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1.
The distributions of iodide, iodate and total iodine were determined along a transect from the Sargasso Sea and across the Gulf Stream to the continental shelf of the South Atlantic Bight during November 1990. The western boundary of the Gulf Stream at the outer shelf-upper slope was characterized by steeply sloping isotherms and isopleths of iodide and iodate, resulting from a dome of cold water that was rich in iodate and nearly devoid of iodide at the slope. Both the mid and the inner shelf were relatively well mixed vertically. The concentration of iodate in the surface waters decreased shoreward from >0.3 μM in the Sargasso Sea/Gulf Stream/outer shelf, to 0.29 μM in the midshelf, 0.19 μM in the outer-inner shelf and 0.11 /IM in the inner-inner shelf. Concomitantly, the concentration of iodide increased from <161 nM to 175 nM, 257 nM and 300 nM. The concentration changes were more abrupt in the inner-inner shelf within about 30 km from the shore. There was no evidence of significant concentrations of organic iodine. These distributions of iodide and iodate suggest that the South Atlantic Bight may act as a geochemical processor of dissolved iodine. Iodate is added to the shelf during topographically induced upwelling and frontal exchange with the Gulf Stream. In the shelf waters, iodate is reduced to iodide in situ. Iodide is exported from the shelf to the Gulf Stream which may eventually further transport it to the ocean interior. A ☐ model calculation suggests that 28% and 43% of the iodate added to the Bight and the inner shelf, respectively, are converted to another form in these waters, almost all of which is iodide. About a third of the reduction of iodate to iodide in the Bight occurs in the inner shelf. Thus, the inner shelf may be the most geochemically active zone within the Bight. The residence times of iodide relative to its production and that of iodate relative to its removal are 3.1 and 3.6 months in the Bight and 0.9 and 1.8 months in the inner shelf.  相似文献   

2.
Tritium data were collected between 1985 and 1987 on several cruises of the German research icebreaker “Polarstern” to the Weddell Sea. Maximum tritium concentrations in the surface waters are of the order of 200 mTU. The minimum values observed in the Weddell Sea Deep Water at about 1000 m depth are about 15–40 mTU. The bottom waters show tritium concentrations of about 70–100 mTU in the central gyre, increasing to about 120 mTU in the northwestern corner of the Weddell Sea. The overflowing Ice Shelf Water observed on the continental slope west of the Filchner Depression has tritium concentrations close to those of the surface waters, indicating rapid renewal of this water mass. The data reflect the rapid renewal of the bottom waters in the northwestern corner of the Weddell Sea and the mixing of bottom water from this boundary current into the bottom waters of the central Weddell Gyre.  相似文献   

3.
In the Scotia and Weddell Seas the concentration of dissolved Al was 1–1.5 nM in ice-free surface waters, up to 3 nM in ice-covered waters and about 2.6 nM in bottom waters. The solubility and the dissolution rate of diatomaceous silica, obtained from net samples and from incubations in the presence or absence of dissolved Al, were inversely related to solid-phase Al/Si ratios. At in situ temperatures, dissolution rates for Antarctic diatoms are higher than those for diatoms from temperate regions. Effects on distribution patterns of silicic acid in the Weddell Sea are discussed.  相似文献   

4.
Transient tracer data (tritium, CFC11 and CFC12) from the southern, central and northwestern Weddell Sea collected during Polarstern cruises ANT III-3, ANT V-2/3/4 and during Andenes cruise NARE 85 are presented and discussed in the context of hydrographic observations. A kinematic, time-dependent, multi-box model is used to estimate mean residence times and formation rates of several water masses observed in the Weddell Sea.Ice Shelf Water is marked by higher tritium and lower CFC concentrations compared to surface waters. The tracer signature of Ice Shelf Water can only be explained by assuming that its source water mass, Western Shelf Water, has characteristics different from those of surface waters. Using the transient nature of tritium and the CFCs, the mean residence time of Western Shelf Water on the shelf is estimated to be approximately 5 years. Ice Shelf Water is renewed on a time scale of about 14 years from Western Shelf Water by interaction of this water mass with glacial ice underneath the Filchner-Ronne Ice shelf. The Ice Shelf Water signature can be traced across the sill of the Filchner Depression and down the continental slope of the southern Weddell Sea. On the continental slope, new Weddell Sea Bottom Water is formed by entrainment of Weddell Deep Water and Weddell Sea Deep Water into the Ice Shelf Water plume. In the northwestern Weddell Sea, new Weddell Sea Bottom Water is observed in two narrow, deep boundary currents flowing along the base of the continental slope. Classically defined Weddell Sea Bottom Water (θ ≤ −0.7°C) and Weddell Sea Deep Water (−0.7°C ≤ θ ≤ 0°C) are ventilated from the deeper of these boundary currents by lateral spreading and mixing. Model-based estimates yield a total formation rate of 3.5Sv for new Weddell Sea Bottom Water (θ = −1.0°C) and a formation rate of at least 11Sv for Antarctic Bottom Water (θ = −0.5°C).  相似文献   

5.
Atmospheric iron and underway sea-surface dissolved (<0.2 μm) iron (DFe) concentrations were investigated along a north–south transect in the eastern Atlantic Ocean (27°N/16°W–19°S/5°E). Fe concentrations in aerosols and dry deposition fluxes of soluble Fe were at least two orders of magnitude higher in the Saharan dust plume than at the equator or at the extreme south of the transect. A weaker source of atmospheric Fe was also observed in the South Atlantic, possibly originating in southern Africa via the north-easterly outflow of the Angolan plume. Estimations of total atmospheric deposition fluxes (dry plus wet) of soluble Fe suggested that wet deposition dominated in the intertropical convergence zone, due to the very high amount of precipitation and to the fact that a substantial part of Fe was delivered in dissolved form. On the other hand, dry deposition dominated in the other regions of the transect (73–97%), where rainfall rates were much lower. Underway sea-surface DFe concentrations ranged 0.02–1.1 nM. Such low values (0.02 nM) are reported for the first time in the Atlantic Ocean and may be (co)-limiting for primary production. A significant correlation (Spearman's rho=0.862, p<0.01) was observed between mean DFe concentrations and total atmospheric deposition fluxes, confirming the importance of atmospheric deposition on the iron cycle in the Atlantic. Residence time of DFe in the surface waters relative to atmospheric inputs were estimated in the northern part of our study area (17±8 to 28±16 d). These values confirmed the rapid removal of Fe from the surface waters, possibly by colloidal aggregation.  相似文献   

6.
The Arabian Sea is characterised by strong seasonal oscillations of biological productivity generated by its monsoonal climate. The southwest monsoon causes reversal in the surface circulation of the Arabian Sea, which generates a seasonal upwelling of nutrient-rich waters along the coast of Oman. Concentrations of biogenic sulphur compounds were measured on a transect from the eutrophic waters off the coast of Oman to the oligotrophic waters of the open Arabian Sea, during the UK NERC Arabesque cruise 27 August–4 October 1994. The concentrations of dimethylsulphide (DMS), dimethylsulphoxide (DMSO) and dimethylsulphoniopropionate (DMSP) were found to be elevated in the eutrophic area due to enhanced biological production. However, this increase in DMS, DMSO and DMSP concentration was not observed until after the southwest monsoon had relaxed, and appeared to correspond to increased concentrations of hexanoyloxyfucoxanthin, an indicator of prymnesiophytes. DMSO concentrations were correlated with those of DMS and DMSP in the near surface waters of the Arabian Sea. Additionally, DMSO appeared to be ubiquitous throughout the water column, being easily detectable in deep waters, which suggests that DMSO may act as a sink for DMS in the world’s oceans.  相似文献   

7.
Iodide oxidation to iodate in near-surface waters of the open oceans is an elusive process, and an unequivocal demonstration of it would simplify modelling of the marine iodine system. In the open ocean, the upward advection of iodate complicates any mathematical treatment of the problem. In this context, the high concentration (0.1 μM) of iodate in the Black Sea surface waters suggested that this Sea might be a place where oxidation might be demonstrated. Hydrologically, the surface waters of the Black Sea appear to be downstream of the deeper waters and, given the latter's anoxicity, the surface waters seemed likely to gain most of their iodine as iodide by upward advection. To test this further, prior to experimentation, an iodine budget for the near-surface waters, based upon the latest hydrological model of the Sea was prepared; this predicts a minimum oxidation flux of 3.89×10−4 mol I m−2 a−1. The chemistry of this oxidation is discussed in the light of existing knowledge of the sulfide system. It is argued that as the redox potential of the IO3−/I− and I2/I− couples at pHs typical of the Black Sea (7.75) are much higher than that of the sulfate–sulfide couple, iodide is probably oxidized in the near-surface domain. This contrasts with sulfide oxidation in the suboxic zone. The possible role of nitrifying bacteria in the oxidation is discussed.  相似文献   

8.
Wintertime temperature-salinity properties of the southeastern Hwanghae (Yellow Sea) were analysed, based on long-term hydrographic data gathered between 1961 and 1980. A strong thermohaline front is formed in the area west of Cheju-do (along 33?40′N in the region bounded by 124? E and 126?20′E) during winter and extends to the bottom. This surface-to-bottom front, running from west to east, divides water properties into two types: one type of low temperature and low salinity to the north of the front and another one of high temperature and high salinity to the south of the front. The existence of the front suggests that there is no northward flow in the study area, a finding which runs counter to the conventional belief that there is the Hwanghae Warm Current carrying waters of high temperature and salinity to the north. T-S diagrams show that in winter the Hwanghae Warm Current Water and the Hwanghae Cold Water are the representative water masses in the study area.  相似文献   

9.
The circulation pattern and volume transports in the eastern Weddell Gyre are estimated on the basis of hydrographic data collected by R.V. Polarstern between 1989 and 1996. In the northeastern edge of the Weddell Gyre, eastward-flowing water masses from the Antarctic Circumpolar Current and the Weddell Sea converge. Due to the strong effect of topographic constraints on ocean currents in the weakly stratified waters of high latitudes, the wedge-like structure of the Southwest Indian Ridge can cause the convergence. The increased shear leads to instabilities of the current at the eastern end of the ridge, which produce an intense mesoscale eddy field between 15° and 30°E. In the eddies, water from the Weddell cold regime and the Antarctic Circumpolar Current waters mix and form the water masses of the Weddell warm regime. These waters are advected southward and flow towards the westward southern rim current, which is driven by the Antarctic eastwind band. Hence, there is not a continous flow from the northern to the southern rim, but a decay of the mean flow in the northeast and a reformation in the south. Volume transports across the Greenwich Meridian, estimated on the basis of a combined CTD/ADCP data set, result in an eastward flow of 61 Sv in the northern rim current and a westward return flow of 66 Sv in the southern part of the gyre. The transport is about twice as high as previous estimates between Kapp Norvegia and the northern tip of the Antarctic Pensinsula, indicating a significant gyre circulation north of 70°S.  相似文献   

10.
南极半岛周边海域水团及水交换的研究   总被引：1，自引：1，他引：0  
利用中国第34次南极考察于2018年1–2月在南极半岛周边海域获得的温盐、海流现场观测数据,分析了调查区域主要水团及水交换特征。结果表明,观测区域内主要存在南极表层水、绕极深层水、暖深层水、南极底层水、布兰斯菲尔德海峡底层水。威德尔海的暖深层水、威德尔海深层水通过南奥克尼海台东侧的奥克尼通道、布鲁斯通道和南奥克尼海台西侧的埃斯佩里兹通道进入斯科舍海,其中奥克尼通道的深层海流最强,流速最大可达0.25 m/s,密度较大的威德尔海深层水可以通过此通道进入斯科舍海;布鲁斯通道海流流速约为0.13 m/s,通过此通道的暖深层水位势温度较高;埃斯佩里兹通道海流流速约为0.10 m/s,通过此通道的暖深层水位势温度最低,威德尔海深层水密度最小。在南奥克尼海台东西两侧均观测到南向和北向的海流,但整体上来看,向北的海流和水交换更强。水体进入斯科舍海后,沿着南斯科舍海岭的北侧向西北方向流动,流速约为0.21 m/s。德雷克海峡中的南极绕极流仅有一部分向东进入斯科舍海南部海域,且受到向西流动的暖深层水、威德尔海深层水的影响,斯科舍海南部海域的绕极深层水明显比德雷克海峡中绕极深层水的高温高盐性质弱;受到南极绕极流的影响,南斯科舍海岭北侧的威德尔海深层水比南侧暖。南斯科舍海岭上的水体可能受到北侧绕极深层水、暖深层水,西侧陆架水,东侧冬季水的影响,因此海岭上水体结构较为复杂。  相似文献   

11.
Qualitative and quantitative analyses of the tintinnids retrieved in surface and vertical (down to 1150 m ) samples in the Scotia, Weddell, Bransfield and Bellingshausen areas allow us to define three distinct zones: (A) the Scotia Sea, Bransfield Strait and oceanic waters of the northern-central Weddell Sea, dominated by Codonelopsis gaussi and Cymatocylis affinis/conmllaria; (B) shelf and mostly ice-covered areas of the southernmost Weddell Sea and the Bellingshausen Sea, characterized by Laackmanniella prolongata and Cymatocylis drygalskii; (C) Bransfield-Weddell waters around the tip of the Antarctic Peninsula, where Codonellopsis balechi accounts for 80% of the tintinnids. These areas have (often significantly) different ice regimes, water-column depths, surface salinities, bulk planktonic settling volumes and microplanktonic concentrations. On the other hand, the composition of tintinnid assemblages is very similar on both sides of the Antarctic Peninsula. Causal interpretations for these heterogeneous distribution patterns and probable specific adaptations to the dissimilar environmental settings involved are analyzed.  相似文献   

12.
Sukhanova  I. N.  Flint  M. V.  Fedorov  A. V.  Sakharova  E. G.  Artemyev  V. A.  Makkaveev  P. N.  Nedospasov  A. A. 《Oceanology》2019,59(5):648-657
Oceanology - The studies were conducted along the transect (11 stations) from the inner part of Khatanga Bay in the south to the Laptev Sea continental slope in the north in September 17—20,...  相似文献   

13.
Regions of the formation of the thermal front in the Baltic Sea (a direct manifestation of the lacustrine thermal bar), and its specific features, were analyzed on the basis of subsurface temperature and salinity. Data were obtained from 25 horizontal tows along sections in the southern and central parts of the Baltic Sea during spring 2010 and autumn/winter 2010/2011. The width of the front was approximately 5?C30 km, and the front lifetime was 1.5 months. Horizontal temperature ranged from 0.7 to 2.5°C; thus, the temperature gradient was one- to twofold larger than the long-term monthly mean equivalent. Analysis of hourly temperature and salinity data from the Arkona basin and at the Darss Sill, obtained at 2 m depth, indicated that the surface temperature increased during the transition through temperatures of maximum density at a rate of approximately 0.01?C0.02°C/h between 3?C5 days; which is 1.4- to 5-fold higher than values before and after this period. The thermal front simultaneously propagated along the main sea axis (due to the significant salinity and buoyancy flux variations from south to north), and from the shallow parts towards the deep parts of the Baltic Sea. Therefore, the horizontal advection of the cold/warm waters clearly contributes to the speed increase of the thermal front at the end of the respective season. The speed of the thermal front propagation from south to north was approximately 28 km/day at the end of the spring period of 2010 (based on field data). This was considerably higher in comparison with the typical values of the lacustrine thermal bar speeds; however, it accords with estimates for a basin with depth/salinity horizontal variation.  相似文献   

14.
黄海西部2005—2007年海雾演变的气候特征研究   总被引：2，自引：0，他引：2  
海雾对沿海地区的交通运输、工农业生产等影响很大,需要开展深入研究,以探索其生消演变规律。本文选择黄海西部的成山头、青岛、海阳、日照等4个测站为代表性测站,分析了2005—2007年海雾发生期间的位势高度、海温、海表面风场、相对湿度、稳定度及散度等要素场特征,着重探讨了海雾演变的气候特征。研究结果表明:500 hPa高空槽前位于黄海上空时有利于成雾;海温异常低的年份雾日较多;风向、散度和低层的层结稳定度是影响黄海海雾的主要因素;地理位置也是影响黄海海雾变化的重要因子;黄海海雾的水平分布具有南北空间不一致的特点。  相似文献   

15.
Measurements of total dissolved arsenic (As(III+V)) and antimony (Sb(III+V) and their simple methylated species are presented for samples collected from three vertical profiles and along three surface transects in the Chatham Rise region, east of New Zealand. As(III+V) concentrations showed a slight increase with depth (16–17 nM at 25 m to 20 nM at 100 m) whereas Sb(III+V) concentrations were conservative with depth (1.02–1.12 nM). Along the three surface water transects, As(III+V) and Sb(III+V) concentrations showed little variation, with average concentrations of 18±2 and 0.99±0.05 nM, respectively. Inorganic arsenic was not correlated with orthophosphate (r2=0.01). Monomethyl- and dimethyl-arsenic (MMAs, DMAs) concentrations (0.04–0.01 and 0.65–0.07 nM, respectively) decreased with depth, suggesting surface water production by biota and degradation at depth. Along the Chatham Rise transect, DMAs concentrations increased on the Rise (0.65 nM maximum) compared to waters north and south of the Rise (∼0.22 nM). Fluctuation in MMAs concentrations were also seen for water samples collected on the Chatham Rise. Monomethyl-, dimethyl- and trimethyl-antimony (MMSb, DMSb, TMSb) species were detected in water samples collected along all the three surface water transects suggesting surface water production by biota. Concentrations of MMSb, DMSb and TMSb in water samples were fairly constant along all the three surface transects (0.06–0.07, 0.015–0.025 and 0.005–0.015 nM, respectively), showing no significant enrichment on the Chatham Rise. These arsenic and antimony results support the current global view that inorganic As and Sb are conservative and the methyl species are of biological origin.  相似文献   

16.
Aerosol (soluble and total) iron and water-column dissolved (DFe, < 0.2 μm) and total dissolvable (TDFe, unfiltered) iron concentrations were determined in the Canary Basin and along a transect towards the Strait of Gibraltar, in order to sample across the Saharan dust plume. Cumulative dust deposition fluxes estimated from direct aerosol sampling during our one-month cruise are representative of the estimated deposition fluxes based on near surface water dissolved aluminium concentrations measured on board. Iron inventories in near surface waters combined with flux estimates confirmed the relatively short residence time of DFe in waters influenced by the Saharan dust plume (6–14 months). Enhanced near surface water concentrations of DFe (5.90–6.99 nM) were observed at the Strait of Gibraltar mainly due to inputs from metal-rich rivers. In the Canary Basin and the transect towards Gibraltar, DFe concentrations (0.07–0.76 nM) were typical of concentrations observed in the surface North Atlantic Waters, with the highest concentrations associated with higher atmospheric inputs in the Canary Basin. Depth profiles showed that DFe and TDFe were influenced by atmospheric inputs in this area with an accumulation of aeolian Fe in the surface waters. The sub-surface minimum of both DFe and TDFe suggests that a simple partitioning between dissolved and particulate Fe is not obvious there and that export may occur for both phases. At depths of around 1000–1300 m, both regeneration and Meddies may explain the observed maximum. Our data suggest that, in deep waters, higher particle concentrations likely due to dust storms may increase the scavenging flux and thus decrease DFe concentrations in deep waters.  相似文献   

17.
The chemical speciation of iron was determined in the Southern Ocean along a transect from 48 to 70°S at 20°E. Dissolved iron concentrations were low at 0.1–0.6 nM, with average concentrations of 0.25±0.13 nM. Organic iron complexing ligands were found to occur in excess of the dissolved iron concentration at 0.72±0.23 nM (equivalent to an excess of 0.5 nM), with a complex stability of log KFeL′=22.1±0.5 (on the basis of Fe3+ and L′). Ligand concentrations were higher in the upper water column (top 200 m) suggesting in situ production by microorganisms, and less at the surface consistent with photochemical breakdown. Our data are consistent with the presence of stable organic iron-complexing ligands in deep global ocean waters at a background level of ∼0.7 nM. It has been suggested that this might help stabilise iron at levels of ∼0.7 nM in deep ocean waters. However, much lower iron concentrations in the waters of the Southern Ocean suggest that these ligands do not prevent the removal of iron (by scavenging or biological uptake) to well below the concentration of these ligands. Scavenging reactions are probably inhibited by such ligand competition, so it is likely that biological uptake is the chief cause for the further removal of iron to these low levels in waters that suffer from very low iron inputs.  相似文献   

18.
A study of inorganic iodine speciation in the waters of seven Croatian coastal caves is described. These are anchialine caves as they are connected hydraulically with Adriatic Sea surface water, with the tide inside the cave rising and falling with that outside, but replenishment of the water is restricted by the karst rock. In effect, the water in the cave probably acts more like a piston, and although moving slightly vertically, has a long residence time compared to a fully-flushing cave. Anchialine environments display a number of unusual features, e.g., a well-developed pycnocline, hypoxia and endemic fauna. Iodate and iodide were determined by differential pulse voltammetry and cathodic stripping square wave voltammetry, respectively. Low iodide concentrations (< 10 nM) have been consistently identified in the bottom water of the caves where concentrations of 90–100 nM would ordinarily be expected from intrusion of Eastern Adriatic surface seawater. Where total inorganic iodine concentrations behave conservatively with salinity the loss of the iodide implies oxidation to iodate. As iodide oxidation remains one of the enduring academic problems of the marine iodine system the study of iodine in anchialine caves may help unravel it. Iodate reduction was observed in mid-water, at the halocline, and mechanisms for the reduction involving either respiration or chemolitho-autotrophic bacteria are considered. The respiration mechanism is favoured because of enhanced alkalinity found in the near surface waters of the caves.  相似文献   

19.
The most plausible scenarios for seasonal to interannual variabilities and their possible causes are investigated for the Tsushima Current system passing through the Japan Sea. The study is based on the north and south two-box model across the polar front in an idealized upper ocean of the Japan Sea. The boxes are connected by lateral diffusive heat transport and cooled by atmospheric forcing at the annual mean state. The south box, i.e. the Tsushima Current region, only interacts with the outside warmer box in the East China Sea and has an eastward thermal-driven current originating in the outside box. The magnitude of this current depends on the strength of the thermal gradient between the north and south boxes; the inflow of warm waters can therefore be maintained by net heat loss through the sea-surface. I call such a thermal-driven inflow process a "Cooling-Induced Current" system in the present study. Under periodical heat forcing, the perturbation response of the model to water temperature fields and inflow transport were examined. It is shown that the lateral diffusion time across the polar front (over a period of 10 years) is crucial to the interannual modeled response. An analysis of the seasonal heat budget suggests that the heat transported into the Japan Sea from the East China Sea in summer is stored mainly within the Tsushima Current region and contributes to heat loss by the sea-surface cooling in winter.  相似文献   

20.
南极威德尔海水动力环境的变化及其对全球变化的响应有着重要的意义,近百年来以全球变暖为特征的全球变化已经影响到该地。对南极威德尔海北部ANT28-D5-6短柱沉积物进行了210Pb测年、粒度参数和冰筏碎屑物含量的测试分析。结果显示威德尔海北部在近百年时间内(1922—2011年)水动力环境发生了显著的转变。在1922—1972年间,威德尔海北部处在高能高速动荡的水动力环境,并携带沉积了大量的冰筏碎屑物,对应了全球温度变化相对较低的阶段。但在1930—1936年间和1946—1952年间发生了2次水动力减弱事件。1939年和1950年两次冰筏碎屑物含量的增加可能与太阳活动峰年引起的威德尔环流经向增强有关。1972—2011年威德尔海北部处在较为平静的弱能状态,对应了全球气温持续升温的阶段。1955—1972年威德尔海水动力环境处在从高能动荡的状态向低能静水状态快速过渡的阶段。  相似文献   

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