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1.
A study was conducted on Cu, Zn, Cd, Fe, Co and Ni levels in Saanich Inlet anoxic seawater. Data on the concentration of these
trace metals and H2S, and other oceanographic parameters were obtained in four cruises.
Equilibrium models are presented together with in situ data. The results strongly support the assumption that the solubilities
of Cu, Zn, Cd, Fe, Co and Ni are controlled by bisulfide and/or polysulfide complexes. The species of Cu, Zn, Cd and Ni are
shown to be Cu(S4)
2
3−
and Cu(Sn4S5)3−, Zn(HS)
2
0
and ZnHS
2
−
, Cd(HS)
2
0
and Ni(HS)
2
0
, respectively. The solid species controlling Fe2+ and Co2+ are respectively the pyrohotites FeS and CoS. The data illustrates that thermodynamic equilibrium has been established in
the H2S-controlled seawater of Saanich Inlet, and that equilibrium has not been established in the H2S−O2-coexisted seawater of Saanich Inlet. The lack of equilibrium in the H2S−O2-coexisted seawater is a result of the flushing or mixing of oxygenated seawater with anoxic water. The new species of trace
metals are still in the processes of reduction and precipitation.
Contribution No. 1428 from Institute of Oceanology, Academia Sinica 相似文献
2.
DISTRIBUTION OF DISSOLVED AND PARTICULATE TRACE METALS IN ANOXIC SEAWATER, SAANICH INLET, B . C. CANADA 总被引：2，自引：0，他引：2
This paper discusses the spatial and seasonal distribution character of dissolved and paniculate trace metals in the anoxic seawater of Saanich Inlet, B.C., Canada. The study showed that concentration of dissolved and paniculate trace metals in anoxic seawater is closely related to (1) the concentration of H2S and the depth of the O2-H2S interface, (2) the exchange of seawater in Saanich Inlet with outside seawater, (3) biotic action, and (4) the flushing event. The study was based in part on the ratio between trace metals and nutrients. There was a steep change in the concentration of dissolved trace metals at the O2-H2S interface. The concentration of dissolved trace metals in the H2S-controlled zone was dependent on the H2S there. The suspended matter in Saanich Inlet comes from the Hero Strait seawater, phytoplankton production and resuspension of flushed-up sediments. The concentration of particulate trace metals was rather low in Saanich Inlet and tended to increase with depth. The total concentra 相似文献
3.
The sea fluxes of trace metals, POC, and settled material were studied in anoxic seawater, Saanich Inlet, B. C., Canada with
sediment traps. This paper discusses the change of mass fluxes of sediment, trace metals and POC for various seasons and depths.
The annual mean of settled material is 1.56 g.m−2.a−1, 84.6 mg. m−2.a−1 for POC, 60.0 mg. m−2.a−1 for Cu, 16.5 mg.m−2.a−1 for Pb, 189 mg.m−2.a−1 for Zn, 2.20 mg.m−2.a−1 for Cd, 699 mg.m−2.a−1 for Fe, 38.8 mg.m−2.a−1 for Co, and 84.6 mg.m−2.a−1 for Ni. The relations between the average fluxes of trace metals and POC, the fluxes of trace metals and settled matter,
and the sea fluxes of trace metals and Fe are in linear progression. The resident times of elements as calculated from sea
flux, are 1.1 a. for Cu, 0.014 a. for Pb, 0.50 a. for Zn, 3.8 a. for Cd, 0.16 a. for Fe, 0.39 a. for Co, and 1.14 a. for Ni.
The order of resident times is as follows: Pb−Fe−Co−Zn−Cu−Ni−Cd. The metal resident times in Saanich Inlet are shorter than
the values estimated for the open ocean. It illustrates that the biochemical processes in shallow Saanich Inlet are faster
than those in the open ocean, and that debries of plankton and fecal pellets of zooplankton play an important role in vertical
transport of organic carbons.
Contribution No. 1650 from the Institute of Oceanology, Academia Sinica. 相似文献
4.
^234Th-^238U disequilibria were applied to examine the particle dynamics in the euphotic zone of the central South China Sea during the spring 2002 cruise. The particulate organic carbon （POC）, ^234Th （including both dissolved and particulate） and ^238U in the water column at three stations were determined. The profiles of ^234Th/^238U activity ratio at the three stations all showed consistent ^234Th deficit as compared to ^238U in the upper 100 m water column. Based on the profiles of the dissolved and particulate ^234Th and a steady state box model, the dissolved ^234Th scavenging rates, the particulate ^234Th removal rates and their resident times were quantified. It was found that the POC downward export fluxes out of the upper 100 m euphotic zone ranged from 9.40 to 14.78 mmol·m^-2·d^-1. The results from this study provide new information for our understanding of carbon biogeochemical cycle in the South China Sea. 相似文献
5.
Stormwater runoff in rural townships has a high potential for water quality impairment but little information is available on strormwater runoff pollution from rural townships.To investigate the characteristics of runoff pollution in a rural township,a catchment(2.32 ha) in Linshan Township,Sichuan,China was selected to examine runoff and quality parameters including precipitation,flow rate,and total nitrogen(TN),dissolved nitrogen(DN),total phosphorus(TP),dissolved phosphorus(DP),particulate phosphorus(PP),chemical oxygen demand(COD) and suspended solid(SS) in 12 rainfall events occurring between June 2006 and July 2007.Results show that the annual pollutant loads were 47.17 kg ha-1 for TN,6.64 kg ha-1 for TP,1186 kg ha-1 for COD,and 4297 kg ha-1 for SS.DN and PP were the main forms of nitrogen and phosphorus in stormwater runoff.TP,COD and SS showed medium mass first flushes,in which nearly 40% of the total pollutant masses were transported by the first 30% of total flow volume.The peak of pollutant concentration appeared before the peak of runoff due to the first flush of accumulative pollutants in impervious areas and drainage ditches.The EMC values of TN,TP,DN and PP were negatively correlated to the maximum rainfall intensity,precipitation,total flow volume,and runoff duration(P<0.05,n=12),while EMC of COD and SS were not related to any rainfall characteristics.The FF30(FF,First Flush) for TN,TP,COD and SS were positively correlated to the maximum rainfall intensity(P<0.05,n=12),and TP was also positively correlated to the average rainfall intensity(P<0.05,n=12),indicating that the magnitude of first flush increased with the rainfall intensity in the Linshan Township. 相似文献
6.
mODUCTIONTheislandsOfHaitan,Yuo,Dalian,DowiangandCaoguinPingtanCoUntyofFu-jianProvincearetogetherthewhtoasPingtan(25'l5'-25o45'E,l19"32'-12o"lo'N,EaStChinaSea).AmngthemHaitangIslanisthedrinoneinPingtanCotmty,andthelargestinFuianProvince.RngtanhaSanatuIalfishinggroUn(SeduMOUntaln)beingrenownedboghoutthecOUnnyandawelldeVfoPedaqUacultUreindusny.Pingtanwa-tersresotirceswerestirveyedforthefirsttimebytheauthorssothattheknowedgegainedcanbeaPPliedforbettereaploitahon,PIDechon,andde… 相似文献
7.
A dynamic box model was applied to study the characteristics of biogeochemical cycling of PO_4-P,NO_3-N,AOU,POC and PON in the southern Taiwan Strait region based on field data of the"Minnan Taiwan Bank Fishing Ground Upwelling Ecosystem Study" during the period of Dec.1987-Nov.1988.According to the unique hydrological and topographical features of the region,six boxesand three layers were considered in the model.The variation rates and fluxes of elements induced by hor-izontal current,upwelling,by diffusion,sinking of particles and biogeochemical processes were estimatedrespectively.Results further confirmed that upwellings had important effects in this region.Thenearshore upwelling areas had net input fluxes of nutrients brought by upwelling water,also had high de-pletion rates of nutrients and production rates of particulate organic matter and dissolved oxygen.Theabnormal net production of nutrients in the middle layer(10-30m) indicated the important role of bacte-ria in this high production region.Th 相似文献
8.
Taking South Lake and Jingyue Pool in Changchun as examples,we determined particulate Hg in ambient air and Hg concentration in precipitation.Results indicated that particulate Hg in air and Hg concentration in precipita-tion in both sites in nonheating period were lower than that in heating period,which is influenced by coal combustion.The annual particulate Hg concentrations in precipitation were 0.268μg/L(South Lake)and 0.108μg/L(Jingyue Pool).The high-er particulate Hg concentrations in precipitation were 0.268μg/L(South Lake) and 0.108μg/L(Jingyue Pool).The high-er particulate Hg concentration in air and Hg concentration in precipitation in South Lake than that of Jingyue Pool indicat-ed that mercury deposition was influenced by anthropogenic sources(especially from coas combustion).Hg concentration in precipitation is related with particulate Hg in the atmosphere.Dry deposition fluxes were estimated by using dry deposi-tion model on the base of particulate Hg concentrations in the atmosphere,they were estimated by using dry deposi-tion model on the base of particulate Hg concentrations in the atmosphere,they were 35.5μg/(m^2.a) for South lake and 15.3μg/(m^2.a)for Jingyue Pool.Combined with precipitation amount,wet deposition fluxes were estimated in these two sites,152.2μg(m^2.a)for South Lake and 61.2μg/(m^2.a)for Jingyue Pool.Atmospheric Hg deposition fluxes were 160.2g/a for South Lake and 328.62g/a for Jingyue Pool.e 相似文献
9.
Biofouling is an important factor that affects the bivalve farming industry. Fouling organisms may reduce growth and survival rate of the cultured species. Fouler are often filter feeders, so they are potential competitors for food resource with the cultured species. The present study was conducted to measure the impact of fouling on food uptake and nutrient release in April and June, 2006 in Daya Bay near Guangzhou, China. Results showed that fouling organisms had significant effect on food uptake and nutrient release. The chlorophyll a uptake rate of fouled scallops was 7.53Lh-1±1.416Lh-1 and 11.94Lh-1±2.497Lh-1 in April and June, respectively, significantly higher than those of cleaned scallops, i.e., 4.23 Lh-1 ±2.744Lh-1 and 2.57Lh-1± 1.832 Lh-1 respectively.The consumption of total particulate matter by fouled scallops in April and June was 5.52Lh-1±0.818Lh-1 and 3.07Lh-1±0.971 Lh-1,respectively; the corresponding results for cleaned scallops are 2.49Lh-1 ±0.614Lh-1 and 2.37± 1.214Lh-1, respectively. Fouling increased ammonia release significantly. The ammonia release rate of fouled scallops was 33.81Lh-1±7.699Lh-1 and 76.39Lh-1 ±9.251Lh-1 in April and June, while cleaned scallops released 2.46Lh-1± 0.5 1 1Lh-1 and 7.23Lh-1± 1.026Lh-1 ammonia, respectively. Phosphate release of fouled scallops was 22.72Lh-1 ± 9.978 Lh-1 in June and cleaned scallops released phosphate 6.01Lh-1 ±0.876 Lh-1 in April. Therefore, fouling contributed much to food reduction and concentration increase of ammonia and phosphate in water. 相似文献
10.
Trare amounts of benzene hydrocarbons obtained in Jiaozhou Bay (Qindao) were enriched bysorption on a GDX-102 column and eluted by carbon disulfide. The eluted was concenttaled and then de-temened by capillary column gas cbornatognphy.The contents of virious kinds of benzene hydrocarbons in Jiaozhou Bay coastal water were benzene(22.3-141.6)× 10～(-9)g/L, toluate (15.2-94.0) × 10~(-9) g/L, ethyl benzene(11.8-85.1)×10~(-9) g/L, p -xylene(15.2-78.5) ×10(-9) g/L, m-xylene (10.9-79.4) ×10(-9) g/L, o -xylene (12.4-80.1) x ×10(-9)g/L; iso-propyl(8.4- 73.1) x ×10(-9)g/L, n -propyl (6.9-76.4) ×10(-9) g/L, 1, 3, 5-trimethylbenzene (10.9- 35.9)×10(-9) g/L, 1,2, 4-trimethybenzene (10.0- 38.0)×10(-9) g/L, n - butydriare (8. 1 - 34.6) ×10(-9)g/L. The recovery of benzenehydrocarbons was (85.1 -95.6)%. 相似文献
11.
Sample seawater containing trace methyl mercury was acidified and adsorbed on hydrosulfo-cotton, washed with hydrochloric
acid, extracted by benzene and dried, and then determined by a gas chromatograph with electron capture detector. This method,
which can detect a minimum concentration of 0.1×10−10%, can be used to monitor the 10−10% content of methyl mercury in seawater. 相似文献
12.
J. Sesh Serebiah M. Rajkumar B. A. Venmathi Maran A.Saravanakumar G. A. Thivakaran 《中国海洋大学学报(英文版)》2011,10(2):153-156
The Gulf of Kachchh in western India, with its arid climate, large semi-diurnal tidal amplitudes, negative water balance and
near-pristine water quality, is being extensively developed as oil importing bases for economic reasons in connection with
its proximity to the oil exporting countries of the Middle East. Besides, new coral rubbings were sighted in Jakhau, north-western
Gulf of Kachchh. Dredging in Mandvi of the north Gulf covering 3.5 km2 revealed a similar assortment of live corals with their associated flora and fauna. These pioneering observations demonstrate
that there exist live corals of young polyps-colony of Favia sp. belonging to the family Faviidae in the north-western Gulf of Kachchh. The environmental parameters there were carefully
recorded as: surface water temperature (°C) varying from 29 to 31.8, salinity (ppt), pH, dissolved oxygen (mgL−1) and total suspended solids (mgL−1) in the ranges of 37–43.5, 7.7–8.45, 5.4–6.8 and 11–31, respectively. 相似文献
13.
ＤｕｒｉｎｇｔｈｅｔｈｒｅｅＭｔ．ＱｏｍｏｌａｎｇｍａＥｘｐｅｄｉｔｉｏｎｓｏｆ１９５９－１９６０，１９６６－１９６８ａｎｄ１９７５，ＣｈｉｎｅｓｅｓｃｉｅｎｔｉｓｔｓｈａｄｏｂｔａｉｎｅｄｍａｎｙｄａｔａｏｆｇｌａｃｉｅｒｓｉｎｔｈｅｄｉｓｔｒｉｃｔｏｆＭｔ．Ｑｏｍｏｌａｎｇｍａ（Ｗａｎｇｅｔａｌ．，１９８０；Ｘｉｅｅｔａｌ．，１９７５；Ｚｈａｎｇｅｔａｌ．，１９７５）．ＩｎＭａｙ１９９７，Ｐｒｏｆ．ＱｉｎＤａｈｅａｎｄＰｒｏｆ．ＰａｕｌＡ．Ｍａｙｅｗｓｋｉｏｒｇａｎｉｚｅｄａｎｏｔｈｅ… 相似文献
14.
A dynamic experiment for oil dispersion into a water column was performed with a 21 m long, 0.5 m wide, and 1 m high wind-driven
wave tank. At wind velocity between 6–12 m/s and with the oil slick kept constant (about 1 μm), the rate of the oil content
increase in the water column could be approximated from the difference between the dispersion rate (R) of the oil slick and the coagulation rate (R′) of the dispersed oil slick. Assuming the coagulation rate is directly proportional to the concentration of the water dispersed
oil slick (i. e.R′-K
*C), the integral form of the dynamic model can be expressed asC=R
* [1−exp(−K
*t)]/K and parametersR andK can be regressed with a computer. The relative deviation of model results from the experimental data was mainly less than
10%. The oil slick dispersion rate (R) had exponential relationship with the wind velocity (U), and can be fitted with a formulaR=A
* (U+1)
B
. The fitted constant of the coagulation rate,K(0.8–3.0* 10−3 min−1) did not have significant relationship with the wind velocity. 相似文献
15.
Distributions of inorganic nutrients in the bohai sea of china 总被引：2，自引：0，他引：2
LI Zhengyan * BAI Jie SHI Jinhui GAO Huiwang College of Environmental Science Engineering Ocean University of China Qingdao P..R.China 《中国海洋大学学报(英文版)》2003,2(1):112-116
1 Introduction TheBohaiSeaislocatedinthenorthernChinawithlongitudesofbetween 117°38′Eand 12 2°31′Eandlat itudesofbetween 37°0 8′Nand 4 1°0 2′N .Itisashal lowseawithanaveragewaterdepthof 18m (LiuandZhang ,2 0 0 0 ) .Severalbigrivers ,suchastheLiaoheRiver,theHaiheRiverandtheYellowRiver ,findtheirwaysintotheBohaiSeaandtransportlargeamountofnutrientsandsuspendedmattersfromthecontinentintothesea (Zhangetal.,1994 ;Zhang ,1996 ) .Duringthelasttwodecades ,marineenviron mentintheBohai… 相似文献
16.
Dual filtration effect of geochemical and biogeochemical processes in the Changjiang Estuary 总被引：2，自引：0，他引：2
Dissolved nutrients (NO
3
−
, PO4
3−, SiO3
2−) and oxygen, chlorophyll- a, pH, and Eh were measured on board during a cruise in August 1988 in the Changjiang Estuary region.
Heavy metals, organic matter and carbonate contents were analyzed in laboratory. The results show that geochemical processes
in the Changjiang Estuary have dual filtration effect: on the one hand geochemical filtration effect, reflected by ferromanganese
oxide flocculation and sedimentation, occurs near the turbidity maximum, and leads to enrichment of heavy metals in suspended
matter and sediments; on the other hand biogeochemical filtration, reflected by nutrients consumption, organic matter and
carbonate sedimentation and enrichment of trace elements in suspended matter, occurs outside the plume water front. The biogeochemical
filtration affects the environmental conditions; the dissolved oxygen and pH increase, in surface water and decrease in bottom
water. The biogeochemical filtration effect outside the plume front is more important than the geochemical filtration effect
near the turbidity maximum. 相似文献
17.
Hamadoun BOKAR 《中国地理科学(英文版)》2004,14(1):63-70
1INTRODUCTIONGroundwater in Changchun City assures about 45% of total water supply. Drinking water supply of Chang-chun City was mostly served by surface water from Shitoukoumen and Xinlicheng reservoirs located in the east and south of the city (ZHANG, 1993). However, with the development of urban construction the ground-water especially from deep boreholes is also used for drinking purpose in suburban areas. The urbanization process in Changchun City threatens the groundwater quali… 相似文献
18.
The process-oriented model Forest-DNDC describing biogeochemical cycling of C and N and GHGs （greenhouse gases） fluxes （CO2, NO and N2O） in forest ecosystems was applied to simulate carbon sequestration and GHGs emissions in Abies fabric forest of the Gongga Mountains at southeastern edge of the Tibetan Plateau. The results indicated that the simulated gross primary production （GPP） of Abies fabric forest was strongly affected by temperature. The annual total GPP was 24,245.3 kg C ha^-1 yr^-1 for 2005 and 26,318.8 kg C ha^-1 yr^-1 for 2006, respectively. The annual total net primary production （NPP） was 5,935.5 and 4,882.2 kg C ha^-1 yr^-1 for 2005 and 2006, and the annual total net ecosystem production （NEP） was 4,815.4 and 3,512.8 kg C ha^-1 yr^-1 for 2005 and 2006, respectively. The simulated seasonal variation in CO2 emissions generally followed the seasonal variations in temperature and precipitation. The annual total CO2 emissions were 3,109.0 and 4,821.0 kg C ha^-1 yr^-1 for 2005 and 2006, the simulated annual total N2O emissions from forest soil were 1.47 and 1.36 kg N ha^-1 yr^-1 for 2005 and 2006, and the annual total NO emissions were 0.09 and o.12 kg N ha^-1 yr^-1 for 2005 and 2006, respectively. 相似文献
19.
CHEMICAL CHARACTERISTICS OF WATER ENVIRONMENT IN LIMNIC WETLANDS IN THE WESTERN SONGNEN PLAIN, CHINA 总被引：1，自引：1，他引：0
Duetoregionalhydrogeologicandclimaticconditions,inthewesternSongnenPlain,themostdistinctcharacteristicofwaterenvironmentinlimnicwetlandsisthatmanywaterbodieshavehighsaltcontentsandpHvalues,andsomelimnicwetlandsbelongtosaltmarshes.Thelimnicwetlandsofthisregionarespecialnaturecomplex.Itisimportantfortheutilizationofwetlandresourcesandtheintegrateddevelopmentofsaline-alkalinesoiltostudychemicalcharacteristicsofwaterenvironmentinthisregion.1NATURALENVIRONMENTCHARACTERISTICSOFTHEWE… 相似文献
20.
The correlation between water quality parameters and hyper-spectral reflectance is studied with models established for each parameter and applied in Dianshan Lake, in the upstream of the Huangpu River running through Shanghai, China. Models are for dissolved oxygen (DO in mg/L): R720/R680 = 20.362×(R720/R680)2-31.438×(R720/R680)+19.156; for turbidity (NTU): R*714.5 = 206.07× (R*714.5)2-582.5×R*714.5 + 423.24; and for total phosphorus (TP in mg/L): R*509.5 = 16.661× (R*509.5)2-32.646×R*509.5+16.116. The R2 values are 0.770 8, 0.660 4 and 0.738 7, respectively, showing strong positive relationships. The models were then applied to assess water quality of different times. Results are quite satisfactory for some samples. 相似文献