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1.
A radiotracer technique, employing 27Mg, is used to determine the Mg released by ammonium exchange on undis-solved humic acid in a seawater medium. This new method allows for the measurement of exchangeable Mg on the solid phase surface, which eliminates the problem caused by the high-Mg background in the seawater matrix. The precision calculated from the counting statistics is better than ±2%; the reproducibility among repeated counts ranged from ±1% to ±3%. The higher sensitivity of the method allows for monitoring the Mg---NH4 exchange at concentrations as low as 30 mM NH4. This is a major improvement relative to the data obtained with the analytical methods used so far, which allow detection of exchangeable Mg only at NH4 concentrations higher than 1 M. The lower experimental concentrations are more in accordance with the natural ammonium levels found in anoxic marine sediments. For the undissolved humic acid used in this experiment, the amount of exchangeable Mg in apparent equilibrium with an ammonium-free seawater matrix was found to be 96.6 ± 0.4 meq/100g. The Mg---NH4 exchange on humic acid in seawater comes to a steady-state value in < 18 min. The conditional equilibrium constant obtained for this reaction, Kcond = 0.039 ± 0.001 M−1. The technique can be expanded to other geochemical solid phases in seawater and it can be modified to study the behavior of the major cations by using 24Na, 42K and 49Ca. 相似文献
2.
DAN HAMMARLUND 《Boreas: An International Journal of Quaternary Research》1999,28(4):564-574
A Late Weichselian sediment succession from the Kullen Peninsula, southern Sweden, was studied by means of stable carbon and oxygen isotope analyses of calcitic valves of selected ostracod taxa. The lower part of the record was deposited in a slightly brackish marginal sea close to the receding inland ice, whereas the upper part is lacustrine in origin as a result of glacio-isostatic rebound. The site was deglaciated at c. 17 200 cal BP (c. 14 500 14C BP) within the earliest ice-free area of Sweden, and the isolation took place c. 1100 cal years later. As a result of extensive input of glacial meltwater to the near-shore, shallow basin, the isotopic records predating the isolation give no clear indications of marine conditions. However, the isolation of the lake from the marginal sea is reflected by a distinct depletion of 18O in ostracod calcite as a response to the changing isotope hydrology of the basin. The change towards a lacustrine environment also fostered a decrease in the input of minerogenic material and a related increase in organic carbon content of the sediments, which may explain a short-lasting depletion of 13C in dissolved inorganic carbon and ostracod calcite. During the period of c. 14 700-13 900 cal BP a pronounced warming occurred associated with the onset of the Late Weichselian interstadial complex (Greenland Interstadial 1). Based on a distinct enrichment of 18O in ostracod calcite and applying modern spatial relations between δ18O of precipitation and temperature, this climatic shift involved an increase in mean annual air temperature in southernmost Sweden of at least 7°C. 相似文献
3.
13C- and 1H-NMR spectra were obtained for humic substances isolated from a coastal marine environment and also for the intracellular and extracellular extracts of a marine diatom. Phaeodactylum tricornutum Bohlin. Highly branched alkyl chains constitute a large proportion of the structure of the marine humic material, whereas aromatic components are less important. Carbohydrate-type materials, possibly uronic acids, are also present in appreciable amounts. Furans (derived from carbohydrates). pyrroles and nitriles (derived from proteins, nucleic acids and/or tetrapyrroles) and phenols and methylphenols (non-lignin derived) are pyrolysis products derived from pyrolysis-gas chromatography-mass spectrometry of the extracts. The results indicate the similarities in chemical structure of P. tricornutum exudate and dissolved marine humic material. 相似文献
4.
Birger Schmitz Stephen L. Ingram David T. Dockery III Gran berg 《Chemical Geology》1997,140(3-4):275-287
Mixed marine, brackish-water and terrestrial vertebrate skeletal apatite is found in the late Paleocene-early Eocene Tuscahoma and Bashi Formations of Mississippi. The co-Occurrence in these near-coastal marine deposits of skeletal apatite with different provenances offers a unique opportunity for unraveling the effects of diagenesis on apatite 87Sr/86Sr composition, with bearings on the use of this isotope pair as paleosalinity indicator. The results show that the Sr isotopes of all originally poorly ordered phases of skeletal apatite have extensively re-equilibrated with pore water with significantly lower 87Sr/86Sr ratios than late Paleocene-early Eocene seawater. For example, marine shark and ray teeth from the Bashi Formation all have clearly nonmarine 87Sr/86Sr ratios, 0.7073-0.7075, compared with a coeval seawater ratio in the range 0.7077-0.7078. However, separated shark tooth enamel, with a high original crystallinity, appears to have retained all or most of its in vivo Sr isotopic signature until the present. Here we also show that 87Sr/86Sr results on recent vertebrate skeletal material from different environments are in good agreement with expected values for respective habitat.
Earlier analyses of calcite material from the Bashi Formation indicated the existence of a shift in seawater 87Sr/86Sr to a lower value at the Paleocene-Eocene boundary. The strong influence of pore water with low, nonmarine 87Sr/86Sr on the apatite in the Bashi Formation suggests that the proposed isotopic shift may be an artifact related to diagenetic processes. 相似文献
5.
大兴安岭北段新林地区晚古生代花岗岩主要出露在大乌苏和富西里附近,岩性主要为二长花岗岩,另有少量花岗闪长岩。对其中二长花岗岩样品进行LA-ICP-MS锆石U-Pb测年表明,大乌苏和富西里岩体侵位年龄分别为（303.7±2.2）和（300.5±0.5）Ma,均为晚石炭世岩浆活动的产物。花岗岩具有富硅（w（SiO2）为66.77%~75.85%）、富碱（w（Na2O+K2O）为7.41%~8.69%）、高铝（w（Al2O3）为12.90%~16.22%）,低MgO、CaO、TiO2的特点,属于钙碱性系列;铝饱和指数（A/CNK）为1.06~1.44,为过铝质岩石;镜下未见原生白云母、堇青石、石榴石等富铝矿物,不同于富铝的S型花岗岩;而w（P2O5）与w（SiO2）负相关,呈I型花岗岩特征;富集LREE和Ba、Rb、K等大离子亲石元素,亏损Nb、Ta、Ti等高场强元素,与后造山I型花岗岩特征相似,应形成于拉张的构造环境。花岗岩的87Sr/86Sr为0.712 938、143Nd/144Nd为0.512 386,（87Sr/86Sr）i值为0.704 4,εNd（t）值为-1.09,TDM2=1 172 Ma,源区物质主要为中-新元古代从亏损地幔增生的地壳物质。结合区域研究成果,大兴安岭新林地区晚石炭世岩浆侵位活动与额尔古纳-兴安地块和松嫩地块碰撞拼合后岩石圈伸展环境有关。 相似文献
6.
7.
Monica M. Grady I. P. Wright L. P. Carr C. T. Pillinger 《Geochimica et cosmochimica acta》1986,50(12):2799-2813
Carbon and nitrogen abundance and isotopic compositions, from four EH4, one EH5, five EL6 chondrites and one aubrite, were determined by using stepped pyrolysis (N only) and combustion (N and C) extractions in attempts to distinguish the components present. Carbon contents range from 0.15 to 0.70 wt%, with no systematic relationship between carbon content and meteorite group or petrologic type. Whole-rock δ13C values range from −28.5 to −4.1 %., Most C occurs as graphite and when temperature steps above 700°C are considered, there is a difference between EH4,5 (δ13C = −9.1 to -5.8%.) and EL6 chondrites (δ13C = −6.7 to +4.2%.). Carbon in Bustee aubrite is isotopically lighter (δ13C = −24%.) than in any enstatite chondrite.
Nitrogen occurs as osbornite, sinoite and in isostructural substitution for oxygen in silicate lattice sites. Nitrogen abundances and isotopic compositions are more variable than C, due to the heterogenous distribution of N-bearing minerals. Three EL6's containing osbornite have higher N concentrations than other type 6 enstatite chondrites. Sinoite, where present, is depleted in 15N relative to osbornite. Nitrogen in the Bustee aubrite has a similar abundance and δ15N value to those of EL6's, again dominated by the presence of osbornite.
In addition to the refractory C-and N-bearing minerals there is also organic material (largely terrestrial contamination) and evidence for at least two “exotic” components. The first is a host for Xe (HL) and is characterized by δ13C <-−47%. and δ15N ≤−73%., whereas the second is less well-defined, but is marked by δ15N = +269%. 相似文献
8.
J. J. Mahoney W. B. Jones F. A. Frey V. J. M. Salters D. G. Pyle H. L. Davies 《Chemical Geology》1995,120(3-4):315-345
Lavas from several major bathymetric highs in the eastern Indian Ocean that are likely to have formed as Early to Middle Cretaceous manifestations of the Kerguelen hotspot are predominantly tholeiitic; so too are glass shards from Eocene to Paleocene volcanic ash layers on Broken Ridge, which are believed to have come from eruptions on the Ninetyeast Ridge. The early dominance of tholeiitic compositions contrasts with the more recent intraplate, alkalic volcanism of the Kerguelen Archipelago. Isotopic and incompatible-element ratios of the plateau lavas are distinct from those of Indian mid-ocean ridge basalts; their Nd, Sr, 207Pb/204Pb and
isotopic ratios overlap with but cover a much wider range than measured for more recent oceanic products of the Kerguelen hotspot (including the Ninetyeast Ridge) or, indeed, oceanic lavas from any other hotspot in the world. Samples from the Naturaliste Plateau and ODP Site 738 on the southern tip of the Kerguelen Plateau are particularly noteworthy, with εNd(T) = − 13 to −7, (87Sr/86Sr)T=0.7090 to 0.7130 and high 207Pb/204Pb relative to 206Pb/204Pb. In addition, the low-εNd(T) Naturaliste Plateau samples are elevated in SiO2 (> 54 wt%). In contrast to “DUPAL” oceanic islands such as the Kerguelen Archipelago, Pitcairn and Tristan da Cunha, the plateau lavas with extreme isotopic characteristics also have relative depletions in Nb and Ta (e.g., Th/Ta, La Nb > primitive mantle values); the lowest εNd(T) and highest Th/Ta and La Nb values occur at sites located closest to rifted continental margins. Accepting a Kerguelen plume origin for the plateau lavas, these characteristics probably reflect the shallow-level incorporation of continental lithosphere in either the head of the early Kerguelen plume or in plume-derived magmas, and suggest that the influence of such material diminished after the period of plateau construction. Contamination of asthenosphere with the type of material affecting Naturaliste Plateau and Site 738 magmatism appears unlikely to be the cause of low-206Pb/04Pb Indian mid-ocean ridge basalts. Finally, because isotopic data for the plateaus do not cluster or form converging arrays in isotope-ratio plots, they provide no evidence for either a quickly evolving, positive εNd, relatively high-206Pb/204Pb plume composition, or a plume source dominated by mantle with εNd of −3 to 0. 相似文献
9.
A wide variety of xenoliths has been entrained in Miocene-to-Recent alkali olivine and hypersthene-normative basalts in the San Francisco Volcanic Field (SFVF), northern Arizona, U.S.A. Based on petrography, mineralogy, bulk rock chemistry and Sr-Nd isotopic characteristics, SFVF xenoliths can be divided into two major groups: cumulates and granulites. The cumulates are genetically related to the Cenozoic volcanic rocks and represent under- and/or intraplated additions to the crust of the Colorado Plateau. Assemblages are mafic to ultramafic and are dominated by clinopyroxene-orthopyroxene-plagioclase-spinel-amphibole-olivine. The granulites are probably Proterozoic in age, mafic-to-intermediate/felsic in bulk composition, either two pyroxene-plagioclase-spinel or plagioclase-alkali feldspar-quartz-magnetite-amphibole-biotite assemblages. Many of the granulites show evidence of partial melting. Some high SiO2, very high Rb/Sr glasses are close in composition to erupted rhyolites, and probably represent end-member melts that have interacted with basalt to produce a variety of hybrid intermediate lavas. The major element, trace element and Sr-Nd isotope geochemistry is highly variable in the SFVF xenoliths. Extremely high Ba contents and Ba/Nb of a number of the granulites are equivalent to values characteristics of modern supra-subduction zone magmas. The considerable variation of chemical and isotopic composition depends upon mineral proportions, assemblages and chemistry. Isotopically, three end-members can be identified within the granulites: (i) lowest 87Sr/86Sr (0.702870) with low 143Nd/144Nd (0.511541, εNd-21.4); (ii) high 87Sr/86Sr (0.711069) with the lowest 143Nd/144Nd (0.511434, εNd-23.5); (iii) highest 87Sr/{86}Sr (0.715306) with low 143Nd/144Nd (0.511793, εNd-16.5). Two important age ranges deduced from the isotopic data probably relate to episodes of crustal-growth beneath the SFVF (1.88 ± 0.33 Ga and Cenozoic). Thermobarometric calculations assuming equilibrium show that the xenoliths are derived from the lower crust (0.6–1.3 GPa, 850–1050 °C). The average SFVF lower crust is mafic in composition. In the absence of partial lithospheric delamination, the lower crust may become mafic with time due to under- and intraplating of continental crust by mafic magmas derived from the mantle. 相似文献
10.
Alkaline magmas from the late-Cenozoic Marie Byrd Land Volcanic Province, West Antarctica, have entrained lithospheric xenoliths which vary from spinel lherzolites to supracrustal rocks. Lower crustal xenoliths have been collected from the Executive Committee Range (Mounts Hampton in the north and Mount Sidley in the south) in central Marie Byrd Land, and their petrological characteristics together with preliminary geochemical data are discussed here. Granulite xenoliths include metaigneous gabbros and norites with varying proportions of clinopyroxene, spinel and either olivine or orthopyroxene. Pyroxenites occur together with granulites, which on the basis of their similar mineral assemblage, texture and composition are considered to be related to the granulites. The composition of xenoliths from Mounts Hampton and Sidley differ (e.g. Mount Sidley xenoliths have Mg# 32–80, are relatively LREE enriched and have 87Sr/86Sr of 0.70286–0.70376 and 143Nd/144Nd of 0.512864–0.512870, whereas Mount Hampton xenoliths have Mg# 68–78, are LREE depleted and have 87Sr/86Sr of 0.70420–0.70458 and 143Nd/144Nd of 0.512771–0.512819), defining a major lateral lower crustal discontinuity beneath the Executive Committee Range. Relict igneous textures and low abundances of incompatible elements indicate that the xenoliths initially formed as cumulates rather than as trapped melts. The xenolith suite differs in composition to the host rocks (Mount Sidley VOLCANICS = 87Sr/86Sr of 0.70300–0.70312 and 143Nd/144Nd of 0.512814–0.512907) and cannot be co-genetic with them. They are interpreted here to represent the cumulates of mantle melts that evolved by crystal fractionation at lower crustal depths. 相似文献
11.
Temporal Variation in Sr and 87Sr/86Sr of Yangtze River: An Example from Datong Hydrological Station
Temporal variation of dissolved 87Sr/86Sr in the Yangtze River is poorly understood compared to other Tibetan rivers. In this study, dissolved Sr and 87Sr/86Sr were measured from a temporal series of water samples collected biweekly at Datong Hydrological Station over a period of one year. Our results show that Sr concentration in the Yangtze River ranges from 1.74 to 2.92 μmol/L with 87Sr/86Sr of 0.710125 to 0.710965. The Sr concentration and 87Sr/86Sr shows a distinct seasonal variation, with a general increase in 87Sr/86Sr ratios from summer to winter and some fluctuations during July and December, then followed by a gradually decrease till the next rainy season. The seasonal variation results from the variation of contributions from different sub-basin due to the spatially and seasonally variable rainfall across the basin. During the flood season, more contribution from upper reach (low 87Sr/86Sr values) due to the strong rainfall decreases the 87Sr/86Sr ratio at lower reach. While the severe drought which happened in the middle-lower reaches (high 87Sr/86Sr values) from January to May explains the decrease in the later part of the data by the decrease of the contribution from middle-lower reaches. The discharge weighted annual 87Sr/86Sr and annual Sr flux of the Yangtze River based on the time series data are 0.710628 and 1.9×109 mol/a, respectively. It was also indicated that dissolved 87Sr/86Sr in the Yangtze River is well correlated to the extreme climate events and might contribute to our explanation for reconstructing past climatic changes by using 87Sr/86Sr ratios of the sedimentary record in the delta . 相似文献
12.
Mantle helium in Sacramento basin natural gas wells 总被引：16，自引：0，他引：16
R. J. Poreda P. D. Jenden I. R. Kaplan H. Craig 《Geochimica et cosmochimica acta》1986,50(12):2847-2853
Helium isotope ratios in Sacramento basin natural gas wells show a strong mantle signal. The 3He/4He ratios range from 0.11 times the atmospheric ratio (0.11 RA) in the Rio Vista field to 2.75 RA in the Moon Bend field, indicating that 1% to 34% of the helium is mantle-derived. 3He/4He versus CH4/4He ratios provide evidence of two-component mixing between crustal and magmatic end-members. Extrapolation of the linear regression line to CH4/4He = 0 gives a hypothetical magmatic end-member 3He/4He ratio of 3.84 RA, half the typical mantle ratio. This indicates that the magmatic end-member may actually represent a mixture of mantle and crustal helium. Gases which deviate from the simple two-component mixture can be explained by addition of pure methane, radiogenic 4He, or a high N2-He component with 3He/4He = 0.6 Ra to 1.0 RA. The CH4/3He ratio of the magmatic end-member remains poorly constrained (0 to 3 × 109) and one cannot rule out the possibility that a significant proportion of the methane in some fields may be of deep-earth origin. However, fields with the highest 3He/4He ratios are associated with buried Plio-Pleistocene intrusives which have up-arched sediments to form hydrocarbon traps. The methane in these fields may have been produced by rapid thermal alteration of the intruded sediment. Elsewhere, the methane appears either to have migrated from deeply-buried sediments in the western basin or to have been produced by local microbial activity. 相似文献
13.
A suite of spinel peridotite xenoliths from the Shavaryn-Tsaram volcano, Tariat Depression (central Mongolia) represents (for major elements) fertile to moderately depleted subcontinental lithosphere. Part of the variation of moderately incompatible trace elements is ascribed to small-scale mineralogical heterogeneities caused by processes like metamorphic differentiation accompanying partial melting or by mechanical segregation. Several bulk lherzolites show a high relative enrichment of the LREE over HREE which can be traced to a grain boundary phase genetically linked to, but not directly representing, the host basanitoid. In Nd and Sr isotopic composition the anhydrous peridotites cover the field of oceanic basalts (143Nd/144Nd = 0.5128-0.5133, 87Sr/86Sr = 0.7020-0.7039). In contrast, a phlogopite peridotite has a high 87Sr/86Sr and also a less radiogenic 143Nd/144Nd. The majority of “dry” lherzolites have Nd and Sr “bulk earth” model ages around 2 Ga. They may be interpreted as dating a small-degree (< ˜5%) melting event which would not have severely affected the major element chemistry of the xenoliths. The ˜2 Ga model ages may indicate a genetic relation between the lithospheric mantle and the stabilization of the continental crust in Mongolia at that time. Alternatively, if the peridotites are unrelated to the overlying crust, they may be pieces of a young asthenospheric diapir. Coexisting ortho-and clinopyroxenes are in Nd isotopic equilibrium for Iherzolites having equilibrated at temperatures around 950°C at mantle pressures. Disequilibrium melting models of mantle rocks are not supported by our data because for medium to coarse-grained mantle spinel peridotite the Rb-Sr and Sm-Nd isotopic systems close with respect to diffusional exchange at temperatures around 900°C, as indicated by recently published diffusion experiment results and supported by our data. 相似文献
14.
A. Rodriguez-Vargas E. Koester G. Mallmann R.V. Conceio K. Kawashita M.B.I. Weber 《Lithos》2005,82(3-4):471-484
In order to provide mantle and crustal constraints during the evolution of the Colombian Andes, Sr and Nd isotopic studies were performed in xenoliths from the Mercaderes region, Northern Volcanic Zone, Colombia. Xenoliths are found in the Granatifera Tuff, a deposit of Cenozoic age, in which mantle- and crustal-derived xenoliths are present in bombs and fragments of andesites and lamprophyres compositions. Garnet-bearing xenoliths are the most abundant mantle-derived rocks, but websterites (garnet-free xenoliths) and spinel-bearing peridotites are also present in minor amounts. Amphibolites, pyroxenites, granulites, and gneisses represent the lower crustal xenolith assemblage. Isotopic signatures for the mantle xenoliths, together with field, petrographic, mineral, and whole-rock chemistry and pressure–temperature estimates, suggest three main sources for these mantle xenoliths: garnet-free websterite xenoliths derived from a source region with low P and T (16 kbar, 1065 °C) and MORB isotopic signature, 87Sr/86Sr ratio of 0.7030, and 143Nd/144Nd ratio of 0.5129. Garnet-bearing peridotite and websterite xenoliths derived from two different sources in the mantle: i) a source with intermediate P and T (29–35 kbar, 1250–1295 °C) conditions, similar to that of sub-oceanic geotherm, with an OIB isotopic signature (87Sr/86Sr ratio of 0.7043 and 143Nd/144Nd ratio of 0.5129); and ii) another source with P and T conditions similar to those of a sub-continental geotherm (>38 kbar, 1140–1175 °C) and OIB isotopic characteristics (87Sr/86Sr ratio=0.7041 and 143Nd/144Nd ratio=0.5135). 相似文献
15.
We investigate the use of a ductile material with temperature-sensitive viscosity for thermomechanical modelling of the lithosphere. First, we consider the scaling of mechanical and thermal properties. For a normal field of gravity, the balance of stresses and body forces sets the stress scale, in proportion to the linear dimensions and the densities. The equation of thermal conduction sets the time scale. The activation enthalpy for creep sets the temperature scale; but the thermal expansivity provides an additional constraint on this temperature scale.
Gum rosin appears to be a suitable material for lithospheric modelling. We have measured its flow properties, at various temperatures, in a specially designed rotary viscometer with unusually low machine friction. The rosin is almost Newtonian. Strain rate depends upon stress to the power n, where 1.0 <n < 1.14. The viscosity varies over 5 orders of magnitude, from about 102 Pa s at 80°C, to about 107 Pa s at 40°C. The activation enthalphy is thus about 250 kJ/mol. Measured with a needle probe, the thermal conductivity is 0.113 ± 0.001 W m−1K−1; the thermal diffusivity, (6±3) ×10−7 m2 s−1. Calculated from X-ray profiles, the thermal expansivity is about 3 × 10−4 K−1. These thermal and mechanical properties make gum rosin suitable for thermomechanical models, where linear dimensions scale down by a factor of 106; time, by 1011; viscosity, by 1017; and temperature change, by 101. 相似文献
16.
Yasuyuki Banno 《Lithos》2000,50(4):289-303
The retrograde chemical zonal structure of amphibole in hematite-bearing basic and quartz schists from the higher grade zone in the Saruta-gawa area of the Sanbagawa belt was studied to investigate the relationships between the prograde and retrograde P–T paths of the Sanbagawa metamorphism. This amphibole coexists with chlorite, epidote, muscovite, albite, quartz and hematite, and is composed of Al-rich core and Al-poor mantle. The core is fairly homogeneous and has a barroisitic composition. In the mantle part, [B]Na increases with decreasing [4]Al towards the margins, which have winchite–magnesioriebeckite compositions. The barroisite–winchite–magnesioriebeckite composite crystal is sometimes rimmed by actinolite and/or winchite with low [4]Al and [B]Na. The Al-rich core and Al-poor mantle are regarded as prograde and retrograde products, respectively. The retrograde mantle in the Saruta-gawa area: (1) is systematically richer in [B]Na [0.40–1.73 per formula unit (pfu; for O=23)] than that from the same grade zone in the Asemi-gawa area (0.19–0.78 pfu), about 8 km south of the studied area; (2) tends to be [B]Na-poorer (less than 1.73 pfu) than prograde sodic amphibole (up to 1.93 [B]Na pfu) produced in the peak temperature stage from the lower grade zone in the same and other areas; and (3) extends its compositional range towards higher [B]Na and lower [4]Al than prograde-formed amphibole from the same grade zone in the same area. These zonal characteristics imply that (1) the Saruta-gawa samples experienced retrograde metamorphism under higher P/T conditions than the Asemi-gawa samples, (2) the retrograde P–T path of the Saruta-gawa area passes on the lower pressure side of the metamorphic field gradient, and (3) the Saruta-gawa samples underwent retrograde metamorphism under higher P/T conditions than the prograde metamorphism. The higher P/T conditions of the retrograde metamorphism suggests an increasing dP/dT of the geotherm during exhumation. Retrograde P–T conditions during the formation of magnesioriebeckite can be roughly estimated at 7–8 kbar, 400–450°C based on semi-quantitative phase relations of actinolite–winchite–magnesioriebeckite–barroisite series associated with chlorite, epidote, muscovite, albite, quartz and hematite. 相似文献
17.
Atmospheric Reactive Nitrogen Cycle and Stable Nitrogen Isotope Processes: Progresses and Perspectives 总被引：1，自引：1，他引：0
Oxidized reactive nitrogen in the atmosphere mainly consists of nitrogen oxides (NO X =NO+NO2, NO3) and nitric acid. The atmospheric cycling of NO X influences the formation of ozone and hydroxyl radicals that are important for atmospheric oxidation capacity. Nitric acid, the final product of NO X oxidation, not only is an important component of particulate pollutants, but also has a direct impact on the ecosystem through dry and wet deposition. The stable nitrogen isotope (δ15N) shows the potential to study reactive nitrogen cycle, and to trace the emission, transport and deposition of reactive nitrogen from local to global scales. Here, we reviewed previous studies using δ15N to investigate NO X emission and atmospheric reactive nitrogen cycle, and discuss the uncertainties of δ15N signatures of different NO X sources from two aspects: NO X generation mechanism and NO X collection methods. We also discussed the nitrogen isotope fractionation and the consequences during the conversions of NO y molecules. We ended up with discussions on the possibility of using δ15N to trace NO X emissions. Although there are still large uncertainties in quantifying and tracing NO X emissions using nitrogen stable isotopes, such isotope tool is efficient enough to trace reactive nitrogen cycles in the atmosphere. On the basis of this, we proposed that we can combine atmospheric chemistry transmission models with isotope tracers to improve our understanding of regional and global atmospheric reactive nitrogen cycle regarding the fluxes of different emission sources, their atmospheric transformation, etc. 相似文献
18.
The 2685–2752 Ma old granite-greenstone crust in the Rainy Lake area, Ontario, consists of metaigneous and metasedimentary rocks that range in composition from tholeiite to monzogranite and include anorthosite, trachyandesite, monzodiorite and high-silica rhyodacite. Major element, rare earth and other trace element data are the basis for modelling the formation of the crust by melting of large-ionlithophile element enriched and unenriched mantle, by melting of basalt at mantle to crustal levels and by melting of monzodiorite and tonalite at crustal levels.
All metaigneous rocks lie on a 143Nd/144Nd vs. 147Sm/144Nd isochron with an age of 2737 ±42 Ma and an initial 143Nd/144Nd of 0.509178 ±33 (εNd = +1.9). This age is consistent with U-Pb zircon ages, which suggests the Nd isotopic system has been unaffected since the crust-forming events. The positive initial εNd's are further evidence for time-averaged depletion in Sm/Nd relative to CHUR for the Archean mantle. The similarity of the initial Nd isotopic composition for both mantle-derived and crustally-derived rocks suggests rapid recycling of crustal components, which were previously derived from depleted mantle sources.
Initial 143Nd/144Nd ratios on individual rocks range from εNd = +3.3 to εNd = −0.4. Younger granitoids have lower εNd values (+1.5 to −0.1) relative to tholeiites and monzodiorites crystallized from mantle-derived melts (+3.3 to +1.0). Thus, incorporation of slightly older crust (ca. 100–200 Ma) in some of the granitoid source areas is possible. Mantle-derived rocks form an isochron of 2764 ±58 Ma that represents a minimum age for enrichment processes in the mantle sources for the Rainy Lake area. Consideration of data from the Abitibi belt suggests such enrichment processes in the mantle may have preceded crust-forming events in a wide area of the Superior Province, perhaps by as much as 50–70 Ma. 相似文献
19.
The late Cretaceous lithospheric mantle beneath the Central Andes: Evidence from phase equilibria and composition of mantle xenoliths 总被引：3，自引：0，他引：3
Temperature estimates and chemical composition of mantle xenoliths from the Cretaceous rift system of NW Argentina (26°S) constrain the rift evolution and chemical and physical properties of the lithospheric mantle at the eastern edge of the Cenozoic Andean plateau. The xenolith suite comprises mainly spinel lherzolite and subordinate pyroxenite and carbonatized lherzolite. The spinel lherzolite xenoliths equilibrated at high-T (most samples >1000 °C) and P below garnet-in. The Sm–Nd systematics of compositionally unzoned clino- and orthopyroxene indicate a Cretaceous minimum age for the high-T regime, i.e., the asthenosphere/lithosphere thermal boundary was at ca. 70 km depth in the Cretaceous rift. Major elements and Cr, Ni, Co and V contents of the xenoliths range between values of primitive and depleted mantle. Calculated densities based on the bulk composition of the xenoliths are <3280 kg/m3 for the estimated P–T conditions and indicate a buoyant, stable upper mantle lithosphere. The well-equilibrated metamorphic fabric and mineral paragenesis with the general lack of high-T hydrous phases did not preserve traces of metasomatism in the mantle xenoliths. Late Mesozoic metasomatism, however, is obvious in the gradual enrichment of Sr, U, Th and light to medium REE and changes in the radiogenic isotope composition of an originally depleted mantle. These changes are independent of the degree of depletion evidenced by major element composition. 143Nd/144Ndi ratios of clinopyroxene from the main group of xenoliths decrease with increasing Nd content from >0.5130 (depleted samples) to ca. 0.5127 (enriched samples). 87Sr/86Sri ratios (0.7127–0.7131, depleted samples; 0.7130–0.7134, enriched samples) show no variation with variable Sr contents. Pbi isotope ratios of the enriched samples are rather radiogenic (206Pb/204Pbi 18.8–20.6, 207Pb/204Pbi 15.6–15.7, 208Pb/204Pbi 38.6–47) compared with the Pb isotope signature of the depleted samples. The large scatter and high values of 208Pb/204Pbi ratios of many xenoliths indicates at least two Pb sources that are characterized by similar U/Pb but by different Th/Pb ratios. The dominant mantle type in the investigated system is depleted mantle according to its Sr and Nd isotopic composition with relatively radiogenic Pb isotope ratios. This mantle is different from the Pacific MORB source and old subcontinental mantle from the adjacent Brazilian Shield. Its composition probably reflects material influx into the mantle wedge during various episodes of subduction that commenced in early Paleozoic or even earlier. Old subcontinental mantle was already replaced in the Paleozoic, but some inheritance from old mantle lithosphere is represented by rare xenoliths with isotope signatures indicating a Proterozoic origin. 相似文献
20.
花岗岩是陆壳的重要组成部分,它是揭示地壳演化地球动力学过程的主要对象之一。为了揭示夹皮沟—海沟构造带的中生代地质演化,本文系统地开展了该带中段松江河地区花岗岩体内部产出的似斑状花岗岩的野外地质调查、岩相学、单颗粒锆石U-Pb同位素年代学、全岩元素、Hf同位素地球化学的研究。研究结果揭示:岩石呈粉红色、普遍发生较强的糜棱岩化作用,发育糜棱叶理构造;获得岩浆锆石的U-Pb同位素谐和年龄为217～169Ma;加权平均年龄为(169.6±1.8)Ma(n=9,MSWD=1.3);主量元素呈现高硅(71.18%～71.99%)、富碱(8.54%～8.93%)、贫镁(0.42%～0.52%)、贫钙(0.93%～1.38%)特征,并且A/NK>1.0,A/CNK<1.1;微量元素呈现低Rb、Zr和高Sr、Ba等质量分数,高Sr/Y和(La/Yb)_N特征;稀土元素表现轻稀土元素富集、重稀土元素亏损和较弱Eu的正异常特征;获得锆石原位^(176 )Yb/^(177 )Hf值为0.010 517～0.050 159,^(176 )Lu/^(177 )Hf值为0.000 476～0.001 784,^(176 )Hf/^(177 )Hf为0.282 310～0.282 457,对应的锆石εHf(t)值为-12.7～-7.5,二阶段模式年龄为2 792～2 325Ma。上述特征揭示,松江河地区中生代似斑状花岗岩属准中等分异、同碰撞向伸展转换的Ⅰ型花岗岩,原始岩浆起源于新太古代陆壳重熔作用,岩浆就位发生在中侏罗世早阶段;它记录了燕山期早侏罗世古太平洋板块向欧亚大陆之下俯冲的挤压陆壳活化产生岩浆,并于中侏罗世地壳伸展岩浆上升过程中经岩浆结晶分离作用而产生的中等分异岩浆结晶形成,成岩后于晚侏罗世遭受了韧脆性构造作用改造。 相似文献