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1.
The Dajia Salento-type bauxite deposit in western Guangxi is hosted within the Quaternary ferrallitic soil profile, and it formed via breaking up, weathering and oxidizing of Permian bauxite orebodies occurring as a semi-continuous layer in the upper Permian. Mineralogical analyses reveal that diaspore, hematite and kaolinite are the major minerals in bauxite ores with small amounts of anatase, chamosite, gibbsite, goethite, illite, zircon, quartz and pyrite. The ore texture and mineral assemblage reveal that the depositional/diagenetic environment of the Dajia bauxite was much close to phreatic environment. Both the ore texture and the morphology of zircon grains also indicate that most of the bauxitic soils were transported a short distance. Diaspore is suggested to be non-metamorphic in origin and mainly formed in a reducing condition of diagenetic environment, while kaolinite is the product of the in situ epigenetic replacement of alumina in diaspore by dissolved silica. Geochemical analyses indicate that Al2O3, Fe2O3, SiO2 and TiO2 are the main components of the bauxite ores and trace elements such as Zr, Hf, Nb, Ta, Th and U were enriched during the bauxitization process. Simultaneously, Zr vs. Hf and Nb vs. Ta show a high correlation. Geochemical indices such as Zr/Hf, Nb/Ta and Eu/Eu* (among others) denote that the magmatic rocks related to the Emeishan plume in western Guangxi and the carbonates in the underlying Maokou Formation provided the main sources of material for the bauxite ores.  相似文献   

2.
The Mandan and Deh-now bauxite deposits are located 40 km northeast of the Dehdasht city in the Zagros simply fold belt. These deposits occur in eroded major NW–SE trending anticlines and occupy karst cavities near or at the boundary between the Sarvak and Ilam Formations. Local uplifts at the end of the Cenomanian and the mid-Turonian caused erosion and karstification of the Sarvak Formation. These unconformities in the Upper Cretaceous favoured the formation and enrichment of bauxite deposits in the Zagros fold belt. The bauxite sequence in the Mandan deposit consists of white, gray, black, pisolitic, red, and yellow bauxites. This sequence was repeated in the Deh-Now area, but without gray and black bauxites. The present mineralogical studies of the Sarvak Formation and the Mandan and Deh-now bauxite deposits indicate oxidizing to reducing conditions during the Upper Cretaceous in the Zagros fold belt, which had a significant effect on the compositions of the bauxites. At least two phases of bauxitization can be distinguished in the study area: (i) an oxidizing phase represented by boehmite, diaspore, hematite and kaolinite; and (ii) a reducing phase represented by pyrite and chlorite. Geochemical data show that trace elements, like Zr, Hf, Nb, Ta, Th, and U, were enriched during bauxitization. The bauxite deposits and carbonate rocks show similar REE patterns, namely they are enriched in REEs although the LREEs are more enriched than the HREEs. Mass change calculations demonstrate that Mg, Mn, Ca, K, and P2O5 were leached out of the weathered system whereas Al, Fe, and Si become concentrated in the residual system. This study indicates that the Mandan and Deh-now deposits are karst-type bauxites formed by karstification and weathering of the Sarvak Formation.  相似文献   

3.
ABSTRACT

We address the growing controversy about the tectonic setting in which Jurassic magmatism of Iran occurred: arc or continental rift. In the Ghorveh area of the northern Sanandaj Sirjan zone (SaSZ), the Ghalayan metabasites are interlayered with marble and schist and locally cut by acidic dikes. Zircon U-Pb dating of the metabasitic rocks shows that these crystallized at ca. 145–144 Ma ago in the Late Jurassic (Tithonian). This complex was metamorphosed in the lower greenschist facies, however, some protolithic structures such as pillow lava and primary minerals are preserved. The metabasites are tholeiites with low SiO2 (45.6–50.5 wt.%), moderate Al2O3 (11.3–17.0 wt.%), and high TiO2 (0.7–2.9 wt.%) and Fe2O3 (9.4–14.1 wt.%). The Ghalayan metabasites are enriched in Light rare earth elements (LREEs) without significant Nb, Ta, Pb, Sr and Ba anomalies, similar to modern continental intra-plate tholeiitic basalts such as Afar and East African rifts. The Ghalaylan metabasites show wide ranges for 87Sr/86Sr(i) (0.7039–0.7077) and positive εNd(t) values (+0.1 to +4.6). These isotopic compositions are similar to those expected for slightly depleted subcontinental lithospheric mantle sources. Independently built discrimination diagrams indicate an intra-continental rifting regime for the source of Jurassic metabasites in the northern SaSZ. Geochemical and tectonic evidence suggests that rifting or a mantle plume was responsible for volcanic activity in the Upper Jurassic SaSZ. Considering the variation of ages of basaltic volcanism along the SaSZ, we suggest that Ghalayan basaltic magmatism reflected a submarine volcano that formed as part of the late stage continental rift, similar to Afar in the East African Rift system. Our results indicate that an extensional tectonic regime dominated SaSZ tectonics in the Middle to Late Jurassic.  相似文献   

4.
The Mombi bauxite deposit is located in 165 km northwest of Dehdasht city, southwestern Iran. The deposit is situated in the Zagros Simply Fold Belt and developed as discontinuous stratified layers in Upper Cretaceous carbonates (Sarvak Formation). Outcrops of the bauxitic horizons occur in NW-SE trending Bangestan anticline and are situated between the marine neritic limestones of the Ilam and Sarvak Formations. From the bottom to top, the deposit is generally consisting of brown, gray, pink, pisolitic, red, and yellow bauxite horizons. Boehmite, diaspore, kaolinite, and hematite are the major mineral components, while gibbsite, goethite, anatase, rutile, pyrite, chlorite, quartz, as well as feldspar occur to a lesser extent. The Eh–pH conditions during bauxitization in the Mombi bauxite deposit show oxidizing to reducing conditions during the Upper Cretaceous. This feature seems to be general and had a significant effect on the mineral composition of Cretaceous bauxite deposits in the Zagros fold belt. Geochemical data show that Al2O3, SiO2, Fe2O3 and TiO2 are the main components in the bauxite ores at Mombi and immobile elements like Al, Ti, Nb, Zr, Hf, Cr, Ta, Y, and Th were enriched while Rb, Ba, K, Sr, and P were depleted during the bauxitization process. Chondrite-normalized REE pattern in the bauxite ores indicate REE enrichment (ΣREE = 162.8–755.28 ppm, ave. ∼399.36 ppm) relative to argillic limestone (ΣREE = 76.26–84.03 ppm, ave. ∼80.145 ppm) and Sarvak Formation (ΣREE = 40.15 ppm). The REE patterns also reflect enrichment in LREE relative to HREE. Both positive and negative Ce anomalies (0.48–2.0) are observed in the Mombi bauxite horizons. These anomalies are related to the change of oxidation state of Ce (from Ce3+ to Ce4+), ionic potential, and complexation of Ce4+ with carbonate compounds in the studied horizons. It seems that the variations in the chemistry of ore-forming solutions (e.g., Eh and pH), function of carbonate host rock as a geochemical barrier, and leaching degree of lanthanide-bearing minerals are the most important controlling factors in the distribution and concentration of REEs. Several lines of evidences such as Zr/Hf and Nb/Ta ratios as well as similarity in REE patterns indicate that the underlying marly limestone (Sarvak Formation) could be considered as the source of bauxite horizons. Based on mineralogical and geochemical data, it could be inferred that the Mombi deposit has been formed in a karstic environment during karstification and weathering of the Sarvak limy Formation.  相似文献   

5.
A mafic sill-like intrusion, ~5?×?30 m, exposed along the eastern shoreline of Kahoolawe Island, Hawaii, represents tholeiitic magma emplaced as diabase among caldera-filling lavas. It differentiated from ~7.8 wt.% MgO to yield low-MgO (2.9 wt.%) vesicular segregation veins. We examined the intrusion for whole-rock and mineral compositions for comparison to Kahoolawe caldera-fill lavas (some also diabasic), to the Uwekahuna laccolith (Kilauea), and to gabbros, diabases, and segregations and oozes of other tholeiitic shield volcanoes (e.g., Mauna Loa and Kilauea lava lakes). We also evaluate this extreme differentiation in terms of MELTS modeling, using parameters appropriate for Hawaiian crystallization environments. Kahoolawe intrusion diabase samples have major and trace element abundances and plagioclase, pyroxene, and olivine compositions in agreement with those in gabbros and diabases of other volcanoes. However, the intrusion samples are at the low-MgO end of the large MgO range formed by the collective comparative samples, as many of those have between 8 and 20 wt.% MgO. The intrusion’s segregation vein has SiO2 53.4 wt.%, TiO2 3.2 wt.%, FeO 13.5 wt.%, Zr 350 ppm, and La 16 ppm. It plots in compositional fields formed by other Hawaiian segregations and oozes that have MgO <5 wt.%—fields that show large variances, such as factor of ~2 differences for incompatible element abundances accompanying SiO2 from ~49 to 59 wt.%. Our MELTS modeling assesses the Kahoolawe intrusion as differentiating from ~8 wt.% MgO parent magma beginning along oxygen buffers equivalent to FMQ and FMQ-2, having magmatic H2O of 0.15 and 0.7 wt.% (plus traces of CO2 and S), and under 100 and 500 bars pressure. Within these parameters, MELTS calculates that <3 wt.% MgO occurs at ~1,086 to 1,060 °C after ~48 to 63 % crystallization, whereby the lesser crystallization percentages and lower temperatures equate to higher magmatic H2O, leading to high SiO2, ~56–58 wt.%. To contrast, greater crystallization is calculated for lower H2O, for which it achieves less SiO2, <55 wt.%. While MELTS reliably predicts SiO2 approaching 58 wt.% for differentiation beyond <4 wt.% MgO, and shows that Kahoolawe intrusion’s segregations and those of Kilauea and Mauna Loa are all reasonably accommodated by the modeled parameters and SiO2 differentiation curves, MELTS fails where it predicts that Fe enrichment is more robust under FMQ than FMQ-2 buffers. That failure not withstanding, MELTS differentiation from liquidus temperatures ~1,205–1,185 °C (depending on the various parameters) gradually increases fO2 (up to ~0.4 log units, as normalized to FMQ) until magnetite crystallizes at ~1,090–1,085 °C, which reduces absolute fO2 ~1 to 1.5 log units. The modeled Kahoolawe intrusion, then, exemplifies how tholeiitic magma differentiation can produce extreme SiO2 and incompatible element compositions, and how Hawaiian segregations from shallow intrusions and lava lakes can be generally modeled under compositional and physical parameters appropriate for Hawaiian tholeiitic magmatism.  相似文献   

6.
Bauxite deposits are widespread in NW Sardinia. They formed during the middle Cretaceous, in consequence of a period of emergence of the Mesozoic carbonate shelf. In the Nurra area the geometries derived by the Middle Cretaceous tectonic phases controlled the ore typologies. Two bauxite profiles, laying on different bedrocks, were sampled. The bauxitization proceeded from the surface downward, with the accumulation of Al2O3 and residual ‘immobile’ elements (Al, Ti, HFSE), and corresponding mobility and loss of SiO2 and Fe2O3. Epigenetic kaolinite formed close to faults and joints, probably as a result of silicification, introduced by low temperature hydrothermal solutions. Rare earth elements, especially LREE, are concentrated in Fe-rich bauxite horizons, probably due to scavenging by goethite. REE-enrichment is not observed in the boehmite-rich horizons. Very high REE contents are observed in a Fe-depleted horizon due to the occurrence of REE accessory minerals, probably of the bastnäsite group. Conservative indices, including TiO2/Al2O3 and Ti/Cr ratios, and Eu anomalies (Eu/Eu*), suggest that the deposits formed by weathering of sediments derived from mafic rocks of the Hercynian basement. This, in turn, implies that the basement was exposed during middle Cretaceous.  相似文献   

7.
Bauxite deposits of Mainpat Plateau Surguja District, India, are composed of kaolinite, gibbsite, goethite, anatase, and bohemite. Quartz and micas are absent in the samples. The presence of boehmite and goethite are evidences of intense weathering during the formation of the bauxite deposits. The Mainpat Plateau is a mesa landform, at an elevation of around 1,060 m from msl in comparison to the general elevation of 580, consisting of Archaeans (granite?gneisses, phyllite, etc.) at the base, Gondwanas and Deccan basalt, and at the top having a cover of laterite and bauxite. The extremely high values of the chemical index of alteration, and the low values of the alkali metals and alkali earth metals, support an intense weathering origin for the bauxite deposit. There is evidence of deposition in the deposits based on the presence of pisoids in the bauxite samples and the composition of the parent rock. Kaolin minerals were first produced by the hydrolytic weathering of aluminous sediments and then gibbsite was formed as early kaolin was desilicated. The bauxite is having high TiO2 up to 17 %. The Mainpat laterite/bauxite deposits are characterized by having 50?58 % average Al2O3 and 10?30 % Fe2O3.  相似文献   

8.
Chemical, mineralogical, and petrographic data from the Los Pijiguaos bauxite deposit, together with the water chemistry of the streams draining the area, were used to study the problem of lateritic bauxite formation at this location. The Los Pijiguaos bauxite, located at the northwestern edge of the Guayana Shield in Venezuela, is a lateritic bauxite developed on a Precambrian Rapakivi Granite Batholith, the Parguaza Granite. This deposit is situated on a planation surface at elevations between 600 and 700 m; it is believed to have originated during an erosional event that took place during Late Cretaceous-early Tertiary times.The weathering profile is composed of an upper bauxite zone, followed by a saprolite, and merging gradually to the fresh granite. The upper bauxitic zone contains gibbsite, quartz, hematite, and goethite. The saprolite contains kaolinite, quartz, and goethite and is characterized by a relict granitic texture that indicates little bulk volume change associated with the weathering process. The upper bauxitic zone has lost any textural resemblance with the parent granite, consistent with extensive volume loss.Bauxite and saprolite are separated by a transition zone where gibbsite and kaolinite coexist. Textures indicating the replacement of kaolinite by gibbsite point to the dynamic nature of the weathering profile, characterized by advancing reaction fronts.The chemical composition of the deposit defines trends that can be traced back to the composition of the parent granite and shows enrichment of Al2O3, Fe2O3, and TiO2, and depletion of SiO2, relative to the parent granite. The uppermost part of the profile is characterized by a further enrichment of Fe2O3 with respect to the other components of the bauxite. Important volume and mass losses in the bauxite have also been calculated, based on chemical composition and density measurements. The calculated losses are consistent with the textural observations in the bauxite.The chemical composition of the waters of streams draining the area shows strong seasonal patterns, consistent with the seasonal nature of the local climate (one dry and one rainy season per year, both about six months long). The balance between dissolved and suspended loads in these streams indicates that the magnitudes of chemical and physical denudation are similar, leading to approximately constant thicknesses of the weathering profiles. These observations are consistent with model calculations based on current climatic conditions and suggest that the bauxitization process is still active.  相似文献   

9.
贵州新民铝土矿矿床Li的地球化学特征与富集机制探究   总被引：2，自引：2，他引：0  
龙珍  付勇  何伟  唐波  龙克树  刘阳  王天顺 《矿床地质》2021,40(4):873-889
新民铝土矿床位于黔北务川-正安-道真地区(简称务正道地区)大塘向斜东翼,铝土矿(岩)型Li资源丰富.含矿岩系大竹园组(P1d)不同岩性的w(Li)有差别:土状-半土状铝土矿平均w(Li)为16.34×10-6,致密块状铝土矿平均w(Li)是803.84×10-6,铝土岩平均w(Li)是1436.22×10-6,黏土岩的平均w(Li)是786.62×10-6,梁山组泥岩的平均w(Li)是51.82×10-,韩家店群泥岩(页岩)的平均w(Li)是48.52×10-6,黄龙组灰岩的平均w(Li)是 11.99×10-6.由此可知,研究区铝土矿(岩)型Li资源主要富集在含矿岩系中上部的致密块状铝土矿、铝土岩和黏土岩中,顶板、底板以及土状-半土状铝土矿w(Li)较低.Li主要赋存于高岭石中,伊利石(水云母)和残存的三水铝石、勃姆石也可富集少量Li,当样品中赋锂矿物(高岭石、伊利石(水云母)、三水铝石和勃姆石)都存在时,高w(Li),主量元素w(Al3O2)、w(SiO2)、w(MgO)、w(K2O)、w(TiO2)和w(TFe2O3)与w(Li)的相关性也证实了上述结果.研究区的地球化学比值 CIA、w(Sr)/w(Cu)、u(CaO)/w(MgO)、w(Sr)/w(Ba)、w(V)/w(V+Ni)和 w(La)/w(Y)综合显示,炎热潮湿的古气候下,有机质腐烂形成酸性环境,半封闭海湾环境下,黏土化阶段中等强烈的化学风化程度和适宜的风化暴露剥蚀时间利于铝硅酸盐矿物和硅酸盐矿物化学键断裂,富集Al3+形成高岭石;风化程度过于强烈和长时间的风化剥蚀,继续脱Si富Al形成以硬水铝石为主的铝土矿;弱酸性-弱碱性以及氧化-还原过渡条件下,使得高岭石能最大程度的吸附Li元素.  相似文献   

10.
Karstic bauxite deposits are widespread in Central Guizhou Province, SW China, and high-grade ores are frequently sandwiched with overlying coal and underlying iron-rich layers and form a special “coal–bauxite–iron” structure. The Lindai deposit, which is one of the most representative karstic bauxite deposits in Central Guizhou Province, was selected as a case study. Based on textural features and iron abundances, bauxite ores in the Lindai deposit are divided into three types of ores, i.e., clastic, compact, and high-iron. The bauxite ores primarily comprise diaspore, boehmite, kaolinite, illite, and hematite with minor quartz, smectite, pyrite, zircon, rutile, anatase, and feldspar. The Al2O3 (53–76.8 wt.%) is the main chemical contents of the bauxite ore samples in the Lindai district, followed by SiO2, Fe2O3, TiO2, CaO, MgO, S, and P etc. Our geological data on the Lindai deposit indicated that the ore-bearing rock series and its underlying stratum have similar rare earth elements distribution pattern and similar Y/Ho, Zr/Hf, and Eu/Eu1 values; additionally, all ore-bearing rock samples are rich in MgO (range from 0.16 wt.% to 0.68 wt.%), and the plots of the dolomites and laterites lie almost on or close to the weathering line fit by the Al-bearing rocks in Zr vs. Hf and Nb vs. Ta diagrams; suggesting that the underlying Middle Cambrian Shilengshui Formation dolomite is the parent rock of bauxite resources in the Lindai district.Simulated weathering experiments on the modern laterite from the Shilengshui Formation dolomite in the Lindai bauxite deposit show that hydrogeological conditions are important for karstic bauxite formation: Si is most likely to migrate, its migration rate is several magnitudes higher than those of Al and Fe under natural conditions; the reducing inorganic acid condition is the most conducive to Al enrichment and Si removal; Fe does not migrate easily in groundwater, Al enrichment and Fe removal can occur only in acidic and reducing conditions with the presence of organic matter.The geological and experimental studies show that “coal–bauxite–iron” structure in Lindai deposit is formed under certain hydrogeological conditions, i.e., since lateritic bauxite or Al-rich laterite deposited upon the semi-closed karst depressions, Si can be continuously removed out under neutral/acidic groundwater conditions; the coal/carbonaceous rock overlying the bauxitic materials were easily oxidized to produce acidic (H2S, H2SO4, etc.) and reductant groundwater with organic materials that percolated downward, resulting in enrichment of Al in underlying bauxite; it also reduced Fe3+ to its easily migrating form Fe2+, moving downward to near the basal carbonate culminated in precipitating of ferruginous (FeS2, FeCO3, etc.) strata of the “coal–bauxite–iron” structure. Thus, the bauxitic materials experienced Al enrichment and Si and Fe removal under above certain hydrogeological conditions forming the high-quality bauxite.  相似文献   

11.
This study deals with the mineralogical and geochemistry of the Euphrates Formation (Lower Miocene) in Bahr Al-Najaf area in order to assess the lithofacies of the Euphrates Formation for Portland cement manufacturing. Petrographic and mineralogical studies were carried out on 210 core samples, collected from 21 boreholes, and showed that calcite is the dominant mineral with few amounts of quartz, gypsum, feldspar, and a rare amount of dolomite. Clay mineral suites (palygorskite, kaolinite, montmorillonite, and illite) formed about 5% from the total mineral composition. Palygorskite precipitated directly in alkali shallow water rich with Si and Mg ions. Chemical weathering of feldspar under acidic conditions participated in formation of Kaolinite. Geochemistry showed that there is no high variation in chemical constituents with depth, and the average of CaO (51.5), MgO (0.83), SO3 (0.54), SiO2 (4.3), Fe2O3 (0.45), Al2O3 (0.93), L.O.I (40.7), Na2O3 (0.08), K2O (0.14), and Cl- (0.1) qualified the lithofacies of Euphrates Formation to be raw materials suitable for manufacturing the Portland cement. Triangle Block method is applied to estimate the reserve on square area (2?×?2 km2) which is computed to be 63 million tons of medium-tough limestone as potential probable reserve.  相似文献   

12.
This article reports our new interpretations of the depositional environment and provenance of the Dawashan Formation in the Longmuco–Shuanghu–Lancangjiang suture zone (LSLSZ), in the Southern Qiangtang terrane of northern Tibet, in order to gain a better understanding of the Ordovician tectonic evolution of the northern margin of Gondwana. The Dawashan Formation is dominated by greywacke and shale, with interlayered bimodal volcanic rocks that were deposited in a bathyal to abyssal marine basin. The detrital zircons in the greywacke of the Dawashan Formation have peak ages of 550, 988, 1640, and 2500 Ma, indicating a northern Gondwana margin provenance. The bimodal metavolcanic rocks from the Dawashan Formation are dominated by metarhyolite with subordinate metabasalt. The results of zircon LA-ICP-MS U–Pb dating indicate that the metarhyolite formed between 470 and 455 Ma. The metavolcanic samples are bimodal (SiO2 = 45.27–55.05 and 66.09–74.59 wt.%). In comparison, the metabasalt has a wide range of MgO concentrations and Mg# values, contains variable Cr and low Ni concentrations, is depleted in Rb, Ba, and Sr, and is enriched in TiO2, Th, U, Nb, and Ta. Geochemical diagrams show that the metabasalt erupted in an intra-plate environment. The metarhyolites have high SiO2, Th, and U concentrations, low concentrations of MgO, P2O5, Nb, Sr, and Ti, and negative Eu anomalies. The metarhyolites yield negative zircon εHf(t) values (–2.08 to – 4.50) and TCDM model ages of 1436–1567 Ma. The metarhyolites formed from magma derived from the partial melting of old continental crust. These data indicate that the Dawashan Formation records Middle–Upper Ordovician bathyal to abyssal turbidite deposition in a deep-water rift basin at the northern margin of Gondwana.  相似文献   

13.
A series of significant geological changes indicated by deformation, magmatic–metallogenic systems, and the climate and environment occurred in East Asia during Late Jurassic to Early Cretaceous time, but the timing and development of the ‘Yanshan movement’ on the north margin of the North China Craton has not been well-established. Based on the evidence of tectonic deformation and magmatic activity, previous studies resulted in two views of the beginning of the Yanshan movement: Early Jurassic vs. late Middle Jurassic. In this work, the timing of the initial Yanshan movement was investigated by examining the Jurassic Chenjiabangou section in the Ningwu–Jingle basin overlying the north-central part of the North China Craton. The timing of the initial Yanshan movement was constrained by restoration of stream flow directions, determination of boundaries of sedimentary cycles, identification of heavy mineral assemblages in clastic rocks, quantification of changes in chemical compositions, and zircon U–Pb isotope dating. The results indicate that the basal conglomerates of the Middle Jurassic Yungang Formation (Bathonian) mark the beginning of the Yanshan movements. Evidence supporting this conclusion includes the following. (1) The switch from transgressive lacustrine deposition to regressive lacustrine deposition in the Yungang Formation sedimentary succession indicates a change from extension to compression, possibly reflecting uplift. (2) Early-stage clastic rocks rich in quartz and feldspar are replaced by feldspar detritus in late-stage clastic rocks; the heavy mineral assemblage dominated by zircon at the early stages changed to garnet-dominated assemblage upsection. Moreover, the concentrations of CaO, MgO, CO2, and Fe2O3 + FeO and the Fe2O3/FeO ratio changed abruptly near the basal conglomerates of the Middle Jurassic Yungang Formation, suggesting increased denudation. (3) Conglomerates at the bottom of the Middle Jurassic Yungang Formation were deposited approximately 168 million years ago, as inferred from the age of zircons in tuffaceous micrite (160.6 ± 0.55 Ma) at the bottom of the Upper Jurassic Tianchihe Formation (Oxfordian) and the age of zircons in pyroclastic rocks (179.2 ± 0.79 Ma) in the Lower Jurassic Yongdingzhuang Formation (Toarcian). These lines of evidence indicate that initial Jurassic Yanshan movement began 168 million years ago during Middle Jurassic time.  相似文献   

14.
The Jurassic succession of western Iraq includes the Ubaid, Hussainiyat, Amij, Muhaiwir, and Najmah formations. Each formation is composed of basal clastic unit overlain by upper carbonate unit. Extensive and huge erosional unconformity occurred at the Triassic–Jurassic boundary due to marked shifting of structural (E–W) strike of the Triassic (Rhaetic) Zor Hauran Formation to (NE–SW) Jurassic formations. Sea level falling (lowstand system tracts) would result in the progradation of the land on the expense of the sea forming the recognizable progradation of the fluvial and deltaic deposits of the lower clastic units of the Jurassic formations, whereas sea level rising (highstand system tract), i.e., sea prograding, causes deposition of the carbonate units of the Jurassic formations system. This progradation resulted to various carbonate environments of deposition ranging from subtidal, intertidal, to supratidal. The main target on most of the exploration blocks in the western part of Iraq focused on the lower Paleozoic successions, whereas prospects in Triassic, Jurassic, and lower Cretaceous targets are less extensive but may have significant potential on certain blocks in both stratigraphic and structural traps. The western part of Iraq was subjected to intermittent pulses of uplifting (sea regression) and subsidence (sea transgression) to form the Jurassic basin system in the area. The Jurassic formations lack the characteristics of petroleum systems. In contrast, in the central and northern parts of Iraq, the Jurassic formations (Najmah and Gotnia formations) were deposited in subsiding basins in which the reservoir and sealed evaporitic rocks existed. In turn, in the western desert of Iraq, the Jurassic formations lack these petroleum system characteristics. Hence, it can be proposed that the petroleum–nonpetroleum inflection could be proposed in the east of area km 160.  相似文献   

15.
山西省石墙区铝土矿地质与地球化学特征研究   总被引：2，自引：0，他引：2  
孙思磊 《地质与勘探》2012,48(3):487-501
[摘 要]山西省原平市石墙区铝土矿属于典型的喀斯特型铝土矿。含矿岩系自下而上包括铁质粘土层、铝土矿层、粘土层,且含矿岩系一般包含两个明显的沉积旋回。矿体主体呈层状、似层状产出,矿石结构以隐晶质结构为主,局部出现碎屑和豆鲕粒结构。矿石构造大都为块状构造。矿物学分析显示,硬水铝石、针铁矿、锐钛矿、高岭石是主要的组成矿物,另外还含有石英、伊利石、绿泥石等矿物。地球化学分析显示,主量元素主要包括Al2O3、SiO2、Fe2O3、H2O+及TiO2,微量元素中碱性和碱土元素Li、Sr、Be、Cs、Ba 及酸土元素Zr、Hf、Nb、Ta、W 均表现为明显富集,且Zr 和Hf 之间以及Nb 和Ta 之间具有高度的相关性。地球化学指标Zr/ Hf、Nb/ Ta 以及Eu/ Eu*- TiO2/ Al2O3图解显示,底板碳酸盐岩是山西省原平市石墙区铝土矿的重要源岩。  相似文献   

16.
Epidote-bearing porphyritic dikes (whole rock analysis: SiO2?=?55–65 wt. %, MgO <2.1 wt. %, K2O <2.5 wt. %, Al2O3 >17 wt. %, Na2O + K2O?=?5.7–9.4 wt. %) situated in the continental margin zone, the Middle Urals, Russian Federation have been dated using SHRIMP U-Pb zircon techniques and give a Middle Devonian age of 388?±?2 Ma and 389?±?6 Ma. The porphyries contain phenocrysts of magmatic epidote (Ps?=?17–25 %), Ca- and Mn-rich (CaO >9 wt. %; MnO >6 wt. %) almandine garnet, Al-rich (Al2O3?=?12–16 wt. %) amphibole, titanite, plagioclase, biotite, muscovite, apatite, and quartz. 60 to 70 % groundmass of the porphyritic dikes consists of fine-grained albite, quartz, and K-feldspar. A variety of thermobarometric estimations, plus comparison with published experimental data indicate that the phenocryst assemblage was stable between 5 and 11 kbar and 690 to 800 °C. Oxygen fugacity was close to or greater than logfo2 = Ni-NiO + 1. Later stage formation of the quartz-feldspar groundmass took place at hypabyssal conditions, corresponding to 1 to 2 kbar and 660 to 690 °C. The porphyritic dikes are metaluminous to slightly peraluminous (ACNK?=?0.7–1.17). They are enriched in REE and depleted Nb and Ti. They show features typical of subduction-related magmas. Chemical composition and isotopic ratios of 86Sr/87Sri?=?0.709–0.720 suggest that both mantle- and deep crustal-derived materials were involved in their petrogenesis.  相似文献   

17.
Isobaric (200 MPa) experiments have been performed to investigate the effects of H2O alone or in combination with P, S, F or Cl on liquid-phase separation in melts in the systems Fe2SiO4–Fe3O4–KAlSi2O6–SiO2, Fe3O4–KAlSi2O6–SiO2 and Fe3O4–Fe2O3–KAlSi2O6–SiO2 with or without plagioclase (An50). Experiments were heated in a rapid-quench internally heated pressure vessel at 1,075, 1,150 or 1,200 °C for 2 h. Experimental fO2 was maintained at QFM, NNO or MH oxygen buffers. H2O alone or in combination with P, S or F increases the temperature and composition range of two-liquid fields at fO2 = NNO and MH buffers. P, S, F and Cl partition preferentially into the Fe-rich immiscible liquid. Two-liquid partition coefficients for Fe, Si, P and S correlate well with the degree of polymerization of the SiO2-rich liquid and plot on similar but distinct power-law curves compared with equivalent anhydrous or basaltic melts. The addition of 2 wt% S to the system Fe3O4–Fe2O3–KAlSi2O6–SiO2 stabilizes three immiscible melts with Fe-, FeS- and Si-rich compositions. H2O-induced suppression of liquidus temperatures in the experimental systems, considered with the effects of pressure on the temperature and composition ranges of two-liquid fields in silicate melts, suggests that liquid-phase separation may be stable in some H2O-rich silicate magmas at pressures in excess of 200 MPa.  相似文献   

18.
《International Geology Review》2012,54(13):1626-1640
Dolerite dike swarms are widespread across the North China Craton (NCC) of Hebei Province (China) and Inner Mongolia. Here, we report new geochemical, Sr–Nd–Pb isotope, and U–Pb zircon ages for representative samples of these dikes. Laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) U–Pb analysis yielded consistent Permian ages of 274.8 ± 2.9 and 275.0 ± 4.5 Ma for zircons extracted from two dikes. The dolerites have highly variable compositions (SiO2 = 46.99–56.18 wt.%, TiO2 = 1.27–2.39 wt.%, Al2O3 = 14.42–16.20 wt.%, MgO = 5.18–7.75 wt.%, Fe2O3 = 8.03–13.52 wt.%, CaO = 5.18–9.75 wt.%, Na2O = 2.46–3.79 wt.%, K2O = 0.26–2.35 wt.%, and P2O5 = 0.18–0.37 wt.%) and are light rare earth element (LREE) and large ion lithophile element (LILE, e.g. Rb, Ba, and K, and Pb in sample SXG1-9) enriched, and Th and high field strength element (HFSE, e.g. Nb and Ta in sample SXG1-9, and Ti) depleted. The mafic dikes have relatively uniform (87Sr/86Sr)i values from 0.7031 to 0.7048, (206Pb/204Pb)i from 17.77 to 17.976, (207Pb/204Pb)i from 15.50 to 15.52, (208Pb/204Pb)i from 37.95 to 38.03, and positive ?Nd(t) (3.6–7.3), and variable neodymium model ages (TDM1 = 0.75–0.99 Ga, TDM2 = 0.34–0.74 Ga). These data suggest that the dike magmas were derived from partial melting of a depleted region of the asthenospheric mantle, and that they fractionated olivine, pyroxene, plagioclase, K-feldspar, and Ti-bearing phases without undergoing significant crustal contamination. These mafic dikes within the NCC formed during a period of crustal thinning in response to extension after Permian collision between the NCC and the Siberian Block.  相似文献   

19.
Major element compositions and chemical weathering features of the purple soils and their corresponding rocks in the Red Sichuan Basin, China were studied in this paper to infer the diagenetic features of the purple rocks and the pedogenetic features of the purple soils. The results showed that all of the rock and soil samples, except those from Yibin, have strongly similar major element compositions and the distribution patterns of their major element compositions are similar to those of the upper continental crust. Chemical index of alteration, chemical index of weathering and Na2O/K2O indicate that the purple soils and rocks have similar chemical weathering intensities, whereas the Al2O3–CaO* + Na2O–K2O (A–CN–K) relationship, suggests that chemical weathering was strong during diagenesis of the purple rocks, but weak during pedogenesis of the purple soils. Variations in major element compositions of the purplish rock samples, except that from Yibin, do not primarily reflect differences in compositions of the sediment source, sediment recycling and potassium metasomatism, and therefore the effects of chemical weathering on the major element compositions were mainly dependent on climate condition and the residence time of material exposed to chemical weathering. Chemical weathering of the purple rocks reached only moderate degrees under the general influence of warm and humid climate during Jurassic and Cretaceous. Warmer and more humid climate conditions partly resulted in stronger chemical weathering of rocks in the southern region of the basin than in the central and western region, whereas shorter residence time of material in upslope position partly resulted in weaker chemical weathering of rocks in the eastern region than in the central and western region. The same climate and stable tectonic setting led to comparable chemical weathering intensities of rocks in the Ziliujing and Jiaguan Formations. Gradually colder and dryer climate from Early Jurassic to Middle Jurassic then to Late Jurassic and shorter residence time in tectonically active setting of Middle Jurassic and late Late Jurassic resulted in the following order of chemical weathering intensity of the purple Jurassic rocks: Ziliujing Formation ? Shaximiao Formation ≈ Suining Formation > Penglaizhen Formation.  相似文献   

20.
Bauxite deposits in the Usambara Mountains of north eastern Tanzania occur as remnants of residual deposits on two geomorphologically related plateaus of Mabughai-Mlomboza and Kidundai at Magamba in Lushoto, Usambara Mountains. The parent rocks for the deposits are mainly granulites and feldspathic gneisses of Neoproterozoic Mozambique belt. The plateaus represent a preserved Late Cretaceous–Lower Tertiary old land surface (African surface). Other parts of the Usambara Mountains and the neighbouring Pare Mountains are covered mostly by red–brown lateritic soils and impure reddish-brown kaolinitic clays. The bauxite deposits contain mainly Al2O3 (40–69 wt.%), Fe2O3 (3–10 wt.%), SiO2 (0.16–7 wt.%) and other elements occur in quantities not substantial to affect the quality or processing of the bauxite, and are attributed to the presence of relic minerals. Gibbsite makes up to 98 vol.% of the bauxite ore in special cases. Gibbsite is accompanied by goethite in the ore. Boehmite occurs in small amounts and is usually accompanied by hematite. Impurities include goethite, hematite, kaolinite, and minor relic quartz and microcline. Kaolinite is the sole clay mineral encountered in the bauxite ore, suggesting mature soil profiles and a development of the bauxite deposits on a well-drained peneplanation. Ore reserve estimates from the drilling data and surface geological mapping of the deposits yielded bauxite reserves of about 37 million tonnes.  相似文献   

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