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1.
方柱石是一种含挥发分的架状铝硅酸盐矿物,其成因一直有争议。对喜马拉雅造山带定结地区基性麻粒岩中方柱石及其出溶物的矿物化学和纳米结构分析表明：（1）方柱石为富S类型;（2）内部出溶矿物为陨硫铁,晶胞参数为a=b=0.5968nm,c=1.174nm,α=β=90°,γ=120°;（3）陨硫铁的（001）面平行于方柱石的（100）面。出溶前的方柱石在榴辉岩相条件下形成,其稳定压力上限与Fe含量呈正相关关系。在麻粒岩相作用时,无水条件下方柱石内的SO42-发生自氧化还原反应而产生出溶矿物和O2,反应方程式为：Fe2++SO42-=FeS+2O2。类似反应可能导致下地壳氧逸度高于中上地壳。方柱石的形成与分解记录了喜马拉雅造山带的形成过程,在大陆俯冲与折返过程中扮演重要角色,对地壳深部挥发分的调节起到了重要作用,并对地球深部氧逸度调节机制的研究开拓了新的思路。 相似文献
2.
萨克斯(Saxa)沉积裂谷盆地年龄为19—18亿年的变火山-沉积岩系中产有许多Cu-Zn-Fe-pb-As硫化物矿体,其空间上与原为大陆拉斑玄武质成分的变质基性岩的岩床、岩脉和熔岩流有关。在较高地层层位上,弱硫化物矿化体产于含钠长石-绿泥石-方解石-石英-阳起石的变质基性岩流之下;在较低地层层位上,硫化物矿化体赋存于(a)空间上与富钾、富微斜长石-方柱石或富黑云母/金云母的变质基性岩床和岩脉伴生,(b)变质基性岩流之下,其中钠长石和方解石被微斜长石和方柱石交代。富钠、富钾变质基性岩证实为分别代表细碧岩化和钾蚀变作用的产物。细碧岩化作用期间,Fe、Cu、Co和HREE从基性岩流淋滤出来,表明是变质基性岩和Cu-Fe硫化物矿化体之间的成因联系。细碧岩化作用可能在温度大致为25℃和400℃之间的海底热液系,由于下降的以海水为主的流体与之相互作用而发生的。钾蚀变作用可能发生在温度较细碧岩化作用要高一些的上升流体中。 相似文献
3.
华北内蒙千里山铁矿的方柱石透辉石岩非常发育，根据与国外其他太古代同类岩石对比可知，这种岩石是太古代变质蒸发岩。无论岩石类型，矿物组合还是岩石化学与矿物化学成分都与已知的太古代蒸发岩相吻合。用微量元素Ba-Sr判别泥质岩属于半咸水沉积。特别是含矿岩系的S同位素成分分析更证明千里山铁矿是蒸发岩成因。其黄铁矿样品中δ^34S最大值为5．7‰，最小值为－1．3‰，平均值为1．4‰，方柱石样品δ^34S最大值为2．3‰，最小值为2．1‰平均值为2．2‰。两种样品的δ^34S相差不大，而且都接近0值。接近原始海洋S同位素成分。这也从另一侧面证明了千里山铁矿是太古代蒸发岩成因。 相似文献
4.
该种方法利用离子色谱仪的电导检测器与电化学检测器串联，十几分钟即可连续完成水中S^2-、SO3^2-、SO4^2-、S2O3^2-的测定，方法具有快速，高效，方便，灵敏，选择性好等特点。方法的检出限分别为：S^2-12.5μg/L；SO3^2-22.4μg/L;SO4^2-5.0μg/L；S2O3^2-5.0μg/L。相对标准偏差在1.5%-6.9%之间，能够不中S^2-、SO3^2-、SO4^2-、S2O3^2-四种阴离子分析测试的需要。 相似文献
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6.
金川岩浆铜镍（铂）硫化物矿床是我国最主要的铂族等战略性关键金属宝库。金川矿床中铂族金属的富集过程和富集机制还存在很多争论。本文通过详细的矿物学及矿床学研究,厘定了金川矿床成矿阶段。成矿阶段可划分为硫化物矿浆结晶阶段、挥发分流体作用阶段及热液改造阶段。其中硫化物矿浆结晶阶段的主要矿物组合为镍黄铁矿（Pn- a）- 磁黄铁矿（Po- a）- 黄铜矿（Ccp- a）;挥发分流体作用阶段的主要矿物组合为镍黄铁矿（Pn- b）- 磁黄铁矿（Po- b）- 黄铜矿（Ccp- b）- 黄铁矿（Py- Ⅰ）- 磁铁矿（Mag- Ⅰ）- 菱铁矿- 叶蛇纹石- 磷灰石- 铬铁矿- 白云石- 方解石（Cal- Ⅰ）- 金云母。热液改造阶段的矿物组合为透闪石- 绿泥石- 蛇纹石- 方解石（Cal- Ⅱ）- 磁铁矿（Mag- Ⅱ）。高倍电子探针镜下发现,金川矿床铂族矿物与磁铁矿（Mag- Ⅰ）、黄铁矿（Py- Ⅰ）、铬铁矿、磷灰石、黄铜矿、磁黄铁矿、镍黄铁矿及菱铁矿等共生。金川铜镍硫化物矿床中铂族元素(PGM)矿物主要包括硫砷铱矿（IrAsS）、钯的铋化物、碲化物和硒化物、钯的金属互化物（PdAu2）、砷铂矿（PtAs2）、铂单质以及铂的金属合金（Pt- Fe）。其中大量的PGM分布于镍黄铁矿的裂隙中,或产于镍黄铁矿、磁黄铁矿及蛇纹石裂隙中。与磁铁矿、菱铁矿、铬铁矿、黄铜矿、磷灰石以及叶蛇纹石等矿物共生,指示PGE富集与氧化性流体加入密切相关。金川矿石镍黄铁矿（Pn- b）、磁黄铁矿（Po- b）、黄铜矿（Ccp- b）、黄铁矿（Py- Ⅰ）、磁铁矿（Mag- Ⅰ）以及菱铁矿中高Co含量,表明流体在Co的超常富集过程中也起到了决定性作用。金川矿石中大量碳酸盐矿物、叶蛇纹石、金云母、磁铁矿、黄铁矿、铬铁矿以及富Cl磷灰石的出现;S、Mg元素呈网脉状分布于蚀变橄榄石和硫化物中,推测流体组分可能是一种富C富Cl的富含挥发分的高氧逸度流体。金川铬铁矿、磁铁矿（Ⅰ）、菱铁矿等矿物中高Ti、高Nb含量和高Nb/Ta比值,暗示此流体可能是一种高温的超临界流体。以上特征综合表明该特征流体对金川铜镍硫化物矿床中铂族元素等关键金属的超常富集起到了关键控制作用。当挥发分流体与残余硫化物矿浆相互作用及改造先存硫化物及橄榄石时,不仅会促使Os、Ir、Ru、Rh、Pt、Pd进一步活化、富集,还会导致流体中PGE强烈富集,使得流体中的Pd、Se、Te、Bi、Pt含量不断提高,最终形成大量的PGM。综上所述,本文认为在岩浆演化晚期可能存在一种高氧逸度的富Cl富C的深源流体注入岩浆房,该深源挥发分流体对PGE及Co的迁移和超常富集起到了关键控制作用。 相似文献
7.
伊犁京希—伊尔曼德金矿床的热液蚀变及成矿流体演化特征 总被引：10，自引：1，他引：10
京希－伊尔曼德金矿床的热液蚀变在空间上有明显的分带性，中心蚀变带以强烈的硅化为主，典型的蚀变矿物组合为石英或玉髓和地开石，中间带为高级泥化带，以地开石－高岭石－石英或玉髓为特征；外带为以蒙脱石－高岭石－伊利石－其他粘土矿物等矿物组合为主的泥化带，蚀变强度和矿物组合的分带性是温度、压力和化学梯度的反映，是流体在不断的水或流体－岩石反应和成分交换的产物。该矿床成矿流体演化过程为：早期酸性（pH=2-3)含矿流体在沿断裂上升过程中，受围岩灰岩中的流体（pH为中性）缓冲，在其进入高渗透性的碎屑岩层时，流速和水－岩石或流休－岩石反应大大加快，并在与大气降水的混合作用下，pH值逐步升高（3－5），产生了流体的温度及成分梯度，在温度和压力迅速下降的条件下，金及蚀变矿物沉淀、结晶生长，形成了蚀变空间分带，中心带保存完好的多孔状石英和地开石等高级泥化矿物组合说明该矿床是高硫化热液体系作用下的产物。 相似文献
8.
四川丹巴地区基性，超基性岩型Cu-Ni-Pt族元素矿床中，含有多种Pt族元素矿物，主要有：（1）碲化物及碲铋化物，碲锑化物类，（2）锑化物类，（3）砷化石类，（4）自然元素类，通过显微镜下的观察鉴定和成分电子探针分析结果，分别计算了矿床中主要矿石矿物的结晶化学式，结果表明，矿床中有7种已知的Pt族元素矿物和6种可能是Pt族元素新矿物或新变种矿物。 相似文献
9.
冈底斯岩浆带中段岩浆混合作用：来自花岗杂岩的证据 总被引：14，自引：22，他引：14
巨型冈底斯岩浆岩带横旦于青藏高原南部,主要由花岗质岩石组成,其中存在大量的镁铁质微粒包体,以辉长岩为主的基性岩相对集中在岩浆岩带南部.辉长岩类与花岗质岩石呈渐变过渡关系.辉长岩中出现有石英,暗色矿物沿着长石颗粒边部分布,花岗闪长岩中出现有基性倍长石（An＞80）,辉长岩中有中长石（An=45）出现,镁铁质微粒包体（MME）包体中倍长石-钙长石（An=72～90）和中长石（An=37）共存,这些矿物组合的不协调现象是岩浆演化过程中混合作用的表现形式;MME的化学成分相对高钾、铝和铁镁,MME、花岗岩类寄主岩及辉长岩类岩石化学成分呈直线变异趋势（相对MgO）,MME的SiO2和K2O、Na2O成分的过渡性变化也都反映出混合作用特征;基性辉长岩类、酸性花岗质岩石和MME包体的稀土配分模式基本一致,其微量元素特征也具有明显的一致性,反映了岩浆混合作用的特征;辉长岩类的^143Nd/^144Nd比值较高,^87Sr/^86Sr比值较低,而偏酸性的花岗质岩石中^143Nd/^144Nd比值较低,^87Sr/^86Sr比值较高,构成直线性分布趋势,并位于地幔演化线的延伸方向上,显示区域岩浆混合作用特征;辉长岩、花岗岩类和MME的同位素年龄值十分接近,也表明三者属于岩浆混旌献饔貌？研究证明,冈底斯岩浆岩带中不同岩性均由不同比例的基性端元和酸性端元成分混合而成,其中基性端元成分所占的比例变化在16%～90%不等,仅从侵入岩浆推算,幔源基性岩浆对冈底斯地壳垂向增厚的贡献率超过5%.可以推断,随着俯冲-碰撞过程中产生的基性岩浆底侵作用,冈底斯岩浆岩带发生壳幔岩浆混合作用,其时代为50～45Ma,属于印度-欧亚大陆碰撞开始15Ma后的主碰撞期内,岩浆混合作用是碰撞过程中壳幔物质与成分交换的主要形式之一,是研究主碰撞带北部青藏高原的陆壳增生与改造、地壳结构及成分变化重要途径之一. 相似文献
10.
东南极拉斯曼丘陵硼硅酸盐矿物组合硅硼镁铝矿-硼柱晶石-电气石的形成过程及其岩石学意义 总被引：1，自引：0，他引：1
东南极拉斯曼丘陵长英质片麻岩中产出大量的电气石-硼柱晶石-硅硼镁铝矿之硼硅酸盐矿物组合,这些矿物(电气石除外)的形成晚于变质峰期一般的硅酸盐矿物。电气石可多次出现,硅硼镁铝矿之后形成硼柱晶石,很少见两种以上的硼硅酸盐矿物能够同时结晶,各种硼硅酸盐矿物在同一期、甚至同一阶段内呈递进关系。在硼硅酸盐矿物的结晶过程中,B2O3和Al2O3较为活动从而SiO2的活度相对受到抑制,即存在组分的分异和活性波动,表明络阴离子SiO44-、PO43-、BO33-活动高峰并非同步因而,挥发分组分对深熔作用的影响可能是有限的;同时,结晶的金属阳离子组分不断发生分异。不同的硼硅酸盐矿物形成的介质条件有所差异:电气石形成于富钙的弱酸性溶液,硅硼镁铝矿应为近中-碱性溶液介质,而硼柱晶石形成于含少量氟的偏碱性介质环境。除温压因素外,流体挥发分种类和介质条件也影响到硼硅酸矿物的多期次、多阶段的变化,从而造成矿物组合的复杂性。本区长英质岩石中硼(B)及其他挥发分组分的较高含量可由原岩成分决定,亦可经由变质-深熔作用引起,即深熔作用时熔体的整体优先吸收硼(硼的第一次富集)及随后熔体结晶阶段的局部残留和富集硼(硼的第二次富集)。Gdd-Prs-Trn硼硅酸盐矿物组合的存在,表明发生了以脱水为主的高级变质作用,同时伴随强烈的深熔作用。挥发分组分在露头尺度体系中可能属于开放性质,而在更大尺度和范围内则基本封闭;在深熔作用中,硼等挥发分的存在影响了熔体的组成使得岩浆熔点降低、熔融成分调整粘度有所降低,更容易运移;而且,熔体可以携带这些挥发分,当熔体结晶时挥发分析出、结晶局部富集而形成硼硅酸盐矿物,尤其是沿着一些构造有利部位发生显著的聚集。 相似文献
11.
Scapolite–wollastonite–grossular bearing calc-silicate rocks from the Vellanad area in the Kerala Khondalite Belt (KKB) of Southern India preserve a number of reaction textures which help to deduce their P–T–fluid history. Textures include calcite+plagioclase±quartz symplectites after scapolite, grossular+quartz coronas between wollastonite and plagioclase, grossular coronas between wollastonite and plagioclase+calcite that replace former scapolite, and grossular blebs replacing anorthite+calcite+quartz pseudomorphs of scapolite. Garnet coronas are also observed between clinopyroxene and wollastonite or scapolite or plagioclase. The reactions, apart from those involving clinopyroxene, can be modelled in the simple CaO–Al2O3–SiO2–CO2 system and interpreted using partial reaction grids constructed for the activities of end-members in the analysed phases. The reaction topologies produced are good approximations for the peak as well as retrograde mineral assemblages and reaction textures. For the compositions of the phases present in this study, the medium pressure calc-silicate assemblages are defined by the stable pseudo-invariant points [Qtz], [Mei] and [Grs]. The textural features interpreted using these activity-corrected grids indicate a phase of isobaric cooling from about 835°C to 750°C at 6 kbar in the Vellanad area. This is inconsistent with earlier studies on other lithologies from the KKB, most of which imply a post-peak P–T path involving near-isothermal decompression. However, as the temperatures obtained for the KKB from the calc-silicates are higher than those previously deduced from metapelites and garnet–orthopyroxene assemblages, the phase of near-isobaric cooling reported here is inferred to have proceeded prior to the onset of the decompression documented from studies of other rock types. 相似文献
12.
Evolution of metamorphic fluid recorded in granulite facies metacarbonate rocks from the middle segment of the Mogok metamorphic belt in central Myanmar 总被引：1，自引：0，他引：1 
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下载免费PDF全文 The Mogok metamorphic belt of Palaeogene age, which records subduction‐ and collision‐related events between the Indian and Eurasian plates, lies along the western margin of the Shan plateau in central Myanmar and continues northwards to the eastern Himalayan syntaxis. Reaction textures of clinohumite‐ and scapolite‐bearing assemblages in Mogok granulite facies metacarbonate rocks provide insights into the drastic change in fluid composition during exhumation of the collision zone. Characteristic high‐grade assemblages of marble and calcsilicate rock are clinohumite+forsterite+spinel+phlogopite+pargasite/edenite+calcite+dolomite, and scapolite+diopside+anorthite+quartz+calcite respectively. Calculated petrogenetic grids in CaO–MgO–Al2O3–SiO2–H2O–CO2 and subsets of this system were employed to deduce the pressure–temperature–fluid evolution of the clinohumite‐ and scapolite‐bearing assemblages. These assemblages suggest higher temperature (>780–810°C) and [=CO2/(CO2+H2O) >0.17–0.60] values in the metamorphic fluid for the peak granulite facies stage, assuming a pressure of 0.8 GPa. Calcite grains commonly show exsolution textures with dolomite particles, and their reintegrated compositions yield temperatures of 720–880°C. Retrograde reactions are mainly characterized by a reaction zone consisting of a dolomite layer and a symplectitic aggregate of tremolite and dolomite grown between clinohumite and calcite in marble, and a replacement texture of scapolite by clinozoisite in calcsilicate rock. These textures indicate that the retrograde reactions developed under lower temperature (<620°C) and (<0.08–0.16) conditions, assuming a pressure of 0.5 GPa. The metacarbonate rocks share metamorphic temperatures similar to the Mogok paragneiss at the peak granulite facies stage. The values of the metacarbonate rock at peak metamorphic stage are, however, distinctly higher than those previously deduced from carbonate mineral‐free paragneiss. Primary clinohumite, phlogopite and pargasite/edenite in marble have F‐rich compositions, and scapolite in calcsilicate rock contains Cl, suggesting a contrast in the halogen compositions of the metamorphic fluids between these two lithologies. The metamorphic fluid compositions were probably buffered within each lithology, and the effective migration of metamorphic fluid, which would have extensively changed the fluid compositions, did not occur during the prograde granulite facies stage throughout the Mogok metamorphic belt. The lower conditions of the Mogok metacarbonate rocks during the retrograde stage distinctly contrast with higher conditions recorded in metacarbonate rocks from other metamorphic belts of granulite facies. The characteristic low conditions were probably due to far‐ranging infiltration of H2O‐dominant fluid throughout the middle segment of the Mogok metamorphic belt under low‐amphibolite facies conditions during the exhumation and hydration stage. 相似文献
13.
The occurrence and origin of marialitic scapolite in the Humboldt lopolith was investigated in the field and in the laboratory using petrographic and experimental techniques. Scapolite occurs in three modes: as a pervasive replacement of plagioclase and other minerals in gabbro, diorite and extrusive rocks; as a poikiloblastic mineral in scapolitite dikes; and as a fracture-filling mineral with analcime, albite and sphene in scapolite veins. Additional secondary minerals associated with scapolite include epidote, prehnite, hornblende and diopside-salite clinopyroxene. Relations with these minerals suggest that most marialitic scapolite grew at temperatures around 400° C. Scapolite composition varies from EqAn12 to EqAn37, containing from 72 to 96 atomic% Cl in the R position. Experiments on systems of similar compositions indicate that NaCl-H2O fluid having more than 40 mol% NaCl is needed to stabilize the scapolite.Variation in scapolite compositions is due to thermal and fluid compositional gradients normal to conduits of hydrothermal fluids, and occurs on a scale up to 100 m. The likely source of Na and Cl is pre-existing evaporites or evaporitic brine derived from the wallrocks. Salinity could have been increased to a level sufficient to stabilize scapolite by hydration of an originally dry magma, possibly aided by hydrothermal boiling. Results may be applied to hydrothermal alteration in areas of rifting or back-arc spreading, and in mid-ocean ridge hydrothermal systems. 相似文献
14.
Essentially isochemical thermal metamorphism of soda-rich Stockton, Lockatong and Brunswick formations of the Newark Group by diabase sills produced unusually varied and unique mineral assemblages, most of which are predominantly Na. feldspar and biotite. Within a meter of a sill Stockton arkose was altered to quartzo-feldspathic hornfels with common diopside and sphene. Within 50 m of a sill Lockatong calcitic and dolomitic mudstone formed calc-silicate hornfels with differing combinations of diopside-hedenbergite, andradite and grossular, prehnite, datolite, idocrase and wollastonite. Within a meter of a sill metamorphosed Lockatong calcareous feldspathic argillite contains sanidine-anorthoclase, aegirine, aegirine-augite, riebeckite and scapolite. Lockatong analcime-dolomite argillite was altered to unique feldspathoidal assemblages containing cancrinite, natrolite-thomsonite and rarely sodalite within 134 m, and nepheline within 30 m of the Byram Sill. Reddish-brown Brunswick mudstone produced spotted pelitic hornfels within a few 10's of meters of a sill.Response to thermal metamorphism varied directly with diminishing grain size. In both sandstone and mudstone Na. feldspar increases and K. feldspar decreases toward intrusions; quartz is rare or absent in highest-grade hornfels. Development of biotite was retarded by detrital clay minerals and hematite pigment, as well as by low temperature. Minor differences in composition among carbonate-rich and analcime-rich Lockatong deposits led to a diversity of closely associated assemblages. Aqueous solutions and relatively low temperature, probably in part during retrogressive metamorphism, produced hydrous minerals. Datolite, tourmaline, scapolite and fluorite suggest minor additions of volatiles, but the widespread feldspathoids were made from soda-rich sedimentary rocks without significant additions from an igneous source. 相似文献
15.
On Baffin Island, the major minerals in lapis lazuli are calcite, lazurite, diopside, nepheline and phlogopite in the Main Occurrence and calcite, lazurite, diopside, plagioclase and scapolite in the North Occurrence. The abundances of Na, K, S, Cl, Br, F and Fe, the well-developed layering parallel to the regional foliation, and the scarcity of intrusive rocks, support the hypothesis that the deposit evolved from an evaporite parent during regional metamorphism. After sedimentation, considerable reduction of sulfur was effected by CO, perhaps aided by H2, Cl? and anaerobic bacteria. Chemographic analysis suggests that the observed phase assemblages represent local equilibrium within small volumes, where SiO2-Al2O3-MgO-Na2O-K2O behaved as inert components at the peak of metamorphism. The lack of systematic zoning of phase assemblages, and the uniformity of mineral compositions within the deposit, also argue against a metasomatic origin. Most phases equilibrated at or near the peak of metamorphism (granulite facies). 相似文献
16.
Scapolite in granulite facies terranes provides a reservoir for volatile components such as sulphur and carbon in rocks that are otherwise considered ‘dry’. Formed at lower crustal conditions, the high‐S end‐member of scapolite, silvialite, is a major host of sulphur in granulites. Compositional and textural changes involving scapolite reveal that S‐rich scapolite becomes unstable during hydration and deformation at amphibolite facies conditions. Either scapolite changes composition, whereby SO42? is exchanged for CO32? or Cl? in its structure, or scapolite is replaced by amphibole and/or epidote. Sulphur that is released from silvialite is deposited as sulphides within the original silvialite grain boundaries and can remain relatively immobile in undeformed anorthosites. However, increased sulphide mobility is evident in areas of increased deformation and hydration. Reactions involving S‐bearing scapolite not only have important implications for sulphide deposition and the S‐cycle, but may also influence conductivity variation in the lower crust. 相似文献
17.
Metamorphic evolution of calcsilicate granulites near Battye Glacier, northern Prince Charles Mountains, East Antarctica 总被引：4，自引：0，他引：4
Calcsilicate granulites of probable Middle Proterozoic age ( c .1000–1100 Ma) in the vicinity of Battye Glacier, northern Prince Charles Mountains, East Antarctica, contain prograde metamorphic assemblages comprising various combinations of wollastonite, scapolite, clinopyroxene, An-rich plagioclase, calcite, quartz, titanite and, rarely, orthoclase, ilmenite, phlogopite and graphite. Comparison of the prograde assemblages with calculated and experimentally determined phase relations in the simple CaO–Al2 O3 –SiO2 –CO2 –H2 O system suggests peak metamorphism at ≥835 °C in the presence (in wollastonite-bearing assemblages at least) of a CO2 -bearing fluid ( X CO ≥0.3) at a probable pressure of 6–7 kbar.
Well-preserved retrograde reaction textures represent: (1) breakdown of scapolite to anorthite+calcite±quartz; (2) formation of grossular–andradite garnet and, locally, (3) epidote, both principally by reactions involving scapolite breakdown products and clinopyroxene; (4) local coupled replacement of clinopyroxene and ilmenite by hornblende and titanite, respectively; and finally (5) local sericitization of prograde and retrograde plagioclase. These retrograde reactions are interpreted to be the result of cooling and variable infiltration by H2 O-rich fluids, possibly derived from crystallizing pegmatitic intrusions and segregations that may be partial melts, which are common throughout the area. 相似文献
Well-preserved retrograde reaction textures represent: (1) breakdown of scapolite to anorthite+calcite±quartz; (2) formation of grossular–andradite garnet and, locally, (3) epidote, both principally by reactions involving scapolite breakdown products and clinopyroxene; (4) local coupled replacement of clinopyroxene and ilmenite by hornblende and titanite, respectively; and finally (5) local sericitization of prograde and retrograde plagioclase. These retrograde reactions are interpreted to be the result of cooling and variable infiltration by H
18.
Fluid-rock history of granulite facies humite-marbles from Ambasamudram, southern India. 总被引：1，自引：0，他引：1
An extensive humite‐bearing marble horizon within a supracrustal sequence at Ambasamudram, southern India, was studied using petrological and stable isotopic techniques to define its metamorphic history and fluid characteristics. At peak metamorphic temperatures of 775±73°C, based on calcite‐graphite carbon isotope thermometry, the mineral assemblages suggest layer‐by‐layer control of fluid compositions. Clinohumite + calcite‐bearing assemblages suggest XCO2 < 0.4 (at 700°C and 5 kbar), calcite + forsterite + K‐feldspar‐bearing assemblages suggest XCO2>0.9 (at 790°C); and local wollastonite + scapolite + grossular‐bearing zones formed at XCO2 of c. 0.3. Retrograde reaction textures such as scapolite + quartz symplectites after feldspar and calcite and replacement of dolomite + diopside or tremolite+dolomite after calcite+forsterite or calcite+clinohumite are indicative of retrogression under high XCO2 conditions. Calcite preserves late Proterozoic carbon and oxygen isotopic signatures and the marble lacks evidence for extensive retrograde fluid infiltration, while during prograde metamorphism the possible infiltration of aqueous fluids did not produce significant isotopic resetting. Isotopic zonation of calcite and graphite grains was likely produced by localized CO2 fluid infiltration during retrogression. Contrary to the widespread occurrence of humite‐marbles related to retrograde aqueous fluid infiltration, the Ambasamudram humite‐marbles record a prograde‐to‐peak metamorphic humite formation and retrogression under conditions of low XH2O. 相似文献
19.
Evidence for pre-regional metamorphic fluid infiltration of the Lower Calcsilicate Unit, Reynolds Range Group (central Australia) 总被引：1，自引：0，他引：1
Grandite garnet-rich calcsilicate rocks from the Lower Calcsilicate Unit of the regionally metamorphosed Reynolds Range Group (central Australia) crop out along a strike-parallel section in which a transition zone from M22 amphibolite to granulite facies rocks is exposed. Across this transition the grandite-rich layers do not show systematic changes in mineral assemblages, compositions and modes, or stable isotope compositions. These layers are deformed by F22 folds that are associated with the peak of regional low-pressure/high-temperature metamorphism. Therefore, the grandite-rich layers appear to pre-date regional metamorphism and to have acted as closed chemical systems during prograde M22 metamorphism. Mineral assemblages in the grandite-rich layers are consistent with their formation through the infiltration of oxidized, water-rich fluids (Xco2 < 0.1–0.3; log fo2 -16 to -14). The stable isotope values of calcite (Δ13C=-4.2 to -0.8%0 PDB; Δ18O = 10.5–14.0%0 V-SMOW) and bulk-silicate fractions (Δ18O = 6.1 to 10.8%) of the grandite-rich layers are most consistent with the infiltrating fluid being from a magmatic source. It is most likely that fluid infiltration occurred during the pre-M22 contact metamorphism (M21) that affected much of the Reynolds Range Group. The preservation of these assemblages is probably due to their high variance and little pervasive fluid-rock interaction having occurred during M22. The clinopyroxene- and feldspar-rich calcsilicate rocks that host the grandite-rich layers contain poikiloblastic grandite garnet that formed during prograde M22 metamorphism. Thin marbles that locally occur with the grandite-rich layers contain a third garnet generation that is post- or late M22. This grossular-rich garnet occurs in coronas around calcite, plagioclase, clinopyroxene, wollastonite and scapolite. These coronas are consistent with cooling and/or compression. However, because the marble assemblages are themselves overprinted by M21 grandite-rich layers the development of coronal garnet does not reflect a continuous P-T-t path. Rather, it more probably reflects the partial re-equilibration of M21 contact metamorphic assemblages to post-M22 conditions. 相似文献
20.
Bruce G. Aitken 《Geochimica et cosmochimica acta》1983,47(3):351-362
At a total pressure of 5 kb, calcic, Cl-free scapolite (Me83) is stable relative to plagioclase-bearing assemblages at , . With decreasing temperature, scapolite breaks down to plagioclase + calcite. Scapolite is replaced by plagioclase + grossular + cancrinite + CO2 in the presence of H2O-rich fluids. The stable coexistence of scapolite and calcite, an assemblage typical of most natural occurrences of calcic scapolite, is limited by the reaction: scapolite + calcite → grossular + cancrinite + CO2, which occurs at 750°C, XCO2 = 0.46; 700°C, XCO2 = 0.33; 650°C, XCO2 = 0.18, for the chosen bulk composition.Generalization of the experimental results to encompass the complete range of fully carbonated scapolite compositions indicates that mizzonite (Me75) has the largest T-XCO2 stability field. For scapolite more calcic than mizzonite, stable growth is restricted to conditions of increasingly higher temperature and XCO2.The experimental results are consistent with various petrologic features of scapolite-bearing rocks, particularly scapolite-clinopyroxene granulites, and indicate that such rocks were formed in the presence of CO2-rich fluids. 相似文献