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1.
The Fe/Mg+Fe) ratios (XFe) of the Quaternary basalts (SiO2 < 53 wt.%) in the Japanese arcs were examined. The XXFe of relatively magnesian basalts decreases from the volcanic front toward the Japan Sea across the arcs. Based on the partition coefficient of Mg-Fe2+ between olivine and liquid, it is suggested that all the basalts near the volcanic front, which are mostly tholeiitic basalts, are significantly fractionated, whereas many basalts near the Japan Sea, which are mostly alkali basalts, are little fractionated. The K2 O content in the primary basalt magmas increases toward the Japan Sea. Combining the XFe and K2 O data, it is suggested that relatively large amounts of tholeiitic magmas are produced near the volcanic front, but they fractionate during their ascent, whereas smaller amounts of alkali basalt magmas are formed near the Japan Sea, but they can ascend with less fractionation. The density of primary tholeiite magma is significantly larger than that of primary alkali basalt magmas. It is most likely that primary tholeiite magmas cannot ascend beyond the upper crust and would fractionate to produce less dense tholeiitic magmas near the volcanic front, whereas primary alkali basalt magmas can ascend through the upper crust without fractionation, as far as buoyancy is the principal ascending force. In the Japanese arcs, the stress field may be less compressional near the Japan Sea than near the volcanic front, so that magmas can ascend more rapidly in the latter region than in the former. These two factors may be responsible for the above mentioned chemical variations of basalt magmas across the arcs. The variation in volume of the Quaternary volcanic rocks across the arcs can be explained by the presence of a melt-rich zone above but nearly parallel to the subducted slab.  相似文献   

2.
Chemical compositions of schlieren in basalt flows are compared with those of the host rocks for tracing the fractionation trends of basalt magmas under extrusive conditions. In the Warner high-alumina basalt of California and in the tholeiite of Hawaii and Japan, total iron increases markedly from the host rock to the schlieren whileSiO 2 is nearly constant. In the high-alumina basalt of Huzi Volcano and in the tholeiite near Catania, Italy, total iron is nearly constant during fractionation whileSiO 2 increases. In basalts of the hypersthenic rock series or calc-alkali rock series from California, total iron is also nearly constant whileSiO 2 increases. The difference in fractionation trend in these flows is attributable to the difference of the state of oxidation of iron in the original magmas. Oxygen partial pressure of the magmas would not be maintained constant during the fractionation of extrusive bodies.  相似文献   

3.
Detailed field mapping in the Güvem area in the Galatia province of NW Central Anatolia, Turkey, combined with K–Ar dating, has established the existence of two discrete Miocene volcanic phases, separated by a major unconformity. The magmas were erupted in a post-collisional tectonic setting and it is possible that the younger phase could be geodynamically linked to the onset of transtensional tectonics along the North Anatolian Fault zone. The Early Miocene phase (18–20 Ma; Burdigalian) is the most voluminous, comprising of over 1500 m of potassium-rich intermediate-acid magmas. In contrast, the Late Miocene volcanic phase (ca. 10 Ma; Tortonian) comprises a single 70-m-thick flow unit of alkali basalt. The major and trace element and Sr–Nd isotope compositions of the volcanics suggest that the Late Miocene basalts and the parental mafic magmas to the Early Miocene series were derived from different mantle sources. Despite showing some similarities to high-K calc-alkaline magma series from active continental margins, the Early Miocene volcanics are clearly alkaline with higher abundances of high field strength elements (Zr, Nb, Ti, Y). Crustal contamination appears to have enhanced the effects of crystal fractionation in the petrogensis of this series and some of the most silica-rich magmas may be crustal melts. The mantle source of the most primitive mafic magmas is considered to have been an asthenospheric mantle wedge modified by crustally-derived fluids rising from a Late Cretaceous–Early Tertiary Tethyan subduction zone dipping northwards beneath the Galatia province. The Late Miocene basalts, whilst still alkaline, have a Sr–Nd isotope composition indicating partial melting of a more depleted mantle source component, which most likely represents the average composition of the asthenosphere beneath the region.  相似文献   

4.
Gabbroic rocks occur only in the west, and are the oldest intrusions in the Peninsular Ranges Cordilleran batholith. They comprise an olivine-pyroxene gabbronorite series and an amphibole gabbro series both of which contain abundant plagioclase and amphibole. They formed by crystal accumulation and in situ differentiation, in multiple intrusive complexes, and are not considered to be related by fractionation to the granitoid rocks of the batholith.Pure mineral separates of plagioclase, olivine, clinopyroxene, orthopyroxene, and amphibole were obtained by magnetic and heavy-liquid methods from a representative suite of gabbroic rocks. Their major- and trace-element contents were determined by X-ray fluorescence, and the data used to test hypotheses on the genesis and fractionation of the gabbros.The plagioclases range from An98 to An65 in composition, olivines, Fo79 to Fo70, occur in rocks where An>36. All clinopyroxenes are augite with Mg #'s varying from 81.1 to 64.7. Orthopyroxene occurs where An<92, and is generally inverted pigeonite or bronzite, and has Mg #'s ranging from 77.9 to 52.1. The amphiboles include tschermakite, tschermakitic hornblende, pargasite, pargasitic hornblende, ferroan pargasite, magnesio-hornblende, and magnesio-taramite, Mg #'s range from 80.4 to 62.5. Systematic chemical and mineralogical changes confirm that differentiation, controlled by mineral assemblages of plagioclase, olivine, spinel, and clinopyroxene initially, and orthopyroxene, amphibole, and magnetite later, took place between intrusive episodes and in situ.The highly clacic plagioclase coexisting with olivine and amphibole suggests that the gabbros were formed from hydrous mafic magmas. The modal mineralogy of the gabbros, and the chemistry of the minerals is very similar to that of the cumulate blocks of the Lesser Antillean volcanoes. These features confirm that the gabbros were derived from a hydrous mafic magma, with high Al2O3 and low TiO2 contents, typical of orogenic environments.Cumulate minerals from the gabbros show little or no zoning and are considered to have formed in equilibrium with the evolving melts. Selected trace-element contents and distribution coefficients are used to calculate the compositions of the melts. The calculations show that the melts in equilibrium with the olivine-pyroxene gabbronorite series contain approximately 100–200 ppm Ba, 200–400 ppm Sr, 30-10 ppm Ni, 20-10 ppm Co, and 300-100 ppm V. K/Rb ratios of the melts, derived from post-cumulus and prismatic amphiboles, are generally in the range 550-250. These values are typical of calc-alkalic basalts and andesites, and it is suggested that they may have erupted at the surface to form a coeval calc-alkalic volcanic sequence.  相似文献   

5.
Some trace element data for volcanic rocks found at different levels, from Tertiary to Holocene, in south-eastern Sicily (Iblean Plateau and Mt. Etna) are presented and discussed in the present paper in order to better the information about the origin and relationships of the various rock types. Four groups of volcanic rocks have been recognized on the basis of their major element chemistry: 1) low-K tholeiites, 2) associated alkali basalts to nephelinites of the Iblean Plateau (Upper Pliocene to Lower Pleistocene), 3) the basal subalkaline lavas of Mt. Etna, and 4) the alkalic suite rocks that make up the bulk of the volcano. The distribution of Rb, Sr, Ni, Cr, Co, Cu, REE, Th and Sc suggests:
  1. an origin of the Iblean magmas by a different degree of partial melting of a Rb-poor and possibly slightly hetereogeneous mantle;
  2. quite distinct source compositions for the Etnean magmas, relative to those of the Iblean area, on the basis of their Rb and Sr contents;
  3. an origin of the alkalic rocks of Mt. Etna from independently generated magma(s) rather than by crystal fractionation of the Etnean subalkaline magmas or of a magma having the geochemical features of the Iblean alkali basalts; evidence for this is given by the distribution features of the incompatible elements showing an origin for these rocks from compositionally different parent magmas and/or an evolution under widely variable environmental conditions;
  4. the primary character for the chemical differences observed in some of the Etnean subalkaline rocks that can be accounted for by different physico-chemical conditions at their source rather than by crystal fractionation processes.
  相似文献   

6.
Origin of andesite and its bearing on the Island arc structure   总被引：1，自引：0，他引：1  
The hypothesis that andesite magmas originate from basalt magmas through fractionation is supported for the following reasons: 1) A close association of andesite and dacite with basalt in many volcanoes and a complete gradation in chemistry and mineralogy throughout this suite. 2) Formation of andesite magmas from basalt magmas by differentiation in situ of some intrusive and extrusive bodies. 3) Agreement between the calculated compositions of solid materials to be subtracted from basalt magmas to yield andesite magmas and the observed mineralogy of phenocrysts in these rocks. 4) Higher alkali contents in andesite and dacite associated with high-alumina basalt than in those associated with tholeiite. 5) A complete gradation from the high iron concentration trend of basalt magma fractionation (Skaergaard) to the low or noniron concentration trend (the calc-alkali series) which can be ascribed to the difference of the stage of magnetite crystallization. 6) Similarity between the orogenic rock suite and plateau basalts in the preferential eruption of magmas of middle fractionation stage, givin rise to the great volume of andesite in the orogenic belts and iron-rich basalt in the plateau lavas. Petrological and seismic refraction studies suggest that a great volume of gabbroic materials are present in the lower crust underneath the volcanic belts as a complementary material for the andesite lavas. The island arc structure would develop by repeated eruption of andesite on the surface and by thickening of the oceanic crust underneath the arc due to the addition of gabbroic materials. The suitable portion of the lower crust may be subjected to partial melting to produce granitic magma in the later stage of development of the arc, successively changing it to a part of the adjacent continent.  相似文献   

7.
The northeastern Japan forms a typical arcuate structure with a remarkable zonal arrangement of many geologic features, including the distribution of Quaternary volcanoes. Thus two distinct zones of volcanoes are noted here: i. e., Nasu zone on the east and Tyokai zone on the west. Some of the volcanoes of Nasu zone are characterized by the presence of pumice flows or pumice falls, sometimes of very large scales. These pumice flows belong to the calc-alkali rock series. While pumice flows or falls are rare in the Tyokai zone, where they are present though on small scale. Migration of the center of activity is noted along linear fissures, running either from east to west, or north to south at some volcanoes of Nasu zone, and consequently large swarms of volcanoes are common in this zone. While central eruption with definite center is typical of the Tyokai zone. From the petrographical and petrochemical study on the lavas and pyroclastics the original magma of the Nasu zone is estimated to be tholeiitic, and that of the Tyokai zone high-alumina basaltic. Abundant calc-alkali rocks are derived from these parental magmas. Thus the difference in the volcanic activity should be ascribed to the different nature of the parental magmas or the magmas derived from them.  相似文献   

8.
True rhyolites are found in two contrasting occurrences in Central America: in recent obsidian domes in the basalt-rhyolite association of southeastern Guatemala, and in late Tertiary ignimbrites in Honduras and adjacent parts of Nicaragua. Both are on the inner side of the main volcanic axis in a region that is visibly underlain by older metamorphic and plutonic rocks. They have not been found in southern Central America where the basement series consists only of older volcanic rocks, eugeosynclinal sediments, and peridotite. Rhyolite obsidian has erupted alternately with basalts in the Obrajuelo Complex of southeastern Guatemala. Cumulate rocks and moderate compositional variations in the basalts provide evidence of limited crystal fractionation, but abundant venocrysts and partially fused xenoliths indicate that partial melting of the plutonic and metamorphic basement may also have been important. Extremely siliceous rhyolite ignimbrites with a volume of several thousands of cubic kilometers closely resemble the rhyolite obsidians in their major element compositions, but in contrast to the totally glassy obsidians they contain abundant phenocrysts of quartz and alkali feldspar. A few ignimbrites contain inclusions of partially melted basement rocks. The basalts with which they are associated have a limited compositional range. Melting experiments performed on rocks of the basement series, together with chemical, isotopic, and volumetric relations, indicate that the ignimbrites are products of partial fusion of the basement series, while obsidians of the Obrajuelo Complex have differentiated from more basic magmas by a process other than crystal fractionation.  相似文献   

9.
Volcanism in the Taupo Volcanic Zone (TVZ) and the Kermadec arc-Havre Trough (KAHT) is related to westward subduction of the Pacific Plate beneath the Indo-Australian Plate. The tectonic setting of the TVZ is continental whereas in KAHT it is oceanic and in these two settings the relative volumes of basalt differ markedly. In TVZ, basalts form a minor proportion (< 1%) of a dominant rhyolite (97%)-andesite association while in KAHT, basalts and basaltic andesites are the major rock types. Neither the convergence rate between the Pacific and Indo-Australian Plates nor the extension rates in the back-arc region or the dip of the Pacific Plate Wadati-Benioff zone differ appreciably between the oceanic and continental segments. The distance between the volcanic front and the axis of the back-arc basin decreases from the Kermadec arc to TVZ and the distance between trench and volcanic front increases from around 200 km in the Kermadec arc to 280 km in TVZ. These factors may prove significant in determining the extent to which arc and backarc volcanism in subduction settings are coupled.All basalts from the Kermadec arc are porphyritic (up to 60% phenocrysts) with assemblages generally dominated by plagioclase but with olivine, clinopyroxene and orthopyroxene. A single dredge sample from the Havre Trough back arc contains olivine and plagioclase microphenocrysts in glassy pillow rind and is mildly alkaline (< 1% normative nepheline) contrasting with the tholeiitic nature of the other basalts. Basalts from the TVZ contain phenocryst assemblages of olivine + plagioclase ± clinopyroxene; orthopyroxene phenocrysts occur only in the most evolved basalts and basaltic andesites from both TVZ and the Kermadec Arc.Sparsely porphyritic primitive compositions (Mg/(Mg+Fe2) > 70) are high in Al2O3 (>16.5%), and project in the olivine volume of the basalt tetrahedron. They contain olivine (Fo87) phenocrysts and plagioclase (> An60) microphenocrysts. These magmas have ratios of CaO/Al2O3, A12O3/TiO2 and CaO/TiO2 in the range of MORB and MORB picrites and can evolve to the low-pressure MORB cotectic by crystallisation of olivine±plagiociase. Such rocks may be the parents of other magmas whose evolutionary pathways are complicated by interaction of crystal fractionation, crystal accumulation and mixing processes and the filtering action of crust of variable density and thickness. The interplay of these processes likely accounts for the scatter of data about the cotectic. More evolved rocks from both TVZ and KAHT contain clinopyroxene and orthopyroxene phenocrysts and their compositions merge with basaltic andesites and andesites. Stepwise least-squares modelling using phenocryst assemblages in proportions observed in the rocks suggest that crystal fractionation and accumulation processes can account for much of the diversity observed in the major-element compositions of all lavas.We conclude that the parental basaltic magmas for volcanism in the TVZ and KAHT segments are similar thereby implying grossly similar source mineralogy. We attribute the diversity to secondary processes influencing liquids as they ascended through complex plumbing systems in the sub arc mantle and cross.  相似文献   

10.
Abundances of major and trace elements were determined for the Tertiary volcanic rocks from SW Hokkaido. The Late Miocene to Pliocene volcanic rocks of this region show geochemical features similar to those of the Quaternary rocks, that is, K/Si, Th/Si and LREE/HREE ratios increasing across the arc, east to west, from the Pacific to the Japan Sea side. In contrast, the Early Miocene volcanic rocks, which are geographically restricted to the Japan Sea coast, are distinct from all later volcanics and show “within-plate” characteristics — in particular, high concentrations of HFS elements. The Quaternary basalts have low Hf/Yb ratios and Hf contents, whereas the Early Miocene basalts are high in Hf/Yb and Hf, similar to Hawaiian alkali basalts. The compositional variation with time may result from the progressive depletion of incompatible HFS elements in the mantle source. Th/Yb ratios increase from Early Miocene to Quaternary, possibly reflecting increase in the LIL element contribution to the mantle source during that time.  相似文献   

11.
Submersible observations and sampling were carried out in the rift valley of the Mid-Atlantic Ridge (MAR) near 34°40′N–35°N. The 4-km-wide rift valley consists of a Neo Volcanic Zone (NVZ) (<1 km wide) bounded at the west by a Median Ridge (MR) (5 km wide and 20 km long) and at the east by the first scarps of the eastern wall. The MR and the eastern wall are characterized by volcanic cones about 200–300 m height culminating at depths of 1500–1900 m which are made up of volcaniclastic deposits (pyroclasts and hyaloclasts) suggestive of explosive volcanism. Based on their surface morphology, degree of vesicularity, and composition, the erupted deposits are classified into four groups: (1) poorly vesicular (<15% vesicles) N- and T-MORBs (K/Ti <0.25, Na2O+K2O<2.9%) consisting of sheet flows and pillows formed during fissure eruptions in the NVZ at 2000–2300 m depths; (2) vesicular (15–30% vesicles) E-MORBs (K/Ti=0.25−0.45,Na2O+K2O>2.8−3.2%) and alkali basalts (K/Ti=0.45−0.70,Na2O+K2O>3.3−4) made up mainly of pillows; (3) highly vesicular (>35% vesicles) pillow lava and pyroclastic (scoria-like) alkali basalts (K/Ti>0.45−0.80,Na2O+K2O>3−4%); and (4) hyaloclastites consisting of glassy shards of alkali basalt composition. The total water and carbon contents of the deposits increase with the incompatible element concentrations. The estimated initial H2O content for the N- and T-MORBs is less than 3500 ppm, whereas for the E-MORBs and alkali basalts the H2O content is near 4000 and 7000 ppm, respectively. While the H2O is mainly in the melt, the carbon is in the form of CO2 filling vesicles. The vesicles are formed from magma with an initial carbon content of 1000–3000 for the N- and T-MORBs, 3000–6500 ppm for the E-MORBs and higher than 1 wt% for the alkali basalts.The various lava types were derived from a heterogeneous mantle source composed of enriched and depleted components during sequential eruptions of N-, T- and E-MORBs and alkali basalts (K/Ti>0.7). The amount of CO2 and H2O in equilibrium with the dissolved species present in the vesicles indicates that CO2 (XCO2=1−0.84) was the main exsolved compound responsible for bubble nucleation. The increase in the degree of vesicularity and pressure of the volatile phases is mainly due to the early exsolution of CO2 from an alkali melt. The exsolution of significant amounts of dissolved water occurred only for the alkali basalt a few hundred meters beneath the seafloor and contributed to late bubble expansion. This subsequent addition of magmatic water to the vesicles increased the gas pressure and triggered explosions. An alternative hypothesis for the explosive volcanism is based on field observations. During crater collapsed, seawater could have been trapped in fractured volcanic conduits and later sealed by hydrothermal fluid circulation and precipitation. In such an environment, this seawater will be heated and vaporized during renewed magmatic upwelling. Both scenarios give rise to fragmented debris (hyaloclasts and pyroclasts) and the explosive events create turbulent flows followed by differential gravity settling of the particles (shards versus lapilli) through the seawater.  相似文献   

12.
Changes in oceanic O–Sr isotopic compositions and global cooling beginning in the Eocene are considered to have been caused by the uplift of the Tibetan Plateau. The specific timing and uplift mechanism, however, have long been subjects of debate. We investigated the Duogecuoren lavas of the central-western Qiangtang Block, which form the largest outcrops among Cenozoic lavas in northern-central Tibet and have widely been considered as shoshonitic. Our study demonstrates, however, that most of these lavas are high-K calc-alkaline andesites, dacites and rhyolites. Moreover, they are characterized by high Sr (367–2472 ppm) and Al2O3 (14.55–16.86 wt.%) and low Y (3.05–16.9 ppm) and Yb (0.31–1.48 ppm) contents and high La/Yb (27–100) and Sr/Y (48–240) ratios, similar to adakitic rocks derived by partial melting of an eclogitic source. They can be further classified as either peraluminous and metaluminous subtypes. The peraluminous rocks have relatively high SiO2 (> 66 wt.%) contents, and low MgO (< 1.0 wt.%), Cr (4.94–23.3 ppm) and Ni (2.33–17.0 ppm) contents and Mg# (20–50) values, while the metaluminous rocks exhibit relatively low SiO2 (55–69 wt.%) contents, and high MgO (1.41–6.34), Cr (25.7–383 ppm), Ni (14.13–183 ppm) and Mg# (46–69) values, similar to magnesian andesites. 40Ar/39Ar and SHRIMP zircon U–Pb dating reveal that both peraluminous and metaluminous adakitic rocks erupted in the Eocene (46–38 Ma). Paleocene–Early Miocene thrust faults and associated syn-contractional basin deposits in the Qiangtang Block suggest that this region was undergoing crustal shortening within a continent during the Eocene. The low εNd (− 2.81 to − 6.91) and high 87Sr/86Sr (0.7057–0.7097), Th (11.2–32.3 ppm) and Th/La (0.23–0.88) values in the Duogecuoren adakitic rocks further indicate that they were not derived by partial melting of subducted oceanic crust. Taking into account tectonic and geophysical data and the compositions of xenoliths in Cenozoic lava in northern-central Tibet, we suggest that the peraluminous adakitic rocks were most probably derived by partial melting of subducted sediment-dominated continent of the Songpan-Ganzi Block along the Jinsha suture to the north at a relatively shallow position (the hornblende + garnet stability field), but the metaluminous adakitic rocks likely originated from the interaction between peraluminous adakitic melts generated at greater depths (the garnet + rutile stability field) and mantle. Because the Duogecuoren adakitic rocks must have originated from a garnet-bearing (namely, eclogite facies) source, Eocene continental subduction along the Jinsha suture caused the thickening of the Qiangtang crust. Given that crustal thickening generally equates with elevation, the uplift of the Central Tibetan Plateau probably began as early as 45–38 Ma, which provides important evidence for tectonically driven models of oceanic O–Sr isotope evolution during global cooling and Asian continental aridification beginning in the Eocene.  相似文献   

13.
A suite of 16 basanitic volcanic rocks, representing all stages in the evolution of the La Breña — El Jagüey (LBEJ) Maar Complex, has been studied petrographically and analyzed for mineral compositions and whole-rock major element, trace element, and Sr–Nd–Pb isotopic compositions. Two feldspathic granulite xenoliths were also studied as possible lower-crustal contaminants to the LBEJ magmas. The volcanic rocks contain the stable minerals olivine, plagioclase, augite, and titanomagnetite±ilmenite, plus a diverse suite of xenocrusts derived from disaggregation of mantle xenoliths of spinel lherzolite (olivine, orthopyroxene, spinel) and lower-crustal granulite xenoliths (plagioclase, quartz, augite, ilmenite). Late-stage interstitial melts rich in Fe and Ti migrated into vesicles in several samples, forming coarse-grained segregation vesicles that are dominated by ilmenite blades up to 2 mm long. The whole-rock elemental data are typical of intra-plate basanitic rocks, with strong enrichments in large ion lithophile elements (i.e. K, Th, U) as well as high field strength elements (i.e. Nb, Ta) relative to mid-ocean ridge basalts (MORB) and estimates of primordial mantle abundances. Mg# increased systematically with time during the evolution of the LBEJ Maar Complex, from 57.0–58.2 in the pre-maar lavas to 59.1–63.8 in the post-maar lavas. Compatible elements (Ca, Sc, Cr, Co, Ni) correlate positively with Mg#, whereas a large group of incompatible elements (Al, Na, K, P, Rb, Sr, Zr, Nb, Ba, La, Ce, Sm, Hf, Ta, Th, U) correlate negatively with Mg#. These trends can be closely reproduced by simple models of fractional crystallization, provided that the incompatible element abundances of the parental, high-Mg# magmas are allowed minor variability. All successful fractionation models demand an important role for augite, despite its presence in the LBEJ volcanic rocks as only a late-stage microphenocrystic and groundmass mineral. Minor garnet fractionation is necessary to produce depletion of heavy rare earth element (REE) abundances in the pre-maar lavas, whose REE patterns cross those for the rest of the suite. The importance of augite and garnet fractionation indicate that the differentiation of the LBEJ magmas took place within the upper mantle, a conclusion that is supported by the presence of spinel lherzolite xenoliths in magmas from all stages in the evolution of the maar complex. Isotopic data for seven LBEJ volcanic rocks show the following ranges: 87Sr/86Sr 0.70327–0.70347, Nd 4.2–5.0, 206Pb/204Pb 18.60–18.81, 207Pb/204Pb 15.58–15.65, 208Pb/204Pb 38.19–38.58. Sr-Nd values are negatively correlated and form a trend parallel to the mantle array, overlapping the field for ocean island basalts (OIB). The LBEJ rocks have similar 87Sr/86Sr values but lower Nd compared to basanitic rocks from the US Basin and Range Province (BRP). Pb isotopic ratios are positively correlated and overlap the braod fields for MORB and OIB and the small fields for Mexican ore deposits and volcanic rocks from the active subduction-related Mexican Volcanic Belt. The LBEJ rocks have slightly more radiogenic Pb than basanitic rocks from the US BRP. Despite correlations among the isotopic ratios of the LBEJ suite, none of these ratios correlate with position in the eruption sequence, Mg#, or any other compositional parameter. The two lower-crustal xenoliths have high 87Sr/86Sr values (0.707, 0.710) and low Nd (-1.5,-8.0) compared to the LBEJ volcanic rocks, but their Pb isotopic compositions are only slightly more radiogenic than the volcanic rocks. These data do not support the widely held view that the lower crust is a major reservoir of unradiogenic Pb. In order to further constrain the role played by crustal contamination in generating the isotopic diversity in the LBEJ suite, we conducted an extensive investigation of Sr–Nd–Pb isotopic ratios for scoria clasts from different levels of a single scoria-fall horizon in the pyroclastic sequence related to the formation of La Breña Maar. Our results do not support an important role for crustal contamination in the LBEJ magmas. Rather, we conclude that minor isotopic variability exists in the mantle source regions beneath the maar complex.  相似文献   

14.
Over the last 42 ka, volcanic activity at Lipari Island (Aeolian Arc, Italy) produced lava domes, flows and pyroclastic deposits with rhyolitic composition, showing in many cases evidence of magma mixing such as latitic enclaves and banding. In this same period, on nearby Vulcano Island, similar rhyolitic lava domes, pyroclastic products and lava flows, ranging in composition from shoshonite to rhyolite, were erupted. As a whole, the post-42 ka products of Lipari and Vulcano show geochemical variations with time, which are well correlated between the two islands and may correspond to a modification of the primary magmas. The rhyolitic products are similar to each other in their major elements composition, but differ in their trace element abundances (e.g. La ranging from 40 to 78 ppm for SiO2 close to 75 wt%). Their isotopic composition is variable, too. The 87Sr/86Sr (0.704723–0.705992) and 143Nd/144Nd (0.512575–0.512526) ranges partially overlap those of the more mafic products (latites), having 87Sr/86Sr from 0.7044 to 0.7047 and 143Nd/144Nd from 0.512672 to 0.512615. 206Pb/204Pb is 19.390–19.450 in latites and 19.350–19.380 in rhyolites. Crystal fractionation and crustal assimilation processes of andesitic to latitic melts, showing an increasing content in incompatible elements in time, may explain the genesis of the different rhyolitic magmas. The rocks of the local crustal basement assimilated may correspond to lithotypes present in the Calabrian Arc. Mixing and mingling processes between latitic and rhyolitic magmas that are not genetically related occur during most of the eruptions. The alignment of vents related to the volcanic activity of the last 40 ka corresponds to the NNW–SSE Tindari–Letojanni strike-slip fault and to the correlated N–S extensional fault system. The mafic magmas erupted along these different directions display evidence of an evolution at different PH2O conditions. This suggests that the Tindari–Letojanni fault played a relevant role in the ascent, storage and diversification of magmas during the recent volcanic activity.  相似文献   

15.
Twenty-three volcanic rocks from the Setouchi volcanic belt, southwest Japan, were analyzed for Nd and Sr isotopic compositions for the purpose of examining the genetic relationships among the basalt, high-magnesium andesite (HMA) and evolved porphyritic andesite. The andesites have higher87Sr/86Sr (0.70487–0.70537) and lower143Nd/144Nd (0.512509–0.512731) than the basalts, i.e., 0.70408–0.70468 and 0.512691–0.512830, respectively. This result confirms earlier conclusions obtained from petrologic study that the andesites cannot be fractionation products of basaltic magma but that the andesitic and basaltic magmas were generated independently. On the basis of melting experiments for HMA and basalt, it is inferred that there is an isotopically stratified mantle beneath southwest Japan. Evolved porphyritic andesites have essentially identical Sr and Nd isotopic ratios to HMA and can be derived by fractionation of primary andesitic magma. A model to produce orogenic andesite is proposed on petrologic, experimental and isotopic bases.  相似文献   

16.
18O/16O and 87Sr/86Sr ratios were determined for Quaternary calc-alkalic volcanic rocks from six volcanic rock suites in the central and western Japan arcs. The δ18O values relative to SMOW and 87Sr/86Sr ratios range from +6.3 to +9.90/00 and 0.70357 to 0.70684, respectively. Both the O- and Sr-isotopic compositions are higher than those for island-arc primitive magmas and their differentiates. The isotopic compositions of the calc-alkalic rocks cannot be derived by a simple fractional crystallization of the primitive magmas. On the other hand, the 18O- and 87Sr-enrichment is confined to the rock suites located in well-developed island arcs having thick continental-type crust with low or negative Bouguer anomalies. Involvement of 18O- and 87Sr-rich crustal material in the magma formation is suggested.The isotopic compositions vary remarkably within individual rock suites as well as from volcano to volcano. The data points in δ18O vs. 87Sr/86Sr plot accord with a mixing model between primitive magmas and crustal material of dioritic composition on an average, assuming their comparative Sr contents. The primitive magmas involved could not be low-Sr tholeiites, but magmas more or less enriched in incompatible elements including Sr, which correspond to high-alkali tholeiites or alkali basalts and their evolved magmas. The nature of the primitive magmas seems to change from tholeiitic to more alkalic with progressing island-arc evolution.Mixing of crust-derived melts is more plausible than assimilation of solid-rocks for involving 20 to 30% crustal material in the magmas along simple mixing curves. Isotopic variations between the rock suites are ascribed to variable Sr concentration radio of the end-members, variable isotopic compositions of crustal material or variable mixing ratio of the end-members. Extremely high-δ 18O rocks with moderate increase in 87Sr/86Sr ratio suggest another mixing process in shallower magma chambers between andesite magmas and metasedimentary rocks having high δ 18O and 87Sr/86Sr values but low Sr content. Subsequent fractional crystallization of once-derived magmas would be the prominent process for the rock suites showing gradual increase in 18O up to 10/00 with uniform 87Sr/86Sr ratios.  相似文献   

17.
Two volcanic zones (Bukavu and Kamituga) south of Lake Kivu (southeastern Zaire) are part of the western branch of the Eastern African rift. They were formed during three volcanic cycles, one pre-rift (70-7 Ma old) and the other two syn-rift (7.8-1.9 Ma old and 14,000 y.-sub-Recent, respectively), and evolved from quartz tholeiites of the pre-rift period to alkali basalts of the rift stage. The basaltic rocks, which strongly predominate, are compositionally similar to other rift-related basalts and also to oceanic-island rocks. Most of the basalts have undergone only limited fractional crystallization (5–10%) dominated by olivine and clinopyroxene. The distinct variations of incompatible elements even in rocks of very similar major-element composition imply that the basaltic rocks were derived from a heterogeneous source by variable degrees of melting. The inferred source composition closely resembles that of metasomatized peridotite xenoliths from alkali basalts.  相似文献   

18.
Mount Drum is one of the youngest volcanoes in the subduction-related Wrangell volcanic field (80×200 km) of southcentral Alaska. It lies at the northwest end of a series of large, andesite-dominated shield volcanoes that show a northwesterly progression of age from 26 Ma near the Alaska-Yukon border to about 0.2 Ma at Mount Drum. The volcano was constructed between 750 and 250 ka during at least two cycles of cone building and ring-dome emplacement and was partially destroyed by violent explosive activity probably after 250 ka. Cone lavas range from basaltic andesite to dacite in composition; ring-domes are dacite to rhyolite. The last constructional activity occurred in the vicinity of Snider Peak, on the south flank of the volcano, where extensive dacite flows and a dacite dome erupted at about 250 ka. The climactic explosive eruption, that destroyed the top and a part of the south flank of the volcano, produced more than 7 km3 of proximal hot and cold avalanche deposits and distal mudflows. The Mount Drum rocks have medium-K, calc-alkaline affinities and are generally plagioclase phyric. Silica contents range from 55.8 to 74.0 wt%, with a compositional gap between 66.8 and 72.8 wt%. All the rocks are enriched in alkali elements and depleted in Ta relative to the LREE, typical of volcanic arc rocks, but have higher MgO contents at a given SiO2, than typical orogenic medium-K andesites. Strontium-isotope ratios vary from 0.70292 to 0.70353. The compositional range of Mount Drum lavas is best explained by a combination of diverse parental magmas, magma mixing, and fractionation. The small, but significant, range in 87Sr/86Sr ratios in the basaltic andesites and the wide range of incompatible-element ratios exhibited by the basaltic andesites and andesites suggests the presence of compositionally diverse parent magmas. The lavas show abundant petrographic evidence of magma mixing, such as bimodal phenocryst size, resorbed phenocrysts, reaction rims, and disequilibrium mineral assemblages. In addition, some dacites and andesites contain Mg and Ni-rich olivines and/or have high MgO, Cr, Ni, Co, and Sc contents that are not in equilibrium with the host rock and indicate mixing between basalt or cumulate material and more evolved magmas. Incompatible element variations suggest that fractionation is responsible for some of the compositional range between basaltic andesite and dacite, but the rhyolites have K, Ba, Th, and Rb contents that are too low for the magmas to be generated by fractionation of the intermediate rocks. Limited Sr-isotope data support the possibility that the rhyolites may be partial melts of underlying volcanic rocks. Received March 13, 1993/Accepted September 10, 1993  相似文献   

19.
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20.
The Sintra igneous complex, Portugal was an important centre of activity in late Cretaceous times. The great proportion of thealkaline rocks are felsic and include five large quartz syenite intrusions and trachyandesite, trachyte and alkali rhyolite lavas and dykes, most of which are oversaturated. Mafic rocks are sparse, but vary widely from alkaline and highly undersaturated types containing high K2O, TiO2 and Ba, similar to the contemporaneous Lisbon lavas, to hypersthene normative trachybasalts and one hypersthene normative basalt. The various magma types are intimately associated and a well-developed netveined complex of alkali gabbro, monzonite and syenite is recognised at Cabo da Roca. A study of the dyke distributions, intersections and orientations suggest a close propinquity of both oversaturated and undersaturated and of both felsic and matic magmas. The basic magmas of Sintra and Lisbon show a continuous range in undersaturation (0 to 16% normative nepheline) and rare hypersthene normative basalts. Derivation of the hypersthene normative and mildly undersaturated basalts from the more undersaturated melts by low pressure fractionation or contamination by siliceous crust is shown to be unlikely. High pressure eclogite fractionation of a hypersthene normative basalt or variations in the percentage partial melting of a mantle under conditions where titanphlogopite is a low melting fraction are both processes compatible with the variations in undersaturation and proportions of TiO2, K2O and Ba. The quartz syenites and over satured felsic lavas of Sintra are thought to be derived from hypersthene nor mative parents.  相似文献   

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