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1.
曝气充氧对城市污染河道内源铵态氮释放的控制   总被引：3，自引：1，他引：2  
凌芬  刘波  王国祥  许宽  周锋  杜旭 《湖泊科学》2013,25(1):23-30
以城市污染河道沉积物和上覆水为研究对象,利用模拟实验方法,探讨不同曝气充氧方式(水曝气EW、底泥曝气ES)对污染河道內源铵态氮(NH4+-N)释放的影响.研究结果发现:从间隙水和沉积物中NH4+-N的削减效果来看,底泥曝气均要优于水曝气;实验结束后,底泥曝气组沉积物与间隙水中NH4+-N含量分别减少63.39%和43.33%,水曝气组分别减少了7.54%和13.98%;从沉积物-水界面NH4+-N的扩散通量变化来看,水曝气组界面通量高于对照组,其变化规律与对照组相似;底泥曝气组沉积物-水界面NH4+-N扩散通量变化过程完全不同于其它两组,在整个试验周期内(除第5 d以外),底泥曝气组的通量低于水曝气组,在第15 d最低,为13.73 mg/(m2.d),仅为水曝气组和对照组的14.68%和19.93%,表明底泥曝气组沉积物NH4+-N的释放潜力低于水曝气组沉积物.  相似文献   

2.
以三峡水库香溪河库湾为研究对象,采用原位加密采样(2021年5月)和室内培养方法,结合沉积物特性与水环境因子分析,探讨了香溪河库湾沉积物甲烷(CH4)释放潜力、沉积物-水界面CH4产生和氧化通量空间分布规律及其影响因素。结果表明:三峡水库泄水期间,香溪河库湾沉积物CH4释放潜力的变化范围是6.35-2029.37 mg/(kg·d),沉积物-水界面CH4产生通量和氧化通量的变化范围分别为0.04～0.73、0.03～0.62 mmol/(m2·d);空间上,沉积物CH4释放潜力、沉积物-水界面CH4产生及氧化通量在香溪河库湾和各典型横切面(XX02、XX05和XX06)间表现出空间差异性,主要受水深、TOC和温度的影响。垂向上,CH4产生速率随沉积物深度的增加而减小,表层20 cm沉积物CH4释放潜力占整柱沉积物的70%,可以用于估算库湾沉积物CH4释放潜力。此外,沉积...  相似文献   

3.
Settled particles of fresh, labile organic matter may be a significant source of oxygen demand and nutrient regeneration in seasonally-hypoxic regions caused by nutrient inputs into stratified coastal zones. Studying the dynamics of this material requires sediment sampling methods that include flocculent organic materials and overlying water (OLW) at or above the sediment–water interface (SWI). A new coring device (“HYPOX” corer) was evaluated for examining nitrogen- (N) and oxygen-dynamics at the SWI and OLW in the northern Gulf of Mexico (NGOMEX). The HYPOX corer consists of a “Coring Head” with a check-valve, a weighted “Drive Unit,” and a “Lander,” constructed from inexpensive components. The corer collected undisturbed sediment cores and OLW from sediments at NGOMEX sampling sites with underlying substrates ranging from sand to dense clay. The HYPOX corer could be deployed in weather conditions similar to those needed for a multi-bottle rosette water-sampling system with 20 L bottles. As an example of corer applicability to NGOMEX issues, NH4+ cycling rates were examined at hypoxic and control sites by isotope dilution experiments. The objective was to determine if N-dynamics in OLW were different from those in the water column. “Ammonium demand,” as reflected by potential NH4+ uptake rates, was higher in OLW than in waters collected from a meter or more above the bottom at both sites, but the pattern was more pronounced at the hypoxia site. By contrast, NH4+ regeneration rates were low in all samples. These preliminary results suggest that heterotrophic activity and oxygen consumption in OLW in the hypoxic region may be regulated by the availability of NH4+, or other reduced N compounds, rather than by the lack of sufficient labile organic carbon.  相似文献   

4.
为了研究太湖底栖动物优势种类——霍甫水丝蚓(Limnodrilus hoffmeisteri)对于湖泊富营养化的影响,以温度和密度为模拟控制条件,对太湖霍甫水丝蚓进行营养盐释放的室内控制实验,研究温度和密度的变化对霍甫水丝蚓NH_4~+-N和PO_4~(3-)-P释放率的影响,根据霍甫水丝蚓铵态氮(NH_4~+-N)和磷酸盐(PO_4~(3-)-P)释放率与温度的关系方程,结合太湖霍甫水丝蚓2007-2010年的生物量估算其对太湖水体氮磷的潜在贡献.结果表明,随温度升高太湖霍甫水丝蚓NH_4~+-N和PO_4~(3-)-P的释放率均呈现逐渐升高的趋势,而密度变化对霍甫水丝蚓NH_4~+-N和PO_4~(3-)-P释放率的影响均不显著,太湖霍甫水丝蚓NH_4~+-N和PO_4~(3-)-P年平均释放量分别为1925.5和210.0 t,分别可达到全太湖沉积物-水界面NH_4~+-N和PO_4~(3-)-P的年净通量的19.3%和23.3%,表明霍甫水丝蚓的营养盐释放对于湖泊生物地化循环和湖泊富营养化具有显著的影响.  相似文献   

5.
We studied the morphological and biochemical changes of mitochondria-rich cells (MRCs) of a demersal teleost, Paralichthys olivaceus, during exposure to 0.98, 2.97 and 4.95 kPa pCO2. The apical opening area of MRCs increased 2.2 and 4.1 times by 24 h exposure to 2.97 and 4.95 kPa pCO2, respectively, while the cross-sectional area or density of MRCs did not change. Gill Na+/K+-ATPase activity more than doubled at 72 h and then returned to the pre-exposure level at 168 h in 0.98 kPa pCO2, while it increased 1.7 times at 24 h at 4.95 kPa. These results indicate that the apical opening area of MRCs and the gill Na+/K+-ATPase activity may be used as an indicator of acute (up to 72 h), but not chronic, impacts of high (>1 kPa) seawater CO2 conditions in P. olivacues. Limitations of those parameters as indices of CO2 impacts are discussed.  相似文献   

6.
三峡水库澎溪河消落区土-气界面CO2和CH4通量初探   总被引：1，自引：0，他引：1  
李哲  张利萍  王琳  郭劲松  高旭  方芳  蒋滔 《湖泊科学》2013,25(5):674-680
水库近岸湿地(消落区)温室气体(CO2、CH4)产汇是水库温室气体效应问题的重要组成部分.本文以三峡水库支流澎溪河的白家溪、养鹿两处大面积消落区为研究对象,于2010年6 9月水库低水位运行期间,对近岸消落区土-气界面CO2、CH4通量进行监测.白家溪消落区土-气界面CO2通量均值为12.38±2.42 mmol/(m2·h);CH4通量均值为0.0112±0.0064 mmol/(m2·h).养鹿消落区CO2、CH4通量均值分别为10.54±5.17、0.14±0.16 mmol/(m2·h).总体上,6 9月土-气界面CO2通量呈增加趋势,而CH4通量水平呈现显著的递减趋势.消落区土地出露后植被恢复,在一定程度上促进了土壤有机质含量的增加,使得6 9月CO2释放通量的总体趋势有所增加.消落区退耕后,其甲烷氧化菌的活性得到恢复,加之在土地出露曝晒过程中土壤透气性增强,使得消落区土壤对大气中CH4吸收氧化潜势增强.尽管如此,仍需进一步的研究以明晰消落区土-气界面CO2、CH4产汇的主要影响因素.  相似文献   

7.
Based on satellite observation data, using dynamics equation, the ionospheric O+ ion’s distribution in the synchronous altitude region for different geomagnetic activity indexK p is studied by theoretical modeling and numerical analyzing, and semi-empirical models for the O+ ion’s density and flux versus longitude in the synchronous altitude region for differentK p are given. The main results show that in the synchronous altitude region: (i) The O+ ion’s density and flux in day-side are larger than those in nightside. (ii) With longitude changing, the higher the geomagnetic activity indexK p is, the higher the O+ ion’s density and flux, and their variation amplitude will be. The O+ ion’s density and flux whenK p ≥ 6 will be about ten times as great as that whenK p = 0. (iii) WhenK p = 0 orK p ≥ 6, the O+ ion’s density reaches maximum at longitudes 120° and 240° respectively, and minimum in the magnetotail. WhenK p = 3−5, the O+ ion’s density gets to maximum at longitude 0°, and minimum in the magnetotail. However, the O+ ion’s flux reaches maximum at longitude 120° and 240° respectively, and minimum in the magnetotail for anyK p value.  相似文献   

8.
The southern Yellow Sea (SYS), located to the north of the East China Sea (ECS), was considered part of the ECS when Tsunogai et al. (1999) proposed the “continental shelf pump” (CSP) hypothesis. However, the original CSP carbon dioxide (CO2) uptake flux (2.9 mol C m−2 yr−1) appears to have been overestimated, primarily due to the differences between the SYS and the ECS in terms of their CO2 system. In this paper, we estimated air-sea CO2 fluxes in the SYS using the surface water partial pressure of CO2 (pCO2) measured in winter, spring, and summer, as well as that estimated in fall via the relationship of pCO2 with salinity, temperature, and chlorophyll a. The results indicate that overall, the entire investigated area was a net source of atmospheric CO2 during summer, winter, and fall, whereas it was a net sink during spring. Spatially, the nearshore area was almost a permanent CO2 source, while the central SYS shifted from being a CO2 sink in spring to a source in the other seasons of the year. Overall, the SYS is a net source of atmospheric CO2 on an annual scale, releasing ∼7.38 Tg C (1 Tg=1012 g) to the atmosphere annually. Thus, the updated CO2 uptake flux in the combined SYS and ECS is reduced to ∼0.86 mol C m−2 yr−1. If this value is extrapolated globally following Tsunogai et al. (1999), the global continental shelf would be a sink of ∼0.29 Pg C yr−1, instead of 1 Pg C yr−1 (1 Pg=1015 g).The SYS as a net annual source of atmospheric CO2 is in sharp contrast to most mid- and high-latitude continental shelves, which are CO2 sinks. We argue that unlike the ECS and the North Sea where carbon on the shelf could be exported to the open ocean, the SYS lacks the physical conditions required by the CSP to transport carbon off the shelf effectively. The global validity of the CSP theory is thus questionable.  相似文献   

9.
Carbon isotope ratios (δ 13C) of 89 C4 plant samples were determined from the loess area in North China. δ 13C values vary between −10.5‰ and −14.6‰ with a mean of −12.6‰. Along a precipitation gradient from the semi-moist area to the semiarid area, then to the arid area, the δ 13C values of C4 plants show a slight decreasing trend. The δ 13C values of C4 plants in the dry season are found lower than those in the wet season. These trends are opposite to those observed for C3 species.  相似文献   

10.
Vesicle characteristics (vesicularity, largest vesicle size, number of vesicles/cm2), CO2-δ13C and CO2-4He-40Ar-40Ar/36Ar in vesicles and CO2-δ13C in the glass have been measured in 19 tholeiitic basalt glasses from the Easter Microplate East Ridge (East Pacific Rise) collected at 3 different sites (26°S East Ridge, Pito Seamount and Pito Deep at 23°S).Carbon supersaturation values (Cmelt/Csolubility) vary from 1.3 to 4.3. Carbon supersaturation values are strongly correlated with the number of vesicles/cm2. There is also a correlation between number of vesicles/cm2 and vesicle size. At the Pito Seamount site, there is a negative correlation between carbon supersaturation values and observed carbon isotope fractionation between CO2 in vesicles and carbon dissolved in the glass (Δ13Cobserved). High 4He/40Ar* ratios in vesicles (from 49 to 190) are observed in both the most and least carbon supersaturated samples, while samples with intermediate carbon supersaturation have the lowest 4He/40Ar* ratios (16±1). These correlations show that most quenched melts record different disequilibrium to equilibrium states during closed-system degassing.The samples showing the highest carbon supersaturation (4.3) have the highest 4He/40Ar* (from 94 to 190). This observation shows for the first time that the 4He/40Ar* ratio can be kinetically fractionated during incomplete degassing of magmas from the magma chamber to the seafloor. This result implies that high 4He/40Ar* ratios are not a systematic indicator of open-system degassing (Rayleigh distillation) and that caution should be taken when using this ratio for any degassing correction.A two-stage degassing model, with the first stage being a closed-system degassing occurring between the source and the magma chamber, and the second stage of degassing (with a mode varying from open-system degassing to different degrees of kinetic closed-system degassing) taking place between the magma chamber and eruption on the seafloor, is the most appropriate to describe the degassing of MORB. Reconstructing initial carbon content of the magma prior to degassing and extrapolating the results to the entire ridge system results in a carbon flux of 1.6-0.3+0.6×1014 g/year. This value implies vigorous exchange of carbon between the mantle and the surface throughout geological times.  相似文献   

11.
Intercalibration of international and domestic 40Ar/39Ar dating standards   总被引：2，自引：0，他引：2  
Four international standards, Ga1550, MMhb-1, Lp-6, Bem 4M, and one domestic standard BT-1 have been intercalibrated. The repeated measurements on MMhb-1 with different mass demonstrate that MMhb-1 is inhomogeneous in age and its average age is 519.8 Ma. The results of Bern 4M and Lp-6 reflect that they have an invariable value of 40Ar*/39Ark (F) and the ages we obtained are consensus with their K-Ar age: Lp-6=127.7Ma; Bern 4M=18.2 Ma. Analyses of BT-1 age spectra, Ca/K and Cl/K spectra as well as inverse isochrons indicate that the sample is homogeneous and invariable and keeps close chemically, with its trapped argon isotope composition close to the atmosphere. The dating results show that age values are reproducible and steady, total fusion age, step-heating age, plateau age and isochron age are in accord with each other within the error range (2σ). Therefore, we recommend 28.7 Ma as the calibrated age of BT-1. We also discuss the variation in neutron flux gradients of Beijing 49-2 reactor. It was found that the neutron flux gradient varies considerably, and more monitors (standard samples) are needed to fix the trend of variation. The coefficient of the 49-2 reactor that transfers the ratio of production rate of 37ArCa/39ArK into Ca/K ratio is 1.78. This is different from that reported earlier, 2.0, which may be caused by the reconstruction of the reactor.  相似文献   

12.
Since October 2001, four soil CO2 flux stations were installed in the island of São Miguel (Azores archipelago), at Fogo and Furnas quiescent central volcanoes. These stations perform measurements by the accumulation chamber method and, as the gas flux may be influenced by external variables, the stations are equipped with several meteorological sensors. Multivariate regression analysis applied to the large datasets obtained allowed observing that the meteorological variables may influence the soil CO2 flux oscillations from 18% to 50.5% at the different monitoring sites. Additionally, it was observed that meteorological variables (mainly soil water content, barometric pressure, wind speed and rainfall) play a different role in the control of the gas flux, depending on the selected monitoring site and may cause significant short-term (spike-like) fluctuations. These divergences may be potentially explained by the porosity and hydraulic conductivity of the soils, topographic effects, drainage area and different exposure of the monitoring sites to the weather conditions. Seasonal effects are responsible for long-term oscillations on the gas flux.  相似文献   

13.
Many large rivers worldwide are enriched with high levels of suspended solids (SS), which are known to be hotspots of many nitrogen (N) transformation processes (e.g., denitrification, nitrification). However, the influence of SS on microbial ammonium (NH4+) recycling remains unclear. Water column NH4+ regeneration rates (REGs) and potential uptake rates (Upots) as well as community biological NH4+ demand (CBAD) was measured in the river-estuary continuum of the third longest river in the world—Yangtze River, which has dramatic SS gradients. We found that REGs, Upots, and CBAD all increased downriver, with higher REGs, Upots, and CBAD in the estuary than in the river sections. The regeneration and uptake of NH4+ were nearly balanced in the river sections, while the positive CBAD in the estuary indicated obvious NH4+ demand of microbes. Concentrations of SS, which also control the content of chemical oxygen demand and particulate N, were the main factor influencing NH4+ recycling rates and CBAD. SS-induced regenerated NH4+ in the river-estuary continuum of Yangtze River was estimated to be 11.02 × 108 kg N yr−1 and accounted for about 14% of total N inputs, suggesting that regenerated NH4+ is an important N source for microbes and may influence nutrient dynamics in lower coasts. To our knowledge, this is the first study to report NH4+ recycling in Yangtze River with an emphasis on its influencing factors and contribution to N budgets.  相似文献   

14.
四川、甘肃地区VS30经验估计研究   总被引：1，自引：0，他引：1       下载免费PDF全文
目前我国建筑工程抗震设计规范中对于工程场地条件的判断依据主要是地表以下20m深度范围内土层的等效剪切波速,简称VS20。相比之下,国外应用较广的是地表以下30m深度范围内的等效剪切波速,简称VS30。这种差别导致国内科研工作者在应用国外的地震工程、工程抗震模型时经常遇到对场地条件描述不准确的困难。为了解决这个问题,本文根据147个四川、甘肃地区国家强震动台站20m左右深度的钻孔剪切波速数据,利用延拓方法、场地分类统计方法以及基于地形特征的VS30估计方法研究各台站VS30与VS20的经验关系,对比发现基于速度梯度延拓的结果最为可取。参考国际上通用的Geomatrix Classification场地分类标准,最终得到四川、甘肃地区各类场地的平均VS30,此结果可以为缺乏钻孔数据的工程场地的VS30估计提供参考。  相似文献   

15.
Partial pressure of CO2 in equilibrium with sample water (pCO2) for the coastal water in the Chukchi Sea was continuously observed in summer, 2008. Average daily CO2 flux calculated from the pCO2 and gas transfer coefficients ranged from −0.144 to −0.0701 g C m−2 day−1 depending on which gas transfer coefficient was used. The pCO2 before the landfast ice sheets melted appeared to be highly biologically controlled based on the following information: (1) the diurnal pattern of pCO2 was strongly correlated with Photosynthetic Photon Flux Density (PPFD); (2) high chlorophyll density was observed during periods of peak uptake; and (3) the day-to-day variation in the pCO2 strongly correlated with the presence or absence of near-shore ice sheets. The lowest pCO2 of 35 ppm together with the highest PPFD of 1362 μmol E m−2 s−1 were observed in the afternoon on June 28 in the presence of sea ice. The very low pCO2 observed in late June was likely caused by high photosynthetic rates related to high phytoplankton densities typically observed from spring to early summer near the ice edge, and by water low in salinity and CO2 released by melting sea ice early in the season.  相似文献   

16.
The effect of the overlying water velocity on ammonium (NH4+) uptake by benthic biofilms was studied in a recirculating laboratory flume (260 cm long, 29 cm wide), packed with 5 cm of silica sand arranged into bedforms. NH4+ uptake was determined as the reduction in NH4+ concentration in the water at average overlying water velocities of 0.8, 2, 4 and 8 cm s?1. NH4+ uptake was relatively constant under laminar flow conditions but increased when the flow regime became turbulent (>4 cm s?1). This pattern was observed for two biofilms differing in their total biomass and in the abundance of the ammonia‐oxidizing bacteria, thus indicating that NH4+ uptake was strongly controlled by mass‐transfer processes. The near stoichiometric relationship between the rates of NH4+ uptake and nitrate (NO3?) accumulation suggests that aerobic nitrification was the main route for NH4+ uptake. Microelectrode measurements showed a sharp decline of oxygen concentrations and pH values within the biofilms, thus supporting strong nitrification activity within the surficial section of the benthic biofilms. The results of this study highlight the key role of hydrodynamic conditions in regulating NH4+ uptake in the transition from laminar to turbulent flow conditions. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

17.
金刚  李钟杰 《湖泊科学》1999,11(1):52-56
极大螺旋藻藻体ＳＯＤ聚丙烯酰胺梯度凝胶电泳呈现４条同工酶带,Ｈ２Ｏ２明显抑制该酶活性,ＫＣＮ对酶活性无影响,确认为Ｆｅ－ＳＯＤ。经硫酸铵分部盐析,离子交换柱层析及凝胶过滤,纯化到电泳单斑点均一程度。纯化的Ｆｅ－ＳＯＤ分子量为３９．３ＫＤ,亚基分子量为２０ＫＤ,金属元素分析表明,每个亚基含０．５５个Ｆｅ原子。该酶在紫外区最大吸收峰值为２７５．８ｎｍ,该酶氨基酸组成与蓝,绿藻和高等植物的Ｆｅ－ＳＯＤ相  相似文献   

18.
A comparison was made between the adsorptive behaviors of Cd2+ and UO 2 2+ relative to two smectites that differed in their ratio of edge sites to fixed-charge sites. Adsorption varied with both pH and ionic strength, consistent with sorptive contributions of ion exchange and coordination reactions to edge hydroxyls. Both clay minerals exhibited a greater affinity for UO 2 2+ than for Cd2+, and the clay with a higher proportion of edge sites retained both ions more strongly. A computational model including fixed-charge sites and edge hydroxyls resulted in a good prediction of overall UO 2 2+ and Cd2+ uptake to both smectites.  相似文献   

19.
自成库以来,三峡水库CO2、CH4等温室气体通量较蓄水前发生明显改变。如何科学认识和客观评估三峡水库修建及运行对其CO2、CH4等温室气体通量的影响备受关注。本文简要回顾了自2009年以来在三峡水库开展CO2、CH4等温室气体通量监测与分析工作,综述认为,现阶段三峡水库温室气体排放以水-气界面扩散释放为主要途径。陆源输入的有机碳是主导三峡水库CO2、CH4产生的主要碳源,但在局部区段或时段自源性有机碳的贡献亦十分显著。同蓄水前相比,三峡水库碳排放量呈现为净增加,淹没效应约占水库C净增量的20%,库区内点面源污染负荷并未对CO2排放的净增量产生显著贡献,阻隔效应和生态系统重建效应对三峡水库碳排放的净增量产生显著贡献。近10年来,监测方法比对、监测点位优化等工作在一定程度上完善了三峡水库温室气体通量监测体系。新方法、新技术的引入也为三峡水库温室气体通量监测分析提供了有利支撑和保障,但复杂水文环境...  相似文献   

20.
Expeditions during the summers of 2002 and 2003 implemented continuous monitoring of near-surface (2 m height) atmospheric CO2 and H2O concentrations at the 4500 m elevation on Muztagata. The resultant data sets reveal a slight decrease of CO2 concentrations (of about 5 μmol·mol-1) and changes in the diurnal variations from the end of June to the middle August. The daily maximum CO2 concentrations occur between 02:30-05:30 AM (local time) and the minimum levels occur between 12:00-15:30 PM. The atmospheric CO2 concentrations in the summer of 2002 were around 5 μmol·mol-1 lower than those during the same period of 2003, whereas the diurnal amplitude was higher. In contrast, we found that the daily mean atmospheric H2O content in 2003 was much lower than that in 2002 and there exists a striking negative correlation between CO2 and H2O concentrations. We therefore suggest that the near-surface atmospheric CO2 concentration is affected not only by photosynthesis and respiration, but also by the air H2O content in the glaciated region around Muztagata.  相似文献   

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