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1.
The primary productivity of terrestrial ecosystems is influenced by soil phosphorus bioavailability, which depends largely on chemical fractions of phosphorus. The sequential fractionation technique developed by Hedley et al. or its subsequent modification is a well-known method to determine soil phosphorus forms. Hedley sequential fractionation technique separates the phosphorus into fractions based on their different chemical solubilities in extractants with certain chemical properties. Recently, synchrotron-based X-ray absorption near edge structure (XANES) spectroscopy has been employed to measure soil phosphorus species directly and non-invasively. The XANES method provides information concerning local structure and chemical information of target elements at a molecular level. Thus, it can distinguish phosphorus fractions bound by metal oxides or hydroxides (such as Fe, Al, and Ca). In this present work, the phosphorus speciation of topsoil along a glacial foreland chronosequence in Gongga Mountain is determined using these two methods. The changes in soil phosphorus bioavailability along the 120-year-old chronosequence are assessed based on comparisons of the results obtained by these two methods. The results indicate that Hedley sequential fractionation technique shows a greater ability to determine soil bioavailable phosphorus (Resin-P and NaCHO3-P), while XANES is effective in distinguishing phosphorus bound by metal compounds. In the chronosequence, Ca- and Al-bound phosphorus were derived mainly from primary minerals, whose phosphorus contents decreased within 120 years of moraine weathering and soil development. The content of soil bioavailable phosphorus increased rapidly after 30 years since deglaciation. The increasing phosphorus bioavailability promoted the colonizing and primary succession vegetation.  相似文献   

2.
Studies on hydrological processes are often emphasized in resource and environmental studies. This paper identifies the hydrological processes in different landscape zones during the wet season based on the isotopic and hydrochemical analysis of glacier, snow, frozen soil, groundwater and other water sources in the headwater catchment of alpine cold regions. Hydrochemical tracers indicated that the chemical compositions of the water are typically characterized by: (1) Ca? HCO3 type in glacier snow zone, (2) Mg? Ca? SO4 type for surface runoff and Ca? Mg? HCO3 type for groundwater in alpine desert zone, (3) Ca? Mg? SO4 type for surface water and Ca? Mg? HCO3 type for groundwater in alpine shrub zone, and (4) Ca? Na? SO4 type in surface runoff in the alpine grassland zone. The End‐Members Mixing Analysis (EMMA) was employed for hydrograph separation. The results showed that the Mafengou River in the wet season was mainly recharged by groundwater in alpine cold desert zones and shrub zones (52%), which came from the infiltration and transformation of precipitation, thawed frozen soil water and glacier‐snow meltwater. Surface runoff in the glacier‐snow zone accounted for 11%, surface runoff in alpine cold desert zones and alpine shrub meadow zones accounted for 20%, thawed frozen soil water in alpine grassland zones accounted for 9% of recharge and precipitation directly into the river channel (8%). This study suggested that the whole catchment precipitation did not produce significant surface runoff directly, but mostly transformed into groundwater or interflow, and finally arrived in the river channel. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

3.
Algae which bloom in open water and accumulate in the littoral zones may affect the biogeochemical cycle of phosphorus in eutrophic lakes. To determine such effects, a part of the lakeshore with little allochthonous nutrient input in Taihu Lake, China was selected for this field study. Distinct differences in sedimentary P forms were found among the different littoral subzones. The surface sedimentary total phosphorus (TP) content was 655 mg/kg in the eulittoral subzone and 631 to 641 mg/kg in the infralittoral subzone. Both were much higher than that in the profundal zone (410 mg/kg). Calcium‐bound P (Ca‐P) was significantly correlated to exchangeable P (Ex‐P), and they both had the highest contents in the infralittoral subzone and the lowest in the profundal zone. The aluminum‐ and iron‐bound P (Al‐P, Fe‐P) contents decreased from land to water along the ecotone section. Lower Fe/P ratios and higher Al‐P/Fe‐P ratios appeared in the infralittoral subzone, as compared with the profundal zone. This suggested that the accumulated algae could lead to a great deposit of P in the littoral zones. However, the active sedimentary P form transformation in the littoral zones would also result in a partial release of the accumulated P to the overlying water.  相似文献   

4.
Estuarine environments are particularly vulnerable to human impacts. In this study, trace elements in Ruppia megacarpa, Halophila ovalis, sediment and porewater were analysed to assess the potential contamination of the Leschenault Estuary, Western Australia, from a primarily agricultural drain. Sediment concentrations of Cd, Cu, Mn, and Ni and were highest nearest the drain while Al, As, Cr, Fe and Zn and were highest further from the drain. H. ovalis showed greater accumulation of Fe, Al, and As than R. megacarpa. Concentrations of Fe, Al, As, and Ni were generally higher in below-ground plant parts than above, suggesting uptake of these trace elements via the sediment-route pathway. This study suggested that the drain was a source of Cu and Mn, with these elements entering the estuary through water inflows. As and Fe, were highest furthest from the drain suggesting input of trace elements from sources other than the drain under study.  相似文献   

5.
Dissolved aluminium (Al) is generally at low concentrations in neutral freshwater due to its insolubility. However, a fall in pH resulting from acid deposition and mining alters the mobility of Al and so entry to adjacent neutral waters. The present study examines the environmental behaviour, cell-associated surface adsorption/absorption and toxicity of Al at neutral pH to the alga Chlamydomonas gigantea in the presence and absence of the key Al-binding ligand silica. We then examined transfer of Al from C. gigantea to the planktonic crustacean Daphnia pulex. Finally, the effect of Al on the elemental composition (and hence nutritional value) of the two organisms was compared to unexposed controls. C. gigantea increased the amount of Al in the algal culture medium. Binding of Al to extracellular glycoprotein is probably the reason why only one-third of the biosorbed Al was absorbed (accumulated) by C. gigantea. Aluminium concentrations between 50 and 500 μg l−1 reduced growth of C. gigantea at 16 days exposure to the metal. Silica reduced biosorption, accumulation and toxicity of Al by C. gigantea. The concentration of Al in D. pulex fed Al-contaminated C. gigantea for 16 days did not differ from those fed alga grown in the absence of added Al. C. gigantea contaminated with Al contained less sulphur, magnesium, potassium and sodium although only sulphur fell in D. pulex subsequently fed the contaminated alga. Chloride, calcium, iron and silicon were significantly higher in D. pulex.  相似文献   

6.
The current study focuses on the vertical profile of different geochemical fractions of phosphorus-loosely bound(Lo–P),aluminium bound(Al–P),iron bound(Fe–P),calcium bound(Ca–P),and organic bound phosphorus(O–P)along with ecological risk assessment of sediment cores from Chilika Lake,eastcoast of India.The percentage contribution of the different fractions to the sedimentary phosphorus in the sediment column of the whole lake are on the order:O–P(33.2%)>Ca–P(20.3%)>Fe–P(18%)>Al–P(6.7%)>Lo–P(0.35%).The Phosphorus Pollution Index(PPI)revealed the contamination of lake sediment with phosphorus.The principal component and cluster analyses highlighted the anthropogenic contribution of phosphorus.The negative loading of Ca–P with Ca points towards its origin from marine shells.The discriminate analysis showed that the variables like Ca–P,bio-available phosphorus(BAP),and pH were able to effectively discriminate the sectors in a significant manner.  相似文献   

7.
Variations in phosphorus speciation in two sets of simulated riparian zones with and without Perennial ryegrass were compared. Each set consisted of four units, each measuring 700 mm × 200 mm × 200 mm, which were enhanced with 0, 2.5, 5, and 7.5% red mud (RM) by weight. The levels of total phosphorus (TP), total dissolved phosphorus (TDP), soluble reactive phosphorus (SRP) in the effluent were analyzed, and phosphorus fractionation in the media were also determined after the systems had been operational for 3 months. The results showed that the unit received 2.5% RM had the highest rate of phosphorus removal, including TP, TDP, SRP, particulate phosphorus (PP), and dissolved organic phosphorus (DOP) were present at the average concentrations of 0.17, 0.10, 0.07, 0.08, and 0.03 mg/L in the effluent. Sequential phosphorus fractionation showed that calcium‐bound phosphorus (Ca–P) was the major component, indicating that the addition of RM induced aluminum/iron‐bound phosphorus (Al/Fe–P), which was intensely bioactive, to form intractable Ca–P, which further inhibited the release of phosphorus from the media. However, the presence of P. ryegrass had little effect on the removal of phosphorus. Therefore, RM, when used directly in riparian zones at a suitable concentration, is a novel and low cost additive material that can be used to remove phosphorus from reclaimed water.  相似文献   

8.
We have produced a P-wave model of the upper mantle beneath Southeast (SE) Asia from reprocessed short period International Seismological Centre (ISC) P and pP data, short period P data of the Annual Bulletin of Chinese Earthquakes (ABCE), and long period PP-P data. We used 3D sensitivity kernels to combine the datasets, and mantle structure was parameterized with an irregular grid. In the best-sampled region our data resolve structure on scale lengths less than 150 km. The smearing of crustal anomalies to larger depths is reduced by a crustal correction using an a priori 3D model. Our tomographic inversions reveal high-velocity roots beneath the Archean Ordos Plateau, the Sichuan Basin, and other continental blocks in SE Asia. Beneath the Himalayan Block we detect high seismic velocities, which we associate with subduction of Indian lithospheric mantle. This structure is visible above the 410 km discontinuity and may not connect to the remnant of the Neo-Tethys oceanic slab in the lower mantle. Our images suggest that only the southwestern part of the Tibetan plateau is underlain by Indian lithosphere and, thus, that the upper mantle beneath northeastern Tibet is primarily of Asian origin. Our imaging also reveals a large-scale high-velocity structure in the transition zone beneath the Yangtze Craton, which could have been produced in multiple subduction episodes. The low P-wave velocities beneath the Hainan Island are most prominent in the upper mantle and transition zone; they may represent counter flow from the surrounding subduction zones, and may not be unrelated to processes beneath eastern Tibet.  相似文献   

9.
Chen T  Yu K 《Marine pollution bulletin》2011,62(10):2114-2121
The P/Ca ratio in coral skeletons is considered to be a direct proxy for the nutrient P in seawater. We examined the reliability of this proxy by analyzing P/Ca in a Porites coral collected from a eutrophic area in the northern South China Sea. P concentrations were significantly higher compared to previously reported values from pristine and open seas, corresponding to the elevated nutrients from the study site. We compared coral P/Ca against recent in-situ records of seawater P concentrations. Our results show that P/Ca was primarily a function of TP sw rather than PO4sw, and that the signal of skeletal P included not only phosphate, but also organic phosphorus. Besides the form of skeletal P, sub-sampling and analytical procedures and the distinctive nutrient regime were the most reasonable explanations for our results. We suggest that total P in coral skeletons may be an efficient proxy for seawater P variations and associated phytoplankton dynamics in eutrophic environments.  相似文献   

10.
《Journal of Hydrology》1999,214(1-4):130-143
Forest drainage is recognized as a means of improving soil conditions for tree growth, but it may also have environmental impacts. This article presents the 5-y time trend of soil and surface water quality observed in a drainage experiment conducted in a black spruce (Picea mariana (Mill.) BSP) peatland of eastern Québec, Canada, using the paired watershed approach. Nutrient content of peat soil water was enhanced by drainage. The effect was generally proportional to ditch closeness for S and Mg, while increases of N, Na, K and Ca were mainly observed within 5 m of the ditches, even though high levels of K and Ca were occasionally observed at 15-m distance. Drainage increased and sustained summer low flows by 25% through a 80 m3 d−1 increase of base flow on the 8 ha basin. The concentration of suspended sediments significantly increased and exceeded acceptable limits for aquatic organisms only during ditching and during the peak flows of the following weeks. No effect on suspended sediments was detected during the spring following ditching but an increase was observed during a storm 2 y after ditching. Drainage modified the basin outflow temperature fluctuations by lowering the average weekly minimum and increasing the maximum, by 2°C and 7°C, respectively. Water temperature increases to 25°C or more at the outlet of the drained basin were above the preferred range for brook trout. The treatment significantly increased specific conductivity of surface water, which was clearly related to increases in mineral N (NH4+NOx), Ca, Mg, Na and S concentrations. However, conductivity and the increased nutrient concentrations remained within the acceptable criteria for aquatic organisms. Drainage also produced a pH increase of one unit, a result attributed to increased runoff from the upland part of the treated watershed. No effect related to drainage was found for Zn, Fe and Al contents.  相似文献   

11.
A 3-year ecological engineering project was carried out from 2003 to 2005 in the drinking water source in Meiliang Bay, Lake Taihu, China. The project area was divided into three zones: Zone C (outside the area), Zone B (pelagic part within the area) and Zone A (littoral part within the area). The community composition, density and biomass of zooplankton were studied as a part in the lake restoration study. Also, the abundance, biomass and composition of fish in the engineering area were annually analyzed in the littoral zone (Zone A). The average density of cladocerans decreased from the outer part to the inner part of the lake, i.e., from Zone C to Zone A, while the average density of copepod did not significantly vary among the 3 zones. The average densities of rotifer and ciliate increased from Zone C to Zone A. RDA analysis indicated that Microcystis biomass more impacted the zooplankton compositions after temperature. In Zone A, many planktivorous fishes, e.g., Coilia nasus, Hemiculter leucisculus, Pseudorasbora parva, dominated the fish community, which caused a marked decrease in the abundance of cladocerans, especially large-sized cladoceran Daphnia galeata and Daphnia obtusa. Our results suggested that both fish predation and other environmental factors such as the Microcystis bloom greatly affected the zooplankton community during the restoration of subtropical eutrophic lakes.  相似文献   

12.
The Pearl River Estuary is among the largest estuaries in the subtropical areas of the world. Along the salinity and turbidity gradient between the freshwater reach of the Pearl River and the marine water of the South China Sea, the spatial and temporal composition and abundance of phytoplankton was examined in relation to physic-chemical variables during the dry and wet seasons of 2009. Water samples for phytoplankton and environmental parameters were collected from 18 stations during two seasons along a transect from upper estuary to estuarine and marine sectors. A total of 162 species belonging to 7 phyla were identified, with diatoms dominated in both seasons while dinoflagellates proliferated in autumn. Two main clusters and three sub-clades under each main cluster corresponding to seasons and water sectors were defined with multivariate analysis (cluster and nMDS). Based on the species composition and abundance of phytoplankton, both seasonal and spatial variability were observed at a significant level (ANOSIM: season effect, R=0.896, P<0.01; station effect, R=0.463, P<0.01). The correlation analysis between biotic and abiotic variables indicated that instead of the “proverbial” anthropogenic nutrients loading and salinity gradient, the best 2-variable combination (temperature and turbidity) showed a significant effect on the pattern of phytoplankton assemblages (ρw=0.49, BIOENV analysis) between wet and dry seasons in the Pearl River Estuary. This result suggests that physical disturbance either natural or manmade is a more important factor in regulating the phytoplankton community structure within the hydrologically distinct zone of estuaries.  相似文献   

13.
The following facts have been established in this study. (1) Fine rhythmic layering can form due to diffusion. For example, the behavior of the elements Fe, Mg, Ca, and Al with a high diffusion coefficient (D 1 ? 1.1 × 10?5 cm2/s) can lead to the formation of fine rhythmic layering in rocks, whereas elements with low diffusion coefficients (D 1 ? 2.7 × 10?10 cm2/s) do not produce rhythmic layering and the distribution of their concentrations is monotonic. Equations derived to describe layering are used to calculate the distribution of magnesium (MgO) concentration in the Kivakka layered intrusion. Comparison of the theoretical distribution curve with in situ data showed their fairly good agreement, confirming the possible role of diffusion in the formation of fine rhythmic layering. (2) Conditions favorable for intermittent convection can occur in a magma chamber. The equation derived to describe the intermittent convection has a periodic solution. A distinctive feature of this type of convection is that zones of active mixing alternate with zones of relative stagnation. Conditions suitable for diffusion can arise in the latter, leading to the formation of fine (with layers up to 5 cm thick) rhythmic layering. An example of possible development of intermittent convection is the layered Akanvaara massif, where zones with a relatively smooth distribution of chemical elements alternate with zones of contrasting layering of rocks.  相似文献   

14.
Volcanogenic contamination of irrigation water, caused by effluent from the hyperacid Ijen crater lake, has severely affected the properties of agricultural soils in East Java, Indonesia. From a comparison of acidified topsoil with subsoil and with top- and subsoil in a reference area, we identified processes responsible for changes in soil and soil solution chemistry induced by acid irrigation water, with emphasis on the nutrients Ca, Mg, Fe, and Mn, and on Al, which may become phytotoxic under acid conditions in soils. Compositional data for bulk soil composition and selective extractions with 1 M KCl and 0.2 M acid ammonium oxalate are used in a mass balance approach to specify element fluxes, including uptake by rice plants. The results show that input via irrigation water has produced an increase in the total aluminum content in the affected topsoil, which is of the same order of magnitude as the increase in labile Al. High bioavailability of Al, as reflected by concentrations in KCl extracts, is consistent with elevated concentrations observed in rice plants. In contrast, and despite the high input via irrigation water, Ca and Mg concentrations have decreased in all measured soil fractions through dissolution of amorphous phases and minerals, and through competition of Al for adsorption sites on the exchange complex and plant roots. Strong leaching is also evident for Fe and especially Mn. In terms of the overall mass balance of the topsoil, plant uptake of Al, Ca, Fe, Mg and Mn is negligible. If the use of acid irrigation would be stopped and the soil pH were to increase to values above 4.5, the observed phytotoxicity of Al will be halted. However, crops may then become fully dependent on the input from irrigation water or fertilizer for essential elements, due to the previous removal from the topsoil through leaching.  相似文献   

15.
Seismic strain and b value are used to quantify seismic potential in the Zagros region (Iran). Small b values (0.69 and 0.69) are related to large seismic moment rates (9.96×1017 and 4.12×1017) in southern zones of the Zagros, indicating more frequent large earthquakes. Medium to large b values (0.72 and 0.92) are related to small seismic moment rates (2.94×1016 and 6.80×1016) in middle zones of the Zagros, indicating less frequent large earthquakes. Small b value (0.64) is related to medium seismic moment rate (1.38×1017) in middle to northern zone of the Zagros, indicating frequent large earthquakes. Large b value (0.87) is related to large seismic moment rate (2.29×1017) in northwestern zone, indicating more frequent large earthquakes. Recurrence intervals of large earthquakes (M > 6) are short in southern (10 and 14 years) and northwestern (13 years) zones, while the recurrence intervals are long in the middle (46 and 114 years) and middle to northern (25 years) zones.  相似文献   

16.
Wave breaking and wave runup/rundown have a major influence on nearshore hydrodynamics, morphodynamics and beach evolution. In the case of wave breaking, there is significant mixing of air and water at the wave crest, along with relatively high kinetic energy, so prediction of the free surface is complicated. Most hydrodynamic studies of surf and swash zone are derived from single-phase flow, in which the role of air is ignored. Two-phase flow modeling, consisting of both phases of water and air, may be a good alternative numerical modeling approach for simulating nearshore hydrodynamics and, consequently, sediment transport. A two-phase flow tool can compute more realistically the shape of the free surface, while the effects of air are accounted for. This paper used models based on two-dimensional, two-phase Reynolds-averaged Navier–Stokes equations, the volume-of-fluid surface capturing technique and different turbulence closure models, i.e., k–ε, k–ω and re-normalized group (RNG). Our numerical results were compared with the available experimental data. Comparison of the employed method with a model not utilizing a two-phase flow modeling demonstrates that including the air phase leads to improvement in simulation of wave characteristics, especially in the vicinity of the breaking point. The numerical results revealed that the RNG turbulence model yielded better predictions of nearshore zone hydrodynamics, although the k–ε model also gave satisfactory predictions. The model provides new insights for the wave, turbulence and means flow structure in the surf and swash zones.  相似文献   

17.
The response of metal accumulation in coral Tubastraea coccinea to various degrees of metal enrichment was investigated from the Yin-Yang Sea (YYS) receiving abandoned mining effluents, the Kueishan Islet (KI) hydrothermal vent field, and the nearshore area of remoted Green Island (GI). The concentrations of most dissolved metals were highest in seawater at YYS, followed by KI, and then GI, showing the effects of anthropogenic and venting inputs on metal levels. Five metals (Co, Fe, Mn, Ni, and Zn) yielded significant differences (p < 0.05) among the skeleton samples. We identified similar patterns in the metal–Ca ratios, indicating that the elevated metals in skeletons was a consequence of external inputs. The coral tissues were relatively sensitive in monitoring metal accumulation, showing significant differences among three locations for Cd, Co, Cu, Fe, Pb, Ni, and Zn. Specific bioconcentration factors provided strong support for the differential metal accumulation in skeletons and tissues.  相似文献   

18.
The paper concerns the complex study of pedogenic and magnetic characteristics of unpolluted soil profiles from Ukraine (3 profiles, of which two represent chernozem and one kastanozem) and Poland (1 profile of chernozem), all with loess parent material. Two of the profiles were situated further south than the other two. The “southern” zone is characterized by lower precipitation rate and higher annual temperatures than the “northern” zone. Depth variations of magnetic properties obtained with various methods were compared with pedogenic characteristics. The common characteristic of all profiles is enhancement of susceptibility in their upper parts related to the presence of superparamagnetic/ single-domain grains of maghemite/oxidized magnetite of pedogenic origin. However, variations of magnetic characteristics measured down depth profiles differ between profiles probably due to differences in climatic conditions and, perhaps, parent loess.  相似文献   

19.
Data for the diffusion of cations in pyroxenes are relevant to a variety of sub-solidus processes including order-disorder and exsolution. Similar data must also be available if the reliability of geobarometers and geothermometers involving pyroxenes is to be assessed. Two types of diffusion experiment have been performed to determine cation diffusion rates in pyroxenes: (1) interdiffusion between single crystals of diopside and polycrystalline sinters enriched in Al and Fe, and (2) interdiffusion between single crystals of diopside and a glass of the same composition which was isotopically enriched in26Mg and43Ca. Following high-temperature annealing for periods up to several hundred hours, analysis of the diffusion couples, using an electron microprobe and an ion microprobe respectively, failed to show any measurable diffusion profiles. From these “null result” experiments the diffusion coefficients (D) for Al and Fe in diopside are estimated to be less than4×10?14cm2s?1 at 1200°C, and values ofD for Ca and Mg in diopside are estimated to be less than7 × 10?14cm2s?1 at 1250°C. These rates are significantly slower than published tracer-type diffusion data for Ca and Al.A review of studies of order-disorder, microstructural coarsening, and diffusion in pyroxenes suggest that activation energies for cation exchange are typically in excess of 60 kcal mol?1. Transport rates will be assisted, and activation energies lowered by sample non-stoichiometry, inhomogeneities, high dislocation densities and the presence of water.The collective data for Al, Mg and Ca diffusion in diopside indicate diffusion coefficients? 10?15cm2s?1 at 1200°C. A comparison with data for diffusion in garnet, olivine and spinel suggests that pyroxenes may have the highest blocking temperatures.  相似文献   

20.
Phragmites australis invasion is altering plant communities and therefore, soil properties have been changed significantly. This study compared the diversity among three communities in a wetland to assess the impact of invasion by Phragmites and the associated impact on soil properties. Three diversity indices, species richness (S), evenness (E) and Shanon-Weiner index (H) had significantly higher values in uninvaded plots compared to invaded in all the communities. Invaded plots had the lowest diversity, with H = 0 and Simpson’s index (D) = 1, (i.e. they were monospecific). These results support the idea that a reduction in diversity can be expected in wetlands colonized by Phragmites. Phragmites invasion significantly increased soil moisture, EC, phenolics, organic carbon, dehydrogenase activity and microbial biomass (C, N, P) with reduction of pH and arbuscular mycorrhizae fungi spore density compared with uninvaded zones. In addition, the study of antifungal phytochemistry of Phragmites elucidated the decrease of the competitive abilities of native plant Melaleuca ericifolia by interfering with formation of mycorrhizal associations and biomass. Our results suggest that Phragmites invasion has caused significant ecological alterations in communities by demonstrating a combined effect to plant diversity and soil variables.  相似文献   

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