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1.
The Bilimoia deposit (2.23 Mt, 24 g/t Au), located in the eastern Central Mobile Belt of mainland Papua New Guinea, is composed of fault‐hosted, NW–NNW‐trending Irumafimpa–Kora and Judd–Upper Kora Au‐quartz veins hosted by Middle–Late Triassic basement that was metamorphosed to medium‐grade greenschist facies between Middle–Late Triassic and Early–Middle Jurassic. Mineralizing fluids were introduced during crustal thickening, rapid uplift, change of plate motions from oblique to orthogonal compression, active faulting and S3 and S4 events in an S1–S4 deformation sequence. The Bilimoia deposit is spatially and temporally related to I‐type, early intermediate to felsic and late mafic intrusions emplaced in Late Miocene (9–7 Ma). Hydrothermal alteration and associated mineralization is divided into 10 main paragenetic stages: (1) chlorite–epidote‐selvaged quartz–calcite–specularite vein; (2) local quartz–illite–pyrite alteration; (3) quartz–sericite–mariposite–fuchsite–pyrite wall‐rock alteration that delimits the bounding shears; (4) finely banded, colloform‐, crustiform‐ and cockade‐textured and drusy quartz ± early wolframite ± late adularia; (5) hematite; (6) pyrite; (7) quartz ± amethyst‐base metal sulfides; (8) quartz–chalcopyrite–bornite–Sn and Cu sulfides–Au tellurides and Te ± Bi ± Ag ± Cu ± Pb phases; (9) Fe ± Mn carbonates; and (10) supergene overprint. Fluid inclusions in stage 4 are characterized by low salinity (0.9–5.4 wt% NaCl equivalent), aqueous–carbonic fluids with total homogenization temperatures ranging from 210 to 330°C. Some of the inclusions that homogenized between 285 and 330°C host coexisting liquid‐ and vapor‐rich (including carbonic) phases, suggesting phase separation. Fluid inclusions in quartz intergrown with wolframite have low salinity (0.9–1.2 wt% NaCl equivalent), aqueous–carbonic fluids at 240–260°C, defining the latter’s depositional conditions. The ore fluids were derived from oxidized magmatic source initially contaminated by reduced basement rocks. Wall‐rock alteration and involvement of circulating meteoric waters were dominant during the first three stages and early part of stage 4. Stage 5 hematite was deposited as a result of stage 4 phase separation or entrainment of oxygenated groundwater. Gold is associated with Te‐ and Bi‐bearing minerals and mostly precipitated as gold‐tellurides during stage 8. Gold deposition occurred below 350°C due to a change in the sulfidation and oxidation state of the fluids, depressurization and decreasing temperature and activities of sulfur and tellurium. Bisulfides are considered to be the main Au‐transporting complexes. The Bilimoia deposit has affinities that are similar to many gold systems termed epizonal orogenic and intrusion‐related. The current data allow us to classify the Bilimoia deposit as a fault‐controlled, metamorphic‐hosted, intrusion‐related mesothermal to low sulfidation epithermal quartz–Au–Te–Bi vein system.  相似文献   

2.
Gold-bearing quartz lodes from the Egat gold mine, South Eastern Desert of Egypt, are associated with pervasively silicified, highly sheared ophiolitic metagabbro and island-arc metavolcanic rocks. The mineralized quartz veins and related alteration haloes are controlled by NNW-trending shear/fault zones. Microscopic and electron probe microanalyses (EPMA) data of the ore and gangue minerals reveal that fine-grained auriferous sulfarsenides represent early high-temperature (355–382 °C) phases, with formation conditions as (fS2?=??10, and fO2 around ?31). A late, low-temperature (302–333 °C) assemblage includes coarse pyrite, arsenopyrite, and free-milling gold grains (88–91 wt.% Au), with formation conditions as (fS2?=??8 and fO2 around ?30). Gold was impounded within early sulfarsenides, while free-milling gold blebs occur along microfractures in quartz veins and as inclusions in late sulfides. Infiltration of hydrothermal fluids under brittle–ductile shear conditions led to mobilization of refractory Au from early sulfarsenide phases and reprecipitated free gold, simultaneous with silicification of the host rocks. The positive correlation between Au and As favors and verifies the use of As as the best pathfinder for gold targets, along the NNW-trending shear zones.  相似文献   

3.
South Greenland has been the site of historic mining of cryolite, copper, graphite and gold, hosts mineral deposits with gold, uranium, zinc, niobium, tantalum, zirconium, hafnium, REE, iron, titanium, vanadium, fluorite and graphite, and has additional potential for lithium, beryllium, phosphorus, gallium and thorium. Data from stream sediment geochemical surveys document that South Greenland is enriched in a range of these elements relative to the rest of Greenland and to estimates of the upper crust composition. Distribution patterns for individual elements within south Greenland exhibit enriched regions that are spatially related to lithological units, crustal structure and known mineralisation.The Northern Domain of South Greenland includes the southernmost part of the orthogneiss-dominated North Atlantic craton. Orogenic gold mineralisation is hosted by quartz veins and hydrothermally altered rocks associated with shear zones intersecting the Mesoarchaean Tartoq Group of mafic metavolcanic rocks. Geochemical exploration indicates that additional potential for gold mineralisation exists within Palaeoproterozoic supracrustal rocks overlying the Archaean basement.Rocks formed during the Palaeoproterozoic Ketilidian orogeny occupy a major part of South Greenland and has been divided into two domains. The Central Domain is underlain by the Julianehåb igneous complex forming a 100 km wide ENE–WSW zone centrally across South Greenland. Intrusive and extrusive, mostly felsic magmatic rocks were emplaced in two main stages (1850–1830 and 1800–1780 Ma) in a continental arc setting. Positive anomalies in aeromagnetic data indicate that mafic plutons are common in the late igneous complex. Intra-arc mafic metavolcanic rocks contain syngenetic stratabound copper sulphide and epigenetic shear zone-hosted copper–silver–gold mineralisation at Kobberminebugt and Kangerluluk, whereas metasedimentary and metapyroclastic rocks contain stratabound uraninite mineralisation. Orthomagmatic iron–titanium–vanadium mineralisation is hosted by a gabbro. A potential for porphyry-type mineralisation related to the late intrusive stages of the Julianehåb igneous complex is suggested by showings with copper, molybdenum and gold together with stream sediment anomalies for these elements. Vein-type uranium mineralisation occurs in fault zones in the Julianehåb igneous complex related to Mesoproterozoic rifting.The Southern Domain contains an assemblage of Palaeoproterozoic metasedimentary and metavolcanic rocks that underwent moderate to strong deformation, peak HT–LP metamorphism and partial melting with subsequent retrograde exhumation at 1790–1765 Ma. The supracrustal rocks contain syngenetic Au, As, Sb, U, and Zn mineralisation in volcanic or graphite- and sulphide-rich sedimentary environments; graphite was mined historically at two sites. Many stream sediment gold anomalies are located in a NE-trending belt along the boundary between the early Julianehåb complex and the supracrustal rocks to the south. They reflect a number of auriferous quartz vein occurrences, including the Nalunaq gold deposit, hosted in a system of shear zones and probably generated as orogenic gold during Ketilidian accretion. The 1755–1730 Ma, A-type Ilua plutonic suite is the latest magmatic event in the Ketilidian orogen.The 1300–1140 Ma Gardar period involved continental rifting, sedimentation and alkaline magmatism. Numerous dykes and 10 ring-shaped intrusion complexes were formed across South Greenland. An orthomagmatic iron–titanium–vanadium deposit is hosted by troctolitic gabbro. Residual magmas and fluids resulting from extreme magmatic differentiation, possibly combined with assimilation of older crust, created mineral deposits including cryolite that was mined at Ivigtut, large low-grade deposits of uranium–rare earth elements–zinc at Kvanefjeld and tantalum–niobium–rare earth element–zirconium at Kringlerne, in the Ilímaussaq complex, as well as tantalum–niobium–rare earth elements at Motzfeldt Sø in the Igaliko complex.The South Greenland crustal evolution records effects of mantle processes, such as lithospheric extension, subduction and underplating, which resulted in recurrent magma emplacement in tectonically active environments. As such, the geology of South Greenland reflects events and circumstances that are favourable to the generation and preservation of hydrothermal ore-forming fluid systems during the Ketilidian orogeny as well as to the development of extreme rock compositions within the Gardar alkaline igneous province.  相似文献   

4.
The Heijianshan Fe–Cu (–Au) deposit, located in the Aqishan-Yamansu belt of the Eastern Tianshan (NW China), is hosted in the mafic–intermediate volcanic and mafic–felsic volcaniclastic rocks of the Upper Carboniferous Matoutan Formation. Based on the pervasive alteration, mineral assemblages and crosscutting relationships of veins, six magmatic–hydrothermal stages have been established, including epidote alteration (Stage I), magnetite mineralization (Stage II), pyrite alteration (Stage III), Cu (–Au) mineralization (Stage IV), late veins (Stage V) and supergene alteration (Stage VI). The Stage I epidote–calcite–tourmaline–sericite alteration assemblage indicates a pre-mineralization Ca–Mg alteration event. Stage II Fe and Stage IV Cu (–Au) mineralization stages at Heijianshan can be clearly distinguished from alteration, mineral assemblages, and nature and sources of ore-forming fluids.Homogenization temperatures of primary fluid inclusions in quartz and calcite from Stage I (189–370 °C), II (301–536 °C), III (119–262 °C) and V (46–198 °C) suggest that fluid incursion and mixing probably occurred during Stage I to II and Stage V, respectively. The Stage II magmatic–hydrothermal-derived Fe mineralization fluids were characterized by high temperature (>300 °C), medium–high salinity (21.2–56.0 wt% NaCl equiv.) and being Na–Ca–Mg–Fe-dominated. These fluids were overprinted by the external low temperature (<300 °C), medium–high salinity (19.0–34.7 wt% NaCl equiv.) and Ca–Mg-dominated basinal brines that were responsible for the subsequent pyrite alteration and Cu (–Au) mineralization, as supported by quartz CL images and H–O isotopes. Furthermore, in-situ sulfur isotopes also indicate that the sulfur sources vary in different stages, viz., Stage II (magmatic–hydrothermal), III (basinal brine-related) and IV (magmatic–hydrothermal). Stage II disseminated pyrite has δ34Sfluid values of 1.7–4.3‰, comparable with sulfur from magmatic reservoirs. δ34Sfluid values (24.3–29.3‰) of Stage III Type A pyrite (coexists with hematite) probably indicate external basinal brine involvement, consistent with the analytical results of fluid inclusions. With the basinal brines further interacting with volcanic/volcaniclastic rocks of the Carboniferous Matoutan Formation, Stage III Type B pyrite–chalcopyrite–pyrrhotite assemblage (with low δ34Sfluid values of 4.6–10.0‰) may have formed at low fO2 and temperature (119–262 °C). The continuous basinal brine–volcanic/volcaniclastic rock interactions during the basin inversion (∼325–300 Ma) may have leached sulfur and copper from the rocks, yielding magmatic-like δ34Sfluid values (1.5–4.1‰). Such fluids may have altered pyrite and precipitated chalcopyrite with minor Au in Stage IV. Eventually, the Stage V low temperature (∼160 °C) and low salinity meteoric water may have percolated into the ore-forming fluid system and formed late-hydrothermal veins.The similar alteration and mineralization paragenetic sequences, ore-forming fluid sources and evolution, and tectonic settings of the Heijianshan deposit to the Mesozoic Central Andean IOCG deposits indicate that the former is probably the first identified Paleozoic IOCG-like deposit in the Central Asian Orogenic Belt.  相似文献   

5.
Vein-type, structurally controlled Cu–Au mineralisation hosted by turbidites of late Silurian to earliest Devonian age, forms an important resource close to the eastern margin of the Cobar Basin. Here we report 103 new sulfur isotope analyses, together with homogenisation temperatures and salinity data for 545 primary two-phase fluid inclusions for the mineralised zones from the central area of the Cobar mining district. A range in δ34S values from 3.8 to 11.2‰ (average 7.9‰) is present. Sulfur is likely to have been derived from rock sulfur/sulfide in basin and basement rocks, but there may be an additional connate-derived component. Homogenisation temperatures (Th) for inclusion fluids trapped in quartz and minor calcite veins range from near 150°C to 397°C. Fluid inclusions are characterised by a low CO2 content and low, but variable salinities (2.1–9.1 wt% NaCl equivalent). Generations of inclusion fluids correspond to six paragenetic stages of vein quartz deposition and recrystallisation at the Chesney mine. Primary fluid inclusions in the first two stages were subjected to re-equilibration resulting from increased confining pressure. Their Th range (151–317°C) is considered a minimum for the temperature of these fluids. Sulfide and gold deposition at Chesney appears to be related to fluids of moderately high Th (range 270–397°C) associated with the final paragenetic stage. Th for the ore-related fluids may be close to the solvus of the H2O–NaCl–CO2 system and hence near trapping temperatures. Late-stage entry of a hot, moderately saline ore-forming fluid is implicated as the origin of the Cu–Au mineralisation. However, comparison with geochemical data for the vein-style Zn–Pb–Ag deposits at Cobar demonstrates that differences in metal content for individual zones cannot be attributed to major differences in fluid temperature or salinity. Rather, these differences are probably due to variations in source-rock reservoirs and structural pathways along which the ore-forming fluids moved.  相似文献   

6.
The K‐rich granitoids of the southern Mt Angelay igneous complex belong to the younger phases of the Williams and Naraku Batholiths (<1540 Ma) in the Cloncurry district. Granitoids of the complex form a series of I‐type, K‐rich, metaluminous monzodiorite to subaluminous syenogranite. These intrusions have geochemical affinities akin to ‘A‐type’ granites and contain plagioclase, alkali feldspar, quartz, biotite, hornblende and typically accessory magnetite, titanite, apatite and zircon. With increasing SiO2 the granitoids vary from alkaline to subalkaline, and exhibit a decrease in TiO2, Al2O3, Fe2O3*, MnO, MgO, CaO, P2O5, Cu, Sr, Zr, LREE and Eu, with an increase in Na2O, K2O, Rb, Pb, Th, U, Y and HREE. This suite of relatively oxidised granitoids (<1.0 log units above NNO) were emplaced after the peak of metamorphism and pre‐ to post‐D3, a major east‐west horizontal‐shortening event. The synchronous emplacement of high‐temperature mafic (>960°C) and foliated felsic (>900°C) granitoids formed zones of mingled and mixed monzonite and quartz monzonite to monzogranite containing abundant rapakivi K‐feldspar. These intrusions are interpreted to have been derived from source rocks of different compositions, and probably by different degrees of partial melting. The unfoliated felsic granitoids are considered to represent the fractionated equivalents of older foliated felsic granitoids. All granitoids possess a Sr‐depleted and Y‐undepleted signature, which suggests that the source material probably contained plagioclase and no garnet, restricting magma production to <800–1000 MPa (～24–30 km). Underplating of mantle‐derived mafic material into mid‐crustal levels is considered the most viable mechanism to produce these high‐temperature K‐rich granitoids at these pressures. The composition of the felsic granitoids is consistent with derivation from a crustal source with a tonalitic to granodioritic composition. However, the mafic granitoids require a more mafic, possibly gabbroic source, which may have been supplemented with minor mantle‐derived material. These granitoids are also enriched in Th, U, LREE and depleted in Ba, Ti, Nb and Sr and compare closely to the Mesoproterozoic granitoids of the Gawler Craton. The economic significance of these styles of granitoids may also be highlighted by the close spatial relationship of hematitic K‐feldspar, magnetite, fluorite and pyrite‐rich veins, alteration and filled miarolitic cavities with the least‐evolved felsic intrusions. This style of veining has a probable magmatic origin and is similar to the gangue assemblage associated with Ernest Henry‐style Fe‐oxide‐(Cu–Au) mineralisation, which suggests that these granitoids represent prospective sources of fluids associated with Cu–Au mineralisation in the district.  相似文献   

7.
The Okrouhlá Radouň shear zone hosted uranium deposit is developed along the contact of Variscan granites and high-grade metasedimentary rocks of the Moldanubian Zone of the Bohemian Massif. The pre-ore pervasive alteration of wall rocks is characterized by chloritization of mafic minerals, followed by albitization of feldspars and dissolution of quartz giving rise to episyenites. The subsequent fluid circulation led to precipitation of disseminated uraninite and coffinite, and later on, post-ore quartz and carbonate mineralization containing base metal sulfides. The fluid inclusion and stable isotope data suggest low homogenization temperatures (～50–140 °C during pre-ore albitization and post-ore carbonatization, up to 230 °C during pre-ore chloritization), variable fluid salinities (0–25 wt.% NaCl eq.), low fluid δ18O values (?10 to +2 ‰ V-SMOW), low fluid δ13C values (?9 to ?15 ‰ V-PDB), and highly variable ionic composition of the aqueous fluids (especially Na/Ca, Br/Cl, I/Cl, SO4/Cl, NO3/Cl ratios). The available data suggest participation of three fluid endmembers of primarily surficial origin during alteration and mineralization at the deposit: (1) local meteoric water, (2) Na–Ca–Cl basinal brines or shield brines, (3) SO4–NO3–Cl–(H)CO3 playa-like fluids. Pre-ore albitization was caused by circulation of alkaline, oxidized, and Na-rich playa fluids, whereas basinal/shield brines and meteoric water were more important during the post-ore stage of alteration.  相似文献   

8.
The El Espino IOCG mining district is characterized by several mineralized bodies the largest of which is the El Espino deposit, which has an estimated geologic resource of 123 Mt at 0.66 % Cu and 0.24 g/t Au. Mineralized bodies are distributed in a 7?×?10 km2 area throughout a 1,000-m vertical section. They range from single veins to stockworks and breccias to manto-type deposits. The ore bodies are hosted primarily by volcanic, volcaniclastic, and sedimentary rocks of the Early Cretaceous Arqueros and Quebrada Marquesa formations, with a few mineralized zones within Late Cretaceous dioritic intrusions. The fault and vein architecture shows that El Espino IOCG system was localized within a dilatational jog along a major transtensional dextral fault system. Sodic alteration (albite) is the most extensive style of alteration in the district, and it is bounded by major NS–NNE trending faults. Sodic–calcic (epidote–albite) alteration occurs at deep to medium elevations (1,000–500 m) and grades inward into calcic alteration. Calcic alteration surrounds dioritic intrusions of the Llahuin plutonic suite. Significant iron oxides are associated with later calcic alteration associations (actinolite–epidote–hematite). The upper portions of the alteration system (0–500 m) display hydrolytic alteration associations with abundant hematite. Hydrolytic veins are feeders to zones of manto-type alteration and mineralization within favorable volcano-sedimentary lithologies that formed El Espino deposit. Sulfides are largely confined to calcic and hydrolytic alteration associations. Hydrothermal fluids responsible for hematite and sulfide mineralization had salinities between 32 and 34 wt% NaCleq and temperature of approximately 425 °C at an estimated depth of 3–4 km. Geochronological U–Pb and 40Ar/39Ar data indicate that hydrothermal alteration was coeval with magmatic intrusive activity. One particular dioritic intrusion (88.5 Ma) preceded the calcic stage (88.4 Ma), which was accompanied by iron oxide copper and gold mineralization. Hydrolytic alteration, related to economic iron oxide copper and gold mineralization, came immediately after at 87.9 Ma.  相似文献   

9.
The newly discovered Jiyuan Cu–Ag–(Pb–Zn–Au) deposit is located in the southern section of the eastern Tianshan orogenic belt, Xinjiang, northwestern China. It is the first documented deposit in the large Aqikekuduke Ag–Cu–Au belt in the eastern Tianshan orogen. Detailed field observations, parageneses, and fluid inclusion studies suggest an epithermal ore genesis for the main Cu–Ag mineralization, accompanied by a complicated hydrothermal alteration history most likely associated with the multi-stage tectonic evolution of the eastern Tianshan. The Jiyuan Cu–Ag ore bodies are located along the EW-striking, south-dipping Aqikekuduke fault and are hosted by Precambrian marble and intercalated siliceous rocks. Early-stage skarn alteration occurred along the contact zone between the marble layers and Early Carboniferous diorite–granodiorite and monzogranite intrusions; the skarns are characterized by diopside–tremolite–andradite–pyrite–(magnetite) assemblages. Local REE-enriched synchysite–rutile–arsenopyrite–(clinochlorite–microcline–albite) assemblages are related to K–Na alteration associated with the monzogranite intrusions and formed under conditions of high temperature (310°C) and high salinity (19.9 wt.% NaCl). Subsequent hydrothermal alteration produced a series of quartz and calcite veins that precipitated from medium- to low-temperature saline fluids. These include early ‘smoky’ quartz veins (190°C; 3.0 wt.% NaCl) that are commonly barren, coarse-grained Cu–Ag mineralized quartz veins (210°C; 2.4 wt.% NaCl), and late-stage unmineralized calcite veins (140°C; 1.1 wt.% NaCl). Tremolite and Ca-rich scapolite veins formed at an interval between early and mineralized quartz veins, indicating a high-temperature, high-salinity (>500°C; 9.5 wt.% NaCl) Ca alteration stage. Fluid mixing may have played an important role during Cu–Ag mineralization and an external low-temperature Ca-rich fluid is inferred to have evolved in the ore-forming system. The Jiyuan auriferous quartz veins possess fluid characteristics distinct from those of the Cu–Ag mineralized quartz veins. CO2-rich fluid inclusions, fluid boiling, and mixing all demonstrate that these auriferous quartz veins acted as hosts for the orogenic-type gold mineralization, a common feature in the Tianshan orogenic belt.  相似文献   

10.
The Oligocene Yao’an syenite porphyry, associated with gold mineralisation, and the Machangqing alkali granite porphyry–monzonite porphyry, associated with Cu mineralisation, belong to the Red River–Jinshajiang alkaline igneous belt that formed in a continental setting in southwestern China. A study of the mineral chemistry of major silicate minerals in these two mineralised intrusions provides insights into their overall crystallisation conditions. The temperature and pressure conditions, derived from amphibole–plagioclase and perthite–plagioclase geothermometry and Al-in-amphibole barometry, suggest that the Yao’an intrusion crystallised at around 820?±?50°C and 0.9–1.3 kbar, whereas the Machangqing intrusion crystallised at around 730?±?50°C and 2.2–2.8 kbar. The higher temperature and lower pressure of crystallisation for the Yao’an intrusion relative to the Machangqing intrusion indicates that it was emplaced at a shallower crustal level. Based on biotite composition, the two intrusions formed under imposed oxygen fugacities above the Ni–NiO buffer (NNO), and the Yao’an intrusion crystallised under more oxidising conditions than the Machangqing intrusion. The results show that the intrusions associated with Cu–Au mineralisation in the Red River–Jinshajiang alkaline igneous belt were emplaced at a relatively high fO2, which, together with the weakly fractionated magma, favoured Au enrichment relative to Cu in the belt.  相似文献   

11.
《Ore Geology Reviews》2010,37(4):265-281
Axi is a low-sulfidation type epithermal gold deposit hosted in Paleozoic subaerial volcanic rocks in the western Tianshan orogenic belt, Xinjiang, China. The resource is more than 50 t gold at an average grade of > 4.4 ppm. The deposit occurs in the Tulasu volcanic fault-basin in the Paleozoic active continental margin on the northern side of the Yili-Central Tianshan plate. The host rocks are andesitic volcaniclastic rocks of the Paleozoic Dahalajunshan Formation, and the orebodies occur as veins in annular faults of a paleocaldera. Mineralization at Axi can be subdivided into five stages: quartz and/or chalcedony vein, quartz vein, quartz-carbonate vein, sulfide vein and carbonate vein. There are two types of ore host: quartz vein and altered rocks. Ore minerals are native gold, electrum, pyrite, marcasite, arsenopyrite, hematite, limonite, and trace amounts of pyrargyrite, polybasite, naumannite, cerargyrite, sphalerite, chalcopyrite, tetrahedrite, galena, pyrrhotite and clausthalite; gangue minerals are mainly quartz, chalcedony, illite, calcite, siderite, dolomite, adularia and laumontite. The main wall-rock alteration is silicification and phyllic alteration, carbonatization and propylitization. The deposit is characterized by an enrichment, relative to crustal abundance, of Au, Ag, As, Sb, Bi, Hg, Se, Te and Mo, depletion in base metals (Cu, Pb, and Zn), and a low Ag/Au ratio (0.5–3.7).Three types of fluid inclusions were recognized in quartz from the major mineralization stages: liquid aqueous inclusions, liquid-rich two-phase inclusions and small amounts of vapor-rich two-phase inclusions. Microthermometric measurements indicate that the final ice melting temperatures are − 0.3 to − 4.4 °C, corresponding to salinities of 0.5–6.9 wt.% NaCl equiv. (2.2 wt.% NaCl equiv. in average). The peak temperatures of ice melting varies from − 0.4 to − 1.9 °C, corresponding to salinities of 0.7–3.1 wt.% NaCl equiv. Homogenization temperatures range mainly between 120 and 240 °C, with an average of 190 °C and a maximum of 335 °C. The fluid density is 0.73 to 0.95 g/cm3 and thus the estimated maximum mineralization depth is about 700 m.Hydrogen and oxygen isotopic compositions of the ore fluids lie within a narrow range: δDH2O is − 98 to − 116‰ and δ18OH2O − 1.8 to 0.4‰. 3He/4He ranges from 0.0218 to 0.138 Ra, with an average of 0.044 Ra, indicating that He derived predominantly from crust with negligible mantle He in the ore fluids. By contrast, the 40Ar/36Ar ranges from 317.7 to 866.0, suggesting that crust-derived radioactive 40Ar⁎ accounts for 7.0 to 66%, and atmospheric 40Ar about 43 to 93% in the ore fluids. Hydrogen, oxygen, carbon, sulfur and noble gas isotopes indicate that the ore-forming fluids of the Axi gold deposit consisted predominantly of circulating meteoric water. Ore-forming metals may have derived mainly from the host volcaniclastic rocks of the Dahalajunshan Formation and basement rocks. The occurrence of adularia, platy calcite, and quartz or sulfide aggregates as pseudomorphs after bladed calcite in ore veins, and occurrence of aqueous liquid, and liquid-rich and vapor-rich two-phase inclusions, indicates that boiling of the ore-forming fluid have occurred, leading to supersaturation of the hydrothermal solution and deposition of ore metals. This is the main mineralization mechanism for quartz-vein type ores in Axi. The ore-forming fluid was buffered to a near-neutral pH in a reduced environment during mineralization. The preservation of this Paleozoic Axi deposit and its discovery required a rapid accumulation of sediments in the basin after formation of the deposit, and minimal amount of erosion after Late Cenozoic uplift.  相似文献   

12.
The Tirek gold deposit hosted in the Archean shield is one of the richest sources of mined gold for Algeria. The deposit is controlled by the East Ouzzal shear zone (EOSZ), a transcurrent N–S lithospheric fault. The EOSZ is a late Pan-African dextral-ductile shear zone separating two contrasting Precambrian domains: the Archean In Ouzzal block to the west (Orthogenesis with subordinate metasediments reworked and granulitized during the ca. 2 Ga Eburnean event) and a middle Proterozoic block to the east involved in the ca. 600 Ma Pan-African event. The auriferous quartz veins are mainly oriented in two directions, N–S veins hosted in mylonitic rocks and NE–SW veins hosted in gabbroic or gneissic bands. The NE–SW veins contain the richest ore. Gold ore is found in a system of veins and lenticular quartz veinlets arranged in anastomosing networks. The hydrothermal alteration associated with these veins is characteristically a carbonate-sericite-albite-pyrite assemblage. Gold is the main metal of economic importance; it is disseminated in the quartz as grains or fibers along microcracks and as microscopic grains in the host rocks. Microthermometric results and Raman laser data from fluid inclusions demonstrate that the ore-forming fluids contained H2O-CO2±CH4 and were low salinity. Homogenization temperatures are commonly 250–310 °C. In the Tirek deposit, the role of the shear zone that hosts the mineralization was to drain the hydrothermal fluid. Interactions between the fluid and the mafic host rocks and CO2 also contributed to the formation of the hydrothermal gold deposit at Tirek.  相似文献   

13.
Sulphide separates from mineralisation in Archaean and Palaeoproterozoic host rocks of the Disko Bugt area, central West Greenland, have been analysed for trace elements and Pb isotopes. Isotopic compositions of lead from sulphide separates of Archaean supracrustal rocks show wide variations. Archaean semi-massive sulphides and sulphides separated from felsic metavolcanites yield an errorchron age of 2821 +77/−82, with a model μ1 value of 7.36; this is comparable to the estimated age of the supracrustal rocks. The two most prominent mineralised sites, the Andersen and Eqip prospects, have their own unique Pb isotope pattern; the Andersen prospect is considered to represent the result of an upper crust of Palaeoproterozoic process. The sulphide separates of Palaeoproterozoic epigenetic mineralisation hosted in shear and fault zones in the supracrustal rocks has a common origin, e.g. linked to a metamorphic peak and/or hydrothermal alteration. Gold-bearing samples indicate a local origin for associated sulphides; no regional processes seem to be involved in the formation of the gold occurrences. Received: 17 March 1997 / Accepted: 8 July 1997  相似文献   

14.
The Sibutad gold deposit has gold associated in quartz veins. The most important of these is the Lalab orebody, which contains ore‐grade gold, predominantly, in milky quartz veins and veinlets. Here, alteration quartz and fine‐grained crystalline clear and milky quartz were formed from hydrothermal fluids in three stages, namely stages I, II and III. Fluid inclusion microthermometry was carried out on stage I milky quartz, stage II fine‐grained alteration quartz and stage III milky quartz ± barite veins and veinlets. Homogenization temperatures (TH) are >248°C in stage I, 214–232°C in stage II and 186–239°C in stage III. These fluid inclusions have salinity between 1 and 2 wt% NaCl equivalent. In terms of gold assay, stage I drill‐core samples have gold grades 0.53–0.76 g/ton Au, stage II samples have 1.12–3.70 g/ton Au and stage III samples have 9.06–23.88 g/ton Au. This correlation suggests that gold was precipitated from the stage II and III fluids.  相似文献   

15.
Ultramafic portions of ophiolitic fragments in the Arabian–Nubian Shield (ANS) show pervasive carbonate alteration forming various degrees of carbonated serpentinites and listvenitic rocks. Notwithstanding the extent of the alteration, little is known about the processes that caused it, the source of the CO2 or the conditions of alteration. This study investigates the mineralogy, stable (O, C) and radiogenic (Sr) isotope composition, and geochemistry of suites of variably carbonate altered ultramafics from the Meatiq area of the Central Eastern Desert (CED) of Egypt. The samples investigated include least-altered lizardite (Lz) serpentinites, antigorite (Atg) serpentinites and listvenitic rocks with associated carbonate and quartz veins. The C, O and Sr isotopes of the vein samples cluster between ?8.1‰ and ?6.8‰ for δ13C, +6.4‰ and +10.5‰ for δ18O, and 87Sr/86Sr of 0.7028–0.70344, and plot within the depleted mantle compositional field. The serpentinites isotopic compositions plot on a mixing trend between the depleted-mantle and sedimentary carbonate fields. The carbonate veins contain abundant carbonic (CO2±CH4±N2) and aqueous-carbonic (H2O-NaCl-CO2±CH4±N2) low salinity fluid, with trapping conditions of 270–300°C and 0.7–1.1 kbar. The serpentinites are enriched in Au, As, S and other fluid-mobile elements relative to primitive and depleted mantle. The extensively carbonated Atg-serpentinites contain significantly lower concentrations of these elements than the Lz-serpentinites suggesting that they were depleted during carbonate alteration. Fluid inclusion and stable isotope compositions of Au deposits in the CED are similar to those from the carbonate veins investigated in the study and we suggest that carbonation of ANS ophiolitic rocks due to influx of mantle-derived CO2-bearing fluids caused break down of Au-bearing minerals such as pentlandite, releasing Au and S to the hydrothermal fluids that later formed the Au-deposits. This is the first time that gold has been observed to be remobilized from rocks during the lizardite–antigorite transition.  相似文献   

16.
The Canan area (Honduras) is characterized by a gold-bearing ore deposit that is associated with quartz-veined shear zones. Gold mineralization occurs in low-to medium-grade metamorphic host-rocks (graphitic and sericitic schists). Hydrothermal fluids, which are associated with the emplacement of Cretaceous-Tertiary granodioritic intrusions, are responsible for the formation of quartz veins and the hydrothermal alteration of wall-rocks. Three main altered zones have been detected in the wall-rocks as far as 150 cm from the quartz veins. The distal zone (up to 50-cm thick) contains quartz, chlorite and illite. The intermediate zone is the thickest (up to 80 cm) and is marked by quartz, muscovite, sulphides, kaolinite and native elements such as Au and Ag. The proximal zone, which is close to the quartz veins, is rather thin (up to 25 cm) and contains clay minerals, Al-oxides-hydroxides and sulphides. The transition from the distal to the proximal zone is accompanied by the enrichment of SiO2 and the depletion of all other major elements, except for Fe2O3(tot). Precious metals occur in the highest concentrations in the intermediate zone (Au up to 7.6 ppm and Ag up to 11 ppm). We suggest that gold was transported as a reduced sulphur complex and was precipitated from the hydrothermal solution by the reaction of the sulphur complexes with Fe2+ from the alteration of the mafic minerals of the host-rock. Fluid–wall-rock interactions seem to be the main cause of gold mineralization. Genetic relationships with a strike-slip fault system, hydrothermal alteration zones within the metamorphic wall-rocks, and an entire set of geochemical anomalies are consistent with orogenic-type gold deposits of the epizonal class.  相似文献   

17.
The Dongping gold deposit hosted in syenites is one of the largest hydrothermal gold deposits in China and composed of ore veins in the upper parts and altered zones in the lower parts of the ore bodies. Pervasive potassic alteration and silicification overprint the wall rocks of the ore deposit. The alteration minerals include orthoclase, microcline, perthite, quartz, sericite, epidote, calcite, hematite and pyrite, with the quartz, pyrite and hematite assemblages closely associated with gold mineralization. The phases of hydrothermal alteration include: (i) potassic alteration, (ii) potassic alteration - silicification, (iii) silicification - epidotization - hematitization, (iv) silicification - sericitization - pyritization and (v) carbonation. Mass-balance calculations in potassic altered and silicified rocks reveal the gain of K2O, Na2O, SiO2, HFSEs and transition elements (TEs) and the loss of REEs. Most major elements were affected by intense mineral reactions, and the REE patterns of the ore are consistent with those of the syenites. Gold, silver and tellurium show positive correlation and close association with silicification. Fluid inclusion homogenization temperatures in quartz veins range from 154 °C to 382 °C (peak at 275 °C–325 °C), with salinities of 4–9 wt.% NaCl equiv. At temperatures of 325 °C the fluid is estimated to have pH = 3.70–5.86, log fO2 = − 32.4 to − 28.1, with Au and Te transported as Au (HS)2− and Te22 − complexes. The ore forming fluids evolved from high pH and fO2 at moderate temperatures into moderate-low pH, low fO2 and low temperature conditions. The fineness of the precipitated native gold and the contents of the oxide minerals (e.g., magnetite and hematite) decreased, followed by precipitation of Au- and Ag-bearing tellurides. The hydrothermal system was derived from an alkaline magma and the deposit is defined as an alkaline rock-hosted hydrothermal gold deposit.  相似文献   

18.
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19.
《International Geology Review》2012,54(15):1852-1872
Medium-grade metabasites and metapelites from the Cajamarca Complex (Central Cordillera of Colombia) are in fault contact with the Jurassic Ibague batholith and show a penetrative foliation, locally mylonitic, suggesting intense dynamic–thermal metamorphism. The amphibolites are composed of calcic amphibole + epidote + plagioclase + quartz plus rutile + titanite + apatite + carbonate as accessory phases. Chlorite and albite appear as retrograde replacements. The metapelites are mainly composed of phengite + quartz + garnet + chlorite, plus epidote + albite + apatite + titanite + haematite as accessory phases. Bulk geochemistry of the amphibolites indicates basaltic protoliths with a mid-ocean ridge basalt (MORB) signature, although enrichment in the mobile large-ion lithophile elements compared to MORB suggests pre- and/or syn-metamorphic alteration by fluids. Peak pressure–temperature determinations for both types of rocks are similar, ranging 550–580°C and 8 kbar (approximately 26 km depth and an apparent geothermal gradient of 22°C/km). 40Ar-39Ar dating of amphibole from two amphibolite samples and one phengitic mica from a pelitic schist yielded plateau ages of 146.5 ± 1.1 Ma and 157.8 ± 0.6 Ma, and 157.5 ± 0.4 Ma, respectively. These Late Jurassic ages contrast with previously published (Permian)Triassic ages of metamorphism in the Cajamarca Complex. Taken together, our data indicate tectonic-driven burial of oceanic supracrustal sequences down to mid-crustal depths during Late Jurassic times and are best explained as the result of terrane collision-related metamorphism and deformation in a fore-arc/volcanic-arc environment of the active western margin of Gondwana rather than as a result of Jurassic thermal–metamorphic resetting of a (Permian)Triassic metamorphic sequence during intrusion of the Jurassic Ibague batholith. Our results represent the first report of Jurassic terrane collision tectonics involving supracrustal oceanic rocks in the northwestern margin of Gondwana in Colombia.  相似文献   

20.
The S.W. Nabitah Mobile Belt, Saudi Arabia, contains a Proterozoic island-arc complex. In the Qadda area, the metavolcanic-dominated supracrustal sequence records amphibolite facies regional metamorphism of high-T , low-P type. Calcsilicate rocks and aluminous dolomitic marbles within the supracrustal sequence have been studied in detail to refine estimates of peak metamorphic P–T conditions and assess the role of fluids during prograde and retrograde metamorphism. Fluid-independent thermobarometers (including the calcite–dolomite thermometer and P-sensitive equilibria involving grossular, wollastonite, anorthite, meionite, quartz and calcite) yield peak P–T conditions of c. 650–660 °C, 4 kbar, both higher than previous estimates, giving a revised average thermal gradient of c. 45 °C km–1. The close match between the peak temperatures implied by calcite–dolomite thermometry and those recorded by univariant devolatilization equilibria suggests that the calcareous rocks were fluid-bearing during late-prograde and peak metamorphic stages. These fluids were essentially binary H2O–CO2 mixtures with low NaCl and HF concentrations. Most were H2O-rich, with XCO2 between 0.02 and 0.2, but values of c. 0.6 are recorded by two samples. High modal abundances of the solid products of decarbonation reactions (e.g. c. 10–50% wollastonite) in many of the rocks that record low-XCO2 equilibrium fluids implies infiltration of significant quantities of externally derived aqueous fluid during late-prograde metamorphism, but not enough to exhaust the buffering capacity of the rocks. Calculated minimum time-integrated fluid-to-rock ratios of five wollastonite-bearing calcsilicate rocks range from 0.7±0.22 to 1.39±0.46 (1σ); those of six marbles range from c. 0 to 4±1.4. The latter variation occurs on a metre-scale, implying focusing of fluid flow. Diopside-rich rocks record fluid-to-rock ratios of up to 88±48. Penetrative wollastonite lineations indicate a temporal link between infiltration and distributed ductile deformation. Infiltrating fluids were probably derived both from the prograde dehydration of adjacent metabasalts and metatuffs and from crystallization of voluminous pretectonic granitoid intrusions. In general, fluid-to-rock ratios deduced for the metavolcanic-dominated Qadda area are similar to those recorded by rocks in the metasediment-dominated terrane of N. New England. The occurrence of post-tectonic retrograde hydration textures in both carbonate-bearing and carbonate-free rocks otherwise lacking hydrous minerals testifies to infiltration of aqueous fluids during retrograde metamorphism in the absence of penetrative deformation. Minimum fluid-to-rock ratios calculated for secondary grossular reaction rims in some calcsilicates are c. 0.04. Later patchy hydration of scapolite probably utilized static, pore-filling fluids remaining after the early retrograde infiltration.  相似文献   

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