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In the past two decades, optical properties of chromophoric dissolved organic matter (CDOM) in marine environments have been extensively studied. Many of these studies report CDOM properties for the offshore environment where this complex mixture of optically active compounds is strongly diluted. Nevertheless, autochthonous and allochthonous sources have been identified and sinks related to photodegradation and bacterial activity have been demonstrated. The calculation of the spectral slope of the CDOM absorption curve has been proven to be useful and is often reported. However, a rigorous uncertainty analysis of the slope calculation is rarely reported. In this paper, we propose a method to evaluate the uncertainty of CDOM spectral slope calculated between 270 and 400 nm, using both naturally sampled and artificial solutions. We use these results to study the ultra-oligotrophic waters of the Mediterranean Sea (central eastern basin), where little is known about CDOM spatial distribution. We show that dilutions of both artificial and natural samples produce a Gaussian distribution of spectral slopes, indicating that consistent values may be determined, with a typical uncertainty of ±0.0004 nm−1 when absorption at 300 nm was greater then 0.1 m−1 (0.1 m pathlength). Comparing the distribution of spectral slopes from central eastern basin samples to a Gaussian distribution, we show differences between measurements that were significantly different. These values allow us to distinguish possible sources (algal derived CDOM), sinks (e.g. photo-bleaching) at different depths. We propose a subdivision of CDOM compounds into refractory and semilabile/refractory pools and evaluate the CDOM spectral slope of algal derived CDOM released at or near deep chlorophyll maximum.  相似文献   

3.
有色溶解性有机物(CDOM)广泛存在于水体中,占溶解有机碳(DOC)10%～90%,其浓度影响水环境碳循环过程、污染物质迁移以及水生生物群落的结构和功能。为分析东北地区水库DOC碳循环情况,本文于2015—2020年对第二松花江流域典型水库白山水库和丰满水库进行5次现场观测和室内实验,在分析CDOM吸收特性的基础上,基于Landsat系列卫星利用波段比值法建立CDOM浓度反演模型(R2=0.82),根据实测值CDOM与DOC的强相关性(R2=0.78),进而估算水库DOC浓度。结果表明：(1)利用野外实测数据和Landsat系列卫星能够对东北内陆水库CDOM浓度进行良好反演,(2)2000—2020年白山水库和丰满水库年际CDOM和DOC浓度变化不大,在2010年之后表现出轻微上升趋势,CDOM浓度从支流和干流的汇入到主库区呈现逐渐减少趋势,(3)白山水库和丰满水库M值(CDOM在250和365 nm处吸收系数比值)和S275～295(CDOM在275～295 nm波段处的吸收光谱的斜率)较小、SUVA254<...  相似文献   

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采用荧光光谱区域体积积分法定量研究洱海沉积物有色可溶性有机物（CDOM）三维荧光空间分布特性,结果表明,洱海沉积物CDOM中类腐殖酸组分占比最高（44.5%~74.2%）,其次为溶解性微生物代谢产物（10.7%~20.4%）和类富里酸物质（8.19%~19.7%）,而类蛋白组分占比最低,类腐殖酸占比与H/C和N/C均呈显著负相关;南部湖心平台区域沉积物类富里酸和类蛋白组分占比较高,其CDOM自生源占比较高;北部水生植物分布区溶解性微生物代谢产物占比较高,CDOM陆源性较强;中部深水区及南北湖湾区域类腐殖酸占比较高,随水深增加沉积物CDOM自生源特征增强.随沉积物深度增加类腐殖酸和溶解性微生物代谢产物占比呈下降趋势,类富里酸占比呈上升趋势,CDOM自生源特征增强,脂肪化程度增高.随湖泊富营养化程度增加沉积物CDOM受微生物代谢产物影响增强,陆源性增加,而自生源性降低,湖泊沉积物CDOM具有富营养化指示意义.  相似文献   

8.
Abiotic effects of UV on planktonic P kinetics   总被引：1，自引：0，他引：1  
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9.
The optical observations on Heiss Island (Φ′ = 75.0°) have been used to study the characteristics of auroras in the near-noon MLT sector after abrupt increases in the solar wind dynamic pressure at negative and positive polarity of the IMF B z component. It has been found out that the 427.8 and 557.7 nm emission intensities considerably increased at B z < 0 both equatorward of the dayside red luminosity band and within this band. The value of the emission intensities at a red luminosity maximum (I 6300/I 5577 ∼ 0.5) indicates that energetic electron precipitation is of the magnetospheric origin. At B z > 0, fluxes of harder (E > 1 keV) precipitating electrons were superimposed on the soft spectrum of precipitating particles in the equatorial part of the red luminosity band. This red band part was hypothetically caused by the low-latitude boundary layer (LLBL) on closed lines of the geomagnetic field, the estimated thickness of which is ∼3 R e . The 557.7 nm emission intensity increased during 3–5 min after SC/SI and was accompanied by the displacement of the red band equatorward boundary toward lower latitudes. The displacement value was ∼150–200 km when the dynamic pressure abruptly increased by a factor of 3–5. After SC/SI, the 630.0 nm emission intensity continued increasing during 16–18 min. It is assumed that the time of an increase in the red line intensity corresponds to the time of saturation of the magnetospheric boundary layers with magnetosheath particles after an abrupt increase in their density.  相似文献   

10.
Body-wave Attenuation in the Region of Garda, Italy   总被引：1，自引：0，他引：1  
We analyzed the spectral amplitude decay with hypocentral distance of P and S waves generated by 76 small magnitude earthquakes (ML 0.9–3.8) located in the Garda region, Central-Eastern Alps, Italy. These events were recorded by 18 stations with velocity sensors, in a distance range between 8 and 120 km. We calculated nonparametric attenuation functions (NAF) and estimated the quality factor Q of both body waves at 17 different frequencies between 2 and 25 Hz. Assuming a homogeneous model we found that the Q frequency dependence of P and S can be approximated with the functions Q P = 65 f 0.9 and Q S = 160 f 0.6 , respectively. At 2 Hz the Q S /Q P ratio reaches the highest value of 2.8. At higher frequencies Q S /Q P varies between 0.7 and 1.7, suggesting that for this frequency band scattering may be an important attenuation mechanism in the region of Garda. To explore the variation of Q in depth, we estimated Q at short (r ≤ 30 km) and intermediate (35–90 km) distance paths. We found that in the shallow crust P waves attenuate more than S (1.3 < Q S /Q P < 2.5). Moreover, P waves traveling along paths in the lower crust (depths approximately greater than 30 km) attenuate more than S waves. To quantify the observed variability of Q in depth we considered a three-layer model and inverted the NAF to estimate Q in each layer. We found that in the crust Q increases with depth. However, in the upper mantle (~40–50 km depth) Q decreases and in particular the high frequency Q S (f > 9 Hz) has values similar to those estimated for the shallow layer of the crust.  相似文献   

11.
In many streams, microbial growth largely relies on terrigenous organic carbon that has been initially stored in soils and that is generally believed to be recalcitrant to microbial metabolism. The various mechanisms that underlie the availability of terrigenous organic carbon as it enters streams remain poorly understood. One possible mechanism can be photodegradation of terrigenous dissolved organic carbon (DOC) upon exposure to sunlight in streamwater. To explore this, we experimentally exposed streamwater, shallow groundwater and soil water from a clear-water Alpine headwater stream, and both soil and algal extracts, to UV-radiation and studied the effects on DOC optical properties and implications for microbial growth. Our results on the apparent quantum yield suggest that DOC from groundwater and soil water is more resistant to photodegradation than DOC in the streamwater itself. This would highlight the relevance of the exposure history of DOC to sunlight. Overall, UV-radiation decreased the aromaticity (as SUVA254) of the DOC and reduced its molecular weight as indicated by the slope ratio, S R (S 275–295/S 350–400). UV-treatment significantly increased bacterial growth rate and bacterial growth efficiency in the streamwater, soil water, groundwater and soil extract but not in algal extract. Our findings suggest photodegradation as one mechanism that contributes to the microbial utilisation of terrigenous DOC even in clear-water streams.  相似文献   

12.
The distribution and photoreactivity of chromophoric dissolved organic matter (CDOM) in the northern Gulf of Mexico along the Louisiana coastal shelf were examined during three cruises in summer 2007, fall 2007, and summer 2008. The influence of the Mississippi River plume was clearly evident as CDOM levels (defined as a305) and dissolved organic carbon (DOC) concentrations were well-correlated with salinity during all cruises. Elevated CDOM and CDOM:DOC ratios of surface samples collected offshore of Atchafalaya Bay and the Breton-Chandeleur Sound complex indicated emanations of organic-rich waters from coastal wetlands are also an important source to nearshore shelf waters. Generally, CDOM and DOC levels were highest in surface waters and decreased with depth, but during summer 2007 and summer 2008, CDOM levels in near-bottom samples were occasionally higher than at mid-depths without concomitant increases in DOC. CDOM photobleaching was measured during 24 irradiations using a SunTest XLS+ solar simulator with photobleaching rate coefficients (k305) ranging from 0.011 to 0.32 h−1. For fall 2007 and summer 2008, higher k305 values were generally observed in samples with higher initial CDOM levels. However, samples collected during summer 2007 did not exhibit a similar pattern nor were there differences in photobleaching rates between surface and bottom samples. Spectral slope coefficients (S275-295 or S350-400) and DOC levels were largely unchanged after 24 h irradiations. Modeled CDOM photobleaching for northern Gulf of Mexico mid-shelf waters predicts that during the summer when solar irradiance is high and the water column becomes stratified, nearly 90% of the CDOM in the upper 1 m may be lost to photobleaching, with losses up to 20% possible even at 10 m depth.  相似文献   

13.
Accumulation rates of marine and terrigenous organic carbon in the continental margin sediments off southwestern Taiwan were estimated from the measured concentrations and isotopic compositions of total organic carbon (TOC) and previously reported sedimentation rates. Surficial sediments were collected from the study area spanning from the narrow shelf near the Kaoping River mouth to the deep slope with depths reaching almost 3000 m. The average sediment loading of Kaoping River is 17 Mt/yr, which yields high sediment accumulation rates ranging from 0.08 to 1.44 g cm−2 yr−1 in the continental margin. About half of the discharged sediments were deposited on the margin within 120 km of the river mouth. Carbon isotopic compositions of terrestrial and marine end-members of organic matter were determined, respectively, based on suspended particulate matter (SPM) collected from three major rivers in the southwestern Taiwan and from an offshore station. All samples were analyzed for the TOC content and its isotopic composition (δ13Corg). The SPM samples were also analyzed for the total nitrogen (TN) content. TOC content in marine sediments ranges from 0.45% to 1.35% with the highest values on the upper slope near the Kaoping River mouth. The TOC/TN ratio of the SPM samples from the offshore station is 6.8±0.6, almost identical to the Redfield ratio, indicating their predominantly marine origin; their δ13Corg values are also typically marine with a mean of −21.5±0.3‰. The riverine SPM samples exhibit typical terrestrial δ13Corg values around −25‰. The δ13Corg values of surficial sediments range from −24.8‰ to −21.2‰, showing a distribution pattern influenced by inputs from the Kaoping River. The relative contributions from marine and terrestrial sources to sedimentary organic carbon were determined by the isotope mixing model with end-member compositions derived from the riverine and marine SPM. High fluvial sediment inputs lead to efficient trapping of organic carbon over a wide range of water depth in this continental margin. The marine organic accumulation rate ranges from 1.6 to 70 g C m−2 yr−1 with an area weighted mean of 4.2 g C m−2 yr−1, which is on a par with the mean terrestrial contribution and accounts for 2.3% of mean primary production. The depth-dependent accumulation rate of marine organic carbon can be simulated with a function involving primary productivity and mineral accumulation rate, which may be applicable to other continental margins with high sedimentation rates. Away from the nearshore area, the content of terrigenous organic carbon in surficial sediments decreases with distance from the river mouth, indicating its degradation in marine environments.  相似文献   

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15.
On the basis of measurements of the intensity of 1.58-μm emissions of the Infrared Atmospheric System of molecular oxygen (IRAO2) conducted at the Zvenigorod scientific station of the Institute of Atmospheric Physics of the Russian Academy of Sciences (φ = 55.7°N, λ = 36.8°E), seasonal variations are estimated for various solar zenith angles. Their amplitude has the maximum value at the solar zenith angles χ S ∼ 105–110°. It decreases at χ S ∼ 125–130° and tends to zero at χ S ∼ 80–85°. The comparison of currently measured values of the 1.58-μm emission intensity of the Infrared Atmospheric System of molecular oxygen with published data on the intensity of this emission obtained in 1961–1966 reveals their decrease over approximately 50 years. This fact is in good agreement with similar behavior of the emission intensity of atomic oxygen (557.7 nm) over the period considered.  相似文献   

16.
IntroductionMany anomalies due to earthquake have been recorded in observation of earth-resistivity for30 years and over, which showed that there objectively existed the anomalies of each-resistivity.The crustal strUcture and medium conditions are quite complex, so the complexity of the temporal,spatial and intensive development of the anomalies is inevitable. Both of time and amplitUde ofanomalies among some stations near an epicenter are different (even among different observational directi…  相似文献   

17.
To explore whether quinone moieties are important in chromophoric dissolved organic matter (CDOM) photochemistry in natural waters, hydrogen peroxide (H2O2) production and associated optical property changes were measured in aqueous solutions irradiated with a Xenon lamp for CDOM model compounds (dihydroquinone, benzoquinone, anthraquinone, napthoquinone, ubiquinone, humic acid HA, fulvic acid FA). All compounds produced H2O2 with concentrations ranging from 15 to 500 μM. Production rates were higher for HA vs. FA (1.32 vs. 0.176 mM h−1); values ranged from 6.99 to 0.137 mM h−1 for quinones. Apparent quantum yields (Θapp; measure of photochemical production efficiency) were higher for HA vs. FA (0.113 vs. 0.016) and ranged from 0.0018 to 0.083 for quinones. Dihydroquinone, the reduced form of benzoquinone, had a higher production rate and efficiency than its oxidized form. Post-irradiation, quinone compounds had absorption spectra similar to HA and FA and 3D-excitation–emission matrix fluorescence spectra (EEMs) with fluorescent peaks in regions associated with CDOM.  相似文献   

18.
Receiver function study in northern Sumatra and the Malaysian peninsula   总被引：1，自引：0，他引：1  
In this receiver function study, we investigate the structure of the crust beneath six seismic broadband stations close to the Sunda Arc formed by subduction of the Indo-Australian under the Sunda plate. We apply three different methods to analyse receiver functions at single stations. A recently developed algorithm determines absolute shear-wave velocities from observed frequency-dependent apparent incidence angles of P waves. Using waveform inversion of receiver functions and a modified Zhu and Kanamori algorithm, properties of discontinuities such as depth, velocity contrast, and sharpness are determined. The combination of the methods leads to robust results. The approach is validated by synthetic tests. Stations located on Malaysia show high-shear-wave velocities (V S) near the surface in the range of 3.4–3.6 km s − 1 attributed to crystalline rocks and 3.6–4.0 km s − 1 in the lower crust. Upper and lower crust are clearly separated, the Moho is found at normal depths of 30–34 km where it forms a sharp discontinuity at station KUM or a gradient at stations IPM and KOM. For stations close to the subduction zone (BSI, GSI and PSI) complexity within the crust is high. Near the surface low V S of 2.6–2.9 km s − 1 indicate sediment layers. High V S of 4.2 km s − 1 are found at depth greater than 6 and 2 km at BSI and PSI, respectively. There, the Moho is located at 37 and 40 km depth. At station GSI, situated closest to the trench, the subducting slab is imaged as a north-east dipping structure separated from the sediment layer by a 10 km wide gradient in V S between 10 and 20 km depth. Within the subducting slab V S ≈ 4.7 km s − 1. At station BSI, the subducting slab is found at depth between 90 and 110 km dipping 20° ± 8° in approximately N 60° E. A velocity increase in similar depth is indicated at station PSI, however no evidence for a dipping layer is found.  相似文献   

19.
Most rivers in Italy are segmented by dams that need rehabilitation because of (1) safety requirements by increasingly risk-averse societies, (2) changes in the downstream river and riparian system after dams building, (3) poor initial design at the time of completion and (4) modified priorities of watershed management. Safe design of flood spillways is a major concern, and requires to cope with low frequency flood hazard. One must estimate flood figures with high return periods (R ⩾ 1000–10,000 years) but statistical methods involve large uncertainties because of the short length of the available records. This paper investigates the return period of the design flood of existing spillways RS of large dams in Italy. We used re-normalized flood frequency approach and regionalization using the Generalized Extreme Value distribution. The estimation of the site specific index flood is carried out by simple scaling with basin area at the regional level. The result show that 55% (245) of the 448 examined dams are equipped by spillway with RS > 10,000; and 71% (315) of the dams have RS > 1000. Conversely, 29% (130) of the dams display RS < 1000 years, lower than acceptable hazard. The spillway of 14% (62) of the dams has RS < 100 years, indicating potential exceedance of spillways capacity. Reservoir routing may dampen the outflow hydrograph, but one should carefully account for the need of achieving accurate dam safety assessment of these dams based on site specific investigations, also accounting for global change forcing.  相似文献   

20.
Transport of non-ergodic solute plumes by steady-state groundwater flow with a uniform mean velocity, μ, were simulated with Monte Carlo approach in a two-dimensional heterogeneous and statistically isotropic aquifer whose transmissivity, T, is log-normally distributed with an exponential covariance. The ensemble averages of the second spatial moments of the plume about its center of mass, <S i i (t)>, and the plume centroid covariance, R i i (t) (i=1,2), were simulated for the variance of Y=log T, σ Y 2=0.1, 0.5 and 1.0 and line sources normal or parallel to μ of three dimensionless lengths, 1, 5, and 10. For σ Y 2=0.1, all simulated <S i i (t)>−S i i (0) and R i i (t) agree well with the first-order theoretical values, where S i i (0) are the initial values of S i i (t). For σ Y 2=0.5 and 1.0 and the line sources normal to μ, the simulated longitudinal moments, <S 11(t)>−S 11(0) and R 11(t), agree well with the first-order theoretical results but the simulated transverse moments <S 22(t)>−S 22(0) and R 22(t) are significantly larger than the first-order values. For the same two larger values of σ Y 2 but the line sources parallel to μ, the simulated <S 11(t)>−S 11(0) are larger than but the simulated R 11 are smaller than the first-order values, and both simulated <S 22(t)>−S 22(0) and R 22(t) stay larger than the first-order values. For a fixed value of σ Y 2, the summations of <S i i (t)>−S i i (0) and R i i , i.e., X i i (i=1,2), remain almost the same no matter what kind of source simulated. The simulated X 11 are in good agreement with the first-order theory but the simulated X 22 are significantly larger than the first-order values. The simulated X 22, however, are in excellent agreement with a previous modeling result and both of them are very close to the values derived using Corrsin's conjecture. It is found that the transverse moments may be significantly underestimated if less accurate hydraulic head solutions are used and that the decreasing of <S 22(t)>−S 22(0) with time or a negative effective dispersivity, defined as , may happen in the case of a line source parallel to μ where σ Y 2 is small.  相似文献   

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