共查询到10条相似文献，搜索用时 349 毫秒
1.
Rare earth element (REE) patterns of hydrothermally altered rhyolite from geothermal systems located in the Taupo Volcanic Zone in the North Island of New Zealand provide evidence of REE mobility. REE trends of unaltered rhyolites are characterised by moderate LREE enrichment ((La/Lu)cn = 3.84 to 5.62) and pronounced negative Eu anomalies. In contrast, REE patterns of hydrothermally altered rhyolites commonly exhibit different signatures and may be placed into four chemically and petrographically distinct categories. Rocks with clay + quartz + feldspar + calcite (±zeolites, epidote, sphene, chlorite, opaque minerals) assemblages typically display patterns subparallel to fresh rock, whereas, samples which contain quartz + chlorite, or quartz + clay + zeolite assemblages have flat patterns without Eu anomalies, and highly silicified samples are characterised by depleted, bowed REE trends. These patterns may be produced by interaction with alkaline or acid fluids. A fourth group of very intensely altered samples, affected by interaction with acid fluids, exhibits unusual REE trends with highly enriched HREE and depleted LREE, or depleted HREE.These results indicate that some of the REE released by the breakdown of primary phases during alteration are transported away in the fluid. In addition, the degree of depletion is positively correlated with alteration intensity and the fluid/rock ratio. The similarity of REE patterns resulting from alteration by alkaline and acid fluids suggests that the shape of the REE trends is controlled principally by fluid/rock ratios and secondarily by mineralogy. The REE are retained in rocks with a diverse alteration mineralogy, whereas in samples with only one dominant alteration phase (e.g. quartz) it is more probable that not all REE liberated during alteration can be accommodated in the altered rock. Eu commonly behaves differently from the other REE, possibly due to the dominance of Eu2+. 相似文献
2.
东坪金矿床成矿过程中稀土元素活动性 总被引：8，自引：2，他引：6
尽管稀土元素常被认为是惰性元素,但在热液交代蚀变和化学风化作用过程中具有一定程度的活动性,河北省东坪与碱性岩有关的改进改造型热液金矿床成矿过程中,热液蚀变作用使近矿围岩ＬＲＥＥ／ＨＲＥＥ比值增大,并出现现铈正常异常;石英脉型金矿石的稀土元素分布模式呈出现明显的继承性,脉石矿物石英,钾长石的稀土元素组成相对富ＨＲＥＥ,且在脉石石英出现明显的铕正异常,研究结果表明在中,高温,近中性,较高氧逸度成矿流体 相似文献
3.
“寨背式”离子吸附型稀土矿床多类型稀土矿化及其成因 总被引：1，自引：0，他引：1
赣南寨背离子吸附型稀土矿床产于寨背复式花岗岩体的风化壳中,自20世纪80年代发现以来一直以轻稀土型开采,近年在轻稀土型花岗岩风化壳中发现了重稀土矿。为了探讨轻稀土型花岗岩风化过程中重稀土元素的迁移、分馏和富集机制,本文选择了区内三个具有代表性的风化壳钻孔(ZK1、ZK2和ZK4)对其进行了全相和离子交换相稀土元素地球化学研究。结果显示：钻孔ZK4中离子交换相稀土含量介于14.90×10-6～835.8×10-6之间,并富集轻稀土(LREE/HREE=2.28～10.78);钻孔ZK1中离子交换相稀土含量达1470×10-6(9件样品均值),具有从轻稀土型向重稀土型过渡的配分特征(LREE/HREE=1.30～1.65),并且剖面自上而下显示轻、重稀土逐渐富集的趋势;钻孔ZK2中离子交换相稀土含量为492.4×10-6(8件样品均值),自上而下稀土配分类型从轻稀土型过渡至重稀土型(LREE/HREE=0.43～2.25),且轻稀土富集在全风化层上部而重稀土则富集在下部。三个钻孔的Nb/Ta和Zr/Hf... 相似文献
4.
为了研究木吉村斑岩型铜(钼)矿床蚀变过程中元素的迁移规律,拟推流体演化规律,笔者通过对赋矿闪长玢岩体的强硅化带、钾长石化带、石英绢云母化带、青磐岩化带中分别取样测试分析,利用Grant方程定量探讨了各蚀变带围岩中主量元素、稀土元素和微量元素的带入、带出特征,结果表明:岩浆初始热液流体富K而贫Na。相对原岩(蚀变弱的青磐岩化带),在各蚀变带中Fe_2O_3、MgO、P_2O_5和TiO_2从深部强硅化带到浅部石英绢云母化带总体上由带出变为带入,SiO_2、MnO则与上述大体相反,FeO在各蚀变带主体为带出元素。各稀土元素从深部向浅部石英绢云母化带带入特征明显,同时各蚀变带在稀土元素球粒陨石标准化曲线上表现出斜率一致的右倾型特征,说明轻重稀土分馏较明显,轻稀土富集,重稀土亏损。Cu和Mo在石英绢云母化带中富集尤为明显,其次在钾长石化带也明显富集,即海拔400~500 m为主要的Cu、Mo富集区。 相似文献
5.
对鄂尔多斯盆地中东部奧陶系马家沟组风化壳岩溶储层的碳酸盐岩、硫酸盐岩和碎屑岩类岩石样品以及上覆层本溪组碎屑岩样品所作的稀土元素含量与配分特征分析表明,稀土元素分馏特征与富集特征明显,非可溶岩的稀土元素总含量与富集程度高于可溶岩。轻、重稀土元素关系分析表明,可溶岩的轻稀土元素迁移大于重稀土元素的分馏效应,揭示了可溶岩经历了不同的岩溶环境,马家沟组碎屑岩中的稀土元素与上覆层本溪组底部砂泥岩中的稀土元素是同源的。δEu与δCe分析表明,δEu的活化迁移,反映了表生期岩溶环境的存在,而δCe的相对富集,揭示了埋藏期岩溶的发育及其与天然气生成运聚的密切关系。 相似文献
6.
Susan A. Welch Andrew G. Christy Lloyd Isaacson Dirk Kirste 《Geochimica et cosmochimica acta》2009,73(1):44-177
Major, trace and rare earth element concentrations were measured in porewater, surface water and sediments at an acid sulfate soil site. The concentrations of La and Ce in porewater are up to 1-3 ppm. There is a strong correlation between REE concentration and acidity, except that the maximum concentrations were consistently found below the horizon of maximum acidity, associated with an increase in pH (to ca. 4) and change in mineralogy from jarosite-dominated to goethite-dominated mottles. Jarosite replacement by goethite is as expected with the rise in pH, which in turn is due to the occurrence of a fossil shell bed just below. The rare earth element patterns in the porewaters are enriched in the MREE with respect to Post-Archaean Australian Shale (PAAS). Measurements and calculations show that this is in accord with experiments on low-degree partial dissolution of jarosite, even when the jarosite itself is highly enriched in LREE. There is a clear fractionation in the patterns between the clay-rich soil matrix, which is slightly depleted in the LREE when normalized to PAAS (La/YbPAAS ∼0.5), and the secondary mineral phase jarosite, which is enriched in the LREE (La/YbPAAS = 15-50). The REE pattern in the porewater changes with the transition from jarosite- to goethite-rich mottles, becoming relatively more enriched in the LREE compared to the HREE, which is consistent with the incongruent dissolution of jarosite to form goethite and the release of greater amounts of jarosite REE to solution, including proportionately more of the jarosite-compatible LREE.Maximum surface water REE concentrations in acidic water were 100-200 ppb La and Ce. REE patterns in surface water were very similar to the porewater transition zone, enriched in the MREE, but asymmetric, relatively enriched in the LREE compared to the HREE. 相似文献
7.
Fifty-seven shallow groundwater samples were collected from Guiyang karst basin, China, to analyze the aqueous rare-earth elements in low-water seasons and it is shown that the total amount of rare-earth elements (ΣREE) in karst groundwater is exceedingly low compared with that in carbonate rocks or weathering crusts of carbonate rocks, and ranges from 0.01 to 0.43, from 0.03 to 0.27, from 0.03 to 0.19 and from 0.05 to 1.38 μg·L-1 for dolomite, dolomitic & limestone, limestone and clastic rock aquifer, respectively. Both distributions and contents of rare-earth elements (REE) in karst groundwater reflect the lithology of host rocks or weathering crusts of carbonate rocks through which groundwater flows. The chondrite-normalized patterns show a non-flat profile with higher enrichment of slightly light rare-earth elements (LREE) than heavy rare-earth elements (HREE), prominent fractionation between LREE and HREE, negative Ce anomalies and negative or positive Eu anomalies. There is more obvious fractionation between LREE and HREE in groundwater than that in carbonate rocks and their weathering crusts due to high contents of HCO3? and PH in groundwater. In shallow karst groundwater, REE(CO3)n2n-3 (n=1 and 2) is the main inorganic species of REE. But for a clastic rock aquifer, both REESO4+ and REECO3+ are the main inorganic species of REE. Species of REE in groundwater is closely associated with the hydrochemical type of groundwater which is predominated by the lithology of host rocks, groundwater-rock interaction and weathering-pedogenesis of carbonate rocks. 相似文献
8.
黔桂交界龙胜地区新元古界青白口系上部丹洲群三门街组玄武岩系内部产出条带状流纹英安岩,与玄武岩共同构成了双峰式火山岩组合。玄武岩、流纹英安岩具有过铝质、钙性的特点;稀土元素配分样式为轻稀土元素富集型,轻、重稀土元素分异明显,弱负Eu异常。玄武岩与流纹英安岩均具有富集型洋中脊玄武岩初始地幔标准化微量元素配分曲线的特点,指示其形成于伸展裂谷环境。双峰式火山岩组合的确立,结合已经发表的年代学数据,对正确进行黔桂地区地层对比、构建江南造山带西南段青白口纪构造具有重要意义。 相似文献
9.
Flat rare earth element patterns as an indicator of cumulate processes in the Lesser Qinling carbonatites, China 总被引：1，自引：0，他引：1
Cheng Xu Ian H. Campbell Charlotte M. Allen Zhilong Huang Liang Qi Huan Zhang Guishan Zhang 《Lithos》2007,95(3-4):267-278
The Lesser Qinling carbonatite dykes are mainly composed of calcites. They are characterized by unusually high heavy rare earth element concentrations (HREE; e.g. Yb > 30 ppm) and flat to weakly light rare earth element (LREE) enriched chondrite-normalized patterns (La/Ybn = 1.0–5.5), which is in marked contrast with all other published carbonatite data. The trace element contents of calcite crystals were measured in situ by laser ablation inductively coupled plasma mass spectrometry (LA-ICPMS). Some crystals show reduced LREE from core to rim, whereas their HREE compositions are relatively constant. The total REE contents and chondrite-normalized REE patterns from the cores of carbonate crystals are similar to those of the whole rock. The carbon and oxygen isotopic compositions of calcites fall within the range of primary, mantle-derived carbonatites. The initial Sr isotopic compositions (0.70480–0.70557) of calcites are consistent with an EM1 source or mixing between HIMU and EM1 mantle sources. However these sources cannot produce carbonatite parental magmas with a flat or slightly LREE enrichment pattern by low degrees of partial melting. Analyses of carbonates from other carbonatites show that carbonates have nearly flat REE pattern if they crystallize from a LREE enriched carbonatite melt. This implies that when carbonates crystallize from a carbonatite melt the calcite/melt partition coefficients (D) for HREE are much greater than the D for the LREE. The nearly flat REE patterns of the Lesser Qinling carbonatites can be explained if they are carbonate cumulates that contain little trapped carbonatite melt. Strong enrichment of HREE in the carbonatites may require their derivation by small degrees of melting from a garnet-poor source. 相似文献
10.
贵州水银洞金矿构造蚀变体稀土元素地球化学特征 总被引：3，自引：0，他引：3
水银洞金矿构造蚀变体(SBT)为产出于茅口租(P2m)和龙潭组(P3l)之间不整合面上的一套强硅化灰岩、灰岩角砾岩、硅化粘土岩组合.呆用ICP-MS测定钻孔岩芯中构造蚀变体样品稀土元素组成,对比研究SBT围岩、区域岩浆岩及现代海底热水系统流体稀土元素组成.结果显示,SBT的轻重稀土分馏明显[LREE/HREE=4.92～17.51,(La/Yb)N=5.94～38.37],曲线右倾型;轻稀土分异明显,曲线右倾程度大;重稀土分异不明显,曲线平坦;负Eu(0.61～0.94)、Ce(0.52～1.07)异常明显;SBT及围岩均具有明显W型稀土元素四分组效应,而不同于区域岩浆岩和现代海底热水系统流体,表明热液流体来源以壳源为主. 相似文献