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1.
Phyllosilicates in rocks which are transitional from mudstone to slate from Lehigh Gap, Pa., have been studied by a variety of techniques, including high resolution Transmission Electron Microscopy and Analytical Electron Microscopy. The principal minerals are white mica which is transitional from illite in mudstone to ordered twolayer mica in slate, and chlorite. 7Å berthierine occurs more rarely. Dioctahedral and trioctahedral layers are shown to be interleaved in individual crystals at all scales between the following two end members: (1) both random and regular 11 interlayering at the scale of individual layers, as shown, in part, by lattice fringe images. (2) packets of trioctahedral and dioctahedral layers up to a few thousand Ångstroms or microns in thickness, detectable with ordinary optical techniques. The complete range of intermediate structures is represented in samples which are in transition to slate. Bulk analytical (EMPA), X-ray diffraction or other measurements are shown to result in averages over both kinds of layers when TEM techniques are not used.Contribution No. 400 from the Mineralogical Laboratory, Department of Geological Sciences, The University of Michigan  相似文献   

2.
Many chloritic minerals in low-grade metamorphic or hydrothermally altered mafic rocks exhibit abnormal optical properties, expand slightly upon glycolation (expandable chlorite) and/or have excess AlVI relative to AlIV, as well as significant Ca, K and Na contents. Chloritic minerals with these properties fill vesicles and interstitial void space in low-grade metabasalt from northern Taiwan and have been studied with a combination of TEM/AEM, EMPA, XRD, and optical microscopy. The chloritic minerals include corrensite, which is an ordered 1:1 mixed-layer chlorite/smectite, and expandable chlorite, which is shown to be a mixed-layer chlorite/corrensite. Corrensite and some mixed-layer chlorite/corrensite occur as rims of vesicles and other cavities, while later-formed mixed-layer chlorite/corrensite occupies the vesicle cores. The TEM observations show that the mixed-layer chlorite/corrensite has ca. 20%, and the corrensite has ca. 50% expandable smectite-like layers, consistent with XRD observations and with their abnormal optical properties. The AEM analyses show that high Si and Ca contents, high AlVI/AlIV and low FeVI/(Fe+Mg)VI ratios of chlorites are correlated with interstratification of corrensite (or smectite-like) layers in chlorite. The AEM analyses obtained from 200–500 Å thick packets of nearly pure corrensite or chlorite layers always show that corrensite has low AlIV/SiIV and low FeVI/(Fe+Mg)VI, while chlorite has high AlIV/SiIV and high FeVI/(Fe+Mg)VI. This implies that the trioctahedral smectite-like component of corrensite has significantly lower AlIV/SiIV and FeVI/(Fe+Mg)VI. The ratios of FeVI/(Fe+Mg)VI and AlIV/SiIV thus decrease in the order chlorite, corrensite, smectite. The proportions of corrensite (or smectite-like) layers relative to chlorite layers in low-grade rocks are inferred to be controlled principally by Fe/Mg ratio in the fluid or the bulk rock and by temperature. Compositional variations of chlorites in low-grade rocks, which appear to correlate with temperature or metamorphic grade, more likely reflect variable proportions of mixed-layered components. The assemblages of trioctahedral phyllosilicates tend to occur as intergrown discrete phases, such as chlorite-corrensite, corrensite-smectite, or chlorite-corrensite-smectite. A model for the corrensite crystal structure suggests that corrensite should be treated as a unique phase rather than as a 1:1 ordered mixed-layer chlorite/smectite.  相似文献   

3.
Clay minerals from the three principal kinds of zeolitic sediments from the type area for zeolite facies alteration, the Triassic Murihiku Supergroup, Southland, New Zealand, have been studied by TEM. Bentonitic tuff consists largely of smectite and heulandite with minor illite; they occur as replacements of glass shards and are inferred to be direct alteration products of tuff alteration. Both analcime- and laumontite-rich tuffs contain chlorite, illite and mixed-layer illite-chlorite, including 11 mixed-layer sequences. Subhedral to euhedral phyllosilicate crystal shapes and other textural features imply that phyllosilicates crystallized from solution derived in part by dissolution of precursor smectite. Intralayer transitions involving illite and chlorite are inferred to be products of crystallization rather than direct alteration and replacement. Petrographically similar bentonitic and analcimized tuffs overlap each other in the stratigraphic section, supporting earlier observations that there is no systematic change in smectite relative to the illite plus chlorite derived from smectite in sections up to 8.5 km thick. The data imply that smectite may be metastable relative to illite plus chlorite. Permeability and fluid chemistry are inferred to be as significant as temperature in promoting reactions in clay minerals as well as zeolites during burial metamorphism.Contribution No. 436, from The Mineralogical Laboratory, Department of Geological Sciences, The University of Michigan, Ann Arbor, Michigan 48109  相似文献   

4.
Olivines which cool under oxidizing conditions exsolve iron oxides at high temperature, and at low temperatures break down to essentially chloritic materials. Olivines which cool under non-oxidizing conditions alter at intermediate temperatures to complex assemblages of chlorite and interstratified phyllosilicates containing a smectite. Alteration under oxidizing conditions at low temperature, probably below 140° C, produces iddingsite, an orientated assemblage of goethite and interstratified phyllosilicates also containing a smectite.Post-deuteric alteration extends or initiates the breakdown of olivine to phyllosilicate mixtures often resulting in widespread movement of materials through the flow. Post-deuteric alteration of iddingsite produces strongly pleochroic, highly ordered varieties which eventually break down to green phyllosilicate assemblages.Weathering of olivine may produce orientated assemblages similar to deuteric forms of iddingsite. Weathering of green alteration products results in oxidation and the liberation of discrete iron hydroxides.Alteration in all cases requires exchange of material between interstitial components and olivine. During deuteric alteration, plagioclase and pyroxene are usually unaffected.  相似文献   

5.
Phyllosilicates occurring as replacements of olivine, clinopyroxene and interstitial materials and as veins or fracture-fillings in hydrothermally altered basalts from DSDP Hole 504B, Leg 83 have been studied using transmission and analytical electron microscopy. The parageneses of phyllosilicates generally change systematically with depth and with the degree of alteration, which in turn is related to permeability of basalts. Saponite and some mixed-layer chlorite/smectite are the dominant phyllosilicates at the top of the transition zone. Chlorite, corrensite, and mixed-layer chlorite/corrensite occur mainly in the lower transition zone and upper levels of the sheeted dike zone. Chlorite, talc, and mixed-layer talc/chlorite are the major phyllosilicates in the sheeted dike zone, although replacement of talc or ohvine by saponite is observed. The phyllosilicates consist of parallel or subparallel discrete packets of coherent layers with packet thicknesses generally ranging from< 100 Å to a few hundred Å. The packets of saponite layers are much smaller or less well defined than those of chlorite, corrensite and talc, indicating poorer crystal-linity of saponite. by contrast, chlorite and talc from the lower transition zone and the sheeted dike zone occur in packets up to thousands of Å thick. The Si/(Si+Al) ratio of these trioctahedral phyllosilicates increases and Fe/(Fe+Mg) decreases in the order chlorite, corrensite, saponite, and talc. These relations reflect optimal solid solution consistent with minimum misfit of articulated octahedral and tetrahedral sheets. Variations in composition of hydrothermal fluids and precursor minerals, especially in Si/(Si+Al) and Fe/(Fe+Mg) ratios, are thus important factors in controlling the parageneses of phyllosilicates. The phyllosilicates are generally well crystallized discrete phases, rather than mixed-layered phases, where they have been affected by relatively high fluid/rock ratios as in high-permeability basalts, in veins, or areas adjacent to veins. Intense alteration in basalts with high permeability (indicating high fluid/rock ratios) is characterized by pervasive albitization and zeolitization. Minimal alteration in the basalts without significant albitization and zeolitization is characterized by the occurrence of saponite±mixed-layer chlorite/smectite in the low-temperature alteration zone, and mixed-layer chlorite/corrensite or mixed-layer talc/chlorite in the high-temperature alteration zone. Textural non-equilibrium for phyllosilicates is represented by mixed layering and poorly defined packets of partially incoherent layers. The approach to textural equilibrium was controlled largely by the availability of fluid or permeability.Contribution No. 488 from the Mineralogical Laboratory, Department of Geological Sciences, The University of Michigan  相似文献   

6.
Quartz-feldspar porphyry dikes in and around the White Devil ore deposit are weakly to strongly altered, with weakly altered cores grading outward toward intensely chloritized marginal zones in contact with massive ironstone or chlorite altered sediments. Petrographic studies indicate the following sequence of alteration: sericitization of the groundmass, sericitization and chloritization of feldspar phenocrysts, chloritization of the groundmass, and alteration of igneous biotite to hydrothermal biotite and then to chlorite, intense chloritization of the groundmass as to remove quartz, and, finally, destruction of quartz phenocrysts. Isocon analyses of whole rock geochemical data from altered porphyry indicate the following relative changes during alteration: (1) consistent, near total losses of Na and Pb, (2) increasing gains of Mg, Fe, Mn and Zn, and increasing losses of Si and Sr with increasing alteration intensity, (3) gains of Ti, Cr and U, and losses of K and Rb upon alteration of feldspar phenocrysts, and (4) losses of Zr, Nb, Y and Th upon the loss of quartz in the groundmass. Of the elements studied only Ca, Al and P did not undergo significant relative changes. Immobile elements such as Ti, Zr, Nb, Y and Cr are highly mobile during the most intense alteration of the White Devil porphyry. Based on evidence from field relationships, alteration studies and petrographic observations, the quartz-feldspar porphyry dikes intruded after the formation of ironstones, but prior to Au-Cu-Bi mineralization. This conclusion is consistent with previous interpretations by Nguyen et al. (1989) and Edwards et al. (1990), but inconsistent with the interpretation by McPhie (1993) that quartz-feldspar porphyry sills at the Peko smelter site intruded into wet sediments. Two or more periods of quartz-feldspar porphyry intrusion occurred in the Tennant Creek district.  相似文献   

7.
Chlorite and berthierine occur through alteration of cordierite within enclaves of metamorphic rocks transformed by the Sierra Albarrana pegmatites. The coexistence of both phyllosilicates allows us to study their stability relationships and to compare their chemical compositions. Samples showing incipient replacement of cordierite by small cryptocrystalline aggregates can be identified by X-ray diffraction (XRD) as berthierine with small quantities of chlorite. Electron Microprobe (EMP) analyses give mixed compositions of berthierine and cordierite. Samples with extensive replacement of cordierite by aggregates show similar characteristics to those with incipient replacement, but some small crystals are present. The last type of sample shows complete replacement of cordierite by crystals showing optical properties of chlorite and EMPA compositions coherent with chlorite or berthierine. Their XRD pattern corresponds to chlorite and their high resolution transmission electron microscopy (HRTEM) images only show perfect sequences of 14 Å lattice fringes. The cryptocrystalline aggregates of the samples with incipient and extensive replacement present coexistent areas of 14 Å and 7 Å lattice fringes that are intergrown at different levels: (1) large areas (> 1 m) of 7 Å layers; (2) packets of 7 Å layers between 14 Å layer areas, with visible 7 Å to 14 Å lateral changes; (3) random mixed-layers 7 Å/14 Å. Chlorite is the final stable product of alteration of cordierite, with berthierine as an intermediate metastable phase. Energy dispersive X-ray spectrometry microanalyses of 14 Å, 7 Å and (14+7) Å areas show lack of systematic differences in chemical compositions between both phyllosilicates which may be considered as true polymorphs.  相似文献   

8.
Smectite, illite, celadonite and chlorite are the major products of alteration of rhyolites and andesites, in the upper part of the Los Azufres geothermal system. Changes in mineral assemblages and composition of phases are observed as a function of depth and host rock lithology. Two different sequences characterize the rhyolites and the andesites from the surface to a depth of about 1500 m: kaolinitesmectite (±interlayered illite/smectite)illitemuscovite (rhyolites), and kaolinitesmectite (±interlayered illite/smectite)illite+celadoniteillite+chloritechlorite (andesites).Illite, and chlorite at depth, are largely dominant. Similar substitutions and correlations among chemical constituents characterize illites from rhyolites or andesites, but their compositions in the two host rock lithologies exhibit slight but significant differences, especially in their Fe and Mg contents which are the highest in illites from andesites. Illite exhibits progressive changes in composition with depth: a strong increase in the K content in the interlayer, together with an increase of the Fe content in the octahedral site. These changes correspond to a slight increase in the molar fraction of Fe-(Mg) celadonite end-members, and mostly to a dramatic decrease of pyrophyllite with increasing temperature.Temperature of the mineralogical and compositional changes was estimated from fluid inclusions studies, combined with other geothermometric approaches (chemical geothermometers and direct measurements). Variation of X-pyrophyllite with temperature is proposed as a geothermometer for different host rock lithologies. Transitions between the stability fields of illite±interstratified illite-smectite and illite+chlorite is around 200±30° C, and between illite+chlorite and chlorite around 290±20° C.  相似文献   

9.
Transmission and scanning electron microscopy were utilized to investigate the nature and mechanisms of alteration of abundant detrital biotite of volcanic origin and progressive modification of phyllosilicate aggregates in a prograde sequence of pelitic rocks (illite crystallinity index = 0.19–0.58λ2θ) from the Gaspé Peninsula in Quebec.
Detrital biotite has been diagenetically altered to form corrensite and chlorite through two mechanisms; (1) layer-by-layer replacement gave rise to interstratification of packets of layers and complex mixed layering via several kinds of layer transitions between biotite and chlorite, corrensite or smectite; (2) dissolution-transport-precipitation resulted in the formation of relatively coarse-grained aggregates of randomly orientated, corrensite-rich flakes and fine-grained corrensite intergrown with chlorite and illite in the matrix.
The data show that stacks consisting of alternating packets of trioctahedral and dioctahedral phyllosilicates originated during early diagenesis when lenticular fissures in strained altering biotite were filled by dioctahedral clays. Subsequent prograde evolution of dioctahedral clays occurred through deformation, dissolution and crystallization, and overgrowth. Illite evolved to muscovite, with K in part provided through biotite alteration, and corrensite/chlorite to homogeneous chlorite. The alteration of detrital biotite is closely related to the formation of titanite and magnetite in diagenetic rocks, and pyrite, calcite and anatase or rutile in the higher grade rocks.
The observations demonstrate that detrital biotite of volcanic origin may be the principal precursor of chlorite in chlorite-rich metapelites originating in marginal basins. The mineral parageneses suggest that the transitions from corrensite to chlorite and illite to muscovite may be a function of local chemistry and time.  相似文献   

10.
Résumé L'étude minéragraphique et autoradiographique du charbon du Schaentzel montre le caractère surimposé de la minéralisation d'uranium, son mode d'introduction et de fixation. On a observé une très faible activité du charbon dépourvu d'inclusions ou de fissures, ainsi qu'une relation entre l'augmentation locale de la réflectivité et la quantité d'uranium.
Mineragraphic and autoradiographic study of the Schaentzel coal shows the superposed character of the uranium mineralization and its mode of introduction and fixation. One observes a very low activity of coal, devoid of inclusions or fractures, and a relationship between the local increase of reflectivity and quantity of uranium.
Zusammenfassung Eine erzmikroskopische und Kernemulsionsplatte Untersuchung der Schaentzel Kohle zeigt den sekundären Charakter der Uranvererzung, die Art ihrer Zufuhr und Ablagerung. Es konnte eine sehr schwache Aktivität der Einschluß- bzw. spaltfreien Kohle, sowie eine Beziehung zwischen den örtlichen Ansteigen des Reflexionsvermögen und der Uranmenge beobachtet werden.
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11.
Zusammenfassung Großräumige geologische Kartierungen in den drei Nordprovinzen Chiles ergaben, daß die Kordilleren von weitgespannten Schuppenstrukturen beherrscht werden. Diese bestehen aus Grundgebirgs- und mesozoisch-känozoischen Deckgebirgsschollen, die durch N-S streichende und 40–60° nach Osten einfallende Überschiebungen bedingt sind. Die Überschiebungen verlaufen weitgehend parallel zu einer berechneten Fläche, auf der sich die Erdbebenhypozentren befinden.An den Rändern des Längstalgrabens finden sich örtlich neben normalen Störungen auch Überschiebungen. Kompressionstektonik herrscht gegenüber Dehnungstektonik vor.Die stratigraphische Position der Salzkordillere bei San Pedro de Atacama und eine Erklärung für die Entstehung der vulkanischen Eisenlagerstätte El Laco werden kurz skizziert.
Regional mapping in northern Chile revealed large scale imbricate structures. The thrust sheets, derived either from the basement or from the postpaleozoic cover, have been moved along N striking, 40–60° E dipping thrust planes, which parallel the mathematically established plane comprising the foci of the earthquakes.At the rims of longitudinal valleys, in addition to normal faults overthrusts occur locally. Compressional tectonic is dominant with respect to tensional tectonic.The stratigraphic position of the Salt Ranges (Cordillera de la Sal) near San Pedro de Atacama and the genesis of the volcanic iron deposits of El Laco are briefly discussed.
Resumen Estudios geológicos regionales en las tres provincias más septentrionales de Chile demuestran que en las cordilleras predomina una amplia estructura de escamas. Estas están constituidas por bloques de rocas antiquas del basamento paleozoico y de formaciones cobertizas mesozoico-cenozoicas que están controladas por fallas inversas y sobreescurrimientos de rumbo N-S y manteo de 40°–60° al este. Estos sobreescurrimientos son sensiblemente paralelos a la superficie en que se situan la mayor parte de los hipocentros sismicos.En los bordes del valle longitudinal o Pampa se encuentran frecuentemente fallas inversas junto a otras de tipo normal, indicando un predominio de procesos de compresión, sobre los de dilatación.Brevemente se discuta la posición estratigráfica de la Cordillera de la Sal, en el Salar de Atacama, y una explicación para la génesis del yacimiento volcánico de hierro del Laco.
Résumé Des travaux géologiques récents ont démontré que le trait structural le plus important dans le nord du Chili est une alternance de blocs anciens et de formations de couverture méso-cénozoïques. Cette structure imbriquée est contrôlée par des failles inverses, parallèles au plan où la plus grande partie des tremblements de terre ont leur origine.Des failles inverses de faible pendage et même des nappes de charriage ne sont pas rares dans les formations sédimentaires jurassiques. La tectonique de compression prédomine sur la tectonique de tension.La position stratigraphique de la Cordillère de Sel près de San Pedro de Atacama et une explication pour la formation du gisement de fer volcanique de El Laco sont brièvement discutées.
, , , . - , , N-S 40–60° . , . — . . San Pedro de Atacama El Laco.
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12.
Zusammenfassung Der Chagnon-Orford-Intrusiv-Komplex ist durch einen zweifachen Zonarbau gekennzeichnet: einmal ein ausgedehnter Zonarbau mit Ultrabasiten in den tieferen Lagen und einer Folge saurerer Differentiationsprodukte in den dachnahen Gebieten des Lakkolithen; zum anderen ein regelmäßiger Wechselrhythmus von Peridotit- und Pyroxenitstreifen in den unteren Partien des Intrusivs. Der Autor ist der Meinung, daß die deutlich in Erscheinung tretende zonale Anordnung der Gesteine im Chagnon-Orford-Lakkolith auf eine gravitative Differentiation in situ zurückzuführen ist.
The Chagnon-Orford Intrusive Complex is characterized by two types of banding: first, a large-scale zoning consisting of ultrabasic rocks at the bottom overlain by belts of successively more acid differentiates at the roof of the laccolith; secondly, a rhythmic banding near the floor of the intrusive, consisting of alternating peridotite and pyroxenite layers. The writer is of the opinion that the zonal arrangement of the Chagnon-Orford laccolith is the result of differentiation in situ under the influence of gravity.
Résumé Le complexe intrusif de Chagon-Orford se caractérise par une structure zonaire double: une structure zonaire avec ultrabasites dans les parties profondes et une série de produits de différenciation plus acides dans la partie du laccolite proche du toit; d'autre part, un ensemble à disposition rythmique régulière formé de lits de péridotite et de pyroxénite se trouve dans la partie inférieure de l'intrusion. L'auteur est d'avis que la disposition zonaire des roches dans le laccolite de Chagnon-Orford est à rapporter à une différenciation in situ par gravité.
Chagnon-Orford - . , .
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13.
The tectonically deepest part of the eastern Betic Cordilleras consists of rocks showing medium grade metamorphism of alpine age. In this zone several individual tectonic units are distinguished, each with a basis of polymetamorphic pre-Silurian schists, covered by a sequence of younger metamorphites considered to be partly of Triassic age. The crystalline schists of the Sierra Nevada, together with their cover of younger schists — which represent the deepest part of the mixed zone of previous authors — form a single tectonic unit. It seems appropriate to combine the crystalline schists of the Sierra Nevada and this former mixed zone to a complex of tectonic units, which are characterized by a medium grade metamorphism of alpine age and for which the name Nevado-Filabride units or Nevado-Filabrides is proposed.The Nevado-Filabrides are tectonically overlain by the Alpujarrides, generally characterized by low grade alpine metamorphism, and these in their turn by the Betic of Málaga — merely present as small dispersed remnants — consisting of rocks that are almost devoid of alpine metamorphism.Important movements, that have taken place after the major thrust movements leading to the formation of the nappe structures, have caused horizontal displacements of considerable magnitude, sometimes resulting in changes of the original tectonic succession.
Zusammenfassung Der tektonisch tiefste Teil der östlichen betischen Kordilleren besteht aus Gesteinen, die eine mittlere Metamorphose alpidischen Alters zeigen. In dieser Zone kann man mehrere selbständige tektonische Einheiten unterscheiden. Bei jeder von ihnen besteht die Basis aus polymetamorphen präsilurischen Schiefern, die überlagert werden von einer Folge jüngerer metamorpher Gesteine, bei denen z. T. triassisches Alter angenommen wird. Die kristallinen Schiefer der Sierra Nevada und die darüber liegenden jüngeren Schiefer (die den tiefsten Teil der Mischungszone älterer Autoren bilden) sind eine telefonische Einheit. Diese kristallinen Schiefer der Sierra Nevada und die früher verwendete Mischungszone faßt man am besten zu einem Komplex tektonischer Einheiten zusammen, die gekennzeichnet sind durch eine mittlere Metamorphose alpidischen Alters. Für sie wird der Name Nevado-Filabride Einheiten oder Nevado-Filabriden vorgeschlagen.Die Nevado-Filabriden werden tektonisch überlagert von den Alpujarriden, die durch einen geringen alpinen Metamorphismus gekennzeichnet werden. Auf diesen liegt das Betikum von Malaga, das vorwiegend in kleinen verstreuten Resten vorliegt und aus Gesteinen besteht, denen eine alpidische Metamorphose fast ganz fehlt.Nach den großen Überschiebungen, die die Deckenstrukturen schufen, haben bedeutende Bewegungen zu Horizontalverschiebungen beträchtlichen Ausmaßes geführt. Bisweilen bewirkten sie eine Änderung der ursprünglichen tektonischen Abfolge.
Résumé La partie tectoniquement la plus profonde des cordillères bétiques orientales est formée de roches montrant un métamorphisme d'âge alpin de degré moyennement élevé. Dans pette zone on distingue plusieurs unités tectoniques individuelles, chacune avec une partie inférieure constituée de schistes polymétamorphiques pré-siluriens, recouverte par une succession de roches métamorphiques plus récentes considérées partiellement d'âge triasique. Les « schistes cristallins de la Sierra Nevada », avec leur couverture de schistes plus récents — qui représentent la partie la plus profonde de la « Mischungszone » des anciens auteursforment une seule unité tectonique. Il semble convenable de considérer les « schistes crystallins de la Sierra Nevada » et cette ancienne « Mischungszone » comme un seul complexe d'unités tectoniques qui sont caractérisées par un métamorphisme de degré moyen, d'âge alpin, et pour lesquelles l'auteur propose le nom d'unités Nevado-Filabrides ou, simplement, Nevado-Filabrides.Les Nevado-Filabrides sont tectoniquement surmontées par les Alpujarrides, généralement caractérisées par un degré de métamorphisme alpin peu élevé, et celles-ci sont à leur tour recouvertes par le Bétique de Málaga, dont n'existent —dans la région en question — que des témoins dispersés, constitués de roches presque dépourvues de métamorphisme alpin.Des mouvements importants, postérieurs aux grands charriages conduisant à la formation de la structure en nappes, ont causé des déplacements horizontaux de grand ampleur, causant parfois des changements dans la succession tectonique originelle.
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14.
Eclogites from the Roberts Victor mine, Kaapvaal craton are classic examples of subducted Achaean oceanic crust brought up as xenoliths by kimberlite. New in situ trace element and oxygen isotope data (18O=3.09–6.99 SMOW) presented here reemphasise their origin from seawater-altered plagioclase-rich precursors. Their Hf–Nd isotopic compositions are not in agreement with compositions predicted by geochemical modelling of the isotopic composition of aged subducted oceanic crust. Instead, Hf isotopic compositions are very heterogeneous, varying between 0.281625 and 0.355077 (–37.8 and +2561 Hf) at the time of kimberlite emplacement (128 Ma) in keeping with equally variable Nd isotopic compositions (0.511124–0.545092; –26.3 to +636 Nd). However, most samples plot on the terrestrial array. The isotopic compositions of some samples are too extreme to play a major role in mixed peridotite-eclogite melting in basalt source regions, whereas the isotopic composition of other samples is reconcilable with a contribution of up to ca. 15% of eclogite partial melt to the MORB source. Most importantly, our results show that ancient subducted oceanic crust is not isotopically homogeneous and should not be treated as a component or reservoir during geochemical modelling. The heterogeneity reflects radiogenic in-growth starting from small compositional heterogeneities in gabbroic protoliths, followed by modification during sea-floor alteration, subduction and emplacement into the subcratonic lithosphere.  相似文献   

15.
Olivine crystals in basaltic andesites which crop out in the Abert Rim, south-central Oregon have been studied by high-resolution and analytical transmission electron microscopy. The observations reveal three distinct assemblages of alteration products that seem to correspond to three episodes of olivine oxidation. The olivine crystals contain rare, dense arrays of coherently intergrown Ti-free magnetite and inclusions of a phase inferred to be amorphous silica. We interpret this first assemblage to be the product of an early subsolidus oxidation event in the lava. The second olivine alteration assemblage contains complex ordered intergrowths on (001) of forsterite-rich olivine and laihunite (distorted olivine structure with Fe3+ charge balanced by vacancies). Based on experimental results for laihunite synthesis (Kondoh et al. 1985), these intergrowths probably formed by olivine oxidation between 400 and 800°C. The third episode of alteration involves the destruction of olivine by low-temperature hydrothermal alteration and weathering. Elongate etch-pits and channels in the margins of fresh olivine crystals contain semi-oriented bands of smectite. Olivine weathers to smectite and hematite, and subsequently to arrays of oriented hematite crystals. The textures resemble those reported by Eggleton (1984) and Smith et al. (1987). We find no evidence for a metastable phase intermediate between olivine and smectite (M — Eggleton 1984). The presence of laihunite exerts a strong control on the geometry of olivine weathering. Single laihunite layers and laihunite-forsteritic olivine intergrowths increase the resistance of crystals to weathering. Preferential development of channels between laihunite layers occurs where growth of laihunite produced compositional variations in olivine, rather than where coherency-strain is associated with laihunite-olivine interfaces.  相似文献   

16.
Tectonic activity in West Africa and the Gulf of Guinea during the last 90 m. y. can be closely related to the palaeocontinental position of Africa. Prior to 90 m. y., during the break up of Gondwanaland and the spreading of the West African rifts, the palaeocontinental position of Africa hardly changed at all. During the last 90 m. y. Africa has moved steadily northwards and rotated slightly in an anticlockwise direction. From 90 m. y. to 40 m. y. tectonic activity in West Africa and the Gulf of Guinea was compressional and from 40 m. y. to present day tectonic activity has been extensional. The change, in West Africa, from peripheral compression of the continental part of the African plate to peripheral extension occurred at approximately the same time as the effective mechanical centre of Africa (localted near Jebel Marra) crossed the equator.Membrane stresses are generated by rigid plates moving on a non-spherical earth. When a plate moves towards the equator it is subjected to peripheral compression and when it moves away it is subjected to peripheral extension. Thus the concept of membrane tectonics provides a possible explanation for the tectonic activity observed in West Africa and the Gulf of Guinea during the last 90 m. y.
Zusammenfassung Die tektonischen Ereignisse in Westafrika und dem Golf von Guinea können währendder letzten 90 Millionen Jahre mit der paläokontinentalen Position von Afrika in Zusammenhang gebracht werden. Vor diesen 90 Millionen Jahren, während des Zerreißens von Gondwanaland und der Dehnung des westafrikanischen Grabenbruchs, veränderte sich die paläokontinentale Position von Afrika kaum. Während der vergangenen 90 Millionen Jahre hat sich Afrika stetig nach Norden bewegt und drehte sich leicht entgegen dem Uhrzeigersinn. Zwischen 90 Millionen Jahren und 40 Millionen Jahren wurde Westafrika und der Golf von Guinea tektonisch eingeengt und von 40 Millionen Jahren bis heute herrscht Dehnung. In Westafrika fand der Wechsel von peripherer Pressung des kontinentalen Teiles der Afrikanischen Platte zu peripherer Dehnung etwa zur selben Zeit statt als der mechanische Mittelpunkt von Afrika (in der Nähe von Jebel Marra) den Äuator überquerte.Membrandruck (Turcotte, 1974) wird durch die Bewegung von festen Platten auf einer nicht ganz sphärischen Erde ausgelöst. Wenn sich eine Platte auf den Äquator zubewegt, wird ein peripherer Druck auf sie ausgeübt, und wenn sie sich vom Äquator wegbewegt, wird sie von einer peripheren Dehnung betroffen. Das Konzept der membrane tectonics (Turcotte, 1974) bietet daher eine mögliche Erklärung für die tektonischen Erscheinungen in Westafrika und dem Golf von Guinea während der vergangenen 90 Millionen Jahre.
Résumé Les événements tectoniques en Afrique occidentale et dans le Golfe de Guinée au cours de ces 90 derniers m. a. peuvent être mis en relation étroite avec la position paléocontinentale de l'Afrique. Avant cette période, pendant la fragmentation du Gondwana et pendant l'ouverture du fossé africain occidental, la position de l'Afrique n'a guère changé. Pendant les derniers 90 m. a., l'Afrique s'est continuellement avancée vers le nord avec une légère rotation sinistrogyre. Entre 90 m. a. et 40 m. a., un état de compression tectonique a existé en Afrique occidentale et dans le Golfe de Guinée, et, depuis ce moment jusqu'à présent, règne un état de distension. Le changement, dans la partie continentale de la plaque africaine, d'une compression périphérique en une distension périphérique s'est produit sensiblement au moment du passage à l'équateur du centre mécanique effectif de l'Afrique (lequel se trouve à proximité du Jebel Marra).Des contraintes de membrane (Turcotte, 1974) se produisent par suite du mouvement de plaques rigides sur une Terre qui n'est pas exactement sphérique. Lorsqu'une plaque se rapproche de l'équateur, elle subit une compression périphérique, et, lorsqu'elle s'en éloigne, une distension périphérique. Donc le concept de «membrane tectonics» (Turcotte, 1974) fournit une explication plausible de l'activité tectonique en Afrique occidentale et dans le Golfe de Guinée au cours de ces 90 derniers m. a.
90 . , - , , . 90 , . 90 40 , 40 . , , Jebel Marra . — (Turcotte, 1974). , ; — . « » (Turcotte, 1974) , 90 .
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17.
Mineral chemistry and crystal growth-deformation relationships in metapelites, orthogneises and metabasic rocks from the Muxia-Finisterre region show that this area has been affected by plurifacial regional metamorphism during the Hercynian Orogenesis. Paragenetic evolution seems to be related to a change of the metamorphic gradient towards relatively lower Ps conditions in the mesozone, while this character is less evident in catazonal rocks. In both cases there was a continuous increase in T and decrease in {ie657-02}.The metamorphic climax was reached during the second metamorphic episode (M2). This event took place during and even after the second deformation phase (P2). The latter gave rise to the main foliation observed in studied rocks (S2) which almost practically erased signs of previous schistosity. Relationships between metamorphic evolution and different geotectonic models are discussed.
Zusammenfassung Mineralchemismus und die Beziehungen Kristallwachstum-Deformation in Metapeliten, Orthogneisen und metabasischen Gesteinen aus der Muxia-Finisterra-Region, zeigen eine Beeinflussung dieses Gebietes durch eine plurifazielle Regionalmetamorphose während der herzynischen Orogenese.Die paragenetische Entwicklung scheint mit einer Veränderung des metamorphen Gradienten in Richtung niedrigerer Ps-Bedingungen in der Mesozone einherzugehen, während dies in katazonalen Gesteinen weniger deutlich ist.In beiden Fällen gab es eine kontinuierliche Zunahme der Temperatur (T) bzw. Abnahme des {ie657-01}.Der Höhepunkt der Metamorphose wurde während der zweiten metamorphen Episode (M2) erreicht. Dieses Ereignis fand statt während und sogar nach der zweiten Deformationsphase (P2). Letzteres verursachte die Hauptschieferung (S2) in den untersuchten Gesteinen, die die Merkmale einer älteren Schieferung nahezu ausgelöscht hat.Beziehungen zwischen metamorpher Entwicklung und verschiedener geotektonischer Modelle werden diskutiert.
Résumé Les compositions chimiques des minéraux ainsi que leur relation croissance-déformation dans les métapélites, ortho-gneiss et métabasites de la région Muxia-Finisterre, suggèrent que cette secteur a subi un métamorphisme régional plurifacial lors de l'Orogenèse Hercynienne. L'évolution des paragenèses semble être liée à un changement du gradient métamorphique vers des conditions de Ps relativement plus basses dans la mésozone, ceci étant moins évident dans les roches catazonales. Dans les deux cas il y a eu une augmentation continue de la T et une diminution de la {ie657-03}. Le paroxisme du métamorphisme a été atteint lors du deuxième épisode métamorphique (M2). Cet événement a lieu généralement pendant ou légèrement après la deuxième phase de déformation (P2). Celle-ci donne la foliation principale de la roche (S2), laquelle a presque entièrement effacé les marques d'une schistosité pré-existante. Des relations entre l'évolution métamorphique et différents modèles géotectoniques sont discutées.
, Muxia-Finisterre , . , , , P , , . (), {ie658-01}. (2) . (2). (S2) , . .
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18.
The gravity survey of the Steinheim impact crater comprises about 500 gravity stations resulting in aBouguer anomaly map of the crater and its surroundings. From this map aBouguer residual anomaly of the impact structure was deduced which shows considerable character. A central negative anomaly with an amplitude of about -2 mgal and a halfwidth of 3 km is surrounded by ring-like relative positive and negative anomalies which extend to a radial distance of about 5–6 km. The interpretation is based on nine radial profiles with close station spacing. Model calculations were performed suggesting the Steinheim crater to be much larger and of different formation than has been assumed. Based on the gravity interpretation, on a morphological analysis, and on additional geological and geophysical observations a model of the Steinheim crater and its development is proposed. The main characteristics are a 500–600 m deep primary excavation and a final, apparent, diameter of roughly 7 km, contrasting to an up to now favoured shallow excavation and a 3.5–4 km final diameter. The model considerations include mass and energy calculations and references to the Ries impact crater.
Zusammenfassung Im Gebiet der Impakt-Struktur Steinheimer Becken wurden in Ergänzung zu früheren Untersuchungen neue Schweremessungen durchgeführt. Mit den nunmehr etwa 500 vorliegenden, nachBouguer reduzierten Schwerewerten wurde eine Karte derBouguer-Anomalien konstruiert, aus der nach Abzug eines Regionalfeldes eine Restfeld-Anomalie für den Impakt-Krater gewonnen wurde. Sie ist grob rotationssymmetrisch und zeigt außerhalb eines zentralen Schwereminimums von –2 mgal ringförmig angeordnete, relative positive und negative Schwereanomalien. Die Interpretation stützt sich auf neun radiale Profile erhöhter Stationsdichte, von denen vier für Modellrechnungen ausgewählt wurden. Auf Grund der berechneten Dichtemodelle, einer ergänzenden morphologischen Analyse der Kraterstruktur sowie zusätzlicher geologischer und geophysikalischer Befunde wird ein Modell für den Aufbau und die Entstehung des Steinheimer Beckens vorgeschlagen. Danach ist das heutige Becken mit einem Durchmesser von rund 3,5 km der Ausdruck einer primären Kraterstruktur, die in einer Exkavationsphase entstand und eine Tiefe von 500–600 m besaß. Ausgleichsbewegungen führten zu einer Massenkonvergenz und Anhebung in der Kratermitte und einer Absenkung außerhalb des primären Kraters, die die endgültige Struktur auf grob 7 km Durchmesser vergrößerte. Die Modell-Betrachtungen schließen Massen- und Energieabschätzungen sowie Vergleiche zum Ries-Krater ein.
Résumé La recherche gravimétrique dans le cratère d'impact de Steinheim et ses environs (Allemagne du Sud) comprend environ 500 stations de mesure qui ont été utilisées pour construire une carte des anomalies deBouguer. Un champ régional a été tracé pour obtenir l'anomalie résiduelle du cratère. On observe une anomalie négative (–2 mgal) au centre de la structure cernée d'anomalies positives et négatives relatives de faible amplitude, jusqu'à une distance radiale de 5–6 km. Pour l'interprétation neuf profils radiaux, où les stations sont à faible distance, ont été utilisés. Les modèles calculés pour quatre profils radiaux suggèrent que la structure de Steinheim est plus grande qu'on ne l'a supposé jusqu'à présent. En partant de l'interprétation des mesures gravimétriques, d'une analyse topographique du cratère et d'observations géologiques et géophysiques complémentaires un modèle de la structure Steinheim et de son développement est proposé. On en conclut que le bassin actuel avec un diamètre de 3,5 km est l'expression d'une structureprimaire du cratère qui s'est formée au cours d'une phase d'excavation et possédait une profondeur de 500–600 mètres. Des mouvements d'égalisation conduisirent à une convergence de masses avec soulèvement dans le centre du cratère et un affaissement à l'extérieur du cratère primaire, lequel s'accrut jusqu'à la structure finale de quelque 7 km. Le modèle inclut le calcul des masses déplacées et des énergies d'impact ainsi qu'une comparaison avec le cratère d'impact du Ries.
, . 500 , , , , . – 2 , . 9- , 4 . . 3,5 , 500 – 600 . , , , 7 . , .
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19.
The Postsvecokarelian development of the Baltic Shield shows a parallel development with tension and dolerite intrusions in the core zone and granite intrusions, compression and crustal shortening in the south-western margin. A crustforming event with calk-alkalic granitoid intrusions which with time moves westwards is followed by remelting and intrusion of alkali-intermediate granites and metamorphism. The south-western margin of the Shield probably was a stable ocean/continent border zone for a very long time. In spite of several attempts, no conclusive testable model for the development can be put forward today.
Zusammenfassung Die postsvekokarelische Entwicklung des Baltischen Schildes ist von einer zeitgemäßen Parallelität mit Tension und Diabasintrusionen in der östlichen Kernzone und Granitintrusionen, Kompression und Krustenverkürzung in der südwestlichen Marginalzone gekennzeichnet. Eine Phase mit Krustenbildung, die mit der Zeit nach Westen rückt, und wo kalkalkalische Granitoide als wesentlichstes neugebildetes Gestein auftreten, wird von Metamorphose und erneutem Aufschmelzen und Intrusionen alkaliintermediärer Granite gefolgt. Die südwestliche Marginalzone des Schildes war ein stabiler Ozean/Kontinent-Grenzbereich während einer langen Zeitperiode. Ein testbares endgültiges Modell der Entwicklung kann heute trotz mehrerer Versuche nicht aufgestellt werden.
Résumé Le développement postsvécokarélien du bouclier baltique est caractérisé par un parallélisme dans le temps entre l'extension et l'intrusion de diabases dans la zone centrale de l'Est et par des intrusions granitiques, une compression et un rétrécissement crustal dans la zone marginale du Sud-ouest. Une phase avec formation d'une croûte, qui se propage vers l'ouest, et au cours de laquelle les nouvelles roches formées sont essentiellement des granitoïdes calco-alcalins, est suivie d'un métamorphisme et d'une palingenèse avec intrusions de granites alcalins intermédiaires. La zone marginale du Sud-ouest du bouclier était un domaine-limite océan-continent »stable«, pendant une longue période de temps. Une modélisation controlable du développement ne peut être avancée aujourd'hui malgré plusieurs tentatives.
- , . , , - , . - /. .
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20.
A major reverse fault with a separation of at least a few thousand meters is exposed in the western Cordillera of Ecuador near 2°S.Ree and other incompatible elements patterns show (i) that the rocks exposed in the upthrust block to the east of the fault areMorb that had not yet been identified and (ii) that a volcanic island-arc assemblage extensively outcrops in the downthrust block west of the fault.The fault therefore bounds a steeply east-dipping thrustsheet comprising the arc and its basement. Thrustsheets of the same type are known farther north in Ecuador. They were stacked in a presently inactive subduction-zone during the early Tertiary when the island-arc, drifting from the west, finally collided with continental south America.The large dextral-slip Guayaquil-Dolores fault system, traditionally but possibly erroneously thought to be the suture-zone between continental south America and the oceanic allochthone blocks collided during the Cretaceous and Tertiary, subsequently disrupted most of that structural arrangement.
Zusammenfassung Die Gesteine einer bei 2° Südlicher Breite in der Westkordillere Ecuadors zu Tage tretenden und um mehrere tausend Meter versetzten Verwerfung wurden in geochemischer Hinsicht untersucht. Die Verteilung der seltenen Erden und der anderen inkompatiblen Elemente in den Proben zeigte östlich dieser Verwerfung das Vorkommen von Tholeiiten desMorb-Typs auf, deren Auftreten hier bis jetzt unbekannt war. Außerdem konnten die westlich der Verwerfung auftretenden Diabase, Andesite und Rhyolite dem Typ eines Inselbogens zugeordnet werden.Diese Verwerfung begrenzt infolgedessen eine stark nach Osten einfallende Schuppe des Sockels. Andere Schuppen dieser Art treten weiter im Norden Ecuadors auf, wo sie zu Beginn des Tertiärs während des Zusammentreffens des von Westen ankommenden, aus der Kreidezeit stammenden Inselbogens mit dem südamerikanischen Kontinent in eine Paläosubduktionszone eingebettet worden sind.Dieses Strukturgefüge ist anschließend zum größten Teil durch das System der rechtsseitigen Verwerfungen von Guayaquil — Dolores verdeckt worden. Dieses System wird für gewöhnlich — aber wahrscheinlich zu Unrecht — für die Nahtstelle des kontinentalen Südamerikas und der während der Kreidezeit und des Tertiärs gegen den Kontinent sto– Benden und/oder obduzierten allochtonen Blöcke ozeanischen Substrats gehalten.
Résumé Une faille inverse exposée dans la cordillère occidentale de l'Equateur vers 2°S a un rejet de plusieurs milliers de mètres. L'étude géochimique des terres rares et autres éléments incompatibles permet de reconnaître à l'est de la faille des tholéiites de ride médio-océanique jusqu'alors non identifiées, alors que les diabases, andésites et rhyolites présentes à l'ouest de la faille appartiennent à une formation d'arc insulaire.Cette faille délimite donc une écaille de socle à fort pendage vers l'est. D'autres écailles de ce type sont connues plus au nord en Equateur. Elles se sont imbriquées au début du Tertiaire dans une paléozone de subduction, lors de la collision de l'arc insulaire, venu de l'ouest, avec le continent sud-américain.Ce dispositif structural a été ensuite oblitéré en majeure partie par le systême faillé dextre de Guayaquil-Dolores, qui passe classiquement, mais probablement à tort, pour être la suture entre l'Amérique du sud continentale et les blocs allochtones à substratum océanique collés au continent et/ou obductés durant le Crétacé et le Tertiaire.
, 2° . . . , . , , , , , , . . , , , - . -. — , , — - , / .
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