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1.
Biochemical composition of surface sediment samples from off major and minor rivers along the east coast of India revealed that spatial distribution of sediment organic carbon (SOC) composition was mainly governed by differential characteristics of discharged water and associated biogeochemical processes in the water column. The northwest (NW) region of coastal Bay of Bengal was influenced by discharges from Ganges river while peninsular (monsoonal) rivers influenced the southwest (SW) region. The NW region characterized by low nutrients suspended particulate matter (SPM), high phytoplankton biomass in the water column and high SOC while contrasting to that observed in the SW region. The isotopic ratios of SOC (?22 ‰) in the NW region were close to that of organic matter derived from phytoplankton (?23 ‰) suggesting in situ production is the major source whereas terrigeneous source contributed significantly in the SW region (?19.6 ‰). Though low in situ biological production in the SW region, relatively higher total carbohydrates (TCHO) were found than in the NW and insignificant difference of total and free amino acid concentrations between NW and SW were resulted from faster removal of organic matter to the sediment in association with SPM in the SW region. Higher proteins concentrations than total amino acids indicate that nitrogenous organic matter is preserved in the former form. The protein to TCHO ratio was lower in the SW suggesting significant contribution of aged and non-living organic matter in this region.  相似文献   

2.
Lake Seeloch is a wind-protected, small and shallow forest lake near Hanau, Rhine-Main area, that has neither surface inflow nor outflow. Wet and dry deposition of atmospheric pollutants and groundwater, but primarily the biochemical degradation of organic matter in the lake generates the bulk of dissolved constituents. Forest derived organic materials (pollen; debris; autumn-shed leaves) are the main sources of supply. Except for nitrate-nitrogen, all essential plant nutrients are available in very high, almost excessively high concentrations. Temporal and spatial distribution patterns of elements are established as a continuous recharge/release system at the water/sediment interface and in the lake water column, where processes related to organic matter decay play a dominant role.  相似文献   

3.
Surface sediment samples from the shelf and continental slope off southwest Africa and sediment cores from the deepest part of the Black Sea were analyzed for sterols. Because the organic matter in these anoxic sediments is relatively well-preserved, the input from source organisms in the water column is important in controlling sterol distribution patterns. The sterol distribution on the Namibian shelf is complex, probably because of the great spatial and temporal variability of biological productivity caused by seasonal upwelling and changes in oxygen concentration. The Black Sea, perhaps because of greater physical stability of the water column, has sterol distributions which can be explained by microbial activity or chemical processes acting on a constant input of organic carbon from surface production.  相似文献   

4.
The analyses of 248 samples have revealed that the composition and distribution patterns of sediments within the Albemarle estuarine system (AES) represent a complex interaction between multiple sediment sources, basin morphology and evolution, and associated estuarine processes. Three sediment end-member types are dominant: sand, peat, and organic-rich mud (ORM). Throughout the AES, shallow perimeter platforms and associated sediment-bank shorelines are eroded into Pleistocene units. Shoreline recession supplies sand to the platforms and mud to the central basins; these sediments mix with suspended sediment from the fluvial drainages. Swamp forest-peat and marsh-peat shorelines are actively eroding and supply fine organic detritus to produce the dominant ORM sediment in the central basins. Perimeter platform sands grade into ORM on the platform slope. ORM constitutes about 70% of the benthic habitats within the AES and has an average composition of 76.2% inorganic mud, 13.1% sand, and 10.7% organic matter. The characteristics of ORM greatly affect the benthic community structure, chemical quality of the sediments, and the water quality of the estuary. ORM readily moves in and out of the water column in response to natural and anthropogenic activities, affecting water column turbidity and trace and major element geochemistry. Organic matter and clay minerals in ORM are chemically reactive and interact with the water column to adsorb or release contaminants, nutrients, and gases. Thus, ORM acts as both a sink and source for many different chemical constituents in the water column and plays important, but poorly understood, functions in the physical and chemical dynamics of estuarine ecosystems.  相似文献   

5.
The nutrients, carbon, nitrogen and phosphorus, significantly affect the quality of aquatic environments, especially when present at concentrations above natural levels. In this context, the sedimentary column can act as an environment for storage or accumulation of these nutrients and for the reprocessing of such substances in the water column and aquatic biota. In this context, this study aimed to estimate the concentration of total organic carbon (TOC), total nitrogen (TN), total phosphorus (TP), inorganic phosphorus (IP) and organic phosphorus (OP) in seven sediment samples that were collected from the Marrecas Stream microbasin (Caxias do Sul, Rio Grande do Sul State, Brazil). The relationships among the sediment nutrient concentrations and the levels of organic matter (OM), fine material (silt–clay) and the concentration of the metal species, Al, Fe and Mn, as well as the possible nutrient sources to the stream studied were also evaluated. The data set suggest that the TOC and IP appear to have a direct correlation with the vast riparian vegetation present in areas adjacent to the sampling points and to the physico-chemical properties of the water and sedimentary column. Moreover, the results obtained for TN suggest that its concentration possibly suffers interference from the temperature of the water and its oxygenation, in addition to other biological activities. On the other hand, one cannot rule out human interference, mainly in the levels of OP, possibly due to the inflow of domestic sewage to the stream.  相似文献   

6.
Hydrocarbon distribution rules in the deep and shallow parts of sedimentary basins are considerably different, particularly in the following four aspects. First, the critical porosity for hydrocarbon migration is much lower in the deep parts of basins: at a depth of 7000 m, hydrocarbons can accumulate only in rocks with porosity less than 5%. However, in the shallow parts of basins (i.e., depths of around 1000 m), hydrocarbon can accumulate in rocks only when porosity is over 20%. Second, hydrocarbon reservoirs tend to exhibit negative pressures after hydrocarbon accumulation at depth, with a pressure coefficient less than 0.7. However, hydrocarbon reservoirs at shallow depths tend to exhibit high pressure after hydrocarbon accumulation. Third, deep reservoirs tend to exhibit characteristics of oil (–gas)–water inversion, indicating that the oil (gas) accumulated under the water. However, the oil (gas) tends to accumulate over water in shallow reservoirs. Fourth, continuous unconventional tight hydrocarbon reservoirs are distributed widely in deep reservoirs, where the buoyancy force is not the primary dynamic force and the caprock is not involved during the process of hydrocarbon accumulation. Conversely, the majority of hydrocarbons in shallow regions accumulate in traps with complex structures. The results of this study indicate that two dynamic boundary conditions are primarily responsible for the above phenomena: a lower limit to the buoyancy force and the lower limit of hydrocarbon accumulation overall, corresponding to about 10%–12% porosity and irreducible water saturation of 100%, respectively.  相似文献   

7.
《Applied Geochemistry》2002,17(4):337-352
Organic C burial rates and C–S relationships were investigated in the Holocene sediment sequences of 3 shallow polymictic coastal lagoons in the southern Baltic Sea to better understand the biogeochemical cycling of C and S in these environmental systems. The results show that these lagoons may have a considerable influence on the environmental status of the southern Baltic Sea area in having the potential to act as a temporary sink or source for heavy metals. High organic C accumulation rates (Corg-AR) can be observed in the sediments due to a high organic matter supply from land and a high productivity of the water bodies as a result of eutrophication. However, organic C burial does not increase as a result of increasing sediment accumulation rates (SAR). Even when high sedimentation rates do occur, there appears to be a thorough recycling and resuspension of the sediment enhancing the biological decay of organic matter before burial or the removal of organic matter from the system by transport. That is why high SAR in the coastal lagoons do not enhance pyrite formation, and thereby permanent fixing of heavy metals in the sediments, to the extent that could be expected from their magnitude. Initially there is a high potential for a temporary binding of heavy metals, but the latter are likely to be subject to mobilization and redistribution within the sediments and the water column. The patterns of burial of organic and mineral matter are different from those observed in the present-day Baltic Proper, implying possible important links in deposition between the central and coastal areas of the Baltic Sea and implications for C cycling in the ecosystem of the Baltic Sea.  相似文献   

8.
Plankton studies in Kachemak Bay, Alaska were combined with short-term sediment trap deployments in order to show the relationships of fluxes of Cu and Mn in organic particulate matter with biological processes occurring in the overlying water column. A large spring bloom decrease throughout the summer, due to decreasing nutrient levels and increasing grazing pressure by zooplankton. The concentration of organically bound Cu and Mn in the sediment trap particulate material increased throughout the summer reaching a maximum in August while fecal pellet production exhibited a similar increase. The fluxes of total particulate matter and organic carbon reached a maximum in June and represented a 30% increase over the corresponding fluxes in May. In contrast, the fluxes of organically bound Cu and Mn and fecal pellets in August represented 200%, 360% and 760% increases, respectively, over their respective fluxes in May. These results suggest that the enrichment of Cu and Mn in the organic particulate matter during August was a result of bioaccumulation of these metals into fecal material. The increase in the flux of the organically bound metals indicates a strong coupling between biological processes in the water column and their vertical transport. Thus, the production and subsequent sinking of fecal pellets may govern the transport of trace metals to the underlying water column and may also govern the transfer of a primary source of food and its associated trace metals to benthic communities.  相似文献   

9.
The Maikop Formation, deposited in eastern Azerbaijan during Oligocene and Early Miocene times, contains prolific source rocks with primarily Type II organic matter. Paleontological analyses of dinoflagellate cysts revealed a Lower to Upper Oligocene age for the investigated succession near Angeharan. A major contribution of aquatic organisms (diatoms, green algae, dinoflagellates, chrysophyte algae) and minor inputs from macrophytes and land plants to organic matter accumulation is indicated by n-alkane distribution patterns, composition of steroids and δ13C of hydrocarbon biomarkers. Microbial communities included heterotrophic bacteria, cyanobacteria, chemoautotrophic bacteria, as well as green sulfur bacteria. Higher inputs of terrigenous organic matter occurred during deposition of the Upper Oligocene units of the Maikop Formation from Angeharan mountains. The terpenoid hydrocarbon composition argues for angiosperm dominated vegetation in the Shamakhy–Gobustan area.High primary bioproductivity resulted in a stratified water column and the accumulation of organic matter rich sediments in the Lower Oligocene units of the Maikop Formation. Organic carbon accumulation during this period occurred in a permanently (salinity-) stratified, mesohaline environment with free H2S in the water column. This is indicated by low pristane/phytane ratios of all sediments (varying from 0.37–0.69), lower methylated-(trimethyltridecyl)chromans ratio in the lower units and their higher contents of aryl isoprenoids and highly branched isoprenoid thiophenes. Subsequently, the depositional environment changed to normal marine conditions with oxygen deficient bottom water. The retreat of the chemocline towards the sediment–water interface and enhanced oxic respiration of OM during deposition of the Upper Oligocene Maikop sediments is proposed.Parallel depth trends in δ13C of total OM, n-alkanes, isoprenoids and steranes argue for changes in the regional carbon cycle, associated with the changing environmental conditions. Increased remineralisation of OM in a more oxygenated water column is suggested to result in low TOC and hydrocarbon contents, as well as 15N enriched total nitrogen of the Upper Oligocene units.  相似文献   

10.
山西省热矿水形成机制分析   总被引:1,自引:0,他引:1  
李世忠  鲁荣安 《地质论评》1994,40(3):221-228
本文以系统理论为指导,在深入研究地质北景的基础上,通过研究热矿水的含水介质,水动力场,水化学物和温度场的特征,划分了热矿水系统,探讨了热矿水的起源及形成机制,将山西热矿水的形成归纳为异常增温型和正常增温型两种基本模式,异常增温型又根据地质结构的不同,地下水径流条件的差异,列举了三种典型模式,最后指出了寻找热矿水的方向,开发利用热矿资源应注意的问题。  相似文献   

11.
Chemical, physical, and biological features of streams and ground water of the North-Eastern area of Rome are jointly analyzed in order to assess the status of water resources. Ground water was investigated with classical survey methods (pH, temperature, and electric conductivity). Microbiological pollution, faunal composition, and stream surrounding area conditions of surface waters were studied, in order to quantify the residual value of these ecosystems from both a human and an environmental point of view. Results show a general impairment of the system and the comparison between superficial waters and shallow ground waters makes it possible to detect the presence of a connection between the two levels. This relationship occurs as an exchange from superficial waters (streams and rivers) to the shallow aquifers. Where superficial waters are contaminated, as in the Tor Sapienza stream, pollutants move to the shallow aquifers too, due to the decreased pressure of the over-exploited aquifer. Moreover, uncontrolled drilling activity, diffused in urban areas, makes it possible the connection between shallow and deep ground water. Notwithstanding this, the mixing between superficial and deep ground water system in Rome is not very widespread and, apparently, limited to restricted areas.  相似文献   

12.
Sedimentary biomarker distributions can record ocean productivity and community structure, but their interpretation must consider alteration during organic matter (OM) export and burial. Large changes in the water column redox state are known to impact on the preservation of biomarkers, but more subtle variation in sediment redox conditions, characteristic of major modern ocean basins, have been less thoroughly investigated. Here we evaluate changes in biomarker distributions during sinking and burial across a nearshore to offshore transect in the southwestern Cape Basin (South East Atlantic), which includes a range of sedimentary environments. Biomarker concentrations and distributions in suspended particulate matter from the upper water column were determined and compared with underlying sedimentary biomarker accumulation rates and distributions. Biomarker distributions were similar in surface and subsurface waters, indicating that the OM signature is exported from the ocean mixed layer with minimal alteration. We show that, while export production (100 m) is similar along this transect, 230Thxs-corrected biomarker accumulation rate varies by over an order of magnitude in sediments and is directly associated with sedimentary redox conditions, ranging from oxic to nitrogenous–ferruginous. Biomarker distributions were dominated by sterols in surface water, and by alkenones in underlying sediments, which we propose to be primarily the result of selective preservation. Notably, the difference in sediment O2 penetration depth was associated with relative biomarker preservation. Subtle variation in sedimentary redox conditions has a dramatic impact on the distribution of preserved biomarkers. We discuss mechanisms for preferential degradation of specific biomarkers within this setting.  相似文献   

13.
江苏平原地区(淮河流域)潜水碘含量控制因素探讨   总被引:1,自引:0,他引:1  
陆徐荣  杨磊  陆华  谷小溪 《地球学报》2014,35(2):211-216
本文通过工作区潜水碘含量的分布特点,与所处土壤、水文地质条件、地形地貌等一起进行综合分析,对地下水中碘的控制因素有了一个全新的认识:与前人认为地下水中碘的含量与有机质成正比的观点不同的是,本文认为地下水中碘的含量与有机质含量无固定关系,但有机质有助于促进水溶性碘的增加,相似水文地质条件下成正比;地下水径流条件对潜水碘含量影响重大,径流条件较好的丘陵、岗地往往较低,地势低平、径流条件较差的洼地和泛滥沉积区往往为高碘地区;相同水文地质条件下,地下水中的碘含量与土壤中的含量成正比;碘的另一重要特征是在地下水中的浓度较为稳定,随时间、开采而变化不大。  相似文献   

14.
恩平凹陷隆起带远离洼陷生烃中心,油气以侧向运移为主。基于浅层断裂埋藏浅、活动晚、封闭性弱的特征,提出穿断成藏模式成功地指导了隆起带勘探,发现一批商业性油田。对恩平凹陷南、北隆起带浅层主要油田成藏特征进行剖析,阐述了浅层油气穿越未成岩断裂运移富集成藏模式及其成因机制。断层岩弱成岩导致有限油柱封闭高度与油气强充注是其形成机制,弱成岩是关键。断裂-输导砂体-构造脊构成多次穿断运移的地层格架,油气充注强度与圈闭汇聚能力的平衡控制穿断运移路径上圈闭的富集程度,断-储排替压差控制穿断过程中油气垂向侧向分流。穿断运移成藏模式对浅层油气成藏具有一定借鉴意义。  相似文献   

15.
在对汶泗河冲洪积平原水文地质条件和污染源现状进行阐述的基础上,对不同含水岩组无机组分指标进行了分析,表明浅层孔隙水和部分地区岩溶裂隙水无机组分含量大幅增高,深层孔隙水无机物含量则变化不大。在有机污染方面,浅层孔隙水有机物检出率26.8%,但含量很低,远未达到饮用水标准限值;岩溶裂隙水有机物检出率46.7%,检出率相对较高,局部地段有机物超标;深层孔隙水有机物基本未检出。该区地下水污染评价结果表明,浅层孔隙水和岩溶裂隙水无机污染呈面状污染特征,且污染程度较重,而有机污染则呈现点状污染特征,且污染程度总体较轻。对研究区地下水污染现状,提出了地下水安全供水对策。  相似文献   

16.
Longitudinal variation in factors affecting phytoplankton production were analyzed to better understand the mechanisms that cause the formation of a chlorophyll maximum within the tidal freshwater James River. Phytoplankton production was two- to threefold higher in the region where persistent elevated chlorophyll concentrations occurred. Near this site, the morphology of the James transitions from a narrow, deep channel to a broad expanse with shallow areas adjoining the main channel. Shallower depths resulted in greater average irradiance within the water column and suggest that release from light limitation was the principal factor accounting for the location of the chlorophyll maximum. Grazing rates were low indicating that little of the algal production was directly consumed by zooplankton. Low exploitation by zooplankton was attributed to poor food quality due to high concentrations of non-algal particulate matter and potential presence of cyanobacteria. Metabolism data suggest that two thirds of net primary production was respired in the vicinity of the chlorophyll maximum and one third was exported via fluvial and tidal advection. Comparison of water column and ecosystem metabolism indicates that the bulk of respiration occurred within the sediments and that sedimentation was the dominant loss process for phytoplankton.  相似文献   

17.
Available data on synthesis, input, and decomposition of organic matter (OM) in the water column and recent bottom sediments of the World Ocean are generalized. The most reliable values of OM production and masses in the ocean, the total supply of organic carbon, and the input of terrigenous OM with coastal erosion, river runoff, and eolian matter are estimated. Maps of fossilization coefficients, distribution, and accumulation of OM in recent bottom sediments of the World Ocean are presented. A numerical expression is proposed for the main circumcontinental pattern of OM accumulation in the ocean. The group and elemental compositions of living matter of the ocean, land, and the Earth as a whole and the organic composition of bottom sediments are briefly considered.  相似文献   

18.
页岩能源矿产已成为国内外研究热点,并掀起一场“页岩革命”,其主要包括油页岩、页岩油、页岩气等非常规页岩能源资源。这套页岩能源矿产与富有机质泥岩密切相关,其在成因上存在一定的联系和共生规律,但成矿(藏)条件又存在明显的不同。松辽盆地上白垩统青山口组发育厚层的暗色泥岩,由于其面积巨大,泥岩中有机质丰度高,埋藏深度差异明显,具备形成页岩能源共生矿产成矿(藏)的地质条件。初步分析认为,松辽盆地青山口组下部暗色泥岩有机质丰度较高,有机质类型主要为I~II1型,为油页岩成矿,页岩油、页岩气成藏提供足够的有机质来源,其中在松辽盆地东南隆起区,青山口组埋藏较浅(深度<1 000 m),有机质热演化程度较低(Ro<0.7%),为良好的油页岩成矿场所。埋藏浅的富有机质泥岩可能因微生物活动而形成生物成因页岩气,较弱的成岩压实作用和极为丰富的有机质为页岩气成藏提供足够的空间(孔隙度4%~14%)。从盆地东部的隆起带到中央凹陷区,随着埋深加大(深度>1 000 m),热演化程度逐渐增强(Ro:0.7%~1.2%),基本处于成熟-过熟阶段,有机质大量排烃,为页岩油、页岩气成藏提供足够的来源。异常高压和排烃造孔形成良好的储层,使泥页岩具备页岩油、气成藏的良好条件。因此,松辽盆地可能存在呈环形的页岩能源矿产成矿(藏)规律,其中在东南隆起区和中央凹陷隆起地区为油页岩成矿和生物型页岩气有利成藏带;中央凹陷大部分地区可能为页岩油、热解型页岩气有利成藏带;中央凹陷埋藏最深部位可能发育热裂解型页岩气有利成藏带。  相似文献   

19.
黑河中下游荒漠区植物多样性分布对土壤水分变化的响应   总被引:9,自引:0,他引:9  
基于对黑河流域中下游荒漠区植被和土壤生境的调查分析,以土壤水分在各调查样地中的差异来反映研究区的生态水文特征,采用种的丰富度和多度来代表荒漠植物多样性研究了荒漠植物,包括隐花植物多样性分布对土壤水分变化的响应。土壤水分变化不仅直接影响着荒漠植物的多样性,而通过影响其它生境因子又间接地影响着多样性的维持。因此,如何维持中下游相对稳定的土壤水分来源是该区荒漠植物多样性保育今后所要面临的挑战。  相似文献   

20.
在川南及邻区下志留统龙马溪组下段沉积相详细研究的基础上,结合偏光显微镜、X衍射及元素地球化学分析等,提出沉积相对页岩气地质条件的影响特征。研究发现:川南及邻区龙马溪组下段主要发育潮坪相和浅海陆棚相。局限滞留的缺氧还原环境、快速海侵形成的分层水体、适宜的沉积速率及较高的生物产率,造成了龙马溪组下段有机质富集,并以硅质型页岩为主,利于页岩气的富集与开发。隆起边缘的潮坪相沉积,为页岩气的非有利区;沉积中心的深水陆棚沉积区,主要发育碳质硅质页岩、碳质页岩与含粉砂含钙碳质页岩,为页岩气的有利区;砂泥质浅水陆棚含有较高的有机质,应为页岩气发育的次级有利区;灰泥质浅水陆棚主要发育“钙质页岩+含碳泥质灰岩”,有机质含量相对较低,为页岩气的较不利发育区。  相似文献   

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