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1.
Rock magnetic studies of three loess-palaeosol sections from Bulgaria (Harletz and Orsoja in the NW and Durankulak in the NE at the Black Sea coast) have been carried out. Thermomagnetic analyses of magnetic susceptibility point to magnetite as the major ferrimagnetic carrier in the loess and palaeosol units. Maghemite gives a significant contribution to the total magnetic signal in the recent soils (S0), while in one of the sections-Orsoja-hematite may also be present. The effective magnetic grain sizes deduced from the hysteresis measurements and the ratios Mrs/Ms and Bcr/Bc fall in the pseudo single domain (PSD) range, but the data distributions in a Day diagram for the three different sections are shifted. This is suggested to be caused by different detrital input (e.g. different dust source areas) and varying degrees of pedogenic modification. The calculated background susceptibilities χbg differ significantly as well. The lowest value is obtained for the Durankulak section-χbg = 9.95 × 10−8 m3/kg, which is in accordance with the data from other studies of loess-palaeosol profiles from the Black Sea area. The corresponding background susceptibilities for the other two sections studied-Harletz and Orsoja-are significantly higher (33.1 and 17.75 × 10−8 m3/kg, respectively). Both parent material and pedogenesis are found to be responsible for the observed differences in the magnetic characteristics.  相似文献   

2.
High-resolution sampling, measurements of organic carbon contents and 14C signatures of selected four soil profiles in the Haibei Station situated on the northeast Tibetan Plateau, and application of 14C tracing technology were conducted in an attempt to investigate the turnover times of soil organic carbon and the soil-CO2 flux in the alpine meadow ecosystem. The results show that the organic carbon stored in the soils varies from 22.12×104 kg C hm−2 to 30.75×104 kg C hm−2 in the alpine meadow ecosystems, with an average of 26.86×104 kg C hm−2. Turnover times of organic carbon pools increase with depth from 45 a to 73 a in the surface soil horizon to hundreds of years or millennia or even longer at the deep soil horizons in the alpine meadow ecosystems. The soil-CO2 flux ranges from 103.24 g C m−2 a−1 to 254.93 gC m−2 a−1, with an average of 191.23 g C m−2 a−1. The CO2 efflux produced from microbial decomposition of organic matter varies from 73.3 g C m−2 a−1 to 181 g C m−2 a−1. More than 30% of total soil organic carbon resides in the active carbon pool and 72.8%281.23% of total CO2 emitted from organic matter decomposition results from the topsoil horizon (from 0 cm to 10 cm) for the Kobresia meadow. Responding to global warming, the storage, volume of flow and fate of the soil organic carbon in the alpine meadow ecosystem of the Tibetan Plateau will be changed, which needs further research. Supported by the National Natural Science Foundation of China (Grant Nos. 40231015, 40471120 and 40473002) and the Guangdong Provincial Natural Science Foundation of China (Grant No. 06300102)  相似文献   

3.
The long-term variations in the second degree sectorial Stokes parameters of the geopotential have been determined from TOPEX-POSEIDON (T/P) satellite altimeter data, covering the period of January 1, 1993 to January 3, 2001 (T/P cycles 11-305). It is the first attempt to determine the variations in the second sectorial harmonics in the Earth’s inertia tensor due to the ocean dynamics. The variations amount to about 1 × 10−10 (J 2 (2) ≈ 1.6 × 10−6 and S 2 (2) ≈ −0.9 × 10−6). The variations are about 5% of the tidal effect. This corresponds to variations in the directions of the equatorial axes of the Earth’s inertia ellipsoid of up to 10 arc-seconds. Consequently, the annual and semi-annual variations of the Earth’s equatorial flattening is about 10−9; i.e. it corresponds to a change of 8 units of its denominator of 91 030. (The equatorial flattening ≈ 1/91 030). Since the coverage of the Earth’s ocean surface is not worldwide, and the inclination of T/P is i = 66°, it is only 58.2% (min. depth of the ocean 2 000 m) of the Earth’s surface which is processed, the torque, resulting from the seasonal transfer of masses within a sea surface layer, is not zero. It amounts up to 1016 kg m2s−2, which is comparable to the total indirect tidal torque due to the Moon and the Sun, ∼ 3.9 × 1016 kg m2s−2. However, the above estimate strongly depends on the adopted thickness of the sea surface layer, ΔR = 50 m. For a larger thickness of ΔR = 100 m, the seasonal torque amounts to about ∼ 2.3 × 1016 kg m2s−2.  相似文献   

4.
The Starunia oil-ozokerite deposit occurs in the Boryslav-Pokuttya Unit of the Carpathian Foredeep, which is the main oil- and gas-bearing part of the Ukrainian Carpathians. Starunia is of great interest in studying the relationship between the magnetic properties of rocks, soils and hydrocarbons due to extensive surface microseeps yielding oil and gas, mineral water, and clay pulp containing hydrocarbons. We identified a local negative magnetic anomaly (30–35 nT) with a width of about 700 m within the MAG1 profile. The magnetic high is associated with the area of the largest mud volcanoes in the Starunia structure. Magnetic susceptibility of the soil was measured on a site with three distinct landscape features: a patch of forest with phaeozem and mass-specific susceptibility (χ) of 20–45 × 10?8 m3/kg for the surface topsoil; an area near the volcano and Nadia-1 well with visible hydrocarbon microseepage at the surface and the topsoil showing no visible evidence of hydrocarbon presence with χ = 20–50 × 10?8 m3/kg; and a patch of lowland with gleysols and χ = 10–20 × 10?8 m3/kg. Hydrocarbon-containing clays and soils from the alluvial sediments of the Velyky Lukavets River and bedrock clays near the Nadia-1 well demonstrated high χ values (up to 250–440 × 10?8 m3/kg).  相似文献   

5.
According to variations of 137Cs and clay contents, 44 flood couplets were identified in a profile of reservoir deposit with a vertical length of 28.12 m in the Yuntaishan Gully. Couplet 27 at the middle of the profile had the highest average 137Cs content of 12.65 Bq kg-1, which indicated the 1963s' deposits, then 137Cs content decreased both downward and upward in the profile. The second top and bottom couplets had average 137Cs contents of 2.15 Bq kg-1 and 0.92 Bq kg-1, respectively. By integrated analysis of reservoir construction and management history, variations of 137Cs contents over the profile, sediment yields of flood couplets and rainfall data during the period of 1958-1970, individual storms related to the flood couplets were identified. 44 floods with a total sediment yield of 2.36×104 m3 occurred and flood events in a year varied between 1 and 10 times during the period of 1960-1970. 7-10 flood events occurred during the wet period of 1961-1964 with very wet autumn, while only 1-2 events during the dry period of 1965-1969. Average annual specific sediment yield was 1.29×104 t km-2 a-1 for the Yuntaishan Gully during the period of 1960-1970, which was slightly higher than 1.11 ×104 t km-2 a-1 for the Upper Yanhe River Basin above the Ganguyi Hydrological Station and slightly lower than 1.40 ×104 t km-2 a-1 for the nearby Zhifang Gully during the same period. Annual specific sediment yields for the Yuntaishan Gully were correlated to the wet season's rainfalls well.  相似文献   

6.
The seasonal and interannual variability in the phytoplankton community in Liverpool Bay between 2003 and 2009 has been examined using results from high frequency, in situ measurements combined with discrete samples collected at one location in the bay. The spring phytoplankton bloom (up to 29.4 mg chlorophyll m−3) is an annual feature at the study site and its timing may vary by up to 50 days between years. The variability in the underwater light climate and turbulent mixing are identified as key factors controlling the timing of phytoplankton blooms. Modelled average annual gross and net production are estimated to be 223 and 56 g C m−2 year−1, respectively. Light microscope counts showed that the phytoplankton community is dominated by diatoms, with dinoflagellates appearing annually for short periods of time between July and October. The zooplankton community at the study site is dominated by copepods and use of a fine mesh (80 μm) resulted in higher abundances of copepods determined (up to 2.5 × 106 ind. m−2) than has previously reported for this location. There is a strong seasonal cycle in copepod biomass and copepods greater than 270 μm contribute less than 10% of the total biomass. Seasonal trends in copepod biomass lag those in the phytoplankton community with a delay of 3 to 4 months between the maximum phytoplankton biomass and the maximum copepod biomass. Grazing by copepods exceeds net primary production at the site and indicates that an additional advective supply of carbon is required to support the copepod community.  相似文献   

7.
Geochemical study of boron isotopes in the process of loess weathering   总被引:1,自引:0,他引:1  
Different types of sedimentary rocks and magmatic rocks show significant variations in their boron isotopic composition, with d 11B values usually within the range of -40? 30塠1]. The boron content of the continental crust is approximately 10?0-6, with …  相似文献   

8.
The sorption of Eu species onto nano-size silica-water interfaces is investigated at pH range of 1―8.5 and the initial Eu concentrations (CEu) of 2×10−5, 2×10−4 and 2×10−3 M using fluorescence spectroscopy. The sorption rate of Eu is initially low, but significantly increases at pH > 4. For the initial CEu of 2×10−5, 2×10−4 and 2×10−3 M, the dissolved Eu species are completely sorbed onto silica-water interfaces at pH = 4.75, −5.8 and 6.6, respectively, with the respective sorption densities of −1.58×10−8, 1.58×10−7 and 1.58×10−6 mol/m2. The sorbed Eu species at pH < 6 is aquo Eu3+, which is sorbed onto silica-water interfaces as an outer-sphere complex at pH < 5, but may be sorbed as an inner-sphere bidentate complex at 5 < pH < 6, due to the decrease of the NH2O to −6 at pH = 6. At pH = 6 – 8, Eu(OH)2+, Eu(CO3)+and Eu(CO3)2 form in the solutions, and Eu(CO3)+is dominant at pH = −7.5. These ions may be sorbed onto silica-water interfaces as inner-sphere bidentate complexes or multi-nuclear pre-cipitates.  相似文献   

9.
《Geofísica Internacional》2014,53(4):411-423
An investigation of the effect of some human activities on the magnetic susceptibility and frequency dependent susceptibility was conducted on top soil samples from, a commercial area, a motor park and a school environment in Jalingo, Taraba State, N-E Nigeria. The purpose was to assess the variation of magnetic susceptibility with different land use, detect pollution hotspots using magnetic proxy parameters and evaluate the contribution of superparamagnetic (SP) grain size contribution to the magnetic susceptibility from calculation of the frequency dependence of magnetic susceptibility (MS). The results of the mass specific low frequency magnetic susceptibility measurements showed significant enhancement with values ranging from 67.8  495.3 × 10−8 m3kg−1 with a mean value of 191.61 × 10−8 × m3kg−1 for the Jalingo College of Education (JCOE) data; 520.1  1612.8 × 10−8 m3kg−1 with a mean value of 901.34 × 10−8 m3kg−1 for the Jalingo main Market (JMM) and 188.5  1203.6 × 10−8m3kg−1 with an average value of 574 92 × 10−6 m3kg−1 for the Jalingo Motor Park (JMP). The significant magnetic enhancement indicates high concentration of ferrimagnetic minerals in the soil and hence increased pollution. The magnetic susceptibility of the different land use studied decreased in the order commercial area (market) > motor park > school premises. The results of the percentage frequency dependence susceptibility showed that most of the samples had a mixture of SP and coarse multi domain grains or SP grains < 0.05 µm. The value of χfd% range from 2.68 to 13.80% with an average value of 8.67% in the JCOE samples, 0.49 to 10.04% with an a-verage of 5.05% in the JMM samples and 0.56 to 13.04% with an average value of 5.86% in the JMP samples.  相似文献   

10.
Decompression experiments of a crystal-free rhyolitic liquid with ≈ 6.6 wt. % H2O were carried out at a pressure range from 250 MPa to 30–75 MPa in order to characterize effects of magma ascent rate and temperature on bubble nucleation kinetics, especially on the bubble number density (BND, the number of bubbles produced per unit volume of liquid). A first series of experiments at 800°C and fast decompression rates (10–90 MPa/s) produced huge BNDs (≈ 2 × 1014 m−3 at 10 MPa/s ; ≈ 2 × 1015 m−3 at 90 MPa/s), comparable to those in natural silicic pumices from Plinian eruptions (1015–1016 m−3). A second series of experiments at 700°C and 1 MPa/s produced BNDs (≈ 9×1012 m−3) close to those observed at 800°C and 1 MPa/s (≈ 6 × 1012 m−3), showing that temperature has an insignificant effect on BNDs at a given decompression rate. Our study strengthens the theory that the BNDs are good markers of the decompression rate of magmas in volcanic conduits, irrespective of temperature. Huge number densities of small bubbles in natural silicic pumices from Plinian eruptions imply that a major nucleation event occurs just below the fragmentation level, at which the decompression rate of ascending magmas is a maximum (≥ 1 MPa/s).  相似文献   

11.
The enhanced magnetic susceptibility of modern soils is assumed to have several reasons including, e.g., weathering of an iron-rich geological basement, natural fires, bacterial processes and atmospheric deposition of anthropogenic particles. We report on a case where none of the above sources of magnetic enhancement is evident: a modern soil with high magnetic susceptibility over the whole soil profile, developed on nonmagnetic limestones, in an area with no industrial activities. The surface magnetic susceptibility varies from 60 to 110×10−5 SI, while that of the rock basement is nearly zero. Moreover, significant frequency-dependent magnetic susceptibility (> 12%) suggests that superparamagnetic secondary magnetite/maghemite plays an important role. Possible mechanisms, responsible for this magnetic enhancement, are discussed.  相似文献   

12.
The KLY-4S Kappabridge and KLF-4A Magnetic Susceptibility Meter enable automated measurement of susceptibility variation with field in the ranges of 2–450 A/m and 5–300 A/m (in effective values), respectively. Unfortunately, the measurement accuracy decreases with decreasing field and it is not easy to decide whether the susceptibility variation at the lowest fields is natural phenomenon or results from measuring errors. To overcome this problem, the accuracies of both the above instruments were investigated experimentally using artificial specimens (mixture of pure magnetite and plaster of Paris) with variable susceptibilities ranging from 1 × 10−5 to 5 × 10−2. The complete curve of the field variation of susceptibility of each specimen was measured 10 times and the relative error was calculated for each field. In the KLY-4S Kappabridge, in specimens with susceptibilities higher than 100 × 10−6, the relative errors are lower than 3% in all fields and lower than 1% in the fields stronger than 10 A/m. In the KLF-4A Magnetic Susceptibility Meter, in relatively strongly magnetic specimens with susceptibilities 5 × 10−4 to 5 × 10−2, the relative error is less than 1.5% in the entire field range. While the former instrument is convenient for investigating almost all rock types, the latter instrument is convenient for measuring moderately and strongly magnetic specimens. To facilitate work with field variation of susceptibility curves, showing variable accuracies with field, the programme FieldVar was written. One of its options is plotting the measured data with corresponding field-variable error bars. In this way, a tool is offered for interpreting such susceptibility changes that are sound and reasonable from the point of view of measuring accuracy.  相似文献   

13.
Tonalites from the island arc rock assemblage in the Zêtang segment of the Yarlung Zangbo suture zone were analyzed for major, trace elements (including REE) and Sr-Nd isotope. The experimental datademonstrate that the tonalites have the adakite-like characteristics, including high SiO2 (58%-63%),Al2O3 (18.4%-22.4%), Sr (810×10-6-940×10-6), Sr/Y (77-106), low HREE (Y=9×10-6-11×10-6, Yb=1×10-6-1.3×10-6), with LREE enrichment and faint Eu positive anomaly. Isr (0.70421-0.70487) is relatively low whereas 143Nd/144Nd (0.512896-0.512929) and εNd(t) values ( 6.7- 7.3) are high. These feainvolvement of a small amount of oceanic sediments. The identification of Z(e)tang adakites, derived from slab melting, presents new evidence for the intra-Tethyan subduction and the previous suggestion about the existence of intra-oceanic island arc within Tethys.  相似文献   

14.
云南程海浮游植物初级生产力的时空变化及其影响因子   总被引:1,自引:0,他引:1  
2016年4月-2017年2月,采用黑白瓶法研究了云南程海单点(码头点位)浮游植物初级生产力的垂直分布及其季节变化,同时基于全湖9个点位的现场调查和生产力垂向归纳模型(VGPM)估算并探讨了程海浮游植物初级生产力的时空变化及其主要影响因子.结果显示,码头点位的年均(均值±标准误)水柱(0~3 m)总初级生产力(GPPC)、净初级生产力(NPPC)和呼吸消耗量(RC)分别为5.40×103±0.64×103、2.36×103±0.63×103和3.06×103±0.82×103 mg O2/(m2·d);不论春夏季(4-8月)、秋冬季(9月-次年2月)还是全年,码头点位的单位生物量GPP(GPP/Chl.a)和单位生物量NPP(NPP/Chl.a)的最大值和最小值均分别出现在水下0.5 m和3.0 m处.经VPGM估算,程海全湖的初级生产力(PPeu)年均值为6.54×103±0.30×103 mg C/(m2·d)(2.74×103~18.62×103 mg C/(m2·d)).PPeu的时空变化方面,春夏季是PPeu快速上升的时节,秋冬季PPeu的月变化则呈波动状态,春夏季与秋冬季PPeu无显著性差异;PPeu整体空间异质性较弱,仅在降水最为充沛的7、8月表现出南北向的异质性,这与降水条件和流域营养盐输入的空间异质性有关.回归分析发现,虽然程海PPeu的主要影响因子具有季节异质性,但不论春夏季、秋冬季还是全年,浮游植物生物量均是重要的影响因子,水温亦是春夏季的重要影响因子.  相似文献   

15.
Forward-Looking Infrared (FLIR) nighttime thermal images were used to extract the thermal and morphological properties for the surface of a blocky-to-rubbley lava mass active within the summit crater of the Caliente vent at Santiaguito lava dome (Guatemala). Thermally the crater was characterized by three concentric regions: a hot outer annulus of loose fine material at 150–400°C, an inner cold annulus of blocky lava at 40–80°C, and a warm central core at 100–200°C comprising younger, hotter lava. Intermittent explosions resulted in thermal renewal of some surfaces, mostly across the outer annulus where loose, fine, fill material was ejected to expose hotter, underlying, material. Surface heat flux densities (radiative + free convection) were dominated by losses from the outer annulus (0.3–1.5 × 104  s−1m−2), followed by the hot central core (0.1–0.4 × 104 J s−1m−2) and cold annulus (0.04–0.1 × 104 J s−1m−2). Overall surface power output was also dominated by the outer annulus region (31–176 MJ s−1), but the cold annulus contributed equal power (2.41–7.07 MJ s−1) as the hot central core (2.68–6.92 MJ s−1) due to its greater area. Cooled surfaces (i.e. the upper thermal boundary layer separating surface temperatures from underlying material at magmatic temperatures) across the central core and cold annulus had estimated thicknesses, based on simple conductive model, of 0.3–2.2 and 1.5–4.3 m. The stability of the thermal structure through time and between explosions indicates that it is linked to a deeper structural control likely comprising a central massive plug, feeding lava flow from the SW rim of the crater, surrounded by an arcuate, marginal fracture zone through which heat and mass can preferentially flow.  相似文献   

16.
The chronology of dust deposition and climate during the last interglacial is poorly known on the Chinese Loess Plateau. Here, 51 samples were taken from the ∼5 m S1 palaeosol (MIS5) at the desert marginal Jingbian site to develop what is currently the most detailed S1 chronology on the Plateau using instrumental dating techniques. We use the post-IR IRSL signal from sand-sized grains of K-rich feldspar. Signal resetting in the agricultural layer shows that it is possible to almost completely zero this signal in nature. First IR stimulation plateau measurements show that there is no clear dependence of De on first IR stimulation temperature between 50 and 260 °C suggesting negligible signal fading. Resultant ages are consistent with a last interglacial age (∼130 to ∼75 ka) and are also consistent within errors with continuous linear sedimentation rates. The average mass accumulation rate for S1 is ∼150 g m−2 a−1, considerably higher than at many other sites but within the overall range of Loess Plateau estimates. The remarkably stable sediment accumulation at the site contrasts with a more complex record of environmental and monsoonal change recorded in grain-size and magnetic susceptibility.  相似文献   

17.
18.
The belowground part of terrestrial ecosystem is a huge carbon pool. It is believed that of the total 2500Gt carbon stored in global terrestrial ecosystem, soil carbon storage within the 1 m surface layer ac- counts for 2000Gt, which is 4-fold of vegetation car- bon storage[1,2]. Compared with the carbon in the vegetation, carbon in the deep soil layers is much more stable, and it will stay in soil profile permanentlyunless geological vicissitude occurs. Essentially, forest restoration is the…  相似文献   

19.
The soil in the Rif, Morocco, is at serious risk because increasing anthropogenic pressures are gradually transforming large natural areas into farmland. The distribution of magnetic minerals within the soil profile can be used to assess soil development and degradation. The soils in the study area are severely eroded because of a combination of highly erodible soils, intense rainstorms and scarce vegetation cover. To sample of representative soil profiles, lithology, slope gradient and land use were considered. The ranges of magnetic susceptibility in the soil profiles distinguished between two primary soil groups. Magnetic susceptibility varied in the soil profile and along the soil toposequence, and the variations were related to the differences in the original magnetic composition and the influence of main erosion factors. Lithology is the main factor contributing to the variation in magnetic susceptibility. The magnetic susceptibility values in soils on Tertiary marls (χ = 13·5 × 10?8 m3 kg?1) differed significantly from those on Quaternary terraces (χ = 122·1 × 10?8 m3 kg?1). Slope affected the distribution of magnetic susceptibility because of the continuous loss of topsoil in some parts of the slope and the deposition of eroded soil in others. Elimination of the natural vegetation cover and a shift to cultivated land for cereals has had a negative impact on soil development and, on similar slopes and substrates, magnetic susceptibility decreased significantly in cultivated soils. The soils on steep slopes that had natural vegetation cover retained the magnetic minerals better than did those on gentler slopes that were under cultivation. Grazing, clearing and, especially, tilling has weakened the soil and made it much more vulnerable to erosion. An analysis of the main factors causing erosion will help to promote rational use of the land and to establish conservation strategies in such fragile agroecosystems. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

20.
Based on the stem analysis of 59 individuals of Pinus elliottii in combination with tree biomass models, we calculated annual biomass increment of forest plots at Qianyanzhou Ecological Station, Chinese Academy of Sciences in subtropical China. In addition, canopy layer and community NPP were calculated based on 12 years’ litter fall data. NPP of the 21-year-old forest was estimated by using the BIOME BGC model; and both measured NPP and estimated NPP were compared with flux data. Community biomass was 10574 g · m−2; its distribution patterns in tree layer, shrub layer, herbaceous layer, tree root, herbaceous and shrub roots and fine roots were 7542, 480, 239, 1810, 230, 274 and 239 g · m−2, respectively. From 1999 to 2004, the average annual growth rate and litter fall were 741 g · m−2 · a−1 (381.31 gC · m−2 · a−1) and 849 g · m−2 · a−1 (463 gC · m−2 · a−1), respectively. There was a significant correlation between annual litter fall and annual biomass increment; and the litter fall was 1.19 times the biomass increment of living trees. From 1985 to 2005, average NPP and GPP values based on BGC modeling were 630.88 (343.31–906.42 gC · m−2 · a−1) and 1 800 gC · m−2 · a−1 (1351.62–2318.26 gC · m−2 · a−1). Regression analysis showed a linear relationship (R 2=0.48) between the measured and simulated tree layer NPP values. NPP accounted for 30.2% (25.6%–32.9%) of GPP, while NEP accounted for 57.5% (48.1%–66.5%) of tree-layer NPP and 41.74% (37%–52%) of stand NPP. Soil respiration accounted for 77.0% of measured tree NPP and 55.9% of the measured stand NPP. NEE based on eddy covariance method was 12.97% higher than the observed NEP. Supported by the National Key Basic Research Special Foundation of China (Grant No. 2002CB4125), International Joint Research Project under Ministry of Science and Technology of China (Grant No. 2006DFB91920)  相似文献   

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