首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献,搜索用时 500 毫秒
1.
化学风化作用中的稀土元素行为及其影响因素   总被引:22,自引:0,他引:22  
地表风化作用长期以来一直是地球和环境科学研究的焦点问题。风化作用中微量元素地球化学行为的研究不但有助于对一系列全球性问题的认识和理解,而且有助于许多与人类生存密切相关的环境问题的解决。系统总结了近年来国内外在风化作用中的稀土元素地球化学研究领域的主要内容和最新进展,着重介绍了风化壳中稀土元素的分布特征、Ce异常成因、稀土元素的赋存状态和迁移方式、影响稀土元素分布和循环的主要因素,以及风化作用稀土元素地球化学的主要研究方法。最后,分析指出有机质和微生物作用对稀土行为的影响是未来的重要研究方向。  相似文献   

2.
The Kopaida plain is a cultivated region of Eastern Greece, with specific characteristics related to the paleogeographic evolution and the changes in land use of the area. This study examines the geochemical conditions of the groundwater and soil, and the correlations between them. 70 samples (50 samples of groundwater and 20 samples of soil) were collected in order to asses the geochemical status and the major natural and manmade affecting processes in the region. Extended chemical analyses were carried out including the assessment of 28 parameters for groundwater and 13 for soil samples. The results revealed that groundwater geochemistry is influenced primary by natural processes such as the geological background, and secondary by manmade impact mainly deriving from the extended use of Nitrogen-fertilizers and the over-exploitation of boreholes. Soil geochemistry is influenced exclusively by natural processes, such as weathering of the prevailing geological formations. Chemical analyses and the statistical processing of data revealed that the major factor for the geochemical status of soils is the weathering of the karstic substrate, as well as the existing lateritic horizons and a weak sulfide mineralization.  相似文献   

3.
人为土壤有机碳的分布特征及其固定意义   总被引:9,自引:0,他引:9       下载免费PDF全文
文章在分析不同类型的人为土壤形成过程及其特点的基础上研究了人为土壤有机碳含量、分布年龄与同位素组成特征。结果表明,人为土壤中有机碳的含量分布不同于起源土壤或者相应的非人为土壤,主要体现在有机碳含量降低的缓慢和不规则性以及有机碳含量的相对富集。通过计算证明人为土壤的有机碳密度高于相邻土壤或起源土壤。放射性碳测定表明人为土壤中的有机碳年龄较老,说明了有机碳在这些土壤中存在的相对稳定性。土壤有机碳的稳定同位素组成分析表明,土壤中深层的有机碳与现代有机碳来源不同,也表明了土壤中有机碳的稳定存在。文章还分析了人为土壤中有机碳富集和稳定的可能机制,包括物理、化学和生物学机制,认为就有机碳的固定而言,人为土壤是一种具有最佳管理方式的可持续利用的土壤资源  相似文献   

4.
The threshold between geochemical background and anomalies can be influenced by the methodology selected for its estimation. Environmental evaluations, particularly those conducted in mineralized areas, must consider this when trying to determinate the natural geochemical status of a study area, quantifying human impacts, or establishing soil restoration values for contaminated sites. Some methods in environmental geochemistry incorporate the premise that anomalies (natural or anthropogenic) and background data are characterized by their own probabilistic distributions. One of these methods uses exploratory data analysis (EDA) on regional geochemical data sets coupled with a geographic information system (GIS) to spatially understand the processes that influence the geochemical landscape in a technique that can be called a spatial data analysis (SDA). This EDA–SDA methodology was used to establish the regional background range from the area of Catorce–Matehuala in north-central Mexico. Probability plots of the data, particularly for those areas affected by human activities, show that the regional geochemical background population is composed of smaller subpopulations associated with factors such as soil type and parent material. This paper demonstrates that the EDA–SDA method offers more certainty in defining thresholds between geochemical background and anomaly than a numeric technique, making it a useful tool for regional geochemical landscape analysis and environmental geochemistry studies.  相似文献   

5.
Extensive agricultural, residential, and industrial activities have increased demand for water supplies, which can lead to groundwater quality degradation. The integration of geochemical methods, multivariate statistical analysis, and geostatistical approaches were carried out on 169 groundwater samples to elucidate the regional factors and processes that influencing the geochemical composition of groundwater in coastal shallow aquifer of Terengganu, Malaysia. Hydrochemical modelling revealed that the abundance of Ca and Mg was contributed by carbonate and silicate weathering while higher HCO3 and Cl were resulted from reverse ion exchange reaction. Therefore, the dominant hydrogeochemical facies of groundwater was Ca-Mg-HCO3-Cl type. The influence of salinization resulting from seawater mixing to the groundwater was corroborated by Cl/HCO3 ratio, which affected around 50.9% of the groundwater samples slightly or moderately. Spatial mapping using ordinary kriging found that the threat of sea water intrusion is more prominent in the major river confluence especially around Terengganu and Marang River in the northeast and Dungun and Kemaman River confluence in southeast of study area. Moreover, factor analyses concluded that salinization, anthropogenic activities, reverse ion exchange, weathering processes, agricultural impact, and seasonal variations were the factors that regulate 63% of the major ion chemistry in study area. Finally, these findings showed the importance of understanding the hydrochemical characteristics for effective utilization, aquifer protection, and prediction of changes to minimize the effects of salinization and reduce human pollution such as agriculture and urbanization. It is essential steps in order to safeguard the utilization of groundwater resources for future generations.  相似文献   

6.
Soil is a dynamic natural body and fundamental resource. Human activities influence intensively the natural processes in soils. They modify and accelerate the development of soils. In this investigation, the deposition of colluvial sediments (colluviation) and soil formation are proposed as geoindicators for a better understanding of long-term environmental changes and environmental impact assessment. Deposition of colluvial sediments during several time periods and subsequent soil formation under different land-use systems reflect important aspects on the long-term human interference in the environment. In this study, we hypothesize that intensive human activities and environmental changes during middle and late Holocene are responsible for a strong modification of soils in an investigation area in Schleswig–Holstein (Germany). Soil age information together with geomorphological data, physical, chemical and biological soil properties provide the database which is necessary to study the types and rates of colluviation and soil formation. After the investigation with a high resolution in time and space, results show that middle and late Holocene land-use changes and land management are responsible for soil formation in colluvial layers. Properties of soils and sediments vary intensively from Mesolithic until Modern times. Intensive soil formation took place during periods of geomorphodynamic stability in dense woodland. Evidence in our investigations shows that colluviation has a strong relation with decision-making and environmental degradation in the past. This confirms, too, that a geoindicator concept is needed to understand and to monitor long-term environmental changes and degradation.  相似文献   

7.
在地球表生系统中,化学风化作用强烈改变着岩石、水体、土壤和大气成分,是元素地球化学循环的最主要驱动力。河水溶解物质主要来源于流域内岩石化学风化,同时受到降水、人类活动的影响。文中通过对鄱阳湖流域河水样品的采集和化学成分分析,结合流域地质背景,研究了河水化学成分特征及其影响因素。结果显示,与20世纪80年代相比,本区河水Cl-、SO24-所占比例显著增高,有逐渐酸化趋势;与世界上其他主要河流相比较,该区Ca2+/Na+、Mg2+/Na+、HCO3-/Na+等比值偏低,反映了较强的蒸发岩溶解及人类活动影响特征。该区河水离子特征主要由岩石风化所控制,降水对该区河水溶解物质贡献率为10.3%,农业生产活动对鄱阳湖水溶解物质贡献率为4.9%,矿山活动对饶河丰水期、枯水期离子总量贡献率分别为8.9%、14.6%。  相似文献   

8.
本文利用层次聚类分析和因子分析两种多元统计方法探讨了贵州省毕节市岩溶地下水水化学组分特征及影响因素。结果表明:研究区地下水组分浓度变化范围较大,具有明显的空间变异性,其受到地理因素、水岩作用过程、土壤等自然因素、人类活动的影响。这四个影响因素能够解释地下水水化学组分82%的特征,其中,水岩作用过程和人类活动是主要影响因素。地下水中HCO3-、SO42-、Ca2+和Mg2+主要来源于碳酸盐岩矿物的溶解,同时也受到人类采煤活动的影响;Cl-、K+、Na+和NO3-则主要受到人类活动,特别是农业化肥、粪肥、农药施用和生活污水排放等因素的影响。本研究有助于深化对西南岩溶地下水水化学特征的理解,有助于有效预测岩溶地下水污染物来源,且对岩溶区水资源的合理开发利用具有积极的指导意义。  相似文献   

9.
碳酸盐岩差异性风化成土特征及其对石漠化形成的影响   总被引:35,自引:0,他引:35  
碳酸盐岩极低的酸不溶物含量使岩石风化产生的残积土壤物质数量极少,并产生巨大的体积缩小,促使早期形成的残积土在重力作用下不断向下塌陷。显著的差异性风化使基岩面强烈起伏,甚至形成大量的岩溶尘洼地、裂隙、地下管道、洞穴系统等。在重力和水的作用下,土粒沿垂直和水平方向上经微距离或短距离搬运到上述低洼或地下空间中,甚至由地下河带到更远的地方,这是碳酸盐岩地区土壤丢失的重要方式,也是形成石漠化最主要的地质因素。土壤在地表分布高度不均匀,是碳酸盐岩地区的地表少土的重要原因。对于酸不溶物含量相当的石灰岩和白云岩而言,由于白云岩的差异性风化明显弱于石灰岩,以及受各种应力作用后,白云岩形成的节理及裂隙密集而均匀,从而提高了近地表白云岩的含水能力,延长了风化过程中的水-岩反应时间,使风化作用可以相对集中于地表或近地表进行,有利于岩石的整体风化作用的进行,同时使白云岩风化壳基岩面起伏相对较小,风化残积形成的土壤分布也相对均匀。因此,白云岩区地表土层较厚,石漠化程度也稍弱于灰岩区。  相似文献   

10.
Weathering and landslide occurrences in parts of Western Ghats,Kerala   总被引:2,自引:0,他引:2  
The climatic condition of Western Ghats has influenced the process of weathering and landslides in this mountainous tract along the southwest coast of India. During the monsoon period, landslides are a common in the Western Ghats, and its intensity depends upon the thickness of the loose unconsolidated soil formed by the process of weathering. Debris landslides with a combination of saprock, saprolite and soil, indicate the role of weathering in landslide occurrences. This paper reports on how the weathering in the windward slope of Western Ghats influences the occurrence of landslides and the factors which accelerate the weathering process. Rock and soil samples were collected from the weathering profile of hornblende gniess and granite gneiss. The chemical analysis and the calculated Chemical Index of Alteration (CIA) indicate the significant weathering and its possible influence on landslide occurrences in the study area. Mainly, the CIA value of lateritic soil and forest loam indicated the extent of high chemical weathering in this region. Rainfall is the dominant parameter influencing the chemical weathering process. In addition, deforestation, land use practices and soil erosion are some of the other important factors accelerating the weathering process and landslide occurrences in the region. The locations of the previous landslides superimposed on geology and soil show that most of the landslide occurrences are associated with the highly weathered zone, particularly lateritic soil and the ‘severe’ (rock outcrop) erodability zone.  相似文献   

11.
广汉市平原区浅层地下水化学演化及其控制因素   总被引:4,自引:0,他引:4  
为在广汉市城乡规划过程中提供地下水资源开发利用的基础信息,采用矿物风化系统分析、相关性分析、主成分分析和PhreeQC反向水文地球化学模拟等方法对广汉市平原区的浅层地下水的地下水水化学组分进行分析,确定了浅层地下水的水化学演化及控制因素,完成了地下水资源的质量及时空分布特征分析。分析表明:Gibbs图显示岩石风化主导该区地下水水化学特征,风化过程产生离子和次生矿物又经历水解作用,在矿物风化系统稳定场图中显示水样中铝硅酸盐矿物逐渐趋于溶解,碳酸盐矿物处于饱和状态;PhreeQC反向水文地球化学模拟结果显示在水流模拟路径上主要发生了钙蒙脱石、钾长石溶解和高岭石、石英、钠长石的沉淀,以及Ca-Na2之间的阳离子交换吸附作用;离子相关性和主成分分析进一步的验证了溶滤作用、蒸发浓缩作用和阳离子交换吸附作用是引起浅层地下水水化学过程和矿物组成改变的主要原因。研究区地下水水质总体不会对人体健康造成不良影响。  相似文献   

12.
Quantifying long-term rates of chemical weathering and physical erosion is important for understanding the long-term evolution of soils, landscapes, and Earth's climate. Here we describe how long-term chemical weathering rates can be measured for actively eroding landscapes using cosmogenic nuclides together with a geochemical mass balance of weathered soil and parent rock. We tested this approach in the Rio Icacos watershed, Puerto Rico, where independent studies have estimated weathering rates over both short and long timescales. Results from the cosmogenic/mass balance method are consistent with three independent sets of weathering rate estimates, thus confirming that this approach yields realistic measurements of long-term weathering rates. This approach can separately quantify weathering rates from saprolite and from overlying soil as components of the total. At Rio Icacos, nearly 50% of Si weathering occurs as rock is converted to saprolite; in contrast, nearly 100% of Al weathering occurs in the soil. Physical erosion rates are measured as part of our mass balance approach, making it particularly useful for studying interrelationships between chemical weathering and physical erosion. Our data show that chemical weathering rates are tightly coupled with physical erosion rates, such that the relationship between climate and chemical weathering rates may be obscured by site-to-site differences in the rate that minerals are supplied to soil by physical erosion of rock. One can normalize for variations in physical erosion rates using the “chemical depletion fraction,” which measures the fraction of total denudation that is accounted for by chemical weathering. This measure of chemical weathering intensity increases with increasing average temperature and precipitation in data from climatically diverse granitic sites, including tropical Rio Icacos and six temperate sites in the Sierra Nevada, California. Hence, across a wide range of climate regimes, analysis of chemical depletion fractions appears to effectively account for site-to-site differences in physical erosion rates, which would otherwise obscure climatic effects on chemical weathering rates. Our results show that by quantifying rates of physical erosion and chemical weathering together, our mass balance approach can be used to determine the relative importance of climatic and nonclimatic factors in regulating long-term chemical weathering rates.  相似文献   

13.
14.
Assessing water quality using water quality index and multivariate analysis   总被引:7,自引:3,他引:4  
Groundwater is increasingly gaining significance as the main solution to the water supply problems in Ghana, especially in the rural areas. This study was conducted to determine which factors play significant roles in the hydrochemistry of groundwater from the southern Voltaian formation. Conventional graphical and multivariate statistical methods were used. The study reveals three main factors controlling the hydrochemistry. Silicate mineral weathering and reverse cation exchange are the most important processes affecting the hydrochemistry of groundwater at this part of the formation. Interpolation maps created from factor scores suggest that these processes are the most pervasive, recording high scores almost everywhere in the study area. Carbonate mineral weathering is the second most important process in the hydrochemistry. This study finds that carbonate mineral weathering in the area is probably facilitated by carbonic acid rather than sulfuric acid. Chemicals from agricultural activities constitute the third most important process influencing groundwater quality in the area. Eighty samples were used to calculate water quality indices, WQI, which were in turn used to classify groundwater from the study area. Over 98% of the samples fall within the “Excellent” and “Good” categories, suggesting that groundwater from the southern Voltaian formation is generally acceptable for drinking purposes.  相似文献   

15.
Chittur block represents a mid-land region of Palakkad district, Kerala and the block differs from the rest of the blocks in its climate and availability of groundwater. About 75% of the people depend on agriculture for their livelihood. Results showed that groundwater salinity levels (up to 1,963 mg/L TDS),fluoride (up to 6.3 mg/L) and nitrate (up to 141 mg/L) contents have increased significantly in tandem with the increase in groundwater abstraction. Before human intervention the chemical weathering of gneisses and granites was the main process impinging on the chemical signature of groundwater. The initial chemical equilibrium conditions change with increasing groundwater withdrawal rates and fertilizer input, in a milieu of lower natural groundwater recharge. The appearance of higher levels of bicarbonate, linked to denitrification processes, and the decrease in calcium, due to calcite precipitation, can lead to increased content of sodium and fluoride in groundwater. In this scenario the use of groundwater resources for human consumption and agriculture represents a public health risk if water management actions do not change the trend in water use in the near future. The potential loss of fertile soil by groundwater salinization must also be considered when planning sustainable policies in a region with over dependence on groundwater resources.  相似文献   

16.
富硒土地资源研究进展与评价方法   总被引:13,自引:0,他引:13  
周国华 《岩矿测试》2020,39(3):319-336
硒是重要的生命必需元素,开发富硒农产品是提升我国人体硒摄入水平的安全有效途径,富硒土地资源评价与利用规划是土地质量地球化学调查成果服务于特色农产品发展与脱贫攻坚的重要切入点。本文评述了近年来在土壤和作物硒含量、土壤硒成因来源、土壤硒赋存形态及其生物有效性影响因素、土壤-作物系统硒吸收运移、硒与重金属镉等元素之间的相互作用等调查研究成果。针对我国土壤硒背景值约0.20mg/kg,远低于世界土壤背景值0.40mg/kg,整体上处于低硒水平的实际情况,认为采用0.40mg/kg Se作为富硒土壤标准具有较强的科学依据;多数情况下土壤硒主要来源于成土地质背景,部分地区与人为活动密切有关;富硒土壤可分为地质高背景、次生富集作用、人为输入及其多种作用的叠加成因,元素地球化学性质决定了硒与镉等重金属元素共生的普遍性;土壤硒成因来源以及pH、Eh、有机质、铁铝氧化物等土壤理化条件决定了硒和重金属赋存形态与生物有效性,进而影响到富硒土地的可利用性,成为制定富硒土壤地方标准的理论基础与考虑因素;不同作物种类对硒吸收富集能力不同,筛选适应当地农田生态环境、富硒低镉的农作物具有实际意义;现有的部分富硒农产品标准未充分考虑人体补硒目的,并存在标准间协调性差等问题,急需加强富硒农产品标准的制定。本文提出,富硒土地资源评价不仅需要考虑土壤硒和重金属含量,而且需综合土壤硒成因来源及其生物有效性、土壤-作物系统硒迁移累积、硒与重金属镉等元素之间的相互作用机制,以及当地气候、土壤和景观条件下作物种植的适宜性,依据富硒土地资源可利用性进行分类分区、科学规划和合理种植管理。同时建议,为满足富硒土地资源调查评价与可利用性分析、富硒农产品健康效应研究的需要,需要加强土壤和作物硒含量及其形态的提取分离与分析测试方法技术研究与应用。  相似文献   

17.
冀中南平原区土壤氟元素来源分析   总被引:1,自引:0,他引:1       下载免费PDF全文
冀中南平原区东部为河北省地方性氟中毒病的高发区。针对土壤异常高氟区,本文通过分析太行山基岩、第四纪火山活动、黄河泛滥和第四纪海侵等自然因素和大气降尘、化肥、灌溉水等人为因素,厘定了自然和人为因素对土壤中氟元素含量的影响和控制程度。得出冀中南平原深层土壤中氟元素含量变化总体上受地质背景控制,在此基础上第四纪火山活动、海侵和黄河泛滥对局部地区土壤氟元素含量具有较强烈影响。土壤异常区及地方病高发区土柱剖面氟及重金属元素含量变化也显示,土壤中氟元素含量变化明显受土壤质地的控制,后期人为作用叠加量很微弱。上述认识和结论为氟中毒地方病预防和治理提供了重要依据。  相似文献   

18.
地壳风化速率研究综述   总被引:6,自引:1,他引:6  
地壳风化速率研究的理论基础是质量守恒原理和溶液与矿物反应动力学法则。元素在风化过程中的行为受多种因素控制,主要包括基岩风化量、大气沉降量、径流量、生物的输出数量和人为输入量(如施肥)。硅酸盐矿物化学风化过程中,矿物与溶液之间总的化学反应速率是单个反应速率之和,其中涉及到 3个关键参数,即:酸中和能力(ANC)、基本阳离子/无机铝(BC/Al无机)比值和临界负荷(CL)。风化速率的研究主要采用四种方法,即PROFILE模型、基本阳离子损耗、元素输入-输出指数和Sr同位素比值等。PROFILE模型是一个稳定态的综合土壤化学模型,矿物的分解速率、矿物的暴露表面积、土壤水饱和度和土壤层厚度决定着该矿物的风化速率,总的风化速率为各种矿物的风化速率之和。元素损耗,主要是基本阳离子(Ca、Na、K和Mg)的损耗,假设Ti、 Zr和Nb在成土过程中含量稳定并不参与风化反应,那么对于给定的土壤层,化学风化损耗的基本阳离子可以通过比较土层与成土母质之间元素组成的差异来计算。输入-输出指数的假设前提是研究的流域处于稳定状态,一般认为输入指数是大气沉降,输出指数是河流搬运溶解部分、悬浮的非岩屑成因部分和生物营养净吸收部分。Sr同位素在生物和化学作用过程中并不分馏,不同生态系统阳离子场中Sr同位素组成是大气和矿物风化来源的Sr的混合物。  相似文献   

19.
This study aims to investigate the hydrochemical characteristics of shallow aquifer in a semi-arid region situated in northwest Algeria, and to understand the major factors governing groundwater quality. The study area is suffering from recurring droughts, groundwater resource over-exploitation and groundwater quality degradation. The approach used is a combination of traditional hydrochemical analysis methods of multivariate statistical techniques, principal component analysis (PCA), and ratios of major ions, based on the data derived from 33 groundwater samples collected in February 2014. Results show that groundwater in the study area are highly mineralized and collectively has a high concentration of chloride (as Cl?). The dominant water types are Na-Cl (27%), Mg-HCO3 (24%) and Mg-Cl (24%). According to the (PCA) approach, salinization is the main process that controls the hydrochemical variability. The PCA analysis reveal the impact of anthropogenic factor especially the agricultural activities on the groundwater quality. The PCA highlighted two types of recharge: Superficial recharge from effective rainfall and excess irrigation water distinguished by the presence of nitrate and lateral recharge or vertical leakage from carbonate formations marked by the omnipresence of HCO3?. Additionally, three categories of samples were identified: (1) samples characterized by good water quality and receiving notable recharge from carbonate formations; (2) samples impacted by the natural salinization process; and (3) samples contaminated by anthropogenic activities. The major natural processes influencing water chemistry are the weathering of carbonate and silicate rocks, dissolution of evaporite as halite, evaporation and cation exchange. The study results can provide the basis for local decision makers to ensure the sustainable management of groundwater and the safety of drinking water.  相似文献   

20.
Teboursouk region, Northwestern Tunisia, is characterized by the diversity of its natural resources (petroleum, groundwater and minerals). It constitutes a particular site widely studied, especially from a tectonic stand point as it exhibits a complex architecture dominated by multi-scale synclinals and Triassic extrusions. It has typical karst landform that constitutes important water resources devoted for human consumption and agriculture activities, besides to the exploitation of the Mio-Plio-Quaternary aquifer (MPQ). Thus, hydrogeological investigations play a significant role in the assessment of groundwater mineralization and the evaluation of the used water quality for different purposes. Hence, the current study based on a combined geochemical–statistical investigation of 50 groundwater samples from the multilayered aquifer system in the study area give crucial information about the principal factors and processes influencing groundwater chemistry. The chemical analysis of the water samples showed that Teboursouk groundwater is dominantly of Ca–Mg–Cl–SO4 water type with little contribution of Ca–Mg–HCO3, Na–K–Cl–SO4 and Na–K–HCO3. The total dissolved solids (TDS) values range from 0.37 to 3.58 g/l. The highest values are located near the Triassic outcrops. Furthermore, the hydrogeochemistry of the studied system was linked with various processes such as carbonates weathering, evaporites dissolution of Triassic outcrops and anthropogenic activities (nitrate contamination). Additionally, the main processes controlling Teboursouk water system were examined by means of multivariate statistical analysis (PCA and HCA) applied in this study based on 10 physicochemical parameters (TDS, pH, SO4, HCO3, pCO2, Ca, Mg, Na, K, Cl and NO3). Two principal components were extracted from PCA accounting 61% of total variance and revealing that the chemical characteristics of groundwater in the region were acquired through carbonates and evaporite dissolution besides to nitrate contamination. Similarly, according to Cluster analysis using Ward’s method and squared Euclidean distance, groundwater from the studied basin belongs to five different groups suggesting that the geochemical evolution of Teboursouk groundwater is controlled by dissolution of carbonates minerals, chemical weathering of Triassic evaporite outcrops, cation exchange and anthropogenic activities (nitrate contamination).  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号