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1.
The age framework of Qarhan Salt Lake in arid western China is still controversial due in part to (1) age discrepancy between conventional 14C and 230Th dating results, and (2) no AMS 14C ages of organic carbon from drilling cores in Qarhan Salt Lake were reported until now. In order to discuss these chronological problems, upper 54.50 m lacustrine sediments from a drilling core (ISL1A) recovered from Qarhan Salt Lake were dated based on 230Th and AMS 14C dating techniques. Results show that (1) AMS 14C ages of total organic carbon (TOC) from 4.65 to 30.29 m are almost in stratigraphic order and consistent with 230Th ages of halite in the corresponding layers; (2) AMS 14C ages of TOC from 30.29 to 54.50 m are younger with increasing depth. This phenomenon was also found in Shell Bar in the study area, suggesting that AMS 14C ages from upper 30.29 m are more reliable while those from lower 24.21 m in ISL1A may be underestimated; (3) 230Th ages of halite from lower 24 m lacustrine sediments are obviously older than AMS 14C ages of TOC in the corresponding layers, which results into different age framework of salt lake sediments in Qarhan Salt Lake; (4) if extrapolating these reliable AMS 14C ages in ISL1A, similar age framework with 230Th ages in this core confirms that 230Th ages are much close to the true ages of these sediments, which suggests that the forming timing of the bottom salt layer is ~50 ka.  相似文献   

2.
At several times during the Quaternary, a major eastward-flowing outlet glacier of the former Patagonian Ice Sheet occupied the Lago San Martin Valley in Argentina (49°S, 72°W). We present a glacial chronology for the valley based on geomorphological mapping and cosmogenic nuclide (10Be) exposure ages (n = 10) of boulders on moraines and lake shorelines. There are five prominent moraine belts in the Lago San Martin Valley, associated with extensive sandar (glaciofluvial outwash plains) and former lake shorelines. Cosmogenic nuclide exposure ages for boulders on these moraines indicate that they formed at 14.3 ± 1.7 ka, 22.4 ± 2.3 ka, 34.4 ± 3.4 ka to 37.6 ± 3.4 ka (and possibly 60 ± 3.5 ka), and 99 ± 11 ka (1σ). These dated glacier advances differ from published chronologies from the Lago San Martin Valley based on 14C age determinations from organic sediments and molluscs in meltwater channels directly in front of moraines or in kettleholes within end moraine ridges. The moraine boulder ages also point to possible pre-LGM glacial advances during the last glacial cycle and a key observation from our data is that the LGM glaciers were probably less extensive in the Lago San Martin Valley than previously thought.  相似文献   

3.
Reliable dating of glaciomarine sediments deposited on the Antarctic shelf since the Last Glacial Maximum (LGM) is challenging because of the rarity of calcareous (micro‐) fossils and the recycling of fossil organic matter. Consequently, radiocarbon (14C) ages of the acid‐insoluble organic fraction (AIO) of the sediments bear uncertainties that are difficult to quantify. Here we present the results of three different methods to date a sedimentary unit consisting of diatomaceous ooze and diatomaceous mud that was deposited following the last deglaciation at five core sites on the inner shelf in the western Amundsen Sea (West Antarctica). In three cores conventional 14C dating of the AIO in bulk samples yielded age reversals down‐core, but at all sites the AIO 14C ages obtained from diatomaceous ooze within the diatom‐rich unit yielded similar uncorrected 14C ages between 13 517 ± 56 and 11 543 ± 47 years before present (a BP). Correction of these ages by subtracting the core‐top ages, which probably reflect present‐day deposition (as indicated by 210Pb dating of the sediment surface at one core site), yielded ages between ca. 10 500 and 8400 cal. a BP. Correction of the AIO ages of the diatomaceous ooze by only subtracting the marine reservoir effect (MRE) of 1300 a indicated deposition of the diatom‐rich sediments between 14 100 and 11 900 cal. a BP. Most of these ages are consistent with age constraints between 13.0 and 8.0 ka for the diatom‐rich unit, which we obtained by correlating the relative palaeomagnetic intensity (RPI) records of three of the sediment cores with global and regional reference curves. As a third dating technique we applied conventional radiocarbon dating of the AIO included in acid‐cleaned diatom hard parts extracted from the diatomaceous ooze. This method yielded uncorrected 14C ages of only 5111 ± 38 and 5106 ± 38 a BP, respectively. We reject these young ages, because they are likely to be overprinted by the adsorption of modern atmospheric carbon dioxide onto the surfaces of the diatom hard parts prior to sample graphitisation and combustion for 14C dating. The deposition of the diatom‐rich unit in the western Amundsen Sea suggests deglaciation of the inner shelf before ca. 13 ka BP. The deposition of diatomaceous oozes elsewhere on the Antarctic shelf around the same time, however, seems to be coincidental rather than directly related. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

4.
Complex glacier and tree-line fluctuations in the White River valley on the northern flank of the St. Elias and Wrangell Mountains in southern Alaska and Yukon Territory are recognized by detailed moraine maps and drift stratigraphy, and are dated by dendrochronology, lichenometry, 14C ages, and stratigraphic relations of drift to the eastern (1230 14C yr BP) and northern (1980 14C yr BP) lobes of the White River Ash. The results show two major intervals of expansion, one concurrent with the well-known and widespread Little Ice Age and the other dated between 2900 and 2100 14C yr BP, with a culmination about 2600 and 2800 14C yr BP. Here, the ages of Little Ice Age moraines suggest fluctuating glacier expansion between ad 1500 and the early 20th century. Much of the 20th century has experienced glacier recession, but probably it would be premature to declare the Little Ice Age over. The complex moraine systems of the older expansion interval lie immediately downvalley from Little Ice Age moraines, suggesting that the two expansion intervals represent similar events in the Holocene, and hence that the Little Ice Age is not unique. Another very short-lived advance occurred about 1230 to 1050 14C yr BP. Spruce immigrated into the valley to a minimum altitude of 3500 ft (1067 m), about 600 ft (183 m) below the current spruce tree line of 4100 ft (1250 m), at least by 8020 14C yr BP. Subsequent intervals of high tree line were in accord with glacier recession; in fact, several spruce-wood deposits above current tree line occur bedded between Holocene tills. High deposits of fossil wood range up to 76 m above present tree line and are dated at about 5250, 3600 to 3000, and 2100 to 1230 14C yr BP. St. Elias glacial and tree-line fluctuations, which probably are controlled predominantly by summer temperature and by length of the growing and ablation seasons, correlate closely with a detailed Holocene tree-ring curve from California, suggesting a degree of synchronism of Holocene summer-temperature changes between the two areas. This synchronism is strengthened by comparison with the glacier record from British Columbia and Mt. Rainier, Likewise, broad synchronism of Holocene events exists across the Arctic between the St. Elias Mountains and Swedish Lappland. Finally, two sequences from the Southern Hemisphere show similar records, in so far as dating allows. Hence, we believe that a preliminary case can be made for broad synchronism of Holocene climatic fluctuations in several regions, although further data are needed and several areas, particularly Colorado and Baffin Island, show major differences in the regional pattern.  相似文献   

5.
In order to better understand modern human behavioral variability in Hokkaido, Japan, we consider the geoarchaeology of the Kamihoronai‐Moi site in terms of its geochronology, stratigraphy, depositional environments, and post‐depositional disturbances. A Paleolithic component is stratigraphically situated between the Eniwa‐a (15,000–17,000 14C yr B.P.) and the Tarumae‐d (8000–9000 14C yr B.P.) tephras. Moreover, six AMS 14C ages on charcoal from a Pleistocene‐aged hearth feature are between 14,400 and 14,800 14C yr B.P. Quantitative examinations of patterns in artifact distributions show a low degree of vertical and horizontal displacement of chipped‐stone artifacts, suggesting that post‐depositional movement of the cultural material was insufficient to disrupt the original pattern of artifact distribution. © 2009 Wiley Periodicals, Inc.  相似文献   

6.
Radiocarbon Dating of Soil Organic Matter   总被引：2，自引：0，他引：2  
Radiocarbon ages of soil organic matter are evaluated with a model which incorporates the dynamics of the14C content of soil organic matter. Measured14C ages of soil organic matter or its fractions are always younger than the true ages of soils due to continuous input of organic matter into soils. Differences in soil C dynamics due to climate or soil depth will result in significantly different14C signatures of soil organic matter for soils of the same age. As a result, the deviation of the measured14C age from the true age of soil formation could differ significantly among different soils or soil horizons. Our model calculations also suggest that14C ages of soil organic matter will eventually reach a steady state provided that no climatic or ecological perturbations occur. Once a soil or a soil horizon has reached a steady state,14C dating of soil organic matter will provide no useful information regarding the age of the soil. However, for soils in which steady state has not been reached, it is possible to estimate the age of soil formation by modeling the measured14C contents of soil organic matter. Radiocarbon dating of buried soils could, in general, overestimate the true age of the burial by as much as the steady-state age of the soil or soil horizon.  相似文献   

7.
Ice core δ18O records from the No. 1 glacier at the head of the ürümqi River were used to characterize the relationship between δ18O and contemporaneous surface air temperature (Ta) nearby the Daxigou Meteorological Station (3539 m above sea level, ∼2km away from the ice core drilling site). Although the ice core records of annually averaged δ18O are positively correlated with contemporaneous surface air temperature, especially summer air temperature, the correlation is less significant than that for the precipitation samples due to depositional and post-depositional modification processes. However, the climatological significance of the ice core δ18O records can be still preserved to a certain degree, which might extend the application of high altitude and sub-tropical ice core δ18O records to paleoclimate reconstruction.  相似文献   

8.
《Applied Geochemistry》1986,1(4):503-511
A recently discovered ore-grade accumulation of U in organic-rich sediments of late Quaternary age provides an opportunity for studying the early association of U, U-daughters, and organic matter in a natural setting. The U occurs in valley-fill sediments of peat, peaty clay, silt, and sand along the north fork of Flodelle Creek, Stevens County, Washington. Radiometric techniques (delayed neutron, high-resolution gamma-ray spectrometry, thin-source alpha spectrometry) were employed to determine the abundance and distribution of U-series nuclides, the extent of secular equilibrium within the U decay series, and the apparent U-series ages of U incorporation.Sixteen lithologically distinct intervals were sampled from a 292 cm core. Uranium contents range from 140 to 2790 ppm and are positively correlated with organic contents. Measured alpha activity ratios of 234U/238U (1.31–1.38) are very similar to those reported in coexisting waters, suggesting a rather constant isotopic composition of introduced U. Much lower Th contents of <10–40 ppm are controlled by the type and abundance of silicate detritus. The youth of the host sediments (<15 000 a) and the paucity of associated radioactivity suggested large excesses of U relative to radioactive daughters and such excesses were observed, particularly in the shallowest intervals. Apparent ages of U emplacement determined by the (alpha) activity ratio of 230Th daughter to 234U parent show a general increase with depth and fair agreement with estimated depositional ages. This observation suggests dominantly syndepositional or early post depositional emplacement of U followed by decay-generated buildup of 230Th daughter with time. However, interval by interval comparisons of the relative abundances of other daughters, particularly 226Ra and 210Pb, indicate variability caused by processes other than closed-system growth and decay, probably because chemically diverse daughters that are decay-generated in situ have differing mobilities and because upwelling ground water continuously adds more U and minor amounts of daughters. If 230Th is considered the least susceptible to these modifications, the data suggest some addition of 234U in the deepest intervals and some loss of 226Ra and/or gain of 222Rn throughout the studied core.  相似文献   

9.
Primnoa resedaeformis is a deep-sea gorgonian coral with a two-part skeleton of calcite and gorgonin (a fibrillar protein), potentially containing long-term records of valuable paleo-environmental information. For various reasons, both radiocarbon and U/Th dating of these corals is problematic over the last few centuries. This paper explores aspartic acid racemization dating of the gorgonin fraction in modern and fossil specimens collected from the NW Atlantic Ocean. Radiocarbon dating of the fossil specimen indicates a lifespan of 700 ± 100 years, the longest yet documented for any octocoral. Gorgonin amino acid compositions were identical in the fossil and modern specimens, indicating resistance to organic diagenesis. Similar to bone collagen, the fibrillar protein of gorgonin may impose conformational constraints on the racemization of Asp at low temperatures. The rate of racemization of aspartic acid (d/l-Asp) was similar to previously published results from an 1800 year old anemone (Gerardia). The age equation was: age (years BP 2000 AD) = [(d/l − 0.020 (±.002))/.0011 (±.0001)]2 (r2 = 0.97, p < .001). The error in an age estimate calculated by d/l-Asp was marginally better than that for 14C dating over the most recent 50-200 years, although the dating error may be improved by inclusion of more samples over a broader time range. These results suggest that d/l-Asp dating may be useful in augmenting 14C dating in cases where 14C calibrations yield two or more intercept ages, or in screening samples for further 14C or U/Th dating.  相似文献   

10.
Cosmogenic nuclide surface exposure dating of boulders and erratics provides new constraints for a glacial chronology in the source area of the Urumqi River, Tian Shan, China. 10Be exposure ages of 15.0 ± 1.3–17.1 ± 1.5 ka from the Upper Wangfeng (UWF) moraines agree well with their previous relative age assignments to marine isotope stage (MIS) 2, but are younger than published AMS 14C and electron spin resonance (ESR) ages (from 22.8 ± 0.6 to 37.4 ka). This difference may result from variations in techniques, or could reflect the impact of surface erosion and sediment/snow cover on surface exposure dating. 10Be ages from the Lower Wangfeng (LWF) moraines (18.7 ± 1.8 and 16.2 ± 1.5 ka) are indistinguishable from the UWF exposure ages, but are significantly younger than previously reported thermoluminescence (TL) and ESR ages (37.7 ± 2.6–184.7 ± 18 ka). Either these two groups were formed during the same period (MIS 2) and there are problems with TL and ESR ages, or the moraines were of very different ages and the similar exposure ages result from different degrees of degradation. Erratics on rock steps and a drumlin along >8 km of the main glacial valley above the UWF have internally consistent and slightly decreasing 10Be exposure ages indicating glacier retreat >2.5 m a?1 after MIS 2 and before middle or late Holocene glacier re‐advances. This retreat rate is similar to rates observed from modern glaciers. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

11.
Transfer of organic carbon (OC) from the terrestrial to the oceanic carbon pool is largely driven by riverine and aeolian transport. Before transport, however, terrigenous organic matter can be retained in intermediate terrestrial reservoirs such as soils. Using compound-specific radiocarbon analysis of terrigenous biomarkers their average terrestrial residence time can be evaluated.Here we show compound-specific radiocarbon (14C) ages of terrigenous biomarkers and bulk 14C ages accompanied by geochemical proxy data from core top samples collected along transects in front of several river mouths in the Black Sea. 14C ages of long chain n-alkanes, long chain n-fatty acids and total organic carbon (TOC) are highest in front of the river mouths, correlating well with BIT (branched and isoprenoid tetraether) indices, which indicates contribution of pre-aged, soil-derived terrigenous organic matter. The radiocarbon ages decrease further offshore towards locations where organic matter is dominated by marine production and aeolian input potentially contributes terrigenous organic matter. Average terrestrial residence times of vascular plant biomarkers deduced from n-C29+31 alkanes and n-C28+30 fatty acids ages from stations directly in front of the river mouths range from 900 ± 70 years to 4400 ± 170 years. These average residence times correlate with size and topography in climatically similar catchments, whereas the climatic regime appears to control continental carbon turnover times in morphologically similar drainage areas of the Black Sea catchment. Along-transect data imply petrogenic contribution of n-C29+31 alkanes and input via different terrigenous biomarker transport modes, i.e., riverine and aeolian, resulting in aged biomarkers at offshore core locations. Because n-C29+31 alkanes show contributions from petrogenic sources, n-C28+30 fatty acids likely provide better estimates of average terrestrial residence times of vascular plant biomarkers. Moreover, sedimentary n-C28 and n-C30 fatty acids appear clearly much less influenced by autochthonous sources than n-C24 and n-C26 fatty acids as indicated by increasing radiocarbon ages with increasing chain-length and are, thus, more representative as vascular plant biomarkers.  相似文献   

12.
Lago Puyehue is a glacigenic lake in the Chilean Lake District (40°S) with a complex deglaciation history. A detailed seismic–stratigraphic study of its sedimentary infill indicates a much earlier retreat of the glacier from the Lago Puyehue basin than the neighbouring glacier from the Lago Rupanco basin. Because of their close proximity, Rupanco meltwater streams played an important part in the depositional processes of Lago Puyehue. A timing discrepancy between the in‐lake ages of a sediment core and the outer‐lake ages of moraine deposits (re)opens the discussion on the timing of deglaciation in the Southern Hemisphere. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

13.
This work presents the first reconstruction of late Pleistocene glacier fluctuations on Uturuncu volcano, in the Southern Tropical Andes. Cosmogenic 3He dating of glacial landforms provides constraints on ancient glacier position between 65 and 14 ka. Despite important scatter in the exposure ages on the oldest moraines, probably resulting from pre-exposure, these 3He data constrain the timing of the moraine deposits and subsequent glacier recessions: the Uturuncu glacier may have reached its maximum extent much before the global LGM, maybe as early as 65 ka, with an equilibrium line altitude (ELA) at 5280 m. Then, the glacier remained close to its maximum position, with a main stillstand identified around 40 ka, and another one between 35 and 17 ka, followed by a limited recession at 17 ka. Then, another glacial stillstand is identified upstream during the late glacial period, probably between 16 and 14 ka, with an ELA standing at 5350 m. This stillstand is synchronous with the paleolake Tauca highstand. This result indicates that this regionally wet and cold episode, during the Heinrich 1 event, also impacted the Southern Altiplano. The ELA rose above 5450 m after 14 ka, synchronously with the Bolling–Allerod.  相似文献   

14.
With accelerated melting of alpine glaciers, understanding the future state of the cryosphere is critical. Because the observational record of glacier response to climate change is short, palaeo‐records of glacier change are needed. Using proglacial lake sediments, which contain continuous and datable records of past glacier activity, we investigate Holocene glacier fluctuations on northeastern Baffin Island. Basal radiocarbon ages from three lakes constrain Laurentide Ice Sheet retreat by ca. 10.5 ka. High sedimentation rates (0.03 cm a?1) and continuous minerogenic sedimentation throughout the Holocene in proglacial lakes, in contrast to organic‐rich sediments and low sedimentation rates (0.005 cm a?1) in neighbouring non‐glacial lakes, suggest that glaciers may have persisted in proglacial lake catchments since regional deglaciation. The presence of varves and relatively high magnetic susceptibility from 10 to 6 ka and since 2 ka in one proglacial lake suggest minimum Holocene glacier extent ca. 6–2 ka. Moraine evidence and proglacial and threshold lake sediments indicate that the maximum Holocene glacier extent occurred during the Little Ice Age. The finding that glaciers likely persisted through the Holocene is surprising, given that regional proxy records reveal summer temperatures several degrees warmer than today, and may be due to shorter ablation seasons and greater accumulation‐season precipitation. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

15.
The North Atlantic Younger Dryas climatic reversal did not cause a glacier advance on Mount Rainier. The glaciers on Mount Rainier seem to have advanced in response to regional or local shifts in climate. However, the Younger Dryas climatic reversal may have affected the Mount Rainier area, causing a cold, but dry, climate unfavorable to glacier advances. Glaciers in the vicinity of Mount Rainier advanced twice during late glacial/early Holocene time. Radiocarbon dates obtained from lake sediments adjacent to the corresponding moraines are concordant, indicating that the ages for the advances are closely limiting. The first advance occurred before 11,300 14C yr BP (13,200 cal yr BP). During the North Atlantic Younger Dryas event, between 11,000 and 10,000 14C yr BP (12,900 and 11,600 cal yr BP), glaciers retreated on Mount Rainier, probably due to a lack of available moisture, but conditions may have remained cold. The onset of warmer conditions on Mount Rainier occurred around 10,000 14C yr BP (11,600 cal yr BP). Organic sedimentation lasted for at least 700 years before glaciers readvanced between 9800 and 8950 14C yr BP (10,900 and 9950 cal yr BP).  相似文献   

16.
Lobate talus slopes in the Deboullie Lakes Ecological Reserve (DLER) of northern Maine exhibit parabolic profiles characteristic of inactive and relict talus‐derived rock glaciers. Vegetated rock glacier surfaces suggest that the landforms are no longer active, and lobes comprising two DLER rock glaciers document periods of past growth. Observations of perennial subsurface ice are supported by datalogger temperature measurements, indicating that sporadic permafrost exists throughout the DLER. We compare the DLER rock glaciers, along with similar features elsewhere in New England and adjacent Québec, to the modern alpine permafrost distribution. Results indicate that a mean annual temperature cooling of ～6°C is required to promote active rock glacier growth. Ages of plant remains recovered from the basal sediments of a local pond constrain deglaciation to before 11 320 14C a BP, and core stratigraphy and organic content reveal that a periglacial environment persisted during the early postglacial era. Thus, we hypothesise that the DLER rock glaciers were active during Lateglacial time despite the lack of glacier activity in the region. We take this to suggest that north‐eastern US rock glaciers formed in response to mean annual temperatures skewed towards the frigid winters of the Younger Dryas chronozone. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

17.
Considerable uncertainty surrounds the timing of glacier advance and retreat during the Younger Dryas or Loch Lomond Stade (LLS) in the Scottish Highlands. Some studies favour ice advance until near the end of the stade (c. 11.7 ka), whereas others support the culmination of glacier advance in mid‐stade (c. 12.6–12.4 ka). Most published 10 Be exposure ages reported for boulders on moraines or deglacial sites post‐date the end of the LLS, and thus appear to favour the former view, but recalibration of 33 10 Be ages using a locally derived 10 Be production rate and assuming rock surface erosion rates of zero to 1 mm ka?1 produces exposure ages 130–980 years older than those originally reported. The recalibrated ages are filtered to exclude anomalous data, and then employed to generate aggregate probability density distributions for the timing of moraine deposition and deglaciation. The results suggest that the most probable age for the timing of the deposition of the sampled outermost moraines lies in the interval 12.4–12.1 ka or earlier. Deglacial ages obtained for sites inside Loch Lomond Stadial glacier limits imply that glaciers at some or all of the sampled sites were retreating prior to 12.1 ka. Use of aggregated data does not exclude the possibility of asynchronous glacier behaviour at different sites, but confirms that some glaciers reached their maximum limits and began to retreat several centuries before the rapid warming that terminated the LLS at 11.7–11.6 ka, consistent with the retrodictions of recent numerical modelling experiments and with geomorphological evidence for gradual oscillatory ice‐margin retreat under stadial conditions.  相似文献   

18.
Conventional biomarker studies typically interpret the distribution, structure and stable isotopic (e.g. 13C, D) composition of sedimentary hydrocarbons and polar compounds. However, compound and compound class specific 14C analysis (CSRA) is becoming increasingly relevant for characterising millennial scale residence and mobilisation of sedimentary organic carbon (OC). Here, the 14C content of the aliphatic and bulk fractions from shallow cores from the hypersaline playa, Lake Tyrrell, southeast Australia were compared. The aliphatic hydrocarbon fractions (predominantly n-alkanes) were substantially older than the corresponding bulk fractions, indicating the presence of active reservoirs of ancient carbon, likely derived from aeolian reworking of sediments. The 14C ages of the aliphatic hydrocarbons in the core revealed two noticeable shifts in age and source of ancient OC that were not apparent using biomarker composition and sedimentology alone. The study shows that aliphatic hydrocarbons are relatively simple to isolate, even from organically lean (ca. 0.05% TOC) terrestrial sediments, and their 14C ages yield information about carbon mobilisation and preservation not amenable to conventional analysis.  相似文献   

19.
中国新疆博斯腾湖全新世沉积环境年代学特征   总被引：18，自引：1，他引：18  
通过对博斯腾湖沉积物湖芯样品进行137Cs,14C-AMS测年分析,湖芯剖面上有明显的1986年的切尔诺贝利核事故蓄积峰,以及1975年和1963年次蓄积峰,这些137Cs蓄积峰对博斯腾湖现代沉积有明显的时标意义。通过质量深度与年代分析,博斯腾湖的沉积速率相对稳定,平均沉积速率为0.13±0.01g/cm2.a。与14C年代获得的中全新世以来的平均沉积速率0.13±0.03cm/a和0.12±0.05cm/a相似,表明博斯腾湖中全新世以来的沉积环境较稳定,并且也说明14C-AMS测年分析所得的结果较为可靠,可以利用博斯腾湖沉积物样品测定的14C年代进行线性回归作年代校正,由于湖泊沉积物中老碳效应的影响,博斯腾湖沉积物有机质14C测年偏老约650a左右。  相似文献   

20.
Thirty-eight fossil coral samples of known age from late Pleistocene uplifted reef terraces have been analyzed for amino acid composition and for the degree of racemization of selected amino acids. Particular attention has been given to the epimerization (racemization about the α-carbon) of isoleucine. The DL ratios observed in many of these samples do not conform to the concept of increasing racemization being associated with increasing fossil age. It is shown that sixteen of the samples demonstrate concordance between their known age and the age estimated from racemization data. Racemization ages are based upon a kinetic model derived from the kinetics observed in foraminifera in marine sediments and published estimates of the temperature dependence of the isoleucine epimerization reaction. Lack of concordance for the remaining samples is explained by either of two separate diagenetic phenomena: extensive leaching of free amino acids from the fossil, or contamination by ‘young’ amino acids. Ambiguities observed in many of the results may be due to the fact that coralline organic matter can have a complex history because of variations in its source and in its relation to the mineral phase. Neither of these factors has been observed to exert such a significant effect on racemization kinetics observed in fossil foraminifera or molluscs. Fossil corals are of only modest value as specimens for amino acid geochronological studies.  相似文献   

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