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1.
In the current study, we determined concentrations and transfer rates of Ag, Al, Ba, Ca, Cd, Co, Cr, Cu, Fe, K, Mg, Mn, Na, Ni, Pb, P, Rb, Sr and Zn to Brown Birch Scaber Stalks (Leccinum scabrum) mushrooms emerged in the area of Sudety Mountains (Sudetes) in Poland. Fruiting bodies and topsoil samples beneath L. scabrum were collected form the K odzka Dale. The trace elements were determined using validated method and inductively coupled plasma - atomic emission spectroscopy (ICP-AES) for final measurement. Mushrooms contained Ag, Cr, Hg, Co, Ni and Sr at < 1.0 μg/g dry weight; Ba and Pb at ~1.0 μg/g dw; Cd at < 5 μg/g dw; Cu and Mn at > 10 μg/g dw; Al and Ca at ~100 μg/g dw; Fe, Na, Rb and Zn at 100 to 500 μg/g dw, Mg at ~1,000 μg/g dw; P at ~5,000 μg/g dw and K at ~30,000 μg/g dw. Ca, Mn and Ni were nearly equally distributed between stipes and caps; stipes compared to caps were enriched in Ba, Na and Sr, while caps were enriched in Ag, Al, Cd, Co, Cr, Cu, Fe, K, P, Pb, Rb and Zn. The values of bioconcentration factor (BCF) varied highly depending on chemical element and were >1 for Ag, Cd, Cu, K, Mg, Na, P, Rb and Zn, while <1 for Al, Ba, Ca, Co, Cr, Fe, Mn, Ni, Pb and Sr. Topsoil showed elevated content of lead and mean concentration was 99 ± 32 μg/g dw, while cadmium was at 0.41 ± 0.15 and those two highly toxic to human elements occurred in edible caps of L. scabrum at 4.5 ± 2.2 and 2.9 ± 2.0 μg/g dw, respectively.  相似文献   

2.
Si, Ti, Al, Fe, Mn, Ca, Mg, K, Na, P and Sr, Ba, Rb, Ga, V, Zr, Cr, Ni, Co, Cu, Zn, Pb,Nb, Y, Th, La in the core S01 were analyzed and the pattems of their enrichment are discussed.Enrichment of Na, Fe, Mn, Ba, Cu elements in the core indicates volcanic material are an importantsoarce of the sediments in the area. The enrichment frequently varying with the deposition processshows bottom volcanism is frequent in the area and that the studied area is a margin basin with distinctoceanic characteristics. The abnormal enrichment of Mn at the layers(0-15 cm and 665-670 cm) of the core could beclosely related to and so, indicate, the wide deposition hiatus that have occurred in the West PacificOcean and adjacent margin seas since Late Pleistocene.  相似文献   

3.
Regular distribution patterns of elements Ca, Sr, K, Na, Mg, Fe, Mn, Ti, Cu, Co, Ni, Zn, Pb, Cr, Rb, Ba, Cd, and U in Late Quaternary strata have been studied in detail. The regional variation patterns of elements in these strata are similar to those in recent surface sediments, showing that the sedimentary environment has been relatively stable since Late Quaternary. Element distribution changes with the variations of lithological characters. Contents of Ca and Sr increase in coarse sediments, while those of other elements decrease. Na content increases in the pumice layer. Mn, content tends to increase sharply towards the surface layer. Ca content decreases sharply in strata where water depth is more than 2,000 m. The strata can be divided based on the distribution curves of element assemblages. The variations in contents of most elements in Holocene Series are smaller than those in Late Pleistocene Series, which might be related to the factors of glacial and interglacial changes, sea level fluctuations and material source differences. Contribution No. 1488 from Institute of Oceanology, Academia Sinica  相似文献   

4.
辽宁金伯利岩地质—地球化学研究结果表明,辽宁金伯利岩主元素丰度较世界金伯利岩的平均成分,显示富Ca、Al和贫K、Na、Mg、Si,碱度偏低;与南非、苏联和我国山东含金刚石金伯利岩相比,Fe 质偏高。辽宁金伯利岩含矿程度由富到贫,有 Fe、Mg 组分增高,Ca 质降低,微量元素多趋富集的总体变化趋势。辽南金伯利岩较辽北金伯利岩具有碱性程度相对偏高,V、Li、Rb、Nb、La、Sn、Mo、Cu、Pb、Zn、Ag、Ba、Cd、B、S、F 等元素相对富集,Co、Ni、Cr、Th、Bi、Au、As、Sb、Hg、Sr 等元素相对贫化的特点。二者的元素组合和相关特征有明显差别。辽南金伯利岩 Na、Ca、Mn 3元素的相关组合特征是富、贫(中)金刚石金伯利岩的一个地球化学标志。  相似文献   

5.
This paper reported the results of the determination of Ag, Al, Ba, Ca, Cd, Co, Cr, Cu, Fe, K, Mg, Mn, Na, Ni, P, Pb, Rb, Sr and Zn in Common Chanterelles (Cantharellus cibarius) Fr. and surface soil layer (0-10 cm) underneath the fruiting bodies. Mushrooms and soils were collected from a lowland site in the Hel Peninsula (Baltic Sea coast) and a high mountain site in the Tatra Mountains. The trace elements were determined using validated method and inductively coupled plasma - atomic emission spectroscopy (ICP-AES). Common Chanterelles that emerged at sites poor in mineral nutrients podzols of the Hel Peninsula forests efficiently bioconcentrated several essential trace elements (K, P, Co, Cu, Mn, Na, Zn), while the abundance of those elements in carpophores was around half less compared to specimens from Zakopane region and which emerged in soils much richer in minerals. Common Chanterelles collected at two spatially distant background areas in Poland were only weakly contaminated with metals such as Ag, Cd, Hg and Pb. The maximum tolerable Cd and Pb contents of certain cultivated mushrooms are regulated in the European Union by law and these hazardous metals in C. cibarius were far below tolerance limits set.  相似文献   

6.
We applied solution-based ICP-MS method to quantify the trace-elemental signatures in statoliths of jumbo flying squid, Dosidius gigas, which were collected from the waters off northern and central Chile during the scientific surveys carried out by Chinese squid jigging vessels in 2007 and 2008. The age and spawning date of the squid were back-calculated based on daily increments in statoliths. Eight elemental ratios(Sr/Ca, Ba/Ca, Mg/Ca, Mn/Ca, Na/Ca, Fe/Ca, Cu/Ca and Zn/Ca) were analyzed. It was found that Sr is the second most abundant element next to Ca, followed by Na, Fe, Mg, Zn, Cu, Ba and Mn. There was no significant relationship between element/Ca and sea surface temperature(SST) and sea surface salinity(SSS), although weak negative or positive tendency was found. MANOVA analysis showed that multivariate elemental signatures did not differ among the cohorts spawned in spring, autumn and winter, and no significant difference was found between the northern and central sampling locations. Classification results showed that all individuals of each spawned cohorts were correctly classified. This study demonstrates that the elemental signatures in D. gigas statoliths are potentially a useful tool to improve our understanding of its population structure and habitat environment.  相似文献   

7.
Sediment samples obtained from the South Mid-Atlantic Ridge were analyzed for the major and trace elements by inductively coupled plasma atomic emission spectroscopy and inductively coupled plasma mass spectrometry. Results revealed that the contents of elements (e.g., Fe, Mn, Cu, Zn, V, Co) were high in samples 22V-TVG10 and 26V-TVG05 from the sites near the hydrothermal areas, and low in sample 22V-TVG14, which was collected far from the hydrothermal areas. The contents of Ca, Sr and Ba in the samples showed opposite trends. A positive correlation between the concentrations of metallic elements (Cu, Zn, Co, Ni, Pb, V) and Fe in the samples were observed. These results are consistent with chemical evolution of the dispersing hydrothermal plume.  相似文献   

8.
A total of 21 elements, Si, Al, K, Na, Ca, Mg, Fe, Mn, Ti, P, Cu, Co, Ni, Zn, Pb, Cr, Rb, Sr Ba, Cd and Corg(organic carbon), was determined in the trough. Average contents of most elements were found to be higher in the trough bottom than in the western and eastern slopes. We call these elements the indicator elements because of their “transition” property. This is in keeping with the “intermediate” geographical position of the trough where the continental crust turns to oceanic crust. Though the authigenic fraction of some elements here increases, the detrital fraction of most elements is still dominant, indicating that the influences of terrigenous and volcanic detrital materials on the trough sediments are still dominant. The abundant biogenous component in the trough is characterized by the increase of Ca, Sr, and Corg contents. Ca existes mainly in the form of CaCo3 that is mostly found in various shells. Sr often easily replaces Ca within the shells. A belt-shaped distribution pattern of elements was found in the south and a “block” pattern in the north trough. Such distribution patterns are directly controlled by water depth, topography, current sediment type, and mineral, biological, and volcanic processes. This paper was published in Chinese in Oceanologia et Limnologia Sinica15(4): 371–379, 1984.  相似文献   

9.
利用土壤元素资料2069448个数据,大肠癌死亡调查资料42480例,研究了大肠癌死亡率与土壤环境中砷、镉、钴、铬、铜、氟、汞、锰、镍、铅、硒、钒、锌、锂、钠、钾、铷、铯、银、铍、镁、钙、锶、钡、硼、铝、镓、铟、铊、钪、钇、镧、铈、镨、钕、钐、铕、钆、铽、镝、钬、铒、铥、镱、镥、钍、铀、锗、锡、钛、锆、铪、锑、铋、钽、碲、钼、钨、溴、碘、铁等61个元素的相关性.结果表明.砷、钒、铯、铊、铀、锑元素与大肠癌死亡率有相关性.等级相关分数分别为-0.5123(p＜0.005),-0.3179(p＜0.05),-0.3190(p＜0.05),-0.4552(p＜0.01),-0.4857(p＜0.005),-0.3232(p＜0.05)  相似文献   

10.
Episodic deposition has been recognized as a major factor affecting the decomposition rate of detrital material in salt marshes. In this paper, three one-off burial treatments, no burial treatment(0 cm, NBT), current burial treatment(10 cm, CBT) and strong burial treatment(20 cm, SBT), were designed in intertidal zone of the Yellow River Estuary to determine the potential influences of episodic deposition on nutrient(C, N) and heavy metal(Pb, Cr, Cu, Zn, Ni, Mn, Cd, V and Co) variations in decomposing litters of Suaeda glauca. Results showed that although various burial treatments showed no statistical difference in decomposition rate of S. glauca, the values generally followed the sequence of CBT(0.002 403/d) SBT(0.002 195/d) NBT(0.002 060/d). The nutrients and heavy metals in decomposing litters of the three burial treatments exhibited different variations except for N, Cu, Cr, Ni and Co. Except for Mn, no significant differences in C, N, Pb, Cr, Cu, Zn, Ni, V and Co concentrations occurred among the three treatments(P 0.05). With increasing burial depth, Cr and Cd levels generally increased while Cu, Ni and Mn concentrations decreased. Although episodic deposition was generally favorable for C and N release from S. glauca, its influence on release was insignificant. In the three burial treatments, Pb, Cr, Zn, Ni, Mn, V and Co stocks in S. glauca generally evidenced the export of metals from litter to environment, and, with increasing burial depth, the export amounts increased greatly. The S. glauca were particular efficient in binding Cd and releasing Pb, Cr, Zn, Ni, Mn, V and Co, and, with increasing burial depth, stocks of Cu in decomposing litters generally shifted from release to accumulation. The experiment indicated that the potential eco-toxic risk of Pb, Cr, Zn, Ni, Mn, V and Co exposure would be serious as the strong burial episodes occurred in S. glauca marsh.  相似文献   

11.
Characteristics of metals in the aerosols of Zhongshan Station, Antarctica   总被引：1，自引：0，他引：1  
Instrumental neutron activation analysis (INAA) was applied to analyze the bulk, high-volume aerosol samples, collected at Zhongshan Station in the Eastern Antarctica, during 1998-2001, to study the chemical species. .A graphical technique was applied to the INAA data. Results showed that Na, Cl, Mg, Ca, Sr, Br, I, Sr and Rb were marine elements while Al, Sc, Fe and Mn were crustal elements. Compared to marine and crustal elements, five elements (Se、Co、Sb、Zn、Cr) were highly abundant in the aerosols collected at Zhongshan station, which indicated that they might come from the petroleum burning, heating and equipment operation. The presence of pollutant elements suggested that human activities have affected the local environments in Antarctica.  相似文献   

12.
作者利用全省不同地质时代和不同地质构造单元内的页岩41种元素的分析数据,计算出辽宁省全域内的页岩元素丰度休系。同时探讨了元素从中、晚元古代至中生代的演化规律,指出Ca、Cd、Sb、As、Na、Mn、P、Sr的元素丰度随时间序列的演化不断增长,B、F、K、Rb、W、Mg则显示出降低的趋势。某些元素比值从老至新表现出明显的规律性变化,如Sr/Ba、Ca/Mg值的演化具有阶段性,K/Na、Th/U值的演化具有方向性,Al/Ti值的演化则具有周期性。  相似文献   

13.
Aerosol samples were collected at two coastal suburban stations, Qingdao （China） in 1995-1996 and Liverpool （U.K.） in 1995, respectively. The samples were analyzed to determine the concentrations of trace metals （Cr, Zn, Cu, Co, Ni, Pb, V, and Cd） as well as A1, Fe and Mn. Data were examined to understand the difference of trace metals in aerosols between coastal zones downwind the developing area （near the Yellow Sea） and developed region （near the Irish Sea）. The results show that most elements at Qingdao have levels 4-5 times higher than those at Liverpool, particularly for the crust-dominated elements （e.g. Al, Fe and Mn）. Moreover, the aerosol composition at Qingdao is higher in spring than in summer, underlying the influence of westerlies and local emissions in combination, whereas seasonal change of aerosol composition is not significant at Liverpool. The enrichment factors for the crustal source elements （EFcrust） at Liverpool are much higher than those at Qingdao. The contributions from the pollutant source （Rp） for some trace metals like Cu, Pb, Zn and Cd are 〉90% at Qingdao and Liverpool, suggesting overwhelming anthropogenic contributions to these metals. The contributions from crustal source （Re） for trace metals tend to increase with higher aerosol levels and Al concentration at Qingdao, indicating a good correlation between the crust-dominated component and the air mass. At Liverpool, the Rc values for trace metals are positively correlated with Al concentrations instead of with aerosol mass, suggesting that Al in aerosols represents the crustal component even though the aerosols come from different sources.  相似文献   

14.
Sediment cores with length of 25 - 45cm at 12 stations in Zhujiang(Pearl) River Estuary were sampled in summer of 1999. Chemical components (Al2O3 , Fe2O3, CaO, TiO2, Cu, Pb, Cr, Zn, Co, Ni, V, Ba, Sr and Y) and grain sizes were analyzed. Sediments in Zhujiang River Estuary are characterized by relatively coarse grain size. The grain sizes of the sediments in the area outside the estuary are relatively finer than those in the north part of the estuary but coarser than those in the middle of Lingdingyang and have a trend similar to the spatial distribution trend of some chemical components such as Fe2O3, Al2O3, TiO2, V, Cu, Ni, Zn and Y. This showed that grain size is an important factor that controls the spatial distribution and depth profile of chemical elements in the Zhujiang River Estuary. Frequent re-suspension, re-transportation and redistribution of settled sediment on estuary floor could be deduced from the spatial distributions and depth profiles of chemical components. Except for CaO and Sr, the chemical components always enrich at the west side of, in the middle of, and at the north side of, the estuary. Fe2O3, Al2O3, Ti, V, Cr, Ni, Zn, Cu and Y in Zhujiang River Estuary sediments mainly result from rock and soil weathering except that parts of Cr, Ni, Zn Cu and Y are anthropogenic. CaO and Sr in sediments originate from marine source. Although Co as well as Pb derives from anthropogenic sources, human activities related to Co might differ from the activities related to Pb.  相似文献   

15.
利用元素分析仪和原子吸收光谱仪分析了褶纹冠蚌(Cristaria plicata Leach)的四个不同培育阶段的珍珠的十三种元素的含量,以期从连续动态的角度探讨珍珠的形成机制。结果表明,随着育珠时间的延长,珍珠中Ca元素的含量是逐渐增加的,C和H元素的含量则是逐渐下降的。在微量元素中,Na、Cu、Zn、Mg和Sr的含量比较高,其中Na在晚期的珍珠中的含量显著高于早期的珍珠,而CuZn、Mg等其它微量元素则是在早期珍珠中的含量明显高于晚期珍珠,它们随着育珠时间的延长呈指数下降。  相似文献   

16.
Marine sediments were dissolved by HNO3-HF-HCIO4 in a sealed container at low pressure; I-IF was evaporated in an open container and salts were dissolved in HCl by heating, then transferred to 2% HNO3 solution. A total of 45 elements, including Li, Be, So, Ti, V, Cr, Mn, Co, Ni, Cu, Zn, Ga, Rb, Sr, Y, Zr, Nb, Mo, Cd, In, Sb, Cs, Ba, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Hf, Ta, W, TI, Pb, Bi, Th and U, were measured by inductively coupled plasma mass spectrometry (ICP-MS). Condi-tions and sample experiments showed that this procedure defines a good experimental method which has the advantages of clear interference, easy operation and reliable results. The concentrations of the 45 elements could be used for resource exploration, envi-ronmental assessment and academic research.  相似文献   

17.
ＤＩＳＴＲＩＢＵＴＩＶＥＴＥＮＤＥＮＣＹＯＦＥＬＥＭＥＮＴＣＯＮＣＥＮＴＲＡＴＩＯＮＳＩＮＬＩＭＥＳＴＯＮＥＳＯＩＬＳＩＮＥＡＳＴＥＲＮＣＨＩＮＡＷｅｎＹａｎｍａｏ（温琰茂）；ＺｅｎｇＳｈｕｉｑｕａｎ（曾水泉）；ＰａｎＳｈｕｒｏｎｇ（潘树荣）；Ｌｕｏ...  相似文献   

18.
A method was developed for content determination of Na, Mg, A1, Si, P,S, C1, K, Ca, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, Ga, Nb, Zr, Y, Sr, Rb, Ba, La and Ce etc. covering 26 major, minor, and trace elements in marine sediment samples using fused glass disc by X-ray Fluorescence spectrometry. Calibration was made using marine sediment certified reference materials and the synthetic standard samples prepared by mixing several marine sediments with stream sediment and carbonate standard samples in different proportions. The matrix effect was corrected using theoretical alpha coefficients, experience coefficients and the scattered radiation as the internal standard （for the trace elements）. The accuracy of the method was evaluated by analysis of certified reference materials GBW07314, GBW07334 and GSMS6. The results are in good agreement with the certified values of the standards with RSD less than 2.60%, except for Y, Cr, Ga, Ce, La, Nb, Rb, and V with RSD less than 9.0% （n=12）.  相似文献   

19.
利用空气—乙炔火焰原子吸收光谱法对马氏珍珠进行了１３个元素的测定，结果表明优质珍珠与劣质珍珠主要在Ｚｎ、Ｍｇ、Ｃｕ、Ｍｎ、Ｐｈ、Ｋ、Ｃｒ、Ｓｒ等元素含量方面有差异。珍珠在加工前后变化很大的元素是Ｚｎ、Ｍｇ、Ｃｕ、Ｎａ、Ｍｎ、Ｃｒ、Ｓｒ等。根据一些元素对珍珠质量的显著影响，提出在加工过程应注意对珍珠质量有利元素的加入和有损珍珠质量的元素的去除。  相似文献   

20.
浅层地下水调查是山东省黄河下游流域生态地球化学调查项目中的一项工作内容。调查是按每16 km2采集1件浅层地下水样品的密度,分析测试As,Ba,Be,Ca,Cd,Co,Cu,Fe,Hg,Pb,Se,Zn,F-,Cl-,Cr6 ,NO2-,COD,pH等33项指标;通过对这些指标在浅层地下水中的背景变化规律研究认为:调查区内浅层地下水中各指标含量起伏变化大,局部富集程度高,特别是As,Fe,K,La,Sb,Sn,Zn,Cl-,NO2-等指标的变异系数均>3.0,说明这些指标在浅层地下水中分布极不均匀,虽然背景含量较低,但在局部地段会形成高含量区,影响浅层地下水质量。选择As,Ba,Be,Cd,Co,Cu,Fe,Hg,Mn,Mo,Ni,Pb,Se,Zn,F-,Cl-,Cr6 ,NO2-,COD,pH等20项指标,按《地下水环境质量标准》中的要求,对浅层地下水环境质量进行的单项组分和综合评价结果显示,达到较好级以上者不足9%,而较差和极差级者达90%以上,表明调查区内浅层地下水环境污染状况较为严重。  相似文献   

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