation has been constructed on the basis of the F6 and F7 satellite observations. The behavior of the auroral injection boundaries and characteristics of precipitating electrons in various precipitation regions during all phases of a statistically mean magnetospheric substorm with an intensity of AL ～ ?400 nT at a maximum is considered in detail. It is shown that during a substorm, the zone of structured auroral oval precipitation AOP and the diffuse auroral zone DAZ are the widest in the nighttime and daytime sectors, respectively. In the daytime sector, all precipitation regions synchronously shift equatorward not only at the origination phase but during the substorm development phase. The strongest shift to low latitudes of the daytime AOP region is observed at a maximum of the development phase. As a result of this shift, the area of the polar cap increases during the phases of substorm origination and development. It is shown that the average position of the precipitation boundaries and the energy fluxes of precipitating electrons at each phase are linearly related to the intensity of a magnetic disturbance. This makes it possible to develop a model of auroral precipitation development during each phase of substorms of any intensity.  相似文献   

16.
Magnetic measurements of deposited atmospehric dust can serve as an additional parameter in assessing environmental pollution. This method is based on the assumption that atmospherically deposited particles contain significant portion of ferrimagnetic iron oxides of anthropogenic origin, which can be easily detected. Aim of this paper is to identify clearly magnetic fraction of daily samples of particulate matter less than 10 μm (PM10), routinely used for air quality assessment and monitoring. We used combination of thermomagnetic analyses and other physical and chemical methods, including scanning electron microscopy (SEM) and Mössbauer spectroscopy. Our results show that daily samples of PM10, collected at sites with different degree of atmospheric pollution, contain magnetite of spherical shape, which is presumably of industrial origin. Thus, magnetic methods can be applied directly to the same substances, which are used routinely in air quality assessment and monitoring.  相似文献   

17.
The AD 79 eruption of Vesuvius is certainly one of the most investigated explosive eruptions in the world. This makes it particularly suitable for the application of numerical models since we can be quite confident about input data, and the model predictions can be compared with field-based reconstruction of the eruption dynamics. Magma ascent along the volcanic conduit and the dispersal of pyroclasts in the atmosphere were simulated. The conduit and atmospheric domain were coupled through the flow conditions computed at the conduit exit. We simulated two different peak phases of the eruption which correspond to the emplacement of the white and gray magma types that produced Plinian fallout deposits with interlayered pyroclastic flow units during the gray phase. The input data, independently constrained and representative of each of the two eruptive phases, consist of liquid magma composition, crystal and water content, mass flow rate, and pressure–temperature–depth of the magma at the conduit entrance. A parametric study was performed on the less constrained variables such as microlite content of magma, pressure at the conduit entrance, and particle size representative of the eruptive mixture. Numerical results are substantially consistent with the reconstructed eruptive dynamics. In particular, the white eruption phase is found to lead to a fully buoyant eruption plume in all cases investigated, whereas the gray phase shows a more transitional character, i.e. the simultaneous production of a buoyant convective plume and pyroclastic surges, with a significant influence of the microlite content of magma in determining the partition of pyroclast mass between convective plumes and pyroclastic flows.  相似文献   

18.
Quantitative textural analyses including crystal size distributions (CSDs) provide insights into crystallisation kinetics of magmatic systems. Investigations of volcanic crystal textures often rely on greyscale variations on backscattered electron images to identify crystal phases, which must then be thresholded and/or traced manually, a laborious task, and investigations are typically restricted to a single crystal phase. A method is presented that uses energy-dispersive X-ray element maps to generate textural data. Each pixel is identified as a crystal phase, glass or vesicle according to relative chemical composition enabling concurrent acquisition of multiphase CSD, crystallinity and mineral mode data. Data processing is less time intensive for the operator but considerable instrument time is required to generate element maps. The method is applied to 17 dacite samples from the 1980–1986 and 3 from the 2004–2005 eruptive periods of Mount St. Helens volcano (USA) to provide quantitative insights into multiphase textural evolution. All of the CSDs are curved and concave-up in the standard CSD plot with curvature increasing with plagioclase content. To facilitate comparisons with previous studies, CSDs for microlites (<50?μm length crystals) are approximated as straight lines. The line intercepts and slopes provide information on n 0 (nucleation density) and characteristic length or Gτ (the product of growth rate (G) and residence time (τ)), respectively. These parameters, as well as the total groundmass crystallinity, show distinct differences between explosive deposits from summer 1980 and post-summer 1980 domes. Post-summer 1980 microlite n 0 values are mostly at the lower end of the range of those measured for summer 1980 samples. Total groundmass crystallinities during summer 1980 are between 10 and 30?vol.%, whereas post-summer 1980 crystallinity increases to between 39 and 51?vol.%. The range of n 0 values is similar to those previously published for Mount St. Helens but Gτ is consistently higher. Gτ of a May 1985 sample analysed in this study is approximately 2?μm higher compared with previously published data for the same sample when processed using similar methodologies. Groundmass crystallinity data show similar trends to those previously published for the 1980 to 1986 eruption, increasing sharply after summer 1980 then increasing more gradually during the dome-building phase of the eruption. The effects of varying L, the apparent crystal size, and crystal aspect ratio on resultant CSDs are also investigated. Whilst relative temporal variations in CSDs for a given dataset can be investigated, absolute values from different studies cannot be compared unless methods of data acquisition and processing are exactly the same.  相似文献   

19.
In this study, mineral magnetic properties and petroleum hydrocarbons were statistically analysed in four sediment cores (C1, A1, T1 and K1) from the north east coast of Tamilnadu, India to examine the feasibility of PHC concentrations assessment using magnetic susceptibility. The C1 and A1 cores reveal a clear horizon of increase in PHC above 35 and 50 cm respectively suggesting the excess anthropogenic loading occurred in the recent past. Magnetic properties which were enhanced in the upper part of the sediment cores were the result of ferrimagnetic minerals from anthropogenic sources. Factor analysis confirmed that the input of magnetic minerals and petroleum hydrocarbons in Chennai coastal sediments are derived from the same sources. The present study shows that instead of expensive and destructive PHC chemical methods, magnetic susceptibility is found to be a suitable, cheap and rapid method for detailed study of petroleum hydrocarbon contamination in marine sediments.  相似文献   

20.
This paper discribes characteristic features of the extrusive dome growth of the Young Shiveluch Volcano in 2001–2013 and analyzes variations in the chemical and mineralogic composition of magmas erupted during this period. It is shown that, compared with the earlier phases in the dome growth during 1980–1981 and 1993–1995, the andesites that were erupted in the 2000s are less homogeneous in bulk composition, crystal contents and contain phenocrysts, which differ in composition and the conditions of crystallization. These compositional feature of rocks are interpreted as resulting from convection in a shallow magma chamber, with the convection being caused by the arrival of a fresh portion of deep magma.  相似文献   

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