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1.
The 18O and 2H (HDO) compositions are summarized for sampled springs (n = 81) within the Elwha watershed (≈692 km2) on the northern Olympic Peninsula. Samples, collected during 2001–2009, of springs (n = 158), precipitation (n = 520), streams (n = 176), and firn (n = 3) assisted the determinations for meteoric composition of recharge waters. The local mean water line (LMWL) is defined
as δ2H = 8.2δ18O − 9.3 for the watershed. Recharge history is surmised from groundwater ages ranging from 5 ± 3 years (apparent 85Kr) to 9,490 ± 420 14C cal years BP. About 56% of the springs were recharged over the last 1,000 years while 13% of springs were recharged over
5,000 years ago. Spring HDO values fluctuate between −11.8 to −15.6‰ δ18O and −90.9 to −119.4‰ δ2H. Deuterium excess values predominate around 4–6‰. The HDO proxy records from springs suggest a pronounced paleoclimate shift
in air masses near 5,000 year BP on the Peninsula. 相似文献
2.
A comparative study on isotopic composition of precipitation in wet tropic and semi-arid stations across southern India 总被引:2,自引:0,他引:2
Isotopic composition of monthly composite precipitation samples from Kozhikode (n = 31), a wet tropic station and Hyderabad (n = 25), a semi-arid station across southern India were studied for a period of four years from 2005 to 2008. During the study
period, the Kozhikode station recorded an average rainfall of 3500 mm while the Hyderabad station showed an average rainfall
of 790 mm. The average stable isotope values in precipitation at the Kozhikode station were δ
18O = −3.52‰, d-excess = 13.72‰; δ
18O = −2.94‰, d-excess = 10.57‰; and δ
18O = −7.53‰, d-excess = 13.79‰, respectively during the pre-monsoon (March–May), monsoon (June–September) and post-monsoon
(October–February) seasons. For the Hyderabad station, the average stable isotope values were δ
18O = −5.88‰, d-excess = 2.34‰; δ
18O = −4.39‰, d-excess = 9.21‰; and δ
18O = −8.69‰, d-excess = 14.29‰, respectively for the three seasons. The precipitation at the two stations showed distinctive
isotopic signatures. The stable isotopic composition of precipitation at the Hyderabad station showed significant variations
from the global trend while the Kozhikode station almost followed the global value. These differences are mainly attributed
to the latitudinal differences of the two stations coupled with the differences in climatic conditions. 相似文献
3.
Geochemical mixing models were used to decipher the dominant source of freshwater (rainfall, canal discharge, or groundwater
discharge) to Biscayne Bay, an estuary in south Florida. Discrete samples of precipitation, canal water, groundwater, and
bay surface water were collected monthly for 2 years and analyzed for salinity, stable isotopes of oxygen and hydrogen, and
Sr2+/Ca2+ concentrations. These geochemical tracers were used in three separate mixing models and then combined to trace the magnitude
and timing of the freshwater inputs to the estuary. Fresh groundwater had an isotopic signature (δ
18O = −2.66‰, δD −7.60‰) similar to rainfall (δ
18O = −2.86‰, δD = −4.78‰). Canal water had a heavy isotopic signature (δ
18O = −0.46‰, δD = −2.48‰) due to evaporation. This made it possible to use stable isotopes of oxygen and hydrogen to separate canal water
from precipitation and groundwater as a source of freshwater into the bay. A second model using Sr2+/Ca2+ ratios was developed to discern fresh groundwater inputs from precipitation inputs. Groundwater had a Sr2+/Ca2+ ratio of 0.07, while precipitation had a dissimilar ratio of 0.89. When combined, these models showed a freshwater input
ratio of canal/precipitation/groundwater of 37%:53%:10% in the wet season and 40%:55%:5% in the dry season with an error of
±25%. For a bay-wide water budget that includes saltwater and freshwater mixing, fresh groundwater accounts for 1–2% of the
total fresh and saline water input. 相似文献
4.
Wilson Yetoh Fantong Hiroshi Satake Festus T. Aka Samuel N. Ayonghe Kazuyoshi Asai Ajit K. Mandal Andrew A. Ako 《Environmental Earth Sciences》2010,60(1):107-120
Unplanned exploitation of groundwater constitutes emerging water-related threats to MayoTsanaga River Basin. Shallow groundwater
from crystalline and detrital sediment aquifers, together with rain, dams, springs, and rivers were chemically and isotopically
investigated to appraise its evolution, recharge source and mechanisms, flow direction, and age which were used to evaluate
the groundwater susceptibility to contamination and the basin’s stage of salinization. The groundwater which is Ca–Na–HCO3 type is a chemically evolved equivalent of surface waters and rain water with Ca–Mg–Cl–SO4 chemistry. The monsoon rain recharged the groundwater preferentially at an average rate of 74 mm/year, while surface waters
recharge upon evaporation. Altitude effect of rain and springs show a similar variation of −0.4‰ for δ18O/100 m, but the springs which were recharged at 452, 679, and 773 m asl show enrichment of δ18O through evaporation by 0.8‰ corresponding to 3% of water loss during recharge. The groundwater which shows both local and
regional flow regimes gets older towards the basins` margin with coeval enrichment in F− and depletion in NO3
−. Incidentally, younger groundwaters are susceptible to anthropogenic contamination and older groundwaters are sinks of lithologenic
fluoride. The basins salinization is still at an early stage. 相似文献
5.
Recharge rate estimation in the Mountain karst aquifer system of Figeh spring, Syria 总被引:3,自引:1,他引:2
A. Al-Charideh 《Environmental Earth Sciences》2012,65(4):1169-1178
Figeh watershed spring is one of the important groundwater aquifer, which is considered a major source for drinking waters
of Damascus city and countryside. The origin identification and recharge estimates of groundwater are significant components
of sustainable groundwater development in this Mountain karst aquifer of Figeh spring. During the period 2001–2009, monthly
groundwater and precipitation samples were taken and the isotopic compositions of δ18O, δ2H, and chloride contents were analyzed to identify groundwater origins and to estimate recharge rates. The δ18O, δ2H of the groundwater show that the groundwater recharge is of meteoric origin. The chloride mass balance (CMB) method was
used to quantify recharge rates of groundwater in the Mountain karst aquifer of Figeh spring. The recharge rate varies from
192 to 826 mm/year, which corresponds to 43 and 67% of the total annual rainfall. Recharge rates estimated by CMB were compared
with values obtained from other methods and were found to be in good agreement. This study can be used to develop effective
programs for groundwater management and development. 相似文献
6.
Recharge source and hydrogeochemical evolution of shallow groundwater in a complex alluvial fan system,southwest of North China Plain 总被引:4,自引:0,他引:4
Fadong Li Guoying Pan Changyuan Tang Qiuying Zhang Jingjie Yu 《Environmental Geology》2008,55(5):1109-1122
Many cities around the world are developed at alluvial fans. With economic and industrial development and increase in population,
quality and quantity of groundwater are often damaged by over-exploitation in these areas. In order to realistically assess
these groundwater resources and their sustainability, it is vital to understand the recharge sources and hydrogeochemical
evolution of groundwater in alluvial fans. In March 2006, groundwater and surface water were sampled for major element analysis
and stable isotope (oxygen-18 and deuterium) compositions in Xinxiang, which is located at a complex alluvial fan system composed
of a mountainous area, Taihang Mt. alluvial fan and Yellow River alluvial fan. In the Taihang mountainous area, the groundwater
was recharged by precipitation and was characterized by Ca–HCO3 type water with depleted δ18O and δD (mean value of −8.8‰ δ18O). Along the flow path from the mountainous area to Taihang Mt. alluvial fan, the groundwater became geochemically complex
(Ca–Na–Mg–HCO3–Cl–SO4 type), and heavier δ18O and δD were observed (around −8‰ δ18O). Before the surface water with mean δ18O of −8.7‰ recharged to groundwater, it underwent isotopic enrichment in Taihang Mt. alluvial fan. Chemical mixture and ion
exchange are expected to be responsible for the chemical evolution of groundwater in Yellow River alluvial fan. Transferred
water from the Yellow River is the main source of the groundwater in the Yellow River alluvial fan in the south of the study
area, and stable isotopic compositions of the groundwater (mean value of −8.8‰ δ18O) were similar to those of transferred water (−8.9‰), increasing from the southern boundary of the study area to the distal
end of the fan. The groundwater underwent chemical evolution from Ca–HCO3, Na–HCO3, to Na–SO4. A conceptual model, integrating stiff diagrams, is used to describe the spatial variation of recharge sources, chemical
evolution, and groundwater flow paths in the complex alluvial fan aquifer system. 相似文献
7.
Xin Liu Xianfang Song Yinghua Zhang Jun Xia Xuecheng Zhang Jingjie Yu Di Long Fadong Li Bing Zhang 《Environmental Earth Sciences》2011,63(5):1105-1118
Groundwater is of utmost significance to socio-economic development and ecological recovery for the Loess Plateau. However,
studies regarding the mechanism governing groundwater recharge over this area appear to be inadequate. This study is to examine
the spatio-temporal variations of δ2H and δ18O in precipitation and shallow groundwater. On the basis of this, the mechanisms governing shallow groundwater recharge were
explored. Precipitation and groundwater were sampled monthly from May to October during the period 2004–2006 at 13 sites in
the Chabagou Catchment (187 km2). In the Caopingxigou Experimental Watershed (0.1 km2), meteorological variables were observed and rainfall larger than 5 mm was sampled immediately after each rain event. Across
the area, 90% of the precipitation occurred from May to September primarily in the form of heavy rains or rainstorms with
great spatial variability. There were about 30 localized rains in each year. It was indicated that there existed notable seasonality
and pronounced spatial variability in precipitation isotopic compositions. Contributing factors and indications of isotopic
compositions, as well as their climatic indications such as monsoon intensities and mixing processes of water vapor, were
investigated. The δ2H–δ18O relation of groundwater was found to be δ2H = 3.22 × δ18O − 38.1, deviating from the local meteoric water line δ2H = 7.57 × δ18O + 3.9. The range of δ values in groundwater is shrunken to be 15–21% of that in individual precipitations, and groundwater in the middle reaches
shows a wider range of δ values. Isotopic results showed that groundwater originates from precipitation with hydrogen and oxygen isotopic compositions
being −69 and −9.7‰, respectively, and most groundwater experiences serious evaporation and adequate mixing with old water
during infiltration or percolation in the aerated zone. It was also founded that obvious fluctuations of isotopic compositions
in groundwater mainly appear in the middle reaches especially at sites that are close to valleys, suggesting varying sources
of groundwater from precipitation, precipitation runoff, isotopically enriched surface water and/or lateral recharge of adjacent
groundwater. 相似文献
8.
Early carbonate cements in the Yanchang Formation sandstones are composed mainly of calcite with relatively heavier carbon isotope (their δ^18O values range from -0.3‰- -0.1‰) and lighter oxygen isotope (their δ^18O values range from -22.1‰- -19.5‰). Generally, they are closely related to the direct precipitation of oversaturated calcium carbonate from alkaline lake water. This kind of cementation plays an important role in enhancing the anti-compaction ability of sandstones, preserving intragranular volume and providing the mass basis for later disso- lution caused by acidic fluid flow to produce secondary porosity. Ferriferous calcites are characterized by relatively light carbon isotope with δ^13C values ranging from -8.02‰ to -3.23‰, and lighter oxygen isotope with δ^18O values ranging from -22.9‰ to -19.7‰, which is obviously related to the decarboxylation of organic matter during the late period of early diagenesis to the early period of late diagenesis. As the mid-late diagenetic products, ferriferous cal- cites in the study area are considered as the characteristic authigenic minerals for indicating large-scaled hydrocarbon influx and migration within the clastic reservoir. The late ankerite is relatively heavy in carbon isotope with δ^13C values ranging from -1.92‰ to -0.84‰, and shows a wide range of variations in oxygen isotopic composition, with δ^18O values ranging from -20.5‰ to -12.6‰. They are believed to have nothing to do with decarboxylation, but the previously formed marine carbonate rock fragments may serve as the chief carbon source for their precipitation, and the alkaline diagenetic environment at the mid-late stage would promote this process. 相似文献
9.
Hydrogeochemical controls and usability of groundwater in the semi-arid Mayo Tsanaga River Basin: far north province,Cameroon 总被引:2,自引:0,他引:2
Wilson Y. Fantong Hiroshi Satake Samuel N. Ayonghe Festus T. Aka Kazuyoshi Asai 《Environmental Geology》2009,58(6):1281-1293
Deuterium, δ
18O, major ions and dissolved silica in groundwater from semi-arid Mayo-Tsanaga river basin in the Far North Province, Cameroon
were used to trace hydrogeochemical processes that control their concentrations and to explore for usability of the water.
Electrical conductivity ranges from 57–2,581 μs/cm with alternating low and high values along the hydraulic gradient. Waters
from piedmont alluvium show low concentrations in major cations, which peak in Mg within basalt, Na within plain alluvium,
and Ca within basalt and the sandy Limani-Yagoua ridge. The initial dominant groundwater composition is CaHCO3, which did not evolve within the basalt and piedmont alluvium, but evolved to NaHCO3 in the granite and plain alluvium. The main processes controlling the major ions composition include the following: (1) dissolution
of silicates and fluorite; (2) precipitation of fluorite and carbonate; (3) cation exchange of Ca in water for Na in clay;
(4) and anthropogenic activities. The δD and δ
18O ratios vary from −35 to 0.7 and −5.3 to 1.1‰, respectively. The lowest and highest isotope ratios are observed in groundwater
within the downstream sandy Limani-Yagoua ridge and the upstream graintes respectively. Variation in isotope ratios depends
on altitude effect of −0.48‰ per 100 m between 600 and 850 m asl, and on evaporation, which had insignificant effect on the
water salinity. Seventy percent of the groundwater shows poor drinking quality and 90% is suitable for irrigation.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
10.
Galip Yuce 《Environmental Geology》2007,51(5):857-868
The aim of this study was to determine geochemical properties of groundwater and thermal water in the Misli Basin and to assess
thermal water intrusion into shallow groundwater due to over-extraction. According to isotope and hydrochemical analyses results,
sampled waters can be divided into three groups: cold, thermal, and mixed waters. Only a few waters reach water–rock chemical
equilibrium. Thermal waters in the area are characterized by Na+–Cl−–HCO3−, while the cold waters by CaHCO3 facies. On the basis of isotope results, thermal waters in the Misli basin are meteoric origin. In particular, δ18O and δ2H values of shallow groundwater vary from −10.2 to −12.2‰ and −71.2 to −82‰, while those of thermal waters range from −7.8
to −10.1‰ and from −67 to −74‰, respectively. The tritium values of shallow groundwater having short circulation as young
waters coming from wells that range from 30 to 70 m in depth vary from 10 to 14 TU. The average tritium activity of groundwater
in depths more than 100 m is 1.59 ± 1.16, which indicates long circulation. The rapid infiltration of the precipitation, the
recycling of the evaporated irrigation water, the influence of thermal fluids and the heterogeneity of the aquifer make it
difficult to determine groundwater quality changes in the Misli Basin. Obtained results show that further lowering of the
groundwater table by over-consumption will cause further intrusion of thermal water which resulted in high mineral content
into the fresh groundwater aquifer. Because of this phenomenon, the concentrations of some chemical components which impairs
water quality in terms of irrigation purposes in shallow groundwaters, such as Na+, B, and Cl−, are highy probably expected to increase in time. 相似文献
11.
Multiple chemical constituents (nutrients; N, O, H, C stable isotopes; 64 organic wastewater compounds, 16 pharmaceutical
compounds) and microbiological indicators were used to assess the impact on groundwater quality from the land application
of approximately 9.5 million liters per day of treated municipal sewage effluent to a sprayfield in the 960-km2 Ichetucknee Springs basin, northern Florida. Enriched stable isotope signatures (δ18O and δ2H) were found in water from the effluent reservoir and a sprayfield monitoring well (MW-7) due to evaporation; however, groundwater
samples downgradient from the sprayfield have δ18O and δ2H concentrations that represented recharge of meteoric water. Boron and chloride concentrations also were elevated in water
from the sprayfield effluent reservoir and MW-7, but concentrations in groundwater decreased substantially with distance downgradient
to background levels in the springs (about 12 km) and indicated at least a tenfold dilution factor. Nitrate-nitrogen isotope
(δ15N–NO3) values above 10 ‰ in most water samples were indicative of organic nitrogen sources except Blue Hole Spring (δ15N–NO3 = 4.6–4.9 ‰), which indicated an inorganic source of nitrogen (fertilizers). The detection of low concentrations the insect
repellent N,N-diethyl-metatoluamide (DEET), and other organic compounds associated with domestic wastewater in Devil’s Eye Spring indicated
that leakage from a nearby septic tank drainfield likely has occurred. Elevated levels of fecal coliforms and enterococci
were found in Blue Hole Spring during higher flow conditions, which likely resulted from hydraulic connections to upgradient
sinkholes and are consistent with previoius dye-trace studies. Enteroviruses were not detected in the sprayfield effluent
reservoir, but were found in low concentrations in water samples from a downgradient well and Blue Hole Spring during high-flow
conditions indicating a human wastewater source. The Upper Floridan aquifer in the Ichetucknee Springs basin is highly vulnerable
to contamination from multiple anthropogenic sources throughout the springs basin. 相似文献
12.
Hydrogeochemical and isotopic investigation of the Bursa-Oylat thermal waters, Turkey 总被引:1,自引:1,他引:0
Suzan Pasvano?lu 《Environmental Earth Sciences》2011,64(4):1157-1167
The Oylat spa is located 80 km southeast of Bursa and 30 km south of Ineg?l in the Marmara region. With temperature of 40°C
and discharge of 45 l/s, the Oylat main spring is the most important hot water spring of the area. Southeast of the spa the
Forest Management spring has a temperature of 39.4°C and discharge of 2 l/s. The G?z spring 2 km north of the spa, which is
used for therapy of eye disease, and cold waters of the Saadet village springs with an acidic character are the further important
water sources of the area. EC values of Main spring and Forest Management hot spring (750–780 μS/cm) are lower than those
of Saadet and G?z spring waters (2,070–1,280 μS/cm) and ionic abundances are Ca > Na + K > Mg and SO4 > HCO3 > Cl. The Oylat and Sızı springs have low Na and K contents but high Ca and HCO3 concentrations. According to AIH classification, these are Ca–SO4–HCO3 waters. Based on the results of δ18O, 2H and 3H isotope analyses, the thermal waters have a meteoric origin. The meteoric water infiltrates along fractures and faults,
gets heated, and then returns to surface through hydrothermal conduits. Oylat waters do not have high reservoir temperatures.
They are deep, circulating recharge waters from higher enhanced elevations. δ13CDIC values of the Main spring and Forest Management hot spring are −6.31 and −4.45‰, respectively, indicating that δ13C is derived from dissolution of limestones. The neutral pH thermal waters are about +18.7‰ in δ34S while the sulfate in the cold waters is about +17‰ (practically identical to the value for the neutral pH thermal waters).
However, the G?z and Saadet springs (acid sulfate waters) have much lower δ34S values (~+4‰). 相似文献
13.
Isotopic constraints on the origin of groundwater in the Ordos Basin of northern China 总被引:7,自引:2,他引:5
Jiansheng Chen Xiaoyan Liu Chiyuen Wang Wenbo Rao Hongbing Tan Haizhou Dong Xiaoxu Sun Yongsen Wang Zhiguo Su 《Environmental Earth Sciences》2012,66(2):505-517
Despite its extreme aridity, the Ordos Basin in northern China is rich in groundwater. Many artesian wells or springs with
large fluxes are utilized for drinking, irrigation and industrial production. In a search for the origin of the groundwater,
a detailed investigation of the stable isotopes of oxygen and hydrogen in the local precipitation, the river water, the springs,
the well water, as well as the soil water extracted from six soil profiles in the Ordos Basin, was carried out. The data show
that δD, δ18O and TDS values of the river water are similar to those of groundwater, while the TDS values of the soil water are about
ten times greater than those of groundwater. Furthermore, the mean isotopic compositions of the local precipitation are significantly
higher than those of river water and groundwater. Based on the chloride mass balance method, the estimated recharge rates
range from 5.2 to 17.2 mm/year, with a mean value of 10.5 mm/year. The results show that the main source of recharge of the
groundwater in the Ordos Basin is not the local precipitation, but must come from a region where the precipitation is characterized
by much lower δD and δ18O values. In addition, the groundwater in the Ordos Basin contains a component of mantle-derived 3He and crust-derived 4He suggesting that the groundwater may partly derive from flows through basement faults beneath the Ordos Basin. 相似文献
14.
Decorative marbles from the Krkonoše-Jizera Terrane (Bohemian Massif,Czech Republic): provenance criteria 总被引:1,自引:0,他引:1
Marbles from western part of the Krkonoše-Jizera Terrane (northern part of the Bohemian Massif) have been studied to obtain
mineropetrographic and chemical reference data for provenance studies. Samples from six different quarries were analysed by
mineralogical-petrographic and geochemical methods (optical microscopy, X-ray diffraction, stable isotope ratio analysis,
cathodoluminescence, bulk magnetic susceptibility). Petrographic characteristics permit a distinction between fine-grained
to medium-grained marbles from the Jizera Mts (amphibolite metamorphic facies) and fine-grained marbles from the Ještěd Mts
(low-grade greenschist facies). The samples studied are mainly calcitic, with the exception of those from Raspenava in which
dolomite is abundant in two types. The mineralogical composition of the insoluble residues is clinochlore ± serpentine ± tremolite ± diopside ± pyrite + magnetite
in case of the locality Raspenava and clinochlore + muscovite ± quartz ± pyrite ± rutile ± haematite in case of the localities
from the Ještěd Mts. δ13C and δ18O variations in primary and secondary carbonate phases allow to distinguish genetically different carbonate veins and permit
quarry separation in one case (Raspenava, Jizera Mts). The δ13C and δ18O values of the groundmass range from −1 to +3‰ and from −8 to −20‰ (PDB), respectively. The δ13C and δ18O values of secondary carbonate veins decrease to −3‰ and reach more negative values up to −26‰ in case of δ18O. The fabric of cathodomicrofacies allows the distinction between calcite and dolomite, except three localities (Pilínkov,
Horní Hanychov, Jitrava—rose type) with majority of quenchers (high content of iron in carbonate). The genetically different
calcite is characterised by a pale and dark orange luminescence distribution. Serpentine, tremolite, forsterite, opaque minerals
and quartz have no luminescence and very dull luminescence, respectively. The majority of studied marbles exhibits low values
of the bulk magnetic susceptibility, with the exception of those from Raspenava rich in magnetite. 相似文献
15.
Hydrochemical characteristics of groundwater in the Zhangye Basin, Northwestern China 总被引:3,自引:0,他引:3
The Zhangye Basin, located in arid northwest China, is an important agricultural and industrial center. In recent years rapid
development has created an increased demand for water, which is increasingly being fulfilled by groundwater abstraction. Detailed
knowledge of the geochemical evolution of groundwater and water quality can enhance understanding of the hydrochemical system,
promoting sustainable development and effective management of groundwater resources. To this end, a hydrochemical investigation
was conducted in the Zhangye Basin. Types of shallow groundwater in the Zhangye Basin were found to be HCO3
−, HCO3
−–SO4
2−, SO4
2−–HCO3
−, SO4
2−–Cl−, Cl−–SO4
2− and Cl− . The deep aquifer groundwater type was found to be HCO3−–SO42− throughout the entire area. Ionic ratio and saturation index calculations suggest that silicate rock weathering and evaporation
deposition are the main processes that determine the ionic composition in the study area. The suitability of the groundwater
for irrigation was assessed based on the US Salinity Laboratory salinity classification and the Wilcox diagram. In the study
area, the compositions of the stable isotopes δ18O and δD in groundwater samples were found to range from −4.00 to −9.28‰ and from −34.0 to −65.0‰, respectively. These values
indicate that precipitation is the main recharge source for the groundwater system; some local values indicate high levels
of evaporation. Tritium analysis was used to estimate the ages of the different groundwaters; the tritium values of the groundwater
samples varied from 3.13 to 36.62 TU. The age of the groundwater at depths of less than 30 m is about 5–10 years. The age
of the groundwater at depths of 30–50 m is about 10–23 years. The age of the groundwater at depths of 50–100 m is about 12–29 years.
For groundwater samples at depths of greater than 100 m, the renewal time is about 40 years. 相似文献
16.
C. O'Reilly G. R. T. Jenkin M. Feely D. H. M. Alderton A. E. Fallick 《Contributions to Mineralogy and Petrology》1997,129(2-3):120-142
Fluid inclusions in granite quartz and three generations of veins indicate that three fluids have affected the Caledonian
Galway Granite. These fluids were examined by petrography, microthermometry, chlorite thermometry, fluid chemistry and stable
isotope studies. The earliest fluid was a H2O-CO2-NaCl fluid of moderate salinity (4–10 wt% NaCl eq.) that deposited late-magmatic molybdenite mineralised quartz veins (V1) and formed the earliest secondary inclusions in granite quartz. This fluid is more abundant in the west of the batholith,
corresponding to a decrease in emplacement depth. Within veins, and to the east, this fluid was trapped homogeneously, but
in granite quartz in the west it unmixed at 305–390 °C and 0.7–1.8 kbar. Homogeneous quartz δ18O across the batholith (9.5 ± 0.4‰n = 12) suggests V1 precipitation at high temperatures (perhaps 600 °C) and pressures (1–3 kbar) from magmatic fluids. Microthermometric data
for V1 indicate lower temperatures, suggesting inclusion volumes re-equilibrated during cooling. The second fluid was a H2O-NaCl-KCl, low-moderate salinity (0–10 wt% NaCl eq.), moderate temperature (270–340 °C), high δD (−18 ± 2‰), low δ18O (0.5–2.0‰) fluid of meteoric origin. This fluid penetrated the batholith via quartz veins (V2) which infill faults active during post-consolidation uplift of the batholith. It forms the most common inclusion type in
granite quartz throughout the batholith and is responsible for widespread retrograde alteration involving chloritization of
biotite and hornblende, sericitization and saussuritization of plagioclase, and reddening of K-feldspar. The salinity was
generated by fluid-rock interactions within the granite. Within granite quartz this fluid was trapped at 0.5–2.3 kbar, having
become overpressured. This fluid probably infiltrated the Granite in a meteoric-convection system during cooling after intrusion,
but a later age cannot be ruled out. The final fluid to enter the Granite and its host rocks was a H2O-NaCl-CaCl2-KCl fluid with variable salinity (8–28 wt% NaCl eq.), temperature (125–205 °C), δD (−17 to −45‰), δ18O (−3 to + 1.2‰), δ13CCO2 (−19 to 0‰) and δ34Ssulphate (13–23‰) that deposited veins containing quartz, fluorite, calcite, barite, galena, chalcopyrite sphalerite and pyrite (V3). Correlations of salinity, temperature, δD and δ18O are interpreted as the result of mixing of two fluid end-members, one a high-δD (−17 to −8‰), moderate-δ18O (1.2–2.5‰), high-δ13CCO2 (> −4‰), low-δ34Ssulphate (13‰), high-temperature (205–230 °C), moderate-salinity (8–12 wt% NaCl eq.) fluid, the other a low-δD (−61 to −45‰), low-δ18O (−5.4 to −3‰), low-δ13C (<−10‰), high-δ34Ssulphate (20–23‰) low-temperature (80–125 °C), high-salinity (21–28 wt% NaCl eq.) fluid. Geochronological evidence suggests V3 veins are late Triassic; the high-δD end-member is interpreted as a contemporaneous surface fluid, probably mixed meteoric
water and evaporated seawater and/or dissolved evaporites, whereas the low-δD end-member is interpreted as a basinal brine
derived from the adjacent Carboniferous sequence. This study demonstrates that the Galway Granite was a locus for repeated
fluid events for a variety of reasons; from expulsion of magmatic fluids during the final stages of crystallisation, through
a meteoric convection system, probably driven by waning magmatic heat, to much later mineralisation, concentrated in its vicinity
due to thermal, tectonic and compositional properties of granite batholiths which encourage mineralisation long after magmatic
heat has abated.
Received: 3 April 1996 / Accepted: 5 May 1997 相似文献
17.
The sedimentary succession of Gallocanta lake, a closed saline lake located in the Iberian Range (NE Spain), documents two
successive lacustrine stages: (1) brackish lake stage and (2) shallow saline lake stage. The saline stage corresponds to the
present-day situation in which the lake water properties are mainly controlled by a strongly negative annual water balance.
The carbonates of the brackish lake stage have relatively constant δ18O values, however, they are rather high (δ18ODo = 2.4‰ and δ18OCc = 4.5‰ mean values) suggesting a hydrologically closed lake with a long residence time of the waters. δ18O values of carbonates from the saline stage vary greatly, and are lighter than in the previous stage (δ18ODo = 0.5‰, δ18OCc = −0.7‰, δ18OMgs = −2.3‰ mean values). These carbonates also precipitated in a hydrologically closed lake, but in equilibrium with a lake
water of more variable isotopic composition. The δ13C values for carbonates of both stages reflect a mixing of different pools of carbon, but during saline stage δ13C values have been more controlled by the equilibrium of the lake waters with atmospheric CO2. During the current stage, calcite and dolomite precipitate in Gallocanta lake mainly during spring and summer, although
dolomite precipitation is more favoured towards the summer. Magnesite precipitates at the beginning of autumn, when the first
rainfall re-dissolves the saline surface crust, producing saline waters with a high Mg2+ content. The isotopic composition of lake waters sampled in 2005 are far higher than those calculated from the carbonates.
It is considered that this could be due to two factors: either because there have not been many extremely dry years (like
the year 2005) during the development of the lake, or because the physical and chemical characteristics of the lake waters
in such conditions are not appropriate for the development of these minerals. 相似文献
18.
Åke Fagereng Chris Harris Mandy La Grange Gary Stevens 《Contributions to Mineralogy and Petrology》2008,155(1):63-78
The Vredefort dome in the Kaapvaal Craton was formed as a result of the impact of a large meteorite at 2.02 Ga. The central
core of Archaean granitic basement rocks is surrounded by a collar of uplifted and overturned strata of the Witwatersrand
Supergroup, exposing a substantial depth section of the Archaean crust. Orthogneisses of the core show little variation in
whole-rock δ
18O value, with the majority being between 8 and 10‰, with a mean of 9.2‰ (n = 35). Quartz and feldspar have per mil differences that are consistent with O-isotope equilibrium at high temperatures,
suggesting minimal interaction with fluids during subsequent cooling. These data refute previous suggestions that the Outer
Granite Gneiss (OGG) and Inlandsee Leucogranofels (ILG) of the core represent middle and lower crust, respectively. Granulite-facies
greenstone remnants from the ILG have δ
18O values that are on average 1.5‰ higher than the ILG host rocks and are unlikely, therefore, to represent the residuum from
the partial melting event that formed the host rock. Witwatersrand Supergroup sedimentary rocks of the collar, which were
metamorphosed at greenschist-to amphibolite-facies conditions, generally have lower δ
18O values than the core rocks with a mean value for metapelites of 7.7‰ (n = 45). Overall, through an ∼20 km thick section of crust, there is a general increase in whole-rock δ
18O value with increasing depth. This is the reverse of what is normal in the crust, largely because the collar rocks have δ
18O values that are unusually low in comparison with metamorphosed sedimentary rocks worldwide. The collar rocks have δD values ranging from −35 to −115‰ (average −62‰, n = 29), which are consistent with interaction with water of meteoric origin, having a δD of about −25 to −45‰. We suggest that fluid movement through the collar rocks was enhanced by impact-induced secondary permeability
in the dome structure.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
19.
Fadong Li Xianfang Song Changyuan Tang Changming Liu Jingjie Yu Wanjun Zhang 《Environmental Geology》2007,53(3):687-696
The groundwater in headwater region is an important recharge source for the adjacent mountain-front plain. In order to reveal
the relationship among precipitation, soil water and groundwater, from June to September in 2004, stable isotopes (deuterium
and oxygen-18) in precipitation and soil waters at the depths of 10, 20, 30, 50, 70, 90, and 110 cm were analyzed at two sites
covered by black locust (Robinia Pseudoacia L.) (Site A) and grass predominated by Themeda triandra (T. japonica (Willd.) Tanaka) and Bothriochloa ischaemum (B. ischaemum (L.) Keng) (Site B) in an experimental catchment at Taihang Mt., North China, respectively. The δ18O of precipitation in daily rain events shows large variations (−13.3 to −4.3‰) with a mean of 8.1‰. The δ18O and δ D of soil waters along profiles in two sites suggest that the influence of canopy cover was just up to 10 cm in top
soil water. The soil water moved over the zero flux plane at 70 cm in-depth is expected to escape the evaporative effect at
the end of September in both sites. The results show that the stable isotope, instead of tritium as tradition, can be used
to trace the soil water behaviors based on the movement of isotopic peak along the vertical profiles in this semi-arid and
semi-humid mountainous region. The infiltration depths of soil water in Taihang Mt. are 12 and 10 mm/day from June to September
in 2004 in Site A and Site B, respectively. Tracing by stable isotope, recharge fluxes of soil water to local groundwater
are of 3.8 and 3.2 mm/day in Site A and Site B, respectively. The results provide desirable information for assessment of
local groundwater resources.
An erratum to this article can be found at 相似文献
20.
Mark E. Brandriss Richard J. Nevle Dennis K. Bird James R. O’Neil 《Contributions to Mineralogy and Petrology》1995,121(1):74-86
Hydrogen and oxygen isotope analyses have been made of hydrous minerals in gabbros and basaltic xenoliths from the Eocene
Kap Edvard Holm intrusive complex of East Greenland. The analyzed samples are of three types: (1) primary igneous hornblendes
and phlogopites that crystallized from partial melts of hydrothermally altered basaltic xenoliths, (2) primary igneous hornblendes
that formed during late–magmatic recrystallization of layered gabbroic cumulates, and (3) secondary actinolite, epidote and
chlorite that formed during subsolidus alteration of both xenoliths and gabbros. Secondary actinolite has a δ18O value of −5.8‰ and a δD value of −158‰. These low values reflect subsolidus alteration by low–δ18O, low–δD hydrothermal fluids of meteoric origin. The δD value is lower than the −146 to −112‰ values previously reported
for amphiboles from other early Tertiary meteoric–hydrothermal systems in East Greenland and Scotland, indicating that the
meteoric waters at Kap Edvard Holm were isotopically lighter than typical early Tertiary meteoric waters in the North Atlantic
region. This probably reflects local climatic variations caused by formation of a major topographic dome at about the time
of plutonism and hydrothermal activity. The calculated isotopic composition of the meteoric water is δD=−110 ± 10‰, δ18O ≈−15‰. Igneous hornblendes and phlogopites from pegmatitic pods in hornfelsed basaltic xenoliths have δ18O values between −6.0 and −3.8‰ and δD values between −155 and −140‰. These are both much lower than typical values of fresh
basalts. The oxygen isotope fractionations between pegmatitic hornblendes and surrounding hornfelsic minerals are close to
equilibrium fractionations for magmatic temperatures, indicating that the pegmatites crystallized from low–δ18O partial melts of xenoliths that had been hydrothermally altered and depleted in 18O prior to stoping. The pegmatitic minerals may have crystallized with low primary δD values inherited from the altered country
rocks, but these values were probably overprinted extensively by subsolidus isotopic exchange with low–δD meteoric–hydrothermal
fluids. This exchange was facilitated by rapid self–diffusion of hydrogen through the crystal structures. Primary igneous
hornblendes from the plutonic rocks have δ18O values between +2.0 and +3.2‰ and δD values between −166 and −146‰. The 18O fractionations between hornblendes and coexisting augites are close to equilibrium fractionations for magmatic temperatures,
indicating that the hornblendes crystallized directly from the magma and subsequently underwent little or no oxygen exchange.
The hornblendes may have crystallized with low primary δD values, due to contamination of the magma with altered xenolithic
material, but the final δD values were probably controlled largely by subsolidus isotopic exchange. This inference is based
partly on the observation that coexisting plagioclase has been extensively depleted in 18O via a mineral–fluid exchange reaction that is much slower than the hydrogen exchange reaction in hornblende. It is concluded
that all hydrous minerals in the study area, whether igneous or secondary, have δD values that reflect extensive subsolidus
isotopic equilibration with meteoric–hydrothermal fluids.
Received: 22 March 1994 / Accepted: 26 January 1995 相似文献