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1.
Proximal and distal lithogeochemical alteration patterns associated with precious-metal and polymetallic vein mineralization in the Andes of Bolivia and Peru are delineated both by sulphophile elements such as Ag, As, Pb, S, Sb, Sn and Zn, and also by hydrothermal alteration indicators such as CaO/MgO, K2O/Na2O, Rb/K and Rb/Sr. In some cases, single-element, ratio and normalized data additive plots permit the detection of a vein at a distance of more than 100 m even when the visible alteration extends for less than 10 m. Asymmetric hanging-wall-footwall halos in both volcanic and sedimentary rocks provide a useful supra-ore/sub-ore indicator for inclined veins. The K2O/Na2O ratio appears to be the most reliable lithogeochemical guide to ore-related hydrothermal alteration.  相似文献   

2.
There are two main granitic rocks cropping out in the study area:1) the syn-orogenic granites are moderately weathered,jointed,exfoliated and characterized by low relief.These rocks are subdivided into tonalite and granodiorite.They are essentially composed of plagioclase,quartz,biotite,hornblende and potash feldspar;and 2) the post-orogenic granites,characterized by high relief terrain and represented by monzogranite,syenogranite and alkali granite.The monzogranites suffered hydrothermal alteration in particular along joints,faults,shear zones and fractures,which recorded the highest values of radioactivity,reflecting the role of post-magmatic alteration processes in the enhancement of radioactivity.The hydrothermal alteration(desilicification and hematitization) resulted in the formation of mineralized(altered) granites.The altered granites are enriched in TiO 2,Al 2 O 3,FeO T,MnO,MgO,Na 2 O,Rb,Sr,Y,Zr,Zn,Ga and Co and depleted in SiO 2,CaO,P 2 O 5,Nb,Pb,Cu,Ni and Cr relative to the fresh monzogranite.The investigated granites contain basic xenoliths as well as pockets of pegmatites.Perthites,quartz,plagioclase and sometimes biotite,represent the essential constituents.Some accessory minerals like zircon are metamicted reflecting their radiogenic nature.The alkali granites are characterized by the presence of aegirine,rebeckite and arfvedsonite.Both syn-and post-orogenic granites show some variations in their bulk chemical compositions.The older granitoids are metaluminous and exhibit characteristics of I-type granites and possess an arc tectonic environment.On the other hand,the younger granites are peraluminous and exhibit the characteristics of post-collisional granites.It is interpreted that radioactivity of the studied rocks is mainly controlled by both magmatic and post-magmatic activities.Frequently,the post-orogenic granites host zoned and unzoned pegmatite pockets.Some of these pockets anomalously attain high radioactivity.The syenogranites and the pegmatites are characterized by high contents of SiO 2 and K 2 O and low CaO and MgO.They have transitional characters from highly fractionated calc-alkaline to alkaline.The alkali granites related to A2-subtype of A-type granites.The post-orogenic granites were originated from magma of dominant crustal source materials and related to post-collisional setting under extensional environment.  相似文献   

3.
The textural relationships and geochemistry of feldspars from least-altered to sericite-hematite altered and mineralised ~ 1.595 Ga Roxby Downs Granite (RDG) at Olympic Dam, South Australia, were examined. The sample suite is representative of RDG both distal (> 5 km) and proximal (< 1 km) to the hydrothermal breccias of the Olympic Dam Breccia Complex (ODBC), which host Fe-oxide Cu-Au-(U) mineralisation at Olympic Dam. Microscopic observations and quantitative analyses indicate that a range of feldspar reactions have taken place within the RDG hosting the Olympic Dam deposit. An early phase of igneous plagioclase (~ An27–34) is recognised, along with a more abundant, less-calcic plagioclase (~ An12–20) both displaying rapakivi and anti-rapakivi textures with alkali feldspar. Alkali feldspars (~ Or55Ab43An2) record post-magmatic evolution from cryptoperthite to patch perthite. Subsequent patch perthite is overprinted by highly porous, near end-member albite and K-feldspar, while plagioclase undergoes replacement by albite + sericite ± Ba-rich K-feldspar. In sericite-hematite altered and mineralised RDG along the margin of the ODBC, sericite replaces all plagioclase, whereas red-stained, Fe-rich K-feldspar persists. Sulphide-uranium-rare earth element mineralisation is observed in association with hydrothermal feldspars, and increases in abundance with proximity to the orebody. Petrographic observations and whole-rock geochemistry illustrate the transformation of plagioclase and alkali feldspar from igneous to hydrothermal processes, and indicate that hydrothermal albite and K-feldspar formed within the RDG without the need for an external source of alkalis. Feldspar geothermometry indicates a minimum crystallisation temperature of 765 °C at 2.2 kbar for alkali feldspar (pressure estimate obtained using plagioclase-amphibole geobarometry) followed by a range of lower temperature transformations. Late-stage magma mixing/contamination is postulated from supportive temperature and pressure estimates along with feldspar and mafic mineral relationships.  相似文献   

4.
分布在汪清县六道崴子地区的碱长花岗岩,研究后认为是A型花岗岩。其特征是具晶洞构造,钾长石是中正微长石,斜长石为钠长石(An=1),SiO2、K2O、Na2O质量分数较高,CaO、MgO质量分数较低。∑REE质量分数为139.3,δEu为0.14,亏损十分明显,是非造山期拉张构造环境形成的碱性花岗岩。  相似文献   

5.
The bulk compositions of the groundmass alkali feldspar from the Hell Canyon Pluton is 0.146mole% albite. The composition of the outermost zone of the oscillatory zoned plagioclase is 0.686 mole% albite, whereas the most calcic cores have a composition of 0.43 mole% albite. The structural state of the alkali feldspar is near orthoclase. Both composition of coexisting feldspars and structural state of the alkali feldspar are nearly constant throughout the pluton.Exsolved albite in the alkali feldspar have a composition of 0.965 mole% albite and the orthoclase host has a composition of 0.032 mole%. Singe crystal X-ray studies indicate that the albite intergrowths are coherent with the host.Equilibrium temperatures derived from the coexisting feldspar average 554 ° C; about 150 ° C, too low for the minimum solidus temperatures for reasonable emplacement pressures (2 kb). If this minimum solidus temperature is assumed, then the alkali feldspar has lost about 0.15 mole% albite. This loss was most likely caused by hydrothermal solutions associated with the crystallizing magma and equilibrated at about 550 ° C. However, based on the coherent albite intergrowths and the orthoclase structure state it can be inferred that the system was relatively free of volatiles below 500 ° C. Final equilibirium between orthoclase host and albite intergrowths occurred at about 311 ° C.  相似文献   

6.
The evaluation of the relatively fresh host rock and altered rock samples associated with the Pantingan Gold System exposed in Mount Mariveles, Bataan yield several notable observations that are useful in pinpointing potential gold pathfinder elements. Geochemical and petrologic analysis showed that the altered rocks can be subdivided into rocks that underwent propylitic alteration (group 1), argillized rocks with silica contents similar to those of the fresh host rocks (group 2), argillized but not strongly silicified rocks (group 3) and argillized and strongly silicified rocks (group 4). Selected element ratio patterns in the altered rocks and gold concentrations in gold‐bearing quartz veins vary between the rock groups. Moreover, mass balance calculation also reflected the geochemical observations pertaining to the gains and losses of SiO2, Fe2O3+ MgO, CaO + Na2O and K2O, which are believed to be chemical reactions (i.e. breakdown of plagioclase, silica inundation or leaching, sulfide and calcite formation) caused by the influx of hydrothermal fluids.  相似文献   

7.
Abstract Microprobe analyses of feldspars in granite mylonites containing flame perthite give compositions that invariably plot as three distinct clusters on a ternary feldspar diagram: orthoclase (Or92–97), albite and oligoclase-andesine. The albite occurs as grains in the matrix, as flame-shaped lamellae in orthoclase, and in patches within plagioclase grains. We present a metamorphic model for albite flame growth in the K-feldspar in these rocks that is related to reactions in plagioclase, rather than alkali feldspar exsolution. Flame growth is attributed to replacement and results from a combination of two retrograde reactions and one exchange reaction under greenschist facies conditions. Reaction 1 is a continuous or discontinuous (across the peristerite solvus) reaction in plagioclase, in which the An component forms epidote or zoisite. Most of the albite component liberated by Reaction 1 stays to form albite in the host plagioclase, but some Na migrates to form the flames within the K-feldspar. Reaction 2 is the exchange of K for Na in K-feldspar. Reaction 3 is the retrograde formation of muscovite (as ‘sericite’) and has all of the chemical components of a hydration reaction of K-feldspar. The Si and Al made available in the plagioclase from Reaction 1 are combined with the K liberated from the K-feldspar, to produce muscovite in Reaction 3. The muscovite forms in the plagioclase, rather than the K-feldspar, as a result of the greater mobility of K relative to Al. The composition of the albite flames is controlled by both the peristerite and the alkali feldspar miscibility gaps and depends on the position of these solvi at the pressure and temperature that existed during the reaction. Using an initial plagioclase composition of An20, the total reaction can be summarized as: 20 oligoclase + 1 K-feldspar + 2 H2O = 2 zoisite + muscovite + 2 quartz + 15 albiteplagioclase+ 1 albiteflame. This model does not require that any additional feldspar framework be accreted at replacement sites: Na and K are the only components that must migrate a significant distance (e.g. from one grain to the next), allowing Al to remain within the altering plagioclase grain. The resulting saussuritization is isovolumetric. The temperature and extent of replacement depends on when, and how much, water infiltrates the rock. The fugacity of the water, and therefore the pressure of the fluid, may have been significantly lower than lithostatic during flame growth.  相似文献   

8.
Diorite plutons at Al Hadah Saudi Arabia, which constitute part of the pan-African magmatic sequence (ca. 600 Ma), exhibit extensive development of epidote. The epidote alteration is concentrated along veins and dyke margins, and is characterised by transformation of plagioclase (Ab 67)+hornblende+biotite+quartz to epidote+hornblende+tremolite−actinolite+plagioclase (Ab 99)±quartz. The reactions involve addition of CaO and total Fe2O3, depletion of MgO, Na2O and K2O, with variable gains or losses of SiO2. Epidotised alteration products are hydrated and oxidised relative to the diorite precursor. The whole rock δ18O of fresh diorite is + 8.2‰ to + 8.8‰, whereas epidote domains have δ18O whole rock of +9.8‰ to +10.48‰ and negative Δ18Oquartz-plagioclase, implying oxygen isotope exchange with fluids at low temperatures. Epidotisation is considered to have accompanied influx of fluids into plutons during cooling and contraction. The fluids were probably deep formation waters with relatively high Ca2+/Na+ ratios, moving up thermal gradient.  相似文献   

9.
Robert J. Stull 《Lithos》1978,11(3):243-249
Mantled feldspars that formed by resorption, development of skeletal plagioclase crystals, and filling with alkali feldspar are common in the Golden Horn batholith, Washington. Subhedral plagioclase mantles have weak normal zoning from An17 to An10. Plagioclase zoning and twinning are crosscut by resorption channels. Resorption cavities and channels are coated with albite (An10). Anhedral, perthitic orthoclase within the plagioclase is optically continuous with orthoclase in channels and on the mantle exterior.This texture resulted from resorption of calcic cores of plagioclase as pressure decreased when water-undersaturated granite magma intruded to a shallow crustal level. At shallow level, only alkali feldspar and quartz crystallized and were available to fill the skeletal plagioclase.  相似文献   

10.
Phase relations of natural aphyric high-alumina basalts and their intrusive equivalents were determined through rock-melting experiments at 2 kb, H2O-saturated with fO2 buffered at NNO. Experimental liquids are low-MgO high-alumina basalt or basaltic andesite, and most are saturated with olivine, calcic plagioclase, and either high-calcium pyroxene or hornblende (±magnetite). Cr-spinel or magnetite appear near the liquidus of wet high-alumina basalts because H2O lowers the appearance temperature of crystalline silicates but has a lesser effect on spinel. As a consequence, experimental liquids follow calcalkaline differentiation trends. Hornblende stability is sensitive to the Na2O content of the bulk composition as well as to H2O content, with the result that hornblende can form as a near liquidus mineral in wet sodic basalts, but does not appear until liquids reach andesitic compositions in moderate Na2O basalts. Therefore, the absence of hornblende in basalts with low-to-moderate Na2O contents is not evidence that those basalts are nearly dry. Very calcic plagioclase (>An90) forms from basaltic melts with high H2O contents but cannot form from dry melts with normal are Na2O and CaO abundances. The presence of anorthite-rich plagioclase in high-alumina basalts indicates high magmatic H2O contents. In sum, moderate pressure H2O-saturated phase relations show that magmatic H2O leads to the early crystallization of spinel, produces calcic plagioclase, and reduces the total proportion of plagioclase in the crystallizing assemblage, thereby promoting the development of the calc-alkaline differentiation trend.  相似文献   

11.
The Parnell Quartz Monzonite in the Pilbara Block of Western Australia is a Proterozoic (1731 ± 14 Ma) pluton characterized by high modal K‐feldspar and a greater abundance of hornblende relative to biotite, as is typical of Phanerozoic monzonitic rocks in eastern Australia. The only geochemical features reflecting its setting in an Archaean terrain are high Na2O, Ni and Cr. The pluton is zoned, with an increase in K‐feldspar, quartz and biotite and a decrease in plagioclase and hornblende from margin to core. Chemically, this zoning is reflected by systematic variation of CaO, K2O, Na2O, Sr and Rb, but ferromagnesian elements have irregular trends, implying preferential extraction of feldspars relative to mafic minerals during differentiation of the magma. The unusual geochemical trends are explained by a model involving ‘in situ’ feldspar fractionation of a K‐rich residual liquid from a mafic crystalline mush.

A parent magma similar to the average rock composition of the pluton is deduced because high ferromagnesian trace element abundances preclude extensive fractionation of mafic minerals. Geochemical and isotopic constraints suggest that the ultimate source was chemically similar to a shoshonitic basaltic andesite, that must have been emplaced beneath the eastern margin of the Pilbara Block in the Early Proterozoic. Subsequent partial melting of this postulated underplated source at ～ 1700 Ma to produce the Parnell Quartz Monzonite was probably associated with tectonism in the Gregory Range Complex.  相似文献   

12.
Early Archean (3.46 Ga) hydrothermally altered basaltic rocks exposed near Marble Bar, eastern Pilbara Craton, have been studied in order to reveal geological and geochemical natures of seafloor hydrothermal carbonatization and to estimate the CO2 flux sunk into the altered oceanic crust by the carbonatization. The basaltic rocks are divided into basalt and dolerite, and the basalt is further subdivided into type I, having original igneous rock textures, and type II, lacking these textures due to strong hydrothermal alteration. Primary clinopyroxene phenocrysts are preserved in some part of the dolerite samples, and the alteration mineral assemblage of dolerite (chlorite + epidote + albite + quartz ± actinolite) indicates that the alteration condition was typical greenschist facies. In other samples, all primary minerals were completely replaced by secondary minerals, and the alteration mineral assemblage of the type I and type II basalts (chlorite + K-mica + quartz + carbonate minerals ± albite) is characterized by the presence of K-mica and carbonate minerals and the absence of Ca-Al silicate minerals such as epidote and actinolite, suggesting the alteration condition of high CO2 fugacity. The difference of the alteration mineral assemblages between basalt and dolerite is probably attributed to the difference of water/rock ratio that, in turn, depends on their porosity.Carbonate minerals in the carbonatized basalt include calcite, ankerite, and siderite, but calcite is quite dominant. The δ13C values of the carbonate minerals are −0.3 ± 1.2‰ and mostly within the range of marine carbonate, indicating that the carbonate minerals were formed by seafloor hydrothermal alteration and that carbonate carbon in the altered basalt was derived from seawater. Whole-rock chemical composition of the basaltic rocks is essentially similar to that of modern mid-ocean ridge basalt (MORB) except for highly mobile elements such as K2O, Rb, Sr, and Ba. Compared to the least altered dolerite, all altered basalt samples are enriched in K2O, Rb, and Ba, and are depleted in Na2O, reflecting the presence of K-mica replacing primary plagioclase. In addition, noticeable CO2 enrichment is recognized in the basalt due to the ubiquitous presence of carbonate minerals, but there was essentially neither gain nor loss of CaO. This suggests that the CO2 in the hydrothermal fluid (seawater) was trapped by using Ca originally contained in the basalt. The CaO/CO2 ratios of the basalt are generally the same as that of pure calcite, indicating that Ca in the basalt was almost completely converted to calcite during the carbonatization, although Mg and Fe were mainly redistributed into noncarbonate minerals such as chlorite.The carbon flux into the Early Archean oceanic crust by the seafloor hydrothermal carbonatization is estimated to be 3.8 × 1013 mol/yr, based on the average carbon content of altered oceanic crust of 1.4 × 10-3 mol/g, the alteration depth of 500 m, and the spreading rate of 1.8 × 1011 cm2/yr. This flux is equivalent to or greater than the present-day total carbon flux. It is most likely that the seafloor hydrothermal carbonatization played an important role as a sink of atmospheric and oceanic CO2 in the Early Archean.  相似文献   

13.
Summary A number of small Palaeoproterozoic granitoid plutons were emplaced in the Khetri Copper Belt, which is an important Proterozoic metallogenic terrane in the northeastern part of Aravalli mountain range. Contiguous Biharipur and Dabla plutons are located about 15 km southeast of Khetri, close to a 170 km long intracontinental rift zone. The plutons are composed of amphibole-bearing alkali-feldspar granites, comprising microcline-albite granite, albite granite and late-stage microgranite. The albite granite in Biharipur is confined to the margins of the pluton, and shows extensive commingling with the synchronous mafic plutonics. Geochemically, the albite granites are characterised by low K2O (∼0.5 wt.%) and elevated Na2O (∼7.0 wt.%) abundances. By contrast, the microcline-albite granite does not show any significant mafic-granite interactions and shows normal concentrations of alkali elements. The granitoids display high concentrations of the rare earth (except Eu) and high field strength elements, high values of Ga/Al (>2.5), agpaitic index and Fe*-number. These features together with their alkaline metaluminous and ferroan nature classify the rocks as typical A-type within-plate granites. All the granitoid facies display similar REE and incompatible element profiles indicating their cogenetic nature. These granitoids were emplaced in a shallow crustal chamber under relatively low pressures, high temperature (≥850 °C) and relatively oxidising conditions. The oxidised nature, HFSE concentrations and Nd isotope data (ɛNd = −1.3 to −2.9) favour derivation of these granitoid rocks from crustal protoliths. The generation of albite granite is attributed to the replacement of alkali feldspar and plagioclase of the original granite by pure albite as a consequence of pervasive infiltration of a high Na/(Na + K) fluid at the late-magmatic stage. This model may have wider significance for the generation of albite granites/low-K granites or albitites in other areas. The A-type plutonism under consideration seems to be an outcome of ensialic rifting of the Bhilwara aulacogen.  相似文献   

14.
The gold mineralization of the Hutti Mine is hosted by nine parallel, N–S trending, steeply dipping, 2–10 m wide shear zones, that transect Archaean amphibolites. The shear zones were formed after peak metamorphism during retrograde ductile D2 shearing in the lower amphibolite facies. They were reactivated in the lower to mid greenschist facies by brittle–ductile D3 shearing and intense quartz veining. The development of a S2–S3 crenulation cleavage facilitates the discrimination between the two deformation events and contemporaneous alteration and gold mineralization. Ductile D2 shearing is associated with a pervasively developed distal chlorite–sericite alteration assemblage in the outer parts of the shear zones and the proximal biotite–plagioclase alteration in the center of the shear zones. D3 is characterized by development of the inner chlorite-K-feldspar alteration, which forms a centimeter-scale alteration halo surrounding the laminated quartz veins and replaces earlier biotite along S3. The average size of the laminated vein systems is 30–50 m along strike as well as down-dip and 2–6 m in width.Mass balance calculations suggest strong metasomatic changes for the proximal biotite–plagioclase alteration yielding mass and volume increase of ca. 16% and 12%, respectively. The calculated mass and volume changes of the distal chlorite–sericite alteration (ca. 11%, ca. 8%) are lower. The decrease in δ18O values of the whole rock from around 7.5‰ for the host rocks to 6–7‰ for the distal chlorite–sericite and the proximal biotite–plagioclase alteration and around 5‰ for the inner chlorite-K-feldspar alteration suggests hydrothermal alteration during two-stage deformation and fluid flow.The ductile D2 deformation in the lower amphibolite facies has provided grain scale porosities by microfracturing. The pervasive, steady-state fluid flow resulted in a disseminated style of gold–sulfide mineralization and a penetrative alteration of the host rocks. Alternating ductile and brittle D3 deformation during lower to mid greenschist facies conditions followed the fault-valve process. Ductile creep in the shear zones resulted in a low permeability environment leading to fluid pressure build-up. Strongly episodic fluid advection and mass transfer was controlled by repeated seismic fracturing during the formation of laminated quartz(-gold) veins. The limitation of quartz veins to the extent of earlier shear zones indicate the importance of pre-existing anisotropies for fault-valve action and economic gold mineralization.  相似文献   

15.
河北东坪金矿区水泉沟岩体的地球化学特征   总被引：17，自引：0，他引：17       下载免费PDF全文
魏菊英  苏琪 《地质科学》1994,29(3):256-266
水泉沟岩体主要由二长岩构成。主要矿物是碱性长石和斜长石,它们的含量高达80%以上。石英不多见,暗色矿物含量少。副矿物主要是磁铁矿、石榴石、榍石和锆石。交代结构发育,蚀变现象普遍。主要化学组分和微量元素含量及δ18O值变化范围大。该二长岩体是由老片麻岩经热液碱交代作用而成。  相似文献   

16.
The results of field, petrographic and geochemical work of the granitoids of Hutti-Gurgunta area in the northern part of Eastern Dharwar Craton (EDC) is presented in this paper. This crustal section comprises polyphase banded to foliated TTG gneisses, middle amphibolite facies Gurgunta schist belt and upper greenschist facies Hutti schist belt and abundant granite plutons. The focus of the present study is mainly on basement TTG gneisses and a granite pluton (∼ 240 sq km areal extent), to discuss crustal accretion processes including changing petrogenetic mechanism and geodynamic setting. The TTGs contain quartz, plagioclase, lesser K-feldspar and hornblende with minor biotite while the granite contain quartz, plagioclase, K-feldspar and hornblende. Late stage alteration (chloritisation, sericitisation and epidotisation) is wide spread in the entire area. A huge synplutonic mafic body which is dioritic to meladioritic in composition injects the granite and displays all stages of progressive mixing and hybridization. The studied TTGs and granite show distinct major and trace element patterns. The TTGs are characterized by higher SiO2, high Al2O3, and Na2O, low TiO2, Mg#, CaO, K2O and LILE, and HFS elements compared to granite. TTGs define strong trondhjemite trend whilst granite shows calc-alkaline trend. However, both TTGs and granite show characteristics of Phanerozoic high-silica adakites. The granite also shows characteristics of transitional TTGs in its high LILE, and progressive increase in K2O with differentiation. Both TTGs and granite define linear to sub-linear trends on variation diagrams. The TTGs show moderate total REE contents with fractionated REE patterns (La/YbN =17.73–61.73) and slight positive or without any significant Eu anomaly implying little amount of amphibole or plagioclase in residual liquid. On the other hand, the granite displays poor to moderate fractionation of REE patterns (La/YbN = 9.06–67.21) without any significant Eu anomaly. The TTGs have been interpreted to be produced by low-K basaltic slab melting at shallow depth, whereas the granite pluton has been formed by slab melting at depth and these melts interacted with peridotite mantle wedge. Such changing petrogenetic mechanisms and geodynamic conditions explain increase in the contents of MgO, CaO, Ni and Cr from 2700 Ma to 2500 Ma granitoids in the EDC.  相似文献   

17.
喀拉果如木铜矿是近年在新疆喀喇昆仑地区发现的铜多金属矿.铜矿化赋存在二长花岗斑岩中,矿石呈细脉浸染状、斑点状.矿石矿物主要为黄铜矿,少量黄铁矿、斑铜矿和毒砂.围岩蚀变有硅化、绢云母化和青磐岩化,具有与斑岩铜矿类似的蚀变组合.二长花岗斑岩主要由斜长石、钾长石、石英、黑云母及蚀变的暗色矿物组成.二长花岗斑岩的SiO2(67.28％ ～73.08％)、Al2 O3(13.38％～15.53％)、K2O(2.92％ ～6.15％)和Na2O(2.78％ ～4.89％)含量较高,CaO和TiO2含量较低,属于高钾钙碱性系列;富集大离子亲石元素(LILE),亏损高场强元素(HFSE)和重稀土元素,Nb和Ta负异常,显示准铝质-弱过铝质过渡的特点,岩浆结晶分异作用明显,具有陆缘孤花岗岩的地球化学亲缘性,微量元素显示其为同碰撞-后碰撞花岗岩.成矿岩体锆石LA-ICP-MS测年结果为189.3 ±2.8Ma,成岩成矿作用发生在早侏罗世.结合区域地质演化,本文认为喀拉果如木铜矿形成于南昆仑地体与喀喇昆仑-甜水海地体之间的古特提斯洋消减闭合之后的后碰撞伸展背景,喀喇昆仑在晚三叠世-早侏罗世进入后碰撞造山时期.  相似文献   

18.
诸广矿区与铀矿化关系密切的碱交代作用广泛发育,碱交代岩与围岩(正常花岗岩)对比,Na2O、K2O明显增高,Al2O3、Fe2O3也增高;SiO2明显降低,FeO、MgO、CaO也降低,表明K2O和Na2O被带入。矿物化学成分分析得出诸广碱交代岩的长石主要为钠长石与钾长石;绿泥石主要属铁镁绿泥石和蠕绿泥石;黄铁矿有的含铀量较高,据Fe/S值属硫亏损型,据S/Se值属岩浆热液矿床范畴;云母属白云母及少量铁白云母;铀矿物和含铀矿物的UO2含量以沥青铀矿较高,钍石较低,铀矿石的蚀变矿物和造岩矿物有的也含微量铀。碱交代作用既释放矿质又为矿质沉淀创造空间,碱交代岩既提供铀源又是一种有利的成矿围岩。  相似文献   

19.
鄂尔多斯盆地延长组储层砂岩发育大量自生钠长石矿物,其成因和产出与浊沸石有关,含量和分布比浊沸石多而广泛,但没有引起人们的注意。大量详细岩相学观察发现延长组储层砂岩发育丰富的自生钠长石,其主要为由斜长石碎屑蚀变形成或呈胶结物充填分布在砂岩碎屑颗粒之间。钠长石中含有大量原生的发亮黄色荧光的油气包裹体,表明其形成与油气注入同时。电子探针成分分析表明,钠长石Na2O含量较高,几乎为斜长石的纯钠长石端员(NaAlSi3O8),没有钙长石端员(CaAl2Si2O8)。激光拉曼光谱特征反映出钠长石为沉积成岩期形成的低温钠长石,而非来源于岩浆岩或者变质岩区的碎屑钠长石。应用LA-MC-ICP/MS原位微分析技术对钠长石进行的稀土元素分析表明,延长组砂岩钠长石具有热水成岩作用地球化学特征,属于热液成岩作用产物。认为大量钠长石形成与石油充注的同时进行导致了储层致密过程中岩性油藏的形成。延长组储层砂岩中热液成岩作用对油藏形成和分布意义重大,值得重视和研究。  相似文献   

20.
The isolated volcano-sedimentary sequences of the Punagarh and Sindreth Groups occur along the western flank of the Delhi Fold Belt in northwest India, and include mafic rocks (pillow basalts and dolerite dykes) that are dominantly olivine tholeiites with minor quartz-normative and alkali basalts. Sindreth samples appear to have higher primary TiO2 and P2O5 abundances relative to those from Punagarh. Both suites of mafic rocks show variable, but profound hydrothermal alteration effects, with loss on ignition (LOI) values up to 10.3 wt.%, and extensive secondary minerals including albite, sericite, chlorite and calcite. Despite this, there is excellent preservation of magmatic textures, but there has been extensive albitization of plagioclase phenocrysts, a hallmark of hydrothermal alteration processes in oceanic crust. Supporting evidence for such hydrothermal alteration comes from correlations of LOI abundances with CaO/Na2O, and evidence for U mobility is apparent on diagrams of Nb/Th vs. Nb/U. Felsic volcanic rocks (rhyolite, dacite) interlayered with the Sindreth basalts yield U–Pb zircon ages (TIMS method) between 761 ± 16 and 767 ± 3 Ma, which we interpret as representing the time of primary magmatic activity. We infer that the volcano-sedimentary rocks of the Punagarh also formed at this time, on the basis of similarities in lithology, stratigraphy, field relations and geochemistry. Intermediate granitoid rocks yield older U–Pb ages of 800 ± 2 and 873 ± 3 Ma, which we correlate with the post-Delhi Supergroup Erinpura Granites. Taken together, the features of the Punagarh and Sindreth Groups are consistent with their formation in a back-arc basin setting. Their coevality with other magmatic systems in NW India (Malani Igneous Suite), the Seychelles and Madagascar, for which a continental arc setting has also been proposed, supports the notion of an extensive convergent margin in western Rodinia at 750–770 Ma.  相似文献   

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