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1.
武都黄土剖面稀土元素研究 总被引：9，自引：0，他引：9
武都剖面晚更新世以来黄土的稀土元素地球化学分析结果表明，轻重稀土元素具有比黄土高原其他地区较强烈的分异作用，而这种强烈的分异作用，与其较高的粘土矿物含量及其吸附作用相关；另一方面，武都稀土元素具有与其他地区黄土相似的稀土分布模式；反映沉积物来源的特征参数显示，武都黄土与黄土高原典型剖面十分一致，故具相同来源。 相似文献
2.
腾格里沙漠南缘武威黄土沉积元素地球化学特征 总被引：18，自引：1，他引：18
对腾格里沙漠南缘武威黄土剖面１８个样品系统的元素地球化学分析结果表明，剖面中８种常量元素氧化物总量平均值为８８.９９%，且整个剖面中变化微弱（８７.２６%～９０.４６%），显示了构成武威黄土物质组成的均一性；反映风化程度的Ｆｅ２Ｏ３/ＦｅＯ和Ａｌ２Ｏ３/ＳｉＯ２，值变化较为明显，平均值分别为１.４６（１.０２～２.８６）和０.１９（０.１７～０.２２）；稀土元素总含量平均值为１８５.４２（１６９.３１～１９９.８２）μｇ/ｇ，稀土分布斜率较大、有较明显Ｅｕ异常，ΣＬＲＥＥ/ΣＨＲＥＥ值平均为８.２３（７.３８～９.６０），表现出较显著的轻重稀土的分镏作用，指示着一定程度的风化作用；而代表原岩特征的稀土参数Ｅｕ/Ｓｍ、Ｓｍ/Ｎｄ、Ｎｄ/Ｌａ、δＣｅ、δＥｕ等变化不大，反映了不同时代黄土物质来源的一致性 相似文献
3.
位于长江中游的鄱阳湖地区深受东亚季风影响,因其特殊的地理、地貌与水文、水系特征,自中更新世以来随着冬季风的加强,在大姑组、九江组砾石层之上风成堆积广泛发育。该区域中、上更新统表现为网纹红土、均质红土和下蜀黄土的独特沉积序列,厘清这三套独特沉积序列的物质来源对于我们认识东亚季风演化及其区域环境响应至关重要。本文选择了长江中游鄱阳湖地区10个典型剖面,基于<20μm颗粒组分的元素地球化学特征,研究了该地区中、上更新统粉尘堆积的特点,并将其与黄土高原西峰黄土和东秦岭黄土做了对比分析。研究认为,长江中游鄱阳湖地区这套独特的沉积序列,元素特征基本相似,具有贫Co、Pb,富Zr、Hf,低Eu/Eu^*(0.53~0.62)、LaN/YbN(4~8)、Ta/Zr(0~0.006)、Nb/Zr(0~0.09),高Y/Ho(28~30)、Zr/Hf(36~48)等特点,与黄土高原与东秦岭黄土有显著区别。基于Hf-Th-Co、Th-Sc-Zr/10和Th-Sc-La蜘蛛图投影分析,鄱阳湖地区第四纪粉尘物质的源岩接近于石英岩类,为被动大陆边缘构造背景下的产物,显著区别于黄土高原与东秦岭黄土(源岩接近于页岩,形成于大陆岛弧构造背景)。进一步分析认为,网纹红土、均质红土的母质均与区域下蜀黄土类似,推测它们均来自于其冬季风上风方向的长江或赣江的古河谷漫滩,这套独特的沉积序列是第四纪以来长江中游现代格局的水系贯通后,冬季风增强,吹蚀大江大河广阔的古河谷漫滩而形成的区域粉尘堆积的结果;是湿热的亚热带季风区对于中更新世以来在轨道尺度上冬夏季风均加强的背景下独特的区域响应。 相似文献
4.
珠江三角洲地区上更新统与全新统之间广泛发育1层杂色黏土,其成因多认为主要是由上更新统沉积物在末次冰盛期暴露于地表风化而成。对取自珠江三角洲3条钻孔（PRD09、PRD16和PRD17）的岩心样品分析表明,受风化作用的影响,其稀土元素含量和分异特征发生了较明显的变化。杂色黏土层的稀土总量大大低于下伏沉积物,而在邻近风化层的下伏沉积物中稀土元素却表现为明显富集,尤其是重稀土元素的富集。风化作用强度较大的PRD09孔和PRD17孔下伏沉积物中的稀土富集程度高于风化作用强度相对较小的PRD16孔。珠江三角洲在末次冰盛期时普遍发育的酸性介质条件,促进了风化层的稀土元素发生溶解和迁移。在风化过程中,由于轻、重稀土元素具有不同的溶解迁移能力和吸附能力,导致杂色黏土层的REE指标值（LREE/HREE、(La/Gd)N和(La/Yb)N）高于下伏沉积物。风化过程对Ce、Eu异常有一定的影响,但不十分明显,杂色黏土层的Ce、Eu异常值仅略低于下伏沉积物。 相似文献
5.
巫山黄土作为中国南方黄土的重要组成部分,弄清该区的物源将为破译这一宝贵沉积记录提供重要的环境信息.对巫山黄土剖面进行了系统取样和Sr-Nd同位素分析,并与黄土高原同期黄土及近源的河流沉积物等进行了比较.结果表明,巫山黄土的87Sr/86Sr值变化范围为0.717 411~0.719 163,平均值为0.717 998,与黄土高原末次冰期黄土的87Sr/86Sr值（变化范围为0.718 235~0.719 673,平均值为0.718 623）几乎一致;巫山黄土εNd（0）值在-10.1~-11.7之间,平均值为-11.4,明显与长江上游现代河漫滩沉积物εNd（0）值（-5.9~-7.2）差别较大,而与黄土高原黄土εNd（0）值（-9.2~-11.3）接近.研究结果表明巫山黄土的粉尘主要为北方输入,与黄土高原黄土同源.据此认为,巫山黄土的形成并不是因为冰期导致三峡地区干旱河滩干涸暴露而引发粉尘近源堆积,这与近年来长江下游下蜀黄土的研究结果有所不同. 相似文献
6.
REE geochemistry of the recent playa sediments from the Thar Desert, India: An implication to playa sediment provenance 总被引：3，自引：0，他引：3
The playas (saline lakes) situated in the Thar Desert, north-west India, provide prominent examples of alkaline brine and varying assemblages of detrital and evaporite mineralogy. The eastern margin of the desert is relatively semi-arid, whereas the central to western region is arid to hyper-arid in nature. Rare earth elements (REEs) systematics in the sediments of nine different playas of the Thar Desert were studied to understand the provenance of the sediments and the intensity of chemical weathering in the region. Based on the REE patterns, fractionation of light REE (LREE) (La/Sm)N and heavy REE (HREE) (Gd/Yb)N, and Eu anomaly (Eu/Eu*), the upper continental crust normalised playa sediments are divided into two different groups. The eastern margin playa sediments show homogeneous REE contents, relatively positive Eu anomaly and depleted HREE values, whereas the western arid core playa sediments have highly variable REE contents, relatively negative Eu anomaly and similarly fractioned LREE and HREE patterns. The dissimilarity in the degree of HREE fractionations both in the eastern and western playa sediments is attributed to the differential distribution of minerals, depending upon their resistance to chemical weathering. It is believed that the relatively higher abundance of REE bearing heavy minerals and the presence of higher amounts of evaporites influence the large variation of REE distribution and enriched HREE in the western playa sediments. Apart from the relatively higher abundance of heavy minerals, the presence of rock fragments of variable petrographic character and roundness mirror the lower rock–water interaction in the arid western region. The presence of well-rounded metamorphic rock fragments and minerals, sourced from the eastern margin Aravalli mountains, indicates that the playas of the entire desert get the detrital and dissolved material mainly from the Aravalli mountains. Additionally, the western playas receive sediments from their surrounding Proterozoic and Mesozoic formations. This interpretation is supported by the presence of angular rock fragments of basalt, rhyolite and limestone in the western playas. 相似文献
7.
Roles of sorting and chemical weathering in the geochemistry and magnetic susceptibility of Xiashu loess, East China 总被引：1，自引：0，他引：1
Fuchun Li Zhangdong Jin Changren Xie Jiayi Feng Libo Wang Yongzhao Yang 《Journal of Asian Earth Sciences》2007,29(5-6):813-822
Uncertainties in paleoenvironmental interpretations for traditional chemical analysis of bulk samples result from different grain-size sub-populations of sediments containing variable distributions of elements and minerals. Therefore, it is important to understand the elemental and mineral distribution in different grain sizes in determining the quantitative relationship between chemical weathering and climatic change. We sieved a series of Xiashu loess samples into three sub-populations of different grain sizes (<2, 2–45 and >45 μm, respectively), and then analyzed each population for rubidium (Rb), strontium (Sr), rare earth elements and magnetic susceptibility. In comparison with elemental concentrations of bulk samples, clay mineralogy and illitic crystallinity, our results show that distinct elemental distributions and magnetic susceptibilities for different grain-size sub-populations are controlled by sorting and/or chemical weathering, although we also suggest that the Xiashu loess may have the same provenance as the Central Chinese Loess. Maximum concentrations of Rb and fine-grained magnetic minerals in the less than 2 μm sub-population, coupled with our finding of maximum Sr in the larger than 45 μm fraction, indicate that Sr was lost during chemical weathering. Grain-size sub-population analysis is, therefore, an effective method for extracting paleoenvironmental information, because individual sub-populations show minimal variations in initial Rb/Sr ratios compared to bulk analysis of all sizes together. Furthermore, a negative correlation between Rb/Sr ratios and Sr concentrations for the <2 μm fraction (R2 = 0.97) may indicate that clay is a sensitive indicator of intensity of chemical weathering and is an ideal sub-population for determining Rb/Sr ratios, but not for magnetic susceptibility. 相似文献
8.
OSL测龄结果表明合肥盆地下蜀黄土(下蜀组)在中更新世晚期已开始沉积;将主量化学元素和粒度分析与西北黄土、镇江下蜀黄土、巫山黄土和宣城黄土进行对比,研究了合肥盆地下蜀黄土物源。研究结果表明,地球化学、粒度及沉积速率等均显示合肥下蜀黄土物源有别于镇江黄土及西北黄土;并从岩相古地理及古气候特征探讨了淮河沿岸及淮北地区河流相、湖相及湖沼相细粒沉积物或许是其潜在的物源。 相似文献
9.
“寨背式”离子吸附型稀土矿床多类型稀土矿化及其成因 总被引：1，自引：0，他引：1
赣南寨背离子吸附型稀土矿床产于寨背复式花岗岩体的风化壳中,自20世纪80年代发现以来一直以轻稀土型开采,近年在轻稀土型花岗岩风化壳中发现了重稀土矿。为了探讨轻稀土型花岗岩风化过程中重稀土元素的迁移、分馏和富集机制,本文选择了区内三个具有代表性的风化壳钻孔(ZK1、ZK2和ZK4)对其进行了全相和离子交换相稀土元素地球化学研究。结果显示：钻孔ZK4中离子交换相稀土含量介于14.90×10-6～835.8×10-6之间,并富集轻稀土(LREE/HREE=2.28～10.78);钻孔ZK1中离子交换相稀土含量达1470×10-6(9件样品均值),具有从轻稀土型向重稀土型过渡的配分特征(LREE/HREE=1.30～1.65),并且剖面自上而下显示轻、重稀土逐渐富集的趋势;钻孔ZK2中离子交换相稀土含量为492.4×10-6(8件样品均值),自上而下稀土配分类型从轻稀土型过渡至重稀土型(LREE/HREE=0.43～2.25),且轻稀土富集在全风化层上部而重稀土则富集在下部。三个钻孔的Nb/Ta和Zr/Hf... 相似文献
10.
不同地质背景物质的Sr-Nd同位素组成往往差异巨大,同时Sr-Nd同位素组成在搬运和沉积过程中相对元素组分更
难被改变,因此是物源示踪研究最常用和有效的手段之一。该研究测试了中国东部代表性黄土堆积的Sr-Nd同位素组成,
包括山东半岛、黄河下游沿岸黄土和下蜀黄土,发现与黄土高原黄土的Sr-Nd同位素特征存在明显差异,指示不同的物质
来源。同时发现,中国东部主要黄土分布区的来源物质可能主要来自其附近的干旱区具有近源性。山东半岛及其滨海黄土
主要来自黄泛平原和冰期暴露陆架的黄河沉积物;黄河下游沿岸黄土可能直接来自黄河河漫滩;下蜀黄土的细颗粒组成物
源还没有定论,需要进一步研究。中国东部局部区域黄土的形成可能与中更新世革命以来冰期气候条件下的荒漠化有关。 相似文献
11.
Mineralization with ion adsorption rare earth elements (REEs) in the weathering profile of granitoid rocks from Nanling region of Southeast China is an important REE resource, especially for heavy REE (HREE) and Y. However, the Jurassic granites in Zhaibei which host the ion adsorption light REE (LREE) ores are rare. It is of peraluminous and high K calc-alkaline composition, which has similar geochemical features of high K2O + Na2O and Zr + Nb + Ce + Y contents and Ga/Al ratio to A-type granite. Based on the chemical discrimination criteria of Eby [Geology 20 (1992) 641], the Zhaibei granite belongs to A1-type and has similar source to ocean island basalts. The rock is enriched in LREE and contains abundant REE minerals including LREE-phosphates and halides. Minor LREE was also determined in the feldspar and biotite, which shows negligible and negative Eu anomalies, respectively. This indicates that the Zhaibei granite was generated by extreme differentiation of basaltic parent magmas. In contrast, granites associated with ion adsorption HREE ores contain amounts of HREE minerals, and show similar geochemical characteristics with fractionated felsic granites. Note that most Jurassic granitoids in the Nanling region contain no REE minerals and cannot produce REE mineralization. They belong to unfractionated M-, I- and S-type granites. Therefore, accumulation of REE in the weathering profile is controlled by primary REE mineral compositions in the granitoids. Intense fractional crystallization plays a role on REE enrichment in the Nanling granitoid rocks. 相似文献
12.
Particle-size analysis is a useful way to determine the source and deposition of sediments. However, there are inconsistencies when this method is used to constrain the origin of the red soils in south-eastern China. To address this problem, we performed a detailed grain-size analysis of two red soil sequences in Xuancheng and Qiliting located along the lower reaches of the Yangtze River. By comparing their particle-size characteristics with those of the loess on the Loess Plateau in northern China, we found that the aeolian samples plot in a particular zone in the C–M (grain size of the cumulative 1% versus median grain size) plot and cluster nearer the lower left corner of the plot as their degree of weathering increases. The grain-size features suggest that the onset of large-scale aeolian deposition along the lower reaches of the Yangtze River occurred at approximately 0.8 Ma. Although both sedimentary sorting and post-depositional weathering control the grain-size variations in the deposits, the extremely strong weathering due to the humid, warm climate along the lower reaches of the Yangtze River primarily modified the grain-size distributions of the primary red soil deposits. Strong weathering increased the very fine silt (2–5 μm) fraction and decreased the coarse (>63 μm) fraction. We also found that certain grain-size parameters of the red soils varied with the weathering intensity, which can be used as indicators of palaeoclimate variations. The grain size variations in both the Qiliting and Xuancheng sequences suggest that the mid-Pleistocene climate transition (MPT) may have affected the lower reaches of the Yangtze River at 0.9 Ma. 相似文献
13.
新疆伊犁黄土化学风化特征及其控制因素 总被引：1，自引：0，他引：1
通过对伊犁盆地昭苏黄土剖面元素地球化学分析,结合与黄土高原典型第四纪风成堆积洛川剖面的对比,对伊犁黄
土常量元素分布规律及化学风化特征进行初步研究发现,伊犁昭苏剖面黄土和古土壤主要元素含量具有较好的一致性,暗
示着沉积后两者所经历的风化作用相似。与黄土高原相比,伊犁黄土和古土壤除CaO,MgO和Na2O,P2O5分别出现较大程度的
富集和较小程度的亏损外,其它常量元素含量的变化趋势基本一致;CIA指数、Na/K比值及A-CN-K图解显示伊犁黄土和古土
壤均经历了低等强度的化学风化作用,弱于黄土高原的洛川黄土及古土壤,黄土和古土壤风化分异作用不明显。气候条件
尤其水热组合模式（降水、温度和蒸发量等）对伊犁黄土化学风化的起着重要的制约作用。 相似文献
14.
Weiguo Zhang Lizhong Yu Min Lu Xiangmin Zheng Junfeng Ji Limin Zhou Xiaoyong Wang 《Quaternary Science Reviews》2009,28(3-4):345-353
The Xiashu Loess, in comparison to the well-studied loess sequences in the Chinese Loess Plateau (CLP), provides a good opportunity for studying East Asian monsoon variations from a southern China perspective. Here we present a study of the iron oxide mineralogy of the Xiashu Loess using integrated geochemical and diffuse reflectance spectroscopy (DRS) measurements as well as magnetic data. Our results show that the free iron oxide (Fed) to total iron (Fet) ratio (Fed/Fet), hematite (Hm) to goethite (Gt) ratio (Hm/Gt) and saturation isothermal remanent magnetization (SIRM) to magnetic susceptibility (χ) ratio (SIRM/χ) all indicate particularly strong summer monsoons during the formation of paleosols PS5 and PS4 (equivalent to Marine Isotope Stage 13 and 11, respectively). However, magnetic susceptibility and Fed/Fet are not consistently reliable indicators of summer monsoon intensity for the whole section. Our results indicate that a multi-proxy approach can give a more reliable summer monsoon intensity reconstruction. The summer monsoon shows a cooling trend and a declining of precipitation from 0.5 to ～0.3 Ma, after which it becomes warmer and wetter towards the top of paleosol PS1 (equivalent to MIS 5). However, PS1 was formed under a relatively cooler temperature and wetter soil conditions in comparison to PS5 and PS4. Such supra-orbital variations in the East Asian summer monsoon superimposed on the effects of glacial–interglacial cycles in southern China are also reflected in the 0.4–0.5 Ma cycle of marine carbon isotopes in the global ocean, possibly indicating a strong link between terrestrial weathering and the global carbon cycle. 相似文献
15.
风尘堆积的物源研究对于揭示物源区的环境演化状况、重建古风场强度和古大气环流格局等都具有重要的意义。目前长江下游地区下蜀土的物质来源问题仍然存在争议。为了解决这一争议问题,本文以南京泰山新村下蜀土剖面为研究对象,开展了系统的地球化学研究。通过对南京下蜀土的常量元素、微量元素、Nd同位素进行测试,并与黄土高原同期黄土进行对比分析,探讨其对长江下游下蜀土的物源指示意义。南京下蜀土与北方黄土具有相似的常、微量元素UCC标准化曲线和稀土元素球粒陨石标准化曲线,但是它的Zr、Hf含量较高,Tl、Pb含量较低,且具有较高的SiO2/Al2O3、TiO2/Al2O3、Nb/Ta和GdN/YbN,较低的SiO2/TiO2、Zr/Hf、Y/Ho、Lu/Hf和εNd(0)值,说明南京下蜀土的物质来源明显有别于黄土高原黄土。南京下蜀土与长江中游下蜀土在地球化学特征方面有较多的相似性,指示其物质来源与中游下蜀土的物质来源相似,主要来源于长江中下游地区的松散沉积物。 相似文献
16.
Nathaniel W Rutter Dean RokoshMichael E Evans Edward C LittleJiri Chlachula Andrei Velichko 《Quaternary Research》2003,60(1):101-109
Loess-paleosol sequences of the last interglacial-glacial cycle are correlated from European Russia to central Siberia and the Chinese Loess Plateau. During cold periods represented by marine oxygen isotope stages (OIS) 2 and 4, loess deposition dominated in the Russian Plain and the Loess Plateau. In central Siberia, loess deposition took place also, but five to seven thin, weakly developed paleosols are identified in both stages. OIS 3, in the Chinese Loess Plateau near Yangchang, consists of a loess bed that is flanked by two weakly developed paleosols. At Kurtak, Siberia, OIS 3 is represented by two distinct, stacked paleosols with no loess bed separating the paleosols. In the Russian Plain, OIS 3 consists of a single, possibly welded paleosol, representing upper and lower stage-3 climates. Brunisols and Chernozems dominate the profiles in China and Siberia, whereas Regosols, Luvisols, and Chernozems are evident in the northern and southern Russian Plain, respectively. OIS 5 is represented in China and the Russian Plain by pedo complexes in a series of welded soils, whereas in contrast, the Kurtak site consists of six paleosols with interbedded loess. The paleosols consist largely of Brunisols and Chernozems. Although the three areas examined have different climates, geographical settings, and loess source areas, they all had similar climate changes during the last interglacial-glacial cycle. 相似文献
17.
丰宁滦河上游的河谷地带有多处黄土堆积,由于该地区黄土分布零星、厚度较小,在以往的研究中却很少引起人们的关注,然而该地区黄土堆积是河北坝上地区环境演化和气候变化的重要地质记录.为了探讨该地区黄土的成因、物源以及化学风化强度,选取代表性的黄土-古土壤剖面77个样品进行了常量元素分析,并与已知典型风成堆积物的地球化学元素特征进行对比.结果表明:(1) 丰宁剖面的主要常量元素(SiO2、Al2O3和Fe2O3)之和以及UCC(Upper Continental Crust)标准化曲线均与典型风成堆积物具有较好的相似性, 表明丰宁黄土和古土壤为风成成因;(2) 丰宁黄土处于初等化学风化阶段,古土壤则进入了中等化学风化阶段.与典型风成堆积物相比,化学风化强度序列为:宣城风成红土＞＞西峰红黏土、镇江下蜀土＞丰宁古土壤、洛川古土壤＞洛川黄土＞丰宁黄土;(3) 常量元素迁移特征表明丰宁黄土和古土壤的化学风化已完成了早期去Na、Ca阶段,并进入到了中期去K阶段;(4) 丰宁黄土、古土壤的K2O/Al2O3和Fe2O3/Al2O3比值与洛川黄土、洛川古土壤、镇江下蜀土、西峰红黏土较为接近,表明这些风成堆积物可能具有相似的源区.而TiO2/Al2O3比值小于其他风成堆积物, 指示丰宁剖面具有其他物源. 相似文献
18.
Veronique Kamgang Kabeyene Beyala Estelle Ndome Effoudou Priso Georges Emmanuel Ekodeck 《Chemie der Erde / Geochemistry》2009,69(1):61-13
An in situ weathering profile overlying chlorite schists in the Mbalmayo-Bengbis formations (South Cameroon) was chosen for the study of the behaviour of REE and the evaluation of geochemical mass balance. After physical and mineralogical studies, the chlorite schists and the undisturbed weathered materials were chemically analyzed for major elements (X-ray fluorescence and titrimetry) and REE (ICP-MS). The behaviour of the REE in the Mbalmayo weathering system was established in comparison with the REE of the reference parent rock. Mass balance calculations were applied to both major elements and REE. The mineralogy of the materials was determined with the aid of a Philips 1720, diffractometer. The chlorite schists of the Mbalmayo sector show low REE contents (Σ=153.44 ppm). These rocks are relatively rich in LREE (about 125 times the chondritic value) and relatively poor in HREE (about 20 times the chondritic value). The REE diagram normalized to chondrites shows a slightly split graph ((La/Yb)N=6.18) with marked enrichment in LREE (LREE/HREE=9.50) in relation to HREE. Moreover, these spectra do not present any Ce anomaly, but a slightly positive Eu anomaly. The imperfectly evolved profile, whose materials are genetically linked, shows an atypical behaviour of REE. In effect, the LREE are more mobile than the HREE during weathering ((La/Yb)NASC<1) with weak Ce anomalies. This has been rarely reported in lateritic profiles characterized by higher HREE mobility than LREE during weathering processes with high Ce anomalies. This is either due to the difference in the stability of REE-bearing minerals, or to the weak acidic to basic pH conditions (6.70<pH<7.80), or even due to the average evolution of the weathering materials. The pathway of the REE along the profile is as follows: (1) leaching in the saprolites and summit of the profile, except for Ce, which precipitates very weakly in the nodular materials and the coarse saprolite materials, (2) at the base of the profile, solutions come in contact with chlorite schist formations, at this level, the pH increases (pH=7.79), HREE and a part of LREE partially void of Ce precipitate and (3) the other part of LREE precipitates further up in the profile. The geochemical mass balance calculations reveal that these elements are leached in the same phases as the relatively high Si, Al, K and Fe2+ contents. 相似文献
19.
长江与黄河沉积物REE地球化学及示踪作用 总被引：66，自引：4，他引：62
长江与黄河沉积物的稀土元素（ＲＥＥ）组成特征不同。长江沉积物ＲＥＥ含量较高,元素含量变化也大于黄河样品;球粒陨石标准化模式表明长江沉积物的（Ｌａ／Ｌｕ）Ｎ、（Ｌａ／Ｙｂ）Ｎ、（Ｇｄ／Ｙｂ）Ｎ的值也相应地比黄河沉积物中的高１０％左右,分布曲线均呈明显的石倾状,轻重稀土分馏明显,相对富集ＬＲＥＥ。且长江样品比黄河样品更富集ＬＲＥＥ,但Ｅｕ亏损不及黄河样品;两者的北美页岩标准化曲线均呈平坦稍右倾状,具有 相似文献
20.
《Applied Geochemistry》2000,15(9):1369-1381
Thirty-eight samples of stream sediments draining high-grade metamorphic rocks in the Walawe Ganga (river) Basin, Sri Lanka, were analysed for their REE contents, together with samples of metamorphic suites from the source region. The metamorphic rocks are enriched in light REE (LREE) compared to heavy REE (HREE) and are characterised by high La/Lu ratios and negative Eu anomalies. The chondrite-normalised patterns for these granulite-grade rocks are similar to that of the average post-Archaean upper crust, but they are slightly enriched with La and Ce. The REE contents of the <63-μm fraction of the stream sediments are similar to the probable source rocks, but the other grain size fractions show more enriched patterns. The <63-μm stream sediments fraction contains lower total REE, more pronouncd negative Eu anomalies, higher EuN/SmN and lower La N/LuN ratios relative to other fractions. The lower La N/LuN ratio is related to the depletion of heavy minerals in the <63-μm fraction. The 63–125-μm and 125–177-μm grain size fractions of sediments are particularly enriched in LREE (average ΣLREE=2990 μg/g and 3410 μg/g, respectively). The total HREE contents are surprisingly uniform in all size fractions. However, the REE contents in the Walawe Ganga sediments are not comparable with those of the granulite-grade rocks from the source region of the sediments. The enrichment of REE is accounted for by the presence of REE containing accessory mineral phases such as zircon, monazite, apatite and garnet. These minerals are derived from an unknown source, presumably from scattered bodies of granitic pegmatites. 相似文献