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1.
Benton C. Clark 《Icarus》1978,34(3):645-665
Converging lines of evidence suggest that a significant portion of the Martian surface fines may consist of salts and smectite clays. Salts can form stoichiometric hydrates as well as eutectic solutions with depressed freezing points; clays contain bound water of constitution and adsorb significant quantities of water from the vapor phase. The formation of ice may be suppressed by these minerals in some regions on Mars, and their presence in abundance would imply important consequences for atmospheric and geologic processes and the prospects for exobiology.  相似文献   

2.
Dust and water vapour are fundamental components of the Martian atmosphere. In view of tracing the past environmental conditions on Mars, that possibly favoured the appearing of life forms, it is important to study the present climate and its evolution. Here dust and water vapour have (and have had) strong influence. Of major scientific interest is the quantity and physical, chemical and electrical properties of dust and the abundance of water vapour dispersed in the atmosphere and their exchange with the surface. Moreover, in view of the exploration of the planet with automated systems and in the future by manned missions, it is of primary importance to analyse the hazards linked to these environmental factors. The Martian Environmental Dust Systematic Analyser (MEDUSA) experiment, included in the scientific payload of the ESA ExoMars mission, accommodates a complement of sensors, based on optical detection and cumulative mass deposition, that aims to study dust and water vapour in the lower Martian atmosphere. The goals are to study, for the first time, in-situ and quantitatively, physical properties of the airborne dust, including the cumulative dust mass flux, the dust deposition rate, the physical and electrification properties, the size distribution of sampled particles and the atmospheric water vapour abundance versus time.  相似文献   

3.
C.B. Leovy 《Icarus》1973,18(1):120-125
A model for exchange of water from the atmosphere to condensing CO2 caps is developed. The rate of water condensation in the caps is assumed to be proportional to the meridional heat flux. It follows that the amount of water condensed in the caps varies inversely with the amount of CO2 condensed. The seasonal phase of the release of water from the caps is not consistent with observed variations in the abundance of atmospheric water. Seasonal variations of atmospheric water abundance are most consistent with vapor exchange between the atmosphere and permafrost in the subtropics. Although water condensation in semipermanent caps is normally very slow, it may take place at a much faster rate at unusually high atmospheric temperatures, such as those produced by absorption of solar radiation by airborne dust.  相似文献   

4.
Analysis of the distribution of the epithermal and fast neutron fluxes from the Martian surface within the ±60° latitude zone measured by the High-Energy Neutron Detector (HEND) from mid-February through mid-June 2002 has revealed regional neutron-flux variations outside the zones of climatic effects, which appear to be attributable to the presence of chemically bound water. With the exception of the epithermal neutron fluxes in Arabia and southwest of Olympus Mons (Medusae Fossae), these variations show no correlation with the geologic structure of the terrain at the level of global geologic maps. The lack of such a correlation probably implies that to the formation depth of the epithermal neutron flux (1–2 m), let alone the fast neutron flux (20–30 cm), much of Mars is covered by a surface material that bears little relation in composition to local bedrocks. Clearly, this is an aeolian cover whose fine-grain component was mixed by dust storms in the geologic time on the scale of large regions. The decrease in the flux of epithermal neutrons in Arabia and southwest of Olympus Mons (Medusae Fossae) appears to be attributable to an enhanced concentration of materials containing chemically bound water (clay minerals, palagonite, hydroxides, and hydrosalts) in the surface layers of these regions.  相似文献   

5.
《Icarus》1987,71(2):250-256
Estimates of the total inventory of the volatile elements C, H, O, and N on Mars, based upon atmospheric gas tracers, vary by a factor of 25 among different authors. Accretion of comets as the source of volatiles can account for less than 5% of the actual inventory, assuming the chondritic S/Cl abundance ratio in comets and a Martian outgassing ratio for these two elements no lower than for the estimated excess volatile inventory on Earth. Sulfate salt formation with the igneous minerals in the regolith can be a major sink for H2O, but first will recycle C and N incorporated in carbonate and nitrate minerals back to the atmosphere. Extrusive and shallow intrusive volcanism, at a persistent but decreasing rate, can interfere with this volatile recycling by irreversibly masking much of the incorporated inventory, resulting in the inevitable evolution to a relatively volatile-poor environment at the outermost, observable surface of Mars.  相似文献   

6.
A method for separating the spectral signatures of the Martian surface and atmosphere was developed and is applied to multiple emission angle data returned from the MGS TES instrument. This method includes correlated-k and index gas removal algorithms that may be applied to all nadir-pointing TES data. Initial results have provided new and refined measurements of the spectral shapes of atmospheric dust and the Martian surface. Surface temperatures and atmospheric dust opacities are also retrieved with improved accuracy over single observation temperature and opacity retrievals. Low-albedo surfaces display absorptions consistent in both shape and depth with previous studies. These surfaces may be closely modeled using a combination of previously derived basalt, andesitic, and high-albedo surface spectral shapes. Short wavelengths display no significant absorptions, indicating both the coarse particulate nature of the surface and the lack of significant amounts of carbonate. Moderate- and high-albedo surfaces have spectral shapes distinctive of fine particulate silicate materials. No single material can match the entire high-albedo surface spectrum, though there are clear indications of a material that closely matches intermediate to calcic plagioclase and an emission peak at ∼1620 cm−1 due to bound water. The lack of residual restrahlen silicate absorptions indicates that minerals such as olivine or pyroxene are not present in high-albedo surfaces at significant (but unknown) abundances. High-albedo surface results presented here are in agreement with and complementary to shorter wavelength observations. The Martian dust is composed of both primary and secondary minerals. Either chemical weathering has not completely altered its source material or the soil is a mixture of altered and unaltered sources. Further laboratory studies are needed to better establish detection limits and behavior of mineral mixtures of fine particulates in the thermal infrared portion of the spectrum.  相似文献   

7.
Abstract— Isotopic signatures and concentrations of xenon have been measured in Shergotty mineral separates by laser step heating. Martian atmosphere and ‘martian interior’ xenon are present, as is a spallation component. Martian atmospheric xenon is 5–10 times more concentrated in opaque minerals (magnetite, ilmenite, and pyrrhotite) and maskelynite than in pyroxenes, perhaps reflecting grain size variation. This is shown to be consistent with shock incorporation. A component consisting of solar xenon with a fission contribution, similar to components previously identified in martian meteorites and associated with the martian interior, is best defined in the pyroxene‐dominated separates. This component exhibits a consistent 129Xe (129Xe/132Xe ?1.2) excess over solar/planetary (129Xe/132Xe ?1.04). We suggest that gas present in the melt, perhaps a mixture of interior xenon and martian atmosphere, was incorporated into the pyroxenes in Shergotty as the minerals crystallized.  相似文献   

8.
Tetsuya Tokano 《Icarus》2003,164(1):50-78
In an effort to test and to understand the global hydrogen distribution in the shallow subsurface of Mars retrieved by the Mars Odyssey gamma-ray spectrometer, the present state and movement of water are investigated by a coupled global subsurface-atmosphere water cycle model. It was found that the observed global subsurface hydrogen distribution is largely consistent with the modeled global water cycle, so a large fraction of hydrogen is likely to exist as water, at low and mid latitudes in the form of adsorbed water. Under the present climate the water content in the shallow subsurface becomes higher in the northern hemisphere than in the southern hemisphere as a result of global water cycle, regardless of the initial water distribution in the soil or adsorptive capacity. The higher annual maximum soil temperature in the south, stronger net northward transport of atmospheric water vapor, and the emission of vapor from the northern residual polar cap in northern summer contribute to this hemispheric asymmetry. The generally higher adsorptive capacity of clay minerals in the northern plains may further increase this bias. The longitudinal inhomogeneity is caused by several factors, such as thermal inertia, adsorptive capacity, and atmospheric surface pressure. The water abundance is locally high in low thermal inertia regions (e.g., Arabia Terra) and at deep places where the surface pressure is high (e.g., Hellas); it is low in soil with a low adsorptive capacity (e.g., Tharsis) and high thermal inertia regions (e.g., Solis Planum). Most of the soil humidity near the surface at low and mid latitudes may originate from the atmosphere. The model implies that the upper soil layer should be largely ice-free because otherwise an excessive sublimation and vapor emission into the atmosphere in warm seasons would violate the observational constraints. Moreover, the more uniform latitudinal variation of the observed hydrogen abundance near the surface compared to that of deeper layers is indicative of the presence of adsorbed water instead of ground ice because the adsorbed water content does not as steeply depend on latitude as the ground ice stability. Concerning the regolith mineralogy, montmorillonite can much better account for the observed water cycle than palagonite. While the presence of permanent ground ice appears likely in the polar region below a thin layer, large seasonal cycle of phase change between pore ice and adsorbed water may be possible. Regolith adsorption/desorption is neither negligible nor crucial for the seasonal atmospheric water cycle, but the surface-atmosphere coupling is a major prerequisite for the long-term evolution of subsurface water distribution.  相似文献   

9.
Northwest Africa (NWA) 5790 is the most recently discovered member of the nakhlite group. Its mineralogy differs from the other nakhlites with a high abundance mesostasis (38.1 ± 3.6 vol%) and scarcity of olivine (4.0 ± 2.2 vol%). Furthermore, zoning of augite phenocrysts, and other petrographic and chemical characteristics suggest that NWA 5790 samples the chilled margin of its parent lava flow/sill. NWA 5790 contains calcite and rare clay minerals that are evidence for its exposure to liquid water. The calcite forms a cement to coatings of dust on the outer surface of the find and extends into the interior of the meteorite within veins. The presence of microbial remains within the coating confirms that the dust and its carbonate cement are terrestrial in origin, consistent with the carbon and oxygen isotope composition of the calcite. The clay minerals are finely crystalline and comprise ~0.003 vol% of the meteorite. δD values of the clay minerals range from ?212 ± 109‰ to ?96 ± 132‰, and cannot be used to distinguish between a terrestrial or Martian origin. As petrographic results are also not definitive, we conclude that secondary minerals produced by Martian groundwaters are at best very rare within NWA 5790. The meteorite has therefore sampled a region of the lava flow/sill with little or no exposure to the aqueous solutions that altered other nakhlites. This isolation could relate to the scarcity of olivine in NWA 5790 because dissolution of olivine in other nakhlites by Martian groundwaters enhanced their porosity and permeability, and provided solutes for secondary minerals.  相似文献   

10.
We investigated exterior and interior subsamples from the Martian shergottite meteorites Allan Hills (ALH) A77005 and Roberts Massif (RBT) 04261 for secondary minerals, oxygen isotopes, Ar‐Ar, and noble gas signatures. Electron microprobe investigations revealed that RBT 04261 does not contain any visible alteration even in its most exterior fractures, whereas fracture fillings in ALHA77005 penetrate into the meteorite up to 300 μm, beyond which the fractures are devoid of secondary minerals. Light noble gases seem to be almost unaffected by terrestrially induced alteration in both meteorites. Thus, a shock metamorphic overprint of 30–35 GPa can be deduced from the helium measurements in RBT 04261. Oxygen isotopes also seem unaffected by terrestrially weathering and variations can easily be reconciled with the differences in modal mineralogy of the exterior and interior subsamples. The measurements on irradiated samples (Ar‐Ar) showed a clear Martian atmospheric contribution in ALHA77005, but this is less apparent in our sample of RBT 04261. Exterior and interior subsamples show slight differences in apparent ages, but the overall results are very similar between the two. In contrast, krypton and xenon are severely affected by terrestrial contamination, demonstrating the ubiquitous presence of elementally fractionated air in RBT 04261. Although seemingly contradictory, our results indicate that RBT 04261 was more affected by contamination than ALHA77005. We conclude that irrespective of on which planet the alteration occurred, exposure of Martian rocks to atmosphere (or brine) introduces noble gases with signatures elementally fractionated relative to the respective atmospheric composition into the rock, and relationships of that process with oxygen isotopes or mineralogical observations are not straightforward.  相似文献   

11.
A theoretical reconstruction of the history of Martian volatiles indicates that Mars probably possessed a substantial reducing atmosphere at the outset of its history and that its present tenous and more oxidized atmosphere is the result of extensive chemical evolution. As a consequence, it is probable that Martian atmospheric chemical conditions, now hostile with respect to abiotic organic synthesis in the gas phase, were initially favorable. Evidence indicating the chronology and degradational history of Martian surface features, surface mineralogy, bulk volatile content, internal mass distribution, and thermal history suggests that Mars catastrophically developed a substantial reducing atmosphere as the result of rapid accretion. This atmosphere probably persisted—despite the direct and indirect effects of hydrogen escape—for a geologically short time interval during, and immediately following, Martian accretion. That was the only portion of Martian history when the atmospheric environment could have been chemically suited for organic synthesis in the gas phase. Subsequent gradual degrassing of the Martian interior throughout Martian history could not sustain a reducing atmosphere due to the low intensity of planet-wide orogenic activity and the short atmospheric mean residence time of hydrogen on Mars. During the post-accretion history of Mars, the combined effects of planetary hydrogen escape, solar-wind sweeping, and reincorporation of volatiles into the Martian surface produced and maintained the present atmosphere.  相似文献   

12.
Abstract– Xenon‐isotopic ratios, step‐heating release patterns, and gas concentrations of mineral separates from Martian shergottites Roberts Massif (RBT) 04262, Dar al Gani (DaG) 489, Shergotty, and Elephant Moraine (EET) 79001 lithology B are reported. Concentrations of Martian atmospheric xenon are similar in mineral separates from all meteorites, but more weathered samples contain more terrestrial atmospheric xenon. The distributions of xenon from the Martian and terrestrial atmospheres among minerals in any one sample are similar, suggesting similarities in the processes by which they were acquired. However, in opaque and maskelynite fractions, Martian atmospheric xenon is released at higher temperatures than terrestrial atmospheric xenon. It is suggested that both Martian and terrestrial atmospheric xenon were initially introduced by weathering (low temperature alteration processes). However, the Martian component was redistributed by shock, accounting for its current residence in more retentive sites. The presence or absence of detectable 129Xe from the Martian atmosphere in mafic minerals may correspond to the extent of crustal contamination of the rock’s parent melt. Variable contents of excess 129Xe contrast with previously reported consistent concentrations of excess 40Ar, suggesting distinct sources contributed these gases to the parent magma.  相似文献   

13.
Within the numerical general-circulation model of the Martian atmosphere MAOAM (Martian Atmosphere: Observation and Modeling), we have developed the water cycle block, which is an essential component of modern general circulation models of the Martian atmosphere. The MAOAM model has a spectral dynamic core and successfully predicts the temperature regime on Mars through the use of physical parameterizations typical of both terrestrial and Martian models. We have achieved stable computation for three Martian years, while maintaining a conservative advection scheme taking into account the water–ice phase transitions, water exchange between the atmosphere and surface, and corrections for the vertical velocities of ice particles due to sedimentation. The studies show a strong dependence of the amount of water that is actively involved in the water cycle on the initial data, model temperatures, and the mechanism of water exchange between the atmosphere and the surface. The general pattern and seasonal asymmetry of the water cycle depends on the size of ice particles, the albedo, and the thermal inertia of the planet’s surface. One of the modeling tasks, which results from a comparison of the model data with those of the TES experiment on board Mars Global Surveyor, is the increase in the total mass of water vapor in the model in the aphelion season and decrease in the mass of water ice clouds at the poles. The surface evaporation scheme, which takes into account the turbulent rise of water vapor, on the one hand, leads to the most complete evaporation of ice from the surface in the summer season in the northern hemisphere and, on the other hand, supersaturates the atmosphere with ice due to the vigorous evaporation, which leads to worse consistency between the amount of the precipitated atmospheric ice and the experimental data. The full evaporation of ice from the surface increases the model sensitivity to the size of the polar cap; therefore, the increase in the latter leads to better results. The use of a more accurate dust scenario changes the model temperatures, which also strongly affects the water cycle.  相似文献   

14.
Global Martian atmospheric results derived from the infrared imaging spectrometer ISM flown aboard the Phobos 2 Soviet spacecraft are presented. Over low altitude regions the expected CO mixing ratio of (8 +/- 3) x 10(-4) is measured. Variations of the 2.35-micrometers feature are inconsistent with this value over the Great Martian Volcanoes. If the 2.35-micrometers band is entirely attributable to carbon monoxide, the CO mixing ratio is typically depleted by a factor of 3 over these high altitude areas. Orography should play a major role in the existence of this CO "hole." If, however, these spectral variations at 2.35 micrometers are due to the surface composition, the fraction of the surface covered by the responsible mineral must smoothly decrease as the surface elevation decreases. This phenomenon implies a strong interaction between the surface and the atmosphere for the Great Martian Volcanoes. Diurnal behavior and latitudinal variations of water vapor are globally consistent with Viking measurements. During the Phobos observations, the water vapor amounts over the bright equatorial regions range around 11 pr-micrometers during the day. These amounts are slightly larger than those inferred from 1976 to 1979. The lack of global dust storms during 1988-1989 could explain the enhancement of H2O in the atmosphere.  相似文献   

15.
The hydrogen isotopic composition of planetary reservoirs can provide key constraints on the origin and history of water on planets. The sources of water and the hydrological evolution of Mars may be inferred from the hydrogen isotopic compositions of mineral phases in Martian meteorites, which are currently the only samples of Mars available for Earth‐based laboratory investigations. Previous studies have shown that δD values in minerals in the Martian meteorites span a large range of ?250 to +6000‰. The highest hydrogen isotope ratios likely represent a Martian atmospheric component: either interaction with a reservoir in equilibrium with the Martian atmosphere (such as crustal water), or direct incorporation of the Martian atmosphere due to shock processes. The lowest δD values may represent those of the Martian mantle, but it has also been suggested that these values may represent terrestrial contamination in Martian meteorites. Here we report the hydrogen isotopic compositions and water contents of a variety of phases (merrillites, maskelynites, olivines, and an olivine‐hosted melt inclusion) in Tissint, the latest Martian meteorite fall that was minimally exposed to the terrestrial environment. We compared traditional sample preparation techniques with anhydrous sample preparation methods, to evaluate their effects on hydrogen isotopes, and find that for severely shocked meteorites like Tissint, the traditional sample preparation techniques increase water content and alter the D/H ratios toward more terrestrial‐like values. In the anhydrously prepared Tissint sample, we see a large range of δD values, most likely resulting from a combination of processes including magmatic degassing, secondary alteration by crustal fluids, shock‐related fractionation, and implantation of Martian atmosphere. Based on these data, our best estimate of the δD value for the Martian depleted mantle is ?116 ± 94‰, which is the lowest value measured in a phase in the anhydrously prepared section of Tissint. This value is similar to that of the terrestrial upper mantle, suggesting that water on Mars and Earth was derived from similar sources. The water contents of phases in Tissint are highly variable, and have been affected by secondary processes. Considering the H2O abundances reported here in the driest phases (most likely representing primary igneous compositions) and appropriate partition coefficients, we estimate the H2O content of the Tissint parent magma to be ≤0.2 wt%.  相似文献   

16.
Richard W. Zurek 《Icarus》1981,45(1):202-215
A δ-Eddington radiative transfer algorithm is used to compute the thermal tidal heating of a dusty Martian atmosphere for a given set of dust optical depth, effective single scattering albedo, and phase function asymmetry parameter. The resulting thermal tidal forcing is used in a classical atmospheric tidal model to compute the amplitudes of the surface pressure oscillations at the Viking Lander 1 site for the two 1977 Martian great dust storms. Parametric studies show that the dust opacities and optical parameters derived from the Viking Lander imaging data are roughly representative of the global dust haze needed to reproduce the tidal surface pressure amplitudes also observed at Lander 1, except that the model-inferred asymmetry parameter is smaller during the onset of a great storm. The observed preferential enhancement during dust-storm onset of the semidiurnal tide at Viking Lander 1 relative to its diurnal counterpart is shown to be due primarily to the elevation of the tidal heating source in a very dusty atmosphere, although resonant enhancement of the main semidiurnal tidal mode makes an important secondary contribution.  相似文献   

17.
A fine grained magnetic iron oxide precipitate found in Denmark has been studied with regard to grain size, magnetic properties, aerosol transport, grain electrification, aggregation and optical reflectance. It has shown itself to be a good Martian dust analogue. The fraction of the Salten Skov I soil sample <63 μm was separated from the natural sample by dry sieving. This fraction could be dispersed by ultrasonic treatment into grains of diameter ～1 μm, in reasonable agreement with suspended dust grains in the Martian atmosphere estimated from the Viking, Pathfinder and Mars Exploration Rover missions. Though mineralogical and chemical differences exist between this analogue and Martian dust material, in wind tunnel experiments many of the physical properties of the atmospheric dust aerosol are reproduced.  相似文献   

18.
The electrification of wind-blown dust grains was studied in a series of laboratory experiments to examine how grain electrification depends on grain size, grain mineralogy, atmospheric composition, atmospheric pressure, and the method of dust dispersal. This work is intended to contribute to a deeper physical understanding of particle electrification on both Mars and Earth. Findings indicate that the amount of electrification per suspended particle generally is independent of dust entrainment process and atmospheric composition. As expected, the electrification process is grain size-dependent, with smaller grains predominantly electrifying negatively. Although there appears to be a weak dependence upon dust mineralogy, this work supports the expectation that dust suspended in the Martian atmosphere will be significantly electrified.  相似文献   

19.
A regional geologic study of Arabia Terra, a densely cratered area of Mars northern hemisphere, has revealed the individuality of this province. This is best expressed by an equatorial belt with a crater age distinctly younger as compared to the northern part of Arabia Terra and to Noachis Terra to the south. We interpret this as an incipient back-arc system provoked by the subduction of Mars lowlands under Arabia Terra during Noachian times. The regional fracture patterns are also best explained in this manner, making it unnecessary to appeal to a rotational instability of the planet, which is not supported by the palaeoclimatic indicators in the area. This model could be the first regional-scale confirmation of Sleep's (1994) hypothesis of a limited plate consumption as an explanation of the martian dichotomy. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

20.
George Ohring 《Icarus》1975,24(3):388-394
The concept is described of deducing the temperature and constituent profile of a planetary atmosphere from orbiter measurements of the planet's ir limb radiance profile. Expressions are derived for the weighting functions associated with the limb radiance profile for a Goody random band model. Analysis of the weighting functions for the Martian atmosphere indicates that a limb radiance profile in the 15 μm CO2 band can be used to determine the Martian atmospheric temperature profile from 20 to 60 km. Simulation of the Martian limb radiance profile in the rotational water vapor band indicates that Martian water vapor mixing ratios can be inferred from limb radiance observations in a water vapor band.  相似文献   

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