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1.
Discovery of Pyrrhotite-Chalcopyrite-Bearing Amphibole Megacrysts in Tongling Area, Anhui Province 总被引：1，自引：0，他引：1
Some pyrrhotite-chalcopyrite-bearing amphibole megacrysts (including pyroxene megacrysts) were discovered in Mesozoic augite diorite-porphyrite at Caoshan in Tongling area, Anhui Province. The amphibole megacrysts, belonging mainly to pargasite and magnesiohastingsite, are characteristic of the amphibole composition derived from mantle and crystallized in lower crust. In general, the aggregates of pyrrhotite-chalcopyrite take the shapes of cylinder and sphere. Three occurrences have been recognized in the amphibole megacrysts: parallel linear, bunchy and scattered. The unique cylinder-like shape of the aggregates and remarkable Ni-poor sulfides in Caoshan are distinctively different from the spherical Ni-rich sulfides in pyroxene megacrysts and any other kinds of megacrysts. In terms of composition, the amphibole megacrysts and their sulfides in Caoshan are similar to those in the pyroxenite xenoliths in Qilin, Guangdong Province. In terms of origin, the pyrrhotite-chalcopyrites as exsolution products resulted from the subsolidus re-equilibration of sulfide solid solution within amphibole megacrysts.amphibole megacrysts were first discovered inside and outside China. This discovery is important for the study of regional magma evolution and its associated mineralizations and ore sources as well. 相似文献
2.
Jean H. Bédard 《Contributions to Mineralogy and Petrology》2001,141(6):747-771
Equilibrium melt trace element contents are calculated from Proterozoic Nain Plutonic Suite (NPS) mafic and anorthositic cumulates, and from plagioclase and orthopyroxene megacrysts. Assumed trapped melt fractions (TMF) <20% generally eliminate all minor phases in most mafic cumulate rocks, reducing them to mixtures of feldspar, pyroxene and olivine, which would represent the high-temperature cumulus assemblage. In anorthosites, TMF <15% generally reduce the mode to a feldspar-only assemblage. All model melts have trace element profiles enriched in highly incompatible elements relative to normal mid-ocean ridge basalt (NMORB); commonly with negative Nb and Th anomalies. Most mafic cumulates yield similar profiles with constant incompatible element ratios, and can be linked through fractional crystallization. High K-La subtypes probably represent crust-contaminated facies. Mafic cumulates are inferred to belong to a tholeiitic differentiation series, variably contaminated by upper and lower crustal components, and probably related to coeval tholeiitic basaltic dyke swarms and lavas in Labrador. Model melts from anorthosites and megacrysts have normalized trace element profiles with steeper slopes than those calculated from mafic cumulates, indicating that mafic cumulates and anorthosites did not crystallize from the same melts. Orthopyroxene megacrysts yield model melts that are more enriched than typical anorthositic model melts, precluding an origin from parental melts. Jotunites have lower K-Rb-Ba-Y-Yb and higher La-Ce than model residues from fractionation of anorthositic model melts, suggesting they are not cosanguineous with them, but provide reasonable fits to evolved mafic cumulate model melts. Incompatible element profiles of anorthositic model melts closely resemble those of crustal melts such as tonalites, with steep Y-Yb-Lu segments that suggest residual garnet in the source. Inversion models yield protoliths similar to depleted lower crustal granulite xenoliths with aluminous compositions, suggesting that the incompatible trace element budget of the anorthosites are derived from remobilization of the lower crust. The similarity of the highly incompatible trace elements and LILE between anorthositic and mafic cumulate model melts suggests that the basalts parental to the mafic cumulates locally assimilated considerable quantities of the same crust that yielded the anorthosites. The reaction between underplating basalt and aluminous lower crust would have forced crystallization of abundant plagioclase, and remobilization of these hybrid plagioclase-rich mushes then produced the anorthosite massifs. 相似文献
3.
Types of Enclaves and Their Features and Origins in Intermediate-Acid Intrusive Rocks from the Tongling District, Anhui Province, China 总被引：9，自引：0，他引：9
WU Cailai WANG Zhihong QIAO Dewu LI Haibing HAO Meiying SHI Rendeng Institute of Geology Chinese Academy of Geological SciencesXi''an Engineering College Geological Mechanics Institute CAAGS 《《地质学报》英文版》2000,74(1):54-67
Enclaves in intermediate-acid plutons from Tongling can be divided into three types: xenoliths, relics and magmatogenic enclaves. The magmatogenic enclaves consist of cumulates, micrograined dioritite mixtite and dioritic chilled border enclaves. Petrologically, relics with eyed and meta-poikilitic texture are characterized by high content of biotite (>80%) and low content of cordierite and grossular. The cumulates with accumulate texture consist of a great amount of pyroxene, hornblende and minor spinel and phlogopite. The micrograined dioritic mixtite is composed of more hornblendes and feldspar and less needle apatites and an ellipsoid basic core included in plagio-clase. The chilled border enclaves have the same mineral association, but more dark minerals than the host rocks consisting of plagioclase, quartz, alkaline feldspar, hornblende and biotite. Geochemically, the relics exhibit high REE content (455.8×10-6) and high ratio of LREE/HREE, more obvious Eu negative anomaly and are rich in Cr and 相似文献
4.
目前对华北克拉通北缘早二叠世基性-超基性岩成因有不同认识, 其中, 一种流行的观点是它们与"安第斯型大陆边缘"的活动有关.通过对冀东地区堆晶岩的研究对这一观点进行了讨论.华北克拉通北缘断续分布了受丰宁-隆化岩石圈断裂控制的早二叠世基性-超基性堆晶岩, 堆晶岩的SHRIMP锆石U-Pb年龄为280~300 Ma.通过岩相学的研究, 确认这是一套由纯橄岩、橄辉岩、辉石岩、角闪岩、辉长岩、闪长岩、斜长岩等不同岩性组成的堆晶岩, 进一步可分为层状堆晶岩和环状堆晶岩, 它们有着明显的堆晶结构.矿物学研究显示堆晶岩中角闪石、辉石、金云母等均具有高镁、高铬的幔源组分特征.不同组分堆晶岩的Sr/Ba比值不随熔融程度变化, 具有分离结晶的趋势.相近的稀土配分形式和过渡族元素组成显示了它们的同源性.从本区晚古生代和早中生代堆晶岩的对比中, 结果表明早二叠世这期堆晶岩具有初始裂谷岩浆的特征, 它传递了华北克拉通陆壳从稳定向活动转化的最早信息.从区域角度看, 这期活动有着更大范围的深部动力学背景. 相似文献
5.
6.
Anorthoclase megacrysts commonly occur with low pressure cumulate nodules (olivine + clinopyroxene + kaersutite ± oligoclase) in alkali basalts and their differentiates. The absence of anorthoclase from the cumulate nodules indicates that anorthoclase remained suspended in the magma while the other minerals sank, forming the cumulates, assuming a congeneric origin for megacrysts and nodules. On this basis, density calculations indicate that anorthoclase crystallised from a magma of approximately trachyandesitic composition, while the anorthoclase megacrysts usually occur in magmas more basic than trachybasalt. Thus, the anorthoclase megacrysts and the associated cumulate nodules did not crystallise from the host magma, but were picked up from a high-level partly crystallised magma pool containing a more evolved alkali basaltic differentiate by a later surge of more basic liquid which then carried both anorthoclase megacrysts and fragmented cumulates to the surface. 相似文献
7.
中国东部新生代玄武岩中巨晶矿物的地球化学 总被引：13，自引：0，他引：13
本文对安徽女山、河北汉诺坝和广东普宁碱性玄武岩中的单斜辉石和角闪石巨晶进行了主要元素、稀土元素、微量元天和Ｓｒ＿Ｎｄ同位素的综合分析。数据显示产出于３个研究区的单斜辉石巨晶有３类：Ａｌ普通辉石、透辉石和Ｆｅ＿Ｎａ透辉石。普宁地区的角闪石巨晶乃世界上罕见的绿钙闪石巨晶。女山和普宁的单斜辉石和角闪石巨晶是碱性玄武岩浆在幔源高压下的结晶产物；汉诺坝的单斜辉石巨晶既可以是碱性玄武岩浆又可以是拉斑玄武岩浆的高压结晶体。所有巨晶相对于寄主岩者属于偶然捕掳晶。巨晶的形成符合“流动结晶模式”。它们与共存的橄榄岩色体无成因 相似文献
8.
9.
天宇和白石泉铜镍矿区含矿镁铁-超镁铁质杂岩体是东疆铜镍成矿带的重要组成部分。天宇矿区杂岩体以角闪辉长岩、角闪单辉橄榄岩、橄榄辉石岩、二辉辉石岩为主;白石泉矿区杂岩体则以辉石闪长岩、角闪辉长岩、橄榄辉石岩、辉石辉长岩、辉石橄榄岩、橄长岩为主;天宇矿区含矿超基性岩中SiO2,Al2O3,CaO,K2O,Na2O的质量分数比白石泉岩体低,Fe2O3,MgO相对较高;两个杂岩体的主要造岩矿物均以橄榄石、辉石、斜长石为主;铜镍矿石的矿物组成都较简单,金属矿物种类基本一致;两个杂岩体基性-超基性岩的成分接近原始岩浆,均来自于地幔,均属含铜镍中等的镁铁质岩石。 相似文献
10.
元古宙岩体型斜长岩的特征及研究现状 总被引：1，自引：0，他引：1
斜长岩是指斜长石含量>90%的岩浆岩,可分为6类。其中,岩体型斜长岩仅赋存于前寒武纪变质地体中,形成时代主要为元古宙（2.1~ 0.9 Ga）,代表地球演化史上很重要的构造-热事件。岩体呈穹隆状或层状产出,具典型堆晶结构,有含钾长石和斜长石出溶片晶的巨晶斜长石和富铝辉石。巨晶的出溶指示了岩浆由高压至低压的变压结晶过程,体现了斜长岩体深成、浅侵位的特点。关于斜长岩的源区,之前普遍认为源于幔源玄武质岩浆,而近10年来更趋向于源区为下地壳,母岩浆的成分为纹长苏长岩和铁闪长岩等新认识;其成因模式以底侵模式和地壳舌状物熔融模式最具代表性。岩体型斜长岩时空上常与奥长环斑花岗岩共生,构成AMCG（Anorthosite Mangerite Charnockite Granite）岩石组合,被认为属非造山岩浆作用的产物,可能代表大陆裂谷环境。然而,新近一些年龄结果显示,它们形成于造山作用的后期阶段,暗示岩体产出于碰撞后环境。斜长岩体中常赋存有Fe Ti V氧化物矿床,有的富含P及Cu,Ni硫化物等,属典型的岩浆矿床。对此,目前主要有结晶分异过程、早期堆晶过程及不混熔分离3种成因机制解释。由此对今后研究中值得关注的问题提出了一些看法。 相似文献
11.
ABSTRACTTongling, in eastern China, is an area well-known for intra-plate adakites. Here, we present the mineral chemistry and zircon U–Pb ages for amphibole cumulate xenoliths, the mineral chemistry of amphibole megacrysts, and the whole–rock chemistry, zircon U–Pb age and Sr–Nd isotopic compositions of host gabbros from Tongling. Zircon U–Pb dating yields a crystallization age of 120.6 ± 1.2 Ma (MSWD = 4.2) for the host gabbros, which are characteristically depleted in high field strength elements (Nb, Ta, and Ti) and enriched in large ion lithophile elements (Ba and Sr), with εNd (t) of ?3.00 to ?4.52 and initial 87Sr/86Sr ratios of 0.7068–0.7072, suggesting an enriched mantle source. Parental melts, as estimated from average amphibole megacryst and cumulate compositions, have Mg# values of 26–33, are enriched in Ba, Th, U, and Nd, and depleted in Nb, Ta, Zr, Hf, and Ti, similar to 136 Ma mafic magmas in Tongling. Zircon U–Pb dating yields a crystallization age of 135.4 ± 1.0 Ma (MSWD = 1.6) for the amphibole cumulates. It is concluded that the Tongling adakitic rocks were formed by polybaric crystallization involving early high-pressure intracrustal fractional crystallization of cumulates comprising hornblende and clinopyroxene, and late low-pressure fractional crystallization of hornblende and plagioclase phenocrysts. The flat subduction of Pacific plate and its subsequent foundering during the Cretaceous may have triggered the generation of extensive adakitic magmas and lithospheric thinning in the Lower Yangtze Region. 相似文献
12.
Sherif Kharbish 《Chemie der Erde / Geochemistry》2010,70(3):257-266
Wadi El-Markh gabbro–diorite complex is composed of pyroxene hornblende gabbros, hornblende gabbros, diorites and quartz diorites. According to their bulk rock geochemistry and mineral chemistry, the gabbroic and dioritic rocks represent fractionates along a single line of descent and crystallized from a calc-alkaline mafic magma. When compared to the primitive mantle, all members of the gabbroic–dioritic rock suite are enriched in the large ion lithophile elements relative to the high field strength elements and display distinctive negative Nb and P2O5 anomalies. This signals an arc setting. Fractionation modeling involving the major elements reveals that the hornblende gabbros were generated from the parent pyroxene hornblende gabbros by 61.86% fractional crystallization. The diorites were produced from the hornblende gabbros by fractional crystallization with a 58.97% residual liquid, whereas the quartz diorites were formed from the diorites by 26.58% fractional crystallization. According to geothermobarometry based on amphibole mineral chemistry, the most primitive pyroxene hornblende gabbros crystallized at ～830 °C/～5 kbar. The crystallization conditions of the quartz diorites were estimated at ～570 °C/～2 kbar. In consequence the Wadi El-Markh gabbro–diorite complex represents a single magmatic suite of which fractionates crystallized in progressively shallower levels of an arc crust. 相似文献
13.
我国东部苏鲁皖地区新生代碱性玄武岩中,除了含有大量地幔橄榄岩类捕虏体以外,尚含有一定数量的石榴石、普通辉石和歪长石巨晶。这些巨晶是在地幔不同深度上从玄武岩中晶出的。巨晶组合的分离结晶作用对熔体稀土元素含量有很大影响。赋存巨晶的碱性玄武岩所具有的LREE富集、HREE亏损的稀土元素分配型式是由地幔橄榄岩类部分熔融程度、石榴石巨晶和普通辉石巨晶的早期高压熔离和玄武岩的结晶分异作用等综合因素造成的。 相似文献
14.
胶州大西庄玄武岩（73 Ma）中的辉石巨晶与寄主玄武岩具有几乎完全相同的同位素组成,其87Sr/86Sr（t）和εNd（t）分别为0.703 3～0.704 1、+4.5～+6.5和0.703 5～0.703 8、+7.1～+7.6,暗示辉石巨晶和寄主岩具有相同的地幔源区,即辉石巨晶是玄武岩浆在高压下结晶的产物.亏损的同位素特征表明：在白垩世末期（～73 Ma）,胶东地区的岩石圈地幔已经由富集转变为亏损,表现出类似于中国东部新生代地幔的同位素特征,即表明当时岩石圈减薄（或置换）已经完成. 相似文献
15.
西藏羌塘地区火山岩主要见于第三系石坪顶组，主要岩石类型是呈熔岩被产出的火山熔岩，包括辉石粗安岩、角闪粗面岩、角闪英安岩、黑云母英安岩等，其次可见次火山岩相的黑云母英安质碎斑熔岩和黑云母粗面质碎斑熔岩，以及辉石黑云母花斑岩．它们均为陆相中心式喷发的产物．岩石化学上属钾玄岩组合，可进一步分为钾玄岩系列和高硅钾玄岩系列，具非常典型的二元岩浆混合成因火山岩的岩石化学特征．其ＲＥＥ及微量元素特点表明二元岩浆混合前两个端元岩浆分别来自幔源和壳源．这些火山岩岩浆热事件对盆地有机烃类转化为石油和天然气是有利的，而破坏作用仅仅发生在火山机构附近 相似文献
16.
1 Introduction The Gaojiacun intrusive complex is one of the numerous ultramafic-mafic intrusions in Sichuan Province of China. It was mapped during the 1970s and studied mainly by Chinese scientists (e.g. Geological Team 106, 1975; Shen et al., 1986, 1989; CGGJC, 1986; Yang et al., 1993; Li et al., 1995; Shen et al., 2003; Zhu et al., 2004a). Since the year 2000, China has become one of the largest PGE consumers. While the country can produce only less than 1 ton PGE/year, the Chin… 相似文献
17.
Harry Becker 《Contributions to Mineralogy and Petrology》1997,128(2-3):272-286
High-temperature peridotite massifs occur as lensoid bodies with high-pressure granulites in the southern Bohemian massif.
In lower Austria the peridotites comprise garnet lherzolites lacking primary spinel, rare garnet and garnet-spinel harzburgites,
and harzburgites containing Cr-rich primary spinel instead of garnet. These phase assemblages suggest initial high-pressure
equilibration and are consistent with results from garnet-orthopyroxene geobarometry indicating equilibration at around 3–3.5 GPa.
Maximum temperature estimates obtained on core compositions of coexisting minerals from the peridotites are not higher than
ca. 1100 °C. In contrast, pyroxene megacryst compositions, garnet exsolution textures in the garnet pyroxenites, and results
from geothermometry indicate much higher original equilibration temperatures in most of the pyroxenites (up to 1400 °C). High
temperatures, modal zoning, the occasional presence of Mg-rich garnetites and chemical evidence suggest that the pyroxenites
are cumulates which crystallized from low-degree melts derived from the sub-lithospheric mantle. Isothermal interpolation
of the high temperatures to an upper mantle adiabat suggests that the melts were derived from a minimum depth of 180–200 km.
The formation of small garnet II grains and garnet exsolution lamellae in the pyroxenites and pyroxene megacrysts may reflect
isobaric cooling of the cumulates from temperatures above 1400 °C to ca. 1100–1200 °C (at 3–3.5 GPa) to approach the ambient
lithospheric isotherm. This model differs from other models in which the formation of garnet II was explained by an increase
in pressure during cooling in a subduction zone. Isobaric cooling was followed by near-isothermal decompression from 3–3.5 GPa
to 1.5–2 GPa at 1000–1200 °C, as indicated by the increase of Al in pyroxenes near garnet. Further cooling in the spinel lherzolite
stability field is indicated by spinel exsolution lamellae in pyroxenes from lherzolites. The formation of symplectites and
kelyphites indicate sub-millimetre scale re-equilibration during exhumation in the course of the Carboniferous collision in
the Bohemian massif. The peridotite massifs represent fragments of normal (non-cratonic) lithospheric mantle from a Paleozoic
convergent plate margin.
Received: 22 July 1996 / Accepted 28 February 1997 相似文献
18.
Prograde and retrograde history of eclogites from the Eastern Blue Ridge, North Carolina, USA 总被引：4，自引：1，他引：4
Abstract The prograde metamorphism of eclogites is typically obscured by chemical equilibration at peak conditions and by partial requilibration during retrograde metamorphism. Eclogites from the Eastern Blue Ridge of North Carolina retain evidence of their prograde path in the form of inclusions preserved in garnet. These eclogites, from the vicinity of Bakersville, North Carolina, USA are primarily comprised of garnet–clinopyroxene–rutile–hornblende–plagioclase–quartz. Quartz, clinopyroxene, hornblende, rutile, epidote, titanite and biotite are found as inclusions in garnet cores. Included hornblende and clinopyroxene are chemically distinct from their matrix counterparts. Thermobarometry of inclusion sets from different garnets record different conditions. Inclusions of clinozoisite, titanite, rutile and quartz (clinozoisite + titanite = grossular + rutile + quartz + H2O) yield pressures (6–10 kbar, 400–600 °C and 8–12 kbar 450–680 °C) at or below the minimum peak conditions from matrix phases (10–13 kbar at 600–800 °C). Inclusions of hornblende, biotite and quartz give higher pressures (13–16 kbar and 630–660 °C). Early matrix pyroxene is partially or fully broken down to a diopside–plagioclase symplectite, and both garnet and pyroxene are rimmed with plagioclase and hornblende. Hypersthene is found as a minor phase in some diopside + plagioclase symplectites, which suggests retrogression through the granulite facies. Two‐pyroxene thermometry of this assemblage gives a temperature of c. 750 °C. Pairing the most Mg‐rich garnet composition with the assemblage plagioclase–diopside–hypersthene–quartz gives pressures of 14–16 kbar at this temperature. The hornblende–plagioclase–garnet rim–quartz assemblage yields 9–12 kbar and 500–550 °C. The combined P–T data show a clockwise loop from the amphibolite to eclogite to granulite facies, all of which are overprinted by a texturally late amphibolite facies assemblage. This loop provides an unusually complete P–T history of an eclogite, recording events during and following subduction and continental collision in the early Palaeozoic. 相似文献
19.
N.-O. Prægel 《Lithos》1981,14(4):305-322
Spinel lherzolite nodules, composed of olivine (Fo88.7?89.2), clinepyroxene (6.5% Al2O3) and Al-rich spinel, and websterite nodules as well as megacrysts of clinopyroxene, orthopyroxene and magnetite occur in a monchiquite at Streap, Scotland. Petrographic data are given and microprobe analyses of coexisting phases in six spinel lherzolite nodules and one websterite nodule are reported, along with analyses of both types of pyroxene megacrysts. The spinel lherzolites show internal chemical homogeneity, and their mineral chemistries suggest equilibrium conditions of 1100–1200°C and 14–23 kb. The websterite nodules are, on the basis of mineral chemistry and petrography, considered to be crustal material. The megacrysts constitute a separate group, differing in composition from analogous phases in associated lherzolites and websterites as well as from monchiquite phenocryst phases, and show systematic chemical variations corresponding to low pressure crystal fractionation processes. 相似文献